JPH0248523B2 - EKITAISENJOZAISOSEIBUTSU - Google Patents
EKITAISENJOZAISOSEIBUTSUInfo
- Publication number
- JPH0248523B2 JPH0248523B2 JP20982987A JP20982987A JPH0248523B2 JP H0248523 B2 JPH0248523 B2 JP H0248523B2 JP 20982987 A JP20982987 A JP 20982987A JP 20982987 A JP20982987 A JP 20982987A JP H0248523 B2 JPH0248523 B2 JP H0248523B2
- Authority
- JP
- Japan
- Prior art keywords
- weight
- component
- acid
- group
- content
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000000203 mixture Substances 0.000 claims description 43
- KWIUHFFTVRNATP-UHFFFAOYSA-N glycine betaine Chemical compound C[N+](C)(C)CC([O-])=O KWIUHFFTVRNATP-UHFFFAOYSA-N 0.000 claims description 17
- -1 polyoxyethylene sulfosuccinic acid Polymers 0.000 claims description 17
- 125000004432 carbon atom Chemical group C* 0.000 claims description 15
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 15
- 239000000194 fatty acid Substances 0.000 claims description 15
- 229930195729 fatty acid Natural products 0.000 claims description 15
- 239000007788 liquid Substances 0.000 claims description 12
- 150000003839 salts Chemical class 0.000 claims description 11
- 239000004711 α-olefin Substances 0.000 claims description 11
- 150000004665 fatty acids Chemical class 0.000 claims description 10
- 239000002253 acid Substances 0.000 claims description 9
- 229960003237 betaine Drugs 0.000 claims description 9
- 238000004140 cleaning Methods 0.000 claims description 9
- 229910052751 metal Inorganic materials 0.000 claims description 6
- 239000002184 metal Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 6
- 229910052783 alkali metal Inorganic materials 0.000 claims description 5
- 125000003342 alkenyl group Chemical group 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 5
- 150000001340 alkali metals Chemical group 0.000 claims description 4
- 125000005907 alkyl ester group Chemical group 0.000 claims description 4
- 239000000654 additive Substances 0.000 claims description 3
- 125000002947 alkylene group Chemical group 0.000 claims description 3
- 230000000052 comparative effect Effects 0.000 description 21
- 239000000344 soap Substances 0.000 description 15
- 235000002639 sodium chloride Nutrition 0.000 description 15
- 238000005187 foaming Methods 0.000 description 13
- 239000002453 shampoo Substances 0.000 description 10
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical group C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- 229910052708 sodium Inorganic materials 0.000 description 8
- 239000003599 detergent Substances 0.000 description 5
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 4
- CSNNHWWHGAXBCP-UHFFFAOYSA-L Magnesium sulfate Chemical compound [Mg+2].[O-][S+2]([O-])([O-])[O-] CSNNHWWHGAXBCP-UHFFFAOYSA-L 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 4
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 4
- 229910001629 magnesium chloride Inorganic materials 0.000 description 4
- 235000011147 magnesium chloride Nutrition 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical group [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 239000006260 foam Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 230000000704 physical effect Effects 0.000 description 3
- 229910052700 potassium Chemical group 0.000 description 3
- 239000011591 potassium Chemical group 0.000 description 3
- 239000003755 preservative agent Substances 0.000 description 3
- 238000003860 storage Methods 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- QJRRBVNPIKYRQJ-UHFFFAOYSA-N 10-methylundecanoic acid Chemical compound CC(C)CCCCCCCCC(O)=O QJRRBVNPIKYRQJ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000005639 Lauric acid Substances 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 235000021314 Palmitic acid Nutrition 0.000 description 2
