JPH0252796A - Suede like thermal transfer film - Google Patents
Suede like thermal transfer filmInfo
- Publication number
- JPH0252796A JPH0252796A JP63203885A JP20388588A JPH0252796A JP H0252796 A JPH0252796 A JP H0252796A JP 63203885 A JP63203885 A JP 63203885A JP 20388588 A JP20388588 A JP 20388588A JP H0252796 A JPH0252796 A JP H0252796A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- thermal transfer
- suede
- resin beads
- support
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012508 resin bead Substances 0.000 claims abstract description 27
- 239000011347 resin Substances 0.000 claims abstract description 26
- 229920005989 resin Polymers 0.000 claims abstract description 26
- 239000010410 layer Substances 0.000 claims abstract description 23
- 239000003973 paint Substances 0.000 claims abstract description 21
- 229920000178 Acrylic resin Polymers 0.000 claims abstract description 17
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 16
- 238000001035 drying Methods 0.000 claims abstract description 16
- 239000002245 particle Substances 0.000 claims abstract description 9
- 229910052782 aluminium Inorganic materials 0.000 claims abstract description 8
- 239000011324 bead Substances 0.000 claims abstract description 8
- 239000012790 adhesive layer Substances 0.000 claims abstract description 5
- 239000000203 mixture Substances 0.000 claims abstract description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 2
- 239000011230 binding agent Substances 0.000 abstract description 9
- 230000000704 physical effect Effects 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 8
- 239000007787 solid Substances 0.000 abstract description 8
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 abstract description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 abstract description 5
- 229920002803 thermoplastic polyurethane Polymers 0.000 abstract description 5
- 239000013522 chelant Substances 0.000 abstract description 4
- 239000003086 colorant Substances 0.000 abstract description 2
- 239000004922 lacquer Substances 0.000 abstract description 2
- 239000000049 pigment Substances 0.000 abstract description 2
- 239000011247 coating layer Substances 0.000 abstract 2
- 230000003796 beauty Effects 0.000 abstract 1
- 238000013329 compounding Methods 0.000 abstract 1
- 238000002360 preparation method Methods 0.000 abstract 1
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- 238000000576 coating method Methods 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 238000000034 method Methods 0.000 description 5
- 239000000463 material Substances 0.000 description 4
- -1 polyethylene terephthalate Polymers 0.000 description 4
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 239000002904 solvent Substances 0.000 description 3
- 239000001993 wax Substances 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 2
- 238000005299 abrasion Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 239000006185 dispersion Substances 0.000 description 2
- 239000006224 matting agent Substances 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- 229920000139 polyethylene terephthalate Polymers 0.000 description 2
- 239000005020 polyethylene terephthalate Substances 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000007605 air drying Methods 0.000 description 1
- 238000010924 continuous production Methods 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 239000002270 dispersing agent Substances 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000011874 heated mixture Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 238000007788 roughening Methods 0.000 description 1
- 229920002050 silicone resin Polymers 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Thermal Transfer Or Thermal Recording In General (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は熱転写フィルムに関し、更に詳しくは優れた物
性及び外観のスェード調表面を被転写材表面に転写でき
る熱転写フィルムに関する。DETAILED DESCRIPTION OF THE INVENTION (Industrial Application Field) The present invention relates to a thermal transfer film, and more particularly to a thermal transfer film capable of transferring a suede-like surface with excellent physical properties and appearance to the surface of a transfer material.
（従来の技術及びその問題点）
従来、物品の表面にスェード調表面を付与する方法とし
て、バインダー樹脂と樹脂ビーズとを含むスェード調塗
料を塗布する方法が知られている。(Prior Art and its Problems) Conventionally, as a method of imparting a suede-like surface to the surface of an article, a method of applying a suede-like paint containing a binder resin and resin beads has been known.
