JPH02273743A - Silver halide photographic sensitive material housed in cartridge - Google Patents

Abstract

PURPOSE:To obtain a print having excellent sharpness and color reproducibility and the aspect ratio of the image plane which is mentally and physiologically preferable in terms of visual sensation by incorporating a specific compd. into the photosensitive material and housing this photosensitive material into a specific cartridge. CONSTITUTION:The photosensitive material contains the compd. expressed by formula I. The effective image plane area per frame to be exposed to the photosensitive material in the aperture of the cartridge is 3.0 to 25.0cm<2> and the ratio of the length on the long side to the length on the short side of the image plane of one frame is 1.2 to 2.0. In the formula, R1 to R4 respectively denote a hydrogen atom, lower alkyl group; R5 denotes a hydrogen atom, acyl amino group, etc.; n denotes 1 to 4 integer; TIME denotes a timing group which is eliminated together with DI and can then release the ID when the compd. of the formula I reacts with a color developing agent; DI denotes a development inhibitor. The print having the excellent sharpness and color reproducibility and the aspect ration of the image plane which is mentally and physiologically preferable in terms of visual sensation are obtd. in this way.

Description

DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a silver halide photographic material housed in a cartridge.

[Conventional technology]

Conventional cartridges for silver halide photographic materials include screen size co, rcmXλ, r! cm so-called instamatic size / colossal size cartridge (
The standard contents are ANSI/ASCPH/, 11-0-/re), jcm
PHt, rr-7rit6), etc. have been used. It is true that these cartridges have advantages such as being easy to load into the camera, being less likely to malfunction, requiring no winding when taking out the film after shooting, and being easy to take out and reload the film during shooting. However, recently, the usage rate has decreased due to the small screen size, poor surface quality when printing, the aspect ratio of the print, which is close to 0, making the print feel unstable, and making it uncomfortable to look at. I've been doing it.

Recently, disposable photosensitive material cartridges such as "Utsurun desu" and "Utsurun desu HiJ" have become popular, but because they are disposable, the price per frame is high. There was.

It is known that the compound of the present invention is used in ordinary silver halide photosensitive materials, but when stored in these T-7lQ size or /44 size cartridges, the screen size is small and the magnification is large. Therefore, the graininess is noticeable, it is difficult to obtain good sharpness because it is easily blurred when printing, and the aspect ratio of the screen is unfavorable, giving a sense of visual psychological and physiological instability. Ta.

Also, there are so-called /3r size /31 cartridges and 1.
A size 20 brownie film containing the compound of the present invention had problems with operability such as loading and winding.

Therefore, there has been a need for a photosensitive material for cartridges that is easy to handle, has high image quality, and is inexpensive.

[Problem to be solved by the invention]

The purpose of the present invention is, firstly, to provide a photosensitive material housed in a cartridge for producing prints with excellent sharpness and color reproducibility, and secondly, to provide a photosensitive material housed in a cartridge for producing prints with excellent sharpness and color reproducibility. Thirdly, it is necessary to supply such a photosensitive material that has an appropriate screen size that does not blur during printing, and thirdly, it is easy to handle the photosensitive material. Is to supply, No.! The second purpose is to supply the photosensitive material for cameras that are not disposable/low in price per frame, and the third purpose is to provide the photosensitive material that has a good shelf life.

[Means to solve the problem]

The above objects of the present invention have been achieved by a silver halide photographic material housed in the following cartridge.

A photographic effect in which a silver halide emulsion layer is provided on a support,
1. A halogen film stored in a cartridge that has a film roll chamber in which the photosensitive material is wound and stored in advance, a take-up chamber in which the film is wound and stored after shooting, and a bridge section that connects them and has an opening for exposing the photosensitive material. In the silver photographic light-sensitive material, the effective screen area per frame exposed to the light-sensitive material at the opening is i, ocm2 or more 2r,
0 cm2 or less, the ratio of the length of the long side to the length of the short side of the screen of one frame is i, i or more and λ, O or less, and the photosensitive material is a compound represented by the following general formula (1) A silver halide photographic material housed in a cartridge characterized by containing.

General formula (1) In the formula, R1, R2, R3 and R4 each represent a hydrogen atom or a lower alkyl group, and R5 represents a hydrogen atom, an aclaramino group, a sulfonamide group, a phosphonamide group, an alkoxycarbonylamino group, or an aryloxycarbonylamino group. group, alkoxysulfonamide crystal, aryloxysulfonamide group, carbamoylamino group, or sulfamoylamino group, n is an integer from 1 to ≠, and TIME is the reaction of the compound represented by general formula (1) with the color developing crude drug. represents a timing fund that can leave with DI and subsequently release DI, where DI represents a development inhibitor.

The present invention will be explained in detail below.

The cartridge of the present invention comprises a film roll chamber for storing a roll of unexposed photosensitive material, a take-up chamber for winding up the exposed photosensitive material, and a bridge section connecting them and having an opening. The effective screen area per frame exposed to the photosensitive material is i,ocm
The length is 2j or more, 00m or less, and the length is relative to the length of the short side of the 7-frame screen.

Ratio of side lengths (aspect ratio is /, / or more).

It is less than or equal to θ.

The preferred effective screen area is t # Oc m or more/
B, θcm or less, particularly preferably r, QCm
It is not less than 10.0 cm2. If the effective screen area is too small, image quality such as graininess and sharpness will be less noticeable to the user. If the effective screen area is too large, the size of the camera will increase, making it even harder for users to easily enjoy taking photos anytime and anywhere.

A preferable aspect ratio is 7.3 or more/and 7 or less, more preferably 1. 1. is below. In general, the preferred aspect ratio is known as the golden section i, t/r, but the optimum aspect ratio for photographic prints was determined based on a monitor test for -acid users.

Especially the current 73! Format's color negative/Eno's Labo 7 stem service system is very complete.
It is highly desirable for the user to select screen sizes and film widths that are compatible with the system.

Preferred film width II′i, 3! ±/m/m, particularly preferably 3! ±0−! m/m.

Figure 1 shows the appearance of a typical cartridge. In addition, Figure 2 shows a conceptual diagram of the relationship between the cartridge and the camera (just before insertion).With this type of conventional cartridge,
It has been common knowledge to use light-shielding paper as disclosed in Japanese Patent Publication No. 32-lμ≠06 and Japanese Patent Publication No. 0-/71 Kota.

However, the presence of light-shielding paper causes deterioration of the flatness of the film at the exposure aperture, making it difficult to obtain sharply focused photographs, and increasing the screen size (which reduces the effect by half), which is undesirable. It is preferable to remove the light shielding means and adopt another light shielding means.Examples of the light shielding means are illustrated below.

(1)/7 seems to be used for the exit of Jj's pato-ne
j 17 Attach a bong to the exit of the film roll chamber and the entrance of the winding chamber. The preferred ribbon width is IO±rm7m. The preferred ribbon height is 7. j.

±0.3m/m.

(2) Jitsugyo Ko 4-300! Publication R, Tokukaisho! Hiro-1
Light-shielding passages, such as those disclosed in Japanese Patent No. llIr2, are provided at the exit of the film roll chamber and the entrance of the winding chamber. The light-shielding passage is located at one of the outer peripheries of the roll chamber and winding chamber.
Preferably, the length is 71 or more.

(3) % Kaisho 5r-t ti77ax Publication 11C
Provide a resin bag as disclosed.

(4) Dye the film base with dye to reduce light and e-ipping. There are no particular limitations on the dye, but due to the general properties of photosensitive materials, it is preferable to dye the dye with a color tone close to gray.

The staining density is at least 0.0 or more preferably 0°03
That's all. Measurements are performed in the visible light range using a color density monitor manufactured by Macbeth.

(5) Heat deformation in the form of twill knurling is applied to the leading and trailing ends of the film to completely reduce light riving.20
It is preferable to apply thermal deformation in the form of twill knurling over an area of m/m or more.

The means (1) to (5) may be appropriately combined or used alone.

(1) and (3), (1) and (4), (1) and (5), (
Combinations of 2) and (3), (2) and (4), and (2) and (5) are preferred.

In order to maximize the effect of increasing the screen size, it is necessary to create a reference surface on the camera and cartridge so that the film surface is at a certain level with respect to the lens inside the camera, and the camera and cartridge should touch here. Preferably, the position of the film plane relative to the lens is determined by . It is preferable to ensure a positional accuracy of ±IO μm. The position Vt of the film surface can also be determined by pressing the back surface of the film in the exposed portion of the cartridge with a pressure plate of the camera.

The cartridge used in the present invention is usually formed from a plastic material, and the cartridge body is preferably hermetically packaged in a moisture-proof sealed container (cartridge case). Furthermore, the cartridge substantially maintains the photographic performance of silver halide photographic materials even when stored at 0C in the cartridge case.

Preferably, it is formed from a plastic material that does not undergo any alteration. Such plastic materials can be selected in the following manner.

Several m/m of plastic chips 10011f A film gold case to be packaged moisture-proof in a metal sealed container of about AOOOcrn with humidity adjusted to 70% with 10011f glycerin.
Heat on oc for 3 days. All the films tested were processed at the same time under the same conditions as above, except that there was no plastic chip. When the treated film is measured at a status M density and the difference in the fog density of cyan, magenta, and yellow for λ samples is within o, io, preferably within r4o, or, it can be preferably used as the plastic material of the present invention. .

Development processing is carried out according to the standard specified processing for each color film.

For example, in the case of color negative film, C-Hiroshi/, CN
Use -/l etc. For color reversal films, use CR-jA, E-4, etc.

Furthermore, in the present invention, the plastic material is
0.03μi/j! It is preferable that the amount of cyan gas generated is as follows.

As a result of detailed analysis of the gas components emitted from plastic materials that are harmful to color films, trace amounts of cyan gas were detected.According to the analysis results, instead of plastic, a trace amount of cyan gas was placed in a sealed container made of di-alkaline earth metal.
Heating for 3 days at 0C showed changes in photographic performance very similar to those tested with plastic material.

From these experiments, plastic materials that do not emit cyan gas are highly preferred for the present invention.

The plastic material preferably used in the present invention has a cyan gas amount of 0.03 μg or less based on the plastic material / II, as determined by the cyan gas detection and quantitative method described below.
Preferably, the amount of cyan gas is within the detection limit of analysis (0,00j
It is a plastic material with a weight of 97g (μ97g) or less.

(Cyan gas analysis method) If necessary, the resin is solidified by cooling with liquid nitrogen and pulverized to make a sample.This sample is s r, i,
i, i Treat the sample in a manner similar to the aeration method, and collect the generated hydrogen cyanide in a sodium hydroxide solution. The cyanide ions in this collection liquid are determined by the above-mentioned Test Method 31.2 Pyridine-Pyrazolone Absorption Photometry.

