JPH0231048B2 - KANONSEIMOHATSUHATSUSHOKUZAI - Google Patents

KANONSEIMOHATSUHATSUSHOKUZAI

Info

Publication number
JPH0231048B2
JPH0231048B2 JP30796587A JP30796587A JPH0231048B2 JP H0231048 B2 JPH0231048 B2 JP H0231048B2 JP 30796587 A JP30796587 A JP 30796587A JP 30796587 A JP30796587 A JP 30796587A JP H0231048 B2 JPH0231048 B2 JP H0231048B2
Authority
JP
Japan
Prior art keywords
hair
temperature
sensitive
liquid crystal
color
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
JP30796587A
Other languages
Japanese (ja)
Other versions
JPH01149712A (en
Inventor
Toshihiko Sugimachi
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Individual
Original Assignee
Individual
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Individual filed Critical Individual
Priority to JP30796587A priority Critical patent/JPH0231048B2/en
Publication of JPH01149712A publication Critical patent/JPH01149712A/en
Publication of JPH0231048B2 publication Critical patent/JPH0231048B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Description

【発明の詳細な説明】 産業上の利用分野 本発明は、毛髪に塗布して使用し、所望の温度
域で発色するようにした感温性毛髪発色剤に関す
る。
DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a temperature-sensitive hair coloring agent that is used by applying to hair and develops color in a desired temperature range.

従来技術と問題点 一般に毛髪を彩色する手段として、毛髪を染め
る、植物性,鉱物性及び合成有機薬品の三種の染
毛剤が用いられている。
Prior Art and Problems Generally, three types of hair dyes are used to color hair: vegetable, mineral, and synthetic organic chemicals.

これ等は何れも、繁雑な髪を染める作業が必要
であり、一旦染めあげると、脱色が容易でないば
かりか、毛髪を傷めやすい欠点がある。又一旦染
めると常時同色に発色した状態にあり復色と発色
機能を期待することはできない。
All of these methods require complicated hair dyeing work, and once dyed, they not only are not easy to bleach, but also have the disadvantage that they tend to damage the hair. Furthermore, once dyed, the color remains the same all the time, and color recovery and color development cannot be expected.

又染毛と異なり、装飾の目的で一時的に毛髪に
着色剤を付着させる方法(カラーリンス)もある
が、これは酒石酸又はクエン酸の酸性水溶液を用
いて着色するもので、予め過酸化水素で毛髪を漂
白せねばならず、復色することが困難であるばか
りか、毛髪を著しく傷める欠点がある。又染毛剤
と同様、環境によつて発色と復色する機能を有し
ていない。
Also, unlike hair dyeing, there is a method of temporarily attaching a coloring agent to the hair for decoration purposes (color rinse), but this method uses an acidic aqueous solution of tartaric acid or citric acid to color the hair. Not only is it difficult to restore the color because the hair must be bleached, but it also has the drawback of significantly damaging the hair. Also, like hair dye, it does not have the ability to develop or restore color depending on the environment.

問題点を解決するための手段 而て本発明は上記従来例における各問題を一掃
し、簡単且つ迅速に所望の色を所望の温度域で発
色するようにし、しかも毛髪を傷めることなく手
軽に塗布して使用できる、又復色も容易に行なえ
るようにした感温性毛髪発色剤を提供せんとする
ものであつて、その手段として、感温発色する液
晶の特徴を利用し、該感温液晶を整髪料と混合し
て感温性毛髪発色剤を構成し、上記目的を達成す
るようにしたものである。
Means for Solving the ProblemsThe present invention eliminates each of the problems in the conventional examples described above, allows a desired color to be easily and quickly developed in a desired temperature range, and can be easily applied without damaging the hair. The purpose of the present invention is to provide a temperature-sensitive hair coloring agent that can be used as a hair coloring agent and that can be easily restored. A temperature-sensitive hair coloring agent is prepared by mixing liquid crystal with a hair styling agent to achieve the above object.

