JPH0286007A - Fine-diameter insulated electric wire - Google Patents

Fine-diameter insulated electric wire

Info

Publication number
JPH0286007A
JPH0286007A JP23825888A JP23825888A JPH0286007A JP H0286007 A JPH0286007 A JP H0286007A JP 23825888 A JP23825888 A JP 23825888A JP 23825888 A JP23825888 A JP 23825888A JP H0286007 A JPH0286007 A JP H0286007A
Authority
JP
Japan
Prior art keywords
polyethylene
melting point
electric wire
metal soap
pts
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP23825888A
Other languages
Japanese (ja)
Inventor
Shigeru Kashiwazaki
柏崎 茂
Shuichi Suganami
菅波 修一
Koichi Nakajima
光一 中島
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Cable Ltd
Original Assignee
Hitachi Cable Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Cable Ltd filed Critical Hitachi Cable Ltd
Priority to JP23825888A priority Critical patent/JPH0286007A/en
Publication of JPH0286007A publication Critical patent/JPH0286007A/en
Pending legal-status Critical Current

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  • Organic Insulating Materials (AREA)

Abstract

PURPOSE:To obtain a thin insulated electric wire with excellent abrasion resistance by covering an insulator added with the preset quantity of metal soap with the preset melting point to polyethylene 100 pts.wt. at the preset thickness. CONSTITUTION:An insulator added with metal soap 0.1-3 pts.wt. with the melting point of 80 deg.C or above to polyethylene 100 pts.wt. is covered at the thickness of 20mum or below to form an insulated electric wire with the outer diameter of 1mm or below. When the metal soap 0.1-3 pts.wt. is added, the abrasion resistance can be improved without deteriorating the electric characteristic of polyethylene. The polyethylene with the yield point stress of 150kg/cm<2> or above and the melting point of 115 deg.C or above is preferable, and cadmium stearate or barium stearate is used for the metal soap with the melting point of 80 deg.C or above.

Description

【発明の詳細な説明】 [産業上の利用分野] この発明は、薄肉細径絶縁電線の耐摩耗性の改善に関す
る。
DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] This invention relates to improving the wear resistance of thin-walled, small-diameter insulated wires.

[従来の技術] 電線を細径化することで、電気機器・電子機器をより小
型に、あるいは装置のスペースをより少なくして小さく
することかできる。
[Prior Art] By reducing the diameter of electric wires, electrical and electronic devices can be made smaller, or devices can be made smaller by reducing their space.

電線を細径化するためには、導体を細くすることおよび
絶縁体を薄くすることか必要である。従来、薄肉の絶縁
体としてはポリウレタンが使用されている。ポリウレタ
ンは薄肉とした場合に最もI!!1題となる機械的特性
、特に耐摩耗性か優れているために好んで用いられてい
た。
In order to reduce the diameter of an electric wire, it is necessary to make the conductor thinner and the insulator thinner. Conventionally, polyurethane has been used as a thin insulator. When polyurethane is made thin, it has the highest I! ! It was preferred because of its excellent mechanical properties, particularly its wear resistance.

しかし、ポリウレタンは、例えば誘電率か7.09体積
抵抗率か1012Ω−cm程度であり、絶縁体としては
用途か限られてしまう。
However, polyurethane has a dielectric constant of 7.09, a volume resistivity of about 1012 Ω-cm, and its use as an insulator is limited.

電気的特性の優れた材料としては、体積抵抗率h)lO
16Ω−cm以上、誘電率かシ、3のポリエチレンを挙
げることかできる。
Materials with excellent electrical properties include volume resistivity h) lO
Polyethylene having a dielectric constant of 16 Ω-cm or more and a dielectric constant of 3.

しかし、ポリエチレンは薄肉とした場合には耐摩耗性が
劣り、実用か制限されていた。
However, polyethylene has poor abrasion resistance when made thin, which limits its practical use.