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 235000021355 Stearic acid Nutrition 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
- 238000005238 degreasing Methods 0.000 description 2
- UKMSUNONTOPOIO-UHFFFAOYSA-N docosanoic acid Chemical compound CCCCCCCCCCCCCCCCCCCCCC(O)=O UKMSUNONTOPOIO-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- YYVJAABUJYRQJO-UHFFFAOYSA-N isomyristic acid Chemical compound CC(C)CCCCCCCCCCC(O)=O YYVJAABUJYRQJO-UHFFFAOYSA-N 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 229910052943 magnesium sulfate Inorganic materials 0.000 description 2
- 235000019341 magnesium sulphate Nutrition 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 230000003020 moisturizing effect Effects 0.000 description 2
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 2
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 2
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 230000002335 preservative effect Effects 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000008117 stearic acid Substances 0.000 description 2
- 239000003760 tallow Substances 0.000 description 2
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 2
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristin Chemical compound CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 2
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- ZONJATNKKGGVSU-UHFFFAOYSA-N 14-methylpentadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCC(O)=O ZONJATNKKGGVSU-UHFFFAOYSA-N 0.000 description 1
- 235000021357 Behenic acid Nutrition 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000005632 Capric acid (CAS 334-48-5) Substances 0.000 description 1
- 235000013162 Cocos nucifera Nutrition 0.000 description 1
- 244000060011 Cocos nucifera Species 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- OYHQOLUKZRVURQ-HZJYTTRNSA-N Linoleic acid Chemical compound CCCCC\C=C/C\C=C/CCCCCCCC(O)=O OYHQOLUKZRVURQ-HZJYTTRNSA-N 0.000 description 1
- 235000021360 Myristic acid Nutrition 0.000 description 1
- TUNFSRHWOTWDNC-UHFFFAOYSA-N Myristic acid Natural products CCCCCCCCCCCCCC(O)=O TUNFSRHWOTWDNC-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 235000015278 beef Nutrition 0.000 description 1
- 229940116226 behenic acid Drugs 0.000 description 1
- 125000002511 behenyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 235000011148 calcium chloride Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000002537 cosmetic Substances 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 125000000816 ethylene group Chemical group [H]C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
- 239000003906 humectant Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 235000020778 linoleic acid Nutrition 0.000 description 1
- OYHQOLUKZRVURQ-IXWMQOLASA-N linoleic acid Natural products CCCCC\C=C/C\C=C\CCCCCCCC(O)=O OYHQOLUKZRVURQ-IXWMQOLASA-N 0.000 description 1
- 125000005645 linoleyl group Chemical group 0.000 description 1
- 235000004213 low-fat Nutrition 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 125000001570 methylene group Chemical group [H]C([H])([*:1])[*:2] 0.000 description 1
- 239000013081 microcrystal Substances 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 235000019198 oils Nutrition 0.000 description 1
- 125000001117 oleyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])/C([H])=C([H])\C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000002304 perfume Substances 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- OTYBMLCTZGSZBG-UHFFFAOYSA-L potassium sulfate Chemical compound [K+].[K+].[O-]S([O-])(=O)=O OTYBMLCTZGSZBG-UHFFFAOYSA-L 0.000 description 1
- 229910052939 potassium sulfate Inorganic materials 0.000 description 1
- 235000011151 potassium sulphates Nutrition 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
Description
産業上の利用分野
本発明は新規な液体洗浄剤組成物に関し、さら
に詳しくは、バスないしシヤワー用ソープとして
