JPH02280893A - Method for immobilizing nitrifying bacteria and water purifying treatment - Google Patents

Method for immobilizing nitrifying bacteria and water purifying treatment

Info

Publication number
JPH02280893A
JPH02280893A JP10133489A JP10133489A JPH02280893A JP H02280893 A JPH02280893 A JP H02280893A JP 10133489 A JP10133489 A JP 10133489A JP 10133489 A JP10133489 A JP 10133489A JP H02280893 A JPH02280893 A JP H02280893A
Authority
JP
Japan
Prior art keywords
nitrifying bacteria
beads
water
added
activated carbon
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP10133489A
Other languages
Japanese (ja)
Inventor
Akira Matsunaga
松永 旭
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Meidensha Corp
Meidensha Electric Manufacturing Co Ltd
Original Assignee
Meidensha Corp
Meidensha Electric Manufacturing Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Meidensha Corp, Meidensha Electric Manufacturing Co Ltd filed Critical Meidensha Corp
Priority to JP10133489A priority Critical patent/JPH02280893A/en
Publication of JPH02280893A publication Critical patent/JPH02280893A/en
Pending legal-status Critical Current

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  • Immobilizing And Processing Of Enzymes And Microorganisms (AREA)

Abstract

PURPOSE:To prepare immobilized nitrifying bacteria for water purifying treatment by adding powdery activated carbon and highly water-absorbable resin to a concn. solution of nitrifying bacteria resulting from the selective culture of activated sludge to form swollen heads and adding calcium chloride to said beads to subject the beads to secondary crosslinking. CONSTITUTION:Selection culture 2 is performed in a medium for nitrifying bacteria based on ammonium sulfide using the activated sludge 1 of a service water treatment plant as sead bacteria and the culture solution is centrifugally separated to exclude a supernatant liquid 5 to obtain a nitrifying bacteria conc. solution 4. Powdery activated carbon is added to 1l of this conc. solution in an activated carbon adding step 6 and 10-20g of a highly water-soluble resin is added thereto under stirring in a highly water-absorbable resin adding step 7 to obtain swollen beads. At this time, nitrifying bacteria are held in the swollen resin along with activated carbon. Next, 2g of calcium chloride is added to the beads to perform stirring for about 20min and the beads are subjected to secondary crosslinking to enhance the water retaining capacity thereof and subsequently washed in a washing step 9 to be gathered in a beads (immobilized nitrifying bacteria) collection process 10 to obtain immobilized nitrifying bacteria for biological treatment of raw service water.

Description

【発明の詳細な説明】 A、産業上の利用分野 本発明は、浄水に用いる硝化菌固定化方法と浄水処理方
法に関する。
DETAILED DESCRIPTION OF THE INVENTION A. Field of Industrial Application The present invention relates to a method for immobilizing nitrifying bacteria and a water purification treatment method for use in water purification.

39発明の概要 請求項(1)の発明は、選択培養した硝化菌を濃縮した
液に粉末活性炭を添加し、撹拌しながら高吸性樹脂を添
加して膨潤したビーズに塩化カルシウムを添加して2次
架橋することにより硝化菌を固定するようにしたもので
ある。
39 Summary of the Invention The invention of claim (1) is based on the method of adding powdered activated carbon to a concentrated solution of selectively cultured nitrifying bacteria, adding a superabsorbent resin while stirring, and adding calcium chloride to the swollen beads. Nitrifying bacteria are immobilized by secondary crosslinking.

請求項(2)の発明は、急速濾過システムの前段に請求
項(1)の方法で得た固定化硝化菌を用いた固定化硝化
処理装置を設けて、アンモニアを硝化して後、急速濾過
するものである。
The invention of claim (2) provides a fixed nitrification treatment device using the fixed nitrifying bacteria obtained by the method of claim (1) upstream of the rapid filtration system, and after nitrifying ammonia, performs rapid filtration. It is something to do.