[発明が解決しようとする課題] このように従来の絶縁材料は、電気特性が劣り、または
耐摩耗性が劣る等の欠点を有している。
[Problems to be Solved by the Invention] As described above, conventional insulating materials have drawbacks such as poor electrical properties and poor wear resistance.

この発明の目的は、上記した欠点を解消し、電気特性と
耐摩耗性に優れた薄肉の細径絶縁電線を提供することに
ある。
An object of the present invention is to eliminate the above-mentioned drawbacks and provide a thin-walled, small-diameter insulated wire with excellent electrical properties and wear resistance.

[課題を解決するための手段] この発明は、ポリエチレン100重量部に対し、融点か
so’c以りの金属石鹸を0.1〜3重置部添加するこ
とにあり、これによってポリエチレンの電気特性の低下
を招くことなく、耐摩耗性を向上させることかできる。
[Means for Solving the Problems] The present invention consists in adding 0.1 to 3 parts of a metal soap having a melting point of 100 parts by weight to 100 parts by weight of polyethylene, thereby increasing the electrical power of polyethylene. Abrasion resistance can be improved without deteriorating properties.

[実 施 例] ポリエチレンは、低密度ポリエチレン、中密度ポリエチ
レン、高密度ポリエチレン、線状低密度ポリエチレン等
何れを用いてもよい。好ましくは、降伏点応力か150
kg/cm2以E、融点が115℃以上のポリエチレン
かよい。
[Example] As the polyethylene, any of low-density polyethylene, medium-density polyethylene, high-density polyethylene, linear low-density polyethylene, etc. may be used. Preferably, the yield stress is 150
kg/cm2 or higher and a melting point of 115°C or higher.

融点か80℃以上の金属石鹸としては、ステアリン酸カ
ドミウム、ステアリン酸バリウム、ラウリン酸バリウム
、リシノール酸バリウム、ステアリン酸カルシウム、ラ
ウリン酸カルシウム、ステアリン酸ストロンチウム、ス
テアリン酸亜鉛、ラウリン酸亜鉛、ステアリン酸鉛、二
塩基性ステアリン酸鉛、ステアリン酸スズ、ステアリン
酸マグネシウム、ラウリン酸カドミウム、リシノール酸
カドミウム、ナフテン斂カドミウム、リシノール酸亜鉛
を挙げることができる。
Metal soaps with a melting point of 80°C or higher include cadmium stearate, barium stearate, barium laurate, barium ricinoleate, calcium stearate, calcium laurate, strontium stearate, zinc stearate, zinc laurate, lead stearate, Mention may be made of basic lead stearate, tin stearate, magnesium stearate, cadmium laurate, cadmium ricinoleate, cadmium naphthenate, and zinc ricinoleate.

金属石鹸は滑剤としての作用を有するか、例えば他のパ
ラフィン系、脂肪酸系、脂肪酸エステル系、 III助
酸ケトン系等の滑剤は、耐摩耗性向上効果か低い、これ
に対して金属石鹸は優れている。
Does metal soap have the effect of a lubricant?For example, other paraffin-based, fatty acid-based, fatty acid ester-based, III-acid ketone-based lubricants have a low effect on improving wear resistance, whereas metal soaps have an excellent effect. ing.

しかし、融点が80℃以下の金属石鹸は耐摩耗性向上の
効果は低く、融点が80℃以上の金属石鹸を用いる必要
がある。この添加量としては0.1〜3重量部である。
However, metal soaps with a melting point of 80° C. or lower are less effective in improving wear resistance, and it is necessary to use metal soaps with a melting point of 80° C. or higher. The amount added is 0.1 to 3 parts by weight.

0.1重量部以下では効果がなく、これを3重量部以上
添加してもその効果が飽和してしまうばかりでなく、加
工が難しくなるためである。
This is because if it is less than 0.1 part by weight, there is no effect, and if it is added in excess of 3 parts by weight, the effect not only becomes saturated but also becomes difficult to process.

以下、この発明の実施例を具体的に説明する。Examples of the present invention will be described in detail below.

