JPH02225578A - Surface-protective adhesive film or sheet - Google Patents

Surface-protective adhesive film or sheet

Info

Publication number
JPH02225578A
JPH02225578A JP4830589A JP4830589A JPH02225578A JP H02225578 A JPH02225578 A JP H02225578A JP 4830589 A JP4830589 A JP 4830589A JP 4830589 A JP4830589 A JP 4830589A JP H02225578 A JPH02225578 A JP H02225578A
Authority
JP
Japan
Prior art keywords
film
sheet
ink
surface protection
adhesive film
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP4830589A
Other languages
Japanese (ja)
Inventor
Toshiharu Konishi
小西 俊春
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Nitto Denko Corp
Original Assignee
Nitto Denko Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Nitto Denko Corp filed Critical Nitto Denko Corp
Priority to JP4830589A priority Critical patent/JPH02225578A/en
Publication of JPH02225578A publication Critical patent/JPH02225578A/en
Pending legal-status Critical Current

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Abstract

PURPOSE:To make it possible to prevent a base film or sheet from easily undergoing breaking or lifting even when it is subjected to, e.g. multistage drawing in a state stuck to a plate by forming a printed part on the film or sheet with an ink which can form a coating film of a specified strength. CONSTITUTION:A printed part of a thickness <=30mum is formed on a base film or sheet (A) of a thickness of 20-150mum (e.g. a film or sheet of low-density PE) by using an ink (B) which comprises a vehicle resin and optionally a colorant, a plasticizer, a surfactant, an antifoamer, a diluent, etc., and can form a coating film of a Young's modulus which is at most 120% of that of component A, and a pressure-sensitive adhesive layer (C) is formed on the back of the film or sheet.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、印刷部を有する表面保護接着フィルムおよび
シート(以下、フィルムおよびシートの両者をフィルム
と総称する)に関するものであり、板状物、特にステン
レス板、アルミニウム板、鋼板のような金属板の表面保
護、就中金属板を多段階絞り加工する等の作業性に優れ
ている、印刷部を有rる表面保護接着フィルムを堤供す
るものである。
Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a surface protection adhesive film and sheet (hereinafter, both the film and the sheet are collectively referred to as a film) having a printed portion, and We provide a surface protection adhesive film with a printed part that has excellent workability, especially for protecting the surface of metal plates such as stainless steel plates, aluminum plates, and steel plates, especially for multi-step drawing processing of metal plates. It is something.

〔従来技術・発明が解決しようとする課題〕従来、上記
の如き金属板等の板状物の表面保護用としてポリオレフ
ィン樹脂フィルムあるいはポリ塩化ビニル系(軟’り樹
脂フィルムに印刷を施したものを基材とした表面保護接
着フィルムが知られている。当該フィルムは、これを単
に板状物の保管または運搬上の表面保護のみを目的とし
て用いる場合は特に問題はないが、板状物に表面保護フ
ィルムを仮着した後、多段階絞り加工等を行った場合、
表面保護フィルムが切れたり、板状物より浮き上がって
次工程の加工時に板状物が傷付いたり、また作業が不可
能となったりすることが多々ある。
[Prior art/problem to be solved by the invention] Conventionally, polyolefin resin films or polyvinyl chloride (soft resin films with printing applied to them) have been used to protect the surfaces of plate-like objects such as metal plates as described above. A surface protection adhesive film using a base material is known.This film poses no particular problem when used solely for the purpose of storing or transporting a plate-like object, but it may cause surface protection on a plate-like object. If a multi-step drawing process is performed after temporarily attaching a protective film,
There are many cases where the surface protection film breaks or lifts up from the plate-like object, causing damage to the plate-like object during the next process, or making the work impossible.

そのため、上記用途には一般に基材フィルムとして、印
刷しないポリ塩化ビニル系樹脂を用いた表面保護接着フ
ィルムが用いられる。これはポリ塩化ビニル系樹脂フィ
ルムの有する強度(降伏点強度)、引張強度等がポリオ
レフィン系樹脂より優れているためである4このように
表面保護接着フィルムにおいて、基材フィルムの材質領
域は表面保護機能に大きく寄与する。
Therefore, in the above applications, a surface protection adhesive film using a non-printed polyvinyl chloride resin is generally used as the base film. This is because the strength (yield point strength), tensile strength, etc. of polyvinyl chloride resin films are superior to polyolefin resins.4 In this way, in surface protection adhesive films, the material area of the base film is used for surface protection. Contributes significantly to functionality.

