JPH0258616B2 - - Google Patents
Info
- Publication number
- JPH0258616B2 JPH0258616B2 JP16121081A JP16121081A JPH0258616B2 JP H0258616 B2 JPH0258616 B2 JP H0258616B2 JP 16121081 A JP16121081 A JP 16121081A JP 16121081 A JP16121081 A JP 16121081A JP H0258616 B2 JPH0258616 B2 JP H0258616B2
- Authority
- JP
- Japan
- Prior art keywords
- diazo
- copying material
- formula
- photosensitive layer
- photosensitive
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 125000000664 diazo group Chemical group [N-]=[N+]=[*] 0.000 claims description 36
- 239000000463 material Substances 0.000 claims description 34
- 239000004094 surface-active agent Substances 0.000 claims description 16
- 150000008049 diazo compounds Chemical class 0.000 claims description 8
- 230000008878 coupling Effects 0.000 claims description 5
- 238000010168 coupling process Methods 0.000 claims description 5
- 238000005859 coupling reaction Methods 0.000 claims description 5
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 claims description 4
- -1 ethyl phenyl group Chemical group 0.000 claims description 4
- 125000005504 styryl group Chemical group 0.000 claims description 2
- 239000007788 liquid Substances 0.000 description 13
- 239000000047 product Substances 0.000 description 11
- 238000000034 method Methods 0.000 description 8
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 7
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 150000001875 compounds Chemical class 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 5
- 239000001397 quillaja saponaria molina bark Substances 0.000 description 4
- 229930182490 saponin Natural products 0.000 description 4
- 150000007949 saponins Chemical class 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 3
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 3
- JIAARYAFYJHUJI-UHFFFAOYSA-L Zinc chloride Inorganic materials [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- 239000012670 alkaline solution Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000035515 penetration Effects 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 235000005811 Viola adunca Nutrition 0.000 description 2
- 240000009038 Viola odorata Species 0.000 description 2
- 235000013487 Viola odorata Nutrition 0.000 description 2
- 235000002254 Viola papilionacea Nutrition 0.000 description 2
- YKYOUMDCQGMQQO-UHFFFAOYSA-L cadmium dichloride Chemical class Cl[Cd]Cl YKYOUMDCQGMQQO-UHFFFAOYSA-L 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- BDAGIHXWWSANSR-UHFFFAOYSA-N methanoic acid Natural products OC=O BDAGIHXWWSANSR-UHFFFAOYSA-N 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- UMGDCJDMYOKAJW-UHFFFAOYSA-N thiourea Chemical compound NC(N)=S UMGDCJDMYOKAJW-UHFFFAOYSA-N 0.000 description 2
- 239000011592 zinc chloride Substances 0.000 description 2
- 235000005074 zinc chloride Nutrition 0.000 description 2
- YYZRXNIZXRJETP-UHFFFAOYSA-N (4e)-4-diazo-n-phenylcyclohexa-1,5-dien-1-amine Chemical compound C1=CC(=[N+]=[N-])CC=C1NC1=CC=CC=C1 YYZRXNIZXRJETP-UHFFFAOYSA-N 0.000 description 1
- QZYDOKBVZJLQCK-UHFFFAOYSA-N 1,2-diethoxybenzene Chemical compound CCOC1=CC=CC=C1OCC QZYDOKBVZJLQCK-UHFFFAOYSA-N 0.000 description 1
- KJCVRFUGPWSIIH-UHFFFAOYSA-N 1-naphthol Chemical compound C1=CC=C2C(O)=CC=CC2=C1 KJCVRFUGPWSIIH-UHFFFAOYSA-N 0.000 description 1
- JXVVASBGLGTWLD-UHFFFAOYSA-N 1h-naphthalene-2,2-diol Chemical compound C1=CC=C2C=CC(O)(O)CC2=C1 JXVVASBGLGTWLD-UHFFFAOYSA-N 0.000 description 1
- RIQXULCAEXVXDY-UHFFFAOYSA-N 2,5-dimethyl-4-(morpholin-4-ylmethyl)phenol Chemical compound C1=C(O)C(C)=CC(CN2CCOCC2)=C1C RIQXULCAEXVXDY-UHFFFAOYSA-N 0.000 description 1