実施例1〜5 第1表に示すように、ポリエチレンとしてミラソン35
30 (三井ポリケミカル(株)製、メルトインデック
ス=0.3、密度=Q、927)を用い、当該樹脂10
0重量部に第1表の金属石鹸を添加したコンパウンドな
、外径0.102mmのスズメツキ銅線を7本撚り合わ
せた導体上に、28mm押出機を用いて肉厚0.1mm
となるように被覆し、外径0.5mmの電線を製造した
Examples 1 to 5 As shown in Table 1, Mirason 35 was used as polyethylene.
30 (manufactured by Mitsui Polychemical Co., Ltd., melt index = 0.3, density = Q, 927), the resin 10
A conductor made of 7 twisted copper wires with an outer diameter of 0.102 mm, made of a compound containing 0 parts by weight of the metal soaps listed in Table 1, was made into a conductor with a wall thickness of 0.1 mm using a 28 mm extruder.
An electric wire with an outer diameter of 0.5 mm was produced.

実施例6〜9 ポリエチレンとしてショーレックス5005(昭和電工
(株)製、メルトインデックス=0.3、密度=Q、9
45)を用い、当該樹脂100重量部に第1表の金属石
鹸を添加したコンバインドとした以外は実施例1〜5ζ
同様にして電線を製造した。
Examples 6 to 9 Shorex 5005 (manufactured by Showa Denko K.K., melt index = 0.3, density = Q, 9) as polyethylene
Examples 1 to 5ζ except that a combination was used in which the metal soap shown in Table 1 was added to 100 parts by weight of the resin.
Electric wires were manufactured in the same manner.

比較例1〜4 ポリエチレンとしてミラソン3530を用い、当該樹脂
100重量部に第1表の滑剤を添加したコンパウンドと
した以外は実施例1〜5と同様にして電線を製造した。
Comparative Examples 1 to 4 Electric wires were manufactured in the same manner as in Examples 1 to 5, except that Mirason 3530 was used as the polyethylene and a compound was prepared by adding the lubricant shown in Table 1 to 100 parts by weight of the resin.

比較例5.6 ポリエチレンとしてショーレックス5005を用い、当
該111脂100重量部に第1表の金属石鹸を添加した
コンパウンドとした以外は実施例1〜5と同様にしてf
at線を製造した。
Comparative Example 5.6 A compound was prepared in the same manner as Examples 1 to 5, except that Shorex 5005 was used as the polyethylene and the metal soap listed in Table 1 was added to 100 parts by weight of the 111 fat.
At-line was manufactured.

比較例7.8 ポリエチレンとしてミラソン3530またはシミーレッ
クス5005を用い、滑剤を添加しないコンパウンドと
した以外は実施例1〜5と同様にして電線を製造した。
Comparative Example 7.8 Electric wires were produced in the same manner as in Examples 1 to 5, except that Mirason 3530 or Similex 5005 was used as the polyethylene and the compound was made without adding a lubricant.

実施例及び比較例の電線について、耐摩耗性を測定した
結果を第1表に示した。耐摩耗性の測定は、第1図に示
す装置により、ピン電極2と導体4か短絡するまでの回
数を数えた。ビン電極2は500gの荷重1を導体4を
絶縁体3で被覆した電線に与えながら、30mmの範囲
の区間を左右に60回/分往復させて短絡したことをラ
ンプ5で検出し、それまでの回数を測定するものである
。なお、符号6は電池である。
Table 1 shows the results of measuring the abrasion resistance of the wires of Examples and Comparative Examples. The wear resistance was measured by counting the number of times until the pin electrode 2 and the conductor 4 were short-circuited using the apparatus shown in FIG. The bottle electrode 2 applies a load 1 of 500 g to the electric wire in which the conductor 4 is covered with the insulator 3, and moves it back and forth 60 times/minute from side to side within a 30 mm range, detects a short circuit with the lamp 5, and then It measures the number of times. In addition, the code|symbol 6 is a battery.

