JPH02267113A - Organic complex clay mineral - Google Patents
Organic complex clay mineralInfo
- Publication number
- JPH02267113A JPH02267113A JP8737789A JP8737789A JPH02267113A JP H02267113 A JPH02267113 A JP H02267113A JP 8737789 A JP8737789 A JP 8737789A JP 8737789 A JP8737789 A JP 8737789A JP H02267113 A JPH02267113 A JP H02267113A
- Authority
- JP
- Japan
- Prior art keywords
- organic
- clay minerals
- oil
- organic substance
- surfactant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002734 clay mineral Substances 0.000 title claims abstract description 44
- 239000000126 substance Substances 0.000 claims abstract description 33
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 21
- 239000003960 organic solvent Substances 0.000 claims abstract description 17
- 239000004094 surface-active agent Substances 0.000 claims abstract description 16
- 238000001694 spray drying Methods 0.000 claims abstract description 12
- 239000011259 mixed solution Substances 0.000 claims abstract description 3
- 239000002131 composite material Substances 0.000 claims description 9
- -1 sucrose fatty acid ester Chemical class 0.000 abstract description 41
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 17
- 239000000194 fatty acid Substances 0.000 abstract description 17
- 229930195729 fatty acid Natural products 0.000 abstract description 17
- 239000000203 mixture Substances 0.000 abstract description 14
- 239000000843 powder Substances 0.000 abstract description 10
- 239000002537 cosmetic Substances 0.000 abstract description 6
- 239000002245 particle Substances 0.000 abstract description 3
- 229930006000 Sucrose Natural products 0.000 abstract description 2
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 abstract description 2
- 229910052901 montmorillonite Inorganic materials 0.000 abstract description 2
- 238000005507 spraying Methods 0.000 abstract description 2
- 239000005720 sucrose Substances 0.000 abstract description 2
- 238000002360 preparation method Methods 0.000 abstract 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 20
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 17
- 239000003921 oil Substances 0.000 description 17
- 235000019198 oils Nutrition 0.000 description 17
- 239000007788 liquid Substances 0.000 description 15
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 13
- 239000004166 Lanolin Substances 0.000 description 13
- 235000019388 lanolin Nutrition 0.000 description 13
- 229940039717 lanolin Drugs 0.000 description 13
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 238000003756 stirring Methods 0.000 description 9
- 239000006185 dispersion Substances 0.000 description 7
- 235000011187 glycerol Nutrition 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- 238000000034 method Methods 0.000 description 7
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 6
- 239000004359 castor oil Substances 0.000 description 6
- 235000019438 castor oil Nutrition 0.000 description 6
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 6
- 239000001993 wax Substances 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 229940094522 laponite Drugs 0.000 description 5
- XCOBTUNSZUJCDH-UHFFFAOYSA-B lithium magnesium sodium silicate Chemical compound [Li+].[Li+].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Na+].[Na+].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3.O1[Si](O2)([O-])O[Si]3([O-])O[Si]1([O-])O[Si]2([O-])O3 XCOBTUNSZUJCDH-UHFFFAOYSA-B 0.000 description 5
- 239000000049 pigment Substances 0.000 description 5
- 239000000232 Lipid Bilayer Substances 0.000 description 4
- 239000003125 aqueous solvent Substances 0.000 description 4
- 235000015278 beef Nutrition 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000003974 emollient agent Substances 0.000 description 4
- 239000003205 fragrance Substances 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 4
- 239000003760 tallow Substances 0.000 description 4
- 229940058015 1,3-butylene glycol Drugs 0.000 description 3
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 235000019437 butane-1,3-diol Nutrition 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 3
- 229940079593 drug Drugs 0.000 description 3
- 239000003814 drug Substances 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 239000003925 fat Substances 0.000 description 3
- 235000019197 fats Nutrition 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 150000005846 sugar alcohols Polymers 0.000 description 3
- DUXYWXYOBMKGIN-UHFFFAOYSA-N trimyristoyl-sn-glycerol Natural products CCCCCCCCCCCCCC(=O)OCC(OC(=O)CCCCCCCCCCCCC)COC(=O)CCCCCCCCCCCCC DUXYWXYOBMKGIN-UHFFFAOYSA-N 0.000 description 3
- 229930003231 vitamin Natural products 0.000 description 3
- 229940088594 vitamin Drugs 0.000 description 3
- 239000011782 vitamin Substances 0.000 description 3
- 235000013343 vitamin Nutrition 0.000 description 3
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- ULQISTXYYBZJSJ-UHFFFAOYSA-N 12-hydroxyoctadecanoic acid Chemical compound CCCCCCC(O)CCCCCCCCCCC(O)=O ULQISTXYYBZJSJ-UHFFFAOYSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- RKJGFHYCZPZJPE-UHFFFAOYSA-N 2,2-bis(16-methylheptadecanoyloxymethyl)butyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCC(CC)(COC(=O)CCCCCCCCCCCCCCC(C)C)COC(=O)CCCCCCCCCCCCCCC(C)C RKJGFHYCZPZJPE-UHFFFAOYSA-N 0.000 description 2
- ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 2,3-dimethylbutane Chemical group CC(C)C(C)C ZFFMLCVRJBZUDZ-UHFFFAOYSA-N 0.000 description 2
- ALYNCZNDIQEVRV-UHFFFAOYSA-N 4-aminobenzoic acid Chemical compound NC1=CC=C(C(O)=O)C=C1 ALYNCZNDIQEVRV-UHFFFAOYSA-N 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 2
- CMBYOWLFQAFZCP-UHFFFAOYSA-N Hexyl dodecanoate Chemical compound CCCCCCCCCCCC(=O)OCCCCCC CMBYOWLFQAFZCP-UHFFFAOYSA-N 0.000 description 2
- 241000039951 Lithocarpus glaber Species 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 229940022663 acetate Drugs 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 150000005215 alkyl ethers Chemical class 0.000 description 2
- OGBUMNBNEWYMNJ-UHFFFAOYSA-N batilol Chemical compound CCCCCCCCCCCCCCCCCCOCC(O)CO OGBUMNBNEWYMNJ-UHFFFAOYSA-N 0.000 description 2
- 235000013871 bee wax Nutrition 0.000 description 2
- 239000012166 beeswax Substances 0.000 description 2
- QUKGYYKBILRGFE-UHFFFAOYSA-N benzyl acetate Chemical compound CC(=O)OCC1=CC=CC=C1 QUKGYYKBILRGFE-UHFFFAOYSA-N 0.000 description 2
- 239000010495 camellia oil Substances 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229940082500 cetostearyl alcohol Drugs 0.000 description 2
- HVYWMOMLDIMFJA-DPAQBDIFSA-N cholesterol Chemical compound C1C=C2C[C@@H](O)CC[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 HVYWMOMLDIMFJA-DPAQBDIFSA-N 0.000 description 2
- 235000019864 coconut oil Nutrition 0.000 description 2
- 239000003240 coconut oil Substances 0.000 description 2
- 238000004040 coloring Methods 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- MMXKVMNBHPAILY-UHFFFAOYSA-N ethyl laurate Chemical compound CCCCCCCCCCCC(=O)OCC MMXKVMNBHPAILY-UHFFFAOYSA-N 0.000 description 2
- 150000004665 fatty acids Chemical class 0.000 description 2
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 2
- 229940100463 hexyl laurate Drugs 0.000 description 2
- XMGQYMWWDOXHJM-UHFFFAOYSA-N limonene Chemical compound CC(=C)C1CCC(C)=CC1 XMGQYMWWDOXHJM-UHFFFAOYSA-N 0.000 description 2
- CDOSHBSSFJOMGT-UHFFFAOYSA-N linalool Chemical compound CC(C)=CCCC(C)(O)C=C CDOSHBSSFJOMGT-UHFFFAOYSA-N 0.000 description 2
- UWKAYLJWKGQEPM-LBPRGKRZSA-N linalyl acetate Chemical compound CC(C)=CCC[C@](C)(C=C)OC(C)=O UWKAYLJWKGQEPM-LBPRGKRZSA-N 0.000 description 2
- 229940057995 liquid paraffin Drugs 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- DNIAPMSPPWPWGF-UHFFFAOYSA-N monopropylene glycol Natural products CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 150000003904 phospholipids Chemical class 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- XOJVVFBFDXDTEG-UHFFFAOYSA-N pristane Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)C XOJVVFBFDXDTEG-UHFFFAOYSA-N 0.000 description 2
- 150000003242 quaternary ammonium salts Chemical class 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000013268 sustained release Methods 0.000 description 2
- 239000012730 sustained-release form Substances 0.000 description 2
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 2
- OULAJFUGPPVRBK-UHFFFAOYSA-N tetratriacontyl alcohol Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCCO OULAJFUGPPVRBK-UHFFFAOYSA-N 0.000 description 2
- 229940118594 trimethylolpropane triisostearate Drugs 0.000 description 2
- 239000001490 (3R)-3,7-dimethylocta-1,6-dien-3-ol Substances 0.000 description 1
- RUHCWQAFCGVQJX-RVWHZBQESA-N (3s,8s,9s,10r,13r,14s,17r)-3-hydroxy-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-1-one Chemical compound C1C=C2C[C@H](O)CC(=O)[C@]2(C)[C@@H]2[C@@H]1[C@@H]1CC[C@H]([C@H](C)CCCC(C)C)[C@@]1(C)CC2 RUHCWQAFCGVQJX-RVWHZBQESA-N 0.000 description 1
- QYIXCDOBOSTCEI-QCYZZNICSA-N (5alpha)-cholestan-3beta-ol Chemical compound C([C@@H]1CC2)[C@@H](O)CC[C@]1(C)[C@@H]1[C@@H]2[C@@H]2CC[C@H]([C@H](C)CCCC(C)C)[C@@]2(C)CC1 QYIXCDOBOSTCEI-QCYZZNICSA-N 0.000 description 1
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- OYHQOLUKZRVURQ-NTGFUMLPSA-N (9Z,12Z)-9,10,12,13-tetratritiooctadeca-9,12-dienoic acid Chemical compound C(CCCCCCC\C(=C(/C\C(=C(/CCCCC)\[3H])\[3H])\[3H])\[3H])(=O)O OYHQOLUKZRVURQ-NTGFUMLPSA-N 0.000 description 1
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 1
- KJPRLNWUNMBNBZ-QPJJXVBHSA-N (E)-cinnamaldehyde Chemical compound O=C\C=C\C1=CC=CC=C1 KJPRLNWUNMBNBZ-QPJJXVBHSA-N 0.000 description 1
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- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 description 1
- QMMJWQMCMRUYTG-UHFFFAOYSA-N 1,2,4,5-tetrachloro-3-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=C(Cl)C(Cl)=CC(Cl)=C1Cl QMMJWQMCMRUYTG-UHFFFAOYSA-N 0.000 description 1
- FRPZMMHWLSIFAZ-UHFFFAOYSA-N 10-undecenoic acid Chemical compound OC(=O)CCCCCCCCC=C FRPZMMHWLSIFAZ-UHFFFAOYSA-N 0.000 description 1
- 229940114072 12-hydroxystearic acid Drugs 0.000 description 1
- FPIPGXGPPPQFEQ-UHFFFAOYSA-N 13-cis retinol Natural products OCC=C(C)C=CC=C(C)C=CC1=C(C)CCCC1(C)C FPIPGXGPPPQFEQ-UHFFFAOYSA-N 0.000 description 1
- DHGBAFGZLVRESL-UHFFFAOYSA-N 14-methylpentadecyl 16-methylheptadecanoate Chemical compound CC(C)CCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C DHGBAFGZLVRESL-UHFFFAOYSA-N 0.000 description 1