- VUQBXYKVVBQMIS-UHFFFAOYSA-N 2-(2-amino-6-diazo-3-ethylcyclohexa-2,4-dien-1-yl)ethanol Chemical compound CCC1=C(N)C(CCO)C(=[N+]=[N-])C=C1 VUQBXYKVVBQMIS-UHFFFAOYSA-N 0.000 description 1
- NYOBKJAAQPNEJU-UHFFFAOYSA-N 2-hydroxy-n-(3-morpholin-4-ylpropyl)naphthalene-1-carboxamide Chemical compound OC1=CC=C2C=CC=CC2=C1C(=O)NCCCN1CCOCC1 NYOBKJAAQPNEJU-UHFFFAOYSA-N 0.000 description 1
- UPHOPMSGKZNELG-UHFFFAOYSA-N 2-hydroxynaphthalene-1-carboxylic acid Chemical compound C1=CC=C2C(C(=O)O)=C(O)C=CC2=C1 UPHOPMSGKZNELG-UHFFFAOYSA-N 0.000 description 1
- PDWBGRKARJFJGI-UHFFFAOYSA-N 2-phenylcyclohexa-2,4-dien-1-one Chemical group O=C1CC=CC=C1C1=CC=CC=C1 PDWBGRKARJFJGI-UHFFFAOYSA-N 0.000 description 1
- WZCUTQZDUZZQSZ-UHFFFAOYSA-N 3,6-dihydroxynaphthalene-2,7-disulfonic acid;sodium Chemical compound [Na].OC1=C(S(O)(=O)=O)C=C2C=C(S(O)(=O)=O)C(O)=CC2=C1 WZCUTQZDUZZQSZ-UHFFFAOYSA-N 0.000 description 1
- FBLAHUMENIHUGG-UHFFFAOYSA-N 3-hydroxy-n-(2-methylphenyl)naphthalene-2-carboxamide Chemical compound CC1=CC=CC=C1NC(=O)C1=CC2=CC=CC=C2C=C1O FBLAHUMENIHUGG-UHFFFAOYSA-N 0.000 description 1
- JFGQHAHJWJBOPD-UHFFFAOYSA-N 3-hydroxy-n-phenylnaphthalene-2-carboxamide Chemical compound OC1=CC2=CC=CC=C2C=C1C(=O)NC1=CC=CC=C1 JFGQHAHJWJBOPD-UHFFFAOYSA-N 0.000 description 1
- VVKHPAIJUBQTMQ-UHFFFAOYSA-N 4-(2,5-dibutoxy-4-diazocyclohexa-1,5-dien-1-yl)morpholine Chemical compound C1=C(OCCCC)C(=[N+]=[N-])CC(OCCCC)=C1N1CCOCC1 VVKHPAIJUBQTMQ-UHFFFAOYSA-N 0.000 description 1
- OSWFIVFLDKOXQC-UHFFFAOYSA-N 4-(3-methoxyphenyl)aniline Chemical compound COC1=CC=CC(C=2C=CC(N)=CC=2)=C1 OSWFIVFLDKOXQC-UHFFFAOYSA-N 0.000 description 1
- LRUJNDUWNJTRHJ-UHFFFAOYSA-N 4-(4-diazo-2,5-diethoxycyclohexa-1,5-dien-1-yl)morpholine Chemical compound C1=C(OCC)C(=[N+]=[N-])CC(OCC)=C1N1CCOCC1 LRUJNDUWNJTRHJ-UHFFFAOYSA-N 0.000 description 1
- SCETWWDGKCBPMK-UHFFFAOYSA-N 4-[(4e)-4-diazocyclohexa-1,5-dien-1-yl]morpholine Chemical compound C1=CC(=[N+]=[N-])CC=C1N1CCOCC1 SCETWWDGKCBPMK-UHFFFAOYSA-N 0.000 description 1
- DLSNCHUXYGNZER-UHFFFAOYSA-N 4-amino-2-hydroxy-3h-naphthalene-2,7-disulfonamide Chemical compound C1=CC(S(N)(=O)=O)=CC2=CC(O)(S(N)(=O)=O)CC(N)=C21 DLSNCHUXYGNZER-UHFFFAOYSA-N 0.000 description 1
- XEGBZEMQPQFNIB-UHFFFAOYSA-N 4-diazo-n,n,2-trimethylcyclohexa-1,5-dien-1-amine Chemical compound CN(C)C1=C(C)CC(=[N+]=[N-])C=C1 XEGBZEMQPQFNIB-UHFFFAOYSA-N 0.000 description 1
- OAWPLNZPUZMDMF-UHFFFAOYSA-N 4-diazo-n,n-diethyl-3-methoxycyclohexa-1,5-dien-1-amine Chemical compound CCN(CC)C1=CC(OC)C(=[N+]=[N-])C=C1 OAWPLNZPUZMDMF-UHFFFAOYSA-N 0.000 description 1
- YZYFPMLAGIGAJJ-UHFFFAOYSA-N 4-diazo-n,n-diethylcyclohexa-1,5-dien-1-amine Chemical compound CCN(CC)C1=CCC(=[N+]=[N-])C=C1 YZYFPMLAGIGAJJ-UHFFFAOYSA-N 0.000 description 1
- LAXPFHMCFLHGKK-UHFFFAOYSA-N 4-diazo-n,n-dimethylcyclohexa-1,5-dien-1-amine Chemical compound CN(C)C1=CCC(=[N+]=[N-])C=C1 LAXPFHMCFLHGKK-UHFFFAOYSA-N 0.000 description 1
- NFHQANYCNWIDTL-UHFFFAOYSA-N 4-diazo-n,n-dipropylcyclohexa-1,5-dien-1-amine Chemical compound CCCN(CCC)C1=CCC(=[N+]=[N-])C=C1 NFHQANYCNWIDTL-UHFFFAOYSA-N 0.000 description 1
- HGWQOFDAUWCQDA-UHFFFAOYSA-N 4-hydroxynaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(O)=CC=C(S(O)(=O)=O)C2=C1 HGWQOFDAUWCQDA-UHFFFAOYSA-N 0.000 description 1
- PHRJWAAKLWPGSJ-UHFFFAOYSA-N 5-diazo-1,4-diethoxy-2-(2-methylphenyl)sulfanylcyclohexa-1,3-diene Chemical compound C1=C(OCC)C(=[N+]=[N-])CC(OCC)=C1SC1=CC=CC=C1C PHRJWAAKLWPGSJ-UHFFFAOYSA-N 0.000 description 1
- NGKOWLBJHKIGHP-UHFFFAOYSA-N 6-diazo-3-(dimethylamino)cyclohexa-2,4-diene-1-carboxylic acid Chemical compound CN(C)C1=CC(C(O)=O)C(=[N+]=[N-])C=C1 NGKOWLBJHKIGHP-UHFFFAOYSA-N 0.000 description 1
- 229940123208 Biguanide Drugs 0.000 description 1
- 229920002261 Corn starch Polymers 0.000 description 1