上記の樹脂ビーズとしては特に着色又は無着色のポリウ
レタン樹脂ビーズが用いられ、バインダーとしては二液
型のウレタン樹脂が使用されている。しかしながらこの
二液型塗料はその硬化に長時間の焼付工程を要し、耐熱
性の低いプラスチック製品には応用が困難である。又、
保存中ゲル化し易いため可使時間の制限がある。In particular, colored or uncolored polyurethane resin beads are used as the resin beads, and a two-component urethane resin is used as the binder. However, this two-component paint requires a long baking process for curing, making it difficult to apply to plastic products with low heat resistance. or,
Because it tends to gel during storage, its pot life is limited.
特にこれらの塗料を用いて転写フィルムを作成するには
、支持体フィルムに塗料を塗工後直ちに乾燥及び巻き取
りが連続的に行われることが必要であり、上記の如き理
由で連続生産が困難である。In particular, in order to create a transfer film using these paints, it is necessary to continuously dry and wind up immediately after coating the support film, making continuous production difficult for the reasons mentioned above. It is.
一方、上記の如き生産性の問題はバインダーとしてラッ
カータイプのものを使用すれば解決されるが、ラッカー
タイプにより形成されたスェード調表面は物性面、特に
耐摩耗性、耐擦傷性等に劣り実用性が低い。On the other hand, the above productivity problem can be solved by using a lacquer-type binder, but the suede-like surface formed by the lacquer-type has poor physical properties, especially wear resistance and scratch resistance, and is not practical. low gender.
従って、本発明の目的は上記の如き欠点を解決し、連続
生産が可能で且つ物性及び美感に優れたスェード調転写
面を与える熱転写フィルムを提供することである。Therefore, an object of the present invention is to solve the above-mentioned drawbacks and provide a thermal transfer film that can be produced continuously and provides a suede-like transfer surface with excellent physical properties and aesthetic appearance.
（問題点を解決するための手段） 上記目的は以下の本発明によって達成される。(Means for solving problems) The above objects are achieved by the present invention as described below.
すなわち、本発明は、支持体の表面に離型層、熱転写層
及び接着層を順次形成してなる熱転写フィルムにおいて
、上記支持体の表面がマット状であり、熱転写層が常温
乾燥型樹脂と樹脂ビーズとを含むスェード調塗料を塗布
及び乾燥させて形成したものであることを特徴とするス
ェード調熱転写フィルムである。That is, the present invention provides a thermal transfer film in which a release layer, a thermal transfer layer, and an adhesive layer are sequentially formed on the surface of a support, wherein the surface of the support is matte, and the thermal transfer layer is composed of a room temperature drying resin and a resin. This is a suede-like thermal transfer film characterized in that it is formed by applying and drying a suede-like paint containing beads.
（作 用）
熱転写層を常温硬化型樹脂と樹脂ビーズとを含む塗料か
ら形成することにより、連続生産で物性及び美感に優れ
たスェード調転写面を与える熱転写フィルムが提供され
る。(Function) By forming the thermal transfer layer from a paint containing a room-temperature curing resin and resin beads, a thermal transfer film that can be continuously produced and provides a suede-like transfer surface with excellent physical properties and aesthetic appearance is provided.
（好ましい実施態様）
次に好ましい実施態様を挙げて本発明を更に詳しく説明
する。(Preferred Embodiments) Next, the present invention will be described in more detail by citing preferred embodiments.
本発明で使用する支持体としては、熱転写フィルムで使
用されている従来公知の支持体でよく、例えば、５乃至
１０μｍの厚みで且つその表面が艶消し処理されたポリ
エチレンテレフタレートフィルムが好ましく使用される
。艶消し処理はマット剤の練り込み、機械的粗面化、マ
ット剤の塗布等によって行うことができ、これらのマッ
ト表面の荒さを調節することによって、転写膜表面の光
沢及び風合を調整することができる。The support used in the present invention may be any conventionally known support used in thermal transfer films; for example, a polyethylene terephthalate film with a thickness of 5 to 10 μm and a matte surface is preferably used. . Matting treatment can be performed by mixing in a matting agent, mechanically roughening the surface, applying a matting agent, etc. By adjusting the roughness of these matte surfaces, the gloss and texture of the transfer film surface can be adjusted. be able to.