作 用 本発明は、ポマード等の整髪料を用いるのと同
様、櫛やへら等を用いて単に塗布するのみで手軽
に使用でき、所望の温度域で感温発色及び復色を
行なわせることができ、例えば室外では地色の黒
髪状態を保ち、室内では自然発色を促すことがで
きるようにしたものである。又上記発色,復色機
能を具備させつつ整髪料としての機能を併有させ
ることができる。
Effects The present invention can be easily used by simply applying it with a comb or spatula, similar to using hair styling products such as pomade, and can perform temperature-sensitive color development and color recovery in a desired temperature range. For example, it is possible to maintain the natural black color of hair outdoors, while promoting natural color development indoors. In addition, it can have the above-mentioned coloring and color restoring functions and also function as a hair styling product.

又従来のように地肌や毛髪を傷めることがな
く、予め毛髪を漂白する等の予備処理を要するこ
となく、利用者が手軽に用いることができ、処理
が簡単且つ迅速に行なえる。
In addition, unlike conventional methods, it does not damage the skin or hair, does not require pre-treatment such as bleaching the hair, and can be easily used by the user, and the treatment can be performed simply and quickly.

実施例 以下本発明の実施例について説明する。Example Examples of the present invention will be described below.

既述の如く本発明は、所望の温度域に達すると
感温発色する液晶の特徴を利用し、感温液晶と整
髪料とを混合して感温性毛髪発色剤を形成するも
のである。
As described above, the present invention takes advantage of the characteristic of liquid crystals that develop temperature-sensitive color when a desired temperature range is reached, and forms a temperature-sensitive hair coloring agent by mixing temperature-sensitive liquid crystals and hair styling products.

該感温液晶として、各種のコレステリツク液晶
(コレステロールの誘導体)を用いる。該コレス
テリツク液晶は、同コレステリツク液晶単品を3
〜7種配合することにより、各種発色の温度域及
び温度巾を調整することができる。
Various cholesteric liquid crystals (derivatives of cholesterol) are used as the temperature-sensitive liquid crystal. The cholesteric liquid crystal consists of 3 pieces of cholesteric liquid crystal.
By blending ~7 types, the temperature range and temperature width of various color development can be adjusted.

その具体的配合例は下記の通りである。 A specific example of the formulation is as follows.

第1配合例 (重量比) コレステリル ノナノエート 59% コレステリル オレイルカーボネート 4% コレステリル ブチレート 17% コレステリル リノレート 20% 発色温度 23→31℃ 第2配合例 コレステリル オレエート 81% コレステリル プロピオネート 19% 発色温度 25→30℃ 第3配合例 コレステリル ノナノエート 70% コレステリル オレイルカーボネート 5% コレステリル ブチレート 20% コレステリル リノレート 25% 発色温度 20→27℃ 以上の他、コレステリツク液晶としては、コレ
ステリル オクタノエート、コレステリル デカ
ノエート、コレステリル アセテート、コレステ
リル クロライド コレステリル ブロマイド、
コレステリル イソステアリルカーボネート等が
掲げられ、これらを適宜配合して用いる。
1st formulation example (weight ratio) Cholesteryl nonanoate 59% Cholesteryl oleyl carbonate 4% Cholesteryl butyrate 17% Cholesteryl linoleate 20% Coloring temperature 23→31℃ 2nd formulation example Cholesteryl oleate 81% Cholesteryl propionate 19% Coloring temperature 25→30℃ 3 formulation examples Cholesteryl nonanoate 70% Cholesteryl oleyl carbonate 5% Cholesteryl butyrate 20% Cholesteryl linoleate 25% Color development temperature 20→27℃ In addition to the above, cholesteric liquid crystals include cholesteryl octanoate, cholesteryl decanoate, cholesteryl acetate, cholesteryl chloride, cholesteryl bromide,
Cholesteryl isostearyl carbonate and the like are listed, and these are appropriately blended and used.

次に上記配合例に従い配合されたコレステリツ
ク液晶に酸化防止剤を添加して耐久性を高める。
Next, an antioxidant is added to the cholesteric liquid crystal compounded according to the above formulation example to increase durability.