ところが、せっか(基材フィルムの物性を合わせても基
材フィルムに印刷をする場合、従来板状物用の表面保護
接着フィルムに使用されているインキを使用した場合に
は、当該インキ被膜の強度が基材フィルムのそれに比較
して、1桁以上大きくなるので、印刷を施した基材フィ
ルムを用いた表面保護接着フィルムを貼って多段階絞り
加工を行った場合、切れや浮き上がり、打痕等になるな
どの重大な問題が生起する。
However, even when the physical properties of the base film are combined, when printing on the base film, when using the ink conventionally used for surface protection adhesive films for plate-shaped objects, the strength of the ink film is is more than an order of magnitude larger than that of the base film, so when applying a surface protection adhesive film using a printed base film and performing a multi-step drawing process, there may be cuts, lifting, dents, etc. Serious problems such as

従って、本発明の目的は板状物、特に金属よりなる板状
物に表面保護接着フィルムを貼って板状物の多段階絞り
加工等を行った場合にも、フィルムの切れや浮き上がり
が極めて少なく、ひいては板状物における打痕等の発生
が少ない表面保護接着フィルムを提供することである。
Therefore, the object of the present invention is to minimize the tearing and lifting of the film even when a surface protection adhesive film is attached to a plate-like object, especially a metal plate-like object, and multi-step drawing processing is performed on the plate-like object. Furthermore, it is an object of the present invention to provide a surface protection adhesive film that is less likely to cause dents or the like on plate-shaped objects.

〔課題を解決するための手段〕[Means to solve the problem]

本発明者は上記問題点を解決するために種々研究を重ね
てきたところ、上記の如き印刷フィルムを基材として用
いてなる表面保護接着フィルムにおいて、その印刷イン
キの被膜強度(即ち、当該インキの乾燥状、態における
ヤング率)が基材フィルムのそれに対して大きく超えな
いこと、具体的には基材フィルムのヤング率に対して1
20%を超えないヤング率を有する被膜強度を形成する
インキを使用することによって上記の問題点が解決され
ること、またそのためには、通常インキの物性値で初期
モデュラス値(ヤング率)が50kg/mm”以下の被
膜強度を形成するインキを使用することが好適であると
いう新知見を得た。
The present inventor has conducted various studies in order to solve the above-mentioned problems, and has found that in a surface protection adhesive film using the above-mentioned printing film as a base material, the film strength of the printing ink (i.e., the strength of the ink) (Young's modulus in a dry state) does not greatly exceed that of the base film, specifically, the Young's modulus of the base film is 1
The above problems can be solved by using an ink that forms a film strength having a Young's modulus not exceeding 20%, and for this purpose, the initial modulus value (Young's modulus) of the physical properties of the ink is usually 50 kg. A new finding has been obtained that it is suitable to use an ink that forms a film strength of 0.2 mm" or less.

従って、本発明は次の(1)および(2)の要旨を有す
るものである。
Therefore, the present invention has the following points (1) and (2).

(1)基材フィルムのヤング率に対して120%を超え
ないヤング率を有する被膜強度を形成するインキを使用
して基材フィルムに印刷部を設けてなる表面保護接着フ
ィルム。
(1) A surface protection adhesive film in which a printed portion is provided on a base film using an ink that forms a film strength having a Young's modulus not exceeding 120% of the Young's modulus of the base film.

(2)基材フィルムにヤング率が50kg/mm2以下
である被膜強度を形成する印刷インキを使用して印刷部
を設けてなる表面保護接着フィルム。
(2) A surface protection adhesive film in which a printed portion is provided on a base film using a printing ink that forms a coating strength with a Young's modulus of 50 kg/mm 2 or less.

本発明で使用されるフィルム基材としては、たとえば、
低密度ポリエチレン(LDPESLLDPE) 、中密
度ポリ、エチレン(MDPE)、高密度ポリエチレン(
HDPE)、 ポリプロピレン(PP)、エチレン−酢
酸ビニル共重合体CEVA(ビニルアセテート:10w
71)%以下))1.lZチルエチレンアクリレートコ
ポリマー(EEA (エチルアクリレ−):10w/w
%以下)〕等が好ましいものとして例示される。フィル
ムのjγみは、一般に20〜150μm、好ましくは2
0〜100μm、さらに好ましくは30〜60μmであ
る。
Examples of film base materials used in the present invention include:
Low-density polyethylene (LDPESLLDPE), medium-density polyethylene (MDPE), high-density polyethylene (
HDPE), polypropylene (PP), ethylene-vinyl acetate copolymer CEVA (vinyl acetate: 10w
71)% or less))1. lZ thyl ethylene acrylate copolymer (EEA (ethyl acrylate): 10w/w
% or less)] and the like are exemplified as preferred. The jγ profile of the film is generally 20 to 150 μm, preferably 2
It is 0 to 100 μm, more preferably 30 to 60 μm.