- LGEZTMRIZWCDLW-UHFFFAOYSA-N 14-methylpentadecyl octadecanoate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCCCCCCCCCCCCCC(C)C LGEZTMRIZWCDLW-UHFFFAOYSA-N 0.000 description 1
- XFOQWQKDSMIPHT-UHFFFAOYSA-N 2,3-dichloro-6-(trifluoromethyl)pyridine Chemical compound FC(F)(F)C1=CC=C(Cl)C(Cl)=N1 XFOQWQKDSMIPHT-UHFFFAOYSA-N 0.000 description 1
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- SFAAOBGYWOUHLU-UHFFFAOYSA-N 2-ethylhexyl hexadecanoate Chemical compound CCCCCCCCCCCCCCCC(=O)OCC(CC)CCCC SFAAOBGYWOUHLU-UHFFFAOYSA-N 0.000 description 1
- OGJDIJKJFYOENF-UHFFFAOYSA-N 2-hexyldecyl tetradecanoate Chemical compound CCCCCCCCCCCCCC(=O)OCC(CCCCCC)CCCCCCCC OGJDIJKJFYOENF-UHFFFAOYSA-N 0.000 description 1
- XATHTZNVYDUDGS-UHFFFAOYSA-N 2-octadecylpropane-1,2,3-triol Chemical compound CCCCCCCCCCCCCCCCCCC(O)(CO)CO XATHTZNVYDUDGS-UHFFFAOYSA-N 0.000 description 1
- LEACJMVNYZDSKR-UHFFFAOYSA-N 2-octyldodecan-1-ol Chemical compound CCCCCCCCCCC(CO)CCCCCCCC LEACJMVNYZDSKR-UHFFFAOYSA-N 0.000 description 1
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 1
- ZQXRINMCMHCYBD-UHFFFAOYSA-N 4-(2-ethylhexoxy)-4-oxobutanoic acid Chemical compound CCCCC(CC)COC(=O)CCC(O)=O ZQXRINMCMHCYBD-UHFFFAOYSA-N 0.000 description 1
- MVJSIAIXMFGVSA-UHFFFAOYSA-N 6-(2-hexyldecoxy)-6-oxohexanoic acid Chemical compound CCCCCCCCC(CCCCCC)COC(=O)CCCCC(O)=O MVJSIAIXMFGVSA-UHFFFAOYSA-N 0.000 description 1
- OMIMMNYMUHKOIG-UHFFFAOYSA-N 6-oxo-6-undecoxyhexanoic acid Chemical compound CCCCCCCCCCCOC(=O)CCCCC(O)=O OMIMMNYMUHKOIG-UHFFFAOYSA-N 0.000 description 1
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 1
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Landscapes
- Cosmetics (AREA)
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Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明は、簡便に得られる、特に化粧品及び医薬品分野
において非常に有用な有機複合粘土鉱物に関し、ざらに
詳しくは、粘土鉱物と、有機溶剤に溶解する有機物質と
、界面活性剤と、水とからなる混合液を噴霧乾燥して得
られる有機複合粘土鉱物に関する。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to an organic complex clay mineral that is easily obtained and is very useful particularly in the cosmetic and pharmaceutical fields. The present invention relates to an organic composite clay mineral obtained by spray drying a liquid mixture consisting of an organic substance dissolved in water, a surfactant, and water.
[従来の技術]
粘土鉱物は各種のアルコール、アミンや水溶性高分子等
の有機極性分子やカチオン性分子と層間反応などを起こ
し、新しい機能を有する有機変性粘土鉱物を生成するこ
とが知られている。しかしながら、粘土鉱物と、有機溶
剤に溶解する有機物質との有機変性粘土鉱物を製造する
には、有機溶剤を用いた含浸法が用いられていた。すな
わち、有機物質を溶解した有機溶剤中に粘土鉱物を浸し
、その後溶媒を留去することにより有機変性粘土鉱物を
得ていた。この方法は、有機物質を一度、有機溶媒に溶
解きせることがら粘土鉱物中に有機物質を分子状に均一
に包含きせることかできるという利点があるものの、大
量の有機溶媒を用いることから、製造中の安全性面ある
いはコスト面に問題があった。[Prior art] It is known that clay minerals undergo interlayer reactions with organic polar molecules and cationic molecules such as various alcohols, amines, and water-soluble polymers, producing organically modified clay minerals with new functions. There is. However, an impregnation method using an organic solvent has been used to produce an organically modified clay mineral consisting of a clay mineral and an organic substance that dissolves in an organic solvent. That is, organically modified clay minerals were obtained by immersing clay minerals in an organic solvent in which an organic substance was dissolved, and then distilling off the solvent. This method has the advantage of being able to uniformly incorporate organic substances into clay minerals in the form of molecules by dissolving them once in an organic solvent, but since it uses a large amount of organic solvent, it There were problems with safety or cost.
[発明が解決しようとする課題]
本発明者等は、有機溶媒を用いずに、有機溶剤に溶解す
る有機物質を粘土鉱物に均一にしかも簡便に包含させる
べく鋭意研究を行なった結果、粘土鉱物と有機物質と界
面活性剤および水とからなる混合液を噴霧乾燥すると、
有機物質が微細な集合体であるため噴霧乾燥した際に得
られる粉末中に均一に包合でき、上記の欠点を解消した
優れた粉末を得るに至った。[Problems to be Solved by the Invention] The present inventors have conducted extensive research in order to uniformly and easily incorporate organic substances that dissolve in organic solvents into clay minerals without using organic solvents, and as a result, they have found that clay minerals When a mixture of organic substances, surfactants, and water is spray-dried,
Since the organic substance is a fine aggregate, it can be uniformly encapsulated in the powder obtained when spray-drying, and an excellent powder that eliminates the above-mentioned drawbacks has been obtained.
[課題を解決するための手段]
すなわち、本発明は粘土鉱物と、有機溶剤に溶解する有
機物質と、界面活性剤と、水とからなる混合液を噴霧乾
燥して得られる有機複合粘土鉱物に関する。[Means for Solving the Problems] That is, the present invention relates to an organic composite clay mineral obtained by spray drying a liquid mixture consisting of a clay mineral, an organic substance dissolved in an organic solvent, a surfactant, and water. .
本発明の有機物質がエモリエント剤である場合は、しっ
とりした使用感触と優れたエモリエント効果を有し、多
量に配合してもべたつくことがなく、また、有機物質が
油溶性色素の場合は、耐光性と着色力が優れ、また、有
機物質が香料の場合は、安全性と徐放性に優れ、また、
有機物質が薬物の場合は安定性を上昇させ、いづれもな
めらかな使用感触を与え、ざらに化粧料に配合した場合
、安定性、使用性に優れるものである。When the organic substance of the present invention is an emollient agent, it has a moist feel and excellent emollient effect, and does not become sticky even when blended in a large amount, and when the organic substance is an oil-soluble pigment, it has light resistance. It has excellent color properties and coloring power, and when the organic substance is a fragrance, it has excellent safety and sustained release properties.