The actual analysis side is all described below.

Take 1001 parts of resin and 1001 parts of water! Add Ll and pH
'6t, o adjusted with acetic acid and sodium hydroxide, kept in a constant temperature water bath ft00c, about 1. Hydrogen cyanide is generated by aeration for λμ time at a rate of /N
- Hydroxide) Absorb in IJum solution. The absorbance of this absorption liquid at A20 nm is read by pyridine-pyrazolone spectrophotometry, and the absorbance obtained in the blank operation is completely subtracted. Using a separately prepared calibration curve, the amount of hydrogen cyanide generated is determined, and the amount generated per sample 19 is calculated.

The plastic material used in the present invention includes addition polymerization of olefins having carbon-carbon double bonds, ring-opening polymerization of small-membered ring compounds, polycondensation (condensation polymerization) between two or more types of polyfunctional compounds,
It can be produced using methods such as polyaddition and addition of a phenol derivative, urea derivative, or melamine derivative with a compound having an aldehyde.

The raw materials for plastics and filaments include olefins with carbon-carbon double bonds, such as styrene, α-methylstyrene, butadiene, methyl methacrylate, butyl acrylate, and acrylonitrile.

Vinyl chloride, vinylidene chloride, vinylpyridine.

Representative examples include N-vinylcarbazole, N-hinylpyrrolitone, hnylidene cyanide, ethylene, and propylene. In addition, examples of small ring compounds include ethylene oxide, propylene oxide, glycidol, 3,3-bischloromethyloxetane, /, ≠
-dioxane, tetrahydrofuran, trioxane, 8
-Caprolactam, β-propiolactone, ethyleneimine.

Typical examples include tetramethylronoxane.

Further, as polyfunctional compounds, for example, carboxylic acids such as terephthalic acid, adipic acid, and glutaric acid, incyanates such as toluene diisocyanate, nato-2-methylene diinocyanate, and hexamethylene diinocyanate, ethylene glycol, buta-pyrene glycol, glycerin, etc. Typical examples include alcohols, amines such as hexamethylene diamine, tetramethylene diamine, para-phenylene diamine, and epoxies. Typical examples of phenol derivatives, urea derivatives, and melamine fat conductors include phenol, cresol, methoxyphenol, chlorophenol, urea, and melamine. Furthermore, compounds with aldehydes include formaldehyde, acetaldehyde,
Representative examples include octanal, dodecanal, and p/dualdehyde. Not only seven types but also two or more types of these raw materials may be used depending on the target performance.

When producing plastic materials using these raw materials, catalysts and solvents may be used.

As a catalyst, (/-72ndylethyl]azodiphenylmethane, dimethyl λ, 2'-azobisin dithilate,
2.2'-azobis(λ-methylpropane), benzoyl peroxide, chlorohexanone peroxide,
Radical polymerization catalysts such as potassium persulfate, sulfuric acid, toluenesulfonic acid, sulfuric acid, perchloric acid, trifluoroborate.

≠Cationic polymerization catalysts such as tin chloride, anionic polymerization catalysts such as n-methyllithium, sodium/naphthalene, terfluorenyllithium, phenylmagnesium bromide, triethylaluminum/tetrachlorotitanium-based Ziegler-Natta
) system catalysts, sodium hydroxide, potassium hydroxide, potassium metal, etc.

There are no particular restrictions on the solvent as long as it does not inhibit polymerization, but examples include hexane, decalin, benzene, toluene, cyclohexane, chloroform, acetone, methyl ethyl ketone, ethyl acetate, methyl acetate, and tetrahydro-7 run.

In molding the plastics of the present invention, a plasticizer is mixed into the entire plastics, if necessary. Examples of the plasticizer include trioctyl phosphate, tributyl phosphate, digtyl 7-talate, diethyl sebacate, methyl amyl ketone, nitrobenzene, r-valerolactone,
Representative examples include di-n-octyl succinate, bromonaphthalene, and butyl palmitate.

Examples of plastic materials used in the present invention are listed below, but the invention is not limited thereto.

P-/P-Hiro-r Polystyrene Polyethylene Polypropylene Polymonochlorotrifluoroethylene Vinylidene chloride resin Vinyl chloride resin Vinyl chloride-vinyl acetate copolymer resin Acryloni-metered rubtagene-styrene copolymer resin Methyl methacrylic resin Vinyl formal resin Vinyl butyral resin Polyethylene 7 Talated Teflon Nylon P-//P-/CotJ P-/≠P-/rPhenol Resin P-/4 Melamine Resin Particularly preferred plastic materials for the present invention are polystyrene, polyethylene, polypropylene, and the like.

Cartridges are usually manufactured using plastic mixed with carbon black or pigments to give them a shimmering effect.

The total weight of the cartridge is usually 5 to 70 fl, preferably /Q-Qy, more preferably /J-io,! i
! It is.

In the present invention, it is preferable that the cartridge be packaged in a sealed state inside a cartridge case, and here, sealed packaging means the humidity difference between the outside air and the inside of the case (20% at 2!0C/
This refers to a state in which the humidity inside the case changes within IO% after 3 months have passed.

The cartridge case is 13! A plastic case such as a size Notrone case or a moisture-proof bag such as a llO size or l-〇 size film case can be used.

The humidity inside the cartridge case is normally at 2r'C relative humidity! ~70%, preferably 50-61%
, more preferably jλ to %.

Cellulose triacetate, polyester base, etc. can be used as the film base. When a polyester base is used, it is preferable to use the water-absorbing polyester base described in Japanese Patent Application No. 1977/7/30r.

The thickness of the film base is usually 0 to 30 μm, more preferably 10 to 30 μm, and more preferably 10 to 30 μm.

Next, general formula (I) will be explained.

R1 is a hydrogen atom or a lower alkyl group with carbon number/~Hiro (
For example, methyl group, ethylene group, n-propyl group, n-
butyl group, etc.), but TIME- of general formula (1)
From the viewpoint of the rate of release to DI', hydrogen is preferred. R2 and R3 are each a hydrogen atom or a lower alkyl group having 7 to ≠ carbon atoms (for example, methyl group, ethyl group, propyl group, 1so-propyl group, butyl group, 1so-propyl group,
-butyl group, 5ec-butyl group, etc.). This alkyl group may have a substituent t-, such as a hydroxyl group, an alkylthio group (eg, methylthio group), or an alkoxycarbonyl group (eg, methoxycarbonyl group, ethoxycarbonyl group, etc.).

Preferably μR2 and R3 are each a hydrogen atom.

R4 is a hydrogen atom or a lower alkyl group having l-hiro carbon atoms (
For example, it represents a methyl group, ethyl group, propyl group, 1so-propyl group, butyl group, 1so-butyl group, 5eC-butyl group, etc.). This alkyl group is a hydroxyl group, an alkoxy group (e.g. methoxy group, ethquin group, etc.)
may be replaced with . R4 is particularly preferably a hydrogen atom or a methyl group, since the cyan dye produced as a result of the coupling reaction between the oxidized crude drug and the compound represented by the general formula CI) has good flowability from the light-sensitive material. . R5 is a hydrogen atom, an acylamino group, a sulfonamide group, a phosphonamide group, an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkoxycarbonylamino group, an aryloxysulfonamide group, a carbamoylamino group, or a sulfamoylamino group is represented by a hydrogen atom, an acylamino group substituted with an alkyl group having carbon number/~μ, a sulfonamide group, and an alkoxyacylamine group are preferred. TIME represents a timing fund in which the compound represented by the general formula (1) reacts with an oxidized product of a color developing agent, and is released together with DI, and thereafter releases DI. As an example of the timing group represented by TIME, U.S. Pat.
No. 2, JP-A-7-16137, which releases PUG'i through an intramolecular nucleophilic substitution reaction; ! ≠
Examples include those that release l'UGi through an electron transfer reaction along a conjugated chain, as disclosed in the specification of No. 23≠. Others, JP-A-Sho r7-it103! No., Mukai 5r
-yr7.2r, same! Tar 2 otriu, 60-
No. 7172, No. AO-Jiaizr, No. to-, 2
．． xrrta issue, same 6゜-22F030, same to-2
336 μri No. 60-23711, AO-, 27
Also included are the timing groups disclosed in 74tμ7.

As qTIME useful in the present invention, the following general formula (II),
(III) and (fV) are included, but are not limited thereto.

General formula (II) The -C- group is substituted at the ortho or para position with respect to Y, and is bonded to the heteroatom contained in DI.

General formula <1) t7 In the formula, X represents an atomic group necessary to complete a benzene ring or a naphthalene ring which may be substituted. Y represents 10-1-S-1-N-, is bonded to the coupling position of the compound represented by general formula (I) (hereinafter referred to as l-naphthol coupler group), and R6*R7 ,
and R8 represents a hydrogen atom, an alkyl group or an aryl group. In the formula, Y, R6, and R7 each represent the general formula (It)
is synonymous with R9 is a hydrogen atom, an alkyl group, an aryl group, an acyl group, a sulfonyl group, an alkoxycarbonyl group, or a heterocyclic residue, and RIO is a hydrogen atom, an alkyl group,
Indicates an aryl group, a heterocyclic residue, an alkoxyl group, an amine group, an acid amide crystal, a sulfo/amide group, a carboxyne, an alkoxycarbonyl group, a carbamoyl group, and cyanide. Also,
As in the general formula (It), this timing group has Y at the coupling position of the l-7 toll coupler represented by the general formula (1), and a -C- group at the coupling position of the DI heteroatom blind. Join.

Next, an example of a timing group released into DI= by an intramolecular nucleophilic substitution reaction is shown by general formula (IV).

General formula (f'i/) Nu -E- In the formula, Nu is a nucleophilic group having an electron-rich oxygen, sulfur or nitrogen atom, and l-
It is bonded to the coupling position of the naphthol coupler group. EH1 is an electrophilic length having an electron deficient carbonyl, thiocarbonyl, phosphinyl or thiophosphinyl group and is bonded to the heteroatom of DI.

X is sterically related to Nu and Ei, and has the general formula (1
) After Nu is released from the l-7tall coupler group represented by It is a bonding group.

DI stands for a development inhibitor, and a representative example thereof is described in US Patent No. 3. koλ7. Yoyo number, same number 3゜3117,
No. 677, same No. 3. t/j, No. 106, No. 3. t/7
．． No. 227, No. 3.733,207 and British Patent No. 1. ≠Mercaptotetrazole group, selenotetrazole group, mercaptobenzothiazole group, selenobenzothiazole group, mercaptobenzoxazole group, selenobenzoxazole group, mercaptobenzimidazole group, selenobenzimidazole, which are described in ≠10,4L7 specification etc. group, benzotriazole group, benzodiazole group, and iodine atom.

