JPH0291198A - Liquid detergent composition - Google Patents
Liquid detergent compositionInfo
- Publication number
- JPH0291198A JPH0291198A JP24295588A JP24295588A JPH0291198A JP H0291198 A JPH0291198 A JP H0291198A JP 24295588 A JP24295588 A JP 24295588A JP 24295588 A JP24295588 A JP 24295588A JP H0291198 A JPH0291198 A JP H0291198A
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- liquid detergent
- formula
- carbon atoms
- alkanolamine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 19
- 239000007788 liquid Substances 0.000 title claims abstract description 12
- 239000003599 detergent Substances 0.000 title abstract description 11
- MTNDZQHUAFNZQY-UHFFFAOYSA-N imidazoline Chemical compound C1CN=CN1 MTNDZQHUAFNZQY-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000004094 surface-active agent Substances 0.000 claims abstract description 10
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 9
- 125000003342 alkenyl group Chemical group 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 6
- 150000001768 cations Chemical class 0.000 claims abstract description 6
- 229910052739 hydrogen Inorganic materials 0.000 claims abstract description 6
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 6
- 229910052700 potassium Inorganic materials 0.000 claims abstract description 5
- 238000004140 cleaning Methods 0.000 claims description 10
- 125000004432 carbon atom Chemical group C* 0.000 claims description 8
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 2
- 239000001257 hydrogen Substances 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- 238000005187 foaming Methods 0.000 abstract description 10
- 239000002253 acid Substances 0.000 abstract description 3
- 150000003839 salts Chemical class 0.000 abstract description 3
- 238000002156 mixing Methods 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract 1
- -1 alkylbenzene sulfonates Chemical class 0.000 description 6
- 239000002453 shampoo Substances 0.000 description 5
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000010521 absorption reaction Methods 0.000 description 3
- 239000002280 amphoteric surfactant Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 239000012153 distilled water Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XWECHXDFKBPXQY-IBGZPJMESA-N (2s)-2-(octadecanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCCCCCCCC(=O)N[C@H](C(O)=O)CC(O)=O XWECHXDFKBPXQY-IBGZPJMESA-N 0.000 description 2
- 108010088751 Albumins Proteins 0.000 description 2
- 102000009027 Albumins Human genes 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- CKLJMWTZIZZHCS-REOHCLBHSA-N L-aspartic acid Chemical compound OC(=O)[C@@H](N)CC(O)=O CKLJMWTZIZZHCS-REOHCLBHSA-N 0.000 description 2
- 108010058846 Ovalbumin Proteins 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 235000003704 aspartic acid Nutrition 0.000 description 2
- OQFSQFPPLPISGP-UHFFFAOYSA-N beta-carboxyaspartic acid Natural products OC(=O)C(N)C(C(O)=O)C(O)=O OQFSQFPPLPISGP-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000007865 diluting Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 239000000178 monomer Substances 0.000 description 2
- 229940092253 ovalbumin Drugs 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- XFBKKGFUMFHHHK-VJIACCKLSA-N (2s)-2-[[(z)-octadec-9-enoyl]amino]butanedioic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)N[C@H](C(O)=O)CC(O)=O XFBKKGFUMFHHHK-VJIACCKLSA-N 0.000 description 1
- VCRXMSMANOGRCM-UHFFFAOYSA-N 2-(dodecanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCC(=O)NC(C(O)=O)CC(O)=O VCRXMSMANOGRCM-UHFFFAOYSA-N 0.000 description 1
- MLOYYKYQLFOZOE-UHFFFAOYSA-N 2-(tetradecanoylamino)butanedioic acid Chemical compound CCCCCCCCCCCCCC(=O)NC(C(O)=O)CC(O)=O MLOYYKYQLFOZOE-UHFFFAOYSA-N 0.000 description 1
