JPH02225556A - Molding material for synthetic resin lacquer ware base - Google Patents
Molding material for synthetic resin lacquer ware baseInfo
- Publication number
- JPH02225556A JPH02225556A JP4809589A JP4809589A JPH02225556A JP H02225556 A JPH02225556 A JP H02225556A JP 4809589 A JP4809589 A JP 4809589A JP 4809589 A JP4809589 A JP 4809589A JP H02225556 A JPH02225556 A JP H02225556A
- Authority
- JP
- Japan
- Prior art keywords
- polyester resin
- molding material
- balloons
- specific gravity
- resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012778 molding material Substances 0.000 title claims abstract description 19
- 229920003002 synthetic resin Polymers 0.000 title claims abstract description 11
- 239000000057 synthetic resin Substances 0.000 title claims abstract description 11
- 239000004922 lacquer Substances 0.000 title abstract description 8
- 229920001225 polyester resin Polymers 0.000 claims abstract description 28
- 239000004645 polyester resin Substances 0.000 claims abstract description 28
- 230000005484 gravity Effects 0.000 claims abstract description 18
- 235000007164 Oryza sativa Nutrition 0.000 claims abstract description 9
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims abstract description 9
- 239000011521 glass Substances 0.000 claims abstract description 9
- 235000009566 rice Nutrition 0.000 claims abstract description 9
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 8
- 239000010903 husk Substances 0.000 claims description 7
- 239000006082 mold release agent Substances 0.000 claims description 4
- 240000007594 Oryza sativa Species 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 9
- 238000002156 mixing Methods 0.000 abstract description 9
- 238000000465 moulding Methods 0.000 abstract description 9
- 241000209094 Oryza Species 0.000 abstract description 8
- XOOUIPVCVHRTMJ-UHFFFAOYSA-L zinc stearate Chemical compound [Zn+2].CCCCCCCCCCCCCCCCCC([O-])=O.CCCCCCCCCCCCCCCCCC([O-])=O XOOUIPVCVHRTMJ-UHFFFAOYSA-L 0.000 abstract description 3
- LYDRKKWPKKEMNZ-UHFFFAOYSA-N tert-butyl benzoate Chemical compound CC(C)(C)OC(=O)C1=CC=CC=C1 LYDRKKWPKKEMNZ-UHFFFAOYSA-N 0.000 abstract 1
- 239000002023 wood Substances 0.000 description 14
- 229920005989 resin Polymers 0.000 description 11
- 239000011347 resin Substances 0.000 description 11
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 description 4
- 239000000945 filler Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 3
- 239000005011 phenolic resin Substances 0.000 description 3
- 229920001568 phenolic resin Polymers 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- 229910000019 calcium carbonate Inorganic materials 0.000 description 2
- 230000006378 damage Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 239000000395 magnesium oxide Substances 0.000 description 2
- CPLXHLVBOLITMK-UHFFFAOYSA-N magnesium oxide Inorganic materials [Mg]=O CPLXHLVBOLITMK-UHFFFAOYSA-N 0.000 description 2
- AXZKOIWUVFPNLO-UHFFFAOYSA-N magnesium;oxygen(2-) Chemical compound [O-2].[Mg+2] AXZKOIWUVFPNLO-UHFFFAOYSA-N 0.000 description 2
- 239000003973 paint Substances 0.000 description 2
- 238000010422 painting Methods 0.000 description 2
- 235000014347 soups Nutrition 0.000 description 2
- 241000692569 Stylephorus chordatus Species 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000006835 compression Effects 0.000 description 1
- 238000007906 compression Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- -1 etc. Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000011256 inorganic filler Substances 0.000 description 1
- 229910003475 inorganic filler Inorganic materials 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 239000012744 reinforcing agent Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 229920002994 synthetic fiber Polymers 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は合成樹脂製の盆その他の合成樹脂製漆器素地を
形成するための成形樹脂材料に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a molded resin material for forming synthetic resin trays and other synthetic resin lacquerware bases.
漆器素地としては、古くから木質材を切削したり９１貫
いたりしたものが使用され、これに漆を塗層して漆器を
製造している。The base material for lacquerware has been cut or 91-pierced wood from ancient times, and lacquerware is manufactured by coating this with a layer of lacquer.
このような天然木質材からなる漆器素地は、多量生産に
適せず、極めて高価なものになるために、近年、アミノ
系又はフェノール系の合成樹脂、或いはポリエステル樹
脂等の熱硬化性樹脂よりなる成形材料によって漆器素地
製品を製造することが行われるようになった。Lacquerware bases made of such natural wood materials are not suitable for mass production and are extremely expensive. Lacquerware base products began to be manufactured using molding materials.