C1従来の技術 わが国においては、水道の需要は年々増加しているが、
供給能力には限界があり、地下水のような良質の水源が
得がたくなってきている。そのため、河川の表流水を水
源とすることが多くなっており、異臭味やトリハロメタ
ン生成などの問題を生じている。一方、美味な水に対す
る国民のニーズが高まっており、現在より高度な浄水処
理が要求されている。既存の浄水処理方式で主流を占め
ている急速濾過システムは水中の濁質の除去と殺菌が主
体であって溶解物質の除去にはあまり有効ではない。異
臭味やトリハロメタンは溶解性有機物に由来するもので
あり、これらを減少させるためには溶解性有機物の除去
能力を高める必要かある。
C1 Conventional technology In Japan, the demand for water supply is increasing year by year.
Supply capacity is limited, and high-quality water sources such as groundwater are becoming difficult to obtain. For this reason, surface water from rivers is increasingly used as a water source, causing problems such as off-flavors and trihalomethane formation. On the other hand, the public's need for delicious water is increasing, and more advanced water purification treatment is currently required. Rapid filtration systems, which are the mainstream of existing water purification methods, mainly remove suspended matter and sterilize water, and are not very effective in removing dissolved substances. Off-flavors and trihalomethanes are derived from soluble organic substances, and in order to reduce these, it is necessary to increase the ability to remove soluble organic substances.

トリハロメタンはアンモニアの除去と殺菌を目的とした
塩素処理の過程において有機物と塩素反応により生成す
るものであるが原水中のアンモニア濃度が高い場合、必
然的に塩素注入量が多くなり、トリハロメタンの生成量
が増加する。
Trihalomethane is produced by the reaction of organic matter with chlorine during the chlorination process for the purpose of removing ammonia and sterilizing it. However, if the ammonia concentration in raw water is high, the amount of chlorine injected will inevitably increase, and the amount of trihalomethane produced will increase. increases.

このため、アンモニアや有機物濃度の高い原水に対して
は塩素注入の前段階において、これらを除去するプロセ
スとして生物活性炭処理や生物酸化処理が行われている
For this reason, biological activated carbon treatment and biological oxidation treatment are performed on raw water with high concentrations of ammonia and organic matter as a process to remove them before chlorine injection.

D0発明が解決しようとする課題 ところが、生物酸化処理は、冬季水温低下時に、アンモ
ニアを硝化する作用のある硝化菌が独立栄養菌であって
増殖速度が小さく、低温下で硝化活性が低下するため、
アンモニアを硝化する能力が低下する。
Problems to be solved by the D0 invention However, in biological oxidation treatment, when the water temperature drops in winter, the nitrifying bacteria that have the effect of nitrifying ammonia are autotrophic bacteria, have a slow growth rate, and their nitrification activity decreases at low temperatures. ,
The ability to nitrify ammonia is reduced.

本発明は、従来の技術の有するこのような問題点に鑑み
てなされたものであり、その目的とするところは、アン
モニアの硝化能力が向上するように高濃度の硝化菌を固
定化する硝化菌固定化方法と、この方法で得た固定化硝
化菌を用いた固定化硝化装置によりアンモニアの硝化能
力を高め、硝化処理後、急速濾過するようにして、急速
濾過における塩素投入量を減少させることのできる浄水
処理方法を提供することにある。
The present invention has been made in view of the above-mentioned problems of the conventional technology, and its purpose is to immobilize nitrifying bacteria at a high concentration so as to improve the nitrifying ability of ammonia. To increase the nitrification ability of ammonia by using an immobilization method and an immobilization nitrification device using immobilized nitrifying bacteria obtained by this method, and to perform rapid filtration after nitrification treatment, thereby reducing the amount of chlorine input in rapid filtration. The purpose of this invention is to provide a water purification method that allows for

81課題を解決するための手段 上記目的を達成するために、本発明の硝化菌固定化方法
は、活性汚泥を選択培養した硝化菌を渦縮し、この濃縮
液に粉末活性炭を添加して撹拌しながら高吸水性樹脂を
添加して膨澗したビーズとし、このビーズに塩化カルシ
ウムを添加して2次架橋することにより硝化菌を固定化
するものである。
81 Means for Solving the Problems In order to achieve the above object, the method for immobilizing nitrifying bacteria of the present invention involves vortexing activated sludge with selectively cultured nitrifying bacteria, adding powdered activated carbon to this concentrate, and stirring. Meanwhile, a super absorbent resin is added to form swollen beads, and calcium chloride is added to the beads for secondary crosslinking, thereby immobilizing nitrifying bacteria.

