JPH0288511A - Solid water-in-oil type emulsified cosmetic - Google Patents

Abstract

PURPOSE:To provide a cosmetic having good stability and durability and having a refreshing feeling in spite of a solid-like state when coated on the skin by containing an oil, a solid wax and/or on oil-gelling agent, water, an oleophilic surfactant and a powder for hydrophobic treatment. CONSTITUTION:The subject cosmetic contains 5-85wt.% of an oil (e.g., silicone oil or olive oil), 5-20wt.% of a solid wax (e.g., paraffinic wax) and/or an oil- gelling agent (e.g., dibenzylidene sorbitol) (the ratio of both is 20:1-3:1), 10wt.% of water, 0.2-10wt.% of an oleophilic surfactant (e.g., sorbitan monoisostearate) and 5-50wt.% of a powder for hydrophobic treatment. The cosmetic is excellent because of being reduced in the evaporations of therefrom and being free from crazes, cracks, etc., has good coverability and exhibits a refreshing feeling of use.

Description

[Detailed Description of the Invention] [Industrial Application Field 1] The present invention has good stability, good makeup retention, and has a refreshing feeling when applied to the skin even though it is solid. The present invention relates to a solid water-in-oil emulsion cosmetic with a novel feel when used.

In addition, in the present invention, solid water-in-oil emulsion cosmetic f: [ refers to those that have no fluidity and solidify (including paste) in the temperature range (0°C to 50°C) where cosmetics are normally used. say.

F Conventional technology J Commonly used base types for solid cosmetics include solid oil-based types made by solidifying oil, solid pressed types made by pressing powder or a mixture of powder and oil, etc. There are different types of cosmetics, and they are used depending on the purpose and method of use of the cosmetic. For example, solid oil-based cosmetics such as lipsticks are generally used, and foundations used in puffs and sponges are generally pressed solid types. In recent years, lipsticks that contain water have been studied and are on the market, but it is difficult to obtain lipsticks that are stable and have good makeup retention, so even if water is added, the amount is small and the texture is poor. The difference from the conventional solid oil-based type was small. Additionally, oil-based products that contain water and powder have drawbacks such as a sudden loss of stability and poor makeup retention when the type of powder is changed. In other words, no solid water-in-oil emulsion cosmetic with good stability and good makeup retention has been found in the prior art. In particular, when a volatile oil is used and a large amount of water is blended, it is more difficult to solve stability problems such as cracks and cracks and to obtain a product with good cosmetic quality.

On the other hand, emulsified cosmetics are generally used as basic cosmetics because they can contain water, moisturizers, etc. and have high treatment properties. In the case of an emulsion type, the content state that can be selected is a fluid emulsion or a less fluid cream. If the emulsion is in a bottle or tube-like container, it is filled in a bottle-like container. For this reason, although emulsified cosmetics have high effects on the skin, they are inferior in portability.

In addition, in recent years, cosmetics using volatile oils have been studied, and although relatively stable emulsions and creams have been obtained, solid products have not been produced. Although the stability was good, the shortcomings in the feel of use, such as makeup retention and refreshing feeling, were not completely resolved.

E. Problems to be Solved by the Present Invention] Therefore, there is no known solid water-in-oil emulsion cosmetic that is stable and has a good feel in use, particularly in cosmetic appearance.

In view of these circumstances, the present inventors conducted extensive research with the aim of obtaining a solid water-in-oil emulsion cosmetic that has good stability and makeup retention, and is easy to use. A solid water-in-oil emulsion cosmetic consisting of an oil-based solidifying agent, a hydrophobized powder, water, and a lipophilic surfactant has extremely good stability and is easy to apply to the skin. At the same time, it has a new feeling of use, such as good makeup application and 'iR cool feeling', and at the same time, it also has an excellent feeling of use such as spreading, 'zabariza', etc. It was discovered that the present invention has the advantage that the range can be expanded, and based on this knowledge, the present invention was completed.

[Means for Solving the Problems J] That is, the present invention combines an oil component, a solid wax and/or an oil gelling agent, water, a lipophilic surfactant, and a hydrophobized powder. The present invention provides a solid water-in-oil emulsion cosmetic characterized by containing:

The configuration of the present invention will be described below.

