JPH02279638A - Azeotropic composition and azeotropic-like composition - Google Patents
Azeotropic composition and azeotropic-like compositionInfo
- Publication number
- JPH02279638A JPH02279638A JP1096478A JP9647889A JPH02279638A JP H02279638 A JPH02279638 A JP H02279638A JP 1096478 A JP1096478 A JP 1096478A JP 9647889 A JP9647889 A JP 9647889A JP H02279638 A JPH02279638 A JP H02279638A
- Authority
- JP
- Japan
- Prior art keywords
- composition
- dimethylbutane
- weight
- chloro
- r244cb
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 68
- HNRMPXKDFBEGFZ-UHFFFAOYSA-N 2,2-dimethylbutane Chemical compound CCC(C)(C)C HNRMPXKDFBEGFZ-UHFFFAOYSA-N 0.000 claims abstract description 48
- 229930195733 hydrocarbon Natural products 0.000 claims abstract description 27
- 150000002430 hydrocarbons Chemical class 0.000 claims abstract description 27
- 239000004215 Carbon black (E152) Substances 0.000 claims abstract description 23
- 239000003208 petroleum Substances 0.000 claims abstract description 11
- NRAYRSGXIOSRHV-UHFFFAOYSA-N 1-chloro-1,2,2,3-tetrafluoropropane Chemical compound FCC(F)(F)C(F)Cl NRAYRSGXIOSRHV-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 239000002904 solvent Substances 0.000 abstract description 10
- NBVXSUQYWXRMNV-UHFFFAOYSA-N fluoromethane Chemical compound FC NBVXSUQYWXRMNV-UHFFFAOYSA-N 0.000 abstract description 6
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical compound CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 abstract description 4
- 238000004064 recycling Methods 0.000 abstract description 3
- 238000000034 method Methods 0.000 abstract description 2
- FXSNEEBOGAOVIM-UHFFFAOYSA-N 1-chloro-1,2,2,3,3-pentafluoropropane Chemical compound FC(F)C(F)(F)C(F)Cl FXSNEEBOGAOVIM-UHFFFAOYSA-N 0.000 abstract 1
- 239000010721 machine oil Substances 0.000 description 15
- 238000004140 cleaning Methods 0.000 description 8
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 6
- 238000009835 boiling Methods 0.000 description 5
- AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 5
- -1 chlorine radicals Chemical class 0.000 description 4
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 4
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 239000004604 Blowing Agent Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 3
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 3
- KDSNLYIMUZNERS-UHFFFAOYSA-N 2-methylpropanamine Chemical compound CC(C)CN KDSNLYIMUZNERS-UHFFFAOYSA-N 0.000 description 2
- RGSFGYAAUTVSQA-UHFFFAOYSA-N Cyclopentane Chemical compound C1CCCC1 RGSFGYAAUTVSQA-UHFFFAOYSA-N 0.000 description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 2
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 description 2
- DKGAVHZHDRPRBM-UHFFFAOYSA-N Tert-Butanol Chemical compound CC(C)(C)O DKGAVHZHDRPRBM-UHFFFAOYSA-N 0.000 description 2
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 238000004821 distillation Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
- 239000003380 propellant Substances 0.000 description 2
- 239000003507 refrigerant Substances 0.000 description 2
- AJDIZQLSFPQPEY-UHFFFAOYSA-N 1,1,2-Trichlorotrifluoroethane Chemical compound FC(F)(Cl)C(F)(Cl)Cl AJDIZQLSFPQPEY-UHFFFAOYSA-N 0.000 description 1
- FRCHKSNAZZFGCA-UHFFFAOYSA-N 1,1-dichloro-1-fluoroethane Chemical compound CC(F)(Cl)Cl FRCHKSNAZZFGCA-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 description 1
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 1
- NAMYKGVDVNBCFQ-UHFFFAOYSA-N 2-bromopropane Chemical compound CC(C)Br NAMYKGVDVNBCFQ-UHFFFAOYSA-N 0.000 description 1