また、浄水処理方法は、急速濾過装置の前段にアンモニ
アを硝化する請求項(1)の硝化菌固定化方法にて得た
固定化硝化菌を用いた固定化硝化処理装置を設け、原水
を硝化処理後、急速濾過を行うにうよしたものである。
In addition, the water purification treatment method includes installing an immobilized nitrification treatment device using immobilized nitrifying bacteria obtained by the nitrifying bacteria immobilization method of claim (1) for nitrifying ammonia in the front stage of the rapid filtration device, and nitrifying raw water. After treatment, rapid filtration is recommended.

F1作用 硝化菌固定化方法 活性汚泥を硝化菌培地で選択培養し、遠心分離又は自然
沈降させることにより濃縮液を得る。この濃縮液に活性
炭添加し、撹拌しながら高吸水性樹脂を添加することに
より膨澗したビーズを得る。
Method for immobilizing F1-acting nitrifying bacteria Activated sludge is selectively cultured in a nitrifying bacteria medium, and a concentrated solution is obtained by centrifugation or natural sedimentation. Activated carbon is added to this concentrated solution, and a superabsorbent resin is added while stirring to obtain swollen beads.

これに塩化カルシウムを添加することにより2次架橋の
ビーズ、即ち高濃度の硝化菌を固定化した固定化硝化菌
を得ることができる。
By adding calcium chloride to this, it is possible to obtain secondary crosslinked beads, that is, immobilized nitrifying bacteria in which a high concentration of nitrifying bacteria is immobilized.

浄水処理方法 急速濾過装置の前段に硝化菌固定化方法で得た高1度の
固定化硝化菌を用いた固定化硝化処理装置を設け、高濃
度の固定化硝化菌によりアンモニアの硝化処理を行うの
で、硝化能力が向上し、低温でもアンモニアを硝化処理
することができる急速濾過装置はアンモニアが硝化され
た原水を浄水処理するため、塩素の投入量を少なくする
ことができる。このため、人体に有害なトリハロメタン
の発生が減少する。
Water purification treatment method A fixed nitrification treatment device using high-1 degree fixed nitrifying bacteria obtained by the nitrifying bacteria immobilization method is installed in front of the rapid filtration device, and ammonia nitrification is performed using a high concentration of immobilized nitrifying bacteria. Therefore, a rapid filtration device that has improved nitrification ability and can nitrify ammonia even at low temperatures purifies raw water in which ammonia has been nitrified, making it possible to reduce the amount of chlorine input. Therefore, the generation of trihalomethane, which is harmful to the human body, is reduced.

G、実施例 本発明の実施例について図面を参照して説明する。G. Example Embodiments of the present invention will be described with reference to the drawings.

先ず、第1図において、硝化菌の高濃化と固定化の方法
を説明する。
First, referring to FIG. 1, a method for highly concentrating and immobilizing nitrifying bacteria will be explained.

上水処理場の活性汚泥1を種菌として硫化アンモニウム
を主体とする硝化菌用培地で選択培養2を行い、培養液
を遠心分離又は自然沈降して上澄液5を排除して硝化菌
濃縮液4を得る。この濃縮液1eに対して粉末活性炭適
量添加6して撹拌を行いつつ高吸水性樹脂(商品名アラ
ソーブ)10〜20gを添加7して膨潤したビーズとす
る。高吸水性樹脂は水を吸収して膨潤し、膨潤後に外力
を加えても水を放出しに(い性質を有しているので、硝
化菌は活性炭と共に膨潤した樹脂内に保持される。次に
塩化カルシウム2gを添加して約20分撹拌を行い、2
次架橋することによりビーズの保水能力を高める。最後
に水洗9をしてから、ビーズを集めてlO上水道原水の
生物処理用固定化硝化菌とする。
Selective culture 2 is performed using activated sludge 1 from a water treatment plant as a seed culture in a nitrifying bacteria medium mainly containing ammonium sulfide, and the culture solution is centrifuged or allowed to settle naturally to remove the supernatant 5 to obtain a nitrifying bacteria concentrate. Get 4. To this concentrated liquid 1e, an appropriate amount of powdered activated carbon is added 6, and while stirring, 10 to 20 g of a super absorbent resin (trade name Arasorb) is added 7 to form swollen beads. Super absorbent resin absorbs water and swells, and after swelling, it does not release water even when external force is applied. Therefore, nitrifying bacteria are retained in the swollen resin together with activated carbon.Next Add 2g of calcium chloride to the solution and stir for about 20 minutes.
The water retention capacity of the beads is increased by subsequent crosslinking. Finally, after washing with water 9, the beads are collected and used as immobilized nitrifying bacteria for biological treatment of lO water supply raw water.

