JPH0284495A - Method for plastic working and production of electrically conductive wire using the same method - Google Patents

Method for plastic working and production of electrically conductive wire using the same method

Info

Publication number
JPH0284495A
JPH0284495A JP23519388A JP23519388A JPH0284495A JP H0284495 A JPH0284495 A JP H0284495A JP 23519388 A JP23519388 A JP 23519388A JP 23519388 A JP23519388 A JP 23519388A JP H0284495 A JPH0284495 A JP H0284495A
Authority
JP
Japan
Prior art keywords
wire
ferrous metal
oil
lubricating
lubricating oil
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP23519388A
Other languages
Japanese (ja)
Other versions
JPH0726110B2 (en
Inventor
Toyohito Uematsu
上松 豊翁
Shigeki Komatsuzaki
小松崎 茂樹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Hitachi Ltd
Original Assignee
Hitachi Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hitachi Ltd filed Critical Hitachi Ltd
Priority to JP63235193A priority Critical patent/JPH0726110B2/en
Priority to EP89108389A priority patent/EP0341688B1/en
Priority to DE8989108389T priority patent/DE68900213D1/en
Publication of JPH0284495A publication Critical patent/JPH0284495A/en
Publication of JPH0726110B2 publication Critical patent/JPH0726110B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

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  • Metal Extraction Processes (AREA)
  • Lubricants (AREA)

Abstract

PURPOSE:To produce an electrically conductive wire suitable as power transmission lines, lead wires, etc., in a state of excellent work efficiency and safety by coating the surface of a nonferrous metal with a lubricating oil of a specific composition and subjecting the coated metal to plastic working using a die. CONSTITUTION:The surface of a nonferrous metal is coated with a lubricating oil prepared by blending a liquid polymer compound having preferably 300-50000cSt viscosity (at 40 deg.C) as a base oil with an additive consisting of animal or vegetable fats and oils and/or an aliphatic dicarboxylic acid. The resultant coated metal is then subjected to diameter reduction working using preferably a drawing die for draw working wires and then wire drawing working while forming a lubricating film with heat generated therefrom to produce the objective electrically conductive wire.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、非鉄金属の塑性加工方法に係り、特に、送電
線、電子部品用リード線等を塑性加工により伸線する導
電線の製造方法に関する。
[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for plastic working of nonferrous metals, and in particular, a method for manufacturing conductive wires for drawing power transmission lines, lead wires for electronic components, etc. by plastic working. Regarding.

[従来の技術] 送電線、電子部品用リード線等の線材、或は、金属芯線
上に銅、アルミニウム等の非鉄金属を被覆した複合導電
線(以下複合線と云う)は、熱間或は温間押出しまたは
熱間圧延等の公知の方法により線素材を製造し、これを
絞りダイスを有する伸線機により縮径することにより所
定寸法の線材が製造されている。工業的には絞りダイス
を有する伸線機をライン上に複数配置した連続伸線機を
用いて、所定寸法の導電線を製造する。
[Prior Art] Wire materials such as power transmission lines and lead wires for electronic components, or composite conductive wires (hereinafter referred to as composite wires) in which non-ferrous metals such as copper and aluminum are coated on metal core wires, are wire materials such as power transmission lines and lead wires for electronic components. A wire rod of a predetermined size is manufactured by manufacturing a wire material by a known method such as warm extrusion or hot rolling, and reducing the diameter of the wire material using a wire drawing machine equipped with a drawing die. Industrially, conductive wires of predetermined dimensions are manufactured using a continuous wire drawing machine in which a plurality of wire drawing machines each having a drawing die are arranged on a line.

複合線の製造においては、芯線と被覆材の変形抵抗が異
なるので、芯線と被覆層の断面積比も伸線されることに
よって変化する。そのため、予め芯線と被覆層の断面積
比の変化を予測し、それに応じて線素材の被覆層の肉厚
を決めて伸線される。
In the production of composite wires, since the deformation resistance of the core wire and the covering material are different, the cross-sectional area ratio of the core wire and the covering layer also changes as the wire is drawn. Therefore, the change in the cross-sectional area ratio between the core wire and the coating layer is predicted in advance, and the thickness of the coating layer of the wire material is determined in accordance with the change, and the wire is drawn.

従来、こうした伸線加工は、加工用潤滑剤として一般に
液体潤滑剤と粉末系潤滑剤が用いられてきた。
Conventionally, in such wire drawing processing, liquid lubricants and powder-based lubricants have generally been used as processing lubricants.

液体潤滑剤としては、鉱油あるいはエステル油等の合成
油またはこれらの混合油をベース油とし、これに各種の
添加剤、例えば「石油製品添加剤」(桜井俊男編著、幸
書房、昭和48年5月発行)に記載されている高級脂肪
酸、高級アルコールのような油性向上剤や燐、塩素、硫
黄系の極圧剤を配合したものがある。
As a liquid lubricant, the base oil is synthetic oil such as mineral oil or ester oil, or a mixture thereof, and various additives are added to it, such as "Petroleum Product Additives" (edited by Toshio Sakurai, Koshobo, May 1971). Some products contain oiliness improvers such as higher fatty acids and higher alcohols, as well as extreme pressure agents such as phosphorus, chlorine, and sulfur.

一方、粉末系潤滑剤としては、カルシウム石鹸やナトリ
ウム石鹸の様な金属石鹸粉末が用いられ、線素材とダイ
スの間に該粉末を圧入し、伸線加工を行う。
On the other hand, as the powder lubricant, metal soap powder such as calcium soap or sodium soap is used, and the powder is press-fitted between the wire material and the die to perform the wire drawing process.

鋼材のみの伸線加工用としては、粒径100μm以下の
金1’iC石鹸粉末をポリブテンに配合した潤滑油(特
開昭55−i35198号)がある。また、パラフィン
ろうと塩素化パラフィンおよび亜リン酸エステル、また
はリン酸エステルを配合した金属引抜加工用潤滑剤(特
開昭62−153396号)、油脂またはワックスと高
分子分散剤、界面活性剤等を水に分散した潤滑剤(特開
昭55−147593号)がある。
For wire drawing of steel materials only, there is a lubricating oil (Japanese Patent Application Laid-open No. 1983-135198) in which gold 1'iC soap powder with a particle size of 100 μm or less is blended with polybutene. In addition, metal drawing lubricants containing paraffin wax, chlorinated paraffin, phosphite esters, or phosphate esters (Japanese Patent Application Laid-Open No. 153396/1982), oils or waxes, polymer dispersants, surfactants, etc. There is a lubricant dispersed in water (JP-A-55-147593).