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- BTANRVKWQNVYAZ-UHFFFAOYSA-N butan-2-ol Chemical compound CCC(C)O BTANRVKWQNVYAZ-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- KFUSEUYYWQURPO-UPHRSURJSA-N cis-1,2-dichloroethene Chemical group Cl\C=C/Cl KFUSEUYYWQURPO-UPHRSURJSA-N 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- HPNMFZURTQLUMO-UHFFFAOYSA-N diethylamine Chemical compound CCNCC HPNMFZURTQLUMO-UHFFFAOYSA-N 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 230000004907 flux Effects 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- DMEGYFMYUHOHGS-UHFFFAOYSA-N heptamethylene Natural products C1CCCCCC1 DMEGYFMYUHOHGS-UHFFFAOYSA-N 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000000976 ink Substances 0.000 description 1
- ZXEKIIBDNHEJCQ-UHFFFAOYSA-N isobutanol Chemical compound CC(C)CO ZXEKIIBDNHEJCQ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 231100001231 less toxic Toxicity 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- YKYONYBAUNKHLG-UHFFFAOYSA-N n-Propyl acetate Natural products CCCOC(C)=O YKYONYBAUNKHLG-UHFFFAOYSA-N 0.000 description 1
- 125000004971 nitroalkyl group Chemical group 0.000 description 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 description 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 229940090181 propyl acetate Drugs 0.000 description 1
- 239000005060 rubber Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000013020 steam cleaning Methods 0.000 description 1
- 239000005437 stratosphere Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- KFUSEUYYWQURPO-OWOJBTEDSA-N trans-1,2-dichloroethene Chemical group Cl\C=C\Cl KFUSEUYYWQURPO-OWOJBTEDSA-N 0.000 description 1
- CYRMSUTZVYGINF-UHFFFAOYSA-N trichlorofluoromethane Chemical compound FC(Cl)(Cl)Cl CYRMSUTZVYGINF-UHFFFAOYSA-N 0.000 description 1
- 229940029284 trichlorofluoromethane Drugs 0.000 description 1
- 239000005436 troposphere Substances 0.000 description 1
- 238000004506 ultrasonic cleaning Methods 0.000 description 1
- NQPDZGIKBAWPEJ-UHFFFAOYSA-N valeric acid Chemical compound CCCCC(O)=O NQPDZGIKBAWPEJ-UHFFFAOYSA-N 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D7/00—Compositions of detergents based essentially on non-surface-active compounds
- C11D7/50—Solvents
- C11D7/5036—Azeotropic mixtures containing halogenated solvents
- C11D7/5068—Mixtures of halogenated and non-halogenated solvents
- C11D7/5072—Mixtures of only hydrocarbons
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は２ 代替フロンとして使用できるとともに溶剤
等として優れた特性を有する新規なフッ素化炭化水素系
共沸組成物及び共沸様組成物に関するものである。Detailed Description of the Invention [Industrial Fields of Application] The present invention relates to a novel fluorinated hydrocarbon azeotropic composition and azeotrope-like composition that can be used as a CFC substitute and have excellent properties as a solvent, etc. It is something.
［従来の技術］
フッ素化炭化水素系化合物（以下単にフロンという）は
、毒性が少なく化学的に安定なものが多く、標準沸点の
異なる各種フロンが入手できることから、これらの特性
を活かして溶剤、発泡剤、プロペラントあるいは冷媒等
として１．１．２−トリクロロ−１，２，２−トリフル
オロエタン（Ｒ１１３）が、発泡剤としてトリクロロモ
ノフルオロメタン（Ｒ１１）が、プロペラントや冷媒と
してジクロロジフルオロメタン（Ｒ１２）が使われてい
る。[Prior Art] Fluorinated hydrocarbon compounds (hereinafter simply referred to as fluorocarbons) are often less toxic and chemically stable, and various types of fluorocarbons with different standard boiling points are available.Using these characteristics, they can be used as solvents, 1,1,2-trichloro-1,2,2-trifluoroethane (R113) is used as a blowing agent, propellant, or refrigerant, trichloromonofluoromethane (R11) is used as a blowing agent, and dichlorodifluoro is used as a propellant or refrigerant. Methane (R12) is used.