本発明で使用されるインキは、上記のフィルム基材のヤ
ング率に対して120%を超えないヤング率を有する被
膜強度を形成するインキ(より好適には100%以下)
であれば特に制限はなく、市販されているインキの中か
ら当該条件を満足するものを適宜選択すればよい。
The ink used in the present invention is an ink that forms a film strength having a Young's modulus not exceeding 120% of the Young's modulus of the film base material (more preferably 100% or less).
If so, there is no particular restriction, and an ink that satisfies the conditions may be appropriately selected from commercially available inks.

当該インキにおいて当該強度を決めるビヒクルの樹脂と
しては、ブチラール系、アクリル系、石油樹脂系、ポリ
エステル系、ポリアミ1′系、ポリウレタン系などの樹
脂が使用でき、特にアクリル系の場合は低ガラス転位点
(好ましくは30 ’C以下、さらに好ましくは0°C
以下)のアクリルエステル系であり、かつ熱可塑性のも
のが好適である。
As the vehicle resin that determines the strength of the ink, butyral-based, acrylic-based, petroleum resin-based, polyester-based, polyamide 1'-based, polyurethane-based resins, etc. can be used, and in the case of acrylic-based resins, resins with a low glass transition point can be used. (preferably 30'C or less, more preferably 0°C
The following acrylic ester type and thermoplastic ones are suitable.

当該インキには、さらに無機、有機系顔料等の着色剤、
エステルや多価アルコールであるグリセリンのエステル
等の可塑剤、脂肪酸その他の有機酸あるいはその金属塩
、オキシ酸及びその誘導体、スルホン酸化合物、レンチ
ル等の界面活性剤、シリコーン等の消泡剤、希釈溶剤等
が配合される。
The ink further contains colorants such as inorganic and organic pigments,
Plasticizers such as esters and esters of glycerin which is a polyhydric alcohol, fatty acids and other organic acids or their metal salts, oxyacids and their derivatives, sulfonic acid compounds, surfactants such as lentil, antifoaming agents such as silicones, and diluents. A solvent and the like are added.

本発明の表面保護接着フィルムにおけるインキ層(イン
キ被膜)の厚さは30μm以下、より好ましくは5〜2
0μmであり、30μmを超えると切れや傷つきとなる
傾向がある。
The thickness of the ink layer (ink coating) in the surface protection adhesive film of the present invention is 30 μm or less, more preferably 5 to 2 μm.
0 μm, and if it exceeds 30 μm, there is a tendency for cuts and scratches to occur.

本発明において感圧性接着剤層用として用いられる感圧
性接着剤としては、本発明の趣旨から、特に特殊なもの
を用いる必要はなく、表面保護接着フィルム用として自
体既知のものを使用すればよい、たとえば、ゴム系接着
剤、合成樹脂系接着剤(例、アクリル系接着剤)が例示
される。
In the present invention, as the pressure-sensitive adhesive used for the pressure-sensitive adhesive layer, there is no need to use a special one in view of the spirit of the present invention, and it is sufficient to use a pressure-sensitive adhesive known per se for use in surface protection adhesive films. Examples include rubber adhesives and synthetic resin adhesives (eg, acrylic adhesives).

本発明の表面保護接着フィルムは、例えばグラビア印刷
法にて、基材フィルムに当該インキを使用して印刷を施
し、さらに上記感圧性接着剤層を自体既知の手段にて上
記フィルムに形成することによって型造される。
The surface protection adhesive film of the present invention can be obtained by printing the ink on a base film using, for example, a gravure printing method, and further forming the pressure-sensitive adhesive layer on the film by a known method. molded by.

本発明の表面保護接着フィルムにおいて、インキは上記
基材フィルムと接着剤層との間に位置することが一般的
には好適であるがその限りではない。
In the surface protection adhesive film of the present invention, it is generally preferable that the ink be located between the base film and the adhesive layer, but this is not a limitation.

