JPH01135871A - Composite molding material - Google Patents
Composite molding materialInfo
- Publication number
- JPH01135871A JPH01135871A JP29200087A JP29200087A JPH01135871A JP H01135871 A JPH01135871 A JP H01135871A JP 29200087 A JP29200087 A JP 29200087A JP 29200087 A JP29200087 A JP 29200087A JP H01135871 A JPH01135871 A JP H01135871A
- Authority
- JP
- Japan
- Prior art keywords
- resin
- filler
- molding
- molding material
- composite molding
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012778 molding material Substances 0.000 title claims abstract description 30
- 239000002131 composite material Substances 0.000 title claims description 20
- 229920005989 resin Polymers 0.000 claims abstract description 55
- 239000011347 resin Substances 0.000 claims abstract description 55
- 239000000945 filler Substances 0.000 claims abstract description 43
- 238000000465 moulding Methods 0.000 claims abstract description 35
- 239000011342 resin composition Substances 0.000 claims abstract description 7
- 239000004793 Polystyrene Substances 0.000 claims abstract description 4
- 229920003051 synthetic elastomer Polymers 0.000 claims description 9
- 239000005061 synthetic rubber Substances 0.000 claims description 9
- 239000000463 material Substances 0.000 claims description 8
- -1 polyethylene Polymers 0.000 claims description 7
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 claims description 6
- 229920000515 polycarbonate Polymers 0.000 claims description 6
- 239000004417 polycarbonate Substances 0.000 claims description 6
- 239000004698 Polyethylene Substances 0.000 claims description 4
- 239000003822 epoxy resin Substances 0.000 claims description 4
- 229920000647 polyepoxide Polymers 0.000 claims description 4
- 244000043261 Hevea brasiliensis Species 0.000 claims description 3
- 229920000877 Melamine resin Polymers 0.000 claims description 3
- 239000004640 Melamine resin Substances 0.000 claims description 3
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 3
- 229930182556 Polyacetal Natural products 0.000 claims description 3
- 239000004952 Polyamide Substances 0.000 claims description 3
- 239000004642 Polyimide Substances 0.000 claims description 3
- 239000004743 Polypropylene Substances 0.000 claims description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 239000012461 cellulose resin Substances 0.000 claims description 3
- 229920002681 hypalon Polymers 0.000 claims description 3
- 239000000113 methacrylic resin Substances 0.000 claims description 3
- 229920003052 natural elastomer Polymers 0.000 claims description 3
- 229920001194 natural rubber Polymers 0.000 claims description 3
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 3
- 239000005011 phenolic resin Substances 0.000 claims description 3
- 229920002492 poly(sulfone) Polymers 0.000 claims description 3
- 229920002647 polyamide Polymers 0.000 claims description 3
- 229920001225 polyester resin Polymers 0.000 claims description 3
- 239000004645 polyester resin Substances 0.000 claims description 3
- 229920000573 polyethylene Polymers 0.000 claims description 3
- 229920001721 polyimide Polymers 0.000 claims description 3
- 229920006324 polyoxymethylene Polymers 0.000 claims description 3
- 229920001955 polyphenylene ether Polymers 0.000 claims description 3
- 229920001155 polypropylene Polymers 0.000 claims description 3
- 229920002223 polystyrene Polymers 0.000 claims description 3
- 239000005077 polysulfide Substances 0.000 claims description 3
- 229920001021 polysulfide Polymers 0.000 claims description 3
- 150000008117 polysulfides Polymers 0.000 claims description 3
- 229920005749 polyurethane resin Polymers 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000004800 polyvinyl chloride Substances 0.000 claims description 3
- 229920002050 silicone resin Polymers 0.000 claims description 3
- 229920006337 unsaturated polyester resin Polymers 0.000 claims description 3
- 239000008096 xylene Substances 0.000 claims description 3
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 2
- 239000000843 powder Substances 0.000 abstract description 15
- 239000000919 ceramic Substances 0.000 abstract description 11
- 238000005299 abrasion Methods 0.000 abstract description 4
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 abstract description 4
- 239000000805 composite resin Substances 0.000 abstract description 3
- 229920005990 polystyrene resin Polymers 0.000 abstract 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 5
- 238000000576 coating method Methods 0.000 description 5
- 239000000835 fiber Substances 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910010293 ceramic material Inorganic materials 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000010438 heat treatment Methods 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000010298 pulverizing process Methods 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- 229920006361 Polyflon Polymers 0.000 description 1
- 238000000071 blow moulding Methods 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 150000002739 metals Chemical class 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
［産業上の利用分野コ
本発明は、成形性及び摩耗性に優れた複合樹脂成形材料
に関する。特に１表面を樹脂で被膜した高硬度充填材を
少なくとも一部に使用した複合成形材料に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a composite resin molding material having excellent moldability and abrasion resistance. In particular, the present invention relates to a composite molding material that uses at least a part of a high-hardness filler whose surface is coated with a resin.