特に起泡性がよく、肌がきしまず、すつきりした
仕上がりになり、さらつとした感触を残し、また
頭髪シヤンプーとして毛髪がきしまず、さらつと
した仕上がりになり、髪が乱れない、身体用ない
し頭髪用液体洗浄剤組成物に関する。
従来技術およびその問題点
一般に繁用のアニオン界面活性剤をバスなしび
シヤワー用ソープとして身体用洗浄剤に繰り返し
使用した場合、皮膚からの脱脂力が強いため使用
後の肌がカサカサしたり、ぬめり感がある。ま
た、アニオン界面活性剤を頭髪用シヤンプーとし
て用いた場合、起泡性が思わしくなく、脱脂力が
強いため、使用後の髪がパサパサになり髪のまと
まりがない。しかも脂肪分が少ないアルフアオレ
フインスルホン酸塩を配合した場合、低温での溶
解性が悪くなり、結晶性の小粒子が生成して商品
価値を損なう。
本発明者らはこれ等の欠点をことごとく解消す
べく鋭意研究を重ねた結果、本発明を完成した。
問題点の解決手段
本発明は下記成分(A)〜(G)からなる液体洗浄剤組
成物である。
下記成分(A)〜(G)からなる液体洗浄剤組成物;
(A) 一般式()で示されるポリオキシエチレン
スルホコハク酸アルキルエステル
(式中、R1は炭素数8〜21のアルキル基また
はアルケニル基、nは1〜15の整数、Xはアル
カリ金属をそれぞれ意味する)
0.5〜5重量%、
(B) 一般式()で示される脂肪酸アミドアルキ
ルジメチルアミノ酢酸ベタイン
(式中、R2は炭素数9〜17のアルキル基また
はアルケニル基、R3は炭素数1〜6のアルキ
レン基をそれぞれ意味する)
0.5〜5重量%、
(C) 炭素数10〜18のα−オレフインスルホン酸塩
1〜20重量%、
(D) 炭素数12〜20の脂肪酸塩
1〜10重量%、
(E) 金属塩
1〜10重量%、
(F) 任意の添加剤
0〜5重量%、
(G) 水
45〜96重量%。
成分(A)について、一般式()で示されるエス
テル化合物において、R1で示されるアルキル基
としては、カプリル基、ラウリル基、ヤシ油脂肪
基、牛脂脂肪基、リミスチル基、ベヘニル基、イ
ソラウリル基、イソミリスチル基、イソパルミチ
ル基、イソステアリル基、イソベヘニル基などが
例示され、またアルケニル基としては、オレイル
基、リノレイル基などが例示される。
Xで示されるアルカリ金属としては、ナトリウ
ムまたはカリウムが好ましい。
成分(A)の含有量については、これが0.5重量%
以下であると、泡立ちが悪く、組成物の安定性が
悪い。逆に成分(A)を5重量%以上配合すると、身
体にねばい感触を与え、組成物の安定性が悪くな
る。したがつて成分(A)の含有量は0.5〜5重量%
に限定される。好ましい含有量は1〜3重量%で
あり、最も好ましい含有量は約2.25重量%であ
る。
つぎに成分(B)について、一般式()で示され
るベタイン化合物において、R2CO−で表わしれ
る基は、カプリン酸、ラウリン酸、ヤシ油脂肪
酸、牛脂脂肪酸、ミリスチン酸、パルミチン酸、
ステアリン酸、ベヘニン酸、イソラウリン酸、イ
ソミリスチレン酸、イソステアリン酸、オレイン
酸、リノール酸などの酸の残基である。
R3で示されるアルキレン基としては、メチレ
ン基、エチレン基、プロピレン基、ブチレン基、
イソプロピレン基、イソブチレン基などが例示さ
れる。
成分(B)の含有量については、これが0.5重量%
より少ないと、泡立ちが悪く、バスないしシヤワ
ー用ソープとしてすつきりした洗い上がりがな
く、肌がかさつき、また頭髪シヤンプーとして髪
がしなやかにならないでパサつく。しかも組成物
の安定性も悪い。逆にこの含有量が5重量%以上
になると、成分(B)のベタインが両性界面活性剤で
あるため、その特性である肌に対するベタつきが
生じ、バスなしシヤワー用ソープとしてまたは頭
髪シヤンプーとして好ましくなく、組成物の安定
性も悪い。したがつて成分(B)の含有量は0.5〜5
重量%に限定される。好ましい含有量は1〜3重
量%であり、最も好ましい含有量は2.25重量%で
ある。
つぎに成分(C)について、α−オレフインスルホ
ン酸塩は、炭素数10〜18のα−オレフインモノス
ルホン酸塩を主体とし、少量のα−オレフインジ
スルホン酸塩、ヒドロキシアルカンモノスルホン
酸塩を含むこともある。
成分(C)の含有量については、これが1重量%以
下であると、洗浄性がなく、バスないしシヤワー
用ソープまたは頭髪シヤンプーとしての機能が生
じない。逆に成分(C)を20重量%以上含有すれば、
組成物の安定性が悪くなり、起泡力がなくなる。
したがつて成分(C)の含有量は1〜20重量%に限定
される。好ましい含有量は5〜15重量%であり、
最も好ましい含有量は9.75重量%である。
つぎに成分(D)について、脂肪酸塩としては、ラ
ウリン酸、ミリスチン酸、パルミチン酸、ステア
リン酸、イソミリスチン酸、イソパルミチン酸、
イソステアリン酸、オレイン酸、リノール酸なの
脂肪酸のアルカリ金属塩、上記脂肪酸とトリエタ
ノールアミンないしジエタノールアミンのような
アミンとの塩などが例示される。
成分(D)の含有量については、これが1重量%以
下であれば、バスないしシヤワー用ソープまたは
頭髪シヤンプーとして泡立ちが少なく機能性がな
い。逆に成分(D)を10重量%以上に含有すれば、組
成物の安定性が悪くなり、泡立ちも悪い、したが
つて成分(D)の含有量は1〜10重量%に限定され
る。好ましい含有量は3〜8重量%であり、最も
好ましい含有量は5.25重量%である。
つぎに金属塩(E)の例としては、塩化ナトリウ
ム、塩化カリウム、塩化マグネシウム、塩化カル
シウム、硫酸ナトリウム、硫酸カリウム、硫酸マ
グネシウムなどのアルカリ金属またはアルカリ土
金属の塩酸または硫酸塩が挙げられる。
金属塩(E)の含有量については、これが1重量%
より少ないし、組成物の安定性が悪く、バスない
しシヤワー用ソープまたは頭髪シヤンプーとして
の使用感が悪い。逆にこの含有量が10重量%以上
になると、組成物がゲル状になり、安定性が悪く
なる上に、機泡力も悪くなる。したがつて、成分
(E)の含有量は1〜10重量%に限定される。好まし
い含有量は2〜7重量%であり、最も好ましい含
有量は、3.25重量%である。
最後に、任意の添加剤(F)としては、防腐剤、香
料、保湿剤あるいは洗浄助剤としてのノニオン活
性剤などの汎用の香粧品原料が、通常の量で任意
に併用される。その含有量は0〜5重量%であ
る。
作 用
本発明による組成物は、ポリオキシエチレンス
ルホコハク酸アルキルエステル(A)を含有するの
で、バスないしシヤワー用ソープまたは頭髪シヤ
ンプーとしての性能が良く、起泡力がすぐれてい
る上に、余分な増脂力がなく、マイルドな洗浄性
が得られる。
また本発明による組成物は、両性界面活性剤で
ある脂肪酸アミドアルキルジメチルアミノ酢酸ベ
タイン(B)および塩化マグネシウムのような金属塩
(E)を含有するので、これらが反応し、PH5〜PH8
の間で起泡力が増し、泡立ちが良くなる上に、適
度な湿潤性が得られ、髪の保湿性が保たれる。
また本発明による組成物は、α−オレフインス
ルホン酸塩(C)を含有するので、洗浄性がよい。そ
して塩化マグネシウムのような金属塩(E)の含有に
より上記塩(C)の微結晶析出がなくなるため、この
組成物をバスないしシヤワー用ソープとに使用し
た場合にいつまでもぬめり感の残る上記塩(C)の欠
点が克服される。またこの組成物を頭髪シヤンプ
ーとして使用した場合は、毛髪のきしみがなくな
り、マイルドな感触になる。
さらに、本発明による組成物は、脂肪酸塩(D)を
含有するので、バスなしいシヤワー用ソープとし
て使用した場合、従来のソープであれば手と手を
こすつて洗うといつまでも泡立ちぬめりがある
が、そのような現象がなくすつきりした洗い上が
りになる。
発明の効果
本発明による液体洗浄剤組成物は、白濁乳液状
の外観を呈し、長期間保存しても極めて安定であ
り、適度良好な粘稠性を保持し、しかも使用時に
はバスないしシヤワー用ソープとして泡立ちが良
く、スポンジタオルを使用しなくても普通のタオ
ルで充分泡立ちが期待できる。そして使用後はす
つきりした洗い上がりであり、ガサつく感触がな
い。また頭髪シヤンプーとしても泡立ちが良く、
毛髪のきしみがなく、湿潤効果があり、毛髪のま
とまりが良い。
実施例
つぎに、本発明の実施例について説明する。
実施例に示す部は重量部であり、%は重量%で
ある。
実施例 1
液体洗浄剤組成物の成分
(A) ポリオキシエチレンスルホコハク酸ラウリ
ルエステル・2Na塩(n=3)
2.25部(純分)
(B) ヤシ油脂肪酸アミドプロピルジメチルアミ
ノ酢酸ベタイン
2.25部(純分)
(C) 炭素数15のα−オレフインモノスルホン酸
ナトリウム(炭素数15のα−オレフインジス
ルホン酸ナトリウムおよび炭素数15のヒドロ
キシアルカンモノスルホン酸ナトリウム混
在)
9.75部(純分)
