JPH02252601A - Fossil fuel reforming equipment by utilizing solar heat - Google Patents
Fossil fuel reforming equipment by utilizing solar heatInfo
- Publication number
- JPH02252601A JPH02252601A JP1073977A JP7397789A JPH02252601A JP H02252601 A JPH02252601 A JP H02252601A JP 1073977 A JP1073977 A JP 1073977A JP 7397789 A JP7397789 A JP 7397789A JP H02252601 A JPH02252601 A JP H02252601A
- Authority
- JP
- Japan
- Prior art keywords
- reforming
- fossil fuel
- tube
- solar heat
- reflecting mirror
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002803 fossil fuel Substances 0.000 title claims abstract description 22
- 238000002407 reforming Methods 0.000 title abstract description 22
- 238000006243 chemical reaction Methods 0.000 claims abstract description 24
- 239000003054 catalyst Substances 0.000 claims abstract description 14
- 239000007789 gas Substances 0.000 claims description 12
- 239000002994 raw material Substances 0.000 abstract description 5
- 238000005336 cracking Methods 0.000 abstract description 2
- 239000000446 fuel Substances 0.000 description 10
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 8
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- 238000010586 diagram Methods 0.000 description 5
- 239000001257 hydrogen Substances 0.000 description 5
- 229910052739 hydrogen Inorganic materials 0.000 description 5
- 229910002090 carbon oxide Inorganic materials 0.000 description 4
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- 150000002431 hydrogen Chemical class 0.000 description 3
- 238000006057 reforming reaction Methods 0.000 description 3
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- 229910002092 carbon dioxide Inorganic materials 0.000 description 2
- 239000001569 carbon dioxide Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- 239000003245 coal Substances 0.000 description 1
- 238000002485 combustion reaction Methods 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000004079 fireproofing Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 239000003915 liquefied petroleum gas Substances 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 238000013021 overheating Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
- Y02P20/133—Renewable energy sources, e.g. sunlight
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Combustion & Propulsion (AREA)
- Inorganic Chemistry (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は水素製造プラント、火力発電所等における化石
燃料の改質装置に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a fossil fuel reforming device in a hydrogen production plant, a thermal power plant, etc.
従来の燃料改質装置は改質反応に必要な熱量を化石燃料
の燃焼によって得られた熱により供給するものが一般的
である。Conventional fuel reformers generally supply the amount of heat necessary for the reforming reaction using heat obtained by burning fossil fuels.
この従来装置の一態様を第3図によって説明する。複数
の加熱用バーナ4を設けた改質炉2内に複数の反応管3
が設けられており、この反応管3は−F部が連通ずる2
重管となっており、環状部分に改質用触媒5が充填され
ていて、原料ガスl(例えば、天然ガス、L P G
、メタノール等)は、外部より反応管3内の改質用触媒
5内を通り、加熱されて反応を起こし、水素及び−酸化
炭素、二酸、化酸素等を改質され、改質ガス6として反
応管3の内管部を通り外部へ排出される。One aspect of this conventional device will be explained with reference to FIG. A plurality of reaction tubes 3 are installed in a reforming furnace 2 equipped with a plurality of heating burners 4.
is provided, and this reaction tube 3 has a -F section communicating with 2.
It is a heavy pipe, and the annular part is filled with a reforming catalyst 5, and the raw material gas l (for example, natural gas, LPG
, methanol, etc.) passes through the reforming catalyst 5 in the reaction tube 3 from the outside, is heated to cause a reaction, and is reformed into hydrogen, carbon oxide, diacid, oxygen oxide, etc., and becomes a reformed gas 6. It passes through the inner tube part of the reaction tube 3 and is discharged to the outside.
又、加熱用バーナ4では、化石燃料(例えば、石油、石
炭等)を燃焼させるものである。Further, the heating burner 4 burns fossil fuel (eg, oil, coal, etc.).
従来の燃料改質装置においては、改質反応に必要な熱量
を化石燃料の燃焼熱により得ているが、燃料改質装置と
供給された熱量を全て燃料改質に用いることは実際の装
置においては不可能である。In conventional fuel reformers, the amount of heat required for the reforming reaction is obtained from the combustion heat of fossil fuels, but in actual equipment it is difficult to use all of the heat supplied to the fuel reformer for fuel reforming. is impossible.
このため、実機においては燃料改質過程において得られ
る発熱量の増加分以上に多くの燃料を用いねばならず、
全体として化石燃料の発熱量を増加させることは不可能
であった。For this reason, in actual equipment, it is necessary to use more fuel than the increase in calorific value obtained in the fuel reforming process.
It has been impossible to increase the calorific value of fossil fuels as a whole.