- QCVGEOXPDFCNHA-UHFFFAOYSA-N 5,5-dimethyl-2,4-dioxo-1,3-oxazolidine-3-carboxamide Chemical compound CC1(C)OC(=O)N(C(N)=O)C1=O QCVGEOXPDFCNHA-UHFFFAOYSA-N 0.000 description 1
- KWIUHFFTVRNATP-UHFFFAOYSA-N Betaine Natural products C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- 241000750631 Takifugu chinensis Species 0.000 description 1
- BAECOWNUKCLBPZ-HIUWNOOHSA-N Triolein Natural products O([C@H](OCC(=O)CCCCCCC/C=C\CCCCCCCC)COC(=O)CCCCCCC/C=C\CCCCCCCC)C(=O)CCCCCCC/C=C\CCCCCCCC BAECOWNUKCLBPZ-HIUWNOOHSA-N 0.000 description 1
- PHYFQTYBJUILEZ-UHFFFAOYSA-N Trioleoylglycerol Natural products CCCCCCCCC=CCCCCCCCC(=O)OCC(OC(=O)CCCCCCCC=CCCCCCCCC)COC(=O)CCCCCCCC=CCCCCCCCC PHYFQTYBJUILEZ-UHFFFAOYSA-N 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 235000001014 amino acid Nutrition 0.000 description 1
- 150000001413 amino acids Chemical class 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 229960003237 betaine Drugs 0.000 description 1
- 239000000872 buffer Substances 0.000 description 1
- 239000007853 buffer solution Substances 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000004587 chromatography analysis Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 238000004925 denaturation Methods 0.000 description 1
- 230000036425 denaturation Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 235000014103 egg white Nutrition 0.000 description 1
- 210000000969 egg white Anatomy 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000007850 fluorescent dye Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930195712 glutamate Natural products 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 235000013923 monosodium glutamate Nutrition 0.000 description 1
- 239000004223 monosodium glutamate Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 208000017520 skin disease Diseases 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000002269 spontaneous effect Effects 0.000 description 1
- 238000010998 test method Methods 0.000 description 1
- 239000012085 test solution Substances 0.000 description 1
- PHYFQTYBJUILEZ-IUPFWZBJSA-N triolein Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCC(OC(=O)CCCCCCC\C=C/CCCCCCCC)COC(=O)CCCCCCC\C=C/CCCCCCCC PHYFQTYBJUILEZ-IUPFWZBJSA-N 0.000 description 1
- 229940117972 triolein Drugs 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Cosmetics (AREA)
- Detergent Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は新規な洗浄剤組成物に関する。さらに詳しくは
、手肌にマイルドで優れた洗浄力、起泡力ヲ有するシャ
ンプー、ボディシャン７′〜洗顔用、食器洗浄用の液体
洗浄剤組成物に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a novel cleaning composition. More specifically, the present invention relates to a liquid detergent composition for shampoos, body shampoos, face washes, and dishwashers that are mild to the skin of hands and have excellent detergency and foaming power.
従来、たとえばシャンプーに配合されるアニオン界面活
性剤としてアルキルベンゼンスルホン酸塩、高級アルコ
ール硫酸エステル塩、アルキルエーテル硫酸塩、高級脂
肪酸塩などの陰イオン界面活性剤が広汎に使用されてい
るが、これらの界面活性剤を含有する洗浄剤は、手肌に
対するマイルド性の点で不十分である。−力、アミノ酸
の一種であるグルタばン酌をアンル化して得られるＮ−
アシルグルタミン酸塩は、皮膚に対して温和であるばか
りでなく皮膚病の原因となる有害微生物の′ｆ：殖を抑
制する効果を有するので、近時シャンプーやボディーシ
ャンプーに配合される傾向にある。Conventionally, anionic surfactants such as alkylbenzene sulfonates, higher alcohol sulfate ester salts, alkyl ether sulfates, and higher fatty acid salts have been widely used as anionic surfactants in shampoos. Cleaning agents containing surfactants are insufficiently mild to the skin of hands. - N, obtained by unruling glutaban, a type of amino acid -
Acyl glutamates are not only mild to the skin, but also have the effect of inhibiting the growth of harmful microorganisms that cause skin diseases, and have recently been incorporated into shampoos and body shampoos.