次に、第2図について、上水処理方法について説明する
Next, the water treatment method will be explained with reference to FIG.

第2図において、11はエアレージジン装置を備えた上
記固定化硝化菌を詰めた固定化硝化処理装置、12はエ
アレージジン装置を備えた固定床式生物酸化処理装置、
13は凝集沈澱、砂濾過。
In FIG. 2, 11 is an immobilized nitrification treatment device packed with the above-mentioned immobilized nitrifying bacteria, and 12 is a fixed bed biological oxidation treatment device equipped with an aeration gin device.
13 is coagulation sedimentation and sand filtration.

塩素処理を行う急速濾過システムである。This is a rapid filtration system that performs chlorine treatment.

第2図(イ)は固定化硝化処理装置11でエアレージジ
ンを行って原水中のアンモニアを亜硝酸性窒素及び硝酸
性窒素に変換し、タンク内の越流堰をオーバーフローし
た硝化処理した水を、既存の急速濾過システム13で凝
集沈澱、砂濾過、塩素処理を行うものである。
Figure 2 (A) shows that the immobilized nitrification treatment equipment 11 performs aeration to convert ammonia in the raw water into nitrite nitrogen and nitrate nitrogen, and the nitrified water that overflows the overflow weir in the tank is The existing rapid filtration system 13 performs coagulation sedimentation, sand filtration, and chlorination.

第2図(ロ)は原水の有機物濃度が高い場合に、固定化
処理装置11の前段に固定床式生物酸化処理装置!2を
設けてエアレージジンを行い原水中の有機物を除去した
後に上記(イ)の固定硝化処理装置11.急速濾過シス
テム13による処理を行うものである。
Figure 2 (b) shows a fixed-bed biological oxidation treatment device installed before the immobilization treatment device 11 when the raw water has a high organic matter concentration. After removing organic matter from the raw water by performing aerage gin using the fixed nitrification treatment equipment 11 of (a) above. Processing is performed by a rapid filtration system 13.

H8発明の効果 本発明は、上述のとおり構成されているので次に記載す
る効果を奏する。
H8 Effects of the Invention Since the present invention is configured as described above, it produces the following effects.

■硝化菌固定化法においては、高濃度の硝化菌を固定化
することができる。
■In the nitrifying bacteria immobilization method, high concentrations of nitrifying bacteria can be immobilized.

■浄化処理方法においては、高濃度の硝化菌を固定化し
た固定化硝化菌で原水中のアンモニアを硝化処理するの
で、硝化能力が向上し、従来不可能であった低温におけ
るアンモニアの処理が可能になる。
■In the purification treatment method, ammonia in raw water is nitrified using immobilized nitrifying bacteria with a high concentration of nitrifying bacteria, improving nitrification ability and making it possible to process ammonia at low temperatures, which was previously impossible. become.

■低温下でも硝化能力があるので、硝化処理後における
急速濾過装置の塩素投入量を減少させることができる。
■Since it has nitrification ability even at low temperatures, it is possible to reduce the amount of chlorine input into the rapid filtration equipment after nitrification treatment.