〔実施例) 以下に実施例を示して本発明をより詳細に説明するが、
本発明はこれらに限定されるものではな実施例I LLDPE樹脂(三菱油化社製、商品名:ユカo7LL
−3]00F%MF R1,3g/Login 、、d
 =0.930g/ca+″)を溶融押出機にて厚さ3
0μmのフィルム状に押出しく当該フィルムのヤング率
=16kg/+n+”) 、その後乾燥後15 kg/
+s+”のヤング率を有するアクリル系インキ(組成ニ
アクリルエステル−アクリロニトリル−アクリル酸共重
合物ビヒクルを主体としたもの)を5μmの曜さでセブ
ラ印刷しさらに該フィルム面にアクリルゴムを主体とす
る感圧性接着剤液を乾燥後の厚みが10umになるよう
に塗布乾燥し、表面保護接着フィルムを得た。
[Example] The present invention will be explained in more detail with reference to Examples below.
The present invention is not limited to these examples. Example I LLDPE resin (manufactured by Mitsubishi Yuka Co., Ltd., product name: Yuka o7LL)
-3]00F%MF R1,3g/Login,,d
=0.930g/ca+'') to a thickness of 3 using a melt extruder
Young's modulus of the film extruded into a 0 μm film = 16 kg/+n+''), then 15 kg/ after drying
+s+" acrylic ink (composition mainly composed of acrylic ester-acrylonitrile-acrylic acid copolymer vehicle) was printed with a 5 μm width, and further, acrylic rubber was mainly applied to the film surface. A pressure sensitive adhesive liquid was applied and dried to a dry thickness of 10 um to obtain a surface protection adhesive film.

比較例1 実施例1と同様にフィルム形成を行い、その後乾燥状態
においてl OOkg/ms”のヤング率を有するアク
リル系インキを実施例】と同じ形で印刷して表面保護接
着フィルムを得た。
Comparative Example 1 A film was formed in the same manner as in Example 1, and then an acrylic ink having a Young's modulus of 1 OO kg/ms'' in a dry state was printed in the same manner as in Example] to obtain a surface protection adhesive film.

比較例2 実施例1の基材フィルムで、かつ印刷部を有しないタイ
プの表面保護接着フィルムを得た。
Comparative Example 2 A surface protection adhesive film using the base film of Example 1 and having no printed portion was obtained.

実験例1 実施例1および比較例1.2で得られた表面保護接着フ
ィルムの物性を調べた。その結果を第1表に示す。
Experimental Example 1 The physical properties of the surface protection adhesive films obtained in Example 1 and Comparative Example 1.2 were investigated. The results are shown in Table 1.

なお、各試験方法は次の通りである。In addition, each test method is as follows.

(絞り加工性) 厚さO,13+mの5US304BA仕上げステンレス
板(100嘘φ)に表面保護接着フィルムを仮着し、第
1図に示すように直径50鵬、曲率半径51の面取りを
したポンチおよび曲率半径5閾の面取りをしたダイにて
絞り、基材の破れ、および加工後に室温24時間放置し
た後の浮きを判定。
(Drawing workability) A surface protective adhesive film was temporarily attached to a 5US304BA finished stainless steel plate (100mm diameter) with a thickness of 0.13+m, and a punch with a diameter of 50mm and a radius of curvature of 51mm was chamfered as shown in Figure 1. Squeezing with a chamfered die with a radius of curvature of 5 thresholds to determine if the base material is torn or if it lifts after being left at room temperature for 24 hours after processing.

(0°C貼合わせ作業性) 4005m1X 100mo−ル状テープを、0 ’C
雰囲気中にて、100閤φネオプレンゴム貼合わせI(
スピード: 50 m/5in)にて、厚さ0.8 m
、1)1400m、長さ1mの5US304BA仕上げ
ステンレス板を貼合わせた時のシワ発生を判定。
(0°C lamination workability) 4005m1×100mol tape at 0'C
In an atmosphere, 100mm diameter neoprene rubber lamination I (
Speed: 0.8 m thick at 50 m/5 in)
, 1) Determine the occurrence of wrinkles when 5US304BA finished stainless steel plates with a length of 1400 m and a length of 1 m are laminated together.

第1表 第1表中の注− 絞り加工性試験結果において0、Δおよび×はそれぞれ
次のことを意味する。
Table 1 Notes to Table 1 - In the drawing workability test results, 0, Δ and × mean the following, respectively.

Q:浮きの面積O〜20% △:浮きの面積21〜50% ×:浮きの面積51〜100% 0℃貼合わせ作業性試験結果においてQおよび×はそれ
ぞれ次のことを意味する。
Q: Floating area 0 to 20% Δ: Floating area 21 to 50% ×: Floating area 51 to 100% In the 0° C. lamination workability test results, Q and × mean the following, respectively.