[発明が解決しようとする課題] 連続伸線機による線材の伸線加工においては、絞りダイ
スを通過する毎に線径が縮径されるので、伸線速度を後
段に行くほど上げる必要がある。最終段工程における伸
線速度は、250〜400m/ m i nにも達する
場合がある。
[Problem to be solved by the invention] When drawing a wire using a continuous wire drawing machine, the diameter of the wire is reduced each time it passes through a drawing die, so it is necessary to increase the drawing speed toward the later stages. . The wire drawing speed in the final step may reach as high as 250 to 400 m/min.

複合線では被覆層の表面性状、導電率の均−性等の要求
が厳しく、特に、導電率を一定にするために、導電線全
長にわたって被覆層の肉厚の均一なものが要求される。
Composite wires have strict requirements regarding the surface properties of the coating layer, uniformity of conductivity, etc. In particular, in order to keep the conductivity constant, the thickness of the coating layer is required to be uniform over the entire length of the conductive wire.

同時に塑性加工により線材表面が焼付いて「かじり」や
、潤滑油の劣化等による「変色」等のない良好な表面性
状のものでなければならない。
At the same time, the wire must have a good surface quality without "galling" caused by burning on the surface of the wire due to plastic working or "discoloration" due to deterioration of lubricating oil.

伸線の表面性状は、芯線と被覆層の断面積比、絞りダイ
スの形状、絞り率等に影響を受けるが、とくに潤滑剤の
影響が大きい、また、生産性向上のために伸線加工の高
速化が要求されているが。
The surface quality of wire drawing is affected by the cross-sectional area ratio of the core wire and the coating layer, the shape of the drawing die, the drawing ratio, etc., but the influence of lubricants is especially large. However, speeding up is required.

伸線加工の高速化には、潤滑油の性能を大幅に高める必
要がある。
To increase the speed of wire drawing, it is necessary to significantly improve the performance of lubricating oil.

従来、こうした点を改善するためにいろいろな潤滑剤が
使用されてきたが、伸線加工の高速化と良好な表面性状
を両立できる潤滑剤はなかった。
In the past, various lubricants have been used to improve these problems, but no lubricant has been able to achieve both high speed wire drawing and good surface quality.

一般に粘度の高い潤滑油は、金属同志の接触が起こりに
くく、伸線時の焼付き防止に有効である。
In general, lubricating oils with high viscosity are less likely to cause metal-to-metal contact and are effective in preventing seizure during wire drawing.

しかし、潤滑油の粘性抵抗が大きいために、伸線加工に
より温度が上昇し、その結果、潤滑油の粘度が低下して
焼付きが発生する。また、伸線時の温度上昇によって線
素材自身の機械的強度も低下するので、従来の潤滑油で
は、伸線速度100〜150m/minがほぼ限界であ
る。
However, since the viscous resistance of the lubricating oil is large, the temperature increases during wire drawing, and as a result, the viscosity of the lubricating oil decreases and seizure occurs. Furthermore, the mechanical strength of the wire material itself decreases due to the rise in temperature during wire drawing, so the wire drawing speed of 100 to 150 m/min is almost the limit for conventional lubricating oils.

また、上記の高粘度潤滑油は、補給等の取扱いや作業性
が悪く、かつ、周囲に飛散して機器表面や床面等に付着
すると、粘度が高いだけに、作業衣や靴等が粘着し、そ
のため作業者が伸線加工機へ巻き込まれたり、転倒する
といった作業安全上からも問題となっている。
In addition, the above-mentioned high-viscosity lubricants have poor handling and workability when replenishing, and if they scatter around and adhere to equipment surfaces or floors, their high viscosity can cause work clothes, shoes, etc. to become sticky. However, this also poses a problem from a work safety standpoint, such as workers getting caught in the wire drawing machine or falling over.

一方、鋼材の伸線加工に適した潤滑剤は、非鉄金属、特
に軟質材である銅またはアルミニウムの加工には適さず
、焼付きや表面割れ等が発生し易い。表面割れは、非鉄
全屈素材自身のせん断抵抗よりも、該素材とダイスとの
摩擦力が大きい場合に起こる現象である。
On the other hand, lubricants suitable for wire drawing of steel materials are not suitable for processing nonferrous metals, especially soft materials such as copper or aluminum, and are likely to cause seizures, surface cracks, etc. Surface cracking is a phenomenon that occurs when the frictional force between the non-ferrous fully bending material and the die is greater than the shear resistance of the material itself.

また、これらの潤滑剤は金属石鹸を多葉に含むので、加
工品の表面が変色し商品価値を低下させると云った欠点
がある。
Furthermore, since these lubricants contain a large amount of metal soap, they have the drawback of discoloring the surface of processed products and lowering their commercial value.

アミニウムの塑性加工用潤滑油としては、粘度171.
000c S t (40℃)以上のボリブデンが使用
できる。しかし既述のように、潤滑油は高粘度なほど素
材とダイスとの焼付きが起りにくく、約200m/mi
nの伸線速度でも伸線加工が可能であるが、高粘度潤滑
油は前記のような作業性や安全上に問題がある。
A lubricating oil for plastic working of aminium has a viscosity of 171.
000c S t (40° C.) or higher can be used. However, as mentioned above, the higher the viscosity of the lubricating oil, the less likely it is that the material and die will seize.
Although wire drawing is possible even at a wire drawing speed of n, high viscosity lubricating oil poses problems in terms of workability and safety as described above.

以上のように、従来の潤滑剤による伸線加工には、多く
の間顕点があった。
As mentioned above, conventional wire drawing using lubricants has had its drawbacks for many years.

本発明の第1の目的は、非鉄金属の塑性加工方法を提供
するものである。
A first object of the present invention is to provide a method for plastic working of nonferrous metals.

本発明の第2の目的は、非鉄金属素材、またはこれらを
芯線に被覆した線素材を、絞りダイスを有する伸線機に
より高速伸線加工する導電線の製造方法を提供するもの
である。
A second object of the present invention is to provide a method for producing a conductive wire, in which a non-ferrous metal material or a wire material in which a core wire is coated with the non-ferrous metal material is subjected to high-speed wire drawing using a wire drawing machine equipped with a drawing die.

更に他の目的は、作業性、安全性においても間顕ない導
電線の製造方法を提供することにある。
Another object of the present invention is to provide a method for manufacturing a conductive wire with excellent workability and safety.

[課題を解決するための手段] 本発明の特徴は、下記のとおりである。[Means to solve the problem] The features of the present invention are as follows.

(1)非鉄金属の表面に、液状高分子化合物をベース油
とし、これに動植物性油脂または脂肪族ジカルボン酸か
ら選ばれる添加剤を配合した潤滑油を塗布し、ダイスを
用いて塑性加工することにより発生する熱により潤滑皮
膜を前記非鉄金属表面に形成しながら塑性加工すること
を特徴とする非鉄金属の塑性加工方法。
(1) A lubricating oil containing a liquid polymer compound as a base oil and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids is applied to the surface of nonferrous metals, and plastic processing is performed using a die. A method for plastic working non-ferrous metals, characterized in that plastic working is performed while forming a lubricating film on the surface of the non-ferrous metal using heat generated by the process.