Specific representative examples of the compounds of the present invention are shown below, but the compounds of the present invention are not limited thereto.

Exemplary compound NO2 [About R] -CH2CH2C00CH3 -CH2c)(2COO(?2H5 -CH2CH2COOC3H7(iso)-CH2CH
2COOC4H9 -CH2CH2COOCH2CH20H-CH2CH2
C00CH2CH20CH3-CH2C00CH3 -CH2COOH -CH2CH2COOH H [About 2] O2 (10) -CHCooCHa CH3 (11) -CHCooCH3 C3H7(iso) (12) -CHC00CH3 CH2H2CH3 CH 3 (13) -CHCOOC2H5 H20H (14n -CHCooCH3 CH2CHz8CHa (15) -CHCooCHa CH2C00CR3 (16) -CHCooCHa CH2CH2COOCH3 (17) -CH2CH2CH2COOCH3 (18
) -CH2CH2CH2CH2COOCH3(21
] O2 NHCOCI I H23 COOC4H9 These compounds represented by the general formula (I) are described in US Pat. 6-l/4c Rihirot
Ji+, same rr-itx Rihiro 2 and same jj-373
It can be synthesized by the method described in No. jO.

The compound represented by the general formula CI) of the present invention is preferably added to a light-sensitive silver halide emulsion layer or a layer adjacent thereto in a light-sensitive material, and the amount added is from 1xio-6 to r
xiθ−3mol/m2, preferably dJX/θ
~2×10 mol/m2 more preferably /x
IO-lrXlo-4 mol/m.

The compound represented by formula (1) of the present invention can be added in the same manner as for ordinary couplers, as described below.

Two or more types of compounds represented by the general formula (1) of the present invention having different DIs as development inhibitors may be used in order to improve color reproducibility by improving interlayer effect and improve sharpness by improving adjacent development effect. is particularly preferred.

In addition, the compound represented by general formula (1) can be used in the layer structure shown below, especially in photosensitive emulsion layers other than the red-sensitive emulsion layer,
That is, it is preferably used in a blue-sensitive emulsion layer and a green-sensitive emulsion layer.

In the present invention, it is particularly preferable to contain a compound represented by the following general formula (n) and/or (I[l) or a salt thereof for the purpose of improving the storage stability of the photosensitive material.

General formula (n) also shows when both R3 and R4 are tails other than amino groups that may contain substituents, or when R3 and R4 are connected! ~
When forming a 6-membered saturated carbocyclic nucleus, at least one of R1 and R2 is a hydrogen atom. ] General formula (III) [wherein, Xl and X2 are oxygen atoms or =NH group, R
1 and R2 are hydrogen atoms, acyl groups, or hydrocarbon residues that may have substituents; R3 and R4 are hydrogen atoms, hydroxyl groups, amide groups that may have substituents; It represents a good hydrocarbon residue or a 10R group (R is a hydrocarbon residue that may have a substituted crystal t-), and R3 and R4 are connected to form a C to 6-membered saturated carbocyclic nucleus. good. However, R
1 and R2 are not methyl hydroxide groups, and both Xl and X2 are oxygen atoms [in the formula +
X3 and X4 are oxygen atoms or =NH groups, R5 and R6 are hydrogen atoms, acyl groups, or hydrocarbon residues that may have 11 substituents, R7 is an imino group that may have substituents or linear substitution Represents a hydrocarbon residue that may have a base. However, R5 and R6 are not hydroxylated methyl groups (
, and when X3 and X4 are both oxygen atoms and R7 is a hydrocarbon residue which may have a substituent, at least seven of R5 and R6 are hydrogen atoms.

] Interesting examples of these compounds are listed below.

(S-/ (S-t) (S-2 (S-+ (S-3 (S-7) S-Hiroshi] S-r) (S-/ (S-/≠n(S-/!) S-/ S-ta(S-// On(8-/ko(8-/7)(S-/1 S-/ Ri(S-koO)(S-ko/(S-2≠H3( S-λri (S-J/) (S-32 0CH3 (8-, 27) (S-26 C) (3 (S-, 27) (S-ko r (8-3! ('S-J ≠) (s-it (S-74 (S-77) (S-Reference 1) (S-31) (S-≠2) (S-3ri) (S=4'J) (S-≠O These compounds are described, for example, in the Bulletin of the Chemical Industry.
n of the Chemical 5oc
ietyof Japan) Volume 1/Ta! 2～lta≦
7 pages, 1774' - /731 pages (/PjJ), Chemische Berichte (Chemische Berichte)
te) JOB volume 1ro2-1ri3 page 1.24/L4A
It can be synthesized according to the method described in page /-J4L7F (/riλl).

These compounds may be added alone or in combination of four or more to any layer in the light-sensitive material, but they may be added to auxiliary layers other than the light-sensitive emulsion layer, such as intermediate layers, filter layers-protective layers, and antihalation layers. It is preferable to do so.

The light-sensitive material of the present invention only needs to have at least one silver halide emulsion layer of a blue-sensitive layer, a green-sensitive layer, and a red-sensitive layer on the support. There are no particular limitations on the number of layers and types of non-photosensitive layers; a typical example is to use a plurality of silver halides with substantially the same color sensitivity but different light sensitivities on the support. A silver halide photographic light-sensitive material having at least one light-sensitive layer consisting of an emulsion layer, the light-sensitive layer being a unit light-sensitive material that develops color sensitivity to blue light, green light, or red light. In a multilayer silver halide color photographic light-sensitive material, generally the unit photosensitive layers are arranged in this order from the support side: a red-sensitive layer, a green-sensitive layer, and a blue-sensitive layer. However, depending on the purpose, the above-mentioned arrangement may be reversed, or the arrangement may be such that different photosensitive layers are sandwiched between the same color-sensitive layer.

Above, halogenated! Non-photosensitive layers such as various intermediate layers may be provided between the photosensitive layers and between the top and bottom layers.

In the intermediate layer, Japanese Patent Application Laid-open Nos. 61-43'748 and 59-
No. 113438, No. 59-113440, No. 61-2
Coupler, DIR compound, etc. as described in No. 0037 and No. 61-20038 may be contained, and a color mixing inhibitor as commonly used may be contained.

A plurality of silver halide emulsion layers constituting each unit photosensitive layer include a high-speed emulsion layer and a low-speed emulsion layer, as described in West German Patent No. 1.121.470 or British Patent No. 923.045. A two-layer structure of 0 can be preferably used.
Usually, it is preferable to arrange the layers so that the photosensitivity decreases toward the support, and a non-photosensitive layer may be provided between each halogen emulsion layer.
-112751, 62-200350, 62-
As described in Nos. 206541 and 62-206543, a low-sensitivity emulsion layer may be provided on the side far from the support, and a high-sensitivity emulsion layer may be provided on the side close to the support.

As a specific example, from the side farthest from the support, low-sensitivity front-window light-sensitive layer (BL) / high-sensitivity front-window light-sensitive layer (BH) / high-sensitivity green light-sensitive layer (GH) / low-sensitivity green light-sensitive layer ( G-shi)
/High intensity red photogenic layer (RH) /Low grade red photogenic layer (I
IL) or BH/BL/GL/GH/RH/R
t, or BH/BL/GH/GL/RL/RH
They can be installed in the following order:

In addition, as described in Japanese Patent Publication No. 55-34932, front window optical N/GH/R
They can also be arranged in the order of H/GL/RL. Alternatively, as described in JP-A-56-25738 and JP-A-62-63936, the blue-sensitive layer/GL/RL/GH/RH can be arranged in this order from the farthest side from the support. .

In addition, as described in Japanese Patent Publication No. 49-15495, the upper layer is a silver halide emulsion layer with the highest sensitivity, the middle layer is a silver halide emulsion layer with lower sensitivity, and the lower layer is more sensitive than the middle layer. An example is an arrangement consisting of three layers with different photosensitivity, in which a silver halide emulsion layer with a low density is disposed and the photosensitivity gradually decreases toward the support. Even when it is composed of three layers with different photosensitivity, as described in JP-A No. 59-202464,
In the same color-sensitive layer, a medium-sensitivity emulsion layer/high-density emulsion layer/low-sensitivity emulsion layer may be arranged in this order from the side remote from the support.

In addition, high-sensitivity emulsion layer / low-temperature emulsion layer / medium-sensitivity emulsion layer,
Alternatively, they may be arranged in the following order: low-speed emulsion layer/medium-speed emulsion layer/high-speed emulsion layer.

Furthermore, even in the case of four or more layers, the arrangement may be changed as described above.

As mentioned above, various layer structures and arrangements can be selected depending on the purpose of each photosensitive material.

The preferred silver halide contained in the photographic emulsion layer of the photographic light-sensitive material used in the present invention is silver iodobromide, silver iodochloride, or silver iodochlorobromide, containing about 30 mol% or less of silver iodide. . Particularly preferred is silver iodobromide or silver iodochlorobromide containing from about 2 mole percent to about 25 mole percent silver iodide.

Silver halide grains in photographic emulsions include those with regular crystals such as cubes, octahedrons, and tetradecahedrons, those with irregular crystal shapes such as spherical and plate shapes, and those with twin planes. It may also be one with crystal defects, or a revived form thereof.

The grain size of the silver halide may be fine grains of about 0.2 microns or less, or large grains with a projected area diameter of up to about 10 microns, and may be a polydisperse emulsion or a monodisperse emulsion.

Examples of silver halide photographic emulsions that can be used in the present invention include Research Disclosure (RD) k17643
(December 1978), pp. 22-23, “1. Emulsion preparation, Lion an
d types) 11. and question circle 18716 (1
November 979), 648 pages, "Physics and Chemistry of Photography" by Glafkide, published by Paul Montell (P, Glafk
ides, Chea+ic et Ph1stque
PhoLograph-ique, Paul Mo
(1967), “Photographic Emulsion Chemistry” by Duffin
, published by Focal Press (G, F, DJfin.

Photographic Emulsion Che
mistry (Focal Press.

1966)), "Manufacture and coating of photographic emulsions" by Zelikman et al., published by Focal Press (V, L, Zelikm)
anet al, + Making and Coat
ing Photographic Emul-sio
It can be prepared using the method described in, for example, J.D., Focal Press, 1964).

U.S. Patent Nos. 3,574,628 and 3,655,39
Monodisperse emulsions such as those described in No. 4 and British Patent No. 1.413.748 are also preferred.