［従来の技術］
現在使用されている成形材料用に用いられる充填材は、
補強のための繊維や金属等がほとんどであるが、今後は
、セラミックス等の硬く安定性のある材料を使用するこ
とが増加すると思われるが、成形機の中で、これらの高
硬度材料は硬度が高いために、成形機及び金型の摩耗の
問題があリ、多量に高硬度充填材を使用し、生産するに
は適さないものである。また、従って、現在のセラミッ
クス充填材を用いて成形製品を生産しているものも高価
な物となっている。[Prior art] Fillers used for molding materials currently in use are:
Most of the materials are fibers and metals for reinforcement, but in the future it is expected that hard and stable materials such as ceramics will be used more frequently. Due to the high hardness, there is a problem of wear of the molding machine and mold, and a large amount of high hardness filler is used, making it unsuitable for production. Furthermore, current molded products made using ceramic fillers are also expensive.
従って、従来、セラミックス材料の粉末は、樹脂成形材
料用のフィラーとして使用されることは少なかった。こ
れは、成形機及び金型の摩耗が激しく、成形機の修理に
費用１時間がかかり、金型が直ぐに使用できなくなり、
実用的なセラミックス・フィラーが用いられていなかっ
た。一般に。Therefore, in the past, ceramic material powders have rarely been used as fillers for resin molding materials. This is due to severe wear on the molding machine and mold, and it takes an hour to repair the molding machine, making the mold unusable immediately.
Practical ceramic fillers were not used. in general.
セラミックス・フィラーを含む成形材料を成形するだめ
の成形機としては、射出成形法、押出成形機、ブロー成
形機などの各種成形機が利用できる。Various molding machines such as an injection molding machine, an extrusion molding machine, and a blow molding machine can be used as a molding machine for molding a molding material containing a ceramic filler.
［発明が解決しようとする問題点］
本発明は、従来の技術では得られなかった高硬度充填材
による成形機及び金型の摩耗問題を解決したすぐれた。[Problems to be Solved by the Invention] The present invention is excellent in solving the problem of wear of molding machines and molds due to high hardness fillers, which could not be achieved with conventional techniques.
実用性のある複合樹脂成形材料と提供することを目的に
する。即ち９本発明は、セラミックス材料のような硬度
の高い粉末を樹脂成形材料用のフィラーとして使用でき
るようにした複合成形材料を提供することを目的にする
。また９本発明は、成形機内部での摩耗及び金型の摩耗
を著しく減少した複合成形材料を提供することを目的に
する。更に２本発明は、セラミックスのような高硬度の
充填材でも使用可能となり、成形製品が耐摩耗性の高い
ものを容易に得ることのできる複合成形材料を提供する
ことを目的にする。The aim is to provide a practical composite resin molding material. That is, an object of the present invention is to provide a composite molding material in which a powder with high hardness such as a ceramic material can be used as a filler for a resin molding material. Another object of the present invention is to provide a composite molding material in which wear inside a molding machine and wear on a mold are significantly reduced. A further object of the present invention is to provide a composite molding material that can be used even with a high-hardness filler such as ceramics, and that allows molded products with high wear resistance to be easily obtained.