［発明が解決しようとする課題］
化学的に特に安定なＲ１１、Ｒ１２、Ｒ１１３は対流圏
内での寿命が長く、拡散して成層圏に達し、ここで太陽
光線により分解して発生する塩素ラジカルがオゾンと連
鎖反応を起こし、オゾン層を破壊するとのことから、こ
れら従来のフロンの使用規制が実施されることとなった
。このなめ、これらの従来のフロンに変わり、オゾン層
を破壊しにくい代替フロンの探索が活発に行なわれてい
る。[Problem to be solved by the invention] R11, R12, and R113, which are particularly stable chemically, have a long life in the troposphere and diffuse into the stratosphere, where they are decomposed by sunlight and generate chlorine radicals, which are converted into ozone. Conventional regulations on the use of these fluorocarbons have been implemented because they are believed to cause a chain reaction and destroy the ozone layer. Because of this, the search for alternative fluorocarbons that are less likely to deplete the ozone layer is being actively conducted in place of these conventional fluorocarbons.
本発明は、従来のフロンが有している優れた特性を満足
しながら代替フロンとして使用できる新規なフロン組成
物を提供することを目的とするものである。An object of the present invention is to provide a new fluorocarbon composition that can be used as an alternative fluorocarbon while satisfying the excellent properties of conventional fluorocarbons.
［課題を解決するための手段］
本発明は１−クロロ−１，２，２，３−テトラフルオロ
プロパン（Ｒ２４４ｃｂ）、３−クロロ−１，１，２，
２，３−ペンタフルオロプロパン（Ｒ２３５ｃａ）から
選ばれる少なくとも一種のフッ素化炭化水素及び２．２
−ジメチルブタン叉は２．２−ジメチルブタンを主成分
とする石油留分から得られる炭素数５〜８の炭化水素混
合物からなるフッ素化炭化水素系共沸組成物及び共沸様
組成物に関するものである０本発明の組成物は共沸組成
が存在し、特に洗浄溶剤として従来のＲ１１３単体と同
程度の洗浄力を有するため、Ｒ１１３代替として極めて
有用なものである。[Means for Solving the Problems] The present invention provides 1-chloro-1,2,2,3-tetrafluoropropane (R244cb), 3-chloro-1,1,2,
At least one fluorinated hydrocarbon selected from 2,3-pentafluoropropane (R235ca) and 2.2
- fluorinated hydrocarbon azeotropic compositions and azeotrope-like compositions consisting of a mixture of hydrocarbons having 5 to 8 carbon atoms obtained from petroleum fractions containing dimethylbutane or 2,2-dimethylbutane as a main component. The composition of the present invention has an azeotropic composition and has a cleaning power comparable to that of conventional R113 alone as a cleaning solvent, so it is extremely useful as a substitute for R113.
更に、リサイクルしても組成の変動が少ないこと、又従
来の単一フロンと同じ使い方ができ、従来技術の大幅な
変更を要しないこと等の利点かある。Furthermore, it has the advantage that there is little change in composition even after recycling, it can be used in the same way as conventional single fluorocarbons, and it does not require major changes to the conventional technology.
本発明の組成物としては、Ｒ２４４ｃｂと２，２−ジメ
チルブタンを用いた場合は、Ｒ２４４ｃｂが１４〜９９
重量％及び２．２−ジメチルブタンが１〜８６重量％で
あり、好ましくはＲ２４４ｃｂが２４〜９９重量％及び
２．２−ジメチルブタンが１〜７６重量％であり、さら
に好ましくはＲ２４４ｃｂが３４重量％及び２，２−ジ
メチルブタン６６重量％からなる共沸組成物であり、さ
らに又、本発明においては、２，２−ジメチルブタンに
替え２，２−ジメチルブタンを主成分とする石油留分か
ら得られる炭素数５〜８の炭化水素混合物を用いること
ができ、この場合の組成は、Ｒ２４４ｃｂが１４〜９９
重量％及び２，２−ジメチルブタンを主成分とする石油
留分から得られる炭素数５〜８の炭化水素混合物が１〜
８６重量％、好ましくは、Ｒ２４４ｃｂが２４〜９９重
量％及び２，２−ジメチルブタンを主成分とする石油留
分から得られる炭素数５〜８の炭化水素混合物が１〜７
６重量％である。In the composition of the present invention, when R244cb and 2,2-dimethylbutane are used, R244cb is 14 to 99
% by weight and 2.2-dimethylbutane is 1-86% by weight, preferably 24-99% by weight of R244cb and 1-76% by weight of 2.2-dimethylbutane, more preferably 34% by weight of R244cb. % and 66% by weight of 2,2-dimethylbutane.Furthermore, in the present invention, in place of 2,2-dimethylbutane, a petroleum fraction containing 2,2-dimethylbutane as a main component is used. The obtained hydrocarbon mixture having 5 to 8 carbon atoms can be used, and in this case, the composition is such that R244cb is 14 to 99
% by weight and a mixture of hydrocarbons having 5 to 8 carbon atoms obtained from petroleum fractions containing 2,2-dimethylbutane as the main component.