- FEWJPZIEWOKRBE-JCYAYHJZSA-N Dextrotartaric acid Chemical compound OC(=O)[C@H](O)[C@@H](O)C(O)=O FEWJPZIEWOKRBE-JCYAYHJZSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 240000006394 Sorghum bicolor Species 0.000 description 1
- FEWJPZIEWOKRBE-UHFFFAOYSA-N Tartaric acid Natural products [H+].[H+].[O-]C(=O)C(O)C(O)C([O-])=O FEWJPZIEWOKRBE-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- HTKFORQRBXIQHD-UHFFFAOYSA-N allylthiourea Chemical compound NC(=S)NCC=C HTKFORQRBXIQHD-UHFFFAOYSA-N 0.000 description 1
- 229960001748 allylthiourea Drugs 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000000987 azo dye Substances 0.000 description 1
- KCXMKQUNVWSEMD-UHFFFAOYSA-N benzyl chloride Chemical compound ClCC1=CC=CC=C1 KCXMKQUNVWSEMD-UHFFFAOYSA-N 0.000 description 1
- 229940073608 benzyl chloride Drugs 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 239000007795 chemical reaction product Substances 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- 235000015165 citric acid Nutrition 0.000 description 1
- 239000008119 colloidal silica Substances 0.000 description 1
- 239000008120 corn starch Substances 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 239000012954 diazonium Substances 0.000 description 1
- 150000001989 diazonium salts Chemical class 0.000 description 1
- 238000002845 discoloration Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000005562 fading Methods 0.000 description 1
- 235000019253 formic acid Nutrition 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229910001629 magnesium chloride Inorganic materials 0.000 description 1
- 239000010446 mirabilite Substances 0.000 description 1
- WIJIGKKVWSUYKJ-UHFFFAOYSA-N n,n-dibenzyl-4-diazocyclohexa-1,5-dien-1-amine Chemical compound C1=CC(=[N+]=[N-])CC=C1N(CC=1C=CC=CC=1)CC1=CC=CC=C1 WIJIGKKVWSUYKJ-UHFFFAOYSA-N 0.000 description 1
- URKUPUNPRLYTAP-UHFFFAOYSA-N n-(4-diazo-2,5-diethoxycyclohexa-1,5-dien-1-yl)benzamide Chemical compound C1=C(OCC)C(=[N+]=[N-])CC(OCC)=C1NC(=O)C1=CC=CC=C1 URKUPUNPRLYTAP-UHFFFAOYSA-N 0.000 description 1
- AWBOTUBOLPUEJY-UHFFFAOYSA-N n-(8-hydroxy-3,6-disulfamoylnaphthalen-1-yl)benzamide Chemical compound C=1C(S(N)(=O)=O)=CC2=CC(S(=O)(=O)N)=CC(O)=C2C=1NC(=O)C1=CC=CC=C1 AWBOTUBOLPUEJY-UHFFFAOYSA-N 0.000 description 1
- XGHSCBCFEWUDQG-UHFFFAOYSA-N n-[(4-diazo-1-methylcyclohexa-2,5-dien-1-yl)methyl]aniline Chemical compound C=1C=CC=CC=1NCC1(C)C=CC(=[N+]=[N-])C=C1 XGHSCBCFEWUDQG-UHFFFAOYSA-N 0.000 description 1
- HWGRZRAZHOLSGU-UHFFFAOYSA-N n-[3-(dimethylamino)propyl]-2-hydroxynaphthalene-1-carboxamide;hydrochloride Chemical compound Cl.C1=CC=C2C(C(=O)NCCCN(C)C)=C(O)C=CC2=C1 HWGRZRAZHOLSGU-UHFFFAOYSA-N 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- QCDYQQDYXPDABM-UHFFFAOYSA-N phloroglucinol Chemical compound OC1=CC(O)=CC(O)=C1 QCDYQQDYXPDABM-UHFFFAOYSA-N 0.000 description 1
- 229960001553 phloroglucinol Drugs 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- GHMLBKRAJCXXBS-UHFFFAOYSA-N resorcinol Chemical compound OC1=CC=CC(O)=C1 GHMLBKRAJCXXBS-UHFFFAOYSA-N 0.000 description 1
- 229960001755 resorcinol Drugs 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- RSIJVJUOQBWMIM-UHFFFAOYSA-L sodium sulfate decahydrate Chemical compound O.O.O.O.O.O.O.O.O.O.[Na+].[Na+].[O-]S([O-])(=O)=O RSIJVJUOQBWMIM-UHFFFAOYSA-L 0.000 description 1
- KVEHFWZHTQMSDQ-UHFFFAOYSA-M sodium;1,6-dihydroxynaphthalene-2-sulfonate Chemical compound [Na+].OC1=C(S([O-])(=O)=O)C=CC2=CC(O)=CC=C21 KVEHFWZHTQMSDQ-UHFFFAOYSA-M 0.000 description 1
- PNGLEYLFMHGIQO-UHFFFAOYSA-M sodium;3-(n-ethyl-3-methoxyanilino)-2-hydroxypropane-1-sulfonate;dihydrate Chemical class O.O.[Na+].[O-]S(=O)(=O)CC(O)CN(CC)C1=CC=CC(OC)=C1 PNGLEYLFMHGIQO-UHFFFAOYSA-M 0.000 description 1