［発明の構成］
［問題点を解決するための手段］
本発明の複合成形材料は、上記の技術的な課題の解決の
ために１表面にあらかじめ樹脂被膜を施した高硬度の充
填材を一部又は全部の充填材として用いて、成形用樹脂
組成物と混合したことよりなる複合成形材料である。高
硬度充填材表面を被覆丈る樹脂は、 ｌｌｌ１ｔ記成形
用樹脂組成物よりも耐熱温度が高いものであることがよ
り好適である。更に、この充填材表面を被覆する樹脂は
、ポリスチレン、ＡＢＳ樹脂、メタクリル樹脂、酢酸ビ
ニル系樹脂、セルロース系樹脂、ポリカーボネート。[Structure of the Invention] [Means for Solving the Problems] In order to solve the above-mentioned technical problems, the composite molding material of the present invention is made by combining a high-hardness filler with a resin coating on one surface in advance. This is a composite molding material that is used partially or completely as a filler and mixed with a molding resin composition. It is more preferable that the resin that covers the surface of the high-hardness filler has a heat resistance temperature higher than that of the molding resin composition. Furthermore, the resin that covers the surface of the filler is polystyrene, ABS resin, methacrylic resin, vinyl acetate resin, cellulose resin, or polycarbonate.
ポリスルホン、シリコーン樹脂、天然ゴム誘導体、ブタ
ジェン系合成ゴム、オレフィン系−合成ゴム、クロロス
ルフォン化ポリエチレン、フェノール樹脂、エリア樹脂
、メラミン樹脂、キシレン樹脂、ポリエステル樹脂、エ
ポキシ樹脂、ポリウレタン樹脂、ポリイミド、ポリエチ
レン、ポリプロピレン、ポリ塩化ビニル、ＡＳｖ４脂、
ポリアミド、ポリアセタール、ポリカーボネート、ＰＥ
ＴｔＭＩＹｆＪ、ＰＢＴＩ６１脂、ポリフェニレンエー
テル。Polysulfone, silicone resin, natural rubber derivatives, butadiene-based synthetic rubber, olefin-based synthetic rubber, chlorosulfonated polyethylene, phenolic resin, area resin, melamine resin, xylene resin, polyester resin, epoxy resin, polyurethane resin, polyimide, polyethylene, Polypropylene, polyvinyl chloride, ASv4 resin,
Polyamide, polyacetal, polycarbonate, PE
TtMIYfJ, PBTI61 fat, polyphenylene ether.
フッ素樹脂、不飽和ポリエステル樹脂、多硫化系合成ゴ
ムからなる群から選択きれる少なくとも１種を利用でき
る。At least one selected from the group consisting of fluororesin, unsaturated polyester resin, and polysulfide synthetic rubber can be used.
本発明による複合成形材料は５次のようなものである。The composite molding material according to the present invention is of the following five types.
即ち、セラミックスのような高硬度の充填材の表面に事
前に樹脂被膜を施したものを充填材の一部又は全部とし
て用いて、成形用樹脂組成物とともに混合したものを複
合成形材料として用いて成形するものである。That is, the surface of a highly hard filler such as ceramics is coated with a resin in advance, and this is used as part or all of the filler, and the mixture is mixed with a molding resin composition and used as a composite molding material. It is something to be molded.
従来、セラミックス等の充填材Ｑ粉末はその性質上硬度
の６６いために、成形機の摩耗が著しいために、そのよ
うな材料は充填材として使用しないか、或いは使用して
も、金型及び成形機の消耗が激しく、多量生産が不可能
で、少量生産のものとなり、製品も高価なものしかでき
ない、そのために９本発明に従って、硬度の高い充填材
１例えば、セラミックス粉末を、成形のための充填材と
して用いるとき、成形前に、樹脂で被覆処理することに
より、成形機或いは金型の摩耗を防止することを見出し
たものである。Conventionally, filler material Q powder such as ceramics has a hardness of 66% due to its nature, so it causes significant wear on molding machines, so such materials are either not used as fillers, or even if they are used, they are difficult to use in molds and molding. Machines are subject to heavy wear and tear, making mass production impossible, requiring small quantity production, and only expensive products can be produced.9 For this reason, according to the present invention, a highly hard filler 1, for example, ceramic powder, is used for molding. It has been discovered that when used as a filler, abrasion of the molding machine or mold can be prevented by coating it with a resin before molding.