而し、Ｎ−アシルグルタミン酸塩は、このもの単独の水
溶液では、油汚垢の著るしく多い汚物、例えばポマード
の付着した髪の洗浄などに対しては洗浄力、起泡力が不
足している。However, N-acyl glutamate, when used alone as an aqueous solution, lacks cleaning power and foaming power when cleaning dirt with a significant amount of oil stains, such as hair with pomade attached. .
このためＮ−アシルグルタミン酸塩をアルキルベタイン
やイミダゾリン系の界面活性剤と併用する事により手肌
に対するマイルド性を損なわずに洗浄力、起泡力を改善
する方法が特公昭５０−２３６８２号公報及び特公昭５
１−４２６０３号公報に開示されているが、洗浄力、起
泡力の点で未だ不十分である。For this reason, Japanese Patent Publication No. 50-23682 discloses a method of improving detergency and foaming power without impairing the mildness to hand skin by using N-acylglutamate in combination with alkyl betaine or imidazoline surfactants. Tokuko Showa 5
Although it is disclosed in Japanese Patent No. 1-42603, it is still insufficient in terms of detergency and foaming power.
本発明は、手肌に対するマイルド性を損なうことなく起
泡力、洗浄力、低温安定性に優れた液体洗浄剤組成物を
提供せんとするものである。The present invention aims to provide a liquid detergent composition that has excellent foaming power, detergency, and low-temperature stability without impairing its mildness to hand skin.
本発明は、Ｎ−アシルアスパラギン酸塩とイミダゾリン
系両性界面活性剤とを含有してなる洗浄剤組成物を提供
するものである。The present invention provides a cleaning composition containing an N-acylaspartate and an imidazoline amphoteric surfactant.
本発明において用いられるＮ−アシルアスパラギン酸塩
は、次の一般式（１）で示される化合物である。The N-acylaspartate used in the present invention is a compound represented by the following general formula (1).
ＲＣＯ−ＮＨ−ＣＨＣＯＯＭｌ （１１ＣＨ２Ｃ
００Ｍ２
（式中、Ｒは〕ないし２１の炭素原子を有するアルキル
基またはアルケニル基、隨およびＭ２は水素またはＮ＆
ＸＫ、 ＮＨ４もしくはアルカノールアミンから誘導さ
れるカチオンである。）Ｎ−アシルアスパラギン酸塩は
、Ｌ一体またはＤ一体または両者の混合物からなり、適
当なものとして、例えば、Ｎ−ラウロイルアスパラギン
酸、Ｎ−ミリストイルアスパラギン酸、Ｎ−ハルきトイ
ルアスパラギン／ｆｆ、Ｎ−ステアロイルアスパラギン
酸、Ｎ−バルミトイルアスパラギン酸、Ｎ−ステアロイ
ルアスパラギン酸、Ｎ−オレオイルアスパラギン酸およ
びＮ−ココイルアスパラギン酸またはそれらの酸のナト
リウム、カリウム、モノエタノールアンモニウム、ジェ
タノールアンモニウムまたはトリエタノールアンモニウ
ム塩などが挙げられる。RCO-NH-CHCOOMl (11CH2C
00M2 (wherein R is an alkyl or alkenyl group having 21 to 21 carbon atoms, and M2 are hydrogen or N&
XK, a cation derived from NH4 or an alkanolamine. ) N-acylaspartate is composed of L monomer or D monomer or a mixture of both, and suitable examples include N-lauroyl aspartic acid, N-myristoyl aspartic acid, N-haloylasparagine/ff, N -stearoyl aspartic acid, N-balmitoyl aspartic acid, N-stearoyl aspartic acid, N-oleoylaspartic acid and N-cocoyl aspartic acid or sodium, potassium, monoethanolammonium, jetanolammonium or triethanol of these acids; Examples include ammonium salts.