上記支持体の表面に設ける剥離層は、支持体と転写層と
の転写時の剥離性を良好にするものであり、上記の如き
支持体フィルム上に全面に或いは画像状に形成する。剥
離層を形成する材料としては、例えば、アクリル酸エス
テル樹脂、シリコーン樹脂、弗素樹脂等の剥離性樹脂が
用いられ、これらの剥離層は、例えば、グラビア印刷方
式、グラビアコート方式等で固形分として０．１ｇ／♂
乃至１０ｇ／ｒｎ”程度の割合で塗工及び乾燥して形成
する。The peeling layer provided on the surface of the support improves the peelability during transfer between the support and the transfer layer, and is formed on the entire surface or in the form of an image on the support film as described above. As the material for forming the release layer, for example, release resins such as acrylic ester resins, silicone resins, and fluorine resins are used. 0.1g/♂
It is formed by coating and drying at a rate of about 10 g/rn''.
剥離層上に形成する転写層は樹脂ビーズを含む常温硬化
型塗料から形成する。この転写層の厚みは通常は２５乃
至６０μｍ程度である。The transfer layer formed on the release layer is formed from a room temperature curing type paint containing resin beads. The thickness of this transfer layer is usually about 25 to 60 μm.
上記の転写層上には転写時に転写層を被転写材に接着さ
せるための接着層を形成する。この接着層は従来公知の
接着剤を用いて、０．５乃至２０μｍ程度の厚みに形成
することが好ましい。An adhesive layer is formed on the transfer layer for adhering the transfer layer to the material to be transferred during transfer. This adhesive layer is preferably formed using a conventionally known adhesive to a thickness of about 0.5 to 20 μm.
本発明において使用し、本発明を主として特徴づける常
温乾燥型樹脂とは、使用直前に硬化剤（架橋剤）を添加
して使用する二液硬化型樹脂と異なり、被膜形成剤であ
る樹脂が反応性基を有するとともに、予め硬化剤を含有
しているタイプであり、塗工後常温で自然乾燥によって
十分な物性の被膜を形成し得るものである。The room temperature drying resin used in the present invention and which mainly characterizes the present invention is different from the two-component curing resin in which a curing agent (crosslinking agent) is added immediately before use, and the resin that is a film forming agent reacts with the resin. This type contains a curing agent in advance as well as a curing agent, and can form a film with sufficient physical properties by air drying at room temperature after coating.
特に好ましい常温乾燥型樹脂は、アルミニウムキレート
変性アクリル樹脂類及びこれとラッカー塗料用アクリル
樹脂類との温合物が挙げられる。Particularly preferred room temperature drying resins include aluminum chelate-modified acrylic resins and warm mixtures of these and acrylic resins for lacquer coatings.
特にアルミニウムキレート変性アクリル樹脂（例えば、
商品名“ユピカコート”ＡＣ−３０００シリーズ、ロ木
ユビカ製）は、樹脂ビーズの固着力もよく、物性、外観
的にも良好な転写膜を作り易く本発明の目的に適してい
る。これらのアクリル樹脂類、特にアルミニウムキレー
ト変性アクリル樹脂の使用により速乾性で連続巻き取り
可能なスェード塗料が可能となったものであり、物性的
にもビーズ固着力の優れた耐摩耗性の良いスェード塗膜
が形成可能となった。Especially aluminum chelate modified acrylic resins (e.g.
The product name "Yupika Coat" AC-3000 series (manufactured by Yubika Roki) has good adhesion of resin beads, and is suitable for the purpose of the present invention because it is easy to produce a transfer film with good physical properties and appearance. The use of these acrylic resins, especially aluminum chelate-modified acrylic resins, has made it possible to create suede paints that dry quickly and can be rolled up continuously.Physically speaking, suede paints have excellent bead adhesion and wear resistance. It became possible to form a coating film.
