JPH02269796A - Method and equipment for wet quenching of red-hot coke - Google Patents

Method and equipment for wet quenching of red-hot coke

Info

Publication number
JPH02269796A
JPH02269796A JP9379889A JP9379889A JPH02269796A JP H02269796 A JPH02269796 A JP H02269796A JP 9379889 A JP9379889 A JP 9379889A JP 9379889 A JP9379889 A JP 9379889A JP H02269796 A JPH02269796 A JP H02269796A
Authority
JP
Japan
Prior art keywords
coke
red
water
hot coke
fire extinguishing
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP9379889A
Other languages
Japanese (ja)
Inventor
Yonezou Terasoma
寺杣 米蔵
Ryuichi Orii
折井 隆一
Kazuo Boshi
傍士 和夫
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nippon Steel Corp
Original Assignee
Sumitomo Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Metal Industries Ltd filed Critical Sumitomo Metal Industries Ltd
Priority to JP9379889A priority Critical patent/JPH02269796A/en
Publication of JPH02269796A publication Critical patent/JPH02269796A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To effectively reduce the generation of H2S in wet quenching of red- hot coke by performing specified treatment before sprinkling water simultaneously over the whole red-hot coke put on a quenching car in a coke quenching tower. CONSTITUTION:Before sprinkling water simultaneously over the whole red-hot coke put on a quenching car in a coke quenching tower, the whole red-hot coke is preliminarily sprinkled with water for a short period of time to lower the temperature of coke and allowed to stand for a while to cool.

Description

【発明の詳細な説明】 (産業上の利用分野] この発明は、消火塔内において消火車に積載された赤熱
コークスを散水消火する湿式消火方法に係り、特に散水
時に発生する硫化水素臭を可及的に抑制する湿式消火方
法に関する。
[Detailed Description of the Invention] (Industrial Application Field) The present invention relates to a wet fire extinguishing method for extinguishing red hot coke loaded on a fire extinguishing truck with water in a fire extinguishing tower. This relates to a wet fire extinguishing method that effectively suppresses fire extinguishing.

〔従来の技術〕[Conventional technology]

コークス炉にて炭化完了した赤熱コークスは、消火車に
積載されて消火塔へと運搬される。そして消火塔内に運
搬された上記の赤熱コークスは、通常、湿式消火法によ
り消火される。
The red-hot coke that has been carbonized in the coke oven is loaded onto a fire extinguishing truck and transported to the fire extinguishing tower. The red-hot coke transported into the fire extinguishing tower is usually extinguished by a wet extinguishing method.

湿式消火法は、消火車に積載された赤熱コークス全体に
、消火塔内に配備した散水管より一斉散水して消火を行
ない、散水時に発生する水蒸気をそのまま消火塔頂部よ
り大気放散させる消火法である。
The wet fire extinguishing method is a fire extinguishing method in which the entire red-hot coke loaded in a fire extinguisher is extinguished by spraying water all at once from a water sprinkler pipe installed in a fire extinguishing tower, and the water vapor generated during the spraying is released directly into the atmosphere from the top of the extinguishing tower. be.

しかし、この湿式消火法は、散水時に水性反応を生じ、
多量の硫化水素(以下H,Sと記す)を水蒸気とともに
消火塔頂部より大気放散させるため、臭気苦情の原因と
なっている。
However, this wet fire extinguishing method produces an aqueous reaction when water is sprayed,
A large amount of hydrogen sulfide (hereinafter referred to as H and S) is released into the atmosphere from the top of the fire extinguishing tower along with water vapor, causing odor complaints.

この対策としては、乾式消火法(CDQ方式)や湿式ガ
ス回収消火法(プレッシャクラエンチング方式)などが
知られている。
As countermeasures against this problem, the dry fire extinguishing method (CDQ method) and the wet gas recovery fire extinguishing method (pressure cracking method) are known.

乾式消火法は、散水を行わず、N、ガスとの熱交換によ
って赤熱コークスの消火を行なう方法。
The dry extinguishing method is a method of extinguishing red-hot coke by exchanging heat with nitrogen and gas without spraying water.