Tabular grains having aspect ratios of about 5 or more can also be used in the present invention. Tabular grains are described by Gutoff, Photographic Science and Engineering.
ence and Engineering), Vol. 14, pp. 248-257 (1970); U.S. Patent No. 4
, 434.226, 4,414.310, 4,
433.048, 4,439,520, and British Patent No. 2.112.157.

The crystal structure may be --like, the inside and outside may have different halogen compositions, it may be a layered structure, or silver halides with different compositions may be joined by epitaxial bonding. It may also be bonded with a compound other than silver halide, such as Rodan oxide or lead oxide.

It is also possible to use a mixture of grains of various crystal forms. Silver halide grains that have been subjected to physical ripening, chemical ripening and spectral sensitization are usually used. Additives used in such processes are listed in Research Disclosure Ha 1764.
3 and Ha 18716, and the cough locations are summarized in the table below.

Known photographic additives that can be used in the present invention are also described in the above two Research Disclosures, and the relevant descriptions are shown in the table below.

! uJJMLL uudanL Kariage lj1 Chemical exacerbation P! Page 23 Page 648 Right column 2 Sensitivity enhancer
Same as above 3 Spectral aggravating agents, pages 23-24 6
Page 48 right column - Super sensitizer Page 649 right column 4 Brightener Page 24 5 Anti-fogging agent Page 24-25 Page 649 right column - and stabilizer 6 Light absorber, page 25-26 Page 649 right column ~Filter dye, page 650 left column UV absorber 7 Stain inhibitor page 25 right column page 650 left to right column 8
Dye image stabilizer page 25 9 Hardener page 26 page 651 left column 10
Binder, page 26 Same as above 11 Plasticizer, lubricant, page 27 Page 650, right column 12 Coating aid, pages 26-27 Page 650, right column Surfactant 13 Static, page 27 Same as above Patch agent Also, photographic performance improvement with formaldehyde gas In order to prevent deterioration, US Patent No. 4,411.98T and US Pat.
．． It is preferable to add a compound capable of reacting with and immobilizing formaldehyde as described in No. 435,503 to the photonic material.

Various color couplers can be used in the present invention, specific examples of which can be found in the above-mentioned Research Disclosure (
RD) N(L 17643, described in the patent listed in ■-〇-G.

As a yellow coupler, for example, U.S. Patent No. 3.93
3.501, 4.022,620, 4.3
No. 26,024, No. 4,401,752, No. 4.
248,961, Japanese Patent Publication No. 58-10739, British Patent No. 1,425,020, British Patent No. 1,476.760, U.S. Patent No. 3,973,968, British Patent No. 4.314,
No. 023, No. 4,511,649, European Patent No. 24
9.473A, etc. are preferred.

5. As a magenta coupler. Pyrazolone and pyrazoloazole compounds are preferred, and are disclosed in U.S. Pat. No. 4,31
0,619, European Patent No. 4.351,897, European Patent No. 73,636, U.S. Patent No. 3,061,432, European Patent No. 3.725.067, Search Disclosure Nα24220 (1984) June), Japanese Patent Application Publication No. 1983
-33552, Research Disclosure Ni1
24230 (June 1984), JP-A-60-436
No. 59, No. 61-72238, No. 60-35730, No. 55-118034, No. 60-185951,
U.S. Patent No. 4.500.630, U.S. Pat. No. 4,540.6
No. 54, No. 4.556.630, International Publication WO38
Particularly preferred are those described in No. 104795 and the like.

Cyan couplers include phenolic and naphthol couplers, and are described in U.S. Pat. No. 4,052.212.
No. 4,146,396, No. 4,228,23
No. 3, No. 4,296,200, No. 2.369,9
No. 29, No. 2.801.171, No. 2,772.
No. 162, No. 2,895,826, No. 3.772
, No. 002, No. 3,758.308, No. 4.33
No. 4.011, No. 4,327,173, West German Patent Publication No. 3゜329.729, European Patent No. 121,365
No. A, No. 249°453A, - U.S. Patent No. 3,4
No. 46.622, No. 4,333,999, No. 4,
No. 775.616, No. 4.451.559, No. 4
．． Preferred are those described in Japanese Patent Application Publication No. 427,767, Japanese Patent Application Publication No. 4.690,889, Japanese Patent No. 4.254°212, Japanese Patent Application Publication No. 4.296,199, and Japanese Patent Application Laid-open No. 42658/1984.

Colored couplers to correct unnecessary absorption of coloring dyes are listed in Research Disclosure 17643.
- Section G, U.S. Patent No. 4,163.670, Japanese Patent Publication No. 1983
-39413, U.S. Patent No. 4,004,929, U.S. Patent No. 4.138,258, British Patent No. 1,146,36
No. 8 is preferred, and also US Pat. No. 4.7
No. 74,181, a coupler that corrects unnecessary absorption of a color-forming dye by a fluorescent dye released upon coupling, and a coupler that can react with a developing agent to form a dye, as described in U.S. Pat. No. 4,777,120. It is also preferred to use couplers in which a dye precursor group is present as a leaving group.

Couplers whose coloring dyes have appropriate diffusivity include U.S. Patent No. 4,366.237 and British Patent No. 2,125.
．． 570, EP 96,570 and DE 3,234,533 are preferred.

Typical examples of polymerized dye-forming couplers are described in U.S. Pat. No. 3,451,820; C180,211
No. 4,367.282, No. 4,409,32
No. 0, No. 4,576°910, British Patent No. 2.102
．． It is described in No. 173, etc.

Couplers that release photographically useful residues upon coupling are also preferably used in the present invention. DIR couplers that release development inhibitors include the aforementioned RD 17643.
, Patents described in sections ■ to F, Japanese Patent Application Laid-Open No. 57-15194
No. 4, No. 57-154234, No. 60-184248
No. 63-37346, U.S. Patent No. 4,248,96
No. 2, No. 4°782.012 is preferred.

Couplers that release a nucleating agent or a development accelerator imagewise during development include British Patent No. 2.097,140;
No. 2,131,188, JP 59-157638
No. 59-170840 is preferred.

In addition, examples of couplers that can be used in the photosensitive material of the present invention include competitive couplers described in U.S. Pat. No. 4,130,427, U.S. Pat. , DIR redox compound releasing couplers described in JP-A-60-185950, JP-A-62-24252, etc., DIR coupler-releasing couplers,
DIR coupler releasing redox compound or DIR redox releasing redox compound, European Patent No. 173゜3
Coupler that releases a dye that recovers color after separation, R, D, described in No. 02A, 11449, 24241, JP-A-61
-201247 etc. bleach accelerator releasing couplers,
Ligand-releasing couplers described in U.S. Pat. No. 4,553,477, leuco dye-releasing colorers described in JP-A-63-75747, U.S. Pat. No. 4,774.1
Examples include couplers that emit fluorescent dyes as described in No. 81.

The coupler used in the present invention can be introduced into the light-sensitive material by various known dispersion methods.

Examples of high boiling point solvents used in the oil-in-water dispersion method are described in U.S. Pat. No. 2,322.027 and the like.

The boiling point at normal pressure used in the oil-in-water dispersion method is 175"C.
Specific examples of the above-mentioned high boiling point solvents include phthalic acid esters (dibutyl phthalate, dicyclohexyl phthalate, di-2-ethylhexyl phthalate, decyl phthalate, bis(2,4-di-1-amylphenyl) phthalate). , bis(2,4-di-t-amyl phenyl) isophthalate, bis(l,1-diethylpropyl) phthalate, etc.), esters of phosphoric acid or phosphonic acid (triphenyl phosphate, tricresyl phosphate,
2-ethylhexyl diphenyl phosphate, tricyclohexyl phosphate, tri-2-ethylhexyl phosphate, tridodecyl phosphate, tributoxyethyl phosphate, trichloropropyl phosphate, di-2-ethylhexylphenyl phosphonate, etc.)
, benzoic acid esters (2-ethylhexylbenzoate, dodecylbenzoate, 2-ethylhexyl-p-
hydroxybenzoate, etc.), amide M (N, N-
diethyldodecaneamide, N,N-diethyllaurylamide, N-tetradecylpicolidone, etc.), alcohols or phenols (isostearyl alcohol, 2
, 4-di-tart-amylphenol, etc.), aliphatic carboxylic acid esters (bis(2-ethylhexyl) sebacate, dioctyl azelate, glycerol tributyrate, isostearyl lactate, trioctyl citrate, etc.), aniline derivatives ( N, tributyl-
2-butoxy-5-tert-1. hydrocarbons (paraffin, dodecylbenzene, diisopropylnaphthalene, etc.). Further, as the auxiliary solvent, an organic solvent having a boiling point of about 30°C or higher, preferably 50°C or higher and about 160°C or lower, can be used, and typical examples include ethyl acetate, butyl acetate, ethyl propionate, methyl ethyl ketone, and cyclohexanone. ,
Examples include 2-ethoxyethyl acetate and dimethylformamide.

The process and effects of latex dispersion methods and specific examples of latex for impregnation are described in U.S. Pat. It is written in the number etc.

The color photosensitive material of the present invention includes JP-A-63-2577
No. 47, No. 62-272248, and JP-A-1-8
1,2-benzisothiazoline-3 described in No. 0941
-one, n-butyl p-hydroxybenzoate, phenol, 4-chloro-3.5-dimethylphenol, 2-phenoxyethanol, 2-(4-thiazolyl)benzimidazole, etc. are added with various preservatives or antifungal agents. It is preferable to do so.

The present invention can be applied to various color photosensitive materials. - Typical examples include color negative film for touch or cinema, color reversal film for slides or television, color paper, color positive film, and color reversal vapor.

Suitable supports that can be used in the present invention include, for example, the above-mentioned R
D, page 28 of 17643, and 6 of 18716
It is described from the right column on page 47 to the left column on page 648.

In the photosensitive material of the present invention, the total thickness of all the hydrophilic colloid layers on the side having the emulsion layer is preferably 28 μm or less, more preferably 23 μm or less, even more preferably 20 μm or less, and the film swelling The speed 'r+zz is preferably 30 seconds or less, more preferably 20 seconds or less.

Film thickness is 55% at 25°C relative temperature! I! The film swelling rate T, /8, which refers to the film thickness measured at room temperature (2 days), can be measured according to techniques known in the art.6 For example, Green et al. Photographic Science and Engineering (Photogr, Sci, Eng,) + 1
It can be measured by using a swellometer (swelling membrane) of the type described in 9@, No. 2, pages 124-129.
/□ is the saturated film thickness, which is 90% of the maximum swelling film thickness reached when treated with a color developing solution at 30°C for 13 minutes and 15 seconds, and this T
I/! Defined as the time it takes to reach a film thickness of .

