JPH025837A - Oil-in-polyhydric alcohol type solubilized composition - Google Patents
Oil-in-polyhydric alcohol type solubilized compositionInfo
- Publication number
- JPH025837A JPH025837A JP63151244A JP15124488A JPH025837A JP H025837 A JPH025837 A JP H025837A JP 63151244 A JP63151244 A JP 63151244A JP 15124488 A JP15124488 A JP 15124488A JP H025837 A JPH025837 A JP H025837A
- Authority
- JP
- Japan
- Prior art keywords
- oil
- polyhydric alcohol
- composition
- solubilized composition
- solubilized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 64
- 150000005846 sugar alcohols Polymers 0.000 title claims abstract description 41
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims abstract description 23
- 239000000787 lecithin Substances 0.000 claims abstract description 23
- 235000010445 lecithin Nutrition 0.000 claims abstract description 23
- 229940067606 lecithin Drugs 0.000 claims abstract description 23
- 102000004190 Enzymes Human genes 0.000 claims description 15
- 108090000790 Enzymes Proteins 0.000 claims description 15
- 239000012071 phase Substances 0.000 claims description 8
- 239000008346 aqueous phase Substances 0.000 claims description 3
- 239000004094 surface-active agent Substances 0.000 abstract description 18
- OENHQHLEOONYIE-UKMVMLAPSA-N all-trans beta-carotene Natural products CC=1CCCC(C)(C)C=1/C=C/C(/C)=C/C=C/C(/C)=C/C=C/C=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C OENHQHLEOONYIE-UKMVMLAPSA-N 0.000 abstract description 6
- TUPZEYHYWIEDIH-WAIFQNFQSA-N beta-carotene Natural products CC(=C/C=C/C=C(C)/C=C/C=C(C)/C=C/C1=C(C)CCCC1(C)C)C=CC=C(/C)C=CC2=CCCCC2(C)C TUPZEYHYWIEDIH-WAIFQNFQSA-N 0.000 abstract description 6
- 235000013734 beta-carotene Nutrition 0.000 abstract description 6
- 239000011648 beta-carotene Substances 0.000 abstract description 6
- 229960002747 betacarotene Drugs 0.000 abstract description 6
- OENHQHLEOONYIE-JLTXGRSLSA-N β-Carotene Chemical compound CC=1CCCC(C)(C)C=1\C=C\C(\C)=C\C=C\C(\C)=C\C=C\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C OENHQHLEOONYIE-JLTXGRSLSA-N 0.000 abstract description 6
- 235000013305 food Nutrition 0.000 abstract description 4
- FPIPGXGPPPQFEQ-OVSJKPMPSA-N all-trans-retinol Chemical compound OC\C=C(/C)\C=C\C=C(/C)\C=C\C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-OVSJKPMPSA-N 0.000 abstract description 3
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 abstract description 2
- ZIIUUSVHCHPIQD-UHFFFAOYSA-N 2,4,6-trimethyl-N-[3-(trifluoromethyl)phenyl]benzenesulfonamide Chemical compound CC1=CC(C)=CC(C)=C1S(=O)(=O)NC1=CC=CC(C(F)(F)F)=C1 ZIIUUSVHCHPIQD-UHFFFAOYSA-N 0.000 abstract description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 abstract description 2
- 102000015439 Phospholipases Human genes 0.000 abstract description 2
- 108010064785 Phospholipases Proteins 0.000 abstract description 2
- 239000008103 glucose Substances 0.000 abstract description 2
- FPIPGXGPPPQFEQ-BOOMUCAASA-N Vitamin A Natural products OC/C=C(/C)\C=C\C=C(\C)/C=C/C1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-BOOMUCAASA-N 0.000 abstract 1
- 239000005445 natural material Substances 0.000 abstract 1
- 235000019155 vitamin A Nutrition 0.000 abstract 1
- 239000011719 vitamin A Substances 0.000 abstract 1
- 229940045997 vitamin a Drugs 0.000 abstract 1
- 238000003756 stirring Methods 0.000 description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 18
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 11
- 235000019198 oils Nutrition 0.000 description 11
- 230000000052 comparative effect Effects 0.000 description 9
- 235000014113 dietary fatty acids Nutrition 0.000 description 9