(D) ミリスチン酸カリウム
5.25部(純分)
(E) 塩化マグネシウム
3.25部(純分)
(F1) 防腐剤メチルパラベン
0.1部(純分)
(F2) 香料
適量
(G) 水
全量が100部になる量
液体洗浄剤組成物の製造
上記成分(A)(B)(C)(D)(E)(F1)を温度75℃〜80
℃で成分(G)の水に均一に溶解し、ついで成分(E)
を室温で加え、全体を均一に撹拌した後、冷却
した。温度50℃の時に成分(F2)を加え、全
体を室温まで冷却しながら撹拌した。こうして
バスないしシヤワー用ソープ組成物を作成し
た。
比較例組成物の製造
(1) 比較例1として、成分(A)の代わりに、N−
ココイル−N−メチル−β−アラニンナトリ
ウムを使用するほかは、実施例1と同様に操
作を行なつた。
(2) 比較例2として、成分(B)の代わりに、2−
アルキル−N−カルボキシエチル−N−ヒド
ロキシエチルイミダゾリウムベタインを使用
するほかは、実施例1と同様に操作を行なつ
た。
(3) 比較例3として、成分(C)の代わりに、ポリ
オキシエチレンラウリルエーテル硫酸塩を使
用するほかは、実施例1と同様に操作を行な
つた。
(4) 比較例4として、成分(D)の代わりに、ミリ
スチン酸エステルを使用するほかは、実施例
1と同様に操作を行なつた。
(5) 比較例5として、成分(E)の代わりに、塩化
アルミニウムを使用するほかは、実施例1と
同様に操作を行なつた。
比較試験
つぎに実施例1の組成物と比較例1〜5の組成
物に対し、第1表に示す項目についての物理的性
質を調べ、また第1表に示す項目についての官能
試験を行なつた。官能試験は女性20名をパネルメ
ンバーとして行ない、第1表中の数字は各項目に
ついて良いと答えた人の人数を示す。
第1表中の項目中、保存安定性は、各組成物を
それぞれ−5℃、5℃、35℃、47℃の各恒温室に
6ケ月間保存した後、各成分が分離したり、結晶
が析出した場合は不安定とし、−5℃から47℃ま
での温度範囲で状態変化がなく、適度な粘性を保
つ場合は安定とした。
また粘度は、ブルツクフイールド回転粘度計
(B型)を用いて30℃で測定し、センチポイズ
(CPS)で表示した。
また起泡力は、ロスマイルス起泡力試験器によ
つて測定し、試料10gを水で1000gに希釈した溶
液を温度40℃で起泡し、10秒後の泡の高さをmmで
表示した。
測定結果および試験結果をつぎの第1表にまと
めて示す。
INDUSTRIAL APPLICATION FIELD The present invention relates to a novel liquid detergent composition, and more specifically, as a bath or shower soap, it has particularly good foaming properties, does not make the skin squeaky, leaves a smooth finish, and leaves the skin silky and silky. To provide a liquid detergent composition for the body or hair, which leaves a feeling of touch, does not make the hair squeaky as a hair shampoo, gives a silky finish, and does not disturb the hair. Conventional technology and its problems When commonly used anionic surfactants are repeatedly used in body cleansing products such as bath and shower soaps, the skin becomes dry and slimy after use due to its strong degreasing ability. There is a feeling. Furthermore, when an anionic surfactant is used as a shampoo for hair, the foaming properties are unsatisfactory and the degreasing power is strong, so the hair becomes dry and untidy after use. Moreover, when an alpha olefin sulfonate with a low fat content is blended, the solubility at low temperatures becomes poor and small crystalline particles are formed, impairing commercial value. The present inventors have completed the present invention as a result of extensive research in order to eliminate all of these drawbacks. Means for Solving the Problems The present invention is a liquid cleaning composition comprising the following components (A) to (G). A liquid cleaning composition consisting of the following components (A) to (G); (A) polyoxyethylene sulfosuccinic acid alkyl ester represented by the general formula () (In the formula, R 1 is an alkyl group or alkenyl group having 8 to 21 carbon atoms, n is an integer of 1 to 15, and X is an alkali metal.) 0.5 to 5% by weight, (B) in the general formula () Fatty acid amidoalkyldimethylaminoacetic acid betaine shown (In the formula, R 2 means an alkyl group or an alkenyl group having 9 to 17 carbon atoms, and R 3 means an alkylene group having 1 to 6 carbon atoms, respectively.) 0.5 to 5% by weight, (C) A group having 10 to 18 carbon atoms α-olefin sulfonate 1-20% by weight, (D) C12-20 fatty acid salt 1-10% by weight, (E) Metal salt 1-10% by weight, (F) Optional additives 0-5 (G) Water 45-96% by weight. Regarding component (A), in the ester compound represented by the general formula (), the alkyl group represented by R 1 includes a capryl group, a lauryl group, a coconut oil fatty group, a beef tallow fatty group, a rimistyl group, a behenyl group, an isolauryl group. , isomyristyl group, isopalmityl group, isostearyl group, isobhenyl group, etc., and examples of the alkenyl group include oleyl group, linoleyl group, etc. The alkali metal represented by X is preferably sodium or potassium. Regarding the content of component (A), this is 0.5% by weight.