本発明において用いられるもう一つの成分であるイミダ
ゾリン系両性界面活性剤は次の一般式（２）で示される
化合物である。The imidazoline amphoteric surfactant, which is another component used in the present invention, is a compound represented by the following general formula (2).
Ｏ
Ｈ
（式中、Ｒ１は炭素ａ４ないし１８のアルキル基または
アルケニル基、Ｒ２は炭素ｅ！Ｌ１ないし４のアルキレ
ン基、烏は炭素数１ないし４のアルキレン基またはＯＨ
基で置換されたアルキレン基、Ｍ３はＨ，Ｎａ、ＫＳＮ
Ｈ４もしくはアルカノールアミンから誘導されるカチオ
ンである。）このような化合物として、例えば下式
で示されるものが挙げられる。O H (wherein, R1 is an alkyl group or alkenyl group having a4 to 18 carbon atoms, R2 is an alkylene group having carbon e!L1 to 4, and Karasu is an alkylene group having 1 to 4 carbon atoms or OH
alkylene group substituted with a group, M3 is H, Na, KSN
It is a cation derived from H4 or an alkanolamine. ) Examples of such compounds include those represented by the following formula.
本発明の液体洗浄剤組成物は、Ｎ−アシルアスパラギン
酸塩とイミダゾリン系界面活性剤の配合比が重置比で５
：ｌから１：５の範囲において特に優れた性能を示す。In the liquid detergent composition of the present invention, the blending ratio of N-acylaspartate and imidazoline surfactant is 5.
Particularly excellent performance is shown in the range of :1 to 1:5.
本発明の洗浄剤組成物においては、前記の各成分の他に
、通常液体洗浄剤組成物に配合される公知の配合成分、
例えば本発明の効果を損なわない１の両性界面活性剤、
非イオン性界！Ｊｉｌｉ活性剤、さらにグリセリンやプ
ロピレングリコール、無機塩などの粘度ｆＩ４整剤１可
溶化剤、香料、螢光染料、無機または有機のビルグーを
含むことができる。In the cleaning composition of the present invention, in addition to the above-mentioned components, known ingredients that are usually added to liquid cleaning compositions,
For example, 1 amphoteric surfactant that does not impair the effects of the present invention,
Non-ionic world! Jili activators, as well as viscosity modifiers, solubilizers such as glycerin, propylene glycol, inorganic salts, fragrances, fluorescent dyes, and inorganic or organic virgoos.
本発明の液体洗浄剤組成物は、皮膚にマイルドでかつ油
汚垢の著るしい汚物に対してすぐれた洗浄力および起泡
力を有するものである。The liquid detergent composition of the present invention is mild to the skin and has excellent detergency and foaming power against dirt with significant oil stains.
次に実施例によって本発明をさらに詳細に説明するが、
本発明はこれらの実施例に限定されるものではない。Next, the present invention will be explained in more detail with reference to Examples.
The present invention is not limited to these examples.
実施例
Ｎ−ラウロイルし一アスパラギン酸ナトリウムと前記式
［２１−（ａ）で示されるイミダゾリン系界面活性剤を
下表１に示すＭ、清百分率で含有する液体洗浄剤組成物
を調製し、その起泡力、洗浄力及びフィルド性を評価し
た。Example N - A liquid detergent composition containing sodium lauroyl monoaspartate and an imidazoline surfactant represented by the above formula [21-(a) at a cleaning percentage of M shown in Table 1 below was prepared. Foaming power, detergency and filling properties were evaluated.
比較例Ｉ
Ｎ−ラウロイルし一アスパラギン酸ナトリウムと前記式
＋２１− （ａ）で示されるイミダゾリン系界面活性剤
をそれぞれ実施例と同様にして比較評価し、その結果を
下表１に示した。Comparative Example I Sodium N-lauroyl monoaspartate and the imidazoline surfactant represented by the formula +21- (a) were comparatively evaluated in the same manner as in the examples, and the results are shown in Table 1 below.
