JPH0260739A - Coated metal piping material - Google Patents
Coated metal piping materialInfo
- Publication number
- JPH0260739A JPH0260739A JP63212255A JP21225588A JPH0260739A JP H0260739 A JPH0260739 A JP H0260739A JP 63212255 A JP63212255 A JP 63212255A JP 21225588 A JP21225588 A JP 21225588A JP H0260739 A JPH0260739 A JP H0260739A
- Authority
- JP
- Japan
- Prior art keywords
- layer
- piping material
- film
- resin
- metal piping
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000463 material Substances 0.000 title claims abstract description 24
- 239000002184 metal Substances 0.000 title claims abstract description 19
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 19
- 239000011347 resin Substances 0.000 claims abstract description 14
- 229920005989 resin Polymers 0.000 claims abstract description 14
- ZCDOYSPFYFSLEW-UHFFFAOYSA-N chromate(2-) Chemical compound [O-][Cr]([O-])(=O)=O ZCDOYSPFYFSLEW-UHFFFAOYSA-N 0.000 claims abstract description 8
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 6
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 6
- JHWNWJKBPDFINM-UHFFFAOYSA-N Laurolactam Chemical compound O=C1CCCCCCCCCCCN1 JHWNWJKBPDFINM-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920000299 Nylon 12 Polymers 0.000 claims abstract description 6
- 239000003822 epoxy resin Substances 0.000 claims abstract description 6
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 6
- 230000002093 peripheral effect Effects 0.000 claims abstract description 5
- 238000007747 plating Methods 0.000 claims abstract description 3
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims abstract 2
- 229910052725 zinc Inorganic materials 0.000 claims abstract 2
- 239000011701 zinc Substances 0.000 claims abstract 2
- 239000011248 coating agent Substances 0.000 claims description 14
- 238000000576 coating method Methods 0.000 claims description 14
- 239000002987 primer (paints) Substances 0.000 claims description 9
- 230000000379 polymerizing effect Effects 0.000 claims description 4
- 238000000151 deposition Methods 0.000 claims description 3
- 230000007797 corrosion Effects 0.000 abstract description 5
- 238000005260 corrosion Methods 0.000 abstract description 5
- 229920006122 polyamide resin Polymers 0.000 abstract description 4
- 238000010438 heat treatment Methods 0.000 abstract description 2
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract 4
- 230000035939 shock Effects 0.000 abstract 1
- 238000005452 bending Methods 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 210000004709 eyebrow Anatomy 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
Landscapes
- Laminated Bodies (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野］
本発明は一般に自動車等の各種給油、給気の供給路とし
て床面等の外部に配設される管径２０ｍ／ｍ程度以下の
比較的細径にして且つ薄肉からなる被覆金属配管材に関
するものである。[Detailed Description of the Invention] [Industrial Application Field] The present invention generally relates to pipes with a diameter of about 20 m/m or less, which are installed outside the floor surface etc. as various oil supply and air supply channels for automobiles, etc. This invention relates to a coated metal piping material having a small diameter and a thin wall.
［従来の技術］
従来、一般に自動車の走行中での飛び石に対する保護性
並びに耐食性の同時要求に関連してなるこの種の被覆金
属配管材としては、例えば第３図に示すようにクロメ−
Ｉ〜被被膜１２’）を形成した亜鉛鍍金層（１２）を有
してなる金属配管材（１１）の外側周面に、直接、熱収
縮性からなる塩化ビニル樹脂或いはポリオレフィン樹脂
等のチューブによる被膜（１３）を被着重合して構成さ
れるものであった。[Prior Art] Conventionally, as this type of coated metal piping material, which is generally required to simultaneously provide protection against flying stones during driving of an automobile and corrosion resistance, for example, chrome-coated metal piping material as shown in FIG. 3 has been used.
A tube made of heat-shrinkable vinyl chloride resin or polyolefin resin is directly attached to the outer peripheral surface of the metal piping material (11) having the galvanized layer (12) on which the coating 12') is formed. It was constructed by depositing and polymerizing the coating (13).