実施例1〜9は、本発明で規定する滑剤を用いた場合で
あり、いずれも優れた耐摩耗性を示している。比較例1
及び2は、融点が80℃以下の金属石鹸を用いた場合で
あり、摩耗回数が少ない。
Examples 1 to 9 are cases in which the lubricant specified by the present invention was used, and all exhibited excellent abrasion resistance. Comparative example 1
and 2 are cases in which a metal soap with a melting point of 80° C. or lower is used, and the number of wears is small.

比較例3及び4は、他の滑剤を用いた場合であり、摩耗
回数が少ない。比較例5は、金属石鹸の添加量が本発明
の規定値よりも少ない場合であり、殆ど効果かない。比
較例6は、金属石鹸の添加量が本発明の規定値よりも多
い場合であり、押山鹿工性か悪く、電線の製造か困難て
あった。比較例7及び8は、滑剤を使用しない場合であ
り。
Comparative Examples 3 and 4 are cases where other lubricants were used, and the number of times of wear was small. Comparative Example 5 is a case where the amount of metal soap added is less than the specified value of the present invention, and has almost no effect. In Comparative Example 6, the amount of metal soap added was greater than the specified value of the present invention, and the workability was poor, making it difficult to manufacture the electric wire. Comparative Examples 7 and 8 are cases where no lubricant was used.

摩耗回数か少ない。The number of wear is low.

この発明は、通常の配合剤、例えば、難燃剤。This invention applies to conventional compounding agents such as flame retardants.

充填剤1着色剤、酸化防止剤等を添加してもよく、また
、電子線やパーオキサイドにより架橋を行なってもよい
Filler 1 Colorants, antioxidants, etc. may be added, and crosslinking may be performed using electron beams or peroxide.

(以下余白) [発明の効果コ 以上説明したとおり、この発明によれば、薄肉の耐摩耗
性に優れた電線を得ることかできる。
(The following is a blank space) [Effects of the Invention] As explained above, according to the present invention, it is possible to obtain a thin electric wire with excellent wear resistance.

【図面の簡単な説明】[Brief explanation of drawings]

図は、耐摩耗性評価装置の略図である。 特許出願人 日立’KL線株式会社 The figure is a schematic diagram of the wear resistance evaluation device. Patent applicant: Hitachi’KL Line Co., Ltd.

Claims (1)

【特許請求の範囲】[Claims] ポリエチレン100重量部に対し、融点が80℃以上の
金属石鹸を0.1〜3重量部添加した絶縁体を、肉厚2
00μm以下で被覆したことを特徴とする外径1mmφ
以下の細径絶縁電線。
An insulator made by adding 0.1 to 3 parts by weight of a metal soap with a melting point of 80°C or higher to 100 parts by weight of polyethylene, with a thickness of 2
Outer diameter 1mmφ characterized by coating with a thickness of 00μm or less
The following small diameter insulated wires.
JP23825888A 1988-09-21 1988-09-21 Fine-diameter insulated electric wire Pending JPH0286007A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP23825888A JPH0286007A (en) 1988-09-21 1988-09-21 Fine-diameter insulated electric wire

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP23825888A JPH0286007A (en) 1988-09-21 1988-09-21 Fine-diameter insulated electric wire

Publications (1)

Publication Number Publication Date
JPH0286007A true JPH0286007A (en) 1990-03-27

Family

ID=17027508

Family Applications (1)

Application Number Title Priority Date Filing Date
JP23825888A Pending JPH0286007A (en) 1988-09-21 1988-09-21 Fine-diameter insulated electric wire

Country Status (1)

Country Link
JP (1) JPH0286007A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06168627A (en) * 1992-11-30 1994-06-14 Hitachi Cable Ltd Thin insulated wire

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55155038A (en) * 1979-05-22 1980-12-03 Showa Denko Kk Resin composition

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS55155038A (en) * 1979-05-22 1980-12-03 Showa Denko Kk Resin composition

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH06168627A (en) * 1992-11-30 1994-06-14 Hitachi Cable Ltd Thin insulated wire

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