湿式ガス回収消火法は、消火部を密閉状態として散水に
より赤熱コークスの消火を行なうとともに、散水時に発
生する水蒸気中のH,Sを含んだ水性ガスを回収利用し
、かつ水蒸気は冷却凝縮して散水用に回収する方法であ
る。
In the wet gas recovery fire extinguishing method, red-hot coke is extinguished by spraying water with the extinguishing section sealed, and the water gas containing H and S in the water vapor generated during water spraying is recovered and utilized, and the water vapor is cooled and condensed. This is a method of collecting water for watering.

(発明が解決しようとする課題〕 しかしながら、乾式消火法や湿式ガス回収消火法は、次
のような問題を有しており、実際には容易に採用し得な
いものであった。
(Problems to be Solved by the Invention) However, the dry fire extinguishing method and the wet gas recovery fire extinguishing method have the following problems and cannot be easily adopted in practice.

すなわち、乾式消火法や湿式ガス回収消火法は、いずれ
も大規模な設備を必要とするため、これらの導入には真
人な設備コストがかかり、広大な設備面積も確保する必
要があること、また、既にン!式消火法を採用している
設備から改造する場合には、既存設備を根本的に改造す
る必要があり、このため操業を長期間停止しなければな
らないこと等である。
In other words, both the dry fire extinguishing method and the wet gas recovery fire extinguishing method require large-scale equipment, so introducing these methods requires significant equipment costs and requires securing a vast equipment area. , already n! When modifying equipment that uses conventional fire extinguishing methods, it is necessary to fundamentally modify the existing equipment, which may require a long period of suspension of operation.

本発明は、このような実情に鑑みなされたもので、乾式
消火法や湿式ガス回収消火法を導入する必要がなく、現
在量も広く採用されている湿式消火法においてH,Sの
発生を効果的に減少できる方法を提供することを目的と
している。
The present invention has been developed in view of these circumstances, and eliminates the need to introduce dry fire extinguishing methods or wet gas recovery fire extinguishing methods, and effectively reduces the generation of H and S in wet fire extinguishing methods, which are currently widely adopted. The aim is to provide a method that can reduce the

〔課題を解決するための手段〕[Means to solve the problem]

上記目的を達成する本発明の第1の方法は、コークス消
火塔内において、消火車に積載された赤熱コークス全体
に一斉散水を行なうに際し、予め上記赤熱コークス全体
にコークス温度を低下させるための短時間の事前散水を
行ない、暫時静置冷却しておくことを特徴とする赤熱コ
ークスの湿式消火法を要旨とする。
A first method of the present invention for achieving the above-mentioned object is to spray water all at once over the entire red-hot coke loaded in a fire extinguishing truck in a coke fire extinguishing tower, by applying a short period of time to lower the coke temperature to the entire red-hot coke in advance. The gist of this paper is a wet extinguishing method for red-hot coke, which is characterized by pre-spraying with water for a period of time and allowing it to cool for a while.

また、本発明の第2の方法は、コークス消火塔内におい
て、消火車に積載された赤熱コークス全体を、部分的に
散水消火してゆくことを特徴とする赤熱コークスの湿式
消火方法を要旨とする。
The second method of the present invention is a wet extinguishing method for red-hot coke, which is characterized by partially extinguishing the entire red-hot coke loaded in a fire extinguishing truck with water in a coke fire extinguishing tower. do.

〔作  用〕[For production]

一般に、H,Sを発生する水性反応は、1000°C以
上の炭素物質に水蒸気を添加すると生じるとされている
。本発明の第1の方法によれば、−斉散水は、事前散水
によって1000°C以下の温度に低下した赤熱コーク
スに対して行われることとなり、水性反応が生じ難く、
Ht Sの発生量が著しく減少する。事前散水は、10
00 ’C以上の高温を保持する赤熱コークスに対して
行われるが、これは極短時間の散水であるため、水性反
応による■1□Sの発生量は僅かである。したがって、
事前散水および一斉散水で発生した水蒸気をそのまま消
火塔頂部より大気放散させても、水蒸気中のH,Si4
度が低いため、臭気苦情の解消が図れることとなる。
Generally, an aqueous reaction that generates H and S is said to occur when water vapor is added to a carbon material at a temperature of 1000°C or higher. According to the first method of the present invention, the simultaneous watering is carried out on red-hot coke whose temperature has been lowered to 1000°C or less by preliminary watering, so that aqueous reactions are less likely to occur;
The amount of HtS generated is significantly reduced. Pre-watering is 10
This is carried out on red-hot coke that maintains a high temperature of 00'C or higher, but since this is a very short-time water sprinkling, the amount of ■1□S generated by the aqueous reaction is small. therefore,
Even if the water vapor generated during pre-spraying and simultaneous watering is released into the atmosphere from the top of the fire extinguishing tower, H, Si4
Since the degree of odor is low, odor complaints can be resolved.