86% by weight, preferably 24-99% by weight of R244cb and 1-7 carbon atoms obtained from a petroleum fraction containing 2,2-dimethylbutane as the main components.
It is 6% by weight.
Ｒ２３５ｃａと２．２−ジメチルブタンを用いた場合は
、Ｒ２３５ｃａが６１〜９９重量％及び２，２−ジメチ
ルブタンが１〜３９重量％であり、好ましくはＲ２３５
ｃａが７１〜９９重量％及び２．２−ジメチルブタンが
１〜２９重量％であり、さらに好ましくはＲ２３５ｃａ
が８１重量％及び２，２−ジメチルブタン１９重量％か
らなる共沸組成物であり、さらに又、本発明においては
、２．２−ジメチルブタンに替え２，２−ジメチルブタ
ンを主成分とする石油留分から得られる炭素数５〜８の
炭化水素混合物を用いることができ、こ°の場合の組成
は、Ｒ２３５ｃａが６１〜９９重量％及び２，２−ジメ
チルブタンを主成分とする石油留分から得られる炭素数
５〜８の炭化水素混合物が１〜３９重量％、好ましくは
、Ｒ２３５ｃａが７１〜９９重量％及び２，２−ジメチ
ルブタンを主成分とする石油留分から得られる炭素数５
〜８の炭化水素混合物が１〜２９重量％である。When R235ca and 2,2-dimethylbutane are used, R235ca is 61 to 99% by weight and 2,2-dimethylbutane is 1 to 39% by weight, preferably R235
ca is 71 to 99% by weight and 2,2-dimethylbutane is 1 to 29% by weight, more preferably R235ca
is an azeotropic composition consisting of 81% by weight and 19% by weight of 2,2-dimethylbutane; A mixture of hydrocarbons having 5 to 8 carbon atoms obtained from petroleum fractions can be used, in which case the composition is 61 to 99% by weight of R235ca and 2,2-dimethylbutane as a main component. The obtained hydrocarbon mixture having 5 to 8 carbon atoms is 1 to 39% by weight, preferably 71 to 99% by weight of R235ca and 5 carbon atoms obtained from a petroleum fraction containing 2,2-dimethylbutane as the main components.
-8 hydrocarbon mixture is 1-29% by weight.
本発明の組成物には、用途に応じてその他の成分を更に
添加混合することができる０例えば、溶剤としての用途
においては、ペンタン、イソペンタン、ヘキサン、イソ
ヘキサン、ヘプタン、イソへブタン、２，３−ジメチル
ブタン、シクロペンタン等の炭化水素類、ニトロメタン
、ニトロエタン、ニトロプロパン等のニトロアルカン類
、ジエチルアミン、トリエチルアミン、イン１０ピルア
ミン、ブチルアミン、イソブチルアミン等のアミン類、
メタノール、エタノール、ｎ−プロピルアルコール、ｉ
−プロピルアルコール、ｎ−ブチルアルコール、ｉ−ブ
チルアルコール、Ｓ−ブチルアルコール、ｔ−ブチルア
ルコール等のアルコール類、メチルセロソルブ、テトラ
ヒドロフラン、１．４−ジオキサン等のエーテル類、ア
セトン、メチルエチルケトン、メチルエチルケトン等の
ケトン類、酢酸エチル、酢酸プロピル、酢酸ブチル等の
エステル類、ジクロロメタン、ｃｉｓ−１，２−ジクロ
ロエチレン、ｔｒａｎｓ−１，２−ジクロロエチレン、
２−ブロモプロパン等のハロゲン化炭化水素類、その他
、１，１−ジクロロ−１−フルオロエタン等の本発明以
外のフロン類等を適宜添加することができる。Other components may be further added to the composition of the present invention depending on the intended use.For example, when used as a solvent, pentane, isopentane, hexane, isohexane, heptane, isohbutane, - Hydrocarbons such as dimethylbutane and cyclopentane, nitroalkanes such as nitromethane, nitroethane and nitropropane, amines such as diethylamine, triethylamine, in-10-pyramine, butylamine and isobutylamine,
methanol, ethanol, n-propyl alcohol, i
- Alcohols such as propyl alcohol, n-butyl alcohol, i-butyl alcohol, S-butyl alcohol, t-butyl alcohol, ethers such as methyl cellosolve, tetrahydrofuran, 1,4-dioxane, acetone, methyl ethyl ketone, methyl ethyl ketone, etc. Ketones, esters such as ethyl acetate, propyl acetate, butyl acetate, dichloromethane, cis-1,2-dichloroethylene, trans-1,2-dichloroethylene,
Halogenated hydrocarbons such as 2-bromopropane, fluorocarbons other than those of the present invention such as 1,1-dichloro-1-fluoroethane, etc. can be added as appropriate.