When the organic substance is a drug, it increases stability and provides a smooth feel when used, and when incorporated into cosmetics, it has excellent stability and usability.
以下、本発明の構成について述べる。The configuration of the present invention will be described below.
本発明に用いる粘土鉱物はスメクタイト属に属する層状
ケイ酸塩鉱物であり、一般にはモンモリロナイト、バイ
デライト、ノントロナイト、サボナイト及び、ヘクトラ
イト等があり、これらは天然又は合成品のいずれであっ
てもよい。市販品では、クニビア、スメクトン(いずれ
もクニミネ工業)、ピーガム(パンダービルド社)、ラ
ポナイト(ラボルテ社)、フッ素四ケイ素雲母(トビ−
工業)等が利用できる。本発明の実施にあたっては、こ
れらの粘土鉱物のうちから、一種または二種以上が任意
に選択される。The clay mineral used in the present invention is a layered silicate mineral belonging to the genus smectite, and generally includes montmorillonite, beidellite, nontronite, sabonite, and hectorite, and these minerals may be natural or synthetic. good. Commercially available products include Kunivia, Smectone (all manufactured by Kunimine Industries), Peagum (Panderbuild), Laponite (Laborte), and Fluorine Tetrasilicon Mica (Toby).
Industrial) etc. can be used. In carrying out the present invention, one or more types of clay minerals are arbitrarily selected from among these clay minerals.
本発明に用いる有機溶剤に溶解する有機物質は、液状油
分、固型油分、半固型油分または水に難溶性の物質のい
ずれでもよく、例えばアボガド油、ツバキ油、タードル
油、マカデミアナツツ油、トウモロコシ油、ミンク油、
オリーブ油、ナタネ油、月見草油、卵黄油、ゴマ油、バ
ーシック油、小麦胚芽油、サザンカ油、ヒマシ油、アマ
ニ油、サフラワー油、綿実油、エノ油、大豆油、落花生
油、茶実油、カヤ油、コメヌカ油、シナキリ油、日本キ
リ油、ホホバ油、胚芽油、トリグリセリン、トリオクタ
ン酸グリセリン、トリイソパルミチン酸グリセリン等の
液体油脂、カカオ脂、ヤシ油、馬脂、硬化ヤシ油、パー
ム油、牛脂、羊脂、硬化牛脂、パーム核油、豚脂、牛骨
脂、モクロウ核油、硬化油、牛脚脂、モクロウ、硬化ヒ
マシ油等の固体油脂、ミツロウ、カンデリラロウ、綿ロ
ウ、カルナウバロウ、ペイベリーOつ、イボタロウ、鯨
ロウ、モンタンロウ、ヌカロウ、ラノリン、カポックロ
ウ、酢酸ラノリン、液状ラノリン、サトウキビロウ、ラ
ノリン脂肪酸イソプロピル、ラウリン酸ヘキシル、還元
ラノリン、ジョジョバロウ、硬質ラノリン、セラックロ
ウ、POEラノリンアルコールエーテル、POEラノリ
ンアルコールアセテート、POEコレステロールエーテ
ル、ラノリン脂肪酸ポリエチレングリコール、POE水
素添加ラノリンアルコールエーテル等のロウ類、流動パ
ラフィン、オシケライト、スクワレン、プリスタン、パ
ラフィン、モンタン、スクワラン、ワセリン、マイクロ
クリスタリンワックス等の炭化水素、ミリスチン酸イソ
プロピル、オクタン酸セチル、ミリスチン酸オクチルド
デシル、パルミチン酸イソプロピル、ステアリン酸ブチ
ル、ラウリン酸ヘキシル、ミリスチン酸ミリスチル、オ
レイン酸デシル、ジメチルオクタン酸へキシルデシル、
乳酸セチル、乳酸ミリスチル、ステアリン酸イソセチル
、イソステアリン酸イソセチル、12−ヒドロキシステ
アリル酸コレステリル、ジー2−エチルヘキシル酸エチ
レングリコール、ジペンタエリスリトール脂肪酸エステ
ル、モノインステアリン酸トアルキルグリコール、シカ
プリン酸ネオペンチルグリコール、リンゴ酸グリセリン
、トリー2−エチルヘキシル酸トリメチロールプロパン
、トリイソステアリン酸トリメチロールプロパン、テト
ラ−2−エチルヘキシル酸ペンタンエリスリトール、ト
リー2−エチルヘキシル酸グリセリン、トリイソステア
リン酸トリメチロールプロパン、セチル−2−エチルヘ
キサノエート、2−エチルへキシルパルミテート、トリ
ミリスチン酸グリセリン、トリー2−ヘプチルウンデカ
ン酸グリセライド、ヒマシ油脂肪酸メチルエステル、オ
レイン酸オレイル、セトステアリルアルコール、アセト
グリセライド、パルミチン酸−2−へブチルウンデシル
、アジピン酸ジイソプロピル、トラウロリルーし−グル
タミン酸−2−オクチルドデシルエスチル、アジピン酸
−2−へブチルウンデシル、エチルラウレート、セパチ
ン酸ジー2−エチルヘキシル、ミリスチン酸−2−へキ
シルデシル、パルミチン酸−2−へキシルデシル、アジ
ピン酸−2−へキシルデシル、セバヂン酸ジイソプロピ
ル、コハク酸−2−エチルヘキシル、酢酸エチル、酢酸
ブチル、酢酸アミル、クエン酸トリエチル等の合成エス
テル、ラウリン酸、ミリスチン酸、パルミチン酸ステア
リン酸、ベヘン(ベヘニル)酸、オレイン酸、12−ヒ
ドロキシステアリン酸、ウンデシレン酸、トール酸、ラ
ノリン脂肪酸、イソステアリン酸、リノール酸すルイン
酸、エイコサペンタエン酸等の高級アルコール脂肪酸、
ラウリルアルコール、セチルアルコール、ステアリルア
ルコール、ベヘニルアルコール、ミリスチルアルコール
、オレイルアルコール、セトステアリルアルコール、モ
ノステアリルグリセリンエーテル(バチルアルコール)
、2−デシルテトラゾシノール、ラノリンアルコール、
コレステロール、フィトステロール、ヘキシルドデカノ
ール、イソステアリルアルコール、オクチルドデカノー
ル等の直鎖、分岐高級アルコール、赤色215号、赤色
218号、赤色223号、赤色225号、だいだい色2
01号、黄色204号、緑色202号、紫色201号な
どのタール色素や、β−カロチン、アナトー、サクロ−
ハイエロー、カルミン酸などの天然色素等の油溶性色素
、リナロール、リナリルアセテート、シンナミックアル
デヒド、ベンジルアセテート、シトラール、リモネンな
どの香料、パラアミノ安息香酸、ホモメンチル−N−ア
セデルアントラニレート、アントラニレート、オクチル
シレート、2.4−ジヒドロキシベンゾフェノンなどの
紫外線吸収剤、ビタミンAおよびその誘導体、ビタミン
Dおよびその誘導体、ビタミンEおよびその誘導体、ビ
タミンにおよびその誘導体等のビタミン類、ステロール
類、精製されたリン脂質含有物、またはその水素添加物
、あるいは合成グリセリン脂質エステルおよびこれらの
混合物などが挙げられる。The organic substance that dissolves in the organic solvent used in the present invention may be a liquid oil, a solid oil, a semi-solid oil, or a substance that is sparingly soluble in water, such as avocado oil, camellia oil, turtle oil, macadamia nut oil, corn oil, mink oil,