また、本発明の第2の方法のように、赤熱コークス全体
を部分的に順次散水消火してゆ(場合は、時間当りの消
火面積が小さくなり、それだけ水性反応の生じる範囲が
狭くなって、時間当りのH,Sの発生量のピーク値が減
少する。したがって、着地濃度は時間当りの発生量に比
例するのでピーク値が減少した分だけ着地濃度も小さく
なり、この場合もやはり臭気苦情の解消が図れることに
なる。
In addition, as in the second method of the present invention, when the entire red-hot coke is partially extinguished by water spray, the extinguishing area per hour becomes smaller, and the range in which the aqueous reaction occurs becomes smaller. The peak value of the amount of H and S generated per hour decreases.Therefore, since the landing concentration is proportional to the amount generated per hour, the landing concentration also decreases by the amount that the peak value decreases, and in this case as well, odor complaints are caused. It will be possible to resolve the issue.

以下、本発明の詳細な説明する。The present invention will be explained in detail below.

〔実施例〕〔Example〕

第1図は、本発明の第1の方法を実施した消火塔の模式
断面図で、消火塔1の内部には消火車2の停止位置上方
に散水管3が設けてあり、散水管3からの散水で消火車
2に積載された赤熱コークス4が消火され、その際発生
する水庫気が消火塔頂部5より大気放散されるようにな
っている。
Fig. 1 is a schematic sectional view of a fire extinguishing tower in which the first method of the present invention has been implemented. The red hot coke 4 loaded on the fire extinguisher 2 is extinguished by the water spraying, and the water vapor generated at this time is radiated into the atmosphere from the top 5 of the extinguishing tower.

散水管3は、第2図に示すように、格子枠状に配管して
あり、その枠部3′からの散水で赤熱コークス4の周辺
部を消火し、複数本の格子部3″からの散水で赤熱コー
クス4の中央部を消火して、赤熱コークス4全体を隈無
く消火するようになっている。散水管3には給水管6が
接続してあり、給水管6には、電動弁7が設けられてい
る。この電動弁7は、散水管3への水の送給と停止を切
り換えるものであり、弁の開閉はタイマー8によって時
間制御できるようにしである。
As shown in Fig. 2, the water sprinkler pipes 3 are arranged in the shape of a lattice frame, and the surrounding area of the red-hot coke 4 is extinguished by spraying water from the frame 3', and the water from the plurality of lattice parts 3'' is extinguished. The central part of the red-hot coke 4 is extinguished by water spraying, and the entire red-hot coke 4 is extinguished completely.A water supply pipe 6 is connected to the water supply pipe 3, and an electric valve is connected to the water supply pipe 6. 7 is provided. This electric valve 7 switches between supplying and stopping water to the sprinkler pipe 3, and the opening and closing of the valve can be time-controlled by a timer 8.

上記のタイマー8に、時間順に事前散水の開始時刻と停
止時刻、次いで一斉散水の開始時刻と停止時刻を設定し
、散水管3からの散水が第3図に示すような散水パター
ンで行われるようにする。
The above-mentioned timer 8 is set in chronological order to start and stop times for preliminary watering, and then to start and stop times for simultaneous watering, so that watering from the watering pipe 3 is performed in a watering pattern as shown in Figure 3. Make it.

すなわち、赤熱コークス4に対する散水を、事前散水と
一斉散水の前後2回に分けて行うのである。
That is, the red-hot coke 4 is sprinkled with water twice: before and after the preliminary watering and the simultaneous watering.