(2)粘度が300〜50,000 c S t (4
0℃)の液状高分子化合物をベース油として用いること
を特徴とする請求項第1項記載の非鉄金属の塑性加工方
法。
(2) Viscosity is 300 to 50,000 cSt (4
2. The method for plastic working of non-ferrous metals according to claim 1, wherein a liquid polymer compound at a temperature of 0° C.) is used as the base oil.

(3)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
とし、これに動植物性油脂又は脂肪族ジカルボン酸から
選ばれる添加剤を配合した潤滑油を塗布して伸線加工用
の絞りダイスに通し、前記線素材を縮径加工することに
より発生する熱により潤滑皮膜を前記非鉄金属表面に形
成しながら伸線加工することを特徴とする導電線の製造
方法。
(3) On the surface of a wire material made of a non-ferrous metal or a wire material whose core wire is coated with a non-ferrous metal, a liquid polymer compound is used as a base oil, and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids is blended with this. The wire is drawn while a lubricating film is formed on the surface of the non-ferrous metal by the heat generated by applying lubricating oil and passing it through a drawing die for wire drawing to reduce the diameter of the wire material. Method of manufacturing conductive wire.

(4)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
とし、これに動植物性油脂又は脂肪族ジカルボン酸から
選ばれる添加剤を配合した潤滑油を塗布して伸線加工用
の絞りダイスに通し、前記線素材を縮径加工することに
より発生する熱により前記非鉄金属と前記潤滑油添加剤
との反応皮膜を前記非鉄金属表面に形成しながら伸線加
工することを特徴とする導電線の製造方法。
(4) On the surface of a wire material made of a non-ferrous metal or a wire material whose core wire is coated with a non-ferrous metal, a liquid polymer compound is used as a base oil, and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids is blended with this. A reaction film of the non-ferrous metal and the lubricating oil additive is formed on the surface of the non-ferrous metal by the heat generated by applying lubricating oil and passing it through a drawing die for wire drawing to reduce the diameter of the wire material. A method for manufacturing a conductive wire, characterized in that wire drawing is performed while the wire is being drawn.

(5)粘度が300〜50,000c S t (40
℃)の液状高分子化合物をベース油として用いることを
特徴とする前項(3)または前項(4)記載の導電線の
製造方法。
(5) Viscosity is 300 to 50,000c St (40
The method for producing a conductive wire according to item (3) or item (4) above, characterized in that a liquid polymer compound having a temperature of 10°C (°C) is used as the base oil.

(6)粘度が300〜50,000 c S t (4
0℃)のポリブデン、ポリメタクリレート、ポリイソブ
チレン、エチレン−α−オレフィン共重合物、ポリアル
キレングリコールから選ばれる1種以上のベース油98
〜75重量%と、動植物性油脂または炭素数5〜36の
脂肪族ジカルボン酸から選ばれる添加剤2〜25重量%
を含む潤滑油を用いることを特徴とする前項(3)また
は前項(4)記載の導電線の製造方法。
(6) Viscosity is 300 to 50,000 cSt (4
0°C) of one or more base oils selected from polybutene, polymethacrylate, polyisobutylene, ethylene-α-olefin copolymer, and polyalkylene glycol98
~75% by weight, and 2 to 25% by weight of an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids having 5 to 36 carbon atoms.
The method for producing a conductive wire according to item (3) or item (4) above, characterized in that a lubricating oil containing the following is used.

(7)非鉄金属が銅またはアルミニウムであることを特
徴とする前項(3)〜前項(6)のいずれかに記載の導
電線の製造方法。
(7) The method for manufacturing a conductive wire according to any one of (3) to (6) above, wherein the nonferrous metal is copper or aluminum.

(8)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
としこれに動植物性油脂又は脂肪族ジカルボン酸から選
ばれる添加剤を配合した潤滑油を塗布して伸線加工用の
絞りダイスに通し、前記線素材を縮径加工することによ
り発生する熱により潤滑皮膜を前記非鉄金属表面に形成
しながら伸線加工したものを2本以上撚り合わせること
を特徴とする導電線の製造方法。
(8) Lubricating the surface of a wire material made of non-ferrous metal or a wire material whose core wire is coated with non-ferrous metal, using a liquid polymer compound as a base oil and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids. The wire is coated with oil and passed through a drawing die for wire drawing, and the wire is drawn while forming a lubricating film on the surface of the non-ferrous metal using the heat generated by reducing the diameter of the wire. Two or more wires are twisted together. A method for manufacturing a conductive wire, characterized by combining.

(9)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
としこれに動植物性油脂又は脂肪族ジカルボン酸から選
ばれる添加剤を配合した潤滑油を塗布して伸線加工用の
絞りダイスに通し、前記線素材を縮径加工することによ
り発生する熱により前記非鉄金属と前記潤滑油添加剤と
の反応皮膜を前記非鉄金属表面に形成しながら伸線加工
したものを2本以上撚り合わせることを特徴とする導電
線の製造方法。
(9) Lubricating the surface of a wire material made of non-ferrous metal or a wire material whose core wire is coated with non-ferrous metal, using a liquid polymer compound as a base oil and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids. A reaction film of the non-ferrous metal and the lubricating oil additive is formed on the surface of the non-ferrous metal by the heat generated by applying oil and passing it through a drawing die for wire drawing to reduce the diameter of the wire material. A method for manufacturing a conductive wire, which comprises twisting two or more wires together.

次に1本発明の導電線の製造方法を、図面により説明す
る。
Next, a method for manufacturing a conductive wire according to the present invention will be explained with reference to the drawings.

第2図に示すように、サプライ1に巻かれた線素材−2
は最初の滑車8に誘導されて伸線加工機N0.1のガイ
ド3を経て、潤滑油4を線材表面に塗布され、絞りダイ
ス5と貯線ドラム7によって第1段の線径に縮径され、
上記ドラム7に巻き取られる。
As shown in Figure 2, wire material-2 wound around supply 1
is guided by the first pulley 8, passes through the guide 3 of the wire drawing machine No. 1, applies lubricating oil 4 to the wire surface, and is reduced to the first stage wire diameter by the drawing die 5 and wire storage drum 7. is,
It is wound up on the drum 7.

次いで、次の滑車8′、8により伸線加工機NO12に
誘導され、上記と同様にして、第2段の線径に縮径され
る。これを所定サイズの線径まで順次伸線加工(No、
n)される。
Next, the wire is guided to the wire drawing machine NO12 by the next pulleys 8' and 8, and is reduced to the second stage wire diameter in the same manner as described above. This is then sequentially drawn to a predetermined wire diameter (No.
n) to be done.