The membrane swelling rate TI/l can be adjusted by adding a hardening agent to gelatin as a binder or by changing the aging conditions after coating. In addition, the swelling rate is preferably 150 to 400%. The swelling rate is calculated from the maximum swollen film thickness under the conditions described above, using the formula: (maximum swollen film thickness -
It can be calculated according to (film thickness)/film thickness.

The color photographic light-sensitive material according to the present invention is described in the above-mentioned RD, pages 28-29 of Magnet 17643, and 6 of Magnet 18716.
15. Development processing can be carried out by the usual methods described in the left column to right column.

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. Aminophenol compounds are also useful as color developing agents, but p-phenylenediamine compounds are preferably used, representative examples of which are 3-methyl-4-amino-N, +1 diethylaniline, 3-methyl -4-amino-N-ethyl-N
-β-hydroxyethylaniline, 3-methyl-4,amino-N-ethyl-N-β-methanesulfonamidoethylaniline, 3-methyl-4-aminoethyl-β-
Examples include methoxyethylaniline and their sulfates, hydrochlorides, and ρ-toluenesulfonates. Among these, 3-methyl-4-amino-N-ethyl-Nβ-hydroxyethylaniline sulfate is particularly preferred, and two or more of these compounds may be used in combination depending on the purpose.

The color developer may contain pH buffering agents such as alkali metal carbonates, borates or phosphates, chloride salts, bromide salts,
It is common to include development inhibitors or antifoggants such as iodide salts, benzimidazoles, benzothiazoles or mercapto compounds. If necessary, various preservatives such as hydroxylamine, diethylhydroxylamine, sulfites, hydrazines such as N,N-biscarboxymethylhydrazine, phenyl semicarbazides, triethanolamine, and catechol sulfonic acids, ethylene glycol, alkaline solvents such as diethylene glycol, development accelerators such as benzyl alcohol, polyethylene glycol, quaternary ammonium salts, amines, dye-forming couplers, competitive couplers, auxiliary developing agents such as 1-phenyl-3-pyrazolidone, viscosity Imparting agent, aminopolycarboxylic acid, aminopolyphosphonic acid,
Various chelating agents such as alkylphosphonic acids and phosphonocarboxylic acids, such as ethylenediaminetetraacetic acid, nitrilotriacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, hydroxyethyliminodiacetic acid, 1-hydroxyethylidene-1, 1-diphosphonic acid, nitrilo-N,N,N-)rimethylenephosphonic acid, ethylenediamine-N,N,N,N-tetramethylenephosphonic acid, ethylene glycol (O-hydroxyphenylacetic acid) and their salts. This can be cited as a representative example.

Further, when performing reversal processing, black and white development is usually performed and then color development is performed. This black and white developer contains known black and white developing agents such as dihydroxybenzenes such as hydroquinone, 3-pyrazolidones such as 1-phenyl-3-pyrazolidone, or 7-minophenols such as N-methyl-p-aminophenol. It can be used alone or in combination.

The pH of these color developing solutions and black and white developing solutions is generally 9 to 12. The amount of replenishment of these developing solutions depends on the color photographic light-sensitive material to be processed, but it should be 31 or less per square meter of photosensitive material, and by reducing the bromide ion concentration in the replenisher, it can be reduced to 500 or less.
It can also be less than d. When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by reducing the area of contact with the air in the processing tank.

The contact area between the photographic processing solution and air in the processing tank can be expressed by the aperture ratio defined below.

That is, the above aperture ratio is preferably 0.1 or less, more preferably 0.001 to 0.05. As a method for reducing the aperture ratio in this way, in addition to providing a shield such as a floating lid on the surface of the photographic processing solution in the processing tank, there are also methods for reducing the aperture ratio.
Method using a movable lid described in No. 2033, JP-A No. 6
The slit development processing method described in No. 3-216050 can be mentioned. It is preferable that reducing the aperture ratio is applicable not only to both color development and black and white development processes, but also to all subsequent processes, such as bleaching, bleach-fixing, fixing, washing, and stabilization. Furthermore, the amount of replenishment can be reduced by using means for suppressing the accumulation of bromide ions in the developer.

The time for color development processing is usually set between 2 and 5 minutes, but the processing time can be further shortened by using high temperature, high pH, and high concentration of color developing agent.

After color development, the photographic emulsion layer is usually bleached.

The bleaching process may be carried out simultaneously with the fixing process (bleach-fixing process) or separately (bleach-fixing process), or in order to speed up the process, it may be carried out in two ways: bleach-fixing process after bleaching process. Depending on the purpose, treatment may be carried out in consecutive bleach-fixing baths, fixing treatment before bleach-fixing treatment, or bleaching treatment after bleach-fixing treatment. Examples of bleaching agents that can be used include compounds of polyvalent metals such as iron (III), peracids, quinones, and nitro compounds. Typical bleaching agents include R complex salts of iron (01);
For example, aminopolycarboxylic acids such as ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, 1,3-diaminoblobanetetraacetic acid, glycol etherdiaminetetraacetic acid, or complex salts of citric acid, tartaric acid, malic acid, etc. can be used. Among these, iron aminopolycarboxylic acid (I[[) complex salts, including ethylenediaminetetraacetic acid iron (l[I) complex salts and 1,3-diaminopropanetetraacetic acid iron (II[Hf salts)] require rapid processing and environmental pollution. Preferable from the viewpoint of prevention, iron aminopolycarboxylate ([[
[) Complex salts are particularly useful in both bleach and bleach-fix solutions. These iron aminopolycarboxylic acids (f [
I) The pH of the bleach or bleach-fix solution using complex salts is usually 4.
．． 0 to 8, but lower to 9 for faster processing
It can also be treated with H.

A bleach accelerator may be used in the bleaching solution, bleach-fixing solution, and their prebaths, if necessary.

Specific examples of useful bleach accelerators are described in U.S. Pat. No. 3,893,858, German Pat.
, No. 290.812, No. 2,059,988, JP-A-53-32736, No. 53-57831, No. 53-
No. 37418, No. 53-72623, No. 53-956
No. 30, No. 53-95631, No. 53-104232
Compounds having a mercapto group or disulfide group described in JP-A No. 53-124424, No. 53-141623, No. 53-28426, Research Disclosure No. k17129 (July 1978), etc.: JP-A-50-140129 Thiazolidine derivatives described in Japanese Patent Publication Nos. 45-8506, 52-20832, 53-32735, and U.S. Patent No. 3,706,561; West German Patent No. 1,127 .71
No. 5, iodide salts described in JP-A-58-16,235;
Polyoxyethylene compounds described in West German Patent No. 966,410 and West German Patent No. 2,748.430;
Polyamine compounds described in No. 836; other JP-A-49-
No. 42.434, No. 49-59,644, No. 53-9
No. 4,927, No. 54-35.727, No. 55-26
, 506, 58-163, 940;
Bromide ion etc. can be used. Among them, compounds having a mercapto group or a disulfide group are preferable from the viewpoint of a large promoting effect, and are particularly preferred as described in U.S. Pat.
．． Preferred are the compounds described in US Pat. No. 630, and also preferred are the compounds described in U.S. Pat. These bleach accelerators are particularly effective when bleach-fixing.

In addition to the above-mentioned compounds, the bleaching solution and bleach-fixing solution preferably contain an organic acid for the purpose of preventing bleach staining. Particularly preferred organic acids have an acid dissociation constant (ρKa) of 2.
-5, specifically acetic acid, propionic acid, etc. are preferred.

Examples of fixing agents used in fixing solutions and bleach-fixing solutions include thiosulfates, thiocyanates, thioether compounds, thioureas, and large amounts of iodide salts, but thiosulfates are commonly used. Among them, ammonium thiosulfate is the most widely used. It is also preferable to use a combination of thiosulfate, thiocyanate, thioether compounds, thiourea, etc. As a preservative for fixing solutions and bleach-fixing solutions, sulfites, bisulfites, carbonyl bisulfite adducts, or European patented The sulfinic acid compounds described in No. 294769A are preferred. Furthermore, various aminopolycarboxylic acids and organic phosphonic acids are preferably added to the fixing solution and bleach-fixing solution for the purpose of stabilizing the solution.

The total time for the desilvering process is preferably as short as possible without causing desilvering defects.The preferred time is 1 minute to 3 minutes, more preferably 1 minute to 2 minutes. In addition, the processing temperature is 25°C
~50°C, preferably 35°C to 45°C. In a preferred temperature range, the desilvering rate is improved and the occurrence of staining after processing is effectively prevented.

In the desilvering process, it is preferable that the stirring be as strong as possible.A specific method for strengthening the stirring is the treatment on the emulsion surface of the photosensitive material described in JP-A-62-183460 and JP-A-62-183461. A method of colliding jets of liquid, a method of increasing the stirring effect using a rotating means as disclosed in JP-A-62483461, and a method of moving the photosensitive material without bringing the emulsion surface into contact with a wiper blade provided in the liquid. Examples include a method of improving the stirring effect by creating turbulence on the surface of the emulsion, and a method of increasing the circulation flow rate of the entire processing liquid. Such means for improving agitation is effective for all bleaching solutions, bleach-fixing solutions, and fixing solutions. It is believed that improved stirring speeds up the supply of the whitening agent and fixing agent into the emulsion film, and as a result increases the desilvering rate. Further, the agitation improving means described above is more effective when a bleach accelerator is used, and can significantly increase the accelerating effect and eliminate the fixing inhibiting effect caused by the bleach accelerator.

The automatic processor used for the photosensitive material of the present invention is JP-A-60-191257, JP-A-60-191258, JP-A-6
The above-mentioned JP-A-60-191257 preferably has the photosensitive material conveying means described in JP-A-60-191259.
As stated in the issue, this type of conveyance means can significantly reduce the amount of processing liquid brought into the post bath from the front bath, and is highly effective in preventing performance deterioration of the processing liquid.This effect reduces the processing time in each process. It is particularly effective in shortening the processing time and reducing the amount of processing solution replenishment.

The silver halide color photographic window light material of the present invention preferably undergoes a water washing and/or stabilization process after desilvering.

The amount of water used in the washing process depends on the characteristics of the S optical material (for example, depending on the materials used such as couplers), the application, the temperature of the washing water, the number of washing tanks (number of stages), the replenishment method such as countercurrent or forward flow, and various other conditions. can be set over a wide range. Among these, the relationship between the number of washing tanks and the amount of water in the multistage countercurrent method is
urn-al or the 5ociety of
Motion Picture and Te1e-v
ision Engineers Volume 64, P, 24
8-253 (May 1955 issue).

