JPH0275153A - Lead-acid battery - Google Patents
Lead-acid batteryInfo
- Publication number
- JPH0275153A JPH0275153A JP63225013A JP22501388A JPH0275153A JP H0275153 A JPH0275153 A JP H0275153A JP 63225013 A JP63225013 A JP 63225013A JP 22501388 A JP22501388 A JP 22501388A JP H0275153 A JPH0275153 A JP H0275153A
- Authority
- JP
- Japan
- Prior art keywords
- separator
- anode
- anode plate
- rib
- discharging
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002253 acid Substances 0.000 title claims description 5
- 229910052787 antimony Inorganic materials 0.000 claims abstract description 9
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 claims abstract description 9
- 239000012982 microporous membrane Substances 0.000 claims description 2
- 229920003002 synthetic resin Polymers 0.000 claims description 2
- 239000000057 synthetic resin Substances 0.000 claims description 2
- 238000005275 alloying Methods 0.000 claims 1
- 238000007599 discharging Methods 0.000 abstract description 6
- 101100334009 Caenorhabditis elegans rib-2 gene Proteins 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 4
- 239000003792 electrolyte Substances 0.000 abstract description 4
- 239000011800 void material Substances 0.000 abstract description 2
- 229910000967 As alloy Inorganic materials 0.000 abstract 1
- 239000013543 active substance Substances 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 229920003023 plastic Polymers 0.000 abstract 1
- 229910045601 alloy Inorganic materials 0.000 description 3
- 239000000956 alloy Substances 0.000 description 3
- 239000006183 anode active material Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 239000011521 glass Substances 0.000 description 2
- 229910001128 Sn alloy Inorganic materials 0.000 description 1
- 239000011149 active material Substances 0.000 description 1
- 238000005452 bending Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M4/00—Electrodes
- H01M4/02—Electrodes composed of, or comprising, active material
- H01M4/14—Electrodes for lead-acid accumulators
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/40—Separators; Membranes; Diaphragms; Spacing elements inside cells
- H01M50/463—Separators, membranes or diaphragms characterised by their shape
- H01M50/466—U-shaped, bag-shaped or folded
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Cell Separators (AREA)
Abstract
Description
【発明の詳細な説明】
産業上の利用分野
本発明は自動車のエンジン始動などに用いられる鉛蓄電
池に関する。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to a lead-acid battery used for starting an automobile engine, etc.
従来の技術
鉛蓄電池の内部は陽極板、陰極板およびそれらを隔離す
るセパレータ等で構成される。The interior of a conventional lead-acid battery is composed of an anode plate, a cathode plate, a separator separating them, and the like.
このなかでセパレータに合成樹脂を主成分としたフィル
ム状微多孔膜を用いるものである。このセパレータは極
板を包みこむように折り曲げて側面をシールして袋状に
して用いられるのが一般的である。Among these, a film-like microporous membrane whose main component is a synthetic resin is used as a separator. This separator is generally used in the form of a bag by bending it so as to wrap around the electrode plate and sealing the sides.
このため陽極板と陰極板とが完全に遮蔽され、長期使用
後に、たとえば陽極活物質が軟化して脱落しても内部短
絡しない。このため従来セパレータと必ず併用し陽極活
物質を保持していたガラスマットは、省略されるのが一
般的である。Therefore, the anode plate and the cathode plate are completely shielded, and even if, for example, the anode active material softens and falls off after long-term use, there will be no internal short circuit. For this reason, the glass mat, which was conventionally always used in combination with the separator to hold the anode active material, is generally omitted.
そしてガラスマットが省略された部分は空隙となるが、
その部分にはフィルム状セパレータの一部にリブをもう
けて極板とセパレータ間の距離を確保するのが一般的で
ある。And the part where the glass mat is omitted becomes a void,
Generally, a rib is provided in a part of the film-like separator to secure the distance between the electrode plate and the separator.
この場合、リブは一般的に陽極板と相対するように設け
られる。これは陽極の充放電反応においては水の生成、
消費反応が関与するため、電池の初期容量、特に急放電
持続時間を確保するのに有利なようにである。In this case, the ribs are generally provided opposite the anode plate. This is due to the generation of water in the charge/discharge reaction of the anode.