また塩素投入の減少により健康に有害なトリハロメタン
の生成を減少させることができる。
Reducing chlorine input also reduces the production of trihalomethanes, which are harmful to health.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、本発明の硝化菌固定化方法の実施例を示す工
程図、第2図(イ)、(ロ)は夫々本発明の浄水処理方
法の実施例を示す浄水処理装置の概略説明図である。 外2名 第2図
FIG. 1 is a process diagram showing an example of the method for immobilizing nitrifying bacteria of the present invention, and FIGS. 2 (a) and (b) are schematic explanations of water purification equipment showing examples of the water purification method of the present invention, respectively. It is a diagram. 2 people outside Figure 2

Claims (2)

【特許請求の範囲】[Claims] (1)活性汚泥を選択培養した硝化菌を濃縮し、この濃
縮液に粉末活性炭を添加して撹拌しながら高吸水性樹脂
を添加して膨潤したビーズとし、このビーズに塩化カル
シウムを添加して2次架橋することにより硝化菌を固定
化することを特徴とする硝化菌固定化方法。
(1) Activated sludge is selectively cultured to concentrate nitrifying bacteria, powdered activated carbon is added to this concentrated solution, and while stirring, a super absorbent resin is added to form swollen beads, and calcium chloride is added to these beads. A method for immobilizing nitrifying bacteria, which comprises immobilizing nitrifying bacteria by secondary crosslinking.
(2)急速濾過装置の前段にアンモニアを硝化する請求
項(1)の硝化菌固定化方法にて得た固定化硝化菌を用
いた固定化硝化処理装置を設け、原水を硝化処理後、急
速濾過することを特徴とする浄水処理方法。
(2) An immobilized nitrification treatment device using the immobilized nitrifying bacteria obtained by the nitrifying bacteria immobilization method of claim (1) is installed before the rapid filtration device to nitrify ammonia, and after the raw water is nitrified, the A water purification method characterized by filtration.
JP10133489A 1989-04-20 1989-04-20 Method for immobilizing nitrifying bacteria and water purifying treatment Pending JPH02280893A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP10133489A JPH02280893A (en) 1989-04-20 1989-04-20 Method for immobilizing nitrifying bacteria and water purifying treatment

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP10133489A JPH02280893A (en) 1989-04-20 1989-04-20 Method for immobilizing nitrifying bacteria and water purifying treatment

Publications (1)

Publication Number Publication Date
JPH02280893A true JPH02280893A (en) 1990-11-16

Family

ID=14297938

Family Applications (1)

Application Number Title Priority Date Filing Date
JP10133489A Pending JPH02280893A (en) 1989-04-20 1989-04-20 Method for immobilizing nitrifying bacteria and water purifying treatment

Country Status (1)

Country Link
JP (1) JPH02280893A (en)

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04281894A (en) * 1991-03-09 1992-10-07 Central Res Inst Of Electric Power Ind Sea water purifying material and sea water purifying method
JPH0780282A (en) * 1993-06-24 1995-03-28 Ebara Res Co Ltd Polymeric hydrogel granular material, production thereof and immobilization of bacteria using the same
JP2003235554A (en) * 2002-02-18 2003-08-26 Hitachi Plant Eng & Constr Co Ltd Microorganism-immobilized carrier and method for producing the same
JPWO2020004662A1 (en) * 2018-06-29 2020-12-17 株式会社クラレ Water treatment method
CN112409635A (en) * 2020-10-30 2021-02-26 东华大学 Method for separating, recycling and utilizing waste polyester-cotton blended fabric

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04281894A (en) * 1991-03-09 1992-10-07 Central Res Inst Of Electric Power Ind Sea water purifying material and sea water purifying method
JPH0780282A (en) * 1993-06-24 1995-03-28 Ebara Res Co Ltd Polymeric hydrogel granular material, production thereof and immobilization of bacteria using the same
JP2003235554A (en) * 2002-02-18 2003-08-26 Hitachi Plant Eng & Constr Co Ltd Microorganism-immobilized carrier and method for producing the same
JPWO2020004662A1 (en) * 2018-06-29 2020-12-17 株式会社クラレ Water treatment method
CN112409635A (en) * 2020-10-30 2021-02-26 东华大学 Method for separating, recycling and utilizing waste polyester-cotton blended fabric

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