JPH02273745A - Silver halide photographic sensitive material housed in cartridge - Google Patents

Abstract

PURPOSE:To improve a preservable property and to obtain the aspect ratio of the image plane which is mentally and physiologically preferable in terms of visual sensation by constituting specific compds. into the photosensitive material and housing this photosensitive material into a specific cartridge. CONSTITUTION:The photosensitive material contains the compds. expressed by formula I and/or formula II. The effective image plane area per frame to be exposed to the photosensitive material in the aperture of the cartridge is 3.0 to 25.0cm<2> and the ratio of the length on the long side to the length on the short side of the image plane of one frame is 1.2 to 2.0. In the formulas, Ra, Rb, denote a hydrogen atom, etc.; X denotes -CO-, etc.; Rc denotes an alkyl group, etc. Coup denotes a residual coupler group having a coupling active position; Ball denotes a group which has the size and shape necessary for imparting diffusion resistance to the compd. of formula II by combining with the coupling active position of Coup and can be eliminated from Coup by a coupling reaction; Sol is a soluble group. The photosensitive material having the excellent preservable property before and after photographing and the aspect ratio of the image plane which is mentally and physiologically preferable in terms of visual sensation are obtd. in this way.

Description

DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a silver halide photographic material housed in a novel cartridge.

[Conventional technology]

Conventional cartridges for silver halide photographic materials include so-called instamatic 126-size cartridges with a screen size of 2.8 cm x 2.85 an (standard content is ANSI/ASCPH1,40-198).
4) and 1.3cWLX 1.7cm so-called pocket-sized 110 size cartridge (the same ANSI/AS
CPH1, 55-1986), etc. have been used. It is true that these cartridges have advantages such as being easy to load into the camera, being less likely to malfunction, requiring no winding when taking out the film after shooting, and being easy to take out and reload the film during shooting. However, recently, the usage rate has decreased due to the small screen size, poor image quality when printing, and the aspect ratio of the print being close to 1.0 (printing feels unstable, making it uncomfortable to look at). I've been doing it.

Recently, disposable type photosensitive material cartridges such as "Utsurun desu" and "Utsurun desu HIJ" have become popular, but because these are disposable, the price per frame is high. there were.

Furthermore, even if light-sensitive materials housed in simple, stable, and inexpensive cartridges become available5, users who use such cartridges will not be able to take many pictures, and the number of frames they will take will be low. It is required that the material has good storage stability before and after photography.

[Problem to be solved by the invention]

The first object of the present invention is to provide a photosensitive material housed in a cartridge that has excellent storage stability before and after photographing.
Second, it is necessary to supply a photosensitive material that provides a screen with an aspect ratio that is visually psychophysiologically preferable, and thirdly, it is necessary to provide a photosensitive material that has an appropriate screen size to prevent blurring during printing. The fourth goal is to provide a photosensitive material that is easy to handle, the fifth is to provide a photosensitive material with excellent color reproducibility, and the sixth is to provide a camera that is not disposable. It is an object of the present invention to supply such a photosensitive material whose price per frame is low.

c! ! 1 m] The above object of the present invention has been achieved by a silver halide photographic material housed in the following cartridge.

A film roll is used to store a photographic light-sensitive material having a silver halide emulsion layer formed on a support by winding it in advance, a winder is used to wind and store the photographic material after photography, and an opening connects these to expose the light-sensitive material. In a silver halide photographic light-sensitive material housed in a cartridge having a bridge portion, the effective screen area per frame exposed to the light-sensitive material at the opening is 3.0cm2 or more and 25.0cz2.
or less, the ratio of the length of the long side to the length of the short side of the screen of 1:11 is 1.1 or more and 2.0 or less, and the photosensitive material is A silver halide photographic material housed in a cartridge characterized by containing general formula CI).

General formula (A) In the formula, Ra and Rb are a hydrogen atom, a halogen atom, a sulfo group, a carboxyl group, an alkyl group, an acylamino group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a sulfonyl group, an acyl group, and a carbamoyl group. group, sulfamoyl group, and Ra and Rb may jointly form a carbocyclic ring. X is 100- or -802
- represents. Ro represents an alkyl group, an aryl group, a heterocyclic group, a cycloalkyl group, an alkoxy group, an aryloxy group, or an amino group. The total number of carbon atoms in Ra, Rb, and Rc is 10 or more. The compound of general formula (A) is substantially colorless and does not form a color image due to a coupling reaction with a developing agent.

General formula (I) Coup -E3oI ax1 In the general formula (1), Coup represents a coupler residue having a coupling active position, Baxx is bonded to the coupling active position of Coup, and a compound represented by the general formula (I) A group having the size and shape necessary to impart diffusion resistance to Coup
represents a more releasable group, S01 is a solubilizing group,
A group that is bonded to the non-coupling position of the Coup and that enables the coupling product (usually an azomethine dye) produced by the coupling reaction to be eluted from the light-sensitive material during color development processing or subsequent processing. represent.

The present invention will be explained in detail below. The cartridge of the present invention comprises a film roll chamber for storing a roll of unexposed photosensitive material, a winding chamber for winding up the exposed photosensitive material, and a bridge section connecting them and having an opening. The effective screen area per frame exposed to the photosensitive material is 3. OcW? 25.0 cm or less, and the ratio of the length of the long side to the length of the short side of the screen of one frame (American square ratio) is 1.1 or more and 2.0 or less.

Is the preferred effective screen area 6.0cIF? Above x6. o
J or less, particularly preferably 8. Ocm” or more10.
It is 0 cm2 or less. If the effective screen area is too small, image quality such as graininess and sharpness may not be acceptable to general users. I enjoyed it.

The preferred ratio is 1.3 or more and 1.8 or less, more preferably 1.4 or more and 1.6 or less.

The generally preferred asquit ratio is 1.61 as the golden section.
Although a value of 8 is known, the optimum aspect ratio for photographic prints was determined based on monitor tests conducted with general users.

Especially the current 135 format color negative/-! -Par's laboratory system has a very complete service lineup, and it is extremely desirable for users to select a screen size and film width that are compatible with the system.

A preferred film width is 35±Lm/1rt1, particularly preferably 35±0.5m/m.

Figure 1 shows the appearance of a typical cartridge. Further, FIG. 2 shows a conceptual diagram of the relationship between the cartridge and the camera immediately before being inserted into the camera.

In the conventional cartridge of this type,
It has been common knowledge to use light-shielding paper as disclosed in Publication No. 4406 and Publication No. 40-17829.

However, the presence of light-shielding paper is undesirable because it causes deterioration of the flatness of the film at the exposure aperture, making it difficult to obtain sharply focused photographs, and reducing the effect of increasing the screen size by half. Therefore, it is preferable to remove the light-shielding paper and adopt another light-shielding means. Specific examples of the light shielding means are illustrated below.

+1) Attach a ribbon like the one used for the exit of the 135 cartridge to the exit of the film roll chamber and the entrance of the winding chamber. The preferred ribbon width is 10±5rrL/rr
It is L. The preferred ribbon height is 1.5±0.3m/
It is m.

(2) Utility Model Publication No. 46-30055, Japanese Unexamined Patent Publication No. 1973
A light shielding passage as disclosed in Japanese Patent No. 111822 is provided at the exit of the film roll chamber and the entrance of the winding chamber. It is preferable that the light-shielding passage has a length equal to or more than 14 times the outer periphery of the roll chamber and the winding chamber.

(3) Providing a resin nozzle as disclosed in Japanese Unexamined Patent Publication No. 58-147742.

(4) Dyeing the film base with dye to reduce light niping. There are no particular limitations on the dye, but due to the general properties of photosensitive materials, it is preferable to dye the dye with a color tone close to gray. The dyeing density is small (both 0.01 or more, preferably 0.03 or more).Measurement is carried out in the visible light range using a dark variable needle manufactured by Macbeth.

(5) Heat deformation in the form of twill knurling is applied to the leading and trailing ends of the film to reduce light piping. 20rn
It is preferable to apply thermal deformation in the form of twill knurling over a distance of /m or more.

The means (1) to (5) may be appropriately combined or used alone.

(1) and (3),! 1) and (4), (1) and (5), (
Combinations of 2) and (3), (2) and (4), and (2) and (5) are preferred.

In order to maximize the effect of increasing the screen size, a reference surface is provided on the camera and cartridge so that the film surface is in a fixed position relative to the lens within the camera. , the position of the film plane relative to the lens is preferably determined. It is preferable to ensure a positional accuracy of ±50 μm. The position of the film surface can also be determined by pressing the back side of the film in the exposed area of the cartridge with a pressure plate of the camera.

The cartridge used in the present invention is usually formed from a plastic material, and the cartridge body is preferably hermetically packaged in a moisture-proof sealed container (cartridge case). Further, the cartridge is preferably formed from a plastic material that does not substantially change the photographic performance of the silver halide photographic light-sensitive material even when stored at 60° C. in the cartridge case. Such plastic materials can be selected in the following manner.

A plastic chip 100I of several m/m is placed in a sealed metal container of about 6000 crn2 whose humidity is adjusted to 701 with glycerin, and a film to be moisture-proof packaged therein is heated at 60° C. for 3 days. Films tested under the same conditions as above, except without the plastic chip, are processed at the same time.

If the processed film is measured at Status M density and the difference in capri density of cyan, magenta, and yellow between the two samples is within 0410, preferably within O,OS, it can be preferably used as the plastic material of the present invention. can.

Development processing is carried out according to the standard specified processing for each color film.

For example, in the case of color negative film, C-41,0N
Use -16 etc. For color reversal films, C! Use R-56, g-6, etc.

Furthermore, in one aspect of the present invention, the plastic material is
It is preferable that the amount of cyan gas generated is 0.03 μm1711 or less.

As a result of detailed analysis of gas components emitted from plastic materials that are harmful to color film, very small amounts of cyan gas were detected. According to the results of this analysis, instead of plastic, it was placed in a sealed container made of di-alkaline earth metal.
Heating for 3 days at 0.degree. C. showed changes in photographic performance that were very similar to those tested with plastic materials.

From these experiments, plastic materials that do not emit cyan gas are highly preferred for the present invention.

The plastic material preferably used in the present invention has a cyan gas amount of 0.03 μl or less based on the plastic material I11, as determined by the cyan gas detection and quantitative method described below.
Preferably, the amount of cyan gas is within the detection limit of analysis (0,005
μI/I) or less plastic material.