Since a consumption reaction is involved, it is advantageous to ensure the initial capacity of the battery, especially the rapid discharge duration.
発明が解決しようとする課題
陽極にアンチモンを含まない電池は、自己放′市および
使用中の減液が少ないという特徴があるが、一般にアン
チモンを用いた電池にくらべて深い充放電における寿命
が短かいとされている。Problems to be Solved by the Invention Batteries that do not contain antimony in their anodes are characterized by less self-release and less liquid loss during use, but they generally have a shorter lifespan during deep charging and discharging than batteries that use antimony. It is said to be important.
本発明は陽極板の格子合金にアンチモンを含まない電池
のこの短所を改善することを目的とする。The present invention aims to improve this disadvantage of batteries that do not contain antimony in the lattice alloy of the anode plate.
課題を解決するための手段
この問題点を解決するための手段として、本発明では先
に述べたように従来陽極板に接するように配置されてい
たセパレータのリブを陰極に接するように、又リブのな
い面を陽極板に接するようにし、袋状セパレータとして
陽極板又は陰極板を包むように構成したものである。Means for Solving the Problem As a means for solving this problem, in the present invention, as mentioned above, the ribs of the separator, which were conventionally arranged so as to be in contact with the anode plate, are changed so that the ribs are in contact with the cathode, and the ribs are The surface without the ridge is in contact with the anode plate, and the bag-shaped separator is configured to wrap around the anode plate or the cathode plate.
作 用
先に述べた陽極板の格子合金にアンチモンを用いない電
池における深い充放電のくりかえしで寿命が短かい理由
は、充放電をくりかえすうち、陽極活物質の粒子間の結
合が弱くなり、充放電反応が格子活物質界面近傍のみで
しかおこらないことによる。The reason why batteries that do not use antimony in the lattice alloy of the anode plate described above have a short life due to repeated deep charging and discharging is that as the batteries are repeatedly charged and discharged, the bonds between the particles of the anode active material become weaker and the charging This is because the discharge reaction occurs only near the interface of the lattice active material.
この現象は特に陽極板近傍の電解液（稀硫酸）濃度が高
い程顕著である。This phenomenon is particularly noticeable as the electrolyte (dilute sulfuric acid) concentration near the anode plate increases.
本発明ではセパレータを陽極板に密着させるようにする
ことにより陽極板への電解液の供給を抑制して陽極近傍
の電解液濃度を低下させてこの現象を緩和するものであ
る。In the present invention, this phenomenon is alleviated by bringing the separator into close contact with the anode plate to suppress the supply of electrolyte to the anode plate and reduce the concentration of the electrolyte near the anode.
実施例 以下実施例により本発明について説明する。Example The present invention will be explained below with reference to Examples.
鉛−カルシウム−錫合金からなるエキスバンド加工した
格子を用いて陽陰極板を常法により作製した。Anode and cathode plates were fabricated by a conventional method using an expanded grid made of a lead-calcium-tin alloy.
このうち陽極板は次の２通りとした。その一つは第１図
ａに示すように従来通りリブ２に極板が接するよう袋状
セパレータ３で包みこんだ。なお４はシール部である。Among these, the following two types of anode plates were used. In one of them, as shown in FIG. 1a, the rib 2 was wrapped in a bag-like separator 3 so that the electrode plate was in contact with the rib 2 as in the past. Note that 4 is a seal portion.
もう一方は第１図すに示す本発明の例でありリブ２のな
いセパレータ３表面が極板１と接するように極板を包み
こんだものである。The other is an example of the present invention shown in FIG. 1, in which the electrode plate 1 is wrapped so that the surface of the separator 3 without ribs 2 is in contact with the electrode plate 1.
このような袋状セパレータ入り陽極板と陰極板その他の
構成要素を用いて常法により５５Ｄ２３形の自動車用蓄
電池を製作した。A 55D23 type automobile storage battery was manufactured by a conventional method using such an anode plate containing a bag-shaped separator, a cathode plate, and other components.
これらの電池について初期性能およびｌｌ５ｑｆ命特性
について調べた。その結果を第１表および第２図に示す
。The initial performance and ll5qf life characteristics of these batteries were investigated. The results are shown in Table 1 and Figure 2.