この充填材の表面を被覆するために使用する樹脂は、成
形用樹脂よりも耐熱温度が高いものが好適である。即ち
、高い硬度の充填材粉末或いは繊維に対して、適切な樹
脂を施し９表面に被膜を形成し、それを加熱処理し安定
化させた後に、成形用の樹脂と混合し、複合成形材料と
することが好適な場合がある。この加熱処理を好適に行
なうために、成形用樹脂よりも耐熱温度が高いものを使
用することが望ましい。The resin used to coat the surface of the filler preferably has a higher temperature limit than the molding resin. That is, a suitable resin is applied to the highly hard filler powder or fibers to form a film on the surface, which is stabilized by heat treatment, and then mixed with a resin for molding to form a composite molding material. It may be appropriate to do so. In order to suitably perform this heat treatment, it is desirable to use a resin that has a higher heat resistance than the molding resin.
この充填材の表面に施すための樹脂は、ポリスチレン、
ＡＢＳ樹脂、メタクリル樹脂、酢酸ビニル系樹脂、セル
ロース系樹脂、ポリカーボネート、ポリスルホン、シリ
コーン樹脂、天然ゴム誘導体、ブタジェン系合成ゴム、
オレフィン系合成ゴム、クロロスルフォン化ポリエチレ
ン、フェノール樹脂、エリア樹脂、メラミン樹脂、キシ
レン樹脂、ポリエステル樹脂、エポキシ樹脂、ポリウレ
タン樹脂、ポリイミド、ＡＢＳ樹脂、ポリエチレン、ポ
リプロピレン、ポリ塩化ビニル、ＡＳＰ！４脂、ポリア
ミド、ポリアセタール、ポリカーボネート、ＰＥＴｍ脂
、ＰＢＴ樹脂、ポリフェニレンエーテル、フッ素樹脂、
不飽和ポリエステル樹脂、多硫化系合成ゴムからなる群
から適宜に選択され、その少なくとも１種を使用できる
。また。The resin to be applied to the surface of this filler is polystyrene,
ABS resin, methacrylic resin, vinyl acetate resin, cellulose resin, polycarbonate, polysulfone, silicone resin, natural rubber derivatives, butadiene synthetic rubber,
Olefin synthetic rubber, chlorosulfonated polyethylene, phenol resin, area resin, melamine resin, xylene resin, polyester resin, epoxy resin, polyurethane resin, polyimide, ABS resin, polyethylene, polypropylene, polyvinyl chloride, ASP! 4 resins, polyamide, polyacetal, polycarbonate, PET resin, PBT resin, polyphenylene ether, fluororesin,
It is appropriately selected from the group consisting of unsaturated polyester resins and polysulfide synthetic rubbers, and at least one thereof can be used. Also.
これらの樹脂を充填材に被覆するために用いるときには
、所望により、硬化剤、カップリング剤。When these resins are used to coat fillers, a curing agent and a coupling agent may be added, if desired.
硬化促進剤などを使用することができる。A curing accelerator and the like can be used.
また、成形用樹脂には、上記に挙げた樹脂から選択して
、或いは組み合わせて使用することができる。更に、成
形用樹脂は、［−記以外の樹脂も使用できる。Moreover, the resin for molding can be selected from the resins listed above, or can be used in combination. Furthermore, resins other than [-] can also be used as the molding resin.
具体的には、硬度の高い充填材粉末又は繊維の表面を、
上記のような被覆樹脂により被膜を作製し、加熱処理し
、安定化した後、再度樹脂と混合した後に、成形するこ
とが好適である。Specifically, the surface of the filler powder or fiber with high hardness,
It is preferable to prepare a film using the above-mentioned coating resin, heat-treat it, stabilize it, mix it with the resin again, and then mold it.
硬度の高い充填材の表面に被覆するための樹脂と、成形
のための樹脂は、同一のＭ４ＭＢでもよく。The resin for coating the surface of the hard filler and the resin for molding may be the same M4MB.
また、成形のための樹脂よりも高い耐熱温度を有する樹
脂を、被覆のための樹脂として用いることが、好適であ
る。Further, it is preferable to use a resin having a higher heat resistance temperature than the resin for molding as the resin for coating.