- IAAKNVCARVEIFS-UHFFFAOYSA-M sodium;4-hydroxynaphthalene-1-sulfonate Chemical compound [Na+].C1=CC=C2C(O)=CC=C(S([O-])(=O)=O)C2=C1 IAAKNVCARVEIFS-UHFFFAOYSA-M 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 238000010189 synthetic method Methods 0.000 description 1
- 239000011975 tartaric acid Substances 0.000 description 1
- 235000002906 tartaric acid Nutrition 0.000 description 1
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical class Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 1
- RHZZVWTVJHZKAH-UHFFFAOYSA-K trisodium;naphthalene-1,2,3-trisulfonate Chemical compound [Na+].[Na+].[Na+].C1=CC=C2C(S([O-])(=O)=O)=C(S([O-])(=O)=O)C(S(=O)(=O)[O-])=CC2=C1 RHZZVWTVJHZKAH-UHFFFAOYSA-K 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/52—Compositions containing diazo compounds as photosensitive substances
- G03C1/61—Compositions containing diazo compounds as photosensitive substances with non-macromolecular additives
Description
本発明はジアゾ複写材料に関し、詳しくはジア
ゾ感光層に特定の界面活性剤が塗工性向上剤とし
て添加されている一成分型あるいは二成分型のジ
アゾ複写材料に関する。
従来より、ジアゾ複写材料はその製造上、支持
体又はプレコート層への感光液（水性）を塗布す
るに際しては、支持体等への濡れをよくし均一塗
工が行なえるようにするために塗工性向上剤とし
てサポニン（天然高分子界面活性物質）およびプ
ロピルアルコールのごとき低級アルコールを少量
感光液に添加している。これらの物質を添加しな
かつた場合には、感光液の支持体等へののりが思
わしくなく感光液がアバタ状、帯状などとなつて
付着しその状態で感光層が形成されるので商品価
値を失なわしめる。
しかしながら、ここで使用されているサポニン
は非常に高価な薬品であり、また低級アルコール
の感光液への添加はジアゾ複写材料の製造におい
て臭気が強まつたり安全性の面でも問題がある。
そうしたことから、安価な合成界面活性剤の配
合によつて感光液の塗工性の向上を得ようとする
検討が行なわれてきたが、一般の合成界面活性剤
の使用では浸透力が強すぎて支持体等への感光液
の浸透が大きくなり、裏抜け（感光液が支持体の
裏面側にまで浸み込んでしまう現象）や、地合の
劣化（感光液の支持体等への浸透が不均一なため
感光層の厚さが不均一となつて、その結果画像の
均一性が劣化する現象）が生じるといつた不都合
が見受けられる。
本発明者らは、数多くの界面活性剤についての
検討、研究を重ねた結果、下記一般式
RO（C2H4O）oＨ
〔但し、Ｒは
The present invention relates to a diazo copying material, and more particularly to a one-component type or two-component type diazo copying material in which a specific surfactant is added to the diazo photosensitive layer as a coatability improver. Conventionally, during the manufacture of diazo copying materials, when applying a photosensitive liquid (aqueous) to the support or precoat layer, coating is carried out to improve wetting of the support and to ensure uniform coating. Small amounts of saponin (a natural polymeric surfactant) and lower alcohols such as propyl alcohol are added to the photosensitive solution as processing improvers. If these substances are not added, the photosensitive liquid will not adhere properly to the support, etc., and the photosensitive liquid will adhere in the form of avatars or bands, and the photosensitive layer will be formed in this state, reducing the commercial value. make you lose it. However, the saponin used here is a very expensive chemical, and the addition of lower alcohols to the photosensitive solution increases the odor in the production of diazo copying materials and poses safety problems. For this reason, studies have been conducted to improve the coating properties of photosensitive liquids by incorporating inexpensive synthetic surfactants, but the use of general synthetic surfactants has too strong penetrating power. This increases the penetration of the photosensitive liquid into the support, etc., resulting in strike-through (a phenomenon in which the photosensitive liquid penetrates to the back side of the support) and deterioration of the formation (the penetration of the photosensitive liquid into the support, etc.). Due to the non-uniformity of the photosensitive layer, the thickness of the photosensitive layer becomes non-uniform, resulting in a phenomenon in which the uniformity of the image deteriorates. As a result of repeated studies and studies on numerous surfactants, the present inventors found the following general formula: RO(C 2 H 4 O) o H [However, R is