Examples of oils used in the present invention include avocado oil, camellia oil, tardle oil, macadamia nut oil, corn oil, mink oil, olive oil, rapeseed oil, egg yolk oil, sesame oil, basic oil, wheat germ oil, sasanqua oil, Castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil,
Peanut oil, tea seed oil, kaya oil, rice bran oil, shinakiri oil,
Japanese tung oil, jojoba oil, germ oil, glycerin trioctanoate, glycerin triisopalmitate, trimethylolpropane triisostearate, isopropyl myristate, glycerol tri-2-ethylhexanoate, pentaerythritol tetra-2-ethylhexanoate ate, lanolin, liquid lanolin, liquid paraffin, squalene, blistane, isoparaffin, squalane, petrolatum, etc. Furthermore, dialkylpolysiloxanes such as dimethylpolysiloxane, dimethylcyclopolysiloxane, and diethylpolysiloxane, alkylaryl-polysiloxanes such as methylphenylpolysiloxane, diarylpolysiloxanes, fatty acid-modified polysiloxanes, higher alcohol-modified polysiloxanes, and amino-modified polysiloxanes. Silicones such as siloxane and polyoxyalkylene-modified polysiloxane? [lI tJ is exemplified.

The solid water-in-oil emulsion makeup f: (2) of the present invention is appropriately selected from the above-mentioned oils and blended therein. The blending amount is 5 to 85% of the total amount of cosmetics.

Among oils, if you are looking for one that feels light on use and has good makeup retention, use the following structural formulas [1] and [2].
It is preferable to use a volatile silicone oil represented by the following formula, and the amount thereof is preferably 30 to 97% by weight in the oil phase.

(The following is a blank space) b = o ~ 3 The solid waxes used in the present invention include paraffin wax, petroleum wax such as microcrystalline wax, mineral wax such as osikelite and ceresin, carnauba wax, etc. Examples include natural waxes with a melting point of 50°C or higher, such as candelilla wax, but in particular mixtures of straight-chain and/or branched hydrocarbons, with straight-chain hydrocarbons having 25 to 52 carbon atoms. Those containing it as a main component are preferred. The type of wax used is selected depending on the type of oil used, but wax esters such as carnauba wax and candelilla wax are difficult to obtain when used alone, and straight and/or branched hydrocarbons It is preferable to mix it with a wax. In addition, generally commercially available hydrocarbon solid waxes are obtained as a mixture, so there is a distribution of carbon numbers, and they also contain isoparaffins and naphthenes. Preferably.

Commercially available products include Boler wax 1014 (manufactured by Boler, USA) and paraffin wax 125.130.
．． 135.140.145°F PW (Nippon Oil Co., Ltd. series product), paraffin wax 140.145.
150.155°F (series product manufactured by Nippon Oil Co., Ltd.),
Microwax 155.180 (manufactured by Nippon Oil Co.), Hymic 2065 (manufactured by Nippon Oil Co.), Aristowax 165°F (manufactured by Union Oil Company, USA), 0ZOKE
Examples include RITE E-626 (manufactured by Francella Ceresin), and mixtures containing these waxes as main components and blending them with other waxes may also be used.

Examples of the oil gelling agent used in the present invention include condensates of benzaldehydes such as dibenzylidene sorbitol, tribenzylidene sorbitol, dibenzylidene xylitol, and paramethoxybenzylidene sorbitol with alcohols having a valence of 5 or more, calcium stearate, calcium palmitate, 2-Ethylhexanoic acid sudji [cum, 12
- metal soaps such as aluminum hydroxystearate;
Derivatives such as amides, esters, and amine salts of N-acyl amino acids such as lauroylglutamic acid dibutylamide, uroylglutamic acid stearylamide, cicabroylridine laurylamine salt, cicabroylridine lauryl ester, cicabroylridine lauroylphenylalanine laurylamide, etc. Dextrin fatty acid esters made of acid hydrolysates of starch saturated fatty acid esters having a degree of ester group substitution of 30% or more, 12-hydroxystearic acid, and the like can be mentioned.

The solid water-in-oil emulsion cosmetic of the present invention may contain one or more of the above solid waxes and oil gelling agents, appropriately selected and blended therein. Among them, a mixture of straight hydrocarbons and/or branched hydrocarbons having 25 to 5 carbon atoms of the straight hydrocarbons.
A solid wax containing 2 as a main component is preferred. The amount of solid wax and/or oil gelling agent can be adjusted depending on the desired hardness, but the ratio of oil content: solid wax and/or oil gelling agent is 20:1 to 3:1.
is preferable, and preferably 5 to 20% by weight in the total cosmetic.