しかしながら、例えばフェノール樹脂に充填材として木
粉を混入してなる材料を直圧成形することにより得られ
た漆器素地は、色彩的にも天然木質材とは異なるばかり
でなく、その比重が１．３以上もあって、天然木質材か
らなる漆器素地に比べ重量が大きく、取扱時において異
質感を与えることになる。However, for example, the lacquerware base obtained by direct pressure molding of a material made of phenolic resin mixed with wood flour as a filler not only differs in color from natural wood materials, but also has a specific gravity of 1. 3 or more, it is heavier than a lacquerware base made of natural wood, giving it a different feel when handled.
このため、ガラスバルーン等の中空のバルーンをフェノ
ール樹脂に混入してその比重を減少させることも考えら
れるが、アミノ系又はフェノール系の樹脂成形材料にお
いては、２００ ｋｇ／ｃ４前後の圧力で直圧成形され
るために、その圧力によって中空のバルーンが破壊され
て比重の軽減化を図ることが困難であり、その上、バル
ーンの破壊跡が成形品の表面に残存して塗料を必要とす
る漆器素地には使用できないものである。For this reason, it may be possible to reduce the specific gravity by mixing hollow balloons such as glass balloons into phenolic resin, but for amino-based or phenolic resin molding materials, direct pressure at a pressure of around 200 kg/c4 is considered. As the lacquerware is molded, the pressure destroys the hollow balloon, making it difficult to reduce the specific gravity.Furthermore, traces of the balloon's destruction remain on the surface of the molded product, requiring paint. It cannot be used on substrates.
このような中空バルーンの破壊は、１００ ｋｇ／ｃ４
以下の圧縮成形が可能なポリエステル樹脂を漆器素地の
成形材料として使用した場合にはなくすることができる
が、ポリエステル樹脂は抜型時に収縮して成形品にクラ
ックを頻繁に発生させる虞れがあり、このため、充填剤
、補強剤として炭酸カルシウムやガラス繊維を多量に添
加しておかねばならないが、このような材料を混入する
と、成形される漆器素地の比重の軽減を図ることが難し
く、その上、炭酸カルシウム等の無機質フィラーをポリ
エステル樹脂に添加してなる成形材料では、天然木質材
からなる漆器素地の木質感等の外観とは程遠くなり、感
触などの風合いにおいても著しく劣るものである。The destruction of such a hollow balloon is 100 kg/c4
This problem can be avoided if the following compression moldable polyester resin is used as the molding material for the lacquerware base, but polyester resin may shrink during mold removal and cause frequent cracks in the molded product. For this reason, it is necessary to add large amounts of calcium carbonate and glass fiber as fillers and reinforcing agents, but if such materials are mixed, it is difficult to reduce the specific gravity of the lacquerware base to be molded. A molding material made by adding an inorganic filler such as calcium carbonate to a polyester resin is far from the woody appearance of a lacquerware base made of natural wood, and is significantly inferior in feel and texture.
本発明はこのような問題点に鑑みてなされてもので、天
然木質材からなる漆器素地と酷似した比重や感触等の風
合いを呈し、且つ成形性、塗装性等の製造作業性に優れ
た合成樹脂製漆器素地の樹脂成形材料を提供するもので
ある。The present invention was made in view of these problems, and is a synthetic material that exhibits textures such as specific gravity and touch that are very similar to lacquerware bases made of natural wood materials, and has excellent manufacturing workability such as moldability and paintability. The present invention provides a resin molding material for resin lacquerware base.
上記目的を達成するために、本発明の合成樹脂製漆器素
地の成形材料は、ポリエステル樹脂１００重量部に対し
て水酸化アルミニウム又は／及び籾殻を３０〜１００重
量部添加すると共に比重０．２８〜０゜３９のガラスバ
ルーン又はシラスバルーンを１０〜７０重量部、適量の
硬化剤、離型剤等と共に添加混合してなるものである。In order to achieve the above object, the molding material for the synthetic resin lacquerware base of the present invention is prepared by adding 30 to 100 parts by weight of aluminum hydroxide or/and rice husks to 100 parts by weight of polyester resin, and having a specific gravity of 0.28 to 100 parts by weight. It is made by adding and mixing 10 to 70 parts by weight of 0.39 glass balloons or shirasu balloons together with appropriate amounts of hardening agents, mold release agents, etc.