［発明が解決しようとする課題］
しかしながら、このような従来の技術においては、−重
の前記被膜（１３）の構造によって比較的厚状からなる
該被膜構造を余儀なくされることとなり、その後の製品
としての複雑な曲げ加工時に著しく作業性が阻害される
こととなり、また概して高価とする傾向にあり、更にそ
の被着重合の状態にあって配管材（１１）側との密着性
に乏ぼしく、前記曲げ加工に際して曲げ部分或いは端管
部に剥離による間隙を生ザしぬ、雨水洗車水等の侵入を
許容する問題を有するものであった。[Problems to be Solved by the Invention] However, in such a conventional technique, the structure of the coating (13) is relatively thick, which makes it difficult for subsequent products. This significantly impedes workability during complicated bending processes, and generally tends to be expensive, and furthermore, it is in a polymerized state and has poor adhesion to the piping material (11) side. However, during the bending process, there are problems in that gaps due to peeling are not created in the bent portion or the end tube portion, and that rainwater, car wash water, etc. are allowed to enter.
本発明は従来技術の有する前記問題に鑑みてなされたも
のであり、飛び石による外部衝撃に対する保護性と耐食
性とを同時に満足することができ、その後の曲げ加工時
にあって作業性を良好となし、且つ曲げ部分及び端管部
での剥離の憂いをなくし、また概して安価に構成するこ
とができ、更に被覆外面が平滑である被覆金属配管材を
提案することを目的とするものて゛ある。The present invention has been made in view of the above-mentioned problems of the prior art, and can simultaneously satisfy protection against external impact caused by flying stones and corrosion resistance, and improve workability during subsequent bending processing. It is an object of the present invention to propose a coated metal piping material that eliminates the fear of peeling at bent portions and end pipe portions, can be generally constructed at low cost, and has a smooth outer coated surface.
［課題を解決するための手段］
本発明は上記目的を達成するため、比較的細径からなる
配管材の外側周面に、クロメート被膜を形成した亜鉛鍍
金層を下層とし、且つ該クロメート被膜上に、必要に応
じプライマー被膜を介在して弗素樹脂層を中間層として
有し、更に該弗素樹脂層の表面にエポキシ樹脂、アクリ
ル樹脂或いはナイロン１２を主体とする共重合ポリアミ
ド系樹脂によるプライマー被膜を敷設して塩化ビニル樹
脂のゾルライニングによるゲル化した被膜を上層として
被着重合して構成した被覆金属配管材を要旨とするもの
である。[Means for Solving the Problems] In order to achieve the above object, the present invention provides a method in which a galvanized layer with a chromate film is formed as a lower layer on the outer peripheral surface of a piping material having a relatively small diameter, and If necessary, a fluororesin layer is provided as an intermediate layer with a primer coating interposed therebetween, and a primer coating made of epoxy resin, acrylic resin, or copolyamide resin mainly composed of nylon 12 is further applied to the surface of the fluororesin layer. The gist is a coated metal piping material constructed by laying and polymerizing a gelled coating formed by sol lining of vinyl chloride resin as an upper layer.
［作用］
本発明はこのように構成されているため、前記上層とし
ての塩化ビニル樹脂のゾルライニングによる被膜を、該
被膜と密着性の良好なエポキシ樹脂、アクリル樹脂、或
いはナイロン１２を主体とする共重合ポリアミド系樹脂
によるプライマー被膜を介してこの被着後の低温加熱に
より、極めて簡易に中間層を有して金属配管材側の表面
に重合して構成されるため、断層状からなる被着重合さ
れた構造により全体を概して薄状の被覆構造とすること
ができ、従ってその後の複雑な曲げ加工時にあっても作
業性を良好となし、また飛び石等の外部衝撃に対する保
護性と耐食性とを同時に満足することができ、更に眉間
相互の充分な密着性によって曲げ部分及び端管部での剥
離の憂いがなく構成することとなる。[Function] Since the present invention is configured as described above, the film formed by sol lining of vinyl chloride resin as the upper layer is mainly made of epoxy resin, acrylic resin, or nylon 12, which has good adhesion to the film. By heating at a low temperature after this deposition via a primer film made of copolymerized polyamide resin, it is extremely easy to polymerize on the surface of the metal piping material side with an intermediate layer, so that it is possible to form an adhesion consisting of a fault-like structure. The polymerized structure allows the overall coating to be made into a generally thin coating structure, which provides good workability even during subsequent complicated bending processes, and provides protection against external impacts such as flying stones and corrosion resistance. This can be satisfied at the same time, and furthermore, due to the sufficient adhesion between the eyebrows, there is no fear of peeling at the bent portions and end tube portions.