According to the multi-stage countercurrent method described in the above-mentioned literature, the amount of water used for washing can be significantly reduced, but due to the increase in the residence time of water in the tank, bacteria will breed, and the generated suspended matter will adhere to the photosensitive material. In the processing of color optical materials of the present invention, such problems can be solved by:
The method for reducing calcium ions and magnesium ions described in JP-A No. 62-288.838 can be used very effectively. Also, JP-A-57-8,542
Chlorinated disinfectants such as isothiazolone compounds, cyabendazole, chlorinated sodium isocyanurate, and other benzotriazoles listed in the issue, Hiroshi Horiguchi, Chemistry of Rooster and Mildew Control Agents J (1986), Sankyo Publishing, Hygiene Technological group “Elimination of microorganisms 2. Sterilization and anti-mold technology,” (191112
It is also possible to use the fungicides described in the "Encyclopedia of Antibacterial and Antifungal Agents" (1986), Society of Industrial Science and Technology, Japan Defense Society of Antifungal Sciences.

The pH of the washing water in the processing of the photosensitive material of the present invention is 4 to 4.
9, preferably 5-8. The washing water temperature and washing time can also be set variously depending on the characteristics of the photosensitive material, its use, etc., but generally it is 20 seconds to 10 minutes at 15 to 45°C, preferably 30 seconds to 5 minutes at 25 to 40°C. A range is selected. Furthermore, the photosensitive material of the present invention can also be directly processed with a stabilizing solution instead of washing with water.

In such stabilization treatment, Japanese Patent Application Laid-Open No. 57-854
All known methods described in No. 3, No. 58-14834, and No. 60-220345 can be used.

Further, following the water washing treatment, a further stabilization treatment may be performed. An example of this is a stabilization bath containing a dye stabilizer and a surfactant, which is used as a final bath for color photographic materials. Examples of the dye stabilizer that can be used include aldehydes such as formalin and grugulaldehyde, N-methylol compounds, hexamethylenetetramine, and aldehyde sulfite adducts.

Various chelating agents and antifungal agents can also be added to this stabilizing bath.

The overflow liquid from water washing and/or replenishment of the stabilizing liquid can be reused in other processes such as the desilvering process.

In a process using an automatic developing machine or the like, when each of the above-mentioned processing liquids undergoes tetracondensation due to evaporation, it is preferable to add water to correct the concentration.

The silver halide color phosphorescent material of the present invention may contain a color developing agent for the purpose of simplifying and speeding up processing. In order to incorporate a color developing agent, it is preferable to use various precursors of the color developing agent. For example, U.S. Patent No. 3,342.59
Indoaniline compound described in No. 7, No. 3,342,
No. 599, Research Disclosure 14, 85
Schiff base type compounds described in No. 0 and No. 15,159,
Aldol compounds described in U.S. Pat. No. 13.924, metal salt complexes described in U.S. Pat.
Examples include urethane compounds described in No. 135628.

The silver halide color brightening material of the present invention may contain various types of 1-phenyl-3 for the purpose of promoting color development, if necessary.
- Pyrazolidones may be incorporated.

Typical compounds are JP-A-56-64339 and JP-A No. 57-
No. 144547 and No. 58-115438.

The various processing solutions used in the present invention are used at a temperature of 10°C to 50°C. Normally, the standard temperature is 33°C to 38°C, but higher temperatures can be used to accelerate the processing and shorten the processing time. Or, conversely, lower the temperature ii! It is possible to achieve improvements in the quality and stability of the processing solution.

In addition, West German Patent No. 2.226.7 for the reduction of silver in the light material.
70 or US Pat. No. 3,674,499 using cobalt intensification or hydrogen peroxide intensification.

Further, the silver halide window optical material of the present invention is disclosed in U.S. Patent No. 4,
No. 500,626, JP-A-60-133449, No. 5
It can also be applied to heat-developable window optical materials described in No. 9-218443, No. 61-238056, European Patent No. 210.66042, and the like.

Example 1 Sample 101, which is a multilayer color light-sensitive material, was prepared on an undercoated cellulose triacetate film support having a thickness of 104 L .mu.m, and each layer having the composition shown below.

(Composition of the photosensitive layer) The coating amount is expressed in units of g/m2 of silver for silver halide and colloidal silver, and in units of ji/m2 for couplers, additives and gelatin. Sensitizing dye (the number of moles is expressed per 7 moles of silver halide in the same layer).

1st layer (antihalation layer) Black colloidal silver 0. /j Gelatin ・・・・・・ /,jE x M −
r... o, orUV-/
・・・・・・ 0.03UV-2・・・・
・・ o, ot 8o1v−λ −−−−・・ o, orUV−
J ・-・・-・0.07cpct-t
-...-Axlo 'th λ layer (intermediate layer) Gelatin UV-/ UV-2 UV-3 ExF-/ 5olv-λ pct-r 3rd layer (first red-sensitive emulsion layer) Silver iodobromide emulsion (Agl Komolti, internally high AgI type,
Equivalent sphere diameter 0.3 μm, coefficient of variation of equivalent sphere diameter Kotachi, normal crystal, twin mixed particle, diameter/thickness ratio Ko,! ] Coated silver amount... /,! 0,03 o,ot 0,07 0.00 ≠ 0.07 txio"'-' O,! 0, r/, 0x10-'!, Ox10-4/X/0-5 0, 22 0, Oj Gelatin Ex S -/ ExS-2 Ex S -j XC-J ExC-μ cpd-t 3×10-'th layer (
Second red-sensitive emulsion layer) Silver iodobromide emulsion (Ag I μmolti, internal high Agl type, equivalent sphere diameter o, r μm, coefficient of variation of equivalent sphere diameter, 2 (7
%, normal crystal, twin mixed grain, diameter/thickness ratio/coated silver amount...6...0.7/, 26/X10' 3x/θ-4/X/ 0-5 0, 33 0.01 0.01 0, O≠ o, or O,Oj! ×/θ-4 Gelatin Ex 8- / ExS-CoEx S -J ExC-7 ExC-HiroExY-/ ExC-7 ExC-λ 8o1v-/ cpd-j th! Layer (Third red-sensitive emulsion layer) Silver iodobromide emulsion (Ag I io morti, internal high Agl type, equivalent sphere diameter o, 7 μm, coefficient of variation of equivalent sphere diameter 30 inches, twinned mixed grains, diameter/thickness ratio 2) Coated silver amount...
・・・・・・ 0.7 gelatin ・・・・・・
o, rExS-/-----lX1
0-'ExS-2・Mountain... 3XIQ''''4 ExS-J・River-・lX10-"Ex
C-!・Mountain... o, orExC-6--
----0,0A Solv-/ -・・-0,1!5olv-
2...0.0t Cpd-Evening...JX/0
-5 6th layer (intermediate layer) Gelatin Cpd-j Cpd-/cpa-Hiroshi5olv-/cpci-3 7th layer (first green-sensitive emulsion layer) /, 0 daX / O-' 0, IO 0 ,00t o, or 0.00r Silver iodobromide emulsion (AgI comolti, internal high Agl type,
Equivalent sphere diameter 0.3 μm, coefficient of variation of equivalent sphere diameter 21%, normal crystal, twin crystal mixed particles, diameter/thickness ratio λ, amount of coated silver... Gelatin... ExS-Hiroshi ...... ExS-1... Ex 8-! ...ExM-ta ......E x Y -/Hiroshi
...ExC-μ ...Ex M -r ...5olv
-/...Cpd-1... Layer (first green-sensitive emulsion layer) Silver iodobromide emulsion (AgI Hiromorchi, internal high Agl type,
Equivalent sphere diameter o, rrμm, coefficient of variation of equivalent sphere diameter 20%, normal crystal, twinned mixed particle, diameter/thickness ratio) 0.30 0, Hiroj×10'-'0.3X10''-' λ× io-' O+ 1 0.0/3 0, Oko 0 0.03 0.2 2X10' Coated silver amount...Gelatin...ExS-μ...ExS- r...ExS-≦
...... ExC-Hiroshi ...... Ex M-2... ExM-r ...... ExM-10.
...ExY-/Hiroshi...5olv-/...cpci-t
...Second layer (Ml green-sensitive emulsion layer) Silver iodobromide emulsion (AgI 10 molti, internal high Agl type, equivalent sphere diameter 0.7 μm, coefficient of variation of one sphere equivalent diameter 30%, normal crystal, twin Crystal mixed particles, diameter/thickness ratio, o) Coated silver amount... o, rz Gelatin.../, 0ExS-
gu・・in・ko,σX10 'Q, to, r yoxio"-'koxio""" 0, JXlo 4 0.010 0, λ! 0.03 o, oiz O,02 0,2 J
ExS-7----s, ox10-'E x M-/
Ko ・・・・・・ Q + 06Ex
M-/J ・-・-・-o, o2Ex
M-1---o, oλ 5olv-/ ...... Q, λ
θ5olv −,2・−・−・o, orcpct−
7... ≠×10' 1st O layer (yellow filter layer) Gelatin ・Old... o, P yellow colloidal silver ・・・・・・ o, orCpd-/
・・・・・・ 0. λSo l v−/
・----・0, / jCp d -1...
... μX10-' 11th layer (7th blue-sensitive emulsion layer) Silver iodobromide emulsion (Agl Hiromoruchi, internal high AgI type,
Equivalent sphere diameter o, rμm Coefficient of variation of equivalent sphere diameter/1%, r-hedral particles) Coated silver amount...O0≠ Gelatin.../, OEχs-
r ・・・・・・ koX / 0-'Ex
Y-/6...0. EXC-p
・・・−・・ o, oitExY
-/ ri ・・・・・・ 0.06S
o l v-/ -----・-0
, 3cpd-j... Hiroshi
o-' 12th layer (4th blue-sensitive emulsion layer silver iodobromide emulsion (AgI 10 molti, internal high AgI type, equivalent sphere diameter /, 3 μm, coefficient of variation of equivalent sphere diameter, 2!
Normal crystal, mixed twin particle, diameter/thickness ratio μ,! ) Coated silver amount... o, r Gelatin... 0.6EX8-
r −-・・-1xio-'ExY-/&
・・・・・・ (7, /, 2ExC-Hiroshi
・・・・・・ 0.007Solv-/
・・・・・・ 0.0≠cpct-t
...... λX / 0-' 13th layer (1st
Protective layer) Fine grain silver iodobromide (average grain size 0.07 μm.

AgI 1 molti) Q, 2 Gelatin ・・・・・・ 01tUV-j
・・・・・・ 00lUV-Hiroshi
・・・・・・ 0. /UV-,r
・・・・・・ 0.2Solv-1−・・・・
・0.041Cpd-1...3X/
0-' 1st Hiro layer (2nd protective layer) Gelatin...O, polymethyl methacrylate particles (diameter i, rμm)...Ol, 2cpa-
t... ≠X10'H-/
・・・・・・ O,g (S of the present invention)
-/7) 0.20 In addition to the above components, a surfactant (t) was added to each layer as a coating aid. The sample prepared as described above was designated as sample 10/.