また、被ｍ樹脂と成形用樹脂との組合わせは。Also, what is the combination of the resin to be treated and the resin for molding?
樹脂同志の相性のよいものを１選択し、得られる成形体
が高い強度になり、充填材との整合性の良好なものが得
られるようにする。Select one resin that has good compatibility with other resins so that the resulting molded product has high strength and good compatibility with the filler.
本発明の複合成形材料により得られるものは。What can be obtained with the composite molding material of the present invention?
セラミンクス充填材、金属粉末充填材のような硬度の高
い充填材を中に入れた複合成形体であり９本発明により
、セラミックスのような高い硬度の材料を充填材にして
、耐摩耗性の高い材料が得られる。It is a composite molded body containing a highly hard filler such as a ceramic filler or a metal powder filler. Materials are obtained.
次に本発明の複合成形材料を具体的に実施例により説明
するが９本発明はそれらによって限定されるものではな
い。Next, the composite molding material of the present invention will be specifically explained with reference to Examples, but the present invention is not limited thereto.
［実施例１］
国産研摩材料株式会社製の電融アルミナを粉砕した粉末
（平均粒径３０μ）に、フッ素樹脂（ポリフロン［ダイ
キン工業株式会社製）を適用し。[Example 1] Fluororesin (Polyflon [manufactured by Daikin Industries, Ltd.]) was applied to powder (average particle size 30 μm) obtained by pulverizing fused alumina manufactured by Kokusan Abrasive Materials Co., Ltd.
フッ素樹脂コートのあるアルミナ粉末を作製する。Fabricate alumina powder coated with fluororesin.
次に、−上記の電融アルミナ粉末３０％と、上記で作製
したフッ素樹脂コートアルミナ粉末７０％の混合アルミ
ナ粉末（平均粒径２０μ）７０ｇを混入したエポキシ樹
脂（大日本インキ化学工業株式会社製エピクロンＮＮ−
６６５ＸＰ）２０と硬化剤として住友ベークライト株式
会社製フェノールノボラックを１０ｇと硬化促進剤とし
て住友化学工業株式会社製スミキュアＤ０．２ｇとの混
合成形材料をトランスファ成形した。その結果について
、充填材としてアルミナ惧独で成形した場合と比較した
。Next, - an epoxy resin (manufactured by Dainippon Ink & Chemicals Co., Ltd.) mixed with 70 g of mixed alumina powder (average particle size 20 μ) consisting of 30% of the above fused alumina powder and 70% of the fluororesin-coated alumina powder prepared above. Epicron NN-
A mixed molding material of 665 The results were compared with the case where alumina was used as a filler.
第」二人
被覆なし成形材料 １０００シヨツト［実施例２］
実施例１の電融アルミナの代わりに、褐色溶融アルミナ
ＡＢＲＡＸを粉砕した粉末（平均粒径２０μ）を使用し
、同じ割合、成形用樹脂、硬化剤、硬化促進剤を用いて
、成形体を作製した。実施例１と同じく、成形機内の摩
耗が少ないものであった。1000 shots of second-person uncoated molding material [Example 2] Instead of the fused alumina of Example 1, a powder obtained by pulverizing brown fused alumina ABRAX (average particle size 20μ) was used, and the same proportions and molding resin were used. A molded body was produced using a curing agent, a curing accelerator, and a curing accelerator. As in Example 1, there was little wear inside the molding machine.
これにより、フッ素樹脂コートアルミナを少なくとも一
部用いた成形材料は、アルミナ単独による成形よりも、
成形金型の摩耗が少ないことが分かった。As a result, molding materials that use at least a portion of fluororesin-coated alumina are more effective than molding materials that use alumina alone.
It was found that there was less wear on the molding die.
［発明の効果］
本発明の複合成形材料は９以上のように、従来の成形機
内部で成形材料として使用しても、金型（成形機）の摩
耗が大幅に減少するものである。[Effects of the Invention] As shown in 9 and above, even when the composite molding material of the present invention is used as a molding material inside a conventional molding machine, the wear of the mold (molding machine) is significantly reduced.
このために、従来使用できなかった充填材も使用できる