成形材料の主成分であるポリエステル樹脂は、低圧によ
る直圧成形が可能であるから、このポリエステル樹脂に
添加しているガラスバルーン又はシラスバルーンの破壊
が防止され、成形された漆器素地の表面塗装が良好に行
えると共にこれらのバルーンの添加量によって天然木質
材よりなる漆器素地に近似した比重の樹脂製漆器素地を
得ることができる。Polyester resin, which is the main component of the molding material, can be molded under direct pressure at low pressure, which prevents the glass balloons or shirasu balloons added to this polyester resin from breaking, and makes it easier to paint the surface of the molded lacquerware base. This can be carried out satisfactorily, and depending on the amount of these balloons added, it is possible to obtain a resin lacquer ware base having a specific gravity similar to that of a lacquer ware base made of natural wood.
さらに、ポリエステル樹脂に充填剤として水酸化アルミ
ニウム又は籾殻の少なくともいずれか一方を３０〜１０
０重量部添加しているから、外観が天然の木質材と酷似
し、且つ上記比重の軽減化と相俟って感触等の風合いが
天然木質材よりなる漆器素地と同等な樹脂製漆器素地が
得られる。Furthermore, at least one of aluminum hydroxide or rice husk is added to the polyester resin as a filler at a concentration of 30 to 10%.
Because 0 parts by weight is added, the appearance is very similar to natural wood, and together with the above-mentioned reduction in specific gravity, the resin lacquerware base is made of resin that has the same texture as the lacquerware base made of natural wood. can get.
又、ポリエステル樹脂の一部に低収縮性ポリエステル樹
脂を使用して、これに少量の増粘剤、硬化剤を添加する
ことにより、成形後のクラックの発生をなくし得るもの
である。Furthermore, by using a low shrinkage polyester resin as a part of the polyester resin and adding a small amount of a thickener and a hardening agent thereto, it is possible to eliminate the occurrence of cracks after molding.
次に本発明の実施例を詳述する。Next, examples of the present invention will be described in detail.
樹脂製漆器素地成形用材料の主成分である合成樹脂とし
てポリエステル樹脂を使用し、このポリエステル樹脂１
００重量部に対して比重が２．４の水酸化アルミニウム
又は比重が１．２〜１．５の粉末状籾殻の少なくとも何
れか一方を３０〜１００重量部添加すると共にガラスバ
ルーン（比重： ０．２８〜０．３９）を１０〜７０重
量部添加し、さらに、少量の酸化マグネシウムとｔ−ブ
チル／ベンドエート、ジンクステアレートを添加混合し
て直圧用合成樹脂漆器成形材料を構成しているものであ
る。Polyester resin is used as the main component of the resin lacquerware base molding material, and this polyester resin 1
00 parts by weight of at least one of aluminum hydroxide having a specific gravity of 2.4 or powdered rice husk having a specific gravity of 1.2 to 1.5, and glass balloons (specific gravity: 0.00 parts by weight). A synthetic resin lacquerware molding material for direct pressure is made by adding 10 to 70 parts by weight of 28 to 0.39) and further adding and mixing a small amount of magnesium oxide, t-butyl/bendate, and zinc stearate. be.
このような成形材料において、上記ポリエステルと樹脂
しては全て一般用ポリエステル樹脂（日本触媒■製；商
品名工ボラックＮ−３４０にｏｒＮ−５４）を使用して
もよいが、成形後におけるクラックの発生を防止する目
的で、該一般用ポリエステル樹脂の一部に低収縮性ポリ
エステル樹脂（日本触媒■製：商品名工ボラックＡＴ−
１００）を、一般用ポリエステル樹脂７０〜９０重量部
に対して低収縮性ポリエステル樹脂１０〜３０重量部の
配合割合で使用することが望ましい。In such a molding material, a general polyester resin (manufactured by Nippon Shokubai ■; trade name: Borac N-340 or N-54) may be used as the polyester and resin, but cracks may occur after molding. In order to prevent this, low shrinkage polyester resin (manufactured by Nippon Shokubai ■, product: Meiko Borac AT-) was added to a part of the general polyester resin.
100) is preferably used in a blending ratio of 10 to 30 parts by weight of the low shrinkage polyester resin to 70 to 90 parts by weight of the general purpose polyester resin.