Olive oil, rapeseed oil, evening primrose oil, egg yolk oil, sesame oil, basic oil, wheat germ oil, sasanquat oil, castor oil, linseed oil, safflower oil, cottonseed oil, eno oil, soybean oil, peanut oil, tea seed oil, kaya oil Liquid oils and fats such as rice bran oil, Shinakiri oil, Japanese tung oil, jojoba oil, germ oil, triglycerin, glycerin trioctanoate, glycerin triisopalmitate, cacao butter, coconut oil, horse tallow, hydrogenated coconut oil, palm oil, Solid fats and oils such as beef tallow, mutton tallow, hydrogenated beef tallow, palm kernel oil, pork fat, beef bone fat, Japanese oak kernel oil, hydrogenated oil, beef leg fat, Japanese oak oil, hydrogenated castor oil, beeswax, candelilla wax, cotton wax, carnauba wax, paiberry Otu, Ibotaro, spermaceti wax, Montan wax, cotton wax, lanolin, kapok wax, acetic acid lanolin, liquid lanolin, sugar cane wax, lanolin fatty acid isopropyl, hexyl laurate, reduced lanolin, Jojo wax, hard lanolin, shellac wax, POE lanolin alcohol ether, POE Waxes such as lanolin alcohol acetate, POE cholesterol ether, lanolin fatty acid polyethylene glycol, POE hydrogenated lanolin alcohol ether, hydrocarbons such as liquid paraffin, osikelite, squalene, pristane, paraffin, montan, squalane, petrolatum, microcrystalline wax, myristin Isopropyl acid, cetyl octoate, octyldodecyl myristate, isopropyl palmitate, butyl stearate, hexyl laurate, myristyl myristate, decyl oleate, hexyldecyl dimethyl octanoate,
Cetyl lactate, myristyl lactate, isocetyl stearate, isocetyl isostearate, cholesteryl 12-hydroxystearate, ethylene glycol di-2-ethylhexylate, dipentaerythritol fatty acid ester, toalkyl monoinstearate glycol, neopentyl glycol capriate, apple Acid glycerin, trimethylolpropane tri-2-ethylhexylate, trimethylolpropane triisostearate, pentaneerythritol tetra-2-ethylhexylate, glycerin tri-2-ethylhexylate, trimethylolpropane triisostearate, cetyl-2-ethylhexanoate , 2-ethylhexyl palmitate, glyceryl trimyristate, tri-2-heptylundecanoic acid glyceride, castor oil fatty acid methyl ester, oleyl oleate, cetostearyl alcohol, acetoglyceride, 2-hebutylundecyl palmitate, adipine diisopropyl acid, traurolyl-2-octyldodecyl ester glutamate, 2-hebutyl undecyl adipate, ethyl laurate, di-2-ethylhexyl sepatate, 2-hexyldecyl myristate, 2-to palmitate Synthetic esters such as xyldecyl, 2-hexyldecyl adipate, diisopropyl sebadate, 2-ethylhexyl succinate, ethyl acetate, butyl acetate, amyl acetate, triethyl citrate, lauric acid, myristic acid, stearic acid palmitate, behen Higher alcohol fatty acids such as (behenyl) acid, oleic acid, 12-hydroxystearic acid, undecylenic acid, tolic acid, lanolin fatty acid, isostearic acid, linoleic acid, sulfuric acid, and eicosapentaenoic acid,
Lauryl alcohol, cetyl alcohol, stearyl alcohol, behenyl alcohol, myristyl alcohol, oleyl alcohol, cetostearyl alcohol, monostearyl glycerin ether (batyl alcohol)
, 2-decyltetrazosinol, lanolin alcohol,
Linear and branched higher alcohols such as cholesterol, phytosterols, hexyldodecanol, isostearyl alcohol, octyldodecanol, Red No. 215, Red No. 218, Red No. 223, Red No. 225, Orange 2
Tar pigments such as No. 01, Yellow No. 204, Green No. 202, and Purple No. 201, β-carotene, annatto, and sacro-
Oil-soluble pigments such as yellow, natural pigments such as carminic acid, fragrances such as linalool, linalyl acetate, cinnamic aldehyde, benzyl acetate, citral, limonene, para-aminobenzoic acid, homomenthyl-N-acedelanthranilate, anthranilate , octyl sylate, ultraviolet absorbers such as 2,4-dihydroxybenzophenone, vitamins such as vitamin A and its derivatives, vitamin D and its derivatives, vitamin E and its derivatives, vitamins and their derivatives, sterols, purified Examples include phospholipid-containing substances, hydrogenated products thereof, synthetic glycerin lipid esters, and mixtures thereof.
また、水に難溶性物質としては、ユビキノン、ビタミン
P等のビタミン類、塩酸クロルヘキシジン、トリクロロ
カルバニリド、イルガラサンDP300などの殺菌剤、
酢酸デキサメタシン等の薬剤などが挙げられる。In addition, poorly soluble substances in water include vitamins such as ubiquinone and vitamin P, bactericidal agents such as chlorhexidine hydrochloride, trichlorocarbanilide, and irgalasan DP300.