The amount of water used in the present invention needs to be at least 5% by weight of the totalized fIiII, and if it is less than this, a refreshing feeling cannot be expected during use. In particular, in order to obtain a very refreshing feeling during use, it is preferable to mix 10 or more layers.

The lipophilic surfactant used in the present invention includes HL
Those with a B value (circular formula) of 8 or less are fine, but among them, sorbitan monoisostearate, sorbitan diisostearate, sorbitan sesquiisostearate, sorbitan monooleate, sorbitan dioleate, sorbitan sesquiolate, and glyceryl. monoisostearate,
Glyceryl diisostearate, glyceryl sesquiisostearate, glyceryl monooleate, glyceryl diolate, glyceryl sesquiolate, diglyceryl diisostearate, diglyceryl diolate, diglycerin monoisostefryl ether, diglycerin diisostearyl ether preferable. The blending amount is selected depending on the amount of the emulsified aqueous phase, but it is 0.2 to 10% of the total amount of cosmetics.
Weight percent is preferred.

The hydrophobized powder used in the present invention is a powder commonly used in cosmetics that has been treated with a conventionally known hydrophobization method. Examples of powders include inorganic powders such as talc, kaolin, mica, sericite, silica, magnesium silicate, calcium silicate, aluminum silicate,
Clay mineral powder such as bentonite and montmorillonite, alumina, barium H oxide, dicalcium phosphate, calcium carbonate, titanium oxide, fine particles of titanium oxide with a particle size of 0.1 um or less, silicone oxide, zinc oxide, hydroxyapatite, iron oxide, titanic acid Examples include pearl pigments such as iron, ultramarine blue, navy blue, chromium oxide, chromium hydroxide, cobalt oxide, cobalt titanate, and titanium oxide coated mica.

In addition, organic powders include polyester, polyethylene,
Polystyrene, methyl methacrylate resin, cellulose,
Cool dyes such as nylon 12, nylon 6, copolymer of styrene and acrylic acid, polypropylene, vinyl chloride, tetrafluoroethylene, boron nitride, fish scale foil, Red No. 3, Red No. 4, Red No. 203, etc. are made into lakes. thing,
Examples include lakes of natural pigments, and composite powders of inorganic and organic powders.

In the present invention, the above powder is used after being treated with a hydrophobizing agent. Hydrophobic treatment can improve makeup hold such as water resistance, sweat resistance, and sebum resistance without causing color separation. especially,! D. For products that contain only one type of powder, it is more important to control the dispersibility of each powder, and by hydrophobicizing each powder, the dispersibility is homogenized and color separation is less likely to occur. , stability is improved. Also, since the powder does not get wet easily, makeup lasts longer. Examples of hydrophobizing agents include organic compounds such as dextrin fatty acid esters, metal soaps, silicone compounds, and dibenzylidesisorbitol. Methods of hydrophobic treatment using these hydrophobizing agents are described, for example, in JP-A-02-205135, JP-A-5-15394, JP-A-61-58499, and JP-A-56-432.
No. 64, special mention No. 56-16404, special publication No. 59-
76009, Special Description No. 60-163973, Japanese Patent Application Publication No. 3-113081, Japanese Patent Application Publication No. 3-113082
An example is the method described in the bulletin.

One or more of the hydrophobized powders described above may be selected and used in the cosmetic of the present invention. The blending amount is 5 to 50% by weight based on the total amount of makeup, and particularly preferably 15 to 40% by weight when used as a foundation. If the total amount of powder is less than 5%, the makeup will be too thin and the makeup effect will not be felt, which is not preferable.

Moreover, if it exceeds 50 times, it becomes impossible to obtain lightness of spread, which is not preferable.

In addition to the above-mentioned essential ingredients, the solid water-in-oil emulsion cosmetic composition of the present invention may contain ingredients commonly used in cosmetics to the extent that they do not impair the effects of the present invention. For example, mucopolysaccharides such as sodium hyaluronate and sodium chondroitin sulfate, amino acids and their salts, organic acids and their salts such as oxyacids and their salts such as citric acid, malic acid, and lactic acid, cationic surfactants, and anionic surfactants. surfactants such as nonionic surfactants, vitamin E
1 Drugs such as vitamin E acetate, astringents, antioxidants, preservatives, fragrance P1, dibasic sodium phosphate, etc.
-I regulators, clay minerals, thickeners, ultraviolet absorbers, etc. Among them, amino acids, mucopolysaccharides, organic acids, and salts thereof are preferably blended to improve word stability.