Next, the chemical structural formulas or chemical names of the compounds used in the present invention are shown below.

UV-j UV-, r: UV-/ 5o1v-/tricresyl diphosphate 5olv-coni7tal relative dibutyl'5olv-j bis(2-ethylhexyl niatalate) ExM-r: UV-λ (t)C+ H9 ExF −/: C2H50SOs- ExC-ko: ExC-j: (i) Q H90CONH ExC-HiroshiExC-&: ExC-7: ExC-/7 ExY-/Hiroshi: ExY-/r: H3 ExC-! : ExM-ta: ExM-10: ExM-/, z: Cpd-/: cpct-2: H Ca Hls (n> ExM-II: ExY-/6: ExS-2: ExS-J: ExS-Hiroshi: α ExS-1: ExS-1r 2H5 H-/: CH2=CH-802-CH2-CONHCH2CH2
=CH802CH2C0NH-CH2=CH-J: ExS-7: H Cpd-≠: Cpd-t: (Sample 102) Sample 10/7th, t% // and 12th layer of ExC-4
tf is halved and 0.3 times the molar amount of the original ExC-4' is added.
C-7' was added to each of the above layers to prepare 10 samples.

(Sample 103) 7th, r% l/ and remaining E of the 72nd layer of sample 102
Sample 1 by replacing xC-4Af with equimolar ExC-/7
03 was produced.

(Sample IOg) ExC-≠tl-i added to each layer of sample 10/
, r times the molar amount of the compound (22) of the present invention to prepare sample 104t.

(Sample ioz, 1ot) The metal compound of the present invention added to each layer of sample 1041 (
Half of 22) was removed and replaced with the compound (1) of the present invention in an amount of 002 times the mole of the original compound (22) to prepare sample 10r, and compound (22) was replaced with (19) to form compound (1)t-(9).
was replaced with sample iot.

When these samples were exposed to light for sensitometry and subjected to the following color development processing, each yellow magenta,
The density, sensitivity, and gradation of cyan were almost similar.

Color development processing Tatami supplementary light weight: Jjmm width of photosensitive material/m length.

A processing solution having the following composition was also prepared.

(color developer) Mother liquid G) diethylenetriamine Pentaacetic acid.

Sodium sulfite Hiroshi, O Potassium carbonate 30.0 Potassium bromide 7.3 Potassium iodide /0.2■Hydroxylamine sulfate Co.O μ-[N-ethyl-N-β-hydroxyethylamino]-2-methyl Aniline sulfate replenisher (!l) 6.0! , Q 37, O O1! 3.6 Add brine and pH (IQ white liquor) - (A) /, 3-diaminopropanetetraacetic acid Iron CI [I] Ammonium 7. 3-diaminoprono ξonetetraacetic acid Ammonium bromide Acetate Ammonium nitrate Add water and acetic acid Adjust pHvI4 with ammonia and ammonia (fixing solution) Ethylenediamine Shiseki Hiroshi, 7 6. Koi, ol i, ol 10.00 10.1! r mother liquor G) 0.2 l mol 3, O r! ! O/, 01 pH3. j mother solution G) /, replenisher) 0.30 mol≠, O /20 Hiroshi O /, 0l pHJ, r replenisher G) 1,! Sodium sulfite 10.0 Sodium bisulfite r.

ammonium thiosulfate aqueous solution <700 g/l) i7o, oxt rhodan ammonium ioo,.

Thiourea i.

3.4-dithia-/.

! -Octanediol 3.0 Add water /,Ol Add ammonia acetate pHit (stable solution) Mother solution and replenisher common formalin (37%)! - Chloroko Methy - Guinthiazoline - 3 - No. 12.0 10.0 Ko00.011Ll /jO,0 Evening, O! ,0/,01 6.7 1.

λd Nkomethyl-μm Intiazolin 3-one t, o'ag i, owhg Surfactant O, a (C, QH
2, ()+CH2CH2Osu10H) Ethylene glycol 1.0 Add water
/, 01 pHr, 0-7.0 These samples were slit to a width of ftA, /cm, and as shown in FIG. 3, they were rolled together with light-shielding paper and processed into a cartridge to produce photosensitive materials A to F that were stored in the cartridge. These light-sensitive materials are used in the Fuji Photo Film camera Fuji Chikara G564.
/-! After removing the back cover and removing the winding core, I loaded the cartridge into a camera that had been modified so that it could be loaded, and the screen size was 4 cm on the long side and 4 cm on the short side (screen effective area 4 cm).
cm, aspect ratio 1. ! ) Cover with black paper so that
'The CMTF pattern was photographed in full screen.

These photographed samples were subjected to the color development process described above, and the obtained samples were processed using Fuji enlarger A Otori O Professional.
At double magnification, Fujicolor Super HG was printed to -par and CP-238 standard processing was performed. MTF value f2×4LOOt of magenta and yellow images of the obtained print
1mf) A/+! - Measured at 9 Yers.

Also, the entire Macbeth color checker chart is IS.
It was photographed at a standard exposure of O100, developed in the above color, and the cyan density of the developed negative corresponding to the yellow part of the chart was measured and determined as the degree of color contamination.

The results obtained are summarized in Table/.

Table 7 (Screen effective area 2μcm2, screen aspect ratio 1.
The lower the cyan density, the less the cyan becomes yellowish.

From Table 1, it can be seen that the photosensitive material containing the compound of the present invention and having the effective screen area ratio of the present invention has excellent sharpness expressed by the MTF value even after printing, and has a low degree of color staining. The low value indicates excellent color reproducibility.

Example 2 The openings of the photosensitive material E of Example 1 were entirely covered with black paper to produce photosensitive materials E-/-E-4 housed in cartridges with openings as shown in Table 1. These photosensitive materials were loaded into the camera used in Example 1, and a half-body portrait of a woman, a portrait of a man and a woman, and a distant view of a mountain were all photographed outdoors on a sunny day. All of these photographed photosensitive materials were color developed using the same processing solution as in Example 1. The processed photosensitive material was subjected to Hiroba print development in the same manner as in Example 1. Only the photographic part of the obtained prints was cut out, and these prints were printed on a gray board with a reflection density of o and it, and 10 prints for each gender were printed under a fluorescent light for color evaluation, ranging from desirable to unpleasant. I asked them to rank things.

The results obtained are shown in Table 2. Table 2 shows that the prints made from the photosensitive material of the present invention had an above-average desirability tOW, demonstrating the effectiveness of the present invention.

Table 2 Tatami The most preferable item is t-, the second most preferable item is μ
One point will be deducted for each point, and the least preferred one is t-7.
The score was the average value of 20 people and 3 scenes.

Example 3 Sample 30/ was prepared by removing (S-/7) of the present invention from the 74th layer of sample/θt. Sample iot and 30/l-
We took 12 photos and processed them in accordance with ANSI standards on a 1.2t cartridge. 0C relative humidity! ! It was left in the water for 2 days.

Under the same conditions, after covering the opening with black paper to a size of 2.4 cm x 2 cm, / 0.4 cm x! , Ocm laminated moisture-proof paper (manufactured by Fuji Film ■, used for 2θ size) and sealed to prepare photosensitive materials G and H.

These samples were stored at T-600C for 3 days and subjected to the same color development process as in Example 1 at the same time as those not placed at TO0C.

The minimum color density of photosensitive materials G and H was higher for those stored to 0c than for those not stored at 0c, but the increase in minimum density was smaller for G than for H (the increase in minimum density was lower than that for yellow). -, magenta, cyan and G is 0
．． /r, 0. /7, O0/AH is Q, Koo, o, iy,
It was O0/7].

Example 4 The following composition was applied to the back surface of cellulose triacetate with a thickness of 120 μm which had been undercoated.

(Pack surface) 1st layer: Carbon black (average particle size 0.03 μm)...
・0.7g/m2 Cellulose substituted with acetyl group and hydroxypropyl group.../, jfl/m2 Second layer: Carbon black (average particle size 0./μm and 0.0λμm
λ pair/mixture) -・-・o, o g y 7rr! Sodium 2-octadecylsulfonate-0,0Or,lit 7m2 Cellulose substituted with acetyl group, hydroxypropyl group, hexahydrophthal group...O, co, 9/m2, on the support shown below A multilayer color photosensitive material≠oi1 was prepared by applying layers having the following compositions.

(Photosensitive layer composition) The numbers corresponding to each component indicate the coating amount expressed in units of 97 m 2 , and for silver halide and colloidal silver, the coating amount is expressed in terms of silver. However, for sensitizing dyes, the same -1
The coating amount per mole of silver halide is shown in mole units.