【式】又は[Formula] or
【式】
（式中、Ｘはベンジル基又はエチルフエニル基を
表わし、ｍは１〜５の整数である。）
あるいは[Formula] (In the formula, X represents a benzyl group or an ethyl phenyl group, and m is an integer from 1 to 5.) or
【式】又は[Formula] or
【式】
（式中、Ｙはベンジル基又はスチリル基を表わ
し、ｐおよびｑは０〜５の整数でｐ＋ｑ＝１〜５
である。）を表わし、ｎは１〜100好ましくは10〜
30の整数である。〕
で示された特定の界面活性剤が、ジアゾ感光液に
おけるサポニンや低級アルコールに充分代替可能
な塗工性向上剤となり得ることを確めた。本発明
はかかる知見に基づいて完成されたものである。
しかして、本発明の目的は、さきに記載したよう
な問題点や不都合のないジアゾ複写材料を提供す
ることにある。
即ち本発明は一成分型又は二成分型ジアゾ複写
材料において、感光層に上記一般式で表わされた
化合物の少なくとも１種が含有されていることを
特徴としている。
以下に本発明をさらに詳細に説明すると、本発
明に係るジアゾ複写材料は特定な界面活性剤（前
記一般式で表わされた化合物）を感光液における
塗工性向上剤として使用するものであるが、それ
自体は公知物質であり、市販品により或いは通常
知られている合成法により容易に入手することが
できる。その合成法の一例としてはフエノール、
ナフトール、モノオキシビフエニル、モノオキシ
フエニルシクロヘキシルなどに公知の方法で塩化
ベンジル又はスチレンを反応させ、その反応生成
物に更に公知の方法でエチレンオキサイドを反応
させる方法をあげることができる。ここで、前記
一般式で表わされる化合物の代表的なものとして
は
などがあげられる。
ジアゾ感光層は、本発明複写材料が一成分型の
ものであればジアゾ化合物（ジアゾニウム塩）を
含むがカツプリング成分を含まず、また二成分型
のものであればジアゾ化合物及びカツプリング成
分を含むもので形成される。この感光層における
ジアゾ化合物、カツプリング成分はいずれも公知
のものが使用できる。ジアゾ化合物のいくつかの
具体例を示せば下記のとおりである。
４―ジアゾ―１―ジメチルアミノベンゼン、４
―ジアゾ―１―ジエチルアミノベンゼン、４―ジ
アゾ―１―ジプロピルアミノベンゼン、４―ジア
ゾ―１―メチルベンジルアミノベンゼン、４−ジ
アゾ−１−ジベンジルアミノベンゼン、４―ジア
ゾ―１―エチルヒドロキシエチルアミノベンゼ
ン、４―ジアゾ―１―ジエチルアミノ―３―メト
キシベンゼン、４―ジアゾ―１―ジメチルアミノ
―２―メチルベンゼン、４―ジアゾ―１―ベンゾ
イルアミノ―２，５―ジエトキシベンゼン、４―
ジアゾ―１―モルホリノベンゼン、４―ジアゾ―
１―モルホリノ―２，５―ジエトキシベンゼン、
４―ジアゾ―１―モルホリノ―２，５―ジブトキ
シベンゼン、４―ジアゾ―１―アニリノ―ベンゼ
ン、４―ジアゾ―１―ジメチルアミノ―３―カル
ボキシベンゼン、４―ジアゾ―１―トルイルメル
カプト―２，５―ジエトキシベンゼン、４―ジア
ゾ―１，４―メトキシベンゾイルアミノ―２，５
―ジエトキシベンゼンなどの塩化物の塩化亜鉛、
塩化カドミウムあるいは塩化すずの複塩など及び
硫酸、４―ふつ化硼素酸、ヘキサフロロリン酸の
酸塩などがあるが、無論これらに限定されるもの
ではない。
また、カツプリング成分（ジアゾ化合物とでア
ゾ染料画像を形成する）のいくつかの具体例を示
せば下記のとおりである。
レゾルシン、フロログルシン、２，５―ジメチ
ル―４―モルホリノメチルフエノール、３―ヒド
ロキシシアノアセトアニリド、パラスルホアセト
アニリド、１―ベンゾイルアミノ―８―ヒドロキ
シナフタレン―３，６―ジスルホンアミド、２，
２―ジヒドロキシナフタレン、２，７―ジヒドロ
キシナフタレン―３，６―ジスルホン酸ソーダ、
２，３―ジヒドロキシ―６―スルホン酸ソーダ、
２，５―ジヒドロキシナフタレン―６―スルホン
酸ソーダ、１―ヒドロキシナフタレン―４―スル
ホン酸ソーダ、１―アミノ―３―ヒドロキシナフ
タレン―３，６―ジスルホンアミド、ナフトール
AS、ナフトールAS―Ｄ、２―ヒドロキシナフタ
レン―３―ビグアナイド、２―ヒドロキシナフト
エ酸モルホリノプロピルアミド、２―ヒドロキシ
ナフトエ酸エタノールアミド、２―ヒドロキシナ
フトエ酸―Ｎ―ジメチルアミノプロピルアミド塩
酸塩、２，４，2′，4′―テトラヒドロキシジフエ
ニル、２，４，2′，4′―テトラヒドロキシジフエ
ニルスルホキシド等。
実際に本発明に係るジアゾ複写材料をつくるに
は、支持体（ジアゾ複写用原紙、樹脂フイルム、
布など）上に必要に応じて、多孔性微粉末（例え
ば粒径が１〜5μm程度のコーンスターチ、コロイ
ド状シリカなど）を結着樹脂中に分散した固形分
付着量が0.5〜3.0ｇ／m2程度のプレコート層が設
けられる。続いて、この支持体又はプレコート層
上に公知の手段によつて固形分付着量が0.3〜2.0
ｇ／m2程度の感光層（ジアゾ感光層）が設けられ
る。
このジアゾ感光層には感光紙（ジアゾ複写材
料）の安定性、保存性、画像色調の彩度向上、変
褪色の防止、コピーの鮮明度の改良などを意図と
して、例えばクエン酸、酒石酸、蓚酸、蟻酸、硼
酸、硫酸アルミニウム、芒硝、塩化亜鉛、塩化マ
グネシウム、尿素、チオ尿素、アリルチオ尿素、
ナフタリントリスルホン酸ソーダ、グリセリンな
どが添加されることが望ましい。また、通常の塗
工性向上剤（サポニン、低級アルコール等）の併
用も可能である。
このジアゾ複写材料の製造過程で注意されるべ
きことは、既述のように、感光液調製の際に塗工
性向上剤として前記一般式で表わされた界面活性
剤の少なくとも１種が添加されることである。そ
の場合、この特定の界面活性剤（塗工性向上剤）
の添加量は、ジアゾ化合物１モルに対して、0.01
〜１モルの範囲が適当である。添加量が0.01モル
より少ないと塗工性向上の効果に乏しく、また１
モルより以上だと得られたジアゾ複写材料の保存
性が劣化するようになる。なお、この塗工性向上
剤は感光液の塗布乾燥後においても、そのほとん
どが感光層中に存在する。
なお、支持体裏面にバツクコート層が設けられ
る場合には、その材料としてはこれも従来公知の
ものが適用可能である。
このようにして製造された本発明のジアゾ複写
材料は、一成分型又は二成分型のものであり、従
つて、アンモニアガスを使用した乾式現像法、ア
ルカリ性溶液あるいはカツプラーを含む中性乃至
アルカリ性溶液を使用した湿式現像法、アルカリ
性有機溶剤あるいはカツプラーを含む中性乃至ア
ルカリ性有機溶剤を使用した半乾式現像法（現像
液のジアゾ複写材料への塗布量が５ｇ／m2以下と
微量な現像法）、複写材料中にあらかじめ含有さ
せた加熱アルカリ発生物質を加熱により分解現像
する熱式現像法などにより顕像化される。
かかる本発明に係るジアゾ複写材料は、所期の
目的を充分達成できるものである。その理由は必
ずしも明確ではないが、前記一般式で表わされる
化合物は、表−１に示したように一般の界面活性
剤に比べ、その式中のＲが分子量的にも立体的に
もより大きいため、支持体等への浸透が少なくジ
アゾ複写材料に求められる界面活性効果を有する
ものと考えられる。[Formula] (wherein, Y represents a benzyl group or a styryl group, p and q are integers of 0 to 5, and p+q=1 to 5
It is. ), where n is 1 to 100, preferably 10 to
is an integer of 30. ] It was confirmed that the specific surfactant shown above can be a coating property improver that can sufficiently replace saponin and lower alcohol in diazo photosensitive solutions. The present invention was completed based on this knowledge.