- 239000000194 fatty acid Substances 0.000 description 9
- 229930195729 fatty acid Natural products 0.000 description 9
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 8
- -1 fatty acid esters Chemical class 0.000 description 8
- 239000000600 sorbitol Substances 0.000 description 8
- 239000000839 emulsion Substances 0.000 description 6
- CNNRPFQICPFDPO-UHFFFAOYSA-N octacosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCCCCCCCO CNNRPFQICPFDPO-UHFFFAOYSA-N 0.000 description 6
- 229930003799 tocopherol Natural products 0.000 description 5
- 239000011732 tocopherol Substances 0.000 description 5
- 229930003427 Vitamin E Natural products 0.000 description 4
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 4
- 235000010384 tocopherol Nutrition 0.000 description 4
- 229960001295 tocopherol Drugs 0.000 description 4
- 239000011709 vitamin E Substances 0.000 description 4
- 235000019165 vitamin E Nutrition 0.000 description 4
- 229940046009 vitamin E Drugs 0.000 description 4
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 4
- 229960002666 1-octacosanol Drugs 0.000 description 3
- 235000019501 Lemon oil Nutrition 0.000 description 3
- 229930006000 Sucrose Natural products 0.000 description 3
- 244000195452 Wasabia japonica Species 0.000 description 3
- 235000000760 Wasabia japonica Nutrition 0.000 description 3
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 239000010501 lemon oil Substances 0.000 description 3
- VQHSOMBJVWLPSR-WUJBLJFYSA-N maltitol Chemical compound OC[C@H](O)[C@@H](O)[C@@H]([C@H](O)CO)O[C@H]1O[C@H](CO)[C@@H](O)[C@H](O)[C@H]1O VQHSOMBJVWLPSR-WUJBLJFYSA-N 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 239000004006 olive oil Substances 0.000 description 3
- 235000008390 olive oil Nutrition 0.000 description 3
- 239000005720 sucrose Substances 0.000 description 3
- 239000000811 xylitol Substances 0.000 description 3
- 235000010447 xylitol Nutrition 0.000 description 3
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 3
- 229960002675 xylitol Drugs 0.000 description 3
- LDVVTQMJQSCDMK-UHFFFAOYSA-N 1,3-dihydroxypropan-2-yl formate Chemical compound OCC(CO)OC=O LDVVTQMJQSCDMK-UHFFFAOYSA-N 0.000 description 2
- 235000013351 cheese Nutrition 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- 238000000034 method Methods 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000007764 o/w emulsion Substances 0.000 description 2
- 150000003904 phospholipids Chemical class 0.000 description 2
- 239000008347 soybean phospholipid Substances 0.000 description 2
- JLPULHDHAOZNQI-ZTIMHPMXSA-N 1-hexadecanoyl-2-(9Z,12Z-octadecadienoyl)-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCC\C=C/C\C=C/CCCCC JLPULHDHAOZNQI-ZTIMHPMXSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- 240000004160 Capsicum annuum Species 0.000 description 1
- 235000008534 Capsicum annuum var annuum Nutrition 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 241000772415 Neovison vison Species 0.000 description 1
- 235000019502 Orange oil Nutrition 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930003316 Vitamin D Natural products 0.000 description 1
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 235000019169 all-trans-retinol Nutrition 0.000 description 1
- 239000011717 all-trans-retinol Substances 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- 239000001511 capsicum annuum Substances 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 230000002255 enzymatic effect Effects 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000000845 maltitol Substances 0.000 description 1
- 235000010449 maltitol Nutrition 0.000 description 1
- 229940035436 maltitol Drugs 0.000 description 1