1st layer (antihalation layer) Black colloidal silver 5olv-≠ gelatin olv-j pd-3 olv-J 8o1v-/5olv-co 2nd layer (intermediate layer) Fine grain silver bromide (average particle size 0.07 μm) O1 /6 Q, l Hiroλ, O 0, θ 7 0.2 0, 02 30.03 0, Ko! 0,/! Gelatin/3 3rd layer (low-sensitivity red-sensitive emulsion layer) Monodisperse silver bromide emulsion (silver iodide, Tamoruchi, average grain size o
, rμm, coefficient of variation related to particle size (hereinafter simply referred to as coefficient of variation)/tachi) / ,! Gelatin λ・λExS-/
Hiro, oxio""'ExS-Koko, 0x10""'ExS-J
o, A×10-'ExC-10,
7 ExC-λ 0.06ExC-
z O,02cpct-/
0.0/8o1v-/
0. r8o1v-J
o, o6Solv-20,2 Solv-r o, orSol
v-4A O,/G layer (high sensitivity red-sensitive emulsion layer) Monodisperse silver iodobromide emulsion (silver iodide 3.7 molti, average grain size 0)
．． 7μm1 coefficient of variation/I%)l, co/, PtXlo-'! X10"-'Olri'x, io-' 0, / da0.03 Q, Oμ o, oio, or O, OJ o, oi O13 0,02 Gelatin Ex S -/ Ex S -J ExS -J ExC-μ ExC-t ExC-2 ExC-J 8o1v-≠ 8o1v-/Solv-j Solv-2 Solv-j \th! layer (middle layer) Gelatin Cpd-CoSolv-j th layer ( Low-sensitivity green-sensitive emulsion layer) Monodisperse silver iodobromide emulsion (silver iodide! mole whisper, 0, 0! 0.7 0.0/average grain size 0.3 μm, coefficient of variation/P%) O, 4c single Dispersed silver iodobromide emulsion (7 mol silver iodide, average grain size o, r
μm, coefficient of variation 20%) O, t Gelatin /, PExS-≠
KOX10-'Exa-r
rxt o-'ExS-+
2xIO-'ExM-60. /7 ExM-7o, ExM-4o, It Compound of the present invention (9) 0, 0λ Compound of the present invention (19) 0, 02Sol
v-co /, 3Solv-/
0.028o1v-IL
□-/, 28o1v-J
O,03Solv-!
0.0 7th layer (high sensitivity green-sensitive emulsion layer) Polydispersed silver iodobromide emulsion (silver iodide, 1 molten, average grain size o
, rμm, coefficient of variation/I%) O, r /, / /, 4CX/Q-' j, tXlo-4 /, Hiroxio-' o, or O, O≠ 0.02 0 + O Hiro, ooz O, 3 0, Q Ko, ot Gelatin ExS-Hiroshi ExS-'z ExS-6 Ex M -7 ExM-r Compound of the present invention (9) Compound of the present invention (19) Solv-/Solv-1 Solv -3 Solv - Hiroth r layer (yellow filter layer yellow colloidal gelatin 5olv-/ pct-2 O, 04A O, Hiro 0.007 Q, Ko5olv-io,
oa8o1v-ko Q,
λ8o1v-440,01A 2nd layer (low sensitivity blue-sensitive emulsion layer) Monodisperse silver iodobromide emulsion (silver iodide t mol, average grain size o, i
μm, coefficient of variation 20cm) 0.3 Monodisperse silver iodobromide emulsion (silver iodide! molar whisper, average grain size o, t
μm, coefficient of variation 17ch) 0.3 Gelatin 2°tExS-7J
X10''''4 EXS-r 1xio-'E
xY-10/, 2 Compound (22) of the present invention 0, 0 HiroE
xC-J o,ozSolv-
-/0.001rSolv-2
0,1 8o1v-30,0j Solv -440,0r 1st Q layer (high sensitivity blue-sensitive emulsion layer) Monodispersed silver iodobromide emulsion (silver iodide t morch, average grain size/,!
μm, coefficient of variation/hiro%) O, r / , 7 0 , Oλ O, Q≠ λ×10−'ko×io' O, ≠ 0.003 0.02 0.0.2 0 , 1 0, oi Gelatin Compound of the present invention (9) Compound of the present invention (22) ExS-7 ExS-r ExY-/θ 5olv-/xC-J Solv-J Solv-2 8o1v-≠ 1st/layer (first protection Layer) Fine grain silver iodobromide emulsion (silver iodide! Morch average grain size 0.07 μm) 0, 37 gelatin Q-rcpa-j
O,/Cpd-Hiropa-1 pd-6 Solv-/Solv-1 8o1v-≠ 12th layer (λth protective layer) Gelatin polymethyl methacrylate particles (diameter/, jμm) Cp d -r Solv-/Solv- J Solv-Hiroshi Compound of the Invention (s-it) In addition, surfactants CPCT-7 and H-2 were added.

, / , 1 , / , Q ta, 03 , O! 0, /3 Oo, 2 0 , j o, or Q , 03 o, or O, λ! Hardener) 1-/, ExS-/: ExS-1: ExS-3: ExS-7: ExS-μ: ExS-r: (CH2)3803- (CH2)3SO3Na (CH2)a 5Oa- (CH2) 3 SO3Na ExC-Hiroshi: 0CH2CONHCH2CH20CH3ExC-r: ExC-/: Cs Hll (t) ExM-7 α xM-r ExC-2 ExC-2 ExC-J cpct-1 Cpd-G CH3 ol V-/2H5 olv-1 Cpd-2 cpct-,? Cpd-Hirocpct-tol V-Hirocpct-7 pa-4 H-/ CH2=CH-802CH2 CH2=CH-8O2-CH2 H-2 (Sample Goko) Book of the 2.10th layer of sample aoi Compound (2z) 2 of the invention
Equimolar amounts of ExC-ta were substituted.

(Sample Hiroshi 777) Compound (9], @t in the first O layer of sample≠02, and compounds (9) and (19) in the 7th layer were all replaced with 1 equimole of ExC-2.

These samples 'ji3. Example 1
The photosensitive material 1.3. was wound into the same cartridge as in Example 1 without using the light-shielding paper used in Example 1, and the opening was t-4 cm x 44 cm. K was produced.

These were baked into paper according to the method of Example 1, and the MTF value was measured. However, color development of the photosensitive material was carried out as follows.

The results obtained are shown in Table 1.

After exposing the color photographic light-sensitive material as described above, use an automatic processor to process Super HRI using the method described below (until the cumulative replenishment amount of the solution becomes three times the capacity of the mother solution tank).
I-700' was treated.

Processing method processing time 3 minutes/! seconds minute 30 seconds λ minutes io seconds μ minutes λO seconds 1 minute Q second tank capacity oL ≠oL , 20L oL 0L Replenishment amount 33 go , 2! ν 1200M , 2! M From (2) to (1) Counterflow piping method.

l-〇oxtl Processing temperature r0c Jr'C, 24L'C roc 2≠oC Process color development bleaching water washing fixing water washing (1) water washing (2) /min oo seconds, 2aoC stable /min Oyo seconds Jr' C-co! 1 Drying Hirobu λO1p! j 0c Refill amount is 3! mm width/m length Next, the composition of the treatment liquid is described.

(Color developer) oL 0L Mother solution η) Replenisher y) Diethylenetriamine /, 0 /, / Pentaacetic acid / -Hydroxyethylidene-71/-Diphosphonic acid Sodium sulfite Potassium carbonate Potassium bromide Potassium iodide Hydroxylamine sulfate Hiroshi - [ N-Ethyl-N-β-hydroxyethylamine]-λ-Methylaniline sulfate was added to E)H (bleaching solution) 3.0 Hiro, O Jo, 0/, 4! /, yo ■ 2, Hiro≠,! 1.0L io, or 3. J Hiroshi, 4L 37.0 0.7 Ko, r! ,! /, 0L 10.10 Mother liquid) Replenisher) Ethylenediamine 100.0 /20.0 Trihydrate Ethylenediamine tetrahydrochloride disodium chloride Ammonium nitrate Ammonium aqueous (27%) Add water and H (Fix) Liquid) Ethylenediaminetetranodic acid disodium salt Sodium sulfite Sodium bisulfite Anthonium thiosulfate aqueous solution (7 (7%) Add all water and n (Stabilizing solution) io.

l≠0.0 30, O Otsu, rim /, OL 6.0 //, 0 160.0 3 o, O ≠°, O go 1, OL ri, 7 Mother liquor i) Replenisher J) 0, r O,7 7,61,0! , Q evening, yo/70.0111 ko00, Oml/, OL
/, OL 4.7 3. A Replenisher (Ji) Formalin (37%) Polyoxyethylene-p-monononylphenyl ether (average degree of polymerization/θ) Add ethylenediaminetetranodic acid disodium salt solution and add H2.0ml 0.3 o,or t,oL t,or,.

3.01 o, 4Ar o, or /、OL r, o-r,.

You can see that

Example 5 The opening was exposed using the sample process of Example 4! Photosensitive material 1-/-r-4 shown in Figure 1 was prepared. These and photosensitive material F were loaded into the camera used in Example 1, the same scene as in Example 1 was photographed, and the image was developed and printed.

I printed it. The print size is lλcmX
! The magnification was fully adjusted so that it was rcm. These - 1 piece
Print out a copy and check if it is acceptable for both men and women! I had someone monitor and evaluate it.

table! This indicates that the photosensitive material of the present invention can be tolerated by most people.

Also, the opening size is cmXjcm (screen effective surface atμcm)
) was prepared, and the above GS6≠! It has been found that a camera that is even larger than the modified machine is required, and that a camera larger than the size of the present invention would be too large and inconvenient.

From the table, the prints printed using the photosensitive material of the present invention have excellent sharpness expressed by MTF value! Tatami acceptable/points, unacceptable 0 points, average value of 2j and 3 rooms,
Rounding down to 3 decimal places Example 6 Sample 10 Hiro, ior, iot and sample ≠O/, ≠02
Sample 60 in which the photosensitive layer composition was coated on the support of Example 1.
/, 402 as the film size in Figure 3 (J! mm
j r Omm ), light-shielding paper size (3!.

J mm cm photosensitive material L1
M, N, 0, Pf, produced. These photosensitive materials are made by Fuji Photo Film ■/! The rA Trone size camera was completely removed, including the back cover of the Tough Guide Date, and loaded into a camera modified so that the above cartridge could be loaded, and photographed and printed in the same manner as in Example 5. The respective tolerances obtained are 0.26, Q, and 6.0. yr%o, 9t, 0. PAC
It was shown that the photosensitive material was quite satisfactory.

It was also found that this camera was smaller than the cameras used in Examples 1 to 5, making it more convenient to carry.

[Brief explanation of drawings]

FIG. 1 shows the positional relationship between the cartridge of the present invention and the camera. / indicates the cartridge of the present invention. 2 represents a camera compatible with it. FIG. 2 shows the car IJ edge of the present invention as seen from the front. FIG. 3 shows the film and light-shielding paper inserted into the cartridge of the present invention. 3 is a film (width lr/, Omm,
Length r3 mm) (i-, da is light-shielding paper (width & j,
Omm, length iotiom)@represents. Conflict over V-side (no change in content)

Claims (1)

[Scope of Claims] A film roll chamber in which a photographic light-sensitive material having a silver halide emulsion layer provided on a support is wound in advance and stored therein, and a winding chamber in which the photographic material is wound and stored after photography are connected and exposed. In a silver halide photographic light-sensitive material housed in a cartridge having a bridge portion having an opening for exposing the material, the effective screen area per frame exposed to the light-sensitive material at the opening is 3.0 cm^2 or more. 25.0cm
^2 or less, the ratio of the length of the long side to the length of the short side of one frame of screen is 1.1 or more and 2.0 or less, and the photosensitive material is expressed by the following general formula (I). A silver halide photographic material housed in a cartridge, characterized in that it contains a compound that is General formula (I) ▲There are numerical formulas, chemical formulas, tables, etc.▼ In the formula, R_1, R_2, R_3 and R_4 each represent a hydrogen atom or a lower alkyl group, and R_5 represents a hydrogen atom, an acylamino group, a sulfonamide group, or a phosphonamide group. basis,
represents an alkoxycarbonylamino group, an aryloxycarbonylamino group, an alkoxysulfonamide group, an aryloxysulfonamide group, a carbamoylamino group, or a sulfamoylamino group, n is an integer from 1 to 4, and TIME is the general formula (I) represents a timing group capable of releasing DI along with DI upon reaction of the compound represented by a color developing agent, and DI represents a development inhibitor.