Ｒ２４４ｃｂ、 Ｒ２３５ｃａから選ばれる。少なく
とも一種のフッ素化炭化水素及び２．２−ジメチルブタ
ン叉は２゜２−ジメチルブタンを主成分とする石油留分
から得られる炭素数５〜８の炭化水素混合物からなる本
発明のフッ素化炭化水素系共沸組成物及び疑共沸組成物
は、従来のフロンと同様、溶剤や発泡剤等の各種用途に
使用でき、特に溶剤として用いた場合、従来のＲ１１３
と同程度の溶解力を有する。ため好適である。溶剤の具
体的な用途としては、フラックス、グリース、油、ワッ
クス、インキ等の除去剤、塗料用溶剤、抽出剤、ガラス
、セラミックス、プラスチック、ゴム、金属製各種物品
、特にｔＣ部品、電気機器、精密機械、光学レンズ等の
洗浄剤や水切り剤等を挙げることができる。洗浄方法と
しては、手拭き、浸漬、スプレー 揺動、超音波洗浄、
蒸気洗浄等を採用すればよい。Selected from R244cb and R235ca. The fluorinated hydrocarbon of the present invention comprises a hydrocarbon mixture having 5 to 8 carbon atoms obtained from a petroleum fraction containing at least one fluorinated hydrocarbon and 2,2-dimethylbutane or 2.2-dimethylbutane as main components. Similar to conventional fluorocarbons, azeotropic compositions and quasi-azeotropic compositions can be used for various purposes such as solvents and blowing agents.
It has the same level of dissolving power. Therefore, it is suitable. Specific uses of the solvent include removers for flux, grease, oil, wax, and ink, paint solvents, extractants, glass, ceramics, plastics, rubber, various metal products, especially TC parts, electrical equipment, Examples include cleaning agents and draining agents for precision instruments, optical lenses, etc. Cleaning methods include hand wiping, dipping, spray shaking, ultrasonic cleaning,
Steam cleaning or the like may be used.
［実施例］ 以下に本発明の実施例を示す。[Example] Examples of the present invention are shown below.
実施例 １
下記の組成からなる溶剤組成物１０００ｇを蒸留フラス
コに入れ、理論段数２０段の精留塔を用い、大気圧下で
蒸留を行なった。Example 1 1000 g of a solvent composition having the composition shown below was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates.
（組成） （重量％）Ｒ２４４
ｃｂ （沸点５８℃）４０
２．２−ジメチルブタン（沸点４９．７℃）６０その結
果、５０℃において留分４００ｇを得な、このものをガ
スクロマトグラフで測定した結果、次の組成であった。(Composition) (% by weight) R244
cb (boiling point 58°C) 40 2.2-Dimethylbutane (boiling point 49.7°C) 60 As a result, 400 g of a fraction was obtained at 50°C, and as a result of measuring this with a gas chromatograph, it had the following composition. .