本発明はかかる状況に鑑み、化石燃料を太陽熱により改
質し、これに伴う化石燃料の消費を低減しようとするも
のである。In view of this situation, the present invention aims to reform fossil fuels using solar heat and reduce the associated consumption of fossil fuels.
本発明は太陽熱を集光する反射鏡と、内部の触媒層を化
石燃料ガスが通過するように構成された反応管・とより
なり、該反応管が前記反射鏡の焦点位置に配設されてな
ることを特徴とする太陽熱利用化石燃料改質装置である
。The present invention comprises a reflecting mirror that concentrates solar heat and a reaction tube configured to allow fossil fuel gas to pass through an internal catalyst layer, and the reaction tube is arranged at the focal point of the reflecting mirror. This is a fossil fuel reformer that utilizes solar heat.
本発明装置の反射鏡は、太陽の方位、高度に対し、常に
鰻通な向きとなるように自動追尾装置を付設することが
好ましい。It is preferable that an automatic tracking device is attached to the reflecting mirror of the device of the present invention so that the reflecting mirror is always oriented in the correct direction with respect to the direction and altitude of the sun.
また、反応管は二重管とし、その環状部に触媒を充填し
、化石燃料ガスは先ずこの環状部を通−で反転し、中心
管から系外に出るように構成することが好ましい。Further, it is preferable that the reaction tube is a double tube, the annular portion thereof is filled with a catalyst, and the fossil fuel gas is first reversed through the annular portion and exits from the system through the central tube.
すなわち、本発明は化石燃料の改質(発熱量の増加及び
水素、−酸化炭素等の有用なガス成分の製造)壱太陽熱
により行うもので、この化石燃料の改質は太陽熱の熱エ
ネルギを反射鏡により集熱し、改質に必要な温度まで反
応管を加熱することにより行うようにした装置である。That is, the present invention involves reforming fossil fuels (increasing calorific value and producing useful gas components such as hydrogen and carbon oxide) using solar heat.This reforming of fossil fuels involves reflecting the thermal energy of solar heat. This device collects heat using mirrors and heats the reaction tube to the temperature required for reforming.
太陽熱を反射鏡により改質反応に必要な温度(化石燃料
の種類により異なる:例えば天然ガス、L、 I) G
等は80°0〜900℃メタノールは250〜300℃
程度)土で集熱・加熱する。Temperature required for reforming reaction of solar heat using a reflecting mirror (varies depending on the type of fossil fuel: e.g. natural gas, L, I) G
etc.: 80°0~900°C Methanol: 250~300°C
Degree) Heat is collected and heated using soil.
集熱部に改質用触媒を充填した反応管を設置し、反応管
内に原料の化石燃料及び改質1気を導入する。原料ガス
は集熱された太陽熱により以下に示す反応を起こし、水
素及び−酸化炭素、二酸化炭素等に改質される。A reaction tube filled with a reforming catalyst is installed in the heat collecting section, and the raw material fossil fuel and reforming gas are introduced into the reaction tube. The raw material gas undergoes the following reaction due to the collected solar heat, and is reformed into hydrogen, carbon oxide, carbon dioxide, and the like.
太陽熱
ω〜■の右辺の唆熱星が太陽エネルギの回収看に相当す
る。The heating star on the right side of solar heat ω~■ corresponds to the solar energy recovery star.
以下、本発明の一実施例を第1図及び第2図によって説
明する。第1図はその全体概略図、第2図は反応管の概
略図である。An embodiment of the present invention will be described below with reference to FIGS. 1 and 2. FIG. 1 is a schematic diagram of the entire structure, and FIG. 2 is a schematic diagram of the reaction tube.
第1図に示すように、太陽光1を反射鏡2により、その
前面に設置された反応管3に集光する。反射鏡2は太陽
の方位、高度に対し常に最適の向きとなるよう自動追尾
装置4により向きを変え得るようになっている。As shown in FIG. 1, sunlight 1 is focused by a reflecting mirror 2 onto a reaction tube 3 installed in front of it. The reflecting mirror 2 can be changed in direction by an automatic tracking device 4 so that it always has the optimum direction with respect to the direction and altitude of the sun.