次に、処理室9内に導入し、矯正機1oを通して歪を矯
正した後、溶剤11と回転ブラシ12によって、表面に
付着している潤滑油を除去し、エアブロ−13で乾燥す
る。乾燥された導電線は、巻取機14に取付けた巻取ド
ラム15に巻取られる。
Next, it is introduced into the processing chamber 9 and straightened through the straightening machine 1o, after which the lubricating oil adhering to the surface is removed using a solvent 11 and a rotating brush 12, and dried with an air blower 13. The dried conductive wire is wound around a winding drum 15 attached to a winding machine 14.

次に、本発明で用いる伸線加工用潤滑油について説明す
る。
Next, the lubricating oil for wire drawing used in the present invention will be explained.

潤滑油は、ベース油と添加剤を含む。一般的なベース油
としては鉱油が考えられる。しかしながら、鉱油は粘度
指数が100以下であり、温度上昇に対する粘度の低下
率が大きい。そのため線素材表面への付着力が低いので
、潤滑不良となり、焼付きや伸線素材の断線等が起こり
易く、円滑な伸線加工ができない、さらに、絞りダイス
温度が120℃以上になると、こうした鉱油をベース油
に用いたものでは伸線表面が変色するので、高速伸線加
工には適さない。
Lubricating oils include base oils and additives. Mineral oil can be considered as a common base oil. However, mineral oil has a viscosity index of 100 or less, and the rate of decrease in viscosity with respect to temperature rise is large. As a result, the adhesion force to the surface of the wire material is low, resulting in poor lubrication, which tends to cause seizure and breakage of the wire drawing material, making it impossible to draw the wire smoothly.Furthermore, if the drawing die temperature exceeds 120℃, such problems may occur. If mineral oil is used as the base oil, the wire drawing surface will discolor, so it is not suitable for high-speed wire drawing processing.

本発明者等はベース油として液状高分子化合物が、添加
剤である動植物性油脂または脂肪族ジカルボン酸の優れ
た潤滑性能を阻害せず、温度上昇に伴う粘度低下が小さ
く、線素材表面への付着性、並びに耐熱性が優れている
ことを見出し、本発明に至ったのである。
The present inventors have discovered that a liquid polymer compound as a base oil does not interfere with the excellent lubricating performance of the additives animal and vegetable oils and fats or aliphatic dicarboxylic acids, has a small decrease in viscosity with temperature rise, and has a low viscosity drop on the surface of the wire material. They discovered that it has excellent adhesion and heat resistance, leading to the present invention.

液状高分子化合物としては、例えば、ポリブチン、ポリ
メタクリレート、ポリイソブチレン、エチレン−α−オ
レフィン共重体等がある。
Examples of the liquid polymer compound include polybutyne, polymethacrylate, polyisobutylene, and ethylene-α-olefin copolymer.

上記の液状高分子化合物は、公知の方法で合成し得る液
状ポリマーであり、その分子量を変えるか、分子量の異
なるものを選択調合することにより、その粘度は自由に
調節できる。
The above-mentioned liquid polymer compound is a liquid polymer that can be synthesized by a known method, and its viscosity can be freely adjusted by changing its molecular weight or selectively blending compounds with different molecular weights.

該液状高分子化合物から成るベース油としては。As a base oil consisting of the liquid polymer compound.

伸線加工の条件、作業性、取扱い性等の面から、40℃
における粘度が、300〜50,000C8tの範囲が
好適である。
From the viewpoint of wire drawing conditions, workability, handling, etc., 40℃
It is preferable that the viscosity is in the range of 300 to 50,000C8t.

ベース油に配合される添加剤(fJ滑性向上剤)として
は1例えば、ヒマシ硬化油、ラード、アマニ油、大豆油
、牛脂硬化油、ラノリン等の動植物性油がある。
Examples of additives (fJ lubricity improvers) to be added to the base oil include animal and vegetable oils such as hydrogenated castor oil, lard, linseed oil, soybean oil, hydrogenated tallow oil, and lanolin.

また、同じく脂肪族ジカルボン酸としては、炭素数5〜
36のものがよい1例えば、グルタル酸、ウジピン酸、
ピメリン酸、スペリン酸、アゼライン酸、セパチン酸、
ウンデカン酸、ドデカン酸。
Similarly, aliphatic dicarboxylic acids have 5 to 5 carbon atoms.
36 is preferable 1 For example, glutaric acid, udipic acid,
pimelic acid, speric acid, azelaic acid, cepatic acid,
undecanoic acid, dodecanoic acid.

トリデカン2酸、ダイマー酸等がある。Examples include tridecane diic acid and dimer acid.

前記ベース油である液状高分子化合物に対する動植物性
油脂または脂肪族ジカルボン酸の配合量は、2〜25重
量%、好ましくは5〜20重量%である。上記動植物性
油脂また脂肪族ジカルボン酸の配合量が2重量%より少
ないと潤滑性向上効果が不充分となり、伸線加工時に焼
付きが生じ易くなる。又、25重量%より多くしても焼
付き防止効果はそれ以上は向上しない。
The blending amount of the animal and vegetable oil or fat or aliphatic dicarboxylic acid with respect to the liquid polymer compound that is the base oil is 2 to 25% by weight, preferably 5 to 20% by weight. If the amount of the animal or vegetable oil or fat or aliphatic dicarboxylic acid blended is less than 2% by weight, the effect of improving lubricity will be insufficient and seizure will easily occur during wire drawing. Further, even if the amount is more than 25% by weight, the anti-seizure effect will not be improved any further.

本発明の伸線加工に使用される潤滑油には、必要に応じ
て高級脂肪酸、高級アルコール等の油性向上剤、燐、塩
素、硫黄系極圧剤、あるいは金属石鹸粉末等を添加する
ことができる。更に、上記潤滑油に水等を加えエマルシ
ョン型潤滑油とすることもできる。この場合、公知の乳
化剤を添加することができる。
The lubricating oil used in the wire drawing process of the present invention may contain oiliness improvers such as higher fatty acids and higher alcohols, phosphorus, chlorine, and sulfur-based extreme pressure agents, or metal soap powder, as necessary. can. Furthermore, water or the like can be added to the above lubricating oil to form an emulsion type lubricating oil. In this case, known emulsifiers can be added.

また1本発明によれば、複合線の芯線材を超電導材とし
、被覆層が銅、アルミニウム等の非鉄金属から成る複合
線も、同様に高速伸線加工することができる。
Furthermore, according to the present invention, a composite wire in which the core wire material of the composite wire is a superconducting material and the coating layer is made of a non-ferrous metal such as copper or aluminum can be similarly drawn at high speed.