It is therefore an object of the present invention to provide a diazo copying material which does not have the problems and disadvantages mentioned above. That is, the present invention is characterized in that a one-component or two-component diazo copying material contains at least one compound represented by the above general formula in the photosensitive layer. The present invention will be explained in more detail below. The diazo copying material according to the present invention uses a specific surfactant (a compound represented by the above general formula) as a coatability improver in a photosensitive liquid. However, it is itself a known substance and can be easily obtained as a commercially available product or by commonly known synthetic methods. An example of its synthesis method is phenol,
Examples include a method in which naphthol, monooxybiphenyl, monooxyphenylcyclohexyl, etc. are reacted with benzyl chloride or styrene by a known method, and the reaction product is further reacted with ethylene oxide by a known method. Here, typical compounds represented by the above general formula are: etc. The diazo photosensitive layer contains a diazo compound (diazonium salt) but not a coupling component if the copying material of the present invention is a one-component type, and contains a diazo compound and a coupling component if it is a two-component type. is formed. As the diazo compound and the coupling component in this photosensitive layer, known ones can be used. Some specific examples of diazo compounds are as follows. 4-Diazo-1-dimethylaminobenzene, 4
-Diazo-1-diethylaminobenzene, 4-diazo-1-dipropylaminobenzene, 4-diazo-1-methylbenzylaminobenzene, 4-diazo-1-dibenzylaminobenzene, 4-diazo-1-ethylhydroxyethyl Aminobenzene, 4-diazo-1-diethylamino-3-methoxybenzene, 4-diazo-1-dimethylamino-2-methylbenzene, 4-diazo-1-benzoylamino-2,5-diethoxybenzene, 4-
Diazo-1-morpholinobenzene, 4-diazo-
1-morpholino-2,5-diethoxybenzene,
4-Diazo-1-morpholino-2,5-dibutoxybenzene, 4-diazo-1-anilino-benzene, 4-diazo-1-dimethylamino-3-carboxybenzene, 4-diazo-1-tolylmercapto-2 ,5-diethoxybenzene, 4-diazo-1,4-methoxybenzoylamino-2,5
- Zinc chloride, chlorides such as diethoxybenzene,
Examples include double salts of cadmium chloride or tin chloride, and salts of sulfuric acid, 4-fluoroboric acid, and hexafluorophosphoric acid, but are not limited to these. Further, some specific examples of the coupling component (which forms an azo dye image with a diazo compound) are as follows. Resorcin, phloroglucin, 2,5-dimethyl-4-morpholinomethylphenol, 3-hydroxycyanoacetanilide, parasulfoacetanilide, 1-benzoylamino-8-hydroxynaphthalene-3,6-disulfonamide, 2,
2-dihydroxynaphthalene, 2,7-dihydroxynaphthalene-3,6-disulfonic acid sodium,
Sodium 2,3-dihydroxy-6-sulfonate,
Sodium 2,5-dihydroxynaphthalene-6-sulfonate, sodium 1-hydroxynaphthalene-4-sulfonate, 1-amino-3-hydroxynaphthalene-3,6-disulfonamide, naphthol
AS, naphthol AS-D, 2-hydroxynaphthalene-3-biguanide, 2-hydroxynaphthoic acid morpholinopropylamide, 2-hydroxynaphthoic acid ethanolamide, 2-hydroxynaphthoic acid-N-dimethylaminopropylamide hydrochloride, 2, 4,2',4'-tetrahydroxydiphenyl, 2,4,2',4'-tetrahydroxydiphenyl sulfoxide, etc. In order to actually produce the diazo copying material according to the present invention, supports (diazo copying base paper, resin film,
Porous fine powder (e.g. corn starch, colloidal silica, etc. with a particle size of about 1 to 5 μm) is dispersed in a binder resin as necessary on a cloth (cloth, etc.) with a solid content of 0.5 to 3.0 g/m Approximately 2 pre-coat layers are provided. Subsequently, on this support or precoat layer, a solid content coating amount of 0.3 to 2.0 is applied by known means.