(Cyan gas analysis method) If necessary, cool the resin with liquid nitrogen, crush it, and use it as a sample. This sample was tested in accordance with 38. 3 & 1.1.1 of the cyanide compound section
Treat the sample using a method similar to the aeration method, and collect the generated hydrogen cyanide in an IJ solution. The cyanide ions in this collection liquid are determined by the above-mentioned test method 38.2 pyridine-pyrazolone absorptiometric method.

An example of actual analysis is described below.

Take 1001 of the resin, add 100 - of water and adjust the pH to 5.0.
Adjust with acetic acid and sodium hydroxide so that
Absorb in IJum solution. The absorbance at 620 nm of this absorption liquid was read using pyridine-pyrazolone spectrophotometry, and the absorbance obtained in the blank operation was subtracted (. Using a separately prepared calibration curve, the amount of hydrogen cyanide generated was determined and Calculate the amount of generation.

The plastic material used in the present invention includes addition polymerization of olefins having carbon-carbon double bonds, ring-opening polymerization of small-membered ring compounds, polycondensation (condensation polymerization) between two or more types of polyfunctional compounds,
It can be produced using methods such as polyaddition and addition condensation of a phenol derivative, urea derivative, or melamine derivative with a compound having zero aldehyde.

Raw materials for plastic materials include olefins with carbon-carbon double bonds, such as styrene, α-methylstyrene, butadiene, methyl methacrylate, butyl acrylate, acrylonitrile, vinyl chloride, vinylidene chloride, vinylpyridine, N- ? "Nylcarbazole, N-
? "Nylpyrrolidone, vinylidene cyanide, ethylene,
Propylene nat is a typical example. or,
Examples of small-membered ring compounds include ethyleneoxyr, propyleneoxyr, cricidol, 3,3-bischloromethyloxetane, 1,4-dioxane, tetrahydrofuran, triosan, ε-caprolactam, β-propiolactone, Typical examples include ethyleneimine and tetramethylsiloxane.

In addition, polyfunctional compounds include, for example, carboxylic acids such as terephthalic acid, adipic acid, and glutaric acid; isocyanates such as toluene diisocyanate, tetramethylene diisocyanate, and hexamethylene diisocyanate; alcohols such as ethylene glycol, propylene glycol, and glycerin; Typical examples include amines such as methylene diamine, tetramethylene cyanide, and paraphenylene diamine, and epoxies. In addition, examples of phenol derivatives, urea derivatives, and melamylon derivatives include phenol, cresol, and diphenol in meth. Representative examples include chlorophenol, urea, and melamine. Furthermore, typical examples of compounds having aldehyde 9 include formaldehyde 9, acetaldehyde 9, octanal, todecanal, and benzaldehyde. Not only one type of these raw materials but also two or more types may be used depending on the target performance.

When producing plastic materials using these raw materials, catalysts and solvents may be used.

As a catalyst, (1-phenylethyl)azodiphenylmethane, dimethyl 2,2'-azobisisobutyrate,
2. Radical polymerization ML (j[,
) Cationic polymerization catalysts such as luenesulfonic acid, trichlorosulfuric acid, perchloric acid, trifluoroboron, tin tetrachloride,
Anionic polymerization catalysts such as n-butyllithium, sodium/naphthalene, 9-fluorenyllithium, and phenylmagnesium bromide, triethylaluminum/tetrachlorotitanium-based Ziegler-Natsuta (Ziegl
er-Natta) type catalyst, sodium hydroxide, potassium hydroxide, potassium metal, etc. are used.

There are no particular restrictions on the solvent as long as it does not inhibit polymerization, but examples include hexane, decalin, benzene, toluene, cyclohexane, chloroform, acetone, methyl ethyl ketone, ethyl acetate, butyl acetate, and tetrahydrofuran.

In molding the plastics of the present invention, a plasticizer is mixed with the plastics as necessary. Examples of the plasticizer include trioctyl phosphate, trinotyl phos7ate, diptylphthalate, diethyl sebacate, methyl amyl ketone, nitrobenzene, γ-valeroctone,
Typical examples include di-n-octyl succinate, fromona 7-talene, and butylpal-electnate.

Specific examples of the plastic materials used in the present invention are listed below on P-9 P-10, but are not limited to these (1° Polystyrene Polyethylene Polypropylene Polymonochlorotrifluoroethylene Vinylidene chloride Resin Vinyl chloride Resin Vinyl chloride Vinyl acetate copolymer resin Acrylonitrile-butadiene-styrene copolymer resin Methyl methacrylic resin Vinyl formal resin Vinyl butyral resin Polyethylene phthalate Teflon Nylon Phenol resin Melamine resin Particularly preferred plastic materials for the present invention include polystyrene, polyethylene, polypropylene, and the like.

Cartridges are usually made of plastic mixed with carbon black or pigments to give them a shimmering effect.

The m weight of the cartridge is usually 5 to 7 oy, preferably 10 to 501 y, more preferably 12 to 30 y.

In the present invention, it is preferable that the cartridge be packaged in a sealed state inside a cartridge case, but here, sealed packaging means that the inside of the case after 12 months at 25°C, assuming a 20% humidity difference between the outside air and the inside of the case. A condition in which the humidity changes within 10 degrees.

As the cartridge case, a plastic ring case such as a 135 size cartridge case or a moisture-proof bag such as a 110 size or 120 size film case can be used.

The humidity inside the cartridge case is usually 45-70% relative humidity at 25°C, preferably 50-65%.
, more preferably 52 to 60%.

Cellulose triacetate, polyester base, etc. can be used as the film base. When a polyester base is used, it is preferable to use a water-absorbing polyester base as described in Japanese Patent Application No. 71308/1983.

The thickness of the film base is usually 40-140 μm.

Preferably 60 to 130 μm, more preferably 8.

~120 pn.

Next, the compound represented by general formula (A) will be explained in detail.

In the formula, Ra and Rb are a hydrogen atom, a halogen atom (e.g. chlorine, bromine, etc.), a sulfo group, a carboxyl group, akdP
k group (e.g. methyl group, pentadecyl group, t-hexyl group, etc.), acylamino group (e.g. acetylamino group, benzoylamino group, etc.), alkoxy group (e.g. methoxy group, butoxy group, etc.), aryloxy group (e.g. phenoxy group) etc.), alkylthio groups (e.g. octylthio group,
hexadecylthio group, etc.), arylthio group (e.g., phenylthio group, etc.), sulfonyl group (e.g., todecanesulfonyl group, p-)luenesulfonyl group, etc.), acyl group (
(e.g., acetyl group, benzoyl group, etc.), carbamoyl group (e.g., N,N-dibutylcarbamoyl group, etc.), sulfamoyl group (e.g., N,N-diethylsulfamoyl group, etc.), and Ra and Rb jointly represent carbon atoms. It may form a ring. X represents -ω- or -802-. R
e is an alkyl group (e.g. heptadecyl group, 1-hexylnonyl group, 1-(2,4-di-t-amylphenoxy)
propyl group, etc.), aryl group (e.g. phenyl group, 3,
5-bis(2-hexyldecanamide 9) phenyl group 1
3.4-his(hexadecyloxycarbonyl)phenyl group, 2.4-his(tetradesiloxy)phenyl group, etc.)
, heterocyclic groups (e.g. 2,6-dihexyl dipyridin-4-yl group, N-tetradecylpyrrolidin-2-yl group, N-octadecylbiyricin-3-yl group, etc.), cycloalkyl groups (e.g. 3-decanamide 0 Cyclohexyl group, 3-((2,4-di-t-amylphenoxy)butanamide 9)cyclohexyl group, etc.), alkoxy group (
For example, hexadecyloxy group), aryloxy group (
For example, 4-t-octylphenoxy group, etc.), amine group (
For example, octadecylamino group, etc.). Ra%Rb
, The total number of carbon atoms in Ra is 10 or more.

The compound of general formula (5) may form a bis-form, a tris-form, a polymer, or the like.

In general formula (A), preferable substituents for Ra and Rb are a hydrogen atom, a halogen atom, an alkyl group, an alkoxy group, and an alkylthio group, and among these, a hydrogen atom,
A halogen atom or an alkyl group is more preferred, and a hydrogen atom is most preferred.

As X in general formula (A), -Go- is relatively preferable.

In general formula), preferable substituents for Re are an alkyl group and an aryl group, and among these, an aryl group is most preferable.

- When Re is an aryl group in Monka (A), the substituents to be further substituted on the aryl group are not particularly limited as long as they are generally known substituents on the aryl ring, but the following are listed below: Substituents are relatively preferred. That is, they are a halogen atom, an alkyl group, an atto9 group, a sulfonyl group, an alkoxy group, an alkoxycarbonyl group, and a carboxyl group. Furthermore, the substituent to be further substituted on the aryl group is preferably a group that does not contain a sulfo group, a carboxyl group, or the like. This is because the presence of these water-soluble groups may adversely affect the storage stability of the photosensitive material.

One of the purposes of the compound used in the present invention is to use it as an agent for preventing color staining and color caprigraphy in photographic materials.
If the compound itself is colored or if a color image is formed during the development process, this will impede good color reproduction of the photographic material and will be contrary to its purpose. Therefore, firstly, the compounds of the invention are substantially colorless. "Substantially colorless" here means that it does not have absorption with a molar absorption coefficient of a5000 or more in the visible wavelength range from 4000 nm to 700 nm. Secondly, the compound used in the present invention contains coupler residues (such as acylacetanilide residues, -pyrazolone residue, l-su7toll residue), and does not form a color image by coupling reaction during the development process.

The alkali-labile precursor of the compound represented by the general formula (A) of the present invention means that the hydroxyl group moieties at the 1st and 4th positions of the hydroquinone skeleton in the crest (A) can be cleaved under alkaline conditions. Refers to a compound that has a protecting group.

As protecting groups, acyl groups (e.g. eva, acetyl group, chloroacetyl group, benzoyl group, ethoxycarbonyl group,
etc.), β-leaving groups (e.g., 2-cyanoethyl group, 2-methanesulfonylethyl group, 2-toluenesulfonylethyl 1, etc.)! >f is listed as a representative example.

These compounds of the present invention represented by the general formula (N) and their alkali-labile precursors are described in US Pat.
, No. 197, Japanese Patent Publication No. 59-37497, Japanese Patent Application Publication No. 1987-
It can be easily synthesized according to the method described in No. 202465, etc.

Specific examples of the compound represented by the general formula (A) and its alkali unstable precursor are listed below, but the present invention is not limited thereto.

compound rot tt αri 0H α〔 αD H H H H H Ei H N+CtsH3y)z 0H (c) t-C5H11 Next, general formula (1) will be explained.