本発明で使用する樹脂ビーズとしては顔料で着色した各
色の樹脂ビーズ及び無着色の樹脂ビーズ等があり、単独
又は温合物で使用できる。好ましい種類としては、アク
リル系樹脂ビーズ、例えば、商品名“ラブロコール”
（大日蹟化工業製）、ウレタン系樹脂ビーズ、商品名“
デコシルり” （トランスモンタン社Ｍ）、商品名“ラ
ビ（Ｂ）“ （大橋化学製）等があり、更に、塩化ビニ
ル樹脂ビーズ、着色ナイロンビーズ等も使用できる。こ
れらのビーズに要求される特性としては、バインダー樹
脂との固着力や均−分散性等があるか、アクリル系及び
ウレタン系樹脂ビーズ等がこれらの特性に優れており、
良好な結果を与える。The resin beads used in the present invention include resin beads of various colors colored with pigments, uncolored resin beads, etc., and can be used alone or in a heated mixture. Preferred types include acrylic resin beads, such as the product name "Loverocol".
(manufactured by Dainichikeika Kogyo), urethane resin beads, product name “
"Decosil" (Transmontan M), product name "Ravi (B)" (Ohashi Chemical Co., Ltd.), etc. In addition, vinyl chloride resin beads, colored nylon beads, etc. can also be used.The characteristics required for these beads. As such, acrylic and urethane resin beads have excellent adhesion strength and uniform dispersibility with the binder resin.
Gives good results.
使用する樹脂ビーズの粒径は１０乃至１００μｍの範囲
が好ましく、粒径が１０μｍより小さいと十分なスェー
ド感が出す、一方、粒径か１００μｍより大粒径では表
面が粗面となりすぎ、スェード調とは云えなくなる。更
に好適な粒径は２０乃至７０μｍ程度であり、多少の粒
径分布をもっている方がスェード感が出易いので好まし
い。樹脂ビーズの配合量は樹脂バインダー固形分１００
重量部に対し１０乃至３００重量部の範囲か好ましく、
１０重量部未満では十分なスェード調にならず、一方、
３００重量部を越えるとバインダーとしての樹脂分が少
なくなり、固着力が低下して物性不良となるので好まし
くない。更に好適な範囲としては樹脂バインダー固形分
１００重量部部に対し、５０乃至１５０重量部の範囲で
ある。The particle size of the resin beads used is preferably in the range of 10 to 100 μm. If the particle size is smaller than 10 μm, a sufficient suede effect will be produced. On the other hand, if the particle size is larger than 100 μm, the surface will be too rough, resulting in a suede look. I can no longer say that. A more preferable particle size is about 20 to 70 μm, and it is preferable to have a slight particle size distribution because it tends to give a suede feel. The blending amount of resin beads is resin binder solid content 100
It is preferably in the range of 10 to 300 parts by weight,
If it is less than 10 parts by weight, the suede effect will not be sufficient;
If it exceeds 300 parts by weight, the resin content as a binder decreases, resulting in a decrease in adhesive strength and poor physical properties, which is not preferable. A more preferable range is 50 to 150 parts by weight per 100 parts by weight of the solid content of the resin binder.
塗料化に際しては樹脂バインダー及び樹脂ビーズの他に
必要に応じて塗料添加剤類、例えば、レベリング剤、分
散剤、ワックス類等を使用できる。又、溶解溶剤、希釈
用溶剤はトルエン、酢酸エチル、ＭＥＫ （メチルエチ
ルケトン）等、速乾性溶剤を使用することにより加工適
性を良くすることができる。When making a paint, in addition to the resin binder and resin beads, paint additives such as leveling agents, dispersants, waxes, etc. can be used as necessary. Furthermore, processing suitability can be improved by using a quick-drying solvent such as toluene, ethyl acetate, MEK (methyl ethyl ketone), etc. as the dissolving solvent and diluting solvent.
このスェード３１塗料の塗工量は、塗１１５！厚く乾燥
塗膜）２５乃至６０μｍ程度がスェード感を出すために
必要であり、塗工はリバースロールコータ−等適切な方
式で均一に塗工する。乾燥は８０乃至１２０℃及び３０
秒乃至２分程度である。The coating amount of this Suede 31 paint is 115 coats! A thick dry coating film of approximately 25 to 60 μm is required to create a suede feel, and the coating is uniformly applied using an appropriate method such as a reverse roll coater. Drying at 80-120℃ and 30℃
It takes about seconds to 2 minutes.