A photosensitive layer (diazo photosensitive layer) of about g/m 2 is provided. This diazo photosensitive layer contains, for example, citric acid, tartaric acid, oxalic acid, etc., with the intention of improving the stability and preservability of photosensitive paper (diazo copying material), improving the saturation of image tone, preventing discoloration and fading, and improving the clarity of copies. , formic acid, boric acid, aluminum sulfate, Glauber's salt, zinc chloride, magnesium chloride, urea, thiourea, allylthiourea,
It is desirable to add sodium naphthalene trisulfonate, glycerin, etc. Further, it is also possible to use common coating property improvers (saponin, lower alcohols, etc.). What should be noted in the manufacturing process of this diazo copying material is that at least one surfactant represented by the above general formula is added as a coatability improver during the preparation of the photosensitive liquid. It is to be done. In that case, this specific surfactant (coatability improver)
The amount added is 0.01 per mole of diazo compound.
A range of 1 mol to 1 mol is suitable. If the amount added is less than 0.01 mol, the effect of improving coating properties will be poor, and
If the amount is more than molar, the storage stability of the obtained diazo copying material will deteriorate. It should be noted that most of this coatability improver remains in the photosensitive layer even after the photosensitive liquid has been applied and dried. In addition, when a back coat layer is provided on the back surface of the support, conventionally known materials can be used as the material for the back coat layer. The diazo copying material of the present invention produced in this way is of a one-component type or a two-component type, and therefore can be developed by a dry development method using ammonia gas, an alkaline solution, or a neutral to alkaline solution containing a coupler. A wet development method using an alkaline organic solvent or a semi-dry development method using a neutral or alkaline organic solvent containing a coupler (a development method in which the amount of developer applied to the diazo copying material is as small as 5 g/m 2 or less) The image is visualized by a thermal development method in which a heated alkali-generating substance previously contained in the copying material is decomposed and developed by heating. The diazo copying material according to the present invention can fully achieve the intended purpose. The reason for this is not necessarily clear, but as shown in Table 1, R in the formula is larger in both molecular weight and steric terms than in general surfactants. Therefore, it is thought that it has little penetration into the support etc. and has the surfactant effect required for diazo copying materials.
【表】
次に実施例を示す。なお、％は重量％である。
実施例 １
微粒子状シリカ（粒径１〜5μm）30ｇ及びポリ
酢酸ビニルエマルジヨン（固形分40％）80ｇを全
体が１になるように水分に分散したものを、ジ
アゾ複写用原紙（55Kg／連の上質紙）上にワイヤ
ーバーで塗布し、乾燥して約２ｇ／m2のプレコー
ト層を設けた。一方[Table] Examples are shown next. In addition, % is weight %. Example 1 30 g of fine particulate silica (particle size 1 to 5 μm) and 80 g of polyvinyl acetate emulsion (solid content 40%) were dispersed in water so that the total weight was 1, and then mixed with diazo copying base paper (55 kg/ream). (high-quality paper) with a wire bar and dried to provide a precoat layer of approximately 2 g/m 2 . on the other hand
【表】【table】
【表】
の組成を全量が１になるように水に溶解乃至分
散して感光層形成液を調製し、これをプレコート
層上にワイヤーバーで塗布乾燥して約１ｇ／m2の
感光層を設けジアゾ複写材料（本発明品１）をつ
くつた。
この複写材料を適当な原図と重ねて露光し、ア
ンモニアガスで現像したところ、均一に発色した
地合もよい青色画像が得られた。
比較のために、上記感光層形成液中の化合物ａ
の代りに一般のノニオン系活性剤であるRO
（C2H4OH）oＨ（Ｒ＝ラウリル、ｎ＝平均14）３ｇ
を用いた以外は全く同様にしてジアゾ複写材料
（比較品１）をつくり、この複写材料を適当な原
図と重ねて露光しアンモニアガスで現像したとこ
ろ、浸み込み斑点の多い地合の悪い青色画像とな
つた。
また、さらに比較のために、上記感光層形成液
中の化合物ａを除去した以外は全く同様にしてジ
アゾ複写材料（比較品２）をつくり、この複写材
料を適当な原因と重ねて露光しアンモニアガスで
現像したところ、部分的に画像のない不均一な青
色画像となつた。
ここに、本発明品によれば、地合がよく均一に
発色した画像が得られることが確認された。
実施例 ２
実施例１におけるジアゾ複写材料（本発明品
１）を適当な原図と重ねて露光し、湿式現像複写
機でアルカリ水溶液を使用して現像したところ、
また半乾式現像複写機でアルカリ溶剤を使用して
現像したところ、ともに均一に発色した地合もよ
い青色画像が得られた。
実施例 ３A photosensitive layer forming solution was prepared by dissolving or dispersing the composition of [Table] in water so that the total amount was 1, and this was applied onto the precoat layer with a wire bar and dried to form a photosensitive layer of about 1 g/m 2 . A diazo copying material (invention product 1) was prepared. When this copying material was exposed to light over a suitable original image and developed with ammonia gas, a uniformly colored blue image with good texture was obtained. For comparison, compound a in the photosensitive layer forming solution
RO, which is a general nonionic activator, instead of
(C 2 H 4 OH) o H (R = lauryl, n = average 14) 3 g
A diazo copying material (comparative product 1) was made in exactly the same manner except that a diazo copying material (comparative product 1) was made, and when this copying material was overlapped with a suitable original image, exposed, and developed with ammonia gas, it turned out to be a blue color with poor texture and many spots. It became an image. For further comparison, a diazo copying material (comparative product 2) was prepared in exactly the same manner except that compound a in the photosensitive layer forming liquid was removed, and this copying material was exposed to light over a suitable source, and ammonia was removed. When developed with gas, the result was a non-uniform blue image with no image in some areas. Here, it was confirmed that according to the product of the present invention, images with good texture and uniform color development could be obtained. Example 2 The diazo copying material in Example 1 (invention product 1) was exposed to light over a suitable original image, and developed using an aqueous alkaline solution in a wet development copying machine.