このような樹脂成形材料は、前記配合割合の一般用ポリ
エステル樹脂液と低収縮性ポリエステル樹脂液との混合
液に、前記水酸化アルミニウム又は粉末状籾殻、或いは
これらの物質を任意の割合で混合して添加し、さらに、
前記ガラスバルーンを加えてニーダにより混練しながら
増粘剤として少量の酸化マグネシウム、硬化剤としてｔ
−ブチル／ベンドエート、離型剤としてジンクステアレ
ートを少量宛添加して混練し、ブロック状に形成するこ
とにより得られるものである。Such a resin molding material is prepared by mixing the aluminum hydroxide, powdered rice husk, or these substances in any ratio into a mixture of a general-purpose polyester resin liquid and a low-shrinkage polyester resin liquid in the above-mentioned mixing ratio. and then add
While adding the glass balloon and kneading with a kneader, add a small amount of magnesium oxide as a thickener and t as a hardening agent.
-Butyl/bendoate and a small amount of zinc stearate as a mold release agent are added and kneaded to form a block.
上記合成樹脂漆器成形材料によって合成樹脂製漆器素地
、例えば直径が１１０ｍｍで、糸尻部２２ｍ■、底面中
央部１０ｍｍ、彎曲部１３ｍｍ、吸口部２ａｕｏの肉厚
を有する汁碗を成形するには、該成形材料を金型内に充
填したのち、金型温度１２０〜１４０″Ｃ、プレス圧力
５０−１００ ｋｇ ／ ｃＩａニ”’ｉ’ ２〜８
分間成形処理ヲ施せばよく、こうして得られた汁碗は、
割れやピンホールが発生していなく、低比重で淡色美麗
な天然木風合いを有するものであった。In order to mold a synthetic resin lacquerware base, for example, a soup bowl with a diameter of 110 mm, a thread tail part of 22 m, a bottom center part of 10 mm, a curved part of 13 mm, and a mouth part of 2 au, using the above synthetic resin lacquer molding material, After filling the mold with the molding material, the mold temperature is 120~140''C and the press pressure is 50~100 kg/cIa 2~8''.
The soup bowl obtained in this way can be formed by a molding process for a minute.
There were no cracks or pinholes, and it had a low specific gravity, light color, and beautiful natural wood texture.
次に、上記合成樹脂漆器成形材料の各組成分の割合を上
記範囲内において適宜に設定し、上記条件下で成形して
得られた成形品の実施例を表示する。Next, examples of molded products obtained by appropriately setting the proportions of each component of the synthetic resin lacquerware molding material within the above range and molding under the above conditions will be shown.
（以下空白）
なお゛、以上の実施例において、各組成分の数値は重量
部を表す。(Blank below) Note that in the above examples, the numerical values for each component represent parts by weight.
以上のように本発明の本発明の合成樹脂製漆器素地の成
形材料は、ポリエステル樹脂１００重量部に対して水酸
化アルミニウム又は／及び籾殻を３０〜１００重量部添
加すると共に比重０．２８〜０．３９のガラスバルーン
又はシラスバルーンを１０〜７０重量部、適量の硬化剤
、離型剤等と共に添加混合してなるものであるから、ポ
リエステル樹脂は低圧による直圧成形が可能であるので
、このポリエステル樹脂に添加しているガラスバルーン
又はシラスバルーンの成形時における破壊を防止するこ
とができ、従って、表面が滑らかな漆器素地を得ること
ができて爾後の表面塗装が良好に行え、成形性、仕上性
、塗装性等の製造作業性を向上させることができると共
にこれらのバルーンの添加量によって天然木質材よりな
る漆器素地に近似した比重の樹脂製漆器素地を得ること
ができるものである。As described above, the molding material for the synthetic resin lacquerware base of the present invention is prepared by adding 30 to 100 parts by weight of aluminum hydroxide or/and rice husk to 100 parts by weight of polyester resin, and having a specific gravity of 0.28 to 0. It is made by adding and mixing 10 to 70 parts by weight of .39 glass balloons or shirasu balloons with appropriate amounts of curing agent, mold release agent, etc., and polyester resin can be directly pressure molded at low pressure. It is possible to prevent glass balloons or shirasu balloons added to polyester resin from breaking during molding. Therefore, it is possible to obtain a lacquerware base with a smooth surface, which allows subsequent surface painting to be performed well, and improves moldability. Manufacturing workability such as finishing and painting properties can be improved, and depending on the amount of these balloons added, a resin lacquerware base with a specific gravity similar to that of a lacquerware base made of natural wood can be obtained.