更に該コレステリツク液晶の発色を長時間持続
させるため、同液晶を化学的汚染(結晶化,酸
化)、物理的損傷から保護する必要があり、その
手段として、ゼラチン水溶液の中に該コレステリ
ツク液晶を10〜20μmの大きさで乳化させ、これ
にアラビアゴム水溶液を加え、PH,温度を調整し
て相分離と呼ぶ物理化学的現象を起こさせ、液晶
滴の周りにゼラチンの膜を形成してカプセル化す
る。
Furthermore, in order to maintain the color development of the cholesteric liquid crystal for a long time, it is necessary to protect the liquid crystal from chemical contamination (crystallization, oxidation) and physical damage. Emulsify it to a size of ~20 μm, add an aqueous gum arabic solution, adjust the pH and temperature to cause a physicochemical phenomenon called phase separation, and form a gelatin film around the liquid crystal droplets to encapsulate them. do.

次に、該カプセル化されたコレステリツク液晶
を10℃以下の温度条件下でグルタールアルデヒド
を小量加えてこれと一定時間反応させ、一週間程
度熟成させ、感温液晶マイクロカプセルスラリー
を得る。
Next, the encapsulated cholesteric liquid crystal is reacted with a small amount of glutaraldehyde at a temperature of 10° C. or less for a certain period of time, and then aged for about one week to obtain a temperature-sensitive liquid crystal microcapsule slurry.

このスラリーの成分は下記の通りである。 The components of this slurry are as follows.

液晶分 22%(重量比) 壁材分 3% 水 分 75% スラリーPH 4.5〜5.0 上記スラリーは、コレステリツク液晶の各配合
例において温度が高温に移行するに伴い、赤,
緑,青の発色を行なう。
Liquid crystal content 22% (weight ratio) Wall material content 3% Moisture 75% Slurry PH 4.5-5.0 The above slurry becomes red, red,
Develops green and blue colors.

更に上記感温液晶マイクロカプセルスラリーを
濾過し、水分を50%程度除去し、これを後記する
ポマード等の整髪料と混合し、目的の発色剤を得
る。
Furthermore, the temperature-sensitive liquid crystal microcapsule slurry is filtered to remove about 50% of the water content, and this is mixed with a hair styling product such as a pomade described later to obtain the desired coloring agent.

上記混合比率を、 感温液晶マイクロカプセルスラリー:整髪料= 30〜70 :70〜30 とし、好ましくは50:50程度とする。 The above mixing ratio is Temperature-sensitive liquid crystal microcapsule slurry: Hair conditioner = 30-70: 70-30 The ratio is preferably about 50:50.

他方、上記感温液晶マイクロカプセルスラリー
と混合される整髪料としては、毛髪に対し常粘性
と常湿性を有する、例えばポマード(ポマードそ
のもの或はその主成分を用いる)、好ましくは水
性を付与したポマードが代表例として掲げられ
る。
On the other hand, the hair styling product to be mixed with the temperature-sensitive liquid crystal microcapsule slurry is a pomade that has normal viscosity and normal humidity for hair, such as a pomade (using the pomade itself or its main component), preferably a pomade that has aqueous properties. is cited as a representative example.

該ポマードの成分は下記の通りである。 The components of the pomade are as follows.

植物性ポマード ヒマシ油、モクロウ、香料、酸化防止剤。vegetable pomade Castor oil, Japanese oak, fragrance, antioxidants.

鉱物性ポマード ワセリン、パラフイン、流動パラフイン、香
料。
Mineral pomade Vaseline, paraffin, liquid paraffin, fragrance.

又ポマードの他、密ロウ、ヒマシ油、モクロ
ウ、香料を成分とするチツクも利用可能である。
更に密ロウ、流動パラフイン、ステアリン酸、界
面活性剤、香料、防腐剤、酸化防止剤、精製水を
成分とするヘアクリームの適用も可能である。
In addition to pomade, ticks containing beeswax, castor oil, Japanese wax, and fragrance can also be used.
Furthermore, it is also possible to apply hair creams containing beeswax, liquid paraffin, stearic acid, surfactants, fragrances, preservatives, antioxidants, and purified water.

これらポマード及びチツク並びにヘアクリーム
は油脂(ワセリン、ヒマシ油、流動パラフイン
等)を主成分とし、これらの主成分と上記感温液
晶マイクロカプセルスラリーを混合するほか、他
の各種の油脂と感温液晶マイクロカプセルスラリ
ーとの混合物によつて組成しても良い。
These pomades, ticks, and hair creams have oils and fats (petrolatum, castor oil, liquid paraffin, etc.) as their main ingredients, and these main ingredients are mixed with the temperature-sensitive liquid crystal microcapsule slurry, as well as various other oils and fats and temperature-sensitive liquid crystals. It may also be composed by a mixture with a microcapsule slurry.