When the images were developed using an alkaline solvent in a semi-dry developing copying machine, blue images with uniform color development and good texture were obtained. Example 3
【表】【table】
【表】
の組成を全量が１となるように水に分散乃至溶
解して感光層形成液を調製し、これをジアゾ複写
用原紙（55Kg／連の上質紙）上にワイヤーバーで
塗布し乾燥して、約1.1ｇ／m2の感光層を設けて
ジアゾ複写材料（本発明品２）をつくつた。この
ものは、アンモニアガスでの現像により均一に発
色した地合のよい青紫色画像が得られた。
実施例 ４Prepare a photosensitive layer forming liquid by dispersing or dissolving the composition of [Table] in water so that the total amount is 1, apply this onto diazo copying base paper (55 kg/ream of high-quality paper) with a wire bar, and dry. A diazo copying material (invention product 2) was prepared by providing a photosensitive layer of about 1.1 g/m 2 . When developed with ammonia gas, a uniformly colored blue-violet image with good texture was obtained. Example 4
【表】
の組成を全量が１となるように水に溶解乃至分
散して感光層形成液を調製し、これをジアゾ複写
用原紙（55Kg／連の上紙）上にワイヤーバーで塗
布し乾燥して、約0.5ｇ／m2の感光層を設けてジ
アゾ複写材料（本発明品３）をつくつた。
このジアゾ複写材料を適当な原図と重ねて露光
し、現像液（NW酸20ｇに水を加、全量を１と
したもの）で現像したところ、均一で地合のよい
紫色画像が得られた。
実施例 ５
実施例３で用いた界面活性剤１ｇの代りに下記
構造式
で表わされる界面活性剤１ｇを用いた以外は実施
例３とまつたく同様にしてジアゾ複写材料（本発
明品４）をつくつた。このものは、アンモニアガ
スでの現像により均一に発色した地合のよい青紫
色画像が得られた。
実施例 ６
実施例４で用いた界面活性剤１ｇの代りに下記
構造式
で表わされる界面活性剤１ｇを用いた以外は実施
例４とまつたく同様にしてジアゾ複写材料（本発
明品５）をつくつた。これを更に実施例４と同様
な操作で露光・現像に供したところ、均一で地合
のよい紫色画像が得られた。Prepare a photosensitive layer forming liquid by dissolving or dispersing the composition of [Table] in water so that the total amount is 1, apply this onto diazo copying base paper (top paper of 55 kg/ream) with a wire bar, and dry. A diazo copying material (invention product 3) was prepared by providing a photosensitive layer of about 0.5 g/m 2 . When this diazo copying material was exposed to light over a suitable original image and developed with a developer (20 g of NW acid added to water to make a total volume of 1), a uniform and well-formed purple image was obtained. Example 5 The following structural formula was used instead of 1 g of the surfactant used in Example 3. A diazo copying material (Product 4 of the present invention) was prepared in the same manner as in Example 3, except that 1 g of the surfactant represented by was used. When developed with ammonia gas, a uniformly colored blue-violet image with good texture was obtained. Example 6 The following structural formula was used instead of 1 g of surfactant used in Example 4. A diazo copying material (Product 5 of the present invention) was prepared in the same manner as in Example 4 except that 1 g of the surfactant represented by was used. When this was further subjected to exposure and development in the same manner as in Example 4, a uniform purple image with good texture was obtained.
Claims (1)
て、ジアゾ化合物を主成分とした或いはジアゾ化
合物及びカツプリング成分を主成分とした感光層
が設けられたジアゾ複写材料において、前記感光
層中に下記一般式で表わされる界面活性剤が含有
されていることを特徴とするジアゾ複写材料。 RO（C2H4O）oＨ 〔但し、Ｒは 【式】【式】 【式】又は 【式】 を表わし、Ｘはベンジル基又はエチルフエニル基
を表わし、ｍは１〜５の整数であり、Ｙはベンジ
ル基又はスチリル基を表わし、ｐおよびｑは０〜
５の整数でｐ＋ｑ＝１〜５であり、ｎは１〜100
の整数である。〕[Scope of Claims] 1. A diazo copying material in which a photosensitive layer containing a diazo compound as a main component or a diazo compound and a coupling component as a main component is provided on a support directly or via a precoat layer, A diazo copying material characterized in that a photosensitive layer contains a surfactant represented by the following general formula. RO(C 2 H 4 O) o H [However, R represents [Formula] [Formula] [Formula] or [Formula], X represents a benzyl group or an ethyl phenyl group, and m is an integer from 1 to 5. , Y represents a benzyl group or a styryl group, p and q are 0-
An integer of 5, p+q=1 to 5, and n is 1 to 100
is an integer. ]
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16121081A JPS5862638A (en) | 1981-10-09 | 1981-10-09 | Diazo copying material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP16121081A JPS5862638A (en) | 1981-10-09 | 1981-10-09 | Diazo copying material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS5862638A JPS5862638A (en) | 1983-04-14 |
| JPH0258616B2 true JPH0258616B2 (en) | 1990-12-10 |
Family
ID=15730692
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP16121081A Granted JPS5862638A (en) | 1981-10-09 | 1981-10-09 | Diazo copying material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS5862638A (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7485603B2 (en) | 2005-02-18 | 2009-02-03 | Infineum International Limited | Soot dispersants and lubricating oil compositions containing same |
-
1981
- 1981-10-09 JP JP16121081A patent/JPS5862638A/en active Granted
Also Published As
| Publication number | Publication date |
|---|---|
| JPS5862638A (en) | 1983-04-14 |
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