- 229940057917 medium chain triglycerides Drugs 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000010502 orange oil Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000223 polyglycerol Polymers 0.000 description 1
- 239000000244 polyoxyethylene sorbitan monooleate Substances 0.000 description 1
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 1
- 229920000053 polysorbate 80 Polymers 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 229960003471 retinol Drugs 0.000 description 1
- 230000007928 solubilization Effects 0.000 description 1
- 238000005063 solubilization Methods 0.000 description 1
- 229940083466 soybean lecithin Drugs 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 235000019149 tocopherols Nutrition 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019166 vitamin D Nutrition 0.000 description 1
- 239000011710 vitamin D Substances 0.000 description 1
- 150000003710 vitamin D derivatives Chemical class 0.000 description 1
- 229940046008 vitamin d Drugs 0.000 description 1
- QUEDXNHFTDJVIY-UHFFFAOYSA-N γ-tocopherol Chemical class OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1 QUEDXNHFTDJVIY-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は、天然由来のリン脂質であるレシチンを界面活
性剤として、多価アルコール中に油相成分を溶解した多
価アルコール中油型可溶化組成物を調製し、食品分野へ
応用するものである。Detailed Description of the Invention (Field of Industrial Application) The present invention is an oil-in-polyhydric alcohol solubilization method in which an oil phase component is dissolved in a polyhydric alcohol using lecithin, which is a naturally derived phospholipid, as a surfactant. The composition is prepared and applied to the food field.
（従来の技術）
従来の多価アルコール中油型可溶化組成物は、食品分野
に使用認可されていない界面活性剤を用いたものが多く
、使用認可されているものでも、親水性ポリグリセリン
脂肪酸エステルによる方法（特開昭５６−３７０４０号
）やショ糖脂肪酸エステルによる方法（特公昭６０−２
５１８３号）など、合成品の界面活性剤が必須成分とさ
れていた。(Prior art) Conventional oil-in-polyhydric alcohol solubilized compositions often use surfactants that are not approved for use in the food field, and even those that are approved for use are hydrophilic polyglycerol fatty acid esters. (Japanese Patent Publication No. 56-37040) and method using sucrose fatty acid ester (Japanese Patent Publication No. 60-2
Synthetic surfactants such as No. 5183) were considered essential ingredients.
（発明が解決しようとする課題）
安定な多価アルコール中油型可溶化組成物を得るために
は、相当量の界面活性剤の使用が不可欠であるが、これ
までは化学合成品の高親水性界面活性剤を用いて研究が
すすめられてきた。このような界面活性剤の例としては
、ポリオキシエチレンセチルエーテル、ポリオキシエチ
レンソルビタンモノオレエート、硬化ヒマシ油エチレン
オキシド付加物、親水性ポリグリセリン脂肪酸エステル
、ショ糖脂肪酸エステルなどが挙げられる。しかし、食
品分野に使用認可されている界面活性剤は限られており
、また、該可溶化組成物中の組成比率が高いことから、
安全な天然由来の界面活性剤として安定性の良いレシチ
ンを用いた可溶化組成物が要望されている。(Problem to be solved by the invention) In order to obtain a stable oil-in-polyhydric alcohol-based solubilized composition, it is essential to use a considerable amount of surfactant. Research has been carried out using surfactants. Examples of such surfactants include polyoxyethylene cetyl ether, polyoxyethylene sorbitan monooleate, hydrogenated castor oil ethylene oxide adduct, hydrophilic polyglycerin fatty acid ester, sucrose fatty acid ester, and the like. However, there are only a limited number of surfactants approved for use in the food field, and because the composition ratio in the solubilized composition is high,
There is a need for a solubilized composition using lecithin, which is a safe, naturally derived surfactant and has good stability.
従って、本発明は天然由来の界面活性剤「レシチン」と
多価アルコールと油相成分から成る、天然系の多価アル
コール中油型可溶化組成物を提供することを目的とする
。Therefore, an object of the present invention is to provide a natural oil-in-polyhydric alcohol solubilized composition comprising a naturally derived surfactant "lecithin", a polyhydric alcohol, and an oil phase component.