If it is below, foaming will be poor and the stability of the composition will be poor. On the other hand, if component (A) is added in an amount of 5% by weight or more, the composition will feel sticky and the stability of the composition will deteriorate. Therefore, the content of component (A) is 0.5 to 5% by weight.
limited to. The preferred content is 1-3% by weight, and the most preferred content is about 2.25% by weight. Next, regarding component (B), in the betaine compound represented by the general formula (), the group represented by R 2 CO- is capric acid, lauric acid, coconut oil fatty acid, tallow fatty acid, myristic acid, palmitic acid,
It is a residue of an acid such as stearic acid, behenic acid, isolauric acid, isomyristyrenic acid, isostearic acid, oleic acid, or linoleic acid. The alkylene group represented by R 3 includes a methylene group, an ethylene group, a propylene group, a butylene group,
Examples include isopropylene group and isobutylene group. Regarding the content of component (B), this is 0.5% by weight.
If the amount is less, the lather will be poor, the soap will not wash cleanly as a bath or shower soap, the skin will be dry, and the hair shampoo will not make the hair supple and dry. Moreover, the stability of the composition is also poor. On the other hand, if this content exceeds 5% by weight, betaine, the component (B), is an amphoteric surfactant, so it becomes sticky to the skin, making it undesirable as a shower soap without a bath or as a hair shampoo. , the stability of the composition is also poor. Therefore, the content of component (B) is 0.5 to 5
% by weight. The preferred content is 1-3% by weight, and the most preferred content is 2.25% by weight. Next, regarding component (C), α-olefin sulfonate is mainly α-olefin monosulfonate having 10 to 18 carbon atoms, and contains small amounts of α-olefin disulfonate and hydroxyalkane monosulfonate. Sometimes. If the content of component (C) is 1% by weight or less, there will be no detergency and the product will not function as a bath or shower soap or hair shampoo. On the other hand, if it contains component (C) at 20% by weight or more,
The stability of the composition deteriorates and the foaming power is lost.
Therefore, the content of component (C) is limited to 1 to 20% by weight. The preferred content is 5 to 15% by weight,
The most preferred content is 9.75% by weight. Next, regarding component (D), the fatty acid salts include lauric acid, myristic acid, palmitic acid, stearic acid, isomyristic acid, isopalmitic acid,
Examples include alkali metal salts of fatty acids such as isostearic acid, oleic acid, and linoleic acid, and salts of the above fatty acids with amines such as triethanolamine and diethanolamine. If the content of component (D) is less than 1% by weight, the soap will not foam well and will not function as a bath or shower soap or hair shampoo. On the other hand, if component (D) is contained in an amount of 10% by weight or more, the stability of the composition will be poor and foaming will be poor, so the content of component (D) is limited to 1 to 10% by weight. The preferred content is 3-8% by weight, and the most preferred content is 5.25% by weight. Examples of the metal salt (E) include hydrochloric acid or sulfate of alkali metals or alkaline earth metals such as sodium chloride, potassium chloride, magnesium chloride, calcium chloride, sodium sulfate, potassium sulfate, and magnesium sulfate. Regarding the content of metal salt (E), this is 1% by weight.
However, the stability of the composition is poor, and the usability as a bath or shower soap or hair shampoo is poor. On the other hand, if this content exceeds 10% by weight, the composition becomes gel-like, resulting in poor stability and poor foaming power. Therefore, the ingredients
The content of (E) is limited to 1 to 10% by weight. The preferred content is 2-7% by weight, and the most preferred content is 3.25% by weight. Finally, as optional additives (F), general-purpose cosmetic raw materials such as preservatives, perfumes, humectants, or nonionic activators as cleaning aids are optionally used in combination in usual amounts. Its content is 0-5% by weight. Effects Since the composition according to the present invention contains polyoxyethylene sulfosuccinic acid alkyl ester (A), it has good performance as a bath or shower soap or hair shampoo, has excellent foaming power, and has no excess It has no fat-increasing power and provides mild cleaning properties. The composition according to the invention also comprises the amphoteric surfactant fatty acid amide alkyldimethylaminoacetic acid betaine (B) and a metal salt such as magnesium chloride.
Contains (E), so these react and the pH ranges from PH5 to PH8.
In between, the foaming power increases and foaming becomes better, and moderate moisture is obtained to maintain hair's moisturizing properties. Furthermore, since the composition according to the present invention contains α-olefin sulfonate (C), it has good detergency. In addition, the inclusion of the metal salt (E) such as magnesium chloride eliminates the precipitation of microcrystals of the salt (C), so when this composition is used in bath or shower soaps, the salt (E) remains slimy forever. The disadvantage of C) is overcome. Furthermore, when this composition is used as a hair shampoo, the hair will not feel squeaky and will have a mild texture. Furthermore, since the composition according to the present invention contains a fatty acid salt (D), when used as a shower soap without a bath, conventional soaps will foam and remain slimy for a long time when you rub your hands together. , such a phenomenon is eliminated and the result is a smooth wash. Effects of the Invention The liquid cleaning composition according to the present invention has a milky milky appearance, is extremely stable even when stored for a long period of time, maintains a moderately good viscosity, and when used as a bath or shower soap. It lathers well, and you can expect it to lather well with a regular towel without using a sponge towel. And after use, it leaves a clean and smooth wash without any dry feeling. It also lathers well as a hair shampoo.