- Monka (1) Coupler residues represented by the % formula % Coup include 9 acylacetanilides, pyrazolones, pyrazolotriazoles, pyrazolobenzimidazoles, indasilones,
These include naphthols and phenols.

The diffusion resistance imparting group represented by Ba11 is Oo -o-1-s--oc-1-osoz-mot, <I
d, an optionally substituted alkyl group, aryl group or heterocyclic group having a total of 8 to 40 carbon atoms bonded to the coupling active position of Coup with -0CNH-, and a total bonded to the coupling active position with a nitrogen atom. There are optionally substituted heterocyclic groups having 10 to 40 carbon atoms. Preferred examples of Ba1x include alkoxy groups having a total number of carbon atoms of 8 to 40, aryloxy groups, alkylthio groups, arylthio groups, acyloxy groups, alkylsulfonyloxy groups, arylsulfonyloxy groups, heterocyclicoxy groups, heterocyclicthio groups, and nitrogen Heterocyclic groups bonded through atoms (e.g. pyrrole, pyrazole, imidazole, triazole, tetrazole, indole, indazole, benzimidazole, incitriazole, succinimide, maleimide 0, phthali 9)*, 2-pyridon, 4-pyridon imidazolidine-2,4-dione, Φsaciridine-2゜4-
:)one, -thiazolidine-2,4-dione, triacylidine-3,5-dione, imidazolidine-2゜4.5
-1 ion, etc.).

These groups represented by Earl may be bonded to each other by divalent or higher polyvalent groups (they may be bonded pendantly to the main chain of the ethylenic polymer. In this case, the number of carbon atoms mentioned above is may be outside the range.

The solubilizing group represented by S01 is a group containing a dissociable human 90xyl group, a carboxyl group, a sulfo group, or an aminosulfonyl group, and this dissociable hydroxyl group,
A carboxyl group, a sulfo group, or an aminosulfonyl group may be bonded directly to the coupler residue, or may be bonded to the coupler residue via a divalent group such as alkylene or arylene, or alkylene, arylene, -O --S-
-5O--8O2--CONH--8O2NB-100NH-11000--8O20--C--NH- etc. may be bonded to the coupler group via a divalent group. good.

Multiple Sobs may be attached to the non-coupling group of the coupler residue. As Sox, a group containing a carboxyl group or a sulfo group is preferable. Examples of preferred Sol are shown below. However, the carboxyl group may be a carboxilade group (e.g. -〇〇〇!fa, -GOOK),
The sulfo group is a sulfonate group (e.g. -Momon [μs-■]) General formula (QS-IV) 03H -CH20H2So3H, -0CH2COOH, -0C
H20H2COOH.

-8CH2COOH, -5CH20H2C00E, -8
o2CH2CH2COOH.

-CONHCH2CH2COOH, -CONHCH2C
OOH.

- The compound represented by Monna (I) is preferably the following - Monna (QS -ff ), (QS-Ill), ["QS-
f'/), (QS-V), (QS-M] or (QS-
■] is a compound represented by

General formula (QS-n) General formula (QS-V) -Stone hole (QS-IV) One pattern hole Cμs-■] General formula (QS-n), (QS-11, (QS-fl/'
1, (QS-V), (QS-■'l and (QS-■), R1 is an alkyl group having 1 to 8 carbon atoms (e.g. methyl, t-butyl), an alkoxy group having 1 to 8 carbon atoms. a group (e.g. LKz), or an aryl group having 6 to 10 carbon atoms (e.g. t
ij'; yenyl, 4-methoxyphenyl).

R2 is a halogen atom (fluorine atom, chlorine atom, bromine atom or iodine atom), an alkyl group having 1 to 8 carbon atoms (e.g. methyl, ethyl, hydroxymethyl), an alkoxy group having 1 to 8 carbon atoms (e.g. ethoxy, ethoxy, methoxyethoxy, hydroxyethoxy), number of carbon atoms: 1
~10 carbon amide groups (e.g. formamide, acetamide, pendazole), sulfonamide groups having 1 to 10 carbon atoms (e.g. methanesulfonamide 9, ethanesulfonamide, p-)luenesulfonamide) or carbon It represents an aryloxy group having 6 to 10 atoms (for example, phenoxy, p-methoxyphenoxy).

R3 is a group having the same meaning as R2, an amino group having 1 to 10 carbon atoms (e.g. diethyla ξ), pyrrolidino, anilino, 2-
chloroanilino) or an aryl group having 6 to 10 carbon atoms (for example, phenyl, 4-chlorophenyl, 3-acetamido7yl, 2-methoxyphenyl).

R4+ R5* R8 and R7 are each a group having the same meaning as R3, a hydrogen atom, an alkylthio group having 1 to 8 carbon atoms (e.g. methylthio, benzylthio), or a group having 6 to 10 carbon atoms.
represents an arylthio group (for example, phenylthio, p-)'Jruthio) or an alkoxycarbonylamino group having 2 to 1 carbon atoms (for example, methoxycarbonylamino, dicarbonylamino, etho).

R8 is a group having the same meaning as R2, a sulfamoyl group having 0 to 1 carbon atoms (e.g. sulfamoyl, methylsulfamoyl, methylsulfamoyl, phenylsulfamoyl)
, charcoal! Alkoxycarbonyl groups having 2 to 10 atoms (e.g. methoxycarbonyl, ethoxycarbonyl, butoxycarbonyl) or carbamoyl groups having 1 to 10 carbon atoms (e.g. carbamoyl, methylcarbamoyl, methylcarbamoyl, phenylcarno-Zmoyl) Table was wasted.

1 represents an integer of 1 or 2, m and n represent an integer of 0 to 4, p represents an integer of O to 2, q represents an integer of 1 or 2, and r represents an integer of O to 3. represent. However, when m, ``1p, or r are multiple, each of multiple R2
may be the same or different, and when 1 or q is 2, the plurality of 8o1s may be the same or different.

QS represented by the above - pattern hole [μs-■] ~ [φ-■]
Among couplers, the general formula (QS-M'l or (Q, S
Q, S couplers represented by -■] are preferred, and QS couplers represented by -monna (QS-■) are particularly preferred.

Specific examples of μsS couplers used in the present invention are shown below, but the present invention is not limited thereto.

(Q-1) 0cocacoNH (Q-2) (Q-4) (Q-8') H3 (Q-10) (Cf12), 5O3K (Q-5) (Q-6) (Q-7) ( Q-11) (Q-12) (Q-13) (Q-14) (Q-15) (Q-16) 0OH (Q-20) H OCHCOOC1□H2S ■ H3 (Q-21) H (Q- 22) H (Q-18) C! 0OH CIsfill-t (Q-23) (Q-24) (Q-25) x/T/P:50/25/25 (weight ratio) (Q-26
) (Q-28) H (Q-27) (Q-29) Compounds represented by the general formula (1) in which C5H11- is used in the present invention are disclosed in, for example, JP-A-59-113440 and JP-A-59-1719.
No. 55, UK Patent No. 1284649, US Patent No. 3227
It can be synthesized by the method described in No. 550 and the like.

The compounds represented by formulas (A) and (I) of the present invention can be added to all layers of the light-sensitive material, but in order to prevent image quality deterioration due to unnecessary diffusion of oxidized developing agent, It is preferable to add it to a layer between photosensitive emulsion layers such as an intermediate layer or a yellow filter layer.

It can also be added to a light-sensitive emulsion layer to improve the graininess of images; in this case, addition to the red-sensitive emulsion layer is most effective, followed by addition to the green-sensitive emulsion layer. The amount added is 0.011 to 5 per Zerachi 7111 in the case of layers that do not contain a photosensitive silver halide emulsion, such as an intermediate layer, a protective layer, a yellow filter layer, and an anti-silver layer.
0jl, preferably from 0.01 to 101. Particularly preferred is a range of 0.1.9 to II. When added to a silver halide emulsion layer, the amount added is preferably in the range of 0.01 g to 100 N, more preferably 0.05 to 5 oy, per mole of silver halide.

In a preferred embodiment, [ is o, o o s ~ as the amount added to the non-photosensitive intermediate layer sandwiched between the photosensitive emulsion layers.
1. O1/go, more preferably 0.02 to 0.5
ri/go, more preferably 0.03 to 0.3.9/77
1' coating.

In the present invention, from the viewpoint of improving storage stability, general formula (B)
It is particularly preferred to add a compound represented by and/or phenol.

-Crest hole (B) Here, Ro represents an alkyl group having 1 to 5 carbon atoms.

Ro represents a methyl group, ethyl group, n-propyl group, 1-propyl group, n-butyl group, 1-butyl group, or 1-butyl group, preferably n-propyl group or n-butyl group. , n-butyl group is particularly preferred.

The light-sensitive material of the present invention only needs to have at least one silver halide emulsion layer of a blue-sensitive layer, a green-sensitive layer, and a red-sensitive layer on the support. There are no particular limitations on the number of layers and types of non-photosensitive layers; a typical example is to use a plurality of halogens with substantially the same color sensitivity but different photosensitivity on the support. A silver halide photographic light-sensitive material having at least one light-sensitive layer consisting of a silver emulsion layer, the light-sensitive layer being a unit light-sensitive layer sensitive to any one of blue light, green light, and red light. In a multilayer silver halide color photographic light-sensitive material, the unit photosensitive layers are generally arranged in this order from the support side: a red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer. However, depending on the purpose, the order of installation may be reversed, or the order of installation may be such that different photosensitive layers are sandwiched between the same color-sensitive layer.

Above, halogenation 1! Non-photosensitive layers such as various intermediate layers may be provided between the photosensitive layers and between the top and bottom layers.

The intermediate layer includes JP-A Nos. 61-43748 and 59-1.
No. 13438, No. 59-113440, No. 61-20
Coupler, DIR compound, etc. as described in No. 037 and No. 61-20038 may be included,
It may also contain a color mixture prevention agent as commonly used.

A plurality of silver halide emulsion layers constituting each unit photosensitive layer are composed of a high-speed emulsion layer and a low-speed emulsion layer, as described in German Patent No. 1.121,470 or British Patent No. 923.045. A two-layer structure can be preferably used0
Usually, it is preferable to arrange the halogen emulsion in a pattern in which the photosensitivity decreases toward the support, and a non-photosensitive layer may be provided between each halogen emulsion layer.
No. 112751, No. 62-200350, No. 62-2
As described in Nos. 06541 and 62-206543, a low-sensitivity emulsion layer may be provided on the side far from the support, and a high-sensitivity emulsion layer may be provided on the side close to the support.