（課題を解決するための手段）
すなわち、本発明の多価アルコール中油型可溶化組成物
は、多価アルコールを主成分とする水相部と酵素処理の
レシチンと油相成分からなり、全配合中、多価アルコー
ルを５〜６５重量％、酵素処理のレシチンを５重量％以
上含有することを特徴とする。(Means for Solving the Problems) That is, the oil-in-polyhydric alcohol solubilized composition of the present invention consists of an aqueous phase mainly composed of a polyhydric alcohol, enzyme-treated lecithin, and an oil phase component, and the total composition is It is characterized by containing 5 to 65% by weight of polyhydric alcohol and 5% by weight or more of enzyme-treated lecithin.
本発明によれば、界面活性剤として、全リン脂質中リゾ
リン脂質を７０％以上含む、対水易分散性酵素処理レシ
チンを使用することができる。According to the present invention, an enzyme-treated lecithin that is easily dispersible in water and contains 70% or more of lysophospholipids among all phospholipids can be used as the surfactant.
以下、本発明につき詳細に説明する。Hereinafter, the present invention will be explained in detail.
本発明に使用する多価アルコールは、分子内に水酸基を
２個以上有するもので、グルコース、マルトース、マル
チトール、ショ糖、フラクトース、キシリトール、ソル
ビトール、澱粉分解糖、澱粉分解糖還元アルコールなど
が挙げられる。これらを単独で使用しても、２種以上併
用してもよい。The polyhydric alcohol used in the present invention has two or more hydroxyl groups in its molecule, and examples thereof include glucose, maltose, maltitol, sucrose, fructose, xylitol, sorbitol, starch-degrading sugar, and starch-degrading sugar-reduced alcohol. It will be done. These may be used alone or in combination of two or more.
また、本発明に使用する多価アルコールの組成比率は５
〜６５重量％であり、５重量％より少ない場合は安定な
可溶化組成物が得られず、また６５重世％より多い場合
は、相対的に界面活性剤の組成比率が低下するために、
やはり安定な可溶化組成物が得られない。Furthermore, the composition ratio of the polyhydric alcohol used in the present invention is 5
~65% by weight, if it is less than 5% by weight, a stable solubilized composition cannot be obtained, and if it is more than 65% by weight, the composition ratio of the surfactant is relatively reduced,
Again, a stable solubilized composition cannot be obtained.
本発明に使用する油相成分は、β−カロチン、パプリカ
色素などの着色料、オレンジオイル、レモンオイル、ワ
サビオイルなどの若番料、トコフェロールなどの酸化防
止剤、ビタミンＡ１ビタミンＤ、オクタコサノールなど
の強化剤、中鎖トリグリセライド、オリーブ油、ミンク
油等の動・植物油脂が挙げられる。The oil phase components used in the present invention include coloring agents such as β-carotene and paprika pigment, young additives such as orange oil, lemon oil, and wasabi oil, antioxidants such as tocopherol, vitamin A1, vitamin D, and octacosanol. Examples include reinforcing agents, medium chain triglycerides, animal and vegetable oils such as olive oil and mink oil.
本発明に使用する界面活性剤「レシチン」は、ホスフォ
リパーゼを用いた酵素処理により、リゾリン脂質の含有
量を高めたものであり、通常の大豆リン脂質と異なり水
相に対し易分散性を示す。The surfactant "lecithin" used in the present invention has an increased content of lysophospholipids through enzymatic treatment using phospholipase, and unlike ordinary soybean phospholipids, it has easy dispersibility in the aqueous phase. show.
酵素処理レシチンの組成比率は全配合量中、５重量％以
上であり、５重量％未満では、安定な多価アルコール中
可溶化組成物は得られない。その安定化力は、２０重量
％以下で十分に発揮できる。The composition ratio of the enzyme-treated lecithin is 5% by weight or more in the total blending amount, and if it is less than 5% by weight, a stable composition solubilized in polyhydric alcohol cannot be obtained. Its stabilizing power can be fully exhibited at 20% by weight or less.
それ以上使用しても、それ以上の効果は得られないので
、好ましくは２０重量％以下の使用で十分である。Even if it is used more than that, no further effect can be obtained, so preferably it is sufficient to use it in an amount of 20% by weight or less.