この場合、事前散水は、赤熱コークス4全体に湿りを与
える程度でよく、散水開始から停止までに要する散水時
間T1は図示例では2〜10秒程度、水量にして後に行
なう一斉散水の1/30〜1/10程度とした。また、
事前散水の停止から一斉散水の開始までに要する静置冷
却時間T2は5〜30秒程度、−斉散水の開始から停止
までに要する散水時間T、は50〜60秒程度とした。
In this case, the preliminary watering is sufficient to moisten the entire red-hot coke 4, and the watering time T1 required from the start to the stop of watering is about 2 to 10 seconds in the illustrated example, and the amount of water is 1/30 of that of the simultaneous watering that will be performed later. It was set to about 1/10. Also,
The standing cooling time T2 required from the stop of preliminary watering to the start of simultaneous watering was about 5 to 30 seconds, and the watering time T required from the start to stop of simultaneous watering was about 50 to 60 seconds.

第4図は、上記した本発明の第1の方法の実施により発
生した水・蒸気中のH,S濃度を、従来の湿式消火法の
場合と比較した散点グラフである。
FIG. 4 is a scatter graph comparing the H and S concentrations in water and steam generated by implementing the first method of the present invention described above with those in the conventional wet fire extinguishing method.

同図に見るように、本発明法(0印で示す)におけるH
、Sのピーク濃度は、従来法(・印で示す)におけるH
 t Sピーク濃度よりも約30%も減少しており、本
発明法がH7Sの生じ難い消火方法であることが明らか
となった。
As seen in the figure, H in the method of the present invention (indicated by 0 mark)
, the peak concentration of S is the peak concentration of H in the conventional method (indicated by
It was about 30% lower than the tS peak concentration, and it became clear that the method of the present invention is a fire extinguishing method that hardly generates H7S.

次に、本発明の第2の方法は、前記第1の方法で説明し
た消火塔の散水管3を、第5図に示すような構造に改造
して実施した。
Next, the second method of the present invention was carried out by modifying the water sprinkler pipe 3 of the fire extinguishing tower described in the first method to have a structure as shown in FIG.

すなわち、消火車2上方に配備される散水管3は、複数
個の独立した矩形管31〜34を消火車2の長平方向に
並列させてなる。これらの矩形管3、〜3.には、いず
れも給水本管6′と接続する独立した給水管61〜64
が接続してあり、それぞれの給水管には、前記同様のタ
イマー8.〜84で開閉が時間制御できる電動弁71〜
74が設けられている。したがって、散水管3を構成す
る各矩形管3.〜3.は、それぞれ独立して、かつ異な
る時間帯に赤熱コークス4に対して散水を行なうことが
でき、るのである。
That is, the water sprinkler pipe 3 arranged above the fire extinguisher 2 is formed by arranging a plurality of independent rectangular pipes 31 to 34 in parallel in the longitudinal direction of the fire extinguisher 2. These rectangular tubes 3, -3. In each case, there are independent water supply pipes 61 to 64 connected to the main water supply pipe 6'.
are connected to each water supply pipe, and a timer 8 similar to the above is connected to each water supply pipe. ~Electric valve 71 whose opening/closing can be controlled by time at ~84~
74 are provided. Therefore, each rectangular pipe 3 configuring the water sprinkler pipe 3. ~3. The red hot coke 4 can be sprinkled with water independently and at different times.