なお、上記において本発明の説明は、主に伸線加工法に
よって説明したが、一般の非鉄金属の塑性加工による部
品の成形も同様に行うことができる。
In addition, although the present invention was mainly explained using the wire drawing method above, parts can be similarly formed by plastic working of general non-ferrous metals.

[作用コ 本発明が用いる潤滑油は、温度に対する粘度低下が小さ
く、熱的にも安定でかつ素材表面に対しても付着性に優
れていることから塑性加工の摩擦面に良好な潤滑膜(油
膜)を形成する。特に、非鉄金属素材表面と、該潤滑油
の添加剤である動植物油脂または脂肪族ジカルボン酸の
反応によって生成した皮膜が、塑性加工面に形成され、
これが優れた潤滑性能を有するために、非鉄金属の塑性
加工焼付きを防止し塑性加工を容易にする。
[Function] The lubricating oil used in the present invention has a small decrease in viscosity with temperature, is thermally stable, and has excellent adhesion to the material surface, so it forms a good lubricant film on the friction surface during plastic working ( form an oil film). In particular, a film formed by the reaction between the surface of the non-ferrous metal material and the animal/vegetable oil or aliphatic dicarboxylic acid that is an additive of the lubricating oil is formed on the plastically processed surface.
Because it has excellent lubrication performance, it prevents plastic processing seizure of nonferrous metals and facilitates plastic processing.

該反応膜は、塑性加工時のダイスとの摩擦熱によって非
鉄金属素材表面と前記添加剤が主として反応し、金属石
鹸の皮膜が形成されるものと推定される(桜井:潤滑油
添加剤の現状と将来:潤滑。
It is assumed that the reaction film is mainly caused by the reaction between the surface of the non-ferrous metal material and the additive due to frictional heat from the die during plastic working, forming a film of metal soap (Sakurai: Current status of lubricating oil additives) And the future: lubrication.

15、 No、6302〜310.1970年)。15, No. 6302-310.1970).

該金属石鹸皮膜は、ダイスと素材表面の局部的な接触部
分に効果的に生成して強固な膜となり。
The metal soap film is effectively formed at the local contact area between the die and the material surface, and becomes a strong film.

ダイスと素材金属との直接接触による「焼付き」を防止
する。そのために、円滑な塑性加工ができるのである。
Prevents "seizing" caused by direct contact between the die and the raw metal. Therefore, smooth plastic working is possible.

特に、伸線加工においてその効果が大きく、これまでに
ない高速伸線加工においても焼付きが発生しない。
The effect is particularly great in wire drawing, and seizure does not occur even in unprecedented high-speed wire drawing.

[実施例] 以下に実施例を示して本発明を具体的に説明する。[Example] EXAMPLES The present invention will be specifically described below with reference to Examples.

実施例1〜11 潤滑ベース油に40”Cの粘度が650cStのポリイ
ソブチレンを用い、これに第1表に示した油脂、脂肪族
ジカルボン酸を10重量%加え加熱溶解した潤滑油を作
成した。これを鋼材を芯線とし1表面に銅を被覆した複
合線素材を第1図に示す伸線機を用いて伸線加工を行っ
た。なお、第3図にダイス部の略図を示す。
Examples 1 to 11 Using polyisobutylene of 40"C and a viscosity of 650 cSt as a lubricating base oil, 10% by weight of the oils and fats shown in Table 1 and aliphatic dicarboxylic acids were added and dissolved by heating to prepare lubricating oils. A composite wire material having a steel core and one surface coated with copper was drawn using a wire drawing machine shown in Fig. 1.A schematic diagram of the die part is shown in Fig. 3.

サプライ1に巻かれた複合線素材1をガイド3により誘
導し、潤滑油4中で浸漬塗布しながら熱伝対6を取付け
た絞りダイス5で縮径し、伸線機に取り付けたドラム7
により巻き取る。
A composite wire material 1 wound around a supply 1 is guided by a guide 3, and while being dip-coated in lubricating oil 4, its diameter is reduced by a drawing die 5 equipped with a thermocouple 6, and then the material is reduced in diameter to a drum 7 attached to a wire drawing machine.
Wind it up.

次いで、処理室9内に取付けた矯正機10を通して歪を
矯正した後、トリクレン溶剤11を吹き付けがら回転ブ
ラシ12で伸線表面に付着した潤滑油を除去した。これ
を、エアブロ−13で溶剤を除去した後、巻取機14に
取付けた巻取ドラム15で巻取った。
Next, after the strain was corrected through a straightening machine 10 installed in the processing chamber 9, the lubricating oil adhering to the wire drawing surface was removed with a rotating brush 12 while spraying a trichloride solvent 11. After removing the solvent with an air blower 13, this was wound up with a winding drum 15 attached to a winder 14.

伸線後の表面を目視でI!aし、焼き付き状態及び表面
の割れを11irI!Iシた。また、絞りダイスの上昇
温度〔(加工時の温度)−(初期温度)〕を測定した。
Visually check the surface after wire drawing! 11irI! I had it. In addition, the rising temperature of the drawing die [(temperature during processing)−(initial temperature)] was measured.

結果を第1表に示す、尚、伸線加工は下記の条件で行な
った。
The results are shown in Table 1. The wire drawing process was performed under the following conditions.

線   材:[材に銅を被覆したもの。Wire material: [Material coated with copper.

(Cu−steel線材) ダイス形状:リダクションアングル2度絞り径 直径2
.89mm ベアリング部長さ 2mm の円錐ダイス 加 工 率:20.4%(直径3.24厘厘を直径  
     2.89諺■に伸線)加工速度:110m/
min ダイス温度:室温12℃ 第 表 O:極めて良好、Q:良好、Δ:焼付き寸前、×:焼付
き 比較例 1〜7 各比較例で用いた潤滑油を第2表に示す、なお括弧内の
数値は40℃における粘度(C5t)を示す。
(Cu-steel wire rod) Die shape: Reduction angle 2 degrees Diameter 2
.. Conical die machining rate of 89mm bearing length 2mm: 20.4% (diameter 3.24mm)
2.89 Proverb ■ Wire drawing) Processing speed: 110m/
min Die temperature: room temperature 12°C Table O: Very good, Q: Good, Δ: On the verge of seizure, ×: Seizure Comparative Examples 1 to 7 The lubricating oils used in each comparative example are shown in Table 2, with parentheses The numerical value inside indicates the viscosity (C5t) at 40°C.

第2表 実施例 12 実施例1〜11と同じ組成の潤滑油を用いアルミニウム
を鋼材芯線の表面に被覆した複合線素材を、第1図の伸
線機を用いて伸線加工を行った。
Table 2 Example 12 A composite wire material in which the surface of a steel core wire was coated with aluminum using a lubricating oil having the same composition as in Examples 1 to 11 was drawn using the wire drawing machine shown in FIG.