通常の大豆リン脂質は、ＨＬＢ値が低いために上記多価
アルコールに対し、難溶であり、本発明の多価アルコー
ル中油型可溶化組成物が得られない。Ordinary soybean phospholipids have a low HLB value and are poorly soluble in the polyhydric alcohol, making it impossible to obtain the oil-in-polyhydric alcohol solubilized composition of the present invention.
その他の界面活性剤、例えば、プロピレングリコール脂
肪酸エステル、脂肪酸モノグリセライドソルビクン脂肪
酸エステルを使用する場合、いずれも親油性が強く、本
発明の多価アルコール中油型可溶化組成物は得られない
。When other surfactants such as propylene glycol fatty acid ester and fatty acid monoglyceride sorbicun fatty acid ester are used, the oil-in-polyhydric alcohol solubilized composition of the present invention cannot be obtained because both have strong lipophilic properties.
本発明の多価アルコール中油型可溶化組成物は、多価ア
ルコール中に油相成分を可溶化した透明もしくは半透明
の粘稠液状であり、このちの自身、製品として使用でき
、また水相成分で希釈することにより微細な乳化粒子を
もつ氷中油滴型エマルションとしても使用できる。The oil-in-polyhydric alcohol solubilized composition of the present invention is a transparent or translucent viscous liquid in which oil phase components are solubilized in polyhydric alcohol, and can be used as a product by itself, and can also be used as a water phase component. By diluting it with water, it can also be used as an oil-in-ice emulsion with fine emulsified particles.
本発明の多価アルコール中油型可溶化組成物はプロペラ
ミキサーのような、通常の攪拌乳化機で製造できるが、
必要に応じ、コロイドミル、ホモミキサー、圧力式ホモ
ジナイザーを使用してもよい。The oil-in-polyhydric alcohol solubilized composition of the present invention can be produced using a conventional stirring emulsifying machine such as a propeller mixer.
If necessary, a colloid mill, homomixer, or pressure homogenizer may be used.
（発明の効果）
本発明による多価アルコール中油型可溶化組成物は、天
然由来の界面活性剤「レシチンｊを用いた天然多価アル
コール中油型可溶化組成物であり、他の界面活性剤を用
いたものと同等もしくはそれ以上の安定性を有している
。しかも２本発明による多価アルコール中油型可溶化組
成物は、イオン交換水により１００〜５００倍に希釈し
ても安定な水中油滴型乳化状態を保つことが可能である
。(Effects of the Invention) The oil-in-polyhydric alcohol solubilized composition according to the present invention is an oil-in-natural polyhydric alcohol solubilized composition using the naturally derived surfactant "Lecithin J", and contains no other surfactants. Furthermore, the oil-in-water solubilized composition according to the present invention is stable even when diluted 100 to 500 times with ion-exchanged water. It is possible to maintain a droplet-type emulsified state.
（実施例および比較例）
以下、実施例および比較例に基づき本発明を具体的に説
明する。(Examples and Comparative Examples) The present invention will be specifically described below based on Examples and Comparative Examples.
実施例１
酵素処理レシチン（リゾリン脂質８１％）５ｇを７０％
ソルビトール溶液７０ｇに対して、攪拌しながら？６解
した。さらに、ｄ−ミックストコフエロール２５ｇを添
加して攪拌を続け、多価アルコール中ビタミンＥ可溶化
組成物を得た。得られた可溶化組成物は、４０℃で３０
日間放置しても安定な状態を保っていた。また、得られ
た可溶化組成物をイオン交換水で１００倍ないし５００
倍に希釈したものは安定な水中油滴型エマルションであ
った。Example 1 Enzyme-treated lecithin (lysophospholipid 81%) 5g to 70%
While stirring for 70g of sorbitol solution? I solved 6. Further, 25 g of d-mixed tocopherol was added and stirring was continued to obtain a vitamin E solubilized composition in polyhydric alcohol. The resulting solubilized composition was heated to 30°C at 40°C.