比較例２
Ｎ−ラウロイルし一グルタミン酸ナトリウムと前記式（
２１−（ａ）で示されるイミダゾリン系界面活性剤を含
有するｒＬ体洗浄剤組成物の各物性を実施例と同様にし
て比較評価し、その結果を下表１に示した。Comparative Example 2 N-lauroyl monosodium glutamate and the above formula (
The physical properties of the rL body cleansing composition containing the imidazoline surfactant represented by 21-(a) were comparatively evaluated in the same manner as in Examples, and the results are shown in Table 1 below.
尚、各特性の評価は次に示す試験法に従って行なった。In addition, evaluation of each characteristic was performed according to the test method shown below.
（１）起泡力
液体洗浄剤組成物を蒸留水で２００倍に希釈した水溶液
を２０−１油成分としてトリオレイン１ｔを共栓付１０
０＊ｔメスシリンダーに入れ、共栓をして２０回激しく
上下に振とつする。振とり後、直ちに水平な場所に静儂
し、泡の容喰を目盛りから読み取りこれを起泡力とする
。(1) Foaming power An aqueous solution prepared by diluting a liquid detergent composition 200 times with distilled water is used as a 20-1 oil component, and 1 t of triolein is added to the 10-10 with a stopper.
Place in a 0*t graduated cylinder, cover with a stopper, and shake vigorously up and down 20 times. Immediately after shaking, place it on a horizontal surface, read the foam volume from the scale, and use this as the foaming power.
（２）洗浄力
スライドグラスをモテル汚垢（下表）に１〜２秒浸透し
、汚垢を付着させ風乾後リーナッッ改良洗浄力試１険器
を用いて試ム険する。試験溶液としては、液体洗浄剤組
成物を２００倍（界面活ｉ生剤として０．１重情％含有
）に蒸留水で希釈した溶液を用いて、２５℃で３分間、
２５Ｏｒｐｍで洗浄し、２５℃で１分間すすぐ。すすい
だ後、スライドグラスを風乾して残存油吐を測定し、下
式から洗、争効率を算出する。(2) Detergency: Penetrate the slide glass into Motel stains (see table below) for 1 to 2 seconds, allow the stains to adhere, and after air drying, test using a Re-Nut Improved Detergency Test 1 instrument. As a test solution, a solution prepared by diluting the liquid detergent composition 200 times (contains 0.1% as a surfactant) with distilled water was used, and the solution was diluted with distilled water at 25°C for 3 minutes.
Wash at 25 rpm and rinse for 1 minute at 25°C. After rinsing, the slide glass is air-dried, the amount of residual oil is measured, and the washing and fighting efficiency is calculated using the formula below.
ＷＳ：洗浄前の油汚垢付府惜
ｗｗ：洗浄後の油汚垢付Ｒ惜
表、モデル汚垢組成
（３）マイルド性
水系高速クロマトグラフィーを利用して卵白アルブミン
のｐＨ７緩衝溶液に洗剤組成物濃度が１重駄％になるよ
うに試料を加えた場合のアルブミンの変性率を、２２０
ｎｍの吸収ピークを用いて下式より算出する。WS: Oil stains before cleaning R: Table of oil stains after cleaning, model stain composition (3) Detergent composition concentration in egg white albumin pH 7 buffer solution using mild aqueous high-speed chromatography The denaturation rate of albumin when the sample is added so that the weight is 1% is 220%.
It is calculated from the following formula using the absorption peak in nm.
ＨＯ；卵白アルブミンの２２０ｎｍ吸収ピークの茜さ
Ｈ３；卵白アルブミン緩衝液に試料を加えたときの２２
０ｎｍ吸収ピークの高さ
マイルド性の判定は下表の基準に拠った。HO; the 220 nm absorption peak of ovalbumin, the brightness H3; 22 when the sample is added to the ovalbumin buffer
The height of the 0 nm absorption peak was determined based on the criteria shown in the table below.