目視による伸線後の表面性状(焼き付き及び表面の割れ
)及びダイス上昇温度の結果を第3表に示した。
Table 3 shows the results of visual inspection of the surface properties (seizing and surface cracks) and die temperature rise after wire drawing.

また、伸線後の線表面の粗さを真円度測定機(小板研究
所製EC−43)により測定したところ、円周方向で約
±2μmであった。
Moreover, when the roughness of the wire surface after wire drawing was measured using a roundness measuring machine (EC-43 manufactured by Koita Research Institute), it was approximately ±2 μm in the circumferential direction.

同様にして、前記比較例2(ポリブテン使用)および比
較例5(ポリブテン+カルシュウム石鹸使用)のものに
ついても、表面粗さ測定したが、いずれも約±4μmで
あった。
In the same manner, the surface roughness of Comparative Example 2 (using polybutene) and Comparative Example 5 (using polybutene + calcium soap) was measured, and the surface roughness was about ±4 μm in both cases.

実施例 13〜38 第4表に示したベース油、油脂および脂肪族ジカルボン
酸を加熱溶解した潤滑油を15〜17℃で実施例2と同
じ伸線機によりアルミニウム被覆鋼I!素材の伸線加工
を行い、ダイス上昇温度及び伸線表面の性状を調べた。
Examples 13 to 38 A lubricating oil obtained by heating and dissolving the base oil, fat, and aliphatic dicarboxylic acid shown in Table 4 was heated to 15 to 17°C using the same wire drawing machine as in Example 2 to produce aluminum coated steel I! The material was wire-drawn, and the die temperature rise and the properties of the wire-drawing surface were investigated.

結果は第4表に示す。The results are shown in Table 4.

第4表の結果から油脂または脂肪族ジカルボン酸の配合
量が2重量%より少なくなるとダイス温度が急上昇する
。また伸線表面が焼付き寸前となる。配合量が20重量
%を超えると性状向上は飽和する傾向がある。
From the results shown in Table 4, when the amount of oil or fat or aliphatic dicarboxylic acid is less than 2% by weight, the die temperature rises rapidly. Moreover, the wire drawing surface is on the verge of seizure. If the blending amount exceeds 20% by weight, the improvement in properties tends to be saturated.

実施例 39 40℃のおける粘度が2oO〜300,000C8tの
ポリブテンにラノリン10重量%配合した潤滑油を実施
例2と同じアルミニウム被覆鋼線素材を用い、第1図の
伸線機で加工率20%の条件で伸線加工を行ない、ベー
ス油の粘度とダイスの上昇温度との関係を測定した。結
果を第4図に示す。
Example 39 Using the same aluminum-coated steel wire material as in Example 2, a lubricating oil containing 10% by weight of lanolin and polybutene with a viscosity of 2oO to 300,000C8t at 40°C was used at a processing rate of 20 using the wire drawing machine shown in Figure 1. %, and the relationship between the viscosity of the base oil and the temperature rise of the die was measured. The results are shown in Figure 4.

粘度が300cSt以下になるとダイス上昇温度が大き
くなる。また、引抜きを一度停止して再び伸線加工を行
なったところ、断線する場合があった・ 一方、35,0OOcSt以上になるとダイス温度が上
昇し始め、潤滑油の持出量が多くなり単頭伸線機、巻取
ドラム、床面等に付着し易くなり。
When the viscosity becomes 300 cSt or less, the die temperature rise increases. In addition, when drawing was stopped once and wire drawing was performed again, the wire sometimes broke. On the other hand, when the temperature exceeds 35,0000cSt, the die temperature begins to rise, and the amount of lubricating oil taken out increases, resulting in a single head. It tends to adhere to wire drawing machines, winding drums, floors, etc.

作業性、特に、潤滑油の補給時の取扱性が悪くなる0作
業性、安全性の上からも潤滑油粘度は。
The viscosity of the lubricating oil is important from the viewpoint of workability and safety, especially the ease of handling when replenishing the lubricating oil.

50.000cSt程度までである。It is up to about 50,000 cSt.

実施例 40 40’Cl71粘度が31.0OOC8tのエチレンα
オレフィン共重合物90重量%、ラノリン10重量%か
らなる潤滑油用いて、直径8 、4 m mのアルミニ
ウム被覆鋼線素材を、第2図に示す連続伸線機で11工
程の伸線加工を行い、実用性能を評価した。加工条件及
び伸線後9表面性状、芯線と被覆層との断面比の結果を
第5表に示す。
Example 40 Ethylene α with 40'Cl71 viscosity of 31.0OOC8t
Using a lubricating oil consisting of 90% by weight of olefin copolymer and 10% by weight of lanolin, an aluminum-coated steel wire material with a diameter of 8.4 mm was drawn in 11 steps using a continuous wire drawing machine shown in Figure 2. and evaluated its practical performance. Table 5 shows the processing conditions, surface properties after wire drawing, and the cross-sectional ratio of the core wire to the coating layer.

第5表の結果から分かるように、極めて良好な表面性状
を示し、円滑な伸線加工を行うことができた。また、芯
線と被覆層との断面比は、34゜8〜36.0%の範囲
であり、極めて良好であった。さらに、11工程後の伸
線表面に付着した潤滑油を、第2図中の処理室9内にで
、トリクレン溶剤11、回転ブラシ12により洗浄した
ところ、−回の洗浄で伸線表面に付着した潤滑油を、は
ぼ完全に除去することができた。
As can be seen from the results in Table 5, extremely good surface properties were exhibited and smooth wire drawing could be performed. Further, the cross-sectional ratio of the core wire to the coating layer was in the range of 34°8 to 36.0%, which was extremely good. Furthermore, when the lubricating oil that had adhered to the wire drawing surface after the 11th step was washed with TriClene solvent 11 and rotating brush 12 in the processing chamber 9 in FIG. It was possible to completely remove the lubricating oil.

第5表 #11工程の伸線加工後トリクレンを用いて付着潤滑油
を洗浄実施例 41 実施例40で得たアルミニウム被覆導電線(素線径2 
、9 amφ)を、タンデム型高速撚り線機を用い、素
線数30本、断面積200mm”の条件で撚り、実用性
能を評価した。その結果1表面に傷等の発生も無く、正
常な撚線を得ることができた。
Example 41: After the wire drawing process in #11 of Table 5, the attached lubricating oil was cleaned using Triclean. Example 41 The aluminum-coated conductive wire obtained in Example 40 (wire diameter
. I was able to get twisted wire.

なお、撚り線作業時にも前記潤滑油を用いると一層効果
的である。
Note that it is even more effective to use the lubricating oil during the wire stranding work.