As a specific example, from the side farthest from the support, low-sensitivity blue-sensitive layer (BL) / high-sensitivity blue-sensitive layer CB)I) / high-sensitivity green-sensitivity layer (GH) / low-sensitivity blue-sensitive layer ([, L)
/High intensity red photosensitive layer (R11)/Low sensitivity red photosensitive layer (R
L) or BH/BL/GL/GH/RH/RL
or in the order of BH/BL/GH/GL/RL/RH.

Further, as described in Japanese Patent Publication No. 55-34932, from the side farthest from the support, the blue-sensitive layer/Gll/
They can also be arranged in the order of RH/GL/RL. Alternatively, as described in JP-A-56-25738 and JP-A-62-63936, the blue-sensitive layer/GL/RL/Gll/RH may be arranged in this order from the farthest side from the support. .

In addition, as described in Japanese Patent Publication No. 49-15495, the upper layer is a silver halide emulsion layer with the highest sensitivity, the middle layer is a silver halide emulsion layer with lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement in which a silver halide emulsion layer with a low density is disposed and is composed of 3Ns having different photosensitivity, the photosensitivity of which is sequentially lowered toward the support. Even when it is composed of three layers with different photosensitivity, as described in JP-A-59-202464 specification 8,
In the same color-sensitive layer, a medium-sensitivity emulsion layer/high-sensitivity emulsion layer/low-sensitivity emulsion layer may be arranged in this order from the side remote from the support.

In addition, high-sensitivity emulsion layer / low-sensitivity emulsion layer / medium-sensitivity emulsion layer,
Alternatively, they may be arranged in the order of low-speed emulsion layer/medium-speed emulsion layer/high-speed emulsion layer, etc.

Furthermore, even in the case of four or more layers, the arrangement may be changed as described above.

As mentioned above, various layer structures and arrangements can be selected depending on the purpose of each photosensitive material.

The preferred silver halide contained in the photographic emulsion layer of the photographic light-sensitive material used in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide, containing about 30 mol% or less of silver iodide. . Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mole percent to about 25 mole percent silver iodide.

Silver halide grains in photographic emulsions include those with regular crystals such as cubes, octahedrons, and tetradecahedrons, those with irregular crystal shapes such as spherical and plate shapes, and those with twin planes. may have crystal defects, or a composite form thereof.

The grain size of the silver halide may be fine grains of about 0.2 microns or less, or large grains with a projected area diameter of up to about 10 microns, and may be a polydisperse emulsion or a monodisperse emulsion.

Silver halide photographic emulsions that can be used in the present invention include, for example, Research Disclosure (RD) Na17643
(December 1978), pp. 22-23.
nd types)”, and Doso 18716 (
(November 1979), p. 64B, "Physics and Chemistry of Photography" by Graf Kide, published by Paul Montell (P, Glaf
kids, Che*ic at Ph1sique
Photograph-ique+ Paul Mo
"Photographic Emulsion Chemistry" by Duffin, published by Focal Press (G, F, Duffia).

Photographic Emulsion C
hemistry (Focal Press.

1966)), "Manufacture and coating of photographic emulsions" by Zelikman et al., published by Focal Press (V, L, Zelikm)
anat al,, Making and Coat
ingPhotographic Emul-sion
, Focat Press+ 1964).

U.S. Patent Nos. 3.574.628 and 3.655.39
Monodisperse emulsions such as those described in No. 4 and British Patent No. 1,413,748 are also preferred.

Tabular grains having aspect ratios of about 5 or more can also be used in the present invention. Tabular grains are described by Gutoff, Photographic Science and Engineering.
ence and Engineering), Vol. 14, pp. 248-257 (1970); U.S. Patent No. 4
．． 434.226, 4,414.310, 4,
433,048, 4,439,520 and British Patent No. 2.112.157.

The crystal structure may be --like, the inside and outside may have different halogen compositions, it may be a layered structure, or silver halides with different compositions may be joined by epitaxial bonding. It may also be bonded with a compound other than silver halide, such as Rodan oxide or lead oxide.

A mixture of grains of various crystal forms may also be used.Silver halide emulsions that have been subjected to physical ripening, chemical ripening and spectral enhancement are usually used. Additives used in such processes are listed in Research Disclosure No. 1764.
3 and Sou 18716, and the relevant parts are summarized in the table below.

Known photographic additives that can be used in the present invention are also described in the above two Research Disclosures, and the relevant descriptions are shown in the table below.

1. Chemical aggravating agents, page 23, page 648, right column 2. Demonic enhancers Same as above 3. Spectral sensitizers,
Pages 23-24 Page 648 Right column ~ Chromatic enhancer
Page 649 right column 4 Brightener Page 24 5 Antifoggant Page 24-25 Page 649 right column ~ and stabilizer 6 Light absorber, page 25-26 Page 649 right column ~ Filter dye, Page 650 left column Ultraviolet LA absorption Agent 7 Anti-stain agent Page 25, right column, page 650, left to right column 8
Dye image stabilizer page 25 9 Hardener page 26 page 651 left column lO binder page 26 Same as above 11 'FIN agent, lubricant page 27 page 650 right column 12 Coating aid page 26-27 page 650 right column surface activity Agent 13 Static Page 27 Same as above Inhibitor In addition, in order to prevent deterioration of photographic performance due to formaldehyde gas, U.S. Pat.
It is preferable to add to the light-sensitive material a compound that can be immobilized by reacting with formaldehyde as described in No. 435.503.

Various color couplers can be used in the present invention, specific examples of which can be found in the above-mentioned Research Disclosure (
RD) It is described in the patent described in 1'7643, ■-〇-G.

As a yellow coupler, for example, U.S. Patent No. 3.93
3.501, 4.022.620, 4.3
No. 26.024, No. 4,401,752, No. 4,
248.961, Japanese Patent Publication No. 58-10739, British Patent No. 1,425.020, British Patent No. 1,476.760, U.S. Patent No. 3.973,968, British Patent No. 4.314.
No. 023, No. 4.511,649, European Patent No. 24
9.473A, etc. are preferred.

As magenta couplers, 5-pyrazolone and pyrazoloazole compounds are preferred, and US Pat.
0.619-4,351,897, European Patent No. 73.636, US Patent No. 3.061.432, US Pat. (June), JP-A-60-3
No. 3552, Research Disclosure NIIL
24230 (June 1984), JP-A-60-436
No. 59, No. 61-72238, No. 60-35730
No. 55-118034, No. 60-185951, U.S. Patent No. 4.500, 630, No. 4.540.
No. 654, No. 4.556,630, International Publication WO3
Particularly preferred are those described in No. 8104795 and the like.

Cyan couplers include phenolic and naphthol couplers, and are described in U.S. Patent No. 4,052.212.
No. 4.146,396, No. 4.228.23
No. 3, No. 4.296,200, No. 2.369.9
No. 29, No. 2,801.171, No. 2.772.
No. 162, No. 2.895,826, No. 3.112
．． No. 002, No. 3.758.308, No. 4,33
4.011, 4.327.173, West German Patent Publication No. 3゜329.729, European Patent No. 121, 36
No. 5A, No. 249°453A, U.S. Patent No. 1 3.4
No. 46.622, No. 4.333,999, No. 4.
No. 775.616, No. 4.451.559, No. 4
．． 427,767-4.690.889, 4.254°212, 4,296.199, and JP-A-61-42658 are preferred.

Colored couplers to correct unnecessary absorption of coloring dyes are described in Research Disclosure No. 17643.
- Section G, - U.S. Patent No. 4,163.670, Japanese Patent Publication No. 5
No. 7-39413, U.S. Patent No. 4. OQ4.929,
No. 4.138.258, British Patent No. 1.146.3
No. 68 is preferred, and US Patent No. 4.
No. 774.181, a coupler that corrects unnecessary absorption of a coloring dye by a fluorescent dye released during coupling, and a coupler that can react with a developing agent to form a dye, as described in U.S. Pat. No. 4,777.120. It is also preferred to use couplers having a dye precursor group as a leaving group.

Couplers whose coloring dyes have appropriate diffusivity include U.S. Patent No. 4.366.237 and British Patent No. 2.125.
．． 510, EP 96,570 and DE 3,234,533 are preferred.

Typical examples of polymerized dye-forming couplers are U.S. Pat.
No. 4.576°910, British Patent No. 2.102.
It is described in No. 173, etc.

Couplers that release photographically useful residues upon coupling are also preferably used in the present invention. DIR couplers that release development inhibitors include the aforementioned RD 17643.
, Patents described in sections ■ to F, Japanese Patent Application Laid-Open No. 57-15194
No. 4, No. 57-154234, No. 60-184248
No. 63-37346, U.S. Patent No. 4゜248.96
No. 2, No. 4°782.012 is preferred.

As a coupler that releases a nucleating agent or a development accelerator imagewise during development, British Patent No. 2.097.140;
No. 2.131,188, JP 59-157638
No. 59-170840 is preferred.

In addition, examples of couplers that can be used in the photosensitive material of the present invention include competitive couplers described in U.S. Pat. , long equivalent couplers described in JP-A No. 4,310.618, etc., DIR redox compound releasing couplers, DIR coupler-releasing couplers described in JP-A-60-185950, JP-A-62-24252, etc.
DIR coupler releasing redox compound or DIR redox releasing redox compound, European Patent No. 173゜3
Couplers that release dyes that produce aftercolor after separation described in No. 02A <R, D, Koji 11449, Koji 24241, JP-A-61
-201247, etc.; ligand-releasing couplers, as described in U.S. Pat. Cylinder 4,774,1
Examples include couplers that emit fluorescent dyes as described in No. 81.

The coupler used in the present invention can be introduced into the light-sensitive material by various known dispersion methods.

Examples of high boiling point solvents used in the oil-in-water dispersion method are described in US Pat. No. 2,322,027 and the like.

Specific examples of phthalic acid esters (dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, esters of phosphoric acid or phosphonic acid °ols (triphenyl phosphate, tricresyl phosphate,
2-ethylhexyl diphenyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl phosphate, tridodecyl phosphate, tributoxyethyl phosphate, trichloropropyl phosphate, di-2-ethylhexyl phenyl phosphonate, etc.)
, benzoic acid esters (2-ethylhexylbenzoate, dodecylbenzoate, 2-ethylhexyl-p-
hydroxybenzoate, etc.), amides (N, N-
diethyldodecaneamide, N,N-diethyllaurylamide, N-tetradecylpyrrolidone, etc.), alcohols or phenols (stearyl alcohol, 2
, 4-di-tert-amylphenol, etc.), aliphatic carboxylic acid esters (bis(2-ethylhexyl) sebacate, dioctyl azelate, glycerol tributyrate, instearyl lactate, trioctyl citrate, etc.), aniline derivatives (N , N-dibutyl-
2-butoxy-5-tert-octylaniline, etc.)
, hydrocarbons 11 (paraffins, dodecylbenzene,
diisopropylnaphthalene, etc.). Further, as the auxiliary solvent, an organic solvent having a boiling point of about 30°C or more, preferably 50°C or more and about 160°C or less, etc. can be used.
Typical examples are ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, cyclohexanone, 2-
Examples include ethoxyethyl acetate and dimethylformamide.