It does not make the hair squeaky, has a moisturizing effect, and makes the hair manageable. Examples Next, examples of the present invention will be described. Parts shown in the examples are parts by weight, and percentages are percentages by weight. Example 1 Components of liquid cleaning composition (A) Polyoxyethylene sulfosuccinic acid lauryl ester/2Na salt (n=3) 2.25 parts (pure) (B) Coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine 2.25 parts (pure) (C) Sodium α-olefin monosulfonate having 15 carbon atoms (mixture of sodium α-olefin disulfonate having 15 carbon atoms and sodium hydroxyalkane monosulfonate having 15 carbon atoms) 9.75 parts (pure content) (D) Myristin Potassium acid 5.25 parts (pure) (E) Magnesium chloride 3.25 parts (pure) (F1) Preservative methylparaben 0.1 part (pure) (F2) Fragrance Appropriate amount (G) Water Amount to make 100 parts Liquid detergent Manufacture of composition The above components (A) (B) (C) (D) (E) (F1) were mixed at a temperature of 75°C to 80°C.
Dissolve component (G) uniformly in water at ℃, then dissolve component (E).
was added at room temperature, the whole was stirred uniformly, and then cooled. Component (F2) was added when the temperature was 50°C, and the whole was stirred while cooling to room temperature. In this way, a bath or shower soap composition was prepared. Manufacture of Comparative Example Composition (1) As Comparative Example 1, in place of component (A), N-
The same procedure as in Example 1 was carried out except that sodium cocoyl-N-methyl-β-alanine was used. (2) As Comparative Example 2, instead of component (B), 2-
The same procedure as in Example 1 was carried out except that alkyl-N-carboxyethyl-N-hydroxyethylimidazolium betaine was used. (3) As Comparative Example 3, the same operation as in Example 1 was performed except that polyoxyethylene lauryl ether sulfate was used instead of component (C). (4) As Comparative Example 4, the same procedure as in Example 1 was carried out except that myristic acid ester was used instead of component (D). (5) As Comparative Example 5, the same operation as in Example 1 was performed except that aluminum chloride was used instead of component (E). Comparative Test Next, the composition of Example 1 and the compositions of Comparative Examples 1 to 5 were examined for physical properties with respect to the items shown in Table 1, and a sensory test was conducted with respect to the items shown in Table 1. Ta. The sensory test was conducted with 20 women as panel members, and the numbers in Table 1 indicate the number of people who responded positively to each item. Among the items in Table 1, storage stability refers to whether each component separates or crystallizes after each composition is stored in a constant temperature room at -5°C, 5°C, 35°C, and 47°C for 6 months. It was considered unstable if it precipitated, and it was considered stable if there was no change in state in the temperature range from -5°C to 47°C and a suitable viscosity was maintained. The viscosity was measured at 30°C using a Bruckfield rotational viscometer (Type B) and expressed in centipoise (CPS). Foaming power is measured using a Rossmiles foaming power tester. A solution prepared by diluting 10g of the sample to 1000g with water is foamed at a temperature of 40℃, and the height of the foam after 10 seconds is expressed in mm. did. The measurement results and test results are summarized in Table 1 below.
【表】
第1表の結果から明らかなように、実施例1の
液体洗浄剤組成物は、比較例の組成物に比較し
て、物理的性質および官能性ともに著しく優れて
いる。
実施例 2
液体洗浄剤組成物の成分
(A) ポリオキシエチレンスルホコハク酸ラウリ
ルエステル・2Na塩(n=3)
2.5部(純分)
(B) ヤシ油脂肪酸アミドプロピルジメチルアミ
ノ酢酸ベタイン
2.5部(純分)
(C) 炭素数15のα−オレフインモノスルホン酸
ナトリウム(炭素数15のα−オレフインジス
ルホン酸ナトリウムおよび炭素数15のヒドロ
キシアルカンモノスルホン酸ナトリウム混
在)
10部(純分)
(D) ヤシ油脂肪酸カリウム
5部(純分)
(E) 硫酸マグネシウム
3部(純分)
(F1) 防腐剤メチルパラベン
0.1部(純分)
(F2) 香料
適量
(G) 水
全量が100部になる量
液体洗浄剤組成物の製造
実施例1と同じ操作を行なつた。
比較例組成物の製造
(1) 比較例6として、成分(A)を使用しないほか
は、実施例2と同様に操作を行なつた。
(2) 比較例7として、成分(B)を使用しないほか
は、実施例2と同様に操作を行なつた。
(3) 比較例8として、成分(C)を使用しないほか
は、実施例2と同様に操作を行なつた。
(4) 比較例9として、成分(D)を使用しないほか
は、実施例2と同様に操作を行なつた。
(5) 比較例10として、成分(E)を使用しないほか
は、実施例2と同様に操作を行なつた。
比較試験
つぎに実施例2の組成物と比較例6〜10の組成
物に対し、第1表に示す項目について、実施例1
と同様に、比較試験を行なつた。