手続補正書 （自発） 事件の表示 事件との関係Procedural amendment (spontaneous) Display of incidents Relationship with the incident
Claims (1)
酸塩と下記一般式（２）で表わされるイミダゾリン系界
面活性剤とを含有してなる液体洗浄剤組成物。 ▲数式、化学式、表等があります▼（１） （式中、Ｒは７ないし２１の炭素原子を有するアルキル
基またはアルケニル基、Ｍ＿１およびＭ＿２は水素また
はＮａ、Ｋ、ＮＨ＿４もしくはアルカノールアミンから
誘導されるカチオンである。）▲数式、化学式、表等が
あります▼（２） （式中、Ｒは炭素数４ないし１８のアルキル基またはア
ルケニル基、Ｒ＿２は炭素数１ないし４のアルキレン基
、Ｒ＿３は炭素数１ないし４のアルキレン基またはＯＨ
基で置換されたアルキレン基、Ｍ＿３はＨ、Ｎａ、Ｋ、
ＮＨ＿４もしくはアルカノールアミンから誘導されるカ
チオンである。）[Scope of Claims] A liquid cleaning composition comprising an N-acylaspartate represented by the following general formula (1) and an imidazoline surfactant represented by the following general formula (2). ▲There are mathematical formulas, chemical formulas, tables, etc.▼ (1) (In the formula, R is an alkyl group or alkenyl group having 7 to 21 carbon atoms, M_1 and M_2 are hydrogen or derived from Na, K, NH_4 or alkanolamine. ) ▲ Numerical formulas, chemical formulas, tables, etc. ▼ (2) (In the formula, R is an alkyl group or alkenyl group having 4 to 18 carbon atoms, R_2 is an alkylene group having 1 to 4 carbon atoms, and R_3 is a cation having 1 to 4 carbon atoms. Alkylene group having 1 to 4 carbon atoms or OH
alkylene group substituted with a group, M_3 is H, Na, K,
It is a cation derived from NH_4 or alkanolamine. )
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63242955A JP2695448B2 (en) | 1988-09-28 | 1988-09-28 | Liquid detergent composition |
| US07/390,211 US5000877A (en) | 1988-08-12 | 1989-08-07 | Aqueous liquid detergent containing an N-acylaspartate and a betaine or imidazoline surfactant |
| DE89114830T DE68910617T2 (en) | 1988-08-12 | 1989-08-10 | Liquid detergent. |
| EP89114830A EP0356784B1 (en) | 1988-08-12 | 1989-08-10 | Liquid detergent composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63242955A JP2695448B2 (en) | 1988-09-28 | 1988-09-28 | Liquid detergent composition |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH0291198A true JPH0291198A (en) | 1990-03-30 |
| JP2695448B2 JP2695448B2 (en) | 1997-12-24 |
Family
ID=17096712
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63242955A Expired - Fee Related JP2695448B2 (en) | 1988-08-12 | 1988-09-28 | Liquid detergent composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2695448B2 (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0423896A (en) * | 1990-05-18 | 1992-01-28 | Kanebo Ltd | Low-irritation detergent composition |
| JP2005350645A (en) * | 2004-05-13 | 2005-12-22 | Asahi Kasei Chemicals Corp | Detergent composition |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59230099A (en) * | 1983-06-13 | 1984-12-24 | 味の素株式会社 | Transparent gel-like detergent composition |
-
1988
- 1988-09-28 JP JP63242955A patent/JP2695448B2/en not_active Expired - Fee Related
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS59230099A (en) * | 1983-06-13 | 1984-12-24 | 味の素株式会社 | Transparent gel-like detergent composition |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0423896A (en) * | 1990-05-18 | 1992-01-28 | Kanebo Ltd | Low-irritation detergent composition |
| JP2005350645A (en) * | 2004-05-13 | 2005-12-22 | Asahi Kasei Chemicals Corp | Detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2695448B2 (en) | 1997-12-24 |
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