Examples include drugs such as dexamethacin acetate.
本発明において界面活性剤とは、非イオン性界面活性剤
、イオン性界面活性剤(カチオン、アニオン、両性)の
いずれでもよいが、通常化粧料に用いられる非イオン性
界面活性剤が望ましい。更に詳しくは、蔗糖脂肪酸エス
テル、マルチトール脂肪酸エステルなどの糖あるいは糖
アルコール脂肪酸エステル、ソルビタン脂肪酸エステル
、グリセリン脂肪酸エステル、ポリグリセリン脂肪酸エ
ステル、プロピレングリコール脂肪酸エステル、ポリオ
キシエチレンソルビタン脂肪酸エステル、ポリオキシエ
チレンソルビット脂肪酸エステル、ポリオキシエチレン
グリセリン脂肪酸エステル、ポリエチレングリコール脂
肪酸エステル、ポリオキシエチレンアルキルエーテル、
ポリオキシエチレンフィトステロール、ポリオキシエチ
レンポリオキシプロビレンアルキルエーテル、ポリオキ
シエチレンアルキルフェニルエーテル、ポリオキシエチ
レンコレスタノールエーテル、ポリオキシエチレンヒマ
シ油、ポリオキシエチレン硬化ヒマシ油、ポリオキシエ
チレンミツロウ誘導体、ポリオキシエチレンラノリン誘
導体、ポリオキシエチレンアルキルアミン、ポリオキシ
エチレンアルキルアミド等が挙げられる。In the present invention, the surfactant may be either a nonionic surfactant or an ionic surfactant (cationic, anionic, or amphoteric), but preferably a nonionic surfactant commonly used in cosmetics. More specifically, sugar or sugar alcohol fatty acid esters such as sucrose fatty acid esters and maltitol fatty acid esters, sorbitan fatty acid esters, glycerin fatty acid esters, polyglycerin fatty acid esters, propylene glycol fatty acid esters, polyoxyethylene sorbitan fatty acid esters, and polyoxyethylene sorbitol. Fatty acid ester, polyoxyethylene glycerin fatty acid ester, polyethylene glycol fatty acid ester, polyoxyethylene alkyl ether,
Polyoxyethylene phytosterol, polyoxyethylene polyoxypropylene alkyl ether, polyoxyethylene alkylphenyl ether, polyoxyethylene cholestanol ether, polyoxyethylene castor oil, polyoxyethylene hydrogenated castor oil, polyoxyethylene beeswax derivative, polyoxy Examples include ethylene lanolin derivatives, polyoxyethylene alkylamines, polyoxyethylene alkylamides, and the like.
本発明において、混合液の製造方法としては、特に限定
されず、例えば、粘土鉱物を水に分散した液と、有機溶
剤に溶解する有機物質と界面活性剤と水とからなる混合
液とを混合する方法や、有機溶剤に溶解する有機物質と
界面活性剤と水とからなる混合液に粘土鉱物を撹拌しな
がら分散させる方法等が挙げられる。なお、ここでいう
有機溶剤に溶解する有機物質と界面活性剤と水とからな
る混合液とはエマルション、可溶化液、脂質二分子膜分
散液等のことをいう。In the present invention, the method for producing the liquid mixture is not particularly limited, and for example, a liquid in which clay minerals are dispersed in water is mixed with a liquid mixture consisting of an organic substance soluble in an organic solvent, a surfactant, and water. Examples include a method of dispersing clay minerals in a mixed solution of an organic substance dissolved in an organic solvent, a surfactant, and water while stirring. Note that the mixed liquid consisting of an organic substance dissolved in an organic solvent, a surfactant, and water refers to an emulsion, a solubilized liquid, a lipid bilayer membrane dispersion, and the like.
エマルションは水中油型あるいはマイクロエマルション
のいずれでもよく、また、エタノール、プロパツール等
の低級アルコール、グリセリン、1.3−ブチレングリ
コール等の多価アルコール等の水性溶剤を含有していて
もよい。The emulsion may be either an oil-in-water type or a microemulsion, and may also contain an aqueous solvent such as a lower alcohol such as ethanol or propatool, or a polyhydric alcohol such as glycerin or 1,3-butylene glycol.
可溶化液は界面活性剤水溶液に有機物質を溶解したもの
で、エタノール、プロパツール等の低級アルコール、グ
リセリン、1,3−ブチレングリコール等の多価アルコ
ール等の水性溶剤を含有してもよい。The solubilizing liquid is an organic substance dissolved in an aqueous surfactant solution, and may contain an aqueous solvent such as a lower alcohol such as ethanol or propatool, or a polyhydric alcohol such as glycerin or 1,3-butylene glycol.
脂質二分子膜分散液とは、リン脂質、ジアルキルジメチ
ルアンモニウムクロリド等の第4級アンモニウム塩型の
合成脂質または第4級アンモニウム塩と高級アルコール
との混合物からなるラメラ状またはベシクル状の分散液
と界面活性剤との混合物のことで、エタノール、プロパ
ツール等の低級アルコール、グリセリン、1.3−ブチ
レングリコール等の多価アルコール等の水性溶剤を含有
してもよい。A lipid bilayer membrane dispersion is a lamellar or vesicular dispersion consisting of a phospholipid, a quaternary ammonium salt type synthetic lipid such as dialkyldimethylammonium chloride, or a mixture of a quaternary ammonium salt and a higher alcohol. It refers to a mixture with a surfactant, and may contain an aqueous solvent such as a lower alcohol such as ethanol or propatool, or a polyhydric alcohol such as glycerin or 1,3-butylene glycol.
これら混合物の調製方法は、任意であり、必要に応じて
デイスパー、ホモミキサー、マントンボウリン等による
撹拌および加温等の操作を用いればよい。The method for preparing these mixtures is arbitrary, and operations such as stirring and heating using a disper, homomixer, Manton Bowlin, etc. may be used as necessary.
また、これら混合液は製造直後に粘土鉱物の水分散液を
混合し、該混合液を噴霧乾燥を行なうことができるので
、混合液は長期的に安定である必要はない。Furthermore, these mixed liquids do not need to be stable over a long period of time, since they can be mixed with an aqueous dispersion of clay minerals immediately after production and spray-dried.