試験結果をつぎの第2表にまとめて示す。[Table] As is clear from the results in Table 1, the liquid detergent composition of Example 1 is significantly superior in both physical properties and organoleptic properties as compared to the composition of Comparative Example. Example 2 Components of liquid cleaning composition (A) Polyoxyethylene sulfosuccinic acid lauryl ester/2Na salt (n=3) 2.5 parts (pure) (B) Coconut oil fatty acid amidopropyldimethylaminoacetic acid betaine 2.5 parts (pure) (C) Sodium α-olefin monosulfonate having 15 carbon atoms (mixture of sodium α-olefin disulfonate having 15 carbon atoms and sodium hydroxyalkane monosulfonate having 15 carbon atoms) 10 parts (pure content) (D) Coconut Potassium oil fatty acid 5 parts (pure) (E) Magnesium sulfate 3 parts (pure) (F1) Preservative methylparaben 0.1 part (pure) (F2) Fragrance Appropriate amount (G) Water Amount to make 100 parts Liquid cleaning Preparation of agent composition The same operation as in Example 1 was performed. Manufacture of Comparative Example Composition (1) As Comparative Example 6, the same operation as in Example 2 was performed except that component (A) was not used. (2) As Comparative Example 7, the same operation as in Example 2 was performed except that component (B) was not used. (3) As Comparative Example 8, the same operation as in Example 2 was carried out except that component (C) was not used. (4) As Comparative Example 9, the same operation as in Example 2 was performed except that component (D) was not used. (5) As Comparative Example 10, the same operation as in Example 2 was carried out except that component (E) was not used. Comparative Test Next, the composition of Example 2 and the compositions of Comparative Examples 6 to 10 were tested for the items shown in Table 1.
A comparative test was conducted in the same way. The test results are summarized in Table 2 below.
【表】
第2表の結果から明らかなように、実施例2の
液体洗浄剤組成物は、比較例の組成物に比較し
て、物理的性質および官能性ともに著しく優れて
いる。
実施例 3
成分(A)の含有量を第3表に示すように変化させ
るほかは、実施例1と同様に操作を行なつた。そ
の結果を第3表に示した。[Table] As is clear from the results in Table 2, the liquid detergent composition of Example 2 is significantly superior in both physical properties and organoleptic properties as compared to the composition of Comparative Example. Example 3 The same procedure as in Example 1 was carried out except that the content of component (A) was changed as shown in Table 3. The results are shown in Table 3.
【表】
第3表から明らかなように、成分(A)の含有量は
0.5〜5%に限定され、好ましい含有量は1〜3
%、最も好ましい含有量は2.25%である。
実施例 4
成分(B)の含有量を第4表に示すように変化させ
るほかは、実施例1と同様に操作を行なつた。そ
の結果を第4表に示した。[Table] As is clear from Table 3, the content of component (A) is
Limited to 0.5-5%, preferred content is 1-3
%, the most preferred content is 2.25%. Example 4 The same procedure as in Example 1 was carried out except that the content of component (B) was changed as shown in Table 4. The results are shown in Table 4.
【表】
第4表から明らかなように、成分(B)の含有量は
0.5〜5%に限定され、好ましい含有量は1〜3
%、最も好ましい含有量は2.25%である。
実施例 5
成分(C)の含有量を第5表に示すように変化させ
るほかは、実施例1と同様に操作を行なつた。そ
の結果を第5表に示した。[Table] As is clear from Table 4, the content of component (B) is
Limited to 0.5-5%, preferred content is 1-3
%, the most preferred content is 2.25%. Example 5 The same procedure as in Example 1 was carried out except that the content of component (C) was changed as shown in Table 5. The results are shown in Table 5.
【表】
第5表から明らかなように、成分(C)の含有量は
1〜20%に限定され、好ましい含有量は5〜15
%、最も好ましい含有量は9.75%である。
実施例 6
成分(D)の含有量を第6表に示すように変化させ
るほかは、実施例1と同様に操作を行なつた。そ
の結果を第6表に示した。[Table] As is clear from Table 5, the content of component (C) is limited to 1 to 20%, and the preferred content is 5 to 15%.
%, the most preferred content is 9.75%. Example 6 The same procedure as in Example 1 was carried out except that the content of component (D) was changed as shown in Table 6. The results are shown in Table 6.
【表】
第6表から明らかなように、成分(D)の含有量は
1〜10%に限定され、好ましい含有量は3〜8
%、最も好ましい含有量は5.75%である。
実施例 7
成分(E)の含有量を第7表に示すように変化させ
るほかは、実施例1と同様に操作を行なつた。そ
の結果を第7表に示した。[Table] As is clear from Table 6, the content of component (D) is limited to 1 to 10%, and the preferred content is 3 to 8%.
%, the most preferred content is 5.75%. Example 7 The same procedure as in Example 1 was carried out except that the content of component (E) was changed as shown in Table 7. The results are shown in Table 7.
【表】
第7表から明らかなように、成分(E)の含有量は
1〜10%に限定され、好ましい含有量は2〜7
%、最も好ましい含有量は3.75%である。
比較例 11
一般式()で示される成分としてn=20のポ
リオキシエチレンスルホコハク酸アルキルエステ
ルを用いて実施例1と同様の操作で組成物を得
た。この組成物は保存安定性が良くなく、起泡力
も100以下であつた。
比較例 12
一般式()で示される成分としてR3=オク
チレンの脂肪酸アミドアルキルジメチルアミノ酢
酸ベタインを用いて実施例1と同様の操作で組成
物を得た。この組成物は保存安定性が良くなく、
起泡力を100以下であつた。[Table] As is clear from Table 7, the content of component (E) is limited to 1 to 10%, and the preferred content is 2 to 7%.