［実施例］
以下、本発明の実施例を図面に基づいて説明すれば、第
１図は本発明の被覆金属配管材の平面図、第２図は第１
図Ａ−Ａ線の切欠きによる一部の拡大断面図であって、
（１）は管径２０ｍ／ｍ程度以下の比較的細径からなる
通常の一重或いは造管上その周面に銅の鍍金膜を有する
二重巻の金属配管材である。そしてその外側周面にクロ
メート被膜（２゛）を形成した亜夕（）鍍金層（２）を
下層として有し、且つ該クロメート被膜上にプライマー
被Ｍ（３）を介在するか（第２図）、或いは介在するこ
となしに中間層として１〜１０μｍの厚さの弗素樹脂層
（４）を有してなるものである。そして該弗素樹脂層の
表面にエポキシ樹脂、アクリル樹脂或いはナイロン１２
を主体とする共重合ポリアミド系樹脂によるプライマー
被ｐＡ（４“）を敷設した状態で、塩化ビニル樹脂のゾ
ルライニングによるゲル化した被膜（５）を上層として
被着し、全体を低温加熱に伴い断層状に重合して構成す
るものである。該被膜（５）は配管材（１）を回転させ
ながら且つ予熱しながら、１ｏｏｏ〜５０００ｃｏの粘
度のゾル槽に浸漬するか、或いはエアーレススプレーで
塗布し、１７０〜３００℃の雰囲気で数十秒乃至数分間
焼付けて形成する。[Example] Hereinafter, examples of the present invention will be described based on the drawings. Fig. 1 is a plan view of the coated metal piping material of the present invention, and Fig.
It is a partially enlarged cross-sectional view taken along the line A-A in FIG.
(1) is a normal single-walled or double-wound metal piping material having a relatively small diameter of about 20 m/m or less, or a double-wound metal piping material having a copper plating film on the circumferential surface of the pipe. It has a chromate coating (2) on its outer peripheral surface as a lower layer, and a primer coating M (3) is interposed on the chromate coating (Fig. 2). ), or it has a fluororesin layer (4) with a thickness of 1 to 10 μm as an intermediate layer without any intervening layer. Then, epoxy resin, acrylic resin, or nylon 12 is applied to the surface of the fluororesin layer.
With the primer coating pA (4") made of a copolymerized polyamide resin mainly composed of The coating (5) is formed by polymerizing in a cross-sectional shape.The coating (5) is formed by immersing the piping material (1) in a sol bath with a viscosity of 100 to 5000 co, while rotating and preheating it, or by airless spraying. It is formed by applying the coating and baking it in an atmosphere of 170 to 300°C for several tens of seconds to several minutes.
［発明の効果］
以上説明したように本発明による被覆金属配管材は、特
にエポキシ樹脂、アクリル樹脂或いはナイロン１２を主
体とする共重合ポリアミド系樹脂によるプライマー被Ｍ
（４“）を敷設した弗素樹脂層（４）からなる中間層を
有して上層としての前記塩化ビニル樹脂のゾルライニン
グによるゲル化した被膜（５）を密着性の良好なプライ
マー被膜（４°）を介して被着重合して構成するため、
断層状からなる被着重合された構造により、全体を概し
て薄状の被覆構造となすことができ、従ってその後の製
品としての複雑な曲げ加工時にあっても作業性を良好と
なし、また自動車等の走行中での飛び石対策として外部
衝撃に対しての保護性と耐食性とを同時に満足すること
ができ、更に眉間相互の充分な密着性によって曲げ部分
及び端管部での剥離の憂いがなく、従って雨水、洗車水
等の侵入を防止し、且つ概して安価に被覆形成すること
ができると共に被覆外面が平滑である等、極めて有用な
被覆金属配管材である。[Effects of the Invention] As explained above, the coated metal piping material according to the present invention can be coated with a primer using an epoxy resin, an acrylic resin, or a copolyamide resin mainly composed of nylon 12.
It has an intermediate layer consisting of a fluororesin layer (4) on which (4") is laid, and a gelled coating (5) formed by sol lining of the vinyl chloride resin as an upper layer, and a primer coating (4") with good adhesion. ), it is formed by adhesion polymerization.
Due to the layered and polymerized structure consisting of fault-like structures, the entire structure can be formed into a generally thin covering structure, which provides good workability even during complex bending processes for subsequent products, and is suitable for use in automobiles, etc. As a countermeasure against flying stones while driving, it can simultaneously satisfy protection against external impact and corrosion resistance, and also has sufficient adhesion between the eyebrows, so there is no fear of peeling at bent parts or end pipe parts. Therefore, it is an extremely useful coated metal piping material that prevents the intrusion of rainwater, car wash water, etc., can be coated at low cost, and has a smooth outer surface.