有機複合粘土鉱物全量中の粘土鉱物の含有量は25〜9
9.5重量%が好ましく、ざらに好ましくは50〜90
.0重量%であり、有機複合粘土鉱物全量中の、有機物
質の含有量は0.05〜75重量%が好ましく、ざらに
好ましくは0.1〜50重量%であり、界面活性剤の含
有量は0.05〜75重量%が好ましく、ざらに好まし
くは0.1〜50重量%である。The content of clay minerals in the total amount of organic composite clay minerals is 25 to 9
9.5% by weight is preferable, preferably 50-90%
.. The content of organic substances in the total amount of organic composite clay minerals is preferably 0.05 to 75% by weight, more preferably 0.1 to 50% by weight, and the content of surfactants is preferably 0.05 to 75% by weight, more preferably 0.1 to 50% by weight.
本発明の有機複合粘土鉱物の製造法は、以下の様な噴霧
乾燥法を用いると、球状形状の整った有機複合粘土鉱物
が得られるので好ましい。In the method for producing an organic composite clay mineral of the present invention, it is preferable to use the following spray drying method because an organic composite clay mineral with a well-shaped spherical shape can be obtained.
すなわち、粘土鉱物を水性溶媒に分散させてゲルとなし
、有機溶剤に溶解する有機物質と界面活性剤と水とから
なる混合液と混合し、しかる後にこれを噴霧乾燥するこ
とによって得られる粘土鉱物を利用する方法である。That is, clay minerals obtained by dispersing clay minerals in an aqueous solvent to form a gel, mixing it with a liquid mixture consisting of an organic substance dissolved in an organic solvent, a surfactant, and water, and then spray-drying the mixture. This is a method that uses
上記ゲルにおける粘土鉱物の濃度は20重量%以下が好
ましく、それ以上の濃度ではゲル粘度が高くなり過ぎて
噴霧乾燥時の噴霧ノズルの液の送りが難しく、またノズ
ルの目詰り等が生じてしまう。The concentration of clay mineral in the above gel is preferably 20% by weight or less; if the concentration is higher than that, the gel viscosity becomes too high, making it difficult to feed the liquid through the spray nozzle during spray drying, and causing nozzle clogging. .
とくに好ましい濃度範囲は1〜10重量%である。A particularly preferred concentration range is 1 to 10% by weight.
ゲルの調製に際しては、粘土鉱物等が、十分に分散、膨
潤するように十分に撹拌することが好ましく、分散、膨
潤が不十分な場合は噴霧乾燥時にノズルの目詰りや、得
られた有機複合粘土鉱物が不揃いとなる場合があり好ま
しくない。When preparing a gel, it is preferable to sufficiently stir the clay minerals, etc. so that they are sufficiently dispersed and swollen. If the dispersion and swelling are insufficient, the nozzle may become clogged during spray drying, and the resulting organic composite may become clogged. Clay minerals may become irregular, which is not preferable.
噴霧乾燥は、ディスクタイプや加圧ノズル式、2流体ノ
ズル式などの一般的噴霧乾燥法が適用できる。General spray drying methods such as a disk type, a pressure nozzle type, and a two-fluid nozzle type can be applied to the spray drying.
いずれの場合も噴霧時の入口空気温度は、有機物質や界
面活性剤及び粘土鉱物が熱的に安定である温度域が好ま
しり、150〜300℃程度である。In either case, the inlet air temperature during spraying is preferably in a temperature range where the organic substance, surfactant, and clay mineral are thermally stable, and is approximately 150 to 300°C.
また排気温度はノズルからの噴霧流量などによって規定
されるが、大量100℃前後で良い。Further, the exhaust temperature is determined by the flow rate of the spray from the nozzle, etc., and may be around 100°C in large quantities.
こうして得られる粘土鉱物は、粘土鉱物の一次粒子が凝
集した構造を有する、球状の粉末であり、有機物質が均
一に粉末内部に含有きれており、粒子径は2〜20μm
程度である。また粒子表面の形態はあらかじめ調製した
ゲルの外観が透明であり粘度が高い(例えば、ラポナイ
トの場合)程、均一でなめらかなものとなる。The clay mineral obtained in this way is a spherical powder having a structure in which primary particles of clay mineral are aggregated, and the organic substance is uniformly contained inside the powder, and the particle size is 2 to 20 μm.
That's about it. Furthermore, the more transparent the appearance of the gel prepared in advance and the higher the viscosity (for example, in the case of laponite), the more uniform and smooth the particle surface morphology becomes.
[発明の効果]
本発明による有機複合粘土鉱物は、非常に簡単に得られ
、有機溶剤を用いずに製造でさ・るため、製造時の安全
性に優れ、また、コスト低減の面からも非常に有利であ
る。[Effects of the Invention] The organic composite clay mineral according to the present invention is extremely easy to obtain and can be produced without using organic solvents, so it has excellent safety during production and is also effective in terms of cost reduction. Very advantageous.
ざらに、化粧品等へ配合すると、ざらつき感のない極め
てすべりの良いなめらかでしっとりした使用感触を与え
るものである。また、含有されている有機物質がエモリ
エント効果を有する油分である場合は皮膚に対するエモ
リエント効果がありながら、全くべとつくことがなく、
油溶性色素の場合は耐性、着色力に優れ、香料の場合は
安定性、徐放性に優れ、また、薬物の場合は安定性に優
れ、更にはいづれも粉末化粧料に対しても安定的にこれ
らの水不溶性又は難溶性物質を配合できる。When blended into cosmetics, etc., it gives an extremely smooth and moist feel without any roughness. In addition, if the organic substance contained is an oil that has an emollient effect, it will have an emollient effect on the skin but will not be sticky at all.
Oil-soluble pigments have excellent resistance and coloring power, fragrances have excellent stability and sustained release properties, drugs have excellent stability, and all of them are stable for powdered cosmetics. These water-insoluble or sparingly soluble substances can be blended with the water-insoluble or sparingly soluble substances.
[実施例]
次に本発明の一層の理解のために、実施例をあげて更に
詳細に説明する。本発明はこれによって限定されるもの
ではない。配合量は全て重量%とする。[Example] Next, in order to further understand the present invention, the present invention will be described in more detail by giving examples. The present invention is not limited thereby. All compounding amounts are in weight%.