（組成） （重量％）Ｒ２４４
ｃｂ ３４２．２−ジメチ
ルブタン ６６実施例 ２
実施例１の組成物（Ｒ２４４ｃｂ／２．２−ジメチルブ
タン・３４重置火／６６重量％）を用いて機械油の洗浄
試験を行なった。(Composition) (% by weight) R244
cb 342.2-dimethylbutane 66 Example 2 A machine oil cleaning test was conducted using the composition of Example 1 (R244cb/2.2-dimethylbutane, 34 times flamed/66% by weight).
５Ｏ３−３０４のテストピース（２５ｍｍＸ ３０ｍｍ
Ｘ ２ｍｍ厚）を機械油（日本石油製ＣＱ−３０）中に
浸漬した後、本発明の前記組成物に５分間浸漬した。そ
の結果、機械油は、Ｒ１１３と同様、良好に除去できる
ことが確認された。5O3-304 test piece (25mmX 30mm
X 2 mm thick) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the composition of the present invention for 5 minutes. As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 ３
Ｒ２４４ｃｂ／２．２−ジメチル１２２２９５重量％１
５重量％を用いて機械油の洗浄試験を行なった。Example 3 R244cb/2.2-dimethyl 122295% by weight 1
A machine oil cleaning test was conducted using 5% by weight.
５Ｏ３−３０４のテストピース（２５ａ＋ｉＸ ３０ｍ
ｍＸ ２ｍｍ厚）を機械油（日本石油製ＣＱ−３０）中
に浸漬した後、本発明の前記組成物に５分間浸漬した。5O3-304 test piece (25a+iX 30m
m x 2 mm thick) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the composition of the present invention for 5 minutes.
その結果、機械油は、Ｒ１１３と同様、良好に除去でき
るこ、とが確認された。As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 ４
実施例３の組成物（Ｒ２４４ｃｂ／２．２−ジメチル１
２２２９５重量％１５重量％）についてタグ式測定法（
ＪＩＳ−に２２６５ ）に従って測定したところ引火点
がなく不燃であることが確認された。Example 4 Composition of Example 3 (R244cb/2.2-dimethyl 1
22295% by weight, 15% by weight) using the tag-type measurement method (
When measured according to JIS-2265), it was confirmed that it had no flash point and was nonflammable.
実施例 ５
Ｒ２４４ｃｂ／２．２−ジメチルブタン含有量８０％の
炭化水素混合物・９０重量％／１０重量％の組成物を用
いて機械油の洗浄試験を行なった。Example 5 A machine oil cleaning test was conducted using a composition of R244cb/2.2-dimethylbutane containing 80% hydrocarbon mixture/90% by weight/10% by weight.
５Ｏ３−３０４のテストピース（２５ｍｍＸ ３０ｍｍ
Ｘ ２ｍｍ厚）を機械油（日本石油製ＣＱ−３０）中に
浸漬した後、本発明の前記組成物に５分間浸漬した。そ
の結果、機械油は、Ｒ１１３と同様、良好に除去できる
ことが確認された。5O3-304 test piece (25mmX 30mm
X 2 mm thick) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the composition of the present invention for 5 minutes. As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 ６
下記の組成からなる溶剤組成物１０００ｇを蒸留フラス
コに入れ、理論段数２０段の精留塔を用い、大気圧下で
蒸留を行なった。Example 6 1000 g of a solvent composition having the composition shown below was placed in a distillation flask and distilled under atmospheric pressure using a rectification column with 20 theoretical plates.
（組成） （重量％）Ｒ２３５
ｃａ （沸点４３．９℃）８０２．２−ジメチルブタン
（沸点４９．７℃）２０その結果、４３℃において留分
５７０ｇを得た。このものをガスクロマトグラフで測定
した結果、次の組成であった。(Composition) (wt%) R235
ca (boiling point 43.9°C) 802.2-dimethylbutane (boiling point 49.7°C) 20 As a result, 570 g of a fraction was obtained at 43°C. As a result of measuring this product with a gas chromatograph, it had the following composition.