実施例 42〜52および比較例8〜14第5図に示す
直径63mmX内径12mmX厚さ12mmのリング状
のアルミ素材A2218(0)  (JIS−H400
]:基づき、400℃。
Examples 42 to 52 and Comparative Examples 8 to 14 Ring-shaped aluminum material A2218(0) (JIS-H400) with diameter 63 mm x inner diameter 12 mm x thickness 12 mm shown in Fig.
]: Based on 400°C.

2時間→室温まで徐冷)の表面に、実施例1〜11およ
び比較例1〜7と同じ組成の潤滑油を塗布して、40個
/分の加工速度で塑性加工を行い、第6図に示す形状の
部品を2000個成形した。
A lubricating oil having the same composition as in Examples 1 to 11 and Comparative Examples 1 to 7 was applied to the surface of the sample (2 hours → slow cooling to room temperature), and plastic working was performed at a processing speed of 40 pieces/min. 2000 parts having the shape shown in the figure were molded.

成形品の表面状態を第6表に示す。表から明らかなよう
に本発明による加工品は焼き付き等の発生もなく優れた
表面性状を示した。
Table 6 shows the surface condition of the molded product. As is clear from the table, the processed products according to the present invention exhibited excellent surface properties without occurrence of burn-in or the like.

第 表 O:極めて良好、0:良好、Δ:焼付き寸前。No. table O: Very good, 0: Good, Δ: On the verge of seizure.

X:焼付き [発明の効果] 本発明の塑性加工方法によれば、非鉄金属を焼付き等の
発生なく塑性加工することができ、加工後の部品の表面
性状も極めて優れているので、高品質の非鉄全屈部品を
提供することができる。
X: Seizure [Effects of the Invention] According to the plastic working method of the present invention, non-ferrous metals can be plastic worked without seizure etc., and the surface properties of the parts after processing are also extremely excellent. We can provide quality non-ferrous fully bent parts.

また、高速伸線においても優れた耐焼付き性。It also has excellent seizure resistance even during high-speed wire drawing.

並びに高潤滑性を有するので、高速伸線加工及び高速撚
り線加工が円滑に行なうことができ、導電線の品質並び
に生産性の向上に優れている。
In addition, since it has high lubricity, high-speed wire drawing and high-speed wire stranding can be performed smoothly, and it is excellent in improving the quality and productivity of conductive wires.

更にまた、複合導電線の導電率(被覆厚さ一定)に対し
ても、本発明の伸線加工法によれば、充分対応できるも
のが提供できる。
Furthermore, according to the wire drawing method of the present invention, it is possible to provide a composite conductive wire that is sufficiently compatible with the conductivity (constant coating thickness).

本発明の伸線加工に用いる潤滑油は低粘度であるため、
作業性及び作業の安全性においても優れている。
Since the lubricating oil used in the wire drawing process of the present invention has a low viscosity,
It is also excellent in workability and work safety.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は伸線機の略図、第2図は連続伸線機の略図、第
3図は伸線機のダイス部の略図、第4図は本発明の方法
により伸線した場合のダイス上昇温度と粘度の関係を示
す曲線図、第5図は塑性加工前のアルミ素材の断面図、
第6図は塑性加工後の部品の断面図である。 1−m−サプライ、  2−m−線素材、  3−m−
ガイド、4−m−潤滑油、  5−一一絞りダイス、 
 6−−−熱電対、  7一−−伸線機ドラム、 8−
−一滑車、9−−−処理室、  10−m−矯正機、 
 11−一一溶剤、12−−−回転ブラシ、  13−
m−エアブロー  14−巻取機、   15−m−巻
取ドラム、   16−−−ロードセル。 も −−一ローi゛区1し 躬 凹 用層油の紡ル(XI03 cSt/4o”C)
Fig. 1 is a schematic diagram of the wire drawing machine, Fig. 2 is a schematic diagram of the continuous wire drawing machine, Fig. 3 is a schematic diagram of the die section of the wire drawing machine, and Fig. 4 is the rise of the die when wire is drawn by the method of the present invention. A curve diagram showing the relationship between temperature and viscosity. Figure 5 is a cross-sectional diagram of the aluminum material before plastic working.
FIG. 6 is a cross-sectional view of the part after plastic working. 1-m-supply, 2-m-wire material, 3-m-
Guide, 4-m-lubricating oil, 5-11 drawing die,
6--Thermocouple, 71--Wire drawing machine drum, 8-
-One pulley, 9--processing chamber, 10-m-straightening machine,
11-11 solvent, 12--rotating brush, 13-
m-air blow 14-winding machine, 15-m-winding drum, 16--load cell. ---1 row i゛ section 1 layer oil spinning for dents (XI03 cSt/4o"C)

Claims (9)