Examples of the process, effects, and latex for impregnation of latex dispersion methods can be found in U.S. Pat. It is described in No. 230, etc.

The color photosensitive material of the present invention includes JP-A-63-2577
No. 47, No. 62-272248, and JP-A-1-8
1,2-benzisothiazoline-3 described in No. 0941
-one, n-butyl ρ-hydroxybenzoate, phenol, 4-chloro-3,5-dimethylphenol,
2-phenoxyethanol, 2-(4-thiazolyl)
It is preferable to add various preservatives or fungicides such as benzimidazole.

The present invention can be applied to various color photosensitive materials. Typical examples include color negative film for general use or movies, color reversal film for slides or television, color paper, color positive film, and color reversal paper.

Suitable supports that can be used in the present invention include, for example, the above-mentioned R
D, Sou 17643, page 28, and the same NIIL 187
16, from the right column on page 647 to the left column on page 648.

In the photosensitive material of the present invention, the total thickness of all the hydrophilic colloid layers on the side having the emulsion layer is preferably 28 μm or less, and 23. Cra+ or less is more preferable, 20 μm or less is even more preferable, and membrane swelling rate T178 is preferably 30 seconds or less, more preferably 20 seconds or less.

The film thickness means the film thickness measured at 25°C and 55% relative humidity (2 days), and the film swelling rate T'+yt can be measured according to a method known in the art.
For example, Nie Green et al., Photographic Science and Engineering (Photogr, Sci, Eng,), 19@,
2, pp. 124-129 (
T'+zz can be measured by using a swelling membrane)
The saturated film thickness is defined as 90% of the maximum swelling film thickness reached when treated with a color developing solution at 30°C for 3 minutes and 15 seconds, and this T17!
Defined as the time it takes to reach a film thickness of .

The membrane swelling rate T,/ can be adjusted by adding a hardening agent to the gelatin used as bangu or by changing the aging conditions after coating. In addition, the swelling rate is preferably 150 to 400%. The swelling rate is calculated from the maximum swollen film thickness under the conditions described above, using the formula: (maximum swollen film thickness -
It can be calculated according to (film thickness)/film thickness.

The color photographic window light material according to the present invention is described in the aforementioned RD, Magnetics 17643, pages 28-29, and the same 18716, 6th page.
15. Development processing can be carried out by the usual methods described in the left column to right column.

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. Aminophenol compounds are also useful as color developing agents, but ρ-phinidinediamine compounds are preferably used, representative examples of which include 3-methyl-4-amino-N,N-diethylaniline, 3-Methyl-4-amino-N-ethyl-N-
β-hydroxyethylaniline, 3-methyl-4-amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-amino-N-ethyl-β-
Examples include methoxyethylaniline and their sulfates, hydrochlorides, p-toluenesulfonates, and the like.

Among these, 3-methyl-4-amino-N-ethyl-N-β-hydroxyethylaniline sulfate is particularly preferred, and two or more of these compounds may be used in combination depending on the purpose.

The color developer may contain pH buffering agents such as alkali metal carbonates, borates or phosphates, chloride salts, bromide salts,
It is common to include development inhibitors or antifoggants such as iodide salts, benzimidazoles, benzothiazoles or mercapto compounds. If necessary, various preservatives such as hydroxylamine, diethylhydroxylamine, sulfites, hydrazines such as N,N-biscarboxymethylhydrazine, phenyl semicarbazides, triethanolamine, and catechol sulfonic acids, ethylene glycol, Organic solvents such as diethylene glycol, development accelerators such as benzyl alcohol, polyethylene glycol, quaternary ammonium salts, amines, dye-forming couplers, competitive couplers, auxiliary developing agents such as 1-phenyl-3-pyrazolidone, viscosity imparting agents. agent, aminopolycarboxylic acid, aminopolyphosphonic acid,
Various chelating agents such as alkylphosphonic acids and phosphonocarboxylic acids, such as ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxyethylidene-1, 1-diphosphonic acid, nitrilo-N,N,N-)rimethylenephosphonic acid, ethylenediamine-N,N,N,N-tetramethylenephosphonic acid, ethylene glycol (0-hydroxyphenylacetic acid) and their salts. This can be cited as a representative example.

Further, when performing reversal processing, black and white development is usually performed and then color development is performed. This black and white developer contains dihydroxybenzenes such as hydroquinone! -Phenyl-3-
Known black and white developing agents such as 3-pyrazolidones such as pyrazolidone or aminophenols such as H-methyl-p-aminophenol can be used alone or in combination.

The pH of these color developing solutions and black and white developing solutions is generally 9 to 12. The amount of replenishment of these developing solutions depends on the color photographic window light material to be processed, but - in most cases, it is less than 31 per square meter of photosensitive material, and by reducing the bromide ion concentration in the replenisher, it can be increased to 500.
It can also be less than d. When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the area of contact with the air in the processing tank.

The contact area between the photographic processing solution and air in the processing tank can be expressed by the aperture ratio defined below.

That is, the above aperture ratio is preferably 0.1 or less, more preferably 0.001 to 0.05. As a method for reducing the aperture ratio in this way, in addition to providing a shield such as a floating lid on the surface of the photographic processing liquid in the processing tank,
Method using a movable lid described in No. 033, JP-A-63
The slit development processing method described in Japanese Patent No. 216050 can be mentioned. Reducing the aperture ratio is important not only for both color development and black and white development processes, but also for subsequent processes,
For example, it is preferable to apply it to all steps such as bleaching, bleach-fixing, fixing, washing, and stabilization.Also, the amount of replenishment can be reduced by using means to suppress the accumulation of bromide ions in the developer. .

The time for color development processing is usually set between 2 and 5 minutes, but it is possible to use a high temperature, high pH, and a high concentration of color developing agent.
By using this method, it is possible to further shorten the processing time.

After color development, the photographic emulsion layer is usually bleached.

The bleaching process may be carried out simultaneously with the fixing process (bleach-fixing process) or separately (bleach-fixing process), or in order to speed up the process, it may be carried out in two ways: bleach-fixing process after bleaching process. Depending on the purpose, treatment may be carried out in consecutive bleach-fixing baths, fixing treatment before bleach-fixing treatment, or bleaching treatment after bleach-fixing treatment. Examples of bleaching agents that can be used include compounds of polyvalent metals such as iron (I [ Use 7-minobocarboxylic acids such as acetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminopropanetetraacetic acid, glycol etherdiaminetetraacetic acid, or complex salts such as citric acid, tartaric acid, malic acid, etc. be able to. Among these, ethylenediaminetetraacetate iron (In) complex salt and 1,3-diaminopropanetetraacetate iron (Ill)! ! Aminopolycarboxylic acid iron(III) complex salts including salts are preferable from the viewpoint of rapid processing and environmental pollution prevention.
I[l) complex salts are particularly useful in both bleach and bleach-fix solutions. These 7-minopolycarboxylic iron iron (
III) The pH of the bleaching solution or bleach-fixing solution using complex salts is usually 4.0 to 8, but the pH can be lowered to speed up the processing.

A bleach accelerator may be used in the bleaching solution, bleach-fixing solution, and their prebaths, if necessary.

Specific examples of useful bleach accelerators are described in U.S. Pat. No. 3.893.858, German Pat.
．． No. 290.812, No. 2,059.988, JP-A No. 53-32736, No. 53-57831, No. 53-
No. 37418, No. 53-72623, No. 53-956
No. 30, No. 53-95631, No. 53-104232
Compounds having a mercapto group or a disulfide group described in JP-A No. 53-124424, No. 53-141623, No. 53-28426, Research Disclosure Th17129 (July 1978), etc.: JP-A-50-14α129 Thiazol l) Zine derivatives described in Japanese Patent Publication No. 45-8506, Japanese Patent Publication No. 52-20832, Japanese Patent Publication No. 53-32735, U.S. Patent No. 3.706.56
Thiourea derivatives described in No. 1; West German Patent No. 1.127.
No. 715, iodide salts described in JP-A-58-16.235; West German Patent Nos. 966.410 and 2,748.43
Polyoxyethylene compounds described in No. 0; Japanese Patent Publication No. 1973
-Polyamine compound described in No. 8836; Others
9-42.43m, 49-59.644, 53
-94.927, 54-35.727, 55-
Compounds described in No. 26.506 and No. 58-163.940; bromide ions, etc. can be used. Among these, compounds having a mercapto group or a disulfide group are preferred from the viewpoint of a large promoting effect, and are particularly preferred as described in U.S. Pat.
No. 8, West German Patent No. 1.290,812, Japanese Unexamined Patent Publication No. 1983-
The compounds described in U.S. Pat. No. 95.630 are preferred, and the compounds described in U.S. Pat. No. 4,552.834 are also preferred. These bleach accelerators are particularly effective when bleach-fixing photosensitive materials.

In addition to the above-mentioned compounds, it is preferable that the bleaching solution or bleach-fixing solution contains a component for the purpose of preventing bleach staining.A particularly preferred component is one having an acid dissociation constant (pea) of 2.
-5, specifically acetic acid, propionic acid, etc. are preferred.

Examples of fixing agents used in fixing solutions and bleach-fixing solutions include thiosulfates, thiocyanates, thioether compounds, thioureas, and large amounts of iodide salts, but thiosulfates are commonly used. Among them, ammonium thiosulfate is the most widely used. It is also preferable to use a combination of thiosulfate, thiocyanate, thioether compounds, thiourea, etc. As a preservative for fixing solutions and bleach-fixing solutions, sulfites, bisulfites, carbonyl bisulfite adducts, or European patented The sulfinic acid compounds described in No. 294769A are preferred. Furthermore, various aminobocarboxylic acids and organic phosphonic acids are preferably added to the fixing solution and bleach-fixing solution for the purpose of stabilizing the solution.

The total time for the desilvering process is preferably as short as possible without causing desilvering defects.The preferred time is 1 minute to 3 minutes, more preferably 1 minute to 2 minutes. In addition, the processing temperature is 25°C to 5°C.
0''C1 is preferably 35° C. to 45° C. In the preferred temperature range, the desilvering rate is improved and the occurrence of staining after processing is effectively prevented.