（効 果）
以上の如き本発明によれば、熱転写層を常温硬化型樹脂
と樹脂ビーズとを含む速乾性のスェード５Ｒ塗料から形
成することにより、物性及び美感に優れたスェード調転
写面を与える熱転写フィルムが優れた生産性で提供され
る。(Effects) According to the present invention as described above, by forming the thermal transfer layer from a quick-drying suede 5R paint containing a room-temperature curing resin and resin beads, a suede-like transfer surface with excellent physical properties and aesthetic appearance is provided. A thermal transfer film is provided with excellent productivity.
又・本発明の熱転写フィルムは、従来公知のホットスタ
ンプ式等のいずれの転写方法でも使用できるものであり
、被転写材としては合成樹脂成形品、プラスチックシー
トアルミ蒸着フィルム、ガラス板、金属製品等いずれの
物品でもよく特に限定されない。Furthermore, the thermal transfer film of the present invention can be used with any conventional transfer method such as hot stamping, and transfer materials include synthetic resin molded products, plastic sheets, aluminum vapor-deposited films, glass plates, metal products, etc. Any article may be used without particular limitation.
（実施例）
次に実施例を挙げて本発明を更にＪ−１一体内に説明す
る。尚、文中、部又は％とあるのは特に断りのない限り
重量基準である。(Example) Next, the present invention will be further explained within J-1 by giving an example. In the text, parts or percentages are based on weight unless otherwise specified.
実施例１
（１）スェード調塗料の作成
アルミキレート変性アクリル樹脂（固形分４０％、日本
ユピカ製） １００部アクリル樹脂着色
ビーズ（大日精化工業■製、粒径２０乃至６０μｍ）
白色 ２０部
黒色 ２０部
ポリエチレンワックス分散液 ５部酢酸エチル
２０部ＭＥに ルエ ル
ン ２０合 計 （固形分４４％） １
８５部上記成分を均一に混合して本発明で使用するスェ
ード調塗料とした。Example 1 (1) Creation of suede-like paint Aluminum chelate modified acrylic resin (solid content 40%, manufactured by Nippon U-Pica) 100 parts Acrylic resin colored beads (manufactured by Dainichiseika Kogyo ■, particle size 20 to 60 μm) White 20 parts Black 20 parts polyethylene wax dispersion 5 parts ethyl acetate 20 parts ME 20 total (solid content 44%) 1
85 parts The above components were uniformly mixed to prepare a suede-like paint used in the present invention.
（２）スェード調熱転写フィルムの製造ＰＥＴマットフ
ィルムに離型剤を塗布後、上記（１）のスェード調塗料
をバーコーターにより乾燥１漠厚５０乃貸６０μｍに塗
装し、１００℃及び２分間の条件で乾燥し、粘着性のな
い塗膜が得られた。これに接着剤を塗布して本発明のス
ェード調熱転写フィルムとした。(2) Manufacture of suede tone heat transfer film After applying a release agent to the PET matte film, apply the suede tone paint from (1) above using a bar coater to a dry thickness of 50 to 60 μm, and heat at 100°C for 2 minutes. It dried under the conditions and a non-tacky coating was obtained. An adhesive was applied to this to obtain a suede thermal transfer film of the present invention.
この熱転写フィルムを用いてシリコンホットロール（１
５０℃）により転写層をＡＢＳ板に転写したところ、美
麗なスェード調の転写面が得られ、この転写面は耐斤耗
性に優れ、乾布５００ ｇ／Ｃば、往復摩耗２，０００
回で下地が露出しなかった。Using this thermal transfer film, silicone hot roll (1
When the transfer layer was transferred to an ABS board using a 50℃ (50℃) transfer layer, a beautiful suede-like transfer surface was obtained, and this transfer surface has excellent abrasion resistance.
The base layer was not exposed in the second step.