【特許請求の範囲】[Claims] (1)非鉄金属の表面に、液状高分子化合物をベース油
とし、これに動植物性油脂または脂肪族ジカルボン酸か
ら選ばれる添加剤を配合した潤滑油を塗布し、ダイスを
用いて塑性加工することにより発生する熱により潤滑皮
膜を前記非鉄金属表面に形成しながら塑性加工すること
を特徴とする非鉄金属の塑性加工方法。
(1) A lubricating oil containing a liquid polymer compound as a base oil and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids is applied to the surface of nonferrous metals, and plastic processing is performed using a die. A method for plastic working non-ferrous metals, characterized in that plastic working is performed while forming a lubricating film on the surface of the non-ferrous metal using heat generated by the process.
(2)粘度が300〜50,000cSt(40℃)の
液状高分子化合物をベース油として用いることを特徴と
する請求項第1項記載の非鉄金属の塑性加工方法。
(2) The method for plastic working of non-ferrous metals according to claim 1, characterized in that a liquid polymer compound having a viscosity of 300 to 50,000 cSt (40°C) is used as the base oil.
(3)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
とし、これに動植物性油脂又は脂肪族ジカルボン酸から
選ばれる添加剤を配合した潤滑油を塗布して伸線加工用
の絞りダイスに通し、前記線素材を縮径加工することに
より発生する熱により潤滑皮膜を前記非鉄金属表面に形
成しながら伸線加工することを特徴とする導電線の製造
方法。
(3) On the surface of a wire material made of a non-ferrous metal or a wire material whose core wire is coated with a non-ferrous metal, a liquid polymer compound is used as a base oil, and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids is blended with this. The wire is drawn while a lubricating film is formed on the surface of the non-ferrous metal by the heat generated by applying lubricating oil and passing it through a drawing die for wire drawing to reduce the diameter of the wire material. Method of manufacturing conductive wire.
(4)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
とし、これに動植物性油脂又は脂肪族ジカルボン酸から
選ばれる添加剤を配合した潤滑油を塗布して伸線加工用
の絞りダイスに通し、前記線素材を縮径加工することに
より発生する熱により前記非鉄金属と前記潤滑油添加剤
との反応皮膜を前記非鉄金属表面に形成しながら伸線加
工することを特徴とする導電線の製造方法。
(4) On the surface of a wire material made of a non-ferrous metal or a wire material whose core wire is coated with a non-ferrous metal, a liquid polymer compound is used as a base oil, and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids is blended with this. A reaction film of the non-ferrous metal and the lubricating oil additive is formed on the surface of the non-ferrous metal by the heat generated by applying lubricating oil and passing it through a drawing die for wire drawing to reduce the diameter of the wire material. A method for manufacturing a conductive wire, characterized in that wire drawing is performed while the wire is being drawn.
(5)粘度が300〜50,000cSt(40℃)の
液状高分子化合物をベース油として用いることを特徴と
する請求項第3項または第4項記載の導電線の製造方法
(5) The method for manufacturing a conductive wire according to claim 3 or 4, characterized in that a liquid polymer compound having a viscosity of 300 to 50,000 cSt (40°C) is used as the base oil.
(6)粘度が300〜50,000cSt(40℃)の
ポリブデン、ポリメタクリレート、ポリイソブチレン、
エチレン−α−オレフィン共重合物、ポリアルキレング
リコールから選ばれる1種以上のベース油98〜75重
量%と、動植物性油脂または炭素数5〜36の脂肪族ジ
カルボン酸から選ばれる添加剤2〜25重量%を含む潤
滑油を用いることを特徴とする請求項第3項または第4
項記載の導電線の製造方法。
(6) Polybutene, polymethacrylate, polyisobutylene with a viscosity of 300 to 50,000 cSt (40°C),
98 to 75% by weight of one or more base oils selected from ethylene-α-olefin copolymers and polyalkylene glycols, and 2 to 25% of additives selected from animal and vegetable oils and aliphatic dicarboxylic acids having 5 to 36 carbon atoms. Claim 3 or 4, characterized in that a lubricating oil containing % by weight is used.
2. Method for manufacturing a conductive wire as described in Section 1.
(7)非鉄金属が銅またはアルミニウムであることを特
徴とする請求項第3項〜第6項のいずれかに記載の導電
線の製造方法。
(7) The method for manufacturing a conductive wire according to any one of claims 3 to 6, wherein the nonferrous metal is copper or aluminum.
(8)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
としこれに動植物性油脂又は脂肪族ジカルボン酸から選
ばれる添加剤を配合した潤滑油を塗布して伸線加工用の
絞りダイスに通し、前記線素材を縮径加工することによ
り発生する熱により潤滑皮膜を前記非鉄金属表面に形成
しながら伸線加工したものを2本以上撚り合わせること
を特徴とする導電線の製造方法。
(8) Lubricating the surface of a wire material made of non-ferrous metal or a wire material whose core wire is coated with non-ferrous metal, using a liquid polymer compound as a base oil and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids. The wire is coated with oil and passed through a drawing die for wire drawing, and the wire is drawn while forming a lubricating film on the surface of the non-ferrous metal using the heat generated by reducing the diameter of the wire. Two or more wires are twisted together. A method for manufacturing a conductive wire, characterized by combining.
(9)非鉄金属から成る線素材または非鉄金属を芯線に
被覆した線素材の表面に、液状高分子化合物をベース油
としこれに動植物性油脂又は脂肪族ジカルボン酸から選
ばれる添加剤を配合した潤滑油を塗布して伸線加工用の
絞りダイスに通し、前記線素材を縮径加工することによ
り発生する熱により前記非鉄金属と前記潤滑油添加剤と
の反応皮膜を前記非鉄金属表面に形成しながら伸線加工
したものを2本以上撚り合わせることを特徴とする導電
線の製造方法。
(9) Lubricating the surface of a wire material made of non-ferrous metal or a wire material whose core wire is coated with non-ferrous metal, using a liquid polymer compound as a base oil and an additive selected from animal and vegetable oils and fats or aliphatic dicarboxylic acids. A reaction film of the non-ferrous metal and the lubricating oil additive is formed on the surface of the non-ferrous metal by the heat generated by applying oil and passing it through a drawing die for wire drawing to reduce the diameter of the wire material. A method for manufacturing a conductive wire, which comprises twisting together two or more wires that have been drawn together.
JP63235193A 1988-05-10 1988-09-20 Conductive wire manufacturing method Expired - Lifetime JPH0726110B2 (en)

Priority Applications (3)

Application Number Priority Date Filing Date Title
JP63235193A JPH0726110B2 (en) 1988-09-20 1988-09-20 Conductive wire manufacturing method
EP89108389A EP0341688B1 (en) 1988-05-10 1989-05-10 A method for manufacturing electrically conductive substances with a lubricant composition
DE8989108389T DE68900213D1 (en) 1988-05-10 1989-05-10 METHOD FOR PRODUCING ELECTRICAL PIPING AGENTS WITH A LUBRICANT COMPOSITION.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63235193A JPH0726110B2 (en) 1988-09-20 1988-09-20 Conductive wire manufacturing method

Publications (2)

Publication Number Publication Date
JPH0284495A true JPH0284495A (en) 1990-03-26
JPH0726110B2 JPH0726110B2 (en) 1995-03-22

Family

ID=16982459

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63235193A Expired - Lifetime JPH0726110B2 (en) 1988-05-10 1988-09-20 Conductive wire manufacturing method

Country Status (1)

Country Link
JP (1) JPH0726110B2 (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991018074A1 (en) * 1990-05-14 1991-11-28 Idemitsu Kosan Co., Ltd. Lubricant composition for metal working
JP2006265316A (en) * 2005-03-23 2006-10-05 Aqua Kagaku Kk Lubricant for coupling of piping
JP2011162853A (en) * 2010-02-10 2011-08-25 Showa Denko Kk Method for retreating tool for metalworking
CN112201414A (en) * 2020-10-14 2021-01-08 浙江一舟电子科技股份有限公司 Controllable oil passing device for cable production
CN113817530A (en) * 2021-09-29 2021-12-21 南京科润工业介质股份有限公司 Drawing oil containing nano-particle additive

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
CHEMICAL ABSTRACTS=1986 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1991018074A1 (en) * 1990-05-14 1991-11-28 Idemitsu Kosan Co., Ltd. Lubricant composition for metal working
JP2006265316A (en) * 2005-03-23 2006-10-05 Aqua Kagaku Kk Lubricant for coupling of piping
JP2011162853A (en) * 2010-02-10 2011-08-25 Showa Denko Kk Method for retreating tool for metalworking
CN112201414A (en) * 2020-10-14 2021-01-08 浙江一舟电子科技股份有限公司 Controllable oil passing device for cable production
CN113817530A (en) * 2021-09-29 2021-12-21 南京科润工业介质股份有限公司 Drawing oil containing nano-particle additive

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