In the desilvering process, it is preferable that the stirring be as strong as possible.A specific method for strengthening the stirring is the treatment on the emulsion surface of the photosensitive material described in JP-A-62-183460 and JP-A-62-183461. There is a method of colliding liquid jets, a method of increasing the stirring effect using a rotating means as described in JP-A No. 62-183461, and a method of moving the photosensitive material without bringing the emulsion surface into contact with a wiper blade installed in the liquid. Examples include a method in which the stirring effect is further improved by making the emulsion surface turbulent, and a method in which the circulation flow rate of the entire processing liquid is increased. Such agitation enhancement means include bleaching solutions,
It is effective in both bleach-fixing solutions and fixing solutions. Improved agitation speeds up the supply of bleaching and fixing agents into the emulsion film,
It is thought that this increases the desilvering rate as a result. Also,
The agitation improvement means described above are more effective when a bleach accelerator is used, and can significantly increase the accelerating effect and eliminate the fixing inhibiting effect of the bleach accelerator.

The automatic developing machine used for the photosensitive material of the present invention is
No. 0-191257, No. 60-191258, No. 60
It is preferable to have a photosensitive material conveying means as described in Japanese Patent Laid-open No. 191259-1912. This effect is particularly effective in shortening the processing time in each step and reducing the amount of processing solution replenishment.

The silver halide color photographic light-sensitive material of the present invention is generally subjected to water washing and/or stabilization steps after desilvering treatment.

The amount of water used in the washing process depends on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), the application, the temperature of the washing water, the number of washing tanks (number of stages), the replenishment method such as countercurrent or forward flow, and various other conditions. Can be set over a wide range. Among these, the relationship between the number of washing tanks and the amount of water in the multistage countercurrent method is
urn-al of the 5ociety or
Motion Picture and Te1e-v
ision Engineers Vol. 64, p. 24
8-253 (No. 5'F1, 1955).

According to the multi-stage countercurrent method described in the above-mentioned literature, the amount of washing water can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria will multiply, and the generated suspended matter will adhere to the photosensitive material. In the processing of the color photosensitive material of the present invention, such problems can be solved by:
The method for reducing calcium ions and magnesium ions described in JP-A No. 62-288.838 can be used very effectively. Also, JP-A-57-8.542
Chlorinated disinfectants such as isothiazolone compounds, cyabendazole, chlorinated sodium incyanurate, and other benzotriazoles described in the issue, Hiroshi Horiguchi, "Chemistry of antibacterial and fungicidal agents J (1986), Sankyo Publishing, Hygiene Technology" Extra notes: “Eradication of microorganisms, stage surfaces, anti-mildew technology,” (1982)
Society of Industrial Engineers, Japan Antibacterial and Antifungal Society “Encyclopedia of Antibacterial and Antifungal Agents” (
It is also possible to use the fungicides described in (1986).

The pH of the washing water in the processing of the photosensitive material of the present invention is 4 to 4.
9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the photosensitive material, its use, etc., but generally it is 20 seconds to 10 minutes at 15 to 45°C, preferably 2
A range of 30 seconds to 5 minutes is selected at 5 to 40°C. Furthermore,
The photosensitive material of the present invention can also be directly processed with a stabilizing solution instead of the above-mentioned washing with water.

In such stabilization treatment, Japanese Patent Application Laid-Open No. 57-854
All known methods described in No. 3, No. 58-14834, and No. 60-220345 can be used.

Further, following the water washing treatment, a further stabilization treatment may be performed. An example of this is a stabilization bath containing a dye stabilizer and a surfactant, which is used as a final bath for color photographic materials. Examples of the dye stabilizer that can be used include aldehydes such as formalin and glutaraldehyde, N-methylol compounds, hexamethylenetetramine, and aldehyde sulfite adducts.

Various chelating agents and antifungal agents can also be added to this stabilizing bath.

The overflow liquid from water washing and/or replenishment of the stabilizing liquid can be reused in other processes such as the derailment process.

In a process using an automatic processor or the like, when each of the above-mentioned processing liquids is concentrated by expulsion, it is preferable to correct the concentration by adding water.

The silver halide color light-sensitive material of the present invention may contain a color developing agent for the purpose of simplifying and speeding up processing. In order to incorporate a color developing agent, it is preferable to use various precursors of the color developing agent. U.S. Patent No. 3.342.59
Indoaniline compound described in No. 7, No. 3.342,
No. 599, Research Disclosure 14.850
Schiff base-type compounds described in No. 15.159 and aldol compounds described in No. 13.924, U.S. Patent No. 3
．． Metal salt complex described in No. 719,492, JP-A-53-1
Examples include urethane compounds described in No. 35628.

The silver halide color light-sensitive material of the present invention may optionally contain various 1=phenyl-3
- Pyrazolidones may be incorporated.

Typical compounds are JP-A-56-64339 and JP-A No. 57-
No. 144547 and No. 58-115438.

The various processing solutions used in the present invention are used at a temperature of 10°C to 50°C. Usually, the standard temperature is 33°C to 38°C, but it is possible to accelerate the processing by increasing the temperature to a higher temperature. It is possible to improve the image quality and the stability of the processing solution by shortening or lowering the temperature.

In addition, West German Patent No. 2.226.7 was developed to save silver on photosensitive materials.
70 or U.S. Pat. No. 3,674,499 using cobalt intensification or hydrogen peroxide intensification.

Further, the silver halide photosensitive material of the present invention is disclosed in US Patent No. 4.
No. 500.626, JP-A No. 60-133449, No. 5
It can also be applied to the heat-developable photosensitive materials described in No. 9-218443, No. 61-238056, European Patent No. 210.66OA2, and the like.

Example 1 A multilayer color photosensitive material 101 was prepared by coating layers having the compositions shown below on a base coated cellulose triacetate film support having a thickness of 86 μm.

(Photosensitive layer composition) The numbers corresponding to each component indicate the coating amount expressed in y·/g units, and for silver halide and colloidal silver, the coating amount is expressed in terms of silver. However, for sensitizing dyes, the coating amount is expressed in moles per mole of silver halide in the same layer.

11th (Haleyshiron prevention layer) Black colloidal silver 0.16So
1v -40,14 Gelatin 2.08a1
v -50,07 Cpdv-30,2 Soxv -30,02 Solv -10,03 Solv -20,25 2nd layer (intermediate layer) Fine grain silver bromide (average particle size 0.07 μm) Gelatin 3rd layer (low Sensitivity red-sensitive emulsion layer) (hereinafter simply referred to as coefficient of variation) 21%) Gelatin ExS -1 f2xS -2 ExE3-3 XC-1 1xC-2 ExC-3 Cpd -1 Solv -1 Solv -3 Solv -2 So1mer 5 Soxv -4 0,15 1,3 1,3 2,2 4, OX 10" 2, OX 10-' 0.6 X 10-' 0.7 0.06 0.02 0.01 0.8 0 .06 0.2 0.08 0.1 4th layer (highly sensitive red-sensitive emulsion layer) Polydisperse silver iodobromide emulsion (silver iodide 10.0 molar average grain size 0
．． 8 μm, coefficient of variation 27%) L2 zectin
1.9T2xS-16X1
0″ EXS -23X10-' ] IExS -30,9X 10-' ExC-40,14 BxC-50,03 IxC-20,04 E engineering Q + 3 0.0
1 Solv -40,08 Soxv -10,03 Solv -50,01 Solv -20,3 Solv -30,02 5th layer (middle layer) To gelatin cp -2 Solv -3 0,80 0,05 0,02 6 layers (low-sensitivity green-sensitive emulsion layer) Monodispersed silver iodobromide emulsion (silver iodide 5 molar ratio, average grain size 0.3
Monodisperse silver iodobromide emulsion (silver iodide 7 molar coefficient, average grain size 0.5 μm variation coefficient 19 cm)
μm, coefficient of variation 20cm) Gelatin EXE-4 T2xS -5 EXE -5 ExM -6 1F:xM -7 EXM -8 ExC-9 Solv-2 Soxv -l 5OIV -4 Solv -3 Solv -5 0,35 0 ,65 1,9 2X 10-'8X10"-' 2X 10"-' 0.25 0.4 0.16 0.05 1.3 0.02 0.12 0.03 0.02 7th layer (high Sensitive green-sensitive emulsion layer) Polydisperse silver iodobromide emulsion (silver iodide 10.0 molar ratio, average grain size 0.8 μm, coefficient of variation 19 inches) Gelatin ExS-4 1i2xs -5 ExS -6 ExM = 7 E: M -8 ExC-9 Solv -l 5o1v -2 Solv -3 Solv -4 0,75 1,1 1,4X 10-'5.6X10"-'1.4X10"-' 0.05 0.04 0. 01 0.005 0.3 0.02 0.06 8th layer (yellow filter layer) Yellow colloid 0 silver gelatin So'lv -1 Cpa -2 S01mer3 0.04 0.3 0.007 0.2 0 .02 Solv-2 Solv-4 No. 97M (Low-sensitivity blue-sensitive emulsion M) Monodispersed silver iodobromide emulsion (silver iodide 4 mol ratio, average grain size 0.3
μm1 coefficient of variation 20%) Monodisperse silver iodobromide emulsion (silver iodide 8
Gelatin (average particle diameter 0.6 μm, coefficient of variation 18%) Gelatin ExE3-7 EXS -8 xY-10 ExC-3 Soxv -l 5o1v-2 So1mer3 So1+tr -4 10th layer (high sensitivity blue-sensitive emulsion layer) Monodisperse silver iodobromide emulsion (silver iodide 10 mmol average grain size 1.
5μm, coefficient of variation 17cm) Gelatin 0.2 0.04 0.25 0.25 2.60 3X 10"-'3X10-' 1.40 0.05 o, o o 5 O13 0,05 0,08 0 ,65 1,7 ExS-7 EXS -8 Morch, average particle size 0.0
7μm) Gelatin cpa -3 cpa -4 Cpa -5 0pd -6 Soxv -l 5o1v -3 Sobmer4 X1O-4 2X 10-' 0.4 0.003 0.02 0.02 0.1 0.03 0 .33 0.8 0.1 0.1 0.1 0.1 0.05 0.03 0.05 12th layer (second protective layer) Gelatin 0.13 Polymethyl methacrylate particles (diameter 1.5 μm) CI ) (L -8 Solv -l 5o1v -3 Solv-4 0,2 0,5 0,05 0,03 0,05 Each layer contained 0.1 wt% cpa with respect to gelatin.
-to, and Q, 2wt of CpcL-11 were added.