実施例２
（１）スェード調塗料の作成
アルミキレート変性アクリル樹脂（固形分４０％）
５０部アクリル樹脂フェス（固
形分４５％） ５０部ウレタン樹脂ビーズ（トランスモ
ンタン社製、粒径２０乃至７０μｍ）
黄色 ２０部
弁柄色 １０部ポリエチレン
ワックス分散液 ５部酢酸エチル
２０部ＭＥに メ ルエ ルケ ン
２０合 計 （固形分４３％） １７５部り記成
分を均一に混合して本発明で使用するスェード′：Ａ塗
料とした。これを用いて実施例１と同じ方法により本発
明のスェード調熱転写フィルムとし、ＡＢＳ板上に転写
させた。Example 2 (1) Creation of suede-like paint Aluminum chelate modified acrylic resin (solid content 40%)
50 parts Acrylic resin face (solid content 45%) 50 parts Urethane resin beads (manufactured by Transmontane, particle size 20 to 70 μm) Yellow 20 parts Bengara color 10 parts Polyethylene wax dispersion 5 parts Ethyl acetate
20th part ME to Merue Luken
20 total (solid content 43%) 175 parts The listed components were uniformly mixed to prepare Suede':A paint used in the present invention. Using this, a suede thermal transfer film of the present invention was prepared in the same manner as in Example 1, and transferred onto an ABS board.
得られた転写面は耐摩耗性の他、耐水、耐アルコール性
等にも優れている。The resulting transfer surface has excellent water resistance, alcohol resistance, etc. in addition to abrasion resistance.
Claims (4)
次形成してなる熱転写フィルムにおいて、上記支持体の
表面がマット状であり、熱転写層が常温乾燥型樹脂と樹
脂ビーズとを含むスェード調塗料を塗布及び乾燥させて
形成したものであることを特徴とするスェード調熱転写
フィルム。(1) In a thermal transfer film in which a release layer, a thermal transfer layer, and an adhesive layer are sequentially formed on the surface of a support, the surface of the support is matte, and the thermal transfer layer contains a resin that dries at room temperature and resin beads. 1. A suede tone thermal transfer film, characterized in that it is formed by applying and drying a suede tone paint containing the following:
リル樹脂類又はこれとアクリル樹脂類との温合物である
請求項１に記載の熱転写フィルム。(2) The thermal transfer film according to claim 1, wherein the room temperature drying resin is an aluminum chelate-modified acrylic resin or a warm mixture of this and an acrylic resin.
：１０乃至３００の割合である請求項１に記載の熱転写
フィルム。(3) Weight ratio of room temperature drying resin and resin beads is 100
The thermal transfer film according to claim 1, wherein the ratio is from 10 to 300.
タン樹脂ビーズ又はアクリル樹脂ビーズである請求項１
に記載の熱転写フィルム。(4) Claim 1 wherein the resin beads are polyurethane resin beads or acrylic resin beads with a particle size of 10 to 100 μm.
Thermal transfer film described in .
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63203885A JPH0252796A (en) | 1988-08-18 | 1988-08-18 | Suede like thermal transfer film |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63203885A JPH0252796A (en) | 1988-08-18 | 1988-08-18 | Suede like thermal transfer film |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH0252796A true JPH0252796A (en) | 1990-02-22 |
Family
ID=16481333
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63203885A Pending JPH0252796A (en) | 1988-08-18 | 1988-08-18 | Suede like thermal transfer film |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0252796A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013230575A (en) * | 2012-04-27 | 2013-11-14 | Toppan Printing Co Ltd | Transfer foil, method of manufacturing decorative molded article and decorative molded article |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60101084A (en) * | 1983-11-08 | 1985-06-05 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS60212392A (en) * | 1984-04-09 | 1985-10-24 | General Kk | Thermal transfer medium |
-
1988
- 1988-08-18 JP JP63203885A patent/JPH0252796A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS60101084A (en) * | 1983-11-08 | 1985-06-05 | Dainippon Printing Co Ltd | Thermal transfer sheet |
| JPS60212392A (en) * | 1984-04-09 | 1985-10-24 | General Kk | Thermal transfer medium |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2013230575A (en) * | 2012-04-27 | 2013-11-14 | Toppan Printing Co Ltd | Transfer foil, method of manufacturing decorative molded article and decorative molded article |
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