一方、反応管3は第2図に示すように、反射鏡2の焦点
部に設置し、太陽熱を有効利用できるよう内管8を挿入
し、改質用(又はクラッキング用)触媒5を環状部に充
填する。改質用原料ガス6(化石燃料と水蒸気の混合ガ
ス)は改質用触媒5層に導入され、内部で水素及び−酸
化炭素等からなる改質ガス7に改質される。改質ガスは
反応路Y後反転して反応管3内に設置された内管8の内
側を通り、触媒層部に熱を回収された後に反応管3外へ
取り出される。On the other hand, as shown in FIG. 2, the reaction tube 3 is installed at the focal point of the reflecting mirror 2, an inner tube 8 is inserted so that solar heat can be effectively utilized, and a reforming (or cracking) catalyst 5 is placed in the annular section. Fill it. The raw material gas for reforming 6 (mixed gas of fossil fuel and steam) is introduced into the five layers of the reforming catalyst, and reformed therein into a reformed gas 7 consisting of hydrogen, carbon oxide, and the like. After the reaction path Y, the reformed gas is reversed, passes inside the inner tube 8 installed in the reaction tube 3, and is taken out of the reaction tube 3 after heat is recovered by the catalyst layer.
本発明により、燃料改質に必要な熱量を太陽エネルギで
賄うことが可能となり、燃料費の低減及び発生する二酸
化炭素の抑制が期待される。The present invention makes it possible to cover the amount of heat required for fuel reforming with solar energy, and is expected to reduce fuel costs and suppress carbon dioxide emissions.
また、従来の燃料改質装置で問題となっていた反応管部
のホットスポットの発生(局部過熱)を防ぐことが可能
となり、信頼性の向上及び安価な材料(SUS材等)の
使用が可能となる。In addition, it is possible to prevent the occurrence of hot spots (local overheating) in the reaction tube, which was a problem with conventional fuel reformers, improving reliability and making it possible to use inexpensive materials (SUS materials, etc.) becomes.
さらには従来装置の熱容量の大部分を占めていた耐火材
、断熱材を極めて軽量化できるため、起動に要する時間
の短縮も可能となる。Furthermore, since the weight of fireproofing and heat insulating materials, which accounted for most of the heat capacity of conventional devices, can be significantly reduced, the time required for startup can also be shortened.
第1図は本発明の一実施例に係る装置の全体概略図、第
2図は本発明の一実施例に係る反応管の概略図、第3図
は従来の燃料改質装置の一態様の概略図である。FIG. 1 is an overall schematic diagram of an apparatus according to an embodiment of the present invention, FIG. 2 is a schematic diagram of a reaction tube according to an embodiment of the present invention, and FIG. 3 is an embodiment of a conventional fuel reformer. It is a schematic diagram.
Claims (1)
スが通過するように構成された反応管とよりなり、該反
応管が前記反射鏡の焦点位置に配設されてなることを特
徴とする太陽熱利用化石燃料改質装置。It consists of a reflecting mirror that collects solar heat and a reaction tube configured to allow fossil fuel gas to pass through an internal catalyst layer, and the reaction tube is arranged at the focal point of the reflecting mirror. This is a fossil fuel reformer that uses solar heat.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1073977A JPH02252601A (en) | 1989-03-28 | 1989-03-28 | Fossil fuel reforming equipment by utilizing solar heat |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1073977A JPH02252601A (en) | 1989-03-28 | 1989-03-28 | Fossil fuel reforming equipment by utilizing solar heat |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02252601A true JPH02252601A (en) | 1990-10-11 |
Family
ID=13533667
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1073977A Pending JPH02252601A (en) | 1989-03-28 | 1989-03-28 | Fossil fuel reforming equipment by utilizing solar heat |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02252601A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005016816A1 (en) * | 2003-08-18 | 2005-02-24 | Sony Corporation | Fuel reformer and fuel reforming method |
JP2012101947A (en) * | 2010-11-05 | 2012-05-31 | Toyota Motor Corp | Hydrogen production apparatus and hydrogen production method |
JP2012171808A (en) * | 2011-02-17 | 2012-09-10 | Ihi Corp | Reaction furnace |
JP2012171978A (en) * | 2011-02-17 | 2012-09-10 | Ihi Corp | Reactor |
CN109695966A (en) * | 2019-01-18 | 2019-04-30 | 河北赛特驰实验器材销售有限公司 | A kind of new application and photo-thermal system of selective absorption material |
-
1989
- 1989-03-28 JP JP1073977A patent/JPH02252601A/en active Pending
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2005016816A1 (en) * | 2003-08-18 | 2005-02-24 | Sony Corporation | Fuel reformer and fuel reforming method |
JP2012101947A (en) * | 2010-11-05 | 2012-05-31 | Toyota Motor Corp | Hydrogen production apparatus and hydrogen production method |
JP2012171808A (en) * | 2011-02-17 | 2012-09-10 | Ihi Corp | Reaction furnace |
JP2012171978A (en) * | 2011-02-17 | 2012-09-10 | Ihi Corp | Reactor |
CN109695966A (en) * | 2019-01-18 | 2019-04-30 | 河北赛特驰实验器材销售有限公司 | A kind of new application and photo-thermal system of selective absorption material |
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