そこで、時間順に、まず矩形管3.のタイマ81に電動
弁7.の開閉時刻を設定し、ついで矩形管3□のタイマ
ー8tに電動弁7□の開閉時刻を設定し、つぎに矩形管
3.のタイマー8.に電動弁7、の開閉時刻を設定し、
最後に矩形管3.のタイマー84に電動弁7.の開閉時
刻を設定して、第6図に示すような散水パターンで散水
が行われるようにする。すなわち、まず矩形管31から
の散水で消火車2の先端部分に積載された赤熱コークス
4が消火され、ついで矩形管3!からの散水で消火車の
中央前半部分に積載された赤熱コークスが消火され、つ
ぎに矩形管3.からの散水で消火車の中央後半部分に積
載された赤熱コークスが消火され、最後に矩形管34か
らの散水で消火車の後端部分に積載された赤熱コークス
が消火されるようにするのである。
Therefore, in chronological order, first rectangular tube 3. The timer 81 of the electric valve 7. Set the opening/closing time of the electric valve 7□ on the timer 8t of the rectangular pipe 3□, and then set the opening/closing time of the electric valve 7□ on the timer 8t of the rectangular pipe 3□. Timer 8. Set the opening/closing time of electric valve 7,
Finally, rectangular tube 3. The timer 84 of the electric valve 7. The opening and closing times are set so that watering is performed in the watering pattern shown in FIG. That is, first, the red hot coke 4 loaded at the tip of the fire extinguisher 2 is extinguished by water spraying from the rectangular pipe 31, and then the rectangular pipe 3! The red-hot coke loaded in the center front half of the fire extinguisher was extinguished by water spray from the rectangular pipe 3. The red-hot coke loaded in the rear center portion of the fire extinguisher is extinguished by water spray from the rectangular pipe 34, and finally the red-hot coke loaded in the rear end of the fire extinguisher is extinguished by water spray from the rectangular pipe 34. .

図示例の場合、各矩形管31〜34の散水開始から停止
までの散水時間T、は、25〜30秒程度とし、先の矩
形管の散水停止から次の矩形管の散水開始までに弁切替
え時間T8として0.5〜1秒の間を置くようにした。
In the illustrated example, the watering time T from the start to the stop of watering for each rectangular pipe 31 to 34 is approximately 25 to 30 seconds, and the valve is switched from the stop of watering for the previous rectangular pipe to the start of watering for the next rectangular pipe. The time T8 was set to be between 0.5 and 1 second.

なお、各矩形管31〜34当りの散水時間Tは、通常の
一斉散水よりも短くなるので、消火不良が生じないよう
散水量を適宜調整する必要がある。
In addition, since the water sprinkling time T per each rectangular pipe 31-34 is shorter than normal simultaneous water sprinkling, it is necessary to adjust the amount of water sprinkling suitably so that inadequate fire extinguishing does not occur.

また、各矩形管3.〜34からの散水は、図示例のよう
に31から始まって3□→33→34と並列順に行なう
のが一般的であるが、これに限る必要はな(、例えば3
.→31→34→3□の順で行うようにしてもよい。
Also, each rectangular tube 3. Watering from ~34 is generally performed in parallel order starting from 31 and going from 3□ to 33 to 34 as shown in the illustrated example, but it is not necessary to limit it to this (for example, from 3 to 34).
.. The steps may be performed in the order of →31→34→3□.

第7図は、上記した本発明の第2の方法の実施により発
生した水蒸気中のH,S発生量を、従来の湿式消火法の
場合と比較した散点グラフである。
FIG. 7 is a scatter graph comparing the amount of H and S generated in the water vapor generated by implementing the second method of the present invention described above with that of the conventional wet fire extinguishing method.

同図に見るように、本発明法(○印で示す)におけるH
、Sのピーク発生量は、従来法(・印で示す)における
H、S発生量よりも約40%減少しており、本発明法が
H,Sの生じ難い消火方法であることが明らかとなった
As seen in the figure, H in the method of the present invention (indicated by a circle)
The peak generation amount of H and S is approximately 40% lower than the amount of H and S generated in the conventional method (indicated by the mark), and it is clear that the method of the present invention is a fire extinguishing method that hardly generates H and S. became.

〔発明の効果〕〔Effect of the invention〕

以上に説明したとおり、本発明によれば、コークス消火
塔において現在量も広く採用されている湿式消火法の欠
点であるH t Sの多量の発生を著しく減少させるこ
とができ、臭気苦情を防止することができる。しかも、
従来の湿式消火設備をほとんど改造する必要がなく、極
めて安価でかつ容易に実施することができる。
As explained above, according to the present invention, it is possible to significantly reduce the generation of large amounts of H t S, which is a drawback of the wet extinguishing method currently widely adopted in coke extinguishing towers, and prevent odor complaints. can do. Moreover,
There is almost no need to modify conventional wet fire extinguishing equipment, and it is extremely inexpensive and easy to implement.