%, the most preferred content is 3.75%. Comparative Example 11 A composition was obtained in the same manner as in Example 1 using polyoxyethylene sulfosuccinic acid alkyl ester with n=20 as the component represented by the general formula (). This composition had poor storage stability and foaming power of less than 100. Comparative Example 12 A composition was obtained in the same manner as in Example 1 using R 3 =octylene fatty acid amide alkyldimethylaminoacetic acid betaine as the component represented by the general formula (). This composition has poor storage stability;
The foaming power was 100 or less.
Claims (1)
スルホコハク酸アルキルエステル (式中、R1は炭素数8〜21のアルキル基また
はアルケニル基、nは1〜15の整数、Xはアル
カリ金属をそれぞれ意味する) 0.5〜5重量%、 (B) 一般式()で示される脂肪酸アミドアルキ
ルジメチルアミノ酢酸ベタイン (式中、R2は炭素数9〜17のアルキル基また
はアルケニル基、R3は炭素数1〜6のアルキ
レン基をそれぞれ意味する) 0.5〜5重量%、 (C) 炭素数10〜18のα−オレフインスルホン酸塩 1〜20重量%、 (D) 炭素数12〜20の脂肪酸塩 1〜10重量%、 (E) 金属塩 1〜10重量%、 (F) 任意の添加剤 0〜5重量%、 (G) 水 45〜96重量%。[Scope of Claims] 1. A liquid cleaning composition comprising the following components (A) to (G); (A) a polyoxyethylene sulfosuccinic acid alkyl ester represented by the general formula (); (In the formula, R 1 is an alkyl group or alkenyl group having 8 to 21 carbon atoms, n is an integer of 1 to 15, and X is an alkali metal.) 0.5 to 5% by weight, (B) in the general formula () Fatty acid amidoalkyldimethylaminoacetic acid betaine shown (In the formula, R 2 means an alkyl group or an alkenyl group having 9 to 17 carbon atoms, and R 3 means an alkylene group having 1 to 6 carbon atoms, respectively.) 0.5 to 5% by weight, (C) A group having 10 to 18 carbon atoms α-olefin sulfonate 1-20% by weight, (D) C12-20 fatty acid salt 1-10% by weight, (E) Metal salt 1-10% by weight, (F) Optional additives 0-5 (G) Water 45-96% by weight.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20982987A JPH0248523B2 (en) | 1987-08-24 | 1987-08-24 | EKITAISENJOZAISOSEIBUTSU |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP20982987A JPH0248523B2 (en) | 1987-08-24 | 1987-08-24 | EKITAISENJOZAISOSEIBUTSU |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS6452712A JPS6452712A (en) | 1989-02-28 |
JPH0248523B2 true JPH0248523B2 (en) | 1990-10-25 |
Family
ID=16579307
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP20982987A Expired - Lifetime JPH0248523B2 (en) | 1987-08-24 | 1987-08-24 | EKITAISENJOZAISOSEIBUTSU |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH0248523B2 (en) |
Families Citing this family (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH01146814A (en) * | 1987-12-02 | 1989-06-08 | Sunstar Inc | Cleaning agent composition |
JP2775154B2 (en) * | 1988-04-26 | 1998-07-16 | 株式会社資生堂 | Anti-skin and anti-aging agents |
DE19754842A1 (en) * | 1997-12-10 | 1999-06-17 | Clariant Gmbh | Pearlescent formulation with surfactant |
JP5875827B2 (en) * | 2011-10-12 | 2016-03-02 | 花王株式会社 | Dishwashing composition for hand washing |
-
1987
- 1987-08-24 JP JP20982987A patent/JPH0248523B2/en not_active Expired - Lifetime
Also Published As
Publication number | Publication date |
---|---|
JPS6452712A (en) | 1989-02-28 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JPS62190298A (en) | Mild oxo-derivative surfactant admixture | |
JP3079158B2 (en) | Detergent composition | |
JPH0248523B2 (en) | EKITAISENJOZAISOSEIBUTSU | |
JP3622267B2 (en) | Cleaning composition | |
JP2002020786A (en) | Creamy detergent composition | |
JP3620140B2 (en) | Liquid detergent composition for skin | |
JPH06116135A (en) | Skin detergent composition | |
JP3377064B2 (en) | Detergent composition | |
JPH08134494A (en) | Detergent composition | |
JP2839897B2 (en) | Skin cleansing composition | |
JP2001019632A (en) | Weakly acidic skin cleansing preparation | |
JPH1143698A (en) | Detergent composition | |
JP2002179553A (en) | Skin cleansing composition | |
JP2019077642A (en) | Creamy skin cleanser | |
JP3444572B2 (en) | Detergent composition | |
JPH0816240B2 (en) | Liquid detergent composition having a pearl-like appearance | |
JP2529865B2 (en) | Skin cleanser composition | |
JPH0361720B2 (en) | ||
JP2630526B2 (en) | Detergent composition | |
JPH0320213A (en) | Liquid detergent composition for body cleaning | |
JP3087398B2 (en) | Detergent composition | |
JP2000119698A (en) | Foam quality-improving agent | |
JP3412874B2 (en) | Detergent composition | |
JP3977718B2 (en) | Cleaning composition | |
JPH0782589A (en) | Detergent composition |