実施例1
■流動パラフィン 10.0■ポ
リオキシエチレン(10モル付加)モノオレイン酸エス
テル 2.0■メチルパラベン
0.15■イオン交換水
残余(製造法)
70℃に加温した■に■、■を溶解し、これをデイスパ
ーで撹拌しつつ、70℃加温した■を除温した後、室温
まで冷却して水中油型エマルションを得た。Example 1 ■Liquid paraffin 10.0■Polyoxyethylene (addition of 10 moles) monooleic acid ester 2.0■Methylparaben
0.15 ■ Ion exchange water
Residue (manufacturing method) Dissolve ■ and ■ in ■ heated to 70℃, stir this with a disper, remove the temperature of ■ heated to 70℃, and then cool to room temperature to form an oil-in-water emulsion. Obtained.
一方、水1店に上記のようにして調製したエマルション
500m Lを加え、そこにラポナイトXLG 30g
を撹拌しながら分散させる。得られたゲルをディスク式
噴霞乾燥器により、ディスク回転数20 、000rp
m、入口温度180℃、排気温度110℃で噴霧乾燥し
、2〜20μmの球状粉末を87g得た。On the other hand, add 500ml of the emulsion prepared as above to one cup of water, and add 30g of Laponite XLG.
Disperse while stirring. The obtained gel was dried in a disc-type fuka dryer at a disc rotation speed of 20,000 rpm.
The mixture was spray-dried at an inlet temperature of 180° C. and an exhaust temperature of 110° C. to obtain 87 g of spherical powder with a diameter of 2 to 20 μm.
実施例2
■ポリオキシエチレン
(60モル付加)硬化ヒマシ油 1.0■香
料 0.1■エタノ
ール 15.0■メチルパラ
ベン 0.10クエン酸
0.1■クエン酸ナトリウ
ム 0.301.3−ブチレングリ
コール 4.0■イオン交換水
残余(製法)
■〜■および■〜■をそれぞれ溶解し、両者を撹拌しつ
つ混合して可溶化液を得た。Example 2 ■ Polyoxyethylene (60 mol addition) hydrogenated castor oil 1.0 ■ Fragrance 0.1 ■ Ethanol 15.0 ■ Methylparaben 0.10 Citric acid
0.1 ■ Sodium citrate 0.30 1.3-butylene glycol 4.0 ■ Ion exchange water
Remains (manufacturing method) Each of ① to ② and ② to ② was dissolved, and both were mixed with stirring to obtain a solubilized liquid.
次に、水1店に上記のようにして調製した可溶化液50
0m Lを加え、そこにラポナイトXLG 30gを撹
拌しながら分散させる。ざらに撹拌して得られたゲルを
実施例1と同ように噴霧乾燥し、2〜20μmの球状粉
末を55g得た。Next, 50% of the solubilized solution prepared as above was added to 1 part of water.
Add 0 mL and disperse 30 g of Laponite XLG therein with stirring. The gel obtained by rough stirring was spray-dried in the same manner as in Example 1 to obtain 55 g of spherical powder with a diameter of 2 to 20 μm.
実施例3
■ポリオキシエチレン(20モル付加)2−オクヂルド
デシルエーテル 1.0■水添大豆レシヂン
1.0■メチルパラヘン
0.1■イオン交換水
残余(製造法)
Φ〜■を混合後、70℃に加温し、ホモミキサーにより
均一に分散させた後に室温まで冷却して、脂質二分子膜
分散液を得た。Example 3 ■Polyoxyethylene (20 mol addition) 2-ocdildodecyl ether 1.0 ■Hydrogenated soybean resin
1.0■ Methylparahen
0.1 ■ Ion exchange water
Remains (Production method) After mixing Φ to ■, the mixture was heated to 70°C, uniformly dispersed using a homomixer, and then cooled to room temperature to obtain a lipid bilayer membrane dispersion.
次に水1店にラポナイトXLG 30gを撹拌しながら
分散させる。得られたゲルに上記のようにして調製した
脂質二分子膜分散液を500m L加え、さらに撹拌す
る。その後実施例1と同様に噴霧乾燥し、2〜20μm
の球状粉末が37g得られた。Next, 30 g of Laponite XLG was dispersed in one portion of water while stirring. 500 mL of the lipid bilayer membrane dispersion prepared as described above is added to the obtained gel and further stirred. Thereafter, it was spray-dried in the same manner as in Example 1, and the thickness of 2 to 20 μm was obtained.
37g of spherical powder was obtained.
合し、噴霧乾燥により、2〜20μmの球状粉末38g
を得た。38 g of spherical powder of 2-20 μm was obtained by combining and spray drying.
I got it.
Claims (1)
面活性剤と、水とからなる混合液を噴霧乾燥して得られ
る有機複合粘土鉱物。(1) An organic composite clay mineral obtained by spray-drying a mixed solution consisting of a clay mineral, an organic substance dissolved in an organic solvent, a surfactant, and water.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8737789A JPH02267113A (en) | 1989-04-06 | 1989-04-06 | Organic complex clay mineral |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP8737789A JPH02267113A (en) | 1989-04-06 | 1989-04-06 | Organic complex clay mineral |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02267113A true JPH02267113A (en) | 1990-10-31 |
Family
ID=13913208
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP8737789A Pending JPH02267113A (en) | 1989-04-06 | 1989-04-06 | Organic complex clay mineral |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02267113A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09315926A (en) * | 1996-05-27 | 1997-12-09 | Lion Corp | Skin protective agent |
KR100484544B1 (en) * | 2002-08-30 | 2005-04-20 | 재단법인 포항산업과학연구원 | Method for manufacturing nano clay powder using spray dryer |
JP2011063475A (en) * | 2009-09-16 | 2011-03-31 | Kunimine Industries Co Ltd | Method for producing organized bentonite, and organized bentonite obtained thereby |
-
1989
- 1989-04-06 JP JP8737789A patent/JPH02267113A/en active Pending
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH09315926A (en) * | 1996-05-27 | 1997-12-09 | Lion Corp | Skin protective agent |
KR100484544B1 (en) * | 2002-08-30 | 2005-04-20 | 재단법인 포항산업과학연구원 | Method for manufacturing nano clay powder using spray dryer |
JP2011063475A (en) * | 2009-09-16 | 2011-03-31 | Kunimine Industries Co Ltd | Method for producing organized bentonite, and organized bentonite obtained thereby |
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