（組成） （重量％）Ｒ２３５
ｃａ ８１２．２−ジメチ
ルブタン １９実施例 ７
実施例６の組成物（１２３５ｃａ／２．２−ジメチルブ
タン＝８１重量％／１９重量％）を用いて機械油の洗浄
試験を行なった。(Composition) (wt%) R235
ca 812.2-dimethylbutane 19 Example 7 A machine oil cleaning test was conducted using the composition of Example 6 (1235ca/2.2-dimethylbutane=81% by weight/19% by weight).
５ＵＳ−３０４のテストピース（２５ｍ＋ａＸ ３ｈ＋
ｍＸ ２ｍｍ厚）を機械油（日本石油製ＣＱ−３０）中
に浸漬した後、本発明の前記組成物に５分間浸漬した。5US-304 test piece (25m+aX 3h+
m x 2 mm thick) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the composition of the present invention for 5 minutes.
その結果、機械油は、Ｒ１１３と同様、良好に除去でき
ることが確認された。As a result, it was confirmed that machine oil could be removed as well as R113.
実施例 ８
１２３５ｃａ／２．２−ジメチルブタン含有量８０％の
炭化水素混合物＝９０重量％／１０重量％の組成物を用
いて機械油の洗浄試験を行なった。Example 8 A machine oil cleaning test was conducted using a composition of 1235 ca/80% hydrocarbon mixture containing 2,2-dimethylbutane=90% by weight/10% by weight.
５ＵＳ−３０４のテストピース（２５ｍｍＸ ３０ｍｍ
Ｘ ２ｍｍ厚）を機械油（日本石油製ＣＱ−３０）中に
浸漬した後、本発明の前記組成物に５分間浸漬した。そ
の結果、機械油は、Ｒ１１３と同様、良好に除去できる
ことが確認された。5US-304 test piece (25mm x 30mm
X 2 mm thick) was immersed in machine oil (Nippon Oil Co., Ltd. CQ-30) and then immersed in the composition of the present invention for 5 minutes. As a result, it was confirmed that machine oil could be removed as well as R113.
［発明の効果］
本発明のフッ素化炭化水素系組成物は、従来のフロン類
が有している優れた特性を満足し、叉、共沸点が存在す
るなめ、リサイクル時に組成変動がない、従来の単一フ
ロンと同じ使い方でき、従来技術の大幅な変更を要しな
い等の利点がある。[Effects of the Invention] The fluorinated hydrocarbon composition of the present invention satisfies the excellent properties of conventional fluorocarbons, and also has an azeotropic point, so there is no change in composition during recycling, compared to conventional fluorocarbons. It has the advantage that it can be used in the same way as a single fluorocarbon, and does not require major changes to the conventional technology.
Claims (1)
パン（Ｒ２４４ｃｂ）、３−クロロ−１、１、２、２、
３−ペンタフルオロプロパン（Ｒ２３５ｃａ）から選ば
れる少なくとも一種のフッ素化炭化水素及び２、２−ジ
メチルブタンからなるフッ素化炭化水素系共沸組成物。 ２、１−クロロ−１、２、２、３−テトラフルオロプロ
パン（Ｒ２４４ｃｂ）３４重量％及び２、２−ジメチル
ブタン６６重量％からなる請求項１に記載の組成物。 ３、３−クロロ−１、１、２、２、３−ペンタフルオロ
プロパン（Ｒ２３５ｃａ）８１重量％及び２、２−ジメ
チルブタン１９重量％からなる請求項１に記載の組成物
。 ４、１−クロロ−１、２、２、３−テトラフルオロプロ
パン（Ｒ２４４ｃｂ）、３−クロロ−１、１、２、２、
３−ペンタフルオロプロパン（Ｒ２３５ｃａ）から選ば
れる少なくとも一種のフッ素化炭化水素及び２、２−ジ
メチルブタンからなるフッ素化炭化水素系共沸様組成物
。 ５、１−クロロ−１、２、２、３−テトラフルオロプロ
パン（Ｒ２４４ｃｂ）１４〜９９重量％及び２、２−ジ
メチルブタン１〜８６重量％からなる請求項４に記載の
組成物。 ６、３−クロロ−１、１、２、２、３−ペンタフルオロ
プロパン（Ｒ２３５ｃａ）６１〜９９重量％及び２、２
−ジメチルブタン１〜３９重量％からなる請求項４に記
載の組成物。 ７、１−クロロ−１、２、２、３−テトラフルオロプロ
パン（Ｒ２４４ｃｂ）、３−クロロ−１、１、２、２、
３−ペンタフルオロプロパン（Ｒ２３５ｃａ）から選ば
れる少なくとも一種のフッ素化炭化水素及び２、２−ジ
メチルブタンを主成分とする石油留分から得られる炭素
数５〜８の炭化水素混合物からなるフッ素化炭化水素系
共沸様組成物。 ８、１−クロロ−１、２、２、３−テトラフルオロプロ
パン（Ｒ２４４ｃｂ）１４〜９９重量％及び２、２−ジ
メチルブタンを主成分とする石油留分から得られる炭素
数５〜８の炭化水素混合物１〜８６重量％からなる請求
項７に記載の組成物。 ９、３−クロロ−１、１、２、２、３−ペンタフルオロ
プロパン（Ｒ２３５ｃａ）６１〜９９重量％及び２、２
−ジメチルブタンを主成分とする石油留分から得られる
炭素数５〜８の炭化水素混合物１〜３９重量％からなる