[Examples] The present invention will be explained in detail with reference to Examples below, but the scope of the present invention is not limited thereto. In addition, all compounding amounts in the examples represent weight %.

[Example 1] (1) Decamethylcyclopentasiloxane 38.0 (
2) Aristowax 165°F 10
゜0(3) Sorbitan diisostearate 2.0(4)
Silicone treated powder (A) 30.0 (
5) Remainder of ion exchange water (6) Appropriate amount of preservative (7) Flavor ↓
Appropriate amount (manufacturing method) After heating (1) to (3) and (7) to 80℃ and dissolving (
Add 4) and disperse with a homogenizer at 80°C. Furthermore, the mixture of (5) and (6) previously heated to 80° C. is added and emulsified. Thereafter, it was filled into a volume of 2 g and cooled to room temperature to obtain the desired solid water-in-oil emulsion cosmetic fl.

The silicone-treated powder (A) used here is as described in JP-A No. 63-113081 and JP-A No. 3-113082.
According to the method described in the report, 3.65 parts of mica, 5.0 parts of titanium oxide, 0.25 parts of iron oxide red, 1.0 parts of iron oxide,
After mixing 0.1 part of iron oxide black, the mixture was reacted with tetramethyltetrahydrodienecyclosiloxane and then subjected to an addition reaction with tetradecene.

[Comparative Example 1] (1) Thecamethylcyclopentasiloxane 38.0
(2) Carnauba wax 10.0 (
3) Sorbitan diisostearate 2.0 (4) Untreated powder (B) 30.0 (5) Ion or water exchange Balance (6) Preservative
Appropriate amount (7) Incense: #
Appropriate amount (manufacturing method) Manufactured by the same manufacturing method as in Example 1.

As the untreated powder (B) used here, the raw material powder mixture before the silicone-treated powder (A) was used as it was.

The solid water-in-oil emulsified cosmetics obtained in Example 1 and Comparative Example 1 were filled into glass bottles and left uncovered in thermostats at 25°C and 50°C to determine the weight loss and stability over time. (Crack, I,
Separation, etc.) and usability (make-up retention, spread, refreshing feel, lightness) were evaluated. The results are shown in Table 1. The evaluation method is as follows.

1 Part amount of emitted component 1 1 After being left at 25°C and 50°C for 3 weeks, if there is no change in condition due to cracks 4, waviness 4, or separation, it is good, and if some changes are observed, it is good. Slightly poor results or cases where changes were observed were considered poor.

Using a panel of 20 people, sensual evaluations were made of makeup dust, spreadability, coolness, and lightness.

People who answered good 15 or more people ○ People who answered good 7 to 14 people People who answered good 6 people or less The type emulsified cosmetic had little weight loss due to volatilization, was stable, and had good usability.

[Example 2] (1) Tekamejirushikukuchipenkushirokiten 38.0
(2) Aristowax 165°F 1o
,.

(3) Silicone treated powder (A) 10.
0(4) Sorbitan sesquiolet 1-2
, 0(5) ion-exchanged water balance (
Manufacturing method) Heat the raw materials (1) to (4) to 80°C, and add (5
) was added and emulsified and then cooled to room temperature to obtain the desired solid water-in-oil emulsion cosmetic.

The following Examples and Comparative Examples were produced in the same manner as in Example 2.

[Example 3] (1) Thecamethylcyclopentasiloxane 38,0
(2) Aristowax 165°F 10
．． 0(3) Calcium stearate treated powder (C) 1
0.0 (4) Sorbitan Sesquiolate 20 (5) Ion-exchanged water The remainder:
The calcium stearate treated powder (C) used here is a mixture of the original 11 powder of the silicone treated powder (A) and 5% by weight of calcium stearate based on the powder;
After mixing, ethanol was further added, and the mixture was kneaded at 70°C, dried, and pulverized.