It remained stable even after being left alone for several days. In addition, the obtained solubilized composition was diluted with ion-exchanged water to a concentration of 100 to 500 times.
The diluted product was a stable oil-in-water emulsion.
実施例２
酵素処理レシチン（リゾリン脂質８１％）２０ｇを７０
％マルチトール溶液３０ｇに対して、攪拌しながら溶解
した。さらに、β−カロチン溶液（純度１０％）５０ｇ
を添加して攪拌を続け、多価アルコール中β−カロチン
可溶化組成物を得た。Example 2 Enzyme-treated lecithin (81% lysophospholipid) 20g
% maltitol solution with stirring. Additionally, 50g of β-carotene solution (purity 10%)
was added and stirring was continued to obtain a β-carotene solubilized composition in polyhydric alcohol.
得られた可溶化組成物は、４０°Ｃで３０日間放置して
も安定な状態を保っていた。また、得られた可溶化組成
物をイオン交換水で１００倍ないし５００倍に希釈した
ものは安定な氷中油滴型エマルションであった。The obtained solubilized composition remained stable even after being left at 40°C for 30 days. Further, the resulting solubilized composition diluted 100 to 500 times with ion-exchanged water was a stable oil-in-ice emulsion.
実施例３
酵素処理レシチン（リゾリン脂質８１％）５ｇを７０％
キシリトール溶液９０ｇに対して、攪拌しながら溶解し
た。さらに、純度１５％のオクタコサノール５ｇを添加
して攪拌を続け、多価アルコール中オクタコサノール可
溶化組成物を得た。Example 3 Enzyme-treated lecithin (lysophospholipid 81%) 5g to 70%
It was dissolved in 90 g of xylitol solution while stirring. Furthermore, 5 g of octacosanol with a purity of 15% was added and stirring was continued to obtain an octacosanol solubilized composition in polyhydric alcohol.
得られた可溶化組成物は、４０℃で３０日間放置しても
安定な状態を保っていた。また、得られた可溶化組成物
をイオン交換水で１００倍ないし５００倍に希釈したも
のは安定な水中油滴型エマルションであった。The obtained solubilized composition remained stable even after being left at 40°C for 30 days. Further, the obtained solubilized composition was diluted 100 to 500 times with ion-exchanged water, and a stable oil-in-water emulsion was obtained.
実施例４
酵素処理レシチン（リゾリン脂質８１％）１０ｇを７０
％ソルビトール溶液６５ｇに対して、撹拌しながら溶解
した。さらに、レモンオイルフレバー２５ｇを添加して
攪拌を続け、多価アルコール中しモンオイル可溶化組成
物を得た。Example 4 Enzyme-treated lecithin (lysophospholipid 81%) 10g at 70%
% sorbitol solution with stirring. Further, 25 g of lemon oil flavor was added and stirring was continued to obtain a lemon oil solubilized composition in polyhydric alcohol.
得られた可溶化組成物は、４０°Ｃで３０日間放置して
も安定な状態を保っていた。また、得られた可溶化組成
物をｐＨ３，５の水で１００倍ないし５００倍に希釈し
たものは安定な氷中油滴型エマルションであった。The obtained solubilized composition remained stable even after being left at 40°C for 30 days. Furthermore, the obtained solubilized composition was diluted 100 to 500 times with water having a pH of 3.5 to give a stable oil-in-ice emulsion.
実施例５
酵素処理レシチン（リゾリン脂質８１％）２０ｇを７０
％ソルビトール溶液８ｇと混合、攪拌した。さらに、ｄ
−ミックストコフェロール７２ｇを添加して多価アルコ
ール中ビタミンＥ可溶化組成物を得た。Example 5 Enzyme-treated lecithin (81% lysophospholipid) 20g
% sorbitol solution and stirred. Furthermore, d
- 72 g of mixed tocopherols were added to obtain a vitamin E solubilized composition in polyhydric alcohol.