【図面の簡単な説明】[Brief explanation of drawings]

第1図は、本発明を実施した消火塔の模式断面図、第2
図および第5図は本発明に係る散水管を説明する図で、
第1図のA−A線矢視図、第3図および第6図は本発明
に係る散水パターンを説明する図、第4図および第7図
は本発明法を実施した時のH□S発生量を従来法との比
較で示す散点グラフである。 l:消火塔、2:消火車、3;散水管、31〜34 :
矩形管、4:赤熱コークス、6,61〜64:給水管、
6′ :給水本管、7,71〜74 :電動弁、8,8
.〜84 ;タイマー
Fig. 1 is a schematic sectional view of a fire extinguishing tower in which the present invention is implemented;
5 and 5 are diagrams for explaining the water sprinkler pipe according to the present invention,
The A-A line arrow view in Fig. 1, Figs. 3 and 6 are diagrams explaining the watering pattern according to the present invention, and Figs. 4 and 7 show H□S when the method of the present invention is implemented. It is a scatter graph showing the amount generated in comparison with the conventional method. 1: Fire tower, 2: Fire engine, 3: Water pipe, 31-34:
Rectangular pipe, 4: Red-hot coke, 6, 61-64: Water supply pipe,
6': Water main, 7, 71-74: Electric valve, 8, 8
.. ~84; timer

Claims (1)

【特許請求の範囲】 1、コークス消火塔内において、消火車に積載された赤
熱コークス全体に一斉散水を行なうに際し、予め上記赤
熱コークス全体にコークス温度を低下させるための短時
間の事前散水を行い、暫時静置冷却しておくことを特徴
とする赤熱コークスの湿式消火方法。 2、コークス消火塔内において、消火車に積載された赤
熱コークス全体を、部分的に散水消火してゆくことを特
徴とする赤熱コークスの湿式消火方法。 3、コークス消火塔の消火車(2)停止位置上方に配備
される散水管(3)が、消火車(2)の長手方向に並列
する複数個の独立した矩形管(3_1)〜(3_4)よ
りなり、これらの矩形管に接続される給水管(6_1)
〜(6_4)に開閉がタイマー(8_1)〜(8_4)
で時間制御できる電動弁(7_1)〜(7_4)が設け
られていることを特徴とする消火塔の湿式消火設備。
[Claims] 1. In a coke fire extinguishing tower, when water is sprayed all at once over the entire red hot coke loaded in a fire extinguisher, water is pre-sprayed over the entire red hot coke for a short time in order to lower the coke temperature. , a wet extinguishing method for red-hot coke, which is characterized by allowing it to cool for a while. 2. A wet method for extinguishing red-hot coke, which is characterized by partially extinguishing the entire red-hot coke loaded in a fire extinguisher with water in a coke extinguishing tower. 3. The water sprinkler pipes (3) installed above the stop position of the coke fire extinguishing tower fire engine (2) are a plurality of independent rectangular pipes (3_1) to (3_4) arranged in parallel in the longitudinal direction of the fire engine (2). Water supply pipe (6_1) connected to these rectangular pipes
~ (6_4) opens and closes on timer (8_1) ~ (8_4)
Wet fire extinguishing equipment for a fire extinguishing tower, characterized in that it is equipped with electric valves (7_1) to (7_4) that can be time-controlled.
JP9379889A 1989-04-12 1989-04-12 Method and equipment for wet quenching of red-hot coke Pending JPH02269796A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP9379889A JPH02269796A (en) 1989-04-12 1989-04-12 Method and equipment for wet quenching of red-hot coke

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP9379889A JPH02269796A (en) 1989-04-12 1989-04-12 Method and equipment for wet quenching of red-hot coke

Publications (1)

Publication Number Publication Date
JPH02269796A true JPH02269796A (en) 1990-11-05

Family

ID=14092439

Family Applications (1)

Application Number Title Priority Date Filing Date
JP9379889A Pending JPH02269796A (en) 1989-04-12 1989-04-12 Method and equipment for wet quenching of red-hot coke

Country Status (1)

Country Link
JP (1) JPH02269796A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100401984B1 (en) * 1998-11-02 2003-12-18 주식회사 포스코 A method and apparatus for extinguishing fire from hot coke

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100401984B1 (en) * 1998-11-02 2003-12-18 주식회사 포스코 A method and apparatus for extinguishing fire from hot coke

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