Example 4J (1) Thecamethylcyclopentasiaxane (2) Paraffin wax 155°F (3) Dextrin fatty acid ester treated powder (1)) (4) Sorbitan sesquiolate (5) Ion exchange water 38.0 10 .0 10.0 2.0 Remainder The Dextrin R costate ester treated powder (D) used here was prepared using the silicone treated powder (A) according to the description in JP-A-62-2051135. Original If1
5% by weight of dextrin fatty acid ester
Add it to the Isopar E (Exxon Chemical) solution, stir, add the solvent, dry, crush, and add it to the solution.

[Example 5J (1) Pentacyl quinan (2) Dextrin palmidic acid partial ester (3) Aristowax 185°F (4) Silicone treated powder (A) (5) Sorbitan sesquiolate (6) Ion exchange Water 38.0 5.0 5.0 10.0 2.0 Remainder E Comparative Example 2J (1) Tecamethylsiloxane (2) Aristowax 165°F (3) Untreated powder (B) (4) Sorbitan sesqui Olate 38.0 10.0 10.0 2.0 (5) Remaining ion-exchanged water [Comparative Example 3] (1) Thecamethylsilopenxiloxane (2) Hydrogenated castor oil (3) Untreated powder (B) (4 ) Sorbitan sesquiolate (5) Ion-exchanged water 38.0 10.0 10.0 2.0 Remainder [Comparative Example 41 (1) Decamethylcyclopentasiloxane (2) Aristowax 165°F (3) Sorvicune diiso Stearate (4) Untreated powder (B) (5) Ion exchange water 75.0 10.0 2.0 10.0 Remainder Solid water-in-oil emulsions of Examples 2 to 5 and Comparative Examples 2 to 4 Table 2 shows the evaluation results of the stability and usability of the cosmetics.

As is clear from Table 2, the solid water-in-oil emulsion cosmetics of Examples 2 to 5 were stable without cracks, cracks, or separation;
Yes, it felt good when using it. It was also excellent in terms of volatilization rate.

[Implementation vq6] Stick-shaped emulsion foundation (1) Methylphenylpolysiloxane 5.0 (
2) Decamethylcyclopentasilocypne 20.0 (3
) Glyceryl triisooctanate 3.0 (4)
Glyceryl diisostearate 2.0 (5) Ceresin wax 7.0 (6) Dibenzylidene sorbitol 3.0 (7) Calcium stearate treated powder (C) 30.0 (8)
Fragrance Appropriate amount (9) Ion exchange water Balance (10) Glycerin 2.0 (11) 1.3
-Butylene glycol 1.0 (12) Preservative Appropriate amount (manufacturing method) After heating and dissolving (1) to (6) and (8) at 80°C (7
) and disperse with a homogenizer at 80°C. Mixture 1 of (9) to (12) preheated to 80°C in a colander
Add soy sauce and emulsify. Thereafter, it was filled into a stick-shaped container and cooled to room temperature to obtain the desired stick-shaped emulsified foundation.

[Example 71 Solid cosmetic (1) Trimethylsiloxysilicate 3.0 (
2) Dimethylpolysiloxane 10.0 (
3) Cetyl isooctanate 10.0 (4) Squalane 10.0 (5) Microwax 155 10.0 (6) Diglycerin diisostearate 2.0 (7) Sorbitan sesquiisostearate 2.0 (8 ) Calcium stearate treated talc 7.0 (9) Ion exchange water
Remainder (10) Urea
3.0 (11) Glycine
3.0 (12) Diglycerin
2.0 (13) Propylene glycol
1.0 (14) Anti-g shoulder
Appropriate amount (manufacturing method) After heating and dissolving (1) to (7) at 80°C, add (8) and mix for minutes. Next, it was preheated to 80°C (
Add the mixture of 9) to (14) and emulsify and disperse. Thereafter, it was filled into an ointment container and cooled to room temperature to obtain the desired urea-containing solid cosmetic.

Note that the calcium stearate-treated talc was obtained by subjecting talc alone to the same treatment as the above-mentioned calcium stearate-treated powder (C).