請求項７に記載の組成物。[Claims] 1,1-chloro-1,2,2,3-tetrafluoropropane (R244cb), 3-chloro-1,1,2,2,
A fluorinated hydrocarbon azeotropic composition comprising at least one fluorinated hydrocarbon selected from 3-pentafluoropropane (R235ca) and 2,2-dimethylbutane. A composition according to claim 1, consisting of 34% by weight of 2,1-chloro-1,2,2,3-tetrafluoropropane (R244cb) and 66% by weight of 2,2-dimethylbutane. 2. A composition according to claim 1, consisting of 81% by weight of 3,3-chloro-1,1,2,2,3-pentafluoropropane (R235ca) and 19% by weight of 2,2-dimethylbutane. 4,1-chloro-1,2,2,3-tetrafluoropropane (R244cb), 3-chloro-1,1,2,2,
A fluorinated hydrocarbon azeotrope-like composition comprising at least one fluorinated hydrocarbon selected from 3-pentafluoropropane (R235ca) and 2,2-dimethylbutane. 5. A composition according to claim 4, consisting of 14 to 99% by weight of 5,1-chloro-1,2,2,3-tetrafluoropropane (R244cb) and 1 to 86% by weight of 2,2-dimethylbutane. 6,3-chloro-1,1,2,2,3-pentafluoropropane (R235ca) 61-99% by weight and 2,2
5. A composition according to claim 4, comprising from 1 to 39% by weight of -dimethylbutane. 7,1-chloro-1,2,2,3-tetrafluoropropane (R244cb), 3-chloro-1,1,2,2,
A fluorinated hydrocarbon consisting of a mixture of at least one fluorinated hydrocarbon selected from 3-pentafluoropropane (R235ca) and a hydrocarbon having 5 to 8 carbon atoms obtained from a petroleum fraction containing 2,2-dimethylbutane as a main component. system azeotrope-like composition. A hydrocarbon having 5 to 8 carbon atoms obtained from a petroleum fraction containing 14 to 99% by weight of 8,1-chloro-1,2,2,3-tetrafluoropropane (R244cb) and 2,2-dimethylbutane. 8. A composition according to claim 7, comprising from 1 to 86% by weight of the mixture. 9,3-chloro-1,1,2,2,3-pentafluoropropane (R235ca) 61-99% by weight and 2,2
The composition according to claim 7, comprising 1 to 39% by weight of a hydrocarbon mixture having 5 to 8 carbon atoms obtained from a petroleum fraction containing -dimethylbutane as a main component.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1096478A JPH02279638A (en) | 1989-04-18 | 1989-04-18 | Azeotropic composition and azeotropic-like composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP1096478A JPH02279638A (en) | 1989-04-18 | 1989-04-18 | Azeotropic composition and azeotropic-like composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02279638A true JPH02279638A (en) | 1990-11-15 |
Family
ID=14166158
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1096478A Pending JPH02279638A (en) | 1989-04-18 | 1989-04-18 | Azeotropic composition and azeotropic-like composition |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02279638A (en) |
-
1989
- 1989-04-18 JP JP1096478A patent/JPH02279638A/en active Pending
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