５１、
第 １ 表
これより初期性能（特に急放電持続時間）は従来品より
若干低いものの、ＪＩＳ寿命については従来品よりも約
５０％改善されることがわかる。51, Table 1 It can be seen that although the initial performance (especially rapid discharge duration) is slightly lower than the conventional product, the JIS life is improved by about 50% over the conventional product.
発明の効果
以上述べたように本発明によれば陽極格子の合金成分に
アンチモンを含まない鉛蓄電池において、特別のコスト
アップすることなしに深い充放電をくりかえしだときの
寿命を改善することができる。Effects of the Invention As described above, according to the present invention, it is possible to improve the life of a lead-acid battery that does not contain antimony in the alloy component of the anode grid when deep charging and discharging are repeated without any particular increase in cost. .
第１図は陽極板を袋状セパレータに挿入した図であり、
（、）は従来例、（ｂ）は本発明の実施例を示し、第２
図は■工Ｓ寿命試験結果を示す図である。
１・・・・・・陽極板、２・・・・・・リブ、３・・・
・・・セパレータ、４・・・・・・ シール部。Figure 1 shows the anode plate inserted into the bag-like separator.
(,) shows the conventional example, (b) shows the embodiment of the present invention, and
The figure is a diagram showing the results of the ■Work S life test. 1... Anode plate, 2... Rib, 3...
... Separator, 4... Seal part.
Claims (1)
有するセパレータを、前記リブのない面が陽極板に接す
るよう袋状とし、この袋状セパレータでアンチモンを合
金成分として含まない格子を備えた陽極板又は陰極板を
包んだ鉛蓄電池。A separator made of a microporous membrane mainly composed of synthetic resin and having ribs on one side is shaped into a bag so that the surface without ribs is in contact with the anode plate, and this bag-shaped separator is provided with a lattice that does not contain antimony as an alloying component. A lead-acid battery with an anode or a cathode plate wrapped around it.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63225013A JPH0275153A (en) | 1988-09-08 | 1988-09-08 | Lead-acid battery |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63225013A JPH0275153A (en) | 1988-09-08 | 1988-09-08 | Lead-acid battery |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0275153A true JPH0275153A (en) | 1990-03-14 |
Family
ID=16822707
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63225013A Pending JPH0275153A (en) | 1988-09-08 | 1988-09-08 | Lead-acid battery |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0275153A (en) |
-
1988
- 1988-09-08 JP JP63225013A patent/JPH0275153A/en active Pending
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US3288642A (en) | Rechargeable dry cell having gelled electrolyte | |
| JP2002313432A (en) | Nickel-hydrogen storage battery | |
| CN107112598B (en) | lead-acid battery | |
| JP4507483B2 (en) | Control valve type lead acid battery | |
| JPH08287944A (en) | Lead-acid battery | |
| JPH0275153A (en) | Lead-acid battery | |
| US4238556A (en) | Lead-acid cell | |
| JP2006318658A (en) | Lead-acid battery | |
| JPH0628169B2 (en) | Sealed lead acid battery | |
| US3457111A (en) | Alkaline storage battery with be(oh)2 in the electrolyte | |
| JPH07312225A (en) | Sealed lead-acid battery | |
| JPH0542114B2 (en) | ||
| JP6870266B2 (en) | Lead-acid battery | |
| JP2000215882A (en) | Nickel-hydrogen storage battery and its using method | |
| JP2809634B2 (en) | Manufacturing method of sealed lead-acid battery | |
| JP2022166455A (en) | Electrode group and lea acid battery | |
| JP2000090964A (en) | Sealed lead-acid battery | |
| JP2000058105A (en) | Lead-acid battery | |
| JP2020107498A (en) | Negative electrode plate for lead storage battery and liquid lead storage battery using the same | |
| JPH10270030A (en) | Sealed lead-acid battery | |
| JPS58147957A (en) | Small sealed lead storage battery | |
| JPH06150961A (en) | Sealed lead-acid battery | |
| JPH08236142A (en) | Sealed type lead-acid battery | |
| JPS60117545A (en) | Lead storage battery | |
| JPH10321221A (en) | Electrode for lead-acid battery |