得られた可溶化組成物は、４０℃で３０日間放置しても
安定な状態を保っていた。また、得られた可溶化組成物
をイオン交換水で１００倍ないし５００倍に希釈したも
のは安定な氷中油滴型エマルションであった。The obtained solubilized composition remained stable even after being left at 40°C for 30 days. Further, the resulting solubilized composition diluted 100 to 500 times with ion-exchanged water was a stable oil-in-ice emulsion.
比較例１
大豆レシチン（リゾリン脂質Ｏ％）５ｇを７０％ソルビ
トール溶液７５ｇに対して、攪拌しながら分散し溶解し
た。さらにｄ−ミックストコフェロール溶液２０ｇを添
加して攪拌を続け、多価アルコール中ビタミンＥ組成物
を調製した。得られた組成物は４０°Ｃで２４時間放置
後、油水の層が分離した。Comparative Example 1 5 g of soybean lecithin (lysophospholipid O%) was dispersed and dissolved in 75 g of a 70% sorbitol solution while stirring. Furthermore, 20 g of d-mixed tocopherol solution was added and stirring was continued to prepare a vitamin E composition in polyhydric alcohol. After the resulting composition was left at 40°C for 24 hours, the oil-water layer was separated.
比較例２
ソルビタン脂肪酸エステル４０ｇを７０％マルチトール
溶液４５ｇに対して、攪拌しながら分散し溶解した。さ
らに純度１０％のβ−カロチン溶液１５ｇを添加して撹
拌を続け、多価アルコール中β−カロチン組成物を調製
した。得られた組成物は４０”Ｃで２４時間放置後、油
水の層が分離した。Comparative Example 2 40 g of sorbitan fatty acid ester was dispersed and dissolved in 45 g of a 70% maltitol solution while stirring. Further, 15 g of a β-carotene solution with a purity of 10% was added and stirring was continued to prepare a β-carotene composition in polyhydric alcohol. After the resulting composition was left at 40''C for 24 hours, the oil-water layer separated.
比較例３
脂肪酸モノグリセライド１０ｇを７０％キシリトール溶
液６５ｇに対して、撹拌しながら分散し溶解した。さら
にワサビオイルフレーバー２５ｇを添加して撹拌を続け
、多価アルコール中ワサビオイル組成物を調製した。得
られた組成物は４０’Ｃで２４時間放置後、油水の層が
分離した。Comparative Example 3 10 g of fatty acid monoglyceride was dispersed and dissolved in 65 g of 70% xylitol solution while stirring. Furthermore, 25 g of wasabi oil flavor was added and stirring was continued to prepare a wasabi oil composition in polyhydric alcohol. After the resulting composition was left at 40'C for 24 hours, the oil-water layer was separated.
比較例４
酵素処理レシチン（リゾリン脂質８１％）２０ｇを７０
％ソルビトール溶液３ｇに対して、攪拌しながら分散し
溶解した。さらにオリーブ油７７ｇを添加して攪拌を続
け、多価アルコール中オリーブ油組成物を調、製した。Comparative Example 4 20g of enzyme-treated lecithin (81% lysophospholipid)
The mixture was dispersed and dissolved in 3 g of % sorbitol solution while stirring. Furthermore, 77 g of olive oil was added and stirring was continued to prepare an olive oil composition in polyhydric alcohol.
得られた組成物は４０℃で２４時間放置後、油水の層が
分離した。After the resulting composition was left at 40° C. for 24 hours, an oil-water layer was separated.
比較例５
酵素処理レシチン（リゾリン脂質８１％）２ｇを７０％
ソルビトール溶液９５ｇに対して、攪拌しながら分散し
溶解した。さらにチーズオイルフレーバー３ｇを添加し
て攪拌を続け、多価アルコール中チーズオイル組成物を
調製した。得られた組成物は４０℃で２４時間放置後、
油水の層が分離した。Comparative Example 5 Enzyme-treated lecithin (lysophospholipid 81%) 2g to 70%
The mixture was dispersed and dissolved in 95 g of sorbitol solution while stirring. Further, 3 g of cheese oil flavor was added and stirring was continued to prepare a cheese oil composition in polyhydric alcohol. After the resulting composition was left at 40°C for 24 hours,
The oil-water layer separated.