In addition, a surfactant Cpa-7 and a hardening agent H-1 were added.

Exa　-1: ExS-2: EXS-5: Bxf3-3: ExS-6: Ex? 3-4: (CH2)3S03Na T2xE3-7: (CH2)3So3 (CH2), 5O3N! L ExS-8: (ai2)3S03 (CT12)3SOsNa EXC-4: ExC-5: ExC-1: xM-7 xM-9 l ExC-2 xM-6 XY-10 EXC-3 ExC-9 CP (1-1 Cpa -6 o1v-1 Soxv-3 2H5 cpa -2 Cpa -3 C4Hs(t) Cpd -4 cpa -5 C4fl, (t) olv-4 Soxv-5 cpa -7 CpA-8 N) IC (Jj4 to 12 H-1 CH, = CH-5o2- CH2 CH,=CH-5o2-CB2 CP(1-9 Cp and -10 Cp(L-11 did.

Color development processing *Replenishment amount: 35cm wide photosensitive material per 1m length.

A processing solution having the following composition was also prepared.

(Sample 102-106) Cpa -2 of the 5th layer and 8th layer of sample 101 is
) (1-6, Compound (5) of the present invention, Sumi 3, (Q-19
) and (Q-21') in equimolar amounts to prepare samples 102, 103, 104, 105 and 106. These samples were slit to a width of 6.1α, rolled up together with light-shielding paper as shown in Fig. 3, and processed into cartridges to produce photosensitive materials A-F stored in the cartridges (the method for storing the cartridges was Fuji Photo Film). 110 size and 126 size manufactured by Co., Ltd.).

Prepare two of each of these photosensitive materials, cover the opening with black paper,
6cIrLx4I. A Fuji Photo Film Co., Ltd. Kema Fujica G5645 was modified by removing the back cover, and the above cartridge was loaded, and a Macbeth color checker chart was photographed using 15O100 standard exposure.

One of the photographed specimens was placed in a freezer, and the remaining one was left at 60° C. and relative humidity of 60° C. for 3 days.

After that, the following color development process was performed, and the optical density was 0.44.
The gray plate part and the unexposed part are on the density side (color developer) Diethylenetriamine Pentaacetic acid Sodium sulfite Potassium carbonate Potassium bromide Potassium iodide Human 90 Xylamine sulfate 4-[N-ethyl-N-β- and b0oxyethyl Amino] -Add 2-methylaniline sulfate and H (Bleach solution) -(A) 1.3-Diaminopropanetetraacetic acid iron Tsukuda) Ammonium 1.3-diaminopropanetetraacetic acid Ammonium bromide Acetic acid mother liquor (II) 5 .0 4.0 30.0 1.3 1.2m9 2.0 4.7 1.01 10.00 Replenisher (Ii) 6.0 5.0 37.0 O05 3,6 6,2 1,01 10,15 Mother liquor (Me) Replenisher (,9) 0.25 mol 0.30 mol 3.0 4.0 Add ammonium nitrate water and adjust pH with acetic acid and ammonia (fixer) Sodium sulfite ethylenethia tetraacetate Sodium bisulfite ammonium thiosulfate aqueous solution (700 Jl/liter Rhodane ammonium thiourea 3.6-cythia 1.8-octanediol Add water and ammonia acetate to pH 1,01 PH 4,3 Mother liquor (I) 1.5 10. 0 8.0 17Q, Qm 100.0 3.0 3.0 1.0/ 6.5 (Stable solution) Mother liquor, replenisher common formalin (37ti) 5-chloro-2-methyl-4-inthiazoline- 3-one 1.0j PH3,5 Replenisher <11> 1.8 12.0 10.0 20 Q, Qmj 150.0 5.0 5.0 1.01 6.7 1.2- 6.0η 2 -Methyl-4-inchazolin 3-one surfactant (C1oHzt -0moCH2CH2O+xoH) Add ethylene glycol water to pH 3,0RI C04 1,Ol 5.0-7.0 Change concentration for each freezer stored sample are shown in Table 1.

It can be seen from Table 1 that the photographic performance of the photosensitive material housed in the cartridge of the present invention after photographing is small.

Example 2 The openings of the photosensitive material E of Example 1 were covered with black paper to form the openings as shown in Table 2. Photosensitive materials 1-1 to 1-5 were prepared as shown in Table 2. These photosensitive materials were loaded into the camera used in Example 1, and the half body of a woman, two men and women, and a distant view of a mountain were photographed outdoors on a sunny day. These photographed photosensitive materials were color developed using the same processing solution as in Example 1. Processed photosensitive material is transferred to Fuji Enlarger A6
Fuji color suit Z-HG 4-z4-K burned at 4x magnification at 90 Professional Festival, CR23
A standard treatment was performed. Cut out only the photographed portion of the resulting prints, place these prints on a gray plate with a reflection density of 0.18, and use a fluorescent knife for color evaluation to determine whether the prints are favorable or unpleasant. I asked them to rank things in order.

The results obtained are shown in Table 2. From Table 2, prints made from the photosensitive material of the present invention have above-average desirability;
The effectiveness of the invention is demonstrated.

* The most preferred one was given 5 points, the second most preferred one was given 4 points, each point was deducted by 1 point, and the least preferred one was given 1 point, and the average value of the three scenes of 20 people was taken.

Example 3 Sample 301, which is a multilayer color light-sensitive material, was prepared on a cellulose triacetate film support having a thickness of 86 .mu.m and undercoated with each layer having the composition shown below.

(Composition of photosensitive layer) The coating amount is g/g for silver halide and colloidal silver.
The amounts of silver are expressed in rrr, and the amounts of coupler additives and ceratin are expressed in g/rd, and the sensitizing dyes are expressed in moles per mole of silver halide in the same layer. .

1st layer: antihalation layer black colloidal silver Silver coating amount 0. 2 Gelatin 2. 2UV-10,
l UV-20,2 Cpd-10,05 Solv-10,01 Solv-20,01 Solv-30,08 2nd layer: Intermediate layer fine grain silver bromide (equivalent sphere diameter 0.07 μm) Silver coating amount
0.15 Gelatin 1.0ExC-
40,03 Cpd-2・0.2 3rd layer:
First red-sensitive emulsion layer Silver iodobromide emulsion (AgI 8.5 mol%, internal high Agl
Type, equivalent sphere diameter 1.0 μm, coefficient of variation of equivalent sphere diameter 25%,
Plate-shaped particles, diameter/thickness ratio 3.0) Silver coating amount 0.
42 silver iodobromide emulsion (Ag1 4.0 mol%, internal high Ag
L type, equivalent sphere diameter 0.4 μm, coefficient of variation of 1 sphere equivalent diameter 22%
, dodecahedral particle primate coating l O, 33 gelatin 1. OE x
S-14,5X10-'mol Ex S-21,5X10-'mol Ex S-
30,4XlO-'mol ExC-10,40 ExC-2 ExC-3 ExC-4 olv-1 4th N: Second red-glare emulsion layer silver iodobromide emulsion (Ag1 8.5 mol%, internal high Agl type, Equivalent sphere diameter 1.0 μm, coefficient of variation of equivalent sphere diameter 25%, plate-like particles, diameter/thickness ratio 3.0) Gelatin xS-1 xS-2 xS-3 ExC-1 ExC-2 ExC-4 olv -1 5th layer: 3rd red-sensitive emulsion layer Silver iodobromide emulsion (AgI Silver coating amount 11.3 mol%, 0.55 0.7 3X10-'mol I X 10-'mol 0.3X10-'mol 0, 10 0.05 0.025 0, 20 Internal high Agl type, equivalent sphere diameter 1.4 μm, coefficient of variation of equivalent sphere diameter 28%, plate-shaped particles, diameter/thickness ratio 6.0) Silver coating amount 1. 29 0.6 2X10-'mol 0.6X10-'mol 0.2X10-'mol 0.08 0, 01 0.06 0, 12 0, 12 Gelatin ExC-t 4 ExC-5 olv-1 olv-2 6th layer: Intermediate layer gelatin pd-5 olv-1 7th layer: 1st green-sensitive emulsion layer Silver iodobromide emulsion (Ag1 8.5 mol%, internal high AgI type , equivalent sphere diameter 1.0 μm, ■, 0 0.1 0.1 Coefficient of variation of equivalent sphere diameter 25%, plate-like particle, diameter/thickness ratio 3
．． 0) Silver coating amount Silver iodobromide emulsion (AgI 4.0 mol%, internal high AgI
Type, equivalent sphere diameter 0.7 μm, coefficient of variation of equivalent sphere diameter 38%,
Plate-shaped particles, diameter/thickness ratio 2.0) Silver coating amount Gelatin xS-5 xS-6 xS-7 xM-1 xM-2 xM-5 olv-1 olv-4 8th layer: 2nd green-sensitive emulsion layer Silver iodobromide emulsion (Ag1 8.5 mol%, internally high iodine type, equivalent sphere diameter 1.0 μm, 0,28 1.0 1.2 5X10-' mol 2X10-' mol I X 10-' mol 0. 50 0,10 0.03 0.2 0.03 0,47 0,35 3.5X10-'mol1.4X10-'mol0.7X10-'mol0,12 0.01 0,15 0,03 Sphere Coefficient of variation of equivalent diameter 25%, plate-shaped particles, diameter/thickness ratio 3
．． 0) Silver coating amount Gelatin xS-5 xS-6 xS-7 xM-1 xM-3 olv-1 olv-4 9th layer: Intermediate layer gelatin 0.5 10th layer: 3rd green-sensitive emulsion layer Iodobromide Silver emulsion (AgI 11.3 mol%, internal high Ag
L type, equivalent sphere diameter 1.4 μm, coefficient of variation of equivalent sphere diameter 28%
, plate-like particles, diameter/thickness ratio 6.0) Gelatin silver coating amount 1, 3 0.8 2 X 10-' mole o, 5xio-' mole 0.8 0.01 0.2 xS-5 xS-6 xS-7 xM-3 xM-4 xC-4 p d-5 Solv-1 11th layer: Yellow filter layer pd-3 Gelatin Solv-1 12th layer: Intermediate Layer gelatin p d-2 13th layer: 1st blue-sensitive emulsion layer Silver iodobromide emulsion (Ag1 10 mol%, internal high iodine type, equivalent sphere diameter 0.7 μm, coefficient of variation of equivalent sphere diameter 14%, 14 Face piece particle) Silver coating! 0.1 0.5 0.1 0.05 0.5 0.1 Silver iodobromide emulsion (Ag1 4.0 mol%, internal high Agl type, equivalent sphere diameter 0.4 μm, coefficient of variation of equivalent sphere diameter 22 %, dodecahedral particles) Silver coating amount 0.05 Gelatin 1.0ExS-
83X10-'mol ExY-10,6 ExY-20,02 Solv-10,15 14th layer: 2nd blue-sensitive emulsion layer silver iodobromide emulsion (Ag1 19.0 mol%, internal high Agl
Type, equivalent sphere diameter 1.0 am, coefficient of variation of equivalent sphere diameter 16%,
Dodecahedral particles)! ! Application 1 0.19 Gelatin 0. 3E x
S -82X10-'mol ExY-10,22 Solv-10,07 15th layer: Intermediate layer fine grain silver iodobromide (Ag 12 mol%, uniform type, equivalent sphere diameter 0.13 μm) tI! Coating amount Gelatin 16th layer: 3rd blue-sensitive emulsion layer Silver iodobromide emulsion (Ag1 14.0 mol%, internal high AgI
Type, equivalent sphere diameter 1.7 μm, coefficient of variation of equivalent sphere diameter 28%,
Plate-shaped particles, diameter/thickness ratio 5.0) 0.2 0, 36 Gelatin xS-9 ExY-1 Solv-1 17th layer: 1st protective layer Gelatin V-1 V-2 Solv-I Solv-2 18th layer: 2nd protective 8W layer Silver coating amount 1.4 0.5 1.5X10-'mol 0.2 0.07 Fine particle silver chloride (equivalent sphere diameter 0.07 μm) Silver coating amount
0.36 Gelatin 0.7 Polymethyl methacrylate particles (diameter 1.5 μm) 0.2W-
10,02 H-10,4 Cpd-61,0 In addition to the above, each layer contains B-1 (total 0.20 g/m")
, 1,2-benzisothiazolin-3-one (about 200 ppm on average based on gelatin), n-butyl p-hydroxybenzoate (about 1.000 ppm on average), and 2-phenoxyethanol (about 10,000 ppm on average)
) was added.