さらに、ポリエステル樹脂に充填剤として水酸化アルミ
ニウム又は籾殻の少なくともいずれか一方を３０〜１０
０重量部添加しているから、外観が天然の木質材と酷似
し、且つ上記比重の軽減化と相俟って感触等の風合いが
天然木質材よりなる漆器素地と同等な樹脂製漆器素地を
得ることができるものであり、 又、ポリエステル樹脂
の一部に低収縮性ポリエステル樹脂を使用して、これに
少量の増粘剤、硬化剤を添加することにより、成形後の
クラックの発生をなくし得るものである。Furthermore, at least one of aluminum hydroxide or rice husk is added to the polyester resin as a filler at a concentration of 30 to 10%.
Because 0 parts by weight is added, the appearance is very similar to natural wood, and together with the above-mentioned reduction in specific gravity, it is possible to create a resin lacquerware base that has the same texture as the lacquerware base made of natural wood. In addition, by using low-shrinkage polyester resin as part of the polyester resin and adding a small amount of thickener and hardening agent to this, it is possible to eliminate the occurrence of cracks after molding. It's something you get.
Claims (1)
アルミニウム又は／及び籾殻を３０〜１００重量部添加
すると共に比重０．２８〜０．３９のガラスバルーン又
はシラスバルーンを１０〜７０重量部、少量の硬化剤、
離型剤等と共に添加混合してなることを特徴とする合成
樹脂製漆器素地の成形材料。(1) Add 30 to 100 parts by weight of aluminum hydroxide or/and rice husk to 100 parts by weight of polyester resin, and add a small amount of 10 to 70 parts by weight of glass balloons or shirasu balloons with a specific gravity of 0.28 to 0.39. curing agent,
A molding material for lacquerware made of synthetic resin, characterized by being mixed with a mold release agent, etc.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4809589A JPH02225556A (en) | 1989-02-27 | 1989-02-27 | Molding material for synthetic resin lacquer ware base |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4809589A JPH02225556A (en) | 1989-02-27 | 1989-02-27 | Molding material for synthetic resin lacquer ware base |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02225556A true JPH02225556A (en) | 1990-09-07 |
Family
ID=12793757
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP4809589A Pending JPH02225556A (en) | 1989-02-27 | 1989-02-27 | Molding material for synthetic resin lacquer ware base |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02225556A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS608355A (en) * | 1983-06-29 | 1985-01-17 | Toshiba Corp | Unsaturated polyester resin composition |
| JPS6241260A (en) * | 1985-08-15 | 1987-02-23 | Matsushita Electric Works Ltd | Resin composition |
-
1989
- 1989-02-27 JP JP4809589A patent/JPH02225556A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS608355A (en) * | 1983-06-29 | 1985-01-17 | Toshiba Corp | Unsaturated polyester resin composition |
| JPS6241260A (en) * | 1985-08-15 | 1987-02-23 | Matsushita Electric Works Ltd | Resin composition |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JPS5825097B2 (en) | Nenrin Moyouou Yuusuruhatsupoutai Seizouhou | |
| EP0335613A3 (en) | Composition and process for making porous articles from ultra high molecular weight polyethylene | |
| JPH02225556A (en) | Molding material for synthetic resin lacquer ware base | |
| JP2007197600A (en) | Thermoplastic resin composition and method for producing the same | |
| JPS61236858A (en) | Thermoplastic resin composition | |
| JPH04504402A (en) | Colored artificial granite and manufacturing method | |
| CN1022676C (en) | Method for making artistic articles of imitation ivory | |
| JPS58104947A (en) | Body of lacquered ware | |
| KR100378777B1 (en) | Manufacturing method for artificial wood including wood powder | |
| JP2000159556A (en) | Production of artificial marble | |
| US5393808A (en) | Composition of matter for wear surfaces and method for producing same | |
| JPH03111427A (en) | Manufacture of special-form material | |
| CN1236714C (en) | Natural plant pefume handicraft article | |
| JPS58142933A (en) | Phenolic resin molding material | |
| JPH04202344A (en) | Artificial ivory material and its production | |
| JPS63146957A (en) | Phenolic resin molding material | |
| US20060112646A1 (en) | Solid surface composites | |
| JPH0445935A (en) | Natural stonelike resin molded body | |
| JPH01135871A (en) | Composite molding material | |
| JPS5884847A (en) | Low-specific gravity phenolic resin molding compound | |
| JPH054204B2 (en) | ||
| JPH0446951A (en) | Phenol resin molding material | |
| JP2007313696A (en) | Resin molding and its manufacturing method | |
| JPH01204941A (en) | Polyvinyl chloride composition, mixing substance, reinforced band, reduction of shrinkage of pattern, improvement of properties | |
| JPH0248583B2 (en) |