[Example 8] Compact emulsion foundation (1) Camel cyclopentasiloxane 36.0
(2) Dimethylpolysiloxane (C5cs)
2.0 (3) Jojoba oil 4
．． 0(4) Ceresin 8.
0(5) Microcrystalline wax 1.0
(6) Sorbitan diisostearate 2.0 (7) Silicone treated powder (A) 20.0 (8)
Ion exchange water Balance (9) Glycerin 15.0 (10) 1.
3-butylene glycol 2.0 (11)
Preservative: Appropriate amount (12) Flavor: Appropriate amount (manufacturing method) After heating (1) to (6) and (12) to 80℃ (7)
Add and disperse. Next, it was preheated to 80℃ (8
) to (11) are added and emulsified and dispersed. Thereafter, it was filled in a medium tray in a fluid state, cooled to room temperature, and placed in a compact container to obtain the desired compact emulsified foundation. The obtained compact emulsion foundation was moist, non-sticky, had a refreshing feel, had good makeup retention, and was convenient to carry.

The manufacturing method of the following examples involves heating and dissolving the oil phase component at 80°C, dispersing the powder, emulsifying and dispersing the preheated aqueous phase component, and filling it into a container in a fluid state. did. The desired product was obtained by cooling it that night. All of them had good stability and excellent usability such as a refreshing feeling.

[Example 9] Blush (1) Liquid paraffin (2) Decamethylcyclopentasiloxane (3) Cetyl isooctanate (4) Diglycerin diisostearyl ether (5) Micro wax 155 (6) Dextrin palmitate (7) ) Fragrance 20.0 10.0 15.0 3.0 10.0 2.0 Appropriate amount (8) Dextrin fatty acid ester treated powder (D) (9) Ion exchange water (10) Sodium hyaluronate (11) Sodium chondroitin sulfate (12) Polyethylene glycol (13) Preservative 30.0 6.9 0.1 1.5 1.5 Adequate amount E Example 1010 Red (1) Octamethylcyclotetrasiloxane 10.0 (
2) Dimethylpolysiloxane (6cs) 20
．． 0(3) Polyoxyalkylene-modified organopolysiloxane 2.0(4) Carnauba wax 2.8(5) Aristowax 165°F 8.0(6) Diglyceryldiolate 3.0(7) Dextrin fatty acid ester treatment oxidation Chichi Red 0.3 (8) Silicone treated iron oxide 1.0 (9) Red 20
No. 4 0.7 (10) Dibutylhydroxytoluene Appropriate amount (11) Fragrance
Appropriate amount (12) Ion exchange water 51.4 (13) Atelocollagen 0.3 (14) Sodium pyrrolidone carboxylate 0.5 (15) Preservative
The dextrin fatty acid ester-treated iron oxide red and the silicone-treated iron oxide used here were obtained by processing according to the above-mentioned processing method.

[Example 11] Lip treatment (1) Squalane (2) Lanolin (3) Octamethylcyclotetrasiloxane (4) Isoparaffin (boiling point 155°C) (5) Trimethylsiloxysilicate (6) Aristowax 165°F (7) Di Glyceryl diisostearate (8) Silicone-treated iron oxide (9) Silicone-treated iron oxide (10) Silicone-treated fine particle titanium oxide 10.0 2.0 10.0 27.0 3.0 8.0 3.0 0.8 0.2 3.0 (11) Ion exchange water balance (1
2) Glycerin 5.0 (13
) Sodium lactate 0.3 (14)
Sodium L-glutamate 0.3 (15)
Sodium hyaluronate 0:1 (16)
Sorbitol 0.5 (17) Red No. 202 0.01 (1
8) Menthol 0.1 (
19) Appropriate amount of fragrance (2
0) Preservative Appropriate amount The silicone-treated iron oxide, silicone-treated iron oxide, and silicone-treated fine particle titanium oxide used here were obtained by processing according to the above-mentioned treatment method.

It has a novel feel of ``cooling'' when applied, and is also characterized by an excellent feeling of use, such as ``spreadability'', ``zabarisa J'', and ``chemical 8f mochi j''.

In particular, when used as a makeup cosmetic, it has good makeup retention, is in solid form, can contain various moisturizing agents and drugs as an aqueous phase component, and has a refreshing feeling during use and a long makeup retention after use. be. Furthermore, due to the excellent stability, the range of container shapes that can be filled can be expanded.

Patent applicant: Shiseido Co., Ltd. [Effect of the invention]

Claims (1)

[Claims] (1) Oil, solid wax and/or oil gelling agent,
A solid water-in-oil emulsion cosmetic comprising water, a lipophilic surfactant, and a hydrophobized powder.