第１図は本発明の一実施例を示す被覆金属配管材の平面
図、第２図は第１図Ａ−Ａ線の切欠きに山る一部の拡大
断面図、第３図は従来例を示す切欠きによる一部の拡大
断面図である。Fig. 1 is a plan view of a coated metal piping material showing an embodiment of the present invention, Fig. 2 is an enlarged cross-sectional view of a part of the notch taken along line A-A in Fig. 1, and Fig. 3 is a conventional example. FIG.
Claims (2)
クロメート被膜（２’）を形成した亜鉛鍍金層（２）を
下層とし、且つ該クロメート被膜上に弗素樹脂層（４）
を中間層として有し、更に該弗素樹脂層の表面にエポキ
シ樹脂、アクリル樹脂或いはナイロン１２を主体とする
共重合ポリアミド系樹脂によるプライマー被膜（４’）
を敷設して塩化ビニル樹脂のゾルライニングによるゲル
化した被膜（５）を上層として被着重合して構成したこ
とを特徴とする被覆金属配管材。(1) On the outer peripheral surface of the piping material (1), which has a relatively small diameter,
A zinc plating layer (2) on which a chromate film (2') is formed is the lower layer, and a fluororesin layer (4) is formed on the chromate film.
as an intermediate layer, and further a primer coating (4') made of epoxy resin, acrylic resin, or copolyamide resin mainly composed of nylon 12 on the surface of the fluororesin layer.
1. A coated metal piping material characterized in that it is constructed by depositing and polymerizing a gelled coating (5) formed by sol lining of vinyl chloride resin as an upper layer.
上に更にプライマー（３）を介在して弗素樹脂層（４）
を形成したことを特徴とする被覆金属配管材。(2) In claim 1, the chromate coating (2')
A fluororesin layer (4) is further interposed on top with a primer (3).
A coated metal piping material characterized by forming.
Priority Applications (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63212255A JPH0260739A (en) | 1988-08-26 | 1988-08-26 | Coated metal piping material |
| GB8919365A GB2223188B (en) | 1988-08-26 | 1989-08-25 | Coated metal pipe and method for manufacturing the same |
| DE3928269A DE3928269A1 (en) | 1988-08-26 | 1989-08-26 | COATED METAL PIPE AND METHOD FOR THE PRODUCTION THEREOF |
| KR1019890012249A KR920001038B1 (en) | 1988-08-26 | 1989-08-26 | A coated metal pipe |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63212255A JPH0260739A (en) | 1988-08-26 | 1988-08-26 | Coated metal piping material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0260739A true JPH0260739A (en) | 1990-03-01 |
Family
ID=16619544
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63212255A Pending JPH0260739A (en) | 1988-08-26 | 1988-08-26 | Coated metal piping material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0260739A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102410408A (en) * | 2011-07-26 | 2012-04-11 | 广东联塑科技实业有限公司 | Production process of plastic coated pipe fitting without secondary tapping |
| CN112113238A (en) * | 2020-09-28 | 2020-12-22 | 台州市德长环保有限公司 | Fluorine lining pipe flue gas heating system |
| CN115889139A (en) * | 2022-11-18 | 2023-04-04 | 陕西华燕航空仪表有限公司 | Surface composite coating for improving humidity resistance, heat resistance and corrosion resistance of magnesium alloy |
-
1988
- 1988-08-26 JP JP63212255A patent/JPH0260739A/en active Pending
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102410408A (en) * | 2011-07-26 | 2012-04-11 | 广东联塑科技实业有限公司 | Production process of plastic coated pipe fitting without secondary tapping |
| CN112113238A (en) * | 2020-09-28 | 2020-12-22 | 台州市德长环保有限公司 | Fluorine lining pipe flue gas heating system |
| CN112113238B (en) * | 2020-09-28 | 2023-02-07 | 台州市德长环保有限公司 | Fluorine lining pipe flue gas heating system |
| CN115889139A (en) * | 2022-11-18 | 2023-04-04 | 陕西华燕航空仪表有限公司 | Surface composite coating for improving humidity resistance, heat resistance and corrosion resistance of magnesium alloy |
| CN115889139B (en) * | 2022-11-18 | 2024-03-19 | 陕西华燕航空仪表有限公司 | Surface composite coating for improving humidity and heat resistance and corrosion resistance of magnesium alloy |
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