比較例６
酵素処理レシチン（リゾリン脂質８１％）５ｇを７０％
ソルビトール溶液９３ｇに対して、攪拌しながら溶解し
た。さらに、ｄ−ミックストコフェロール２ｇを添加し
て攪拌を続け、多価アルコール中ビタミンＥ可溶化組成
物を調製した。得られた可溶化組成物は、４０℃で３０
日間放置すると油水の層が分離した。また、得られた可
溶化組成物をイオン交換水で１００倍ないし５００倍に
希釈したものは安定な氷中油滴型エマルションではなか
った。Comparative Example 6 Enzyme-treated lecithin (lysophospholipid 81%) 5g to 70%
It was dissolved in 93 g of sorbitol solution with stirring. Furthermore, 2 g of d-mixed tocopherol was added and stirring was continued to prepare a vitamin E solubilized composition in polyhydric alcohol. The resulting solubilized composition was heated to 30°C at 40°C.
When left for a day, the oil-water layer separated. Further, the resulting solubilized composition diluted 100 to 500 times with ion-exchanged water was not a stable oil-in-ice emulsion.
以上、実施例および比較例から、本発明の酵素処理のレ
シチンを用いた多価アルコール中油型可溶化組成物は、
イオン交換水により１００〜５００倍に希釈しても安定
な氷中油滴型乳化状態を保つことがわかる。From the above Examples and Comparative Examples, the oil-in-polyhydric alcohol solubilized composition using the enzyme-treated lecithin of the present invention is as follows:
It can be seen that a stable oil-in-ice emulsion state is maintained even when diluted 100 to 500 times with ion-exchanged water.
Claims (1)
チンと油相成分からなる多価アルコール中油型可溶化組
成物において、全配合中、多価アルコールを５〜６５重
量％、酵素処理のレシチンを５重量％以上含有すること
を特徴とする多価アルコール中油型可溶化組成物。In an oil-in-polyhydric alcohol solubilized composition consisting of an aqueous phase mainly composed of polyhydric alcohol, enzyme-treated lecithin, and an oil phase component, 5 to 65% by weight of polyhydric alcohol and 5 to 65% by weight of polyhydric alcohol, enzyme-treated lecithin, and oil phase components are used. An oil-in-polyhydric alcohol solubilized composition containing 5% by weight or more of lecithin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63151244A JPH025837A (en) | 1988-06-21 | 1988-06-21 | Oil-in-polyhydric alcohol type solubilized composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63151244A JPH025837A (en) | 1988-06-21 | 1988-06-21 | Oil-in-polyhydric alcohol type solubilized composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH025837A true JPH025837A (en) | 1990-01-10 |
Family
ID=15514414
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63151244A Pending JPH025837A (en) | 1988-06-21 | 1988-06-21 | Oil-in-polyhydric alcohol type solubilized composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH025837A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078245A1 (en) * | 2007-12-19 | 2009-06-25 | Foodtech Trading Co., Ltd. | Transparent emulsified composition and cosmetic and food containing the same |
| WO2017094753A1 (en) * | 2015-11-30 | 2017-06-08 | キユーピー 株式会社 | Oil composition and oxidation inhibiting method of oil |
-
1988
- 1988-06-21 JP JP63151244A patent/JPH025837A/en active Pending
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2009078245A1 (en) * | 2007-12-19 | 2009-06-25 | Foodtech Trading Co., Ltd. | Transparent emulsified composition and cosmetic and food containing the same |
| WO2017094753A1 (en) * | 2015-11-30 | 2017-06-08 | キユーピー 株式会社 | Oil composition and oxidation inhibiting method of oil |
| JPWO2017094753A1 (en) * | 2015-11-30 | 2018-07-26 | キユーピー株式会社 | Oil composition and method for inhibiting oxidation of oil |
| US10640730B2 (en) | 2015-11-30 | 2020-05-05 | Kewpie Corporation | Oil composition and oxidation inhibiting method of oil |
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