上記の如くして得られた感温性毛髪発色剤はバ
ツクが黒、即ち黒髪である場合に所定の温度領域
で発色する性質を有する。従つて同発色剤は、毛
髪が黒であることを利用して創意されたものであ
る。
The temperature-sensitive hair coloring agent obtained as described above has a property of developing color in a predetermined temperature range when the background is black, that is, black hair. Therefore, the coloring agent was created by taking advantage of the fact that hair is black.

ポマード等を感温液晶と混合する整髪料として
用いた場合は、櫛やへらにて適量を毛髪に付着
し、引き延ばすだけで良い。又チツクを整髪料と
して用いた場合には直接塗布すれば良い。
When pomade or the like is used as a hair styling product mixed with temperature-sensitive liquid crystal, it is sufficient to simply apply an appropriate amount to the hair with a comb or spatula and stretch it out. In addition, when using the chick as a hair conditioner, it may be applied directly.

発明の効果 以上説明した通り、本発明に係る感温性毛髪発
色剤は、ポマード等の整髪料を用いるのと同様、
櫛やへら等を用いて毛髪に単に塗布するのみで手
軽に使用でき、所望の温度域で感温発色と復色
(黒髪色)を行なわせることができ、例えば室外
では地色の黒髪状態を保ち、室内では自然発色を
促すことができるものである。又上記発色,復色
機能を具備させつつ整髪料としての機能を併有さ
せることができる。
Effects of the Invention As explained above, the temperature-sensitive hair coloring agent according to the present invention can be used in the same way as hair styling products such as pomade.
It can be easily used by simply applying it to the hair using a comb or spatula, and it can perform temperature-sensitive color development and color restoration (black hair color) in the desired temperature range. It can be maintained and promote natural color development indoors. In addition, it can have the above-mentioned coloring and restoring functions and also function as a hair styling product.

又従来のように地肌や毛髪を傷めることがな
く、予め毛髪を漂白する等の予備処理を要するこ
となく、利用者が手軽に用いることができ、処理
が簡単且つ迅速に行なえる利点がある。
In addition, unlike conventional methods, this method does not damage the skin or hair, does not require preliminary treatment such as bleaching the hair, and can be easily used by the user, and has the advantage that the treatment can be performed simply and quickly.

Claims (1)

【特許請求の範囲】 1 感温液晶と整髪料とを混合して成る感温性毛
髪発色剤。 2 上記感温液晶と整髪料を30〜70対70〜30の比
率で混合して成る特許請求の範囲第1項記載の感
温性毛髪発色剤。
[Scope of Claims] 1. A temperature-sensitive hair coloring agent made by mixing a temperature-sensitive liquid crystal and a hair styling agent. 2. The temperature-sensitive hair coloring agent according to claim 1, which is obtained by mixing the temperature-sensitive liquid crystal and the hair styling product in a ratio of 30 to 70:70 to 30.
JP30796587A 1987-12-05 1987-12-05 KANONSEIMOHATSUHATSUSHOKUZAI Expired - Lifetime JPH0231048B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP30796587A JPH0231048B2 (en) 1987-12-05 1987-12-05 KANONSEIMOHATSUHATSUSHOKUZAI

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP30796587A JPH0231048B2 (en) 1987-12-05 1987-12-05 KANONSEIMOHATSUHATSUSHOKUZAI

Publications (2)

Publication Number Publication Date
JPH01149712A JPH01149712A (en) 1989-06-12
JPH0231048B2 true JPH0231048B2 (en) 1990-07-11

Family

ID=17975297

Family Applications (1)

Application Number Title Priority Date Filing Date
JP30796587A Expired - Lifetime JPH0231048B2 (en) 1987-12-05 1987-12-05 KANONSEIMOHATSUHATSUSHOKUZAI

Country Status (1)

Country Link
JP (1) JPH0231048B2 (en)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US7135168B2 (en) * 2002-09-10 2006-11-14 Revlon Consumer Products Corporation Hair color compositions and methods for coloring hair

Also Published As

Publication number Publication date
JPH01149712A (en) 1989-06-12

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