O:シワなく貼れたもの ×:シワ発生 〔作用・効果〕 本発明の表面保護接着フィルムは均一成形性を有するも
のである。
O: Can be pasted without wrinkles. ×: Wrinkles occur [Function/Effect] The surface protection adhesive film of the present invention has uniform moldability.

従って、板状物に当該表面保護接着フィルムを貼って板
状物の多段階絞り加工等を行った場合にも、フィルムの
切れや浮き上がりが極めて少なく、ひいては板状物にお
ける打痕等の発生が少ないという効果が得られる。
Therefore, even when the surface protection adhesive film is applied to a plate-shaped object and the plate-shaped object is subjected to multi-step drawing processing, there is very little chance of the film breaking or lifting up, and furthermore, the occurrence of dents etc. on the plate-shaped object is minimized. You can get the effect of less.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の表面保護接着フィルムの絞り加工性を
調べるための装置の概略断面回である。 ■・・・表面保護接着フィルム 2・・・ステンレス板 3・・・ポンチ 4.4′ ・・・押さえ ・ダイ
FIG. 1 is a schematic cross-sectional view of an apparatus for examining the drawability of the surface protection adhesive film of the present invention. ■...Surface protection adhesive film 2...Stainless steel plate 3...Punch 4.4'...Pressure/die

Claims (4)

【特許請求の範囲】[Claims] (1)基材フィルムまたはシートのヤング率に対して1
20%を超えないヤング率を有する被膜強度を形成する
インキを使用して基材フィルムまたはシートに印刷部を
設けてなることを特徴とする表面保護接着フィルムまた
はシート。
(1) 1 for the Young's modulus of the base film or sheet
1. A surface protection adhesive film or sheet, characterized in that a printed portion is provided on a base film or sheet using an ink that forms a film strength having a Young's modulus not exceeding 20%.
(2)基材フィルムまたはシートにヤング率が50kg
/mm^2以下である被膜強度を形成する印刷インキを
使用して印刷部を設けてなることを特徴とする表面保護
接着フィルムまたはシート。
(2) Young's modulus of base film or sheet is 50 kg
1. A surface protection adhesive film or sheet, characterized in that a printed portion is provided using a printing ink that forms a coating strength of /mm^2 or less.
(3)インキ層の厚さが30μm以下であることを特徴
とする請求項(1)または(2)記載の表面保護接着フ
ィルムまたはシート。
(3) The surface protection adhesive film or sheet according to claim (1) or (2), wherein the ink layer has a thickness of 30 μm or less.
(4)インキが基材フィルムまたはシートと接着剤層と
の間に位置することを特徴とする請求項(1)または(
2)記載の表面保護接着フィルムまたはシート。
(4) Claim (1) or (4) characterized in that the ink is located between the base film or sheet and the adhesive layer.
2) The surface protection adhesive film or sheet described above.
JP4830589A 1989-02-27 1989-02-27 Surface-protective adhesive film or sheet Pending JPH02225578A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP4830589A JPH02225578A (en) 1989-02-27 1989-02-27 Surface-protective adhesive film or sheet

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4830589A JPH02225578A (en) 1989-02-27 1989-02-27 Surface-protective adhesive film or sheet

Publications (1)

Publication Number Publication Date
JPH02225578A true JPH02225578A (en) 1990-09-07

Family

ID=12799713

Family Applications (1)

Application Number Title Priority Date Filing Date
JP4830589A Pending JPH02225578A (en) 1989-02-27 1989-02-27 Surface-protective adhesive film or sheet

Country Status (1)

Country Link
JP (1) JPH02225578A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2781183A1 (en) * 1998-07-15 2000-01-21 Disa Thin dry transfer for marking aircraft, includes lacquer and ink layers of two-part polyurethane with adhesive based on acrylic polymer
EP1059345A1 (en) * 1999-06-09 2000-12-13 LINTEC Corporation Pressure-sensitive adhesive sheet which is peelable and having a display function

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2781183A1 (en) * 1998-07-15 2000-01-21 Disa Thin dry transfer for marking aircraft, includes lacquer and ink layers of two-part polyurethane with adhesive based on acrylic polymer
EP1059345A1 (en) * 1999-06-09 2000-12-13 LINTEC Corporation Pressure-sensitive adhesive sheet which is peelable and having a display function

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