ExC-5 ExM-1 UV-1: UV-2: 'f2xc -1 I H x/y=7/3 (weight ratio) (weight ratio) Average molecular weight 40.000 ExC-2 ExC-3 ExC-4 ExM -2 ExM-4 l PExS -3 F2xS-5 xS-6 Kan s-7 ExY-5 ExY -1 ExY -2 xS-2 EXS -8 olv-1 Soxmer 2 o1v-3 S01mer 4 cpa -5 cpa -1 Cpd -6 H cpa -2 E C3li''17SO□NHCH2CH2CH20CH2
CH2N(CH3) 3Cpd -3 (Samples 302 to 306) C, Ri(L -5 in the 6th layer of Sample 301 and cpa -2 in the 12th layer were replaced with the compound of the present invention (Q-15), (Q
Samples 302 to 305 were prepared by replacing -19), (13) and (17) in equimolar amounts. Furthermore, 1,2-benzisothiazoline-3- contained in each layer of sample 305
on, n-7'thyl-p-hydrozoate, 2
- Sample 306 was prepared from which phenoxyethanol was removed. These samples were stored in a cartridge whose size was changed from Fig. 3 (the film size was changed to 35m x 550cm).
The size of the light-shielding paper was 35.2 m x 950 cm.

(12 sheets were swept). This cartridge was left for 2 days at 25°C and 50% relative humidity, and under the same conditions 120+mX
60cm Dennate Moistureproof Paper (Fuji Photo Film Co., Ltd.)
Same as 110 size and 120 size packaging paper)
Two each of photosensitive materials G1 artificial, J, K, and L were prepared.

One of each of these was left in a freezer, and the remaining one was left at 50° C. for 7 days, after which the following color development was performed.

As described above (after exposing the color photographic light-sensitive material, use an automatic processor and process as described below until the cumulative replenishment amount of the solution becomes three times the capacity of the mother solution tank) using Super HG-4.
Processed with 00.

Table - Processing method Processing time Processing temperature Replenishment amount Tank capacity 3 minutes 15
seconds 38℃ 33tnl 2016 minutes 30
seconds 38℃ 2511114012 minutes 10 seconds
24℃ 1200117 2014 minutes 20 seconds
38℃ 25rnl 3011 minutes 05 seconds
24℃ (2 k) et al (1b 10! Countercurrent piping system.

1 minute 00 seconds 24℃ 12001117 lo
Jl minute 05 seconds 38℃ 25ag 104
! 4 minutes 20 seconds 55°C Replenishment amount per 35 m width and 1 m length Color development Bleaching Washing Fixing Washing with water (1) Washing with water (2) Stable drying Next, the composition of the processing solution is described.

(Color developer) diethylenetriaminepentaacetic acid 1-hyproxyethylidene-1゜1-diphosphonic acid Sodium sulfite Potassium carbonate Potassium bromide Potassium iodide Hydroxyl amine sulfate 4-[N-ethyl-N-β- hydroxyethyl az)] - Add 2-methylaniline sulfate solution and H (Bleach solution) Mother solution (,?) Replenisher solution (,9) 1.0 1.1 3.0 4.0 30.0 1.4 1. 5■ 2.4 2.8 4.5 5.5 1, O1! 1.01 10.05 10.10 Mother liquor (M) Replenisher (F) Ethylenediaminetetraacetic acid ferric sodium trihydrate 100.0 Ethylenediaminetetraacetic acid disodium salt 10.0 120.0 11.0 Ammonium bromide 140. 0 ammonium nitrate 30.0 ammonia water (27 ti)
Add 6.5m water
t, o ipH6,0 Ethylenediaminetetraacetic acid disodium salt 0.5 Sodium sulfite 7.0 Sodium bisulfite
5.0 Ammonium thiosulfate aqueous solution (70%)
Add tyo and oml water 1.0
IPH6,7 (stable solution) Mother liquor <y) Formalin (37%') 2.0rtt
l Pholioxyethylene-p-monononylphenyl ether (average degree of polymerization 10) 0.3 Ethylenediaminetetraacetic acid disodium salt 0.05 Add water and H 1,Ol 5.0-8.0 160.0 35.0 4,〇-1,0! 5.7 0.7 8.0 5.5 2 Q O,0I1 1,Ol 6.6 Replenisher 9 3,Od 0.45 0.08 t,Ol 5.0-8.0 50 for freezer stored products Table 3 shows the variations in the minimum yellow, magenta, and cyan densities of the products stored at °C.

Table 3 Example 4 Using Sample 104 of Example 1, photosensitive materials D-1 to D-6 having openings shown in Table 4 were produced. These and the photosensitive materials used in the RFT Example were loaded into a camera, three scenes of people and one scene of scenery were photographed, developed and printed. Print size is 12cIPL x 8cWL
The magnification was adjusted so that These were printed one by one and 25 men and women were asked to evaluate whether they were acceptable or not.

Table 4 shows that the photosensitive material of the present invention can be tolerated by most people.

Also, the opening is 9cFILx6cr! L (screen effective area 5
When a photosensitive material with a length of 4 m” was prepared, the above G564
It was found that an even larger camera than the modified model No. 5 was required, and that a camera larger than the size of the present invention would be too large and inconvenient.

Table 3 shows that the photographic performance of the photosensitive materials of the present invention shows little change during storage.

Table "Average value of 25 people and 4 scenes with 1 point acceptable and 0 points unacceptable Example 5 Samples 104 and 105 were processed into the same cartridge as in Example 3, and the screen size stored in the cartridge was 3.6 cm
A photosensitive material of X%y of 2.41 was prepared. These light-sensitive materials were loaded into a camera which had been modified so that the above cartridge could be loaded by removing the back cover etc. of a Tough Guide Date for a 135 cartridge size camera manufactured by Fuji Photo Film Co., Ltd., and photographed and printed in the same manner as in Example 4. . The tolerance obtained in each case was 0.97.

It was also found that this camera was smaller than the cameras used in Examples 1 to 4, making it more convenient to carry.

[Brief explanation of drawings]

FIG. 1 shows the positional relationship between the cartridge of the present invention and the camera. 1 represents the cartridge of the present invention, and 2 represents a camera compatible with it. FIG. 2 represents the cartridge of the invention from the front. FIG. 3 shows the film and light-shielding paper inserted into the cartridge of the present invention. 3 is film (width 61.0 pigeon length 8
35cm), 4 is light-shielding paper (width 63.0cm, length 1040cm)
Respect). Engraving of the drawing (no changes to the content) Figure 1

Claims (1)

[Scope of Claims] A film roll chamber in which a photographic light-sensitive material having a silver halide emulsion layer provided on a support is wound in advance and stored therein, a winding chamber in which the photographic light-sensitive material is wound and stored after photography, and a light-sensitive material in which these are connected. In a silver halide photographic light-sensitive material housed in a cartridge having a bridge portion having an opening for exposing light, the effective screen area per frame exposed to the light-sensitive material at the opening is 3.0 cm^2 or more25 .0cm
^2 or less, the ratio of the length of the long side to the length of the short side of one frame of screen is 1.1 or more and 2.0 or less, and the photosensitive material has the following general formula (A) and/or General formula ( I
) A silver halide photographic material housed in a cartridge. General formula (A) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ In the formula, R_a and R_b are hydrogen atoms, halogen atoms, sulfo groups, carboxyl groups, alkyl groups, acylamino groups,
It represents an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a sulfonyl group, an acyl group, a carbamoyl group, or a sulfamoyl group, and R_a and R_b may jointly form a carbon ring. X is -CO- or -
Represents SO_2-. R_c represents an alkyl group, an aryl group, a heterocyclic group, a cycloalkyl group, an alkoxy group, an aryloxy group, or an amino group. R_a, R_b, R_
The total number of carbon atoms in c is 10 or more. The compound of general formula (A) is substantially colorless and does not form a color image through a coupling reaction with a developing agent. General formula (I) ▲There are mathematical formulas, chemical formulas, tables, etc.▼ In the general formula (I), Coup represents a coupler residue having a coupling active position, Ball is bonded to the coupling active position of Coup, and the general formula ( I) A group having the size and shape necessary to impart diffusion resistance to the compound represented by
Sol represents a group that can be separated from Coup, and Sol is a solubilizing group, which binds to the non-coupling position of Coup and allows the coupling product (usually an azomethine dye) produced by the coupling reaction to be subjected to color development processing or subsequent processing. Represents a group that allows elution from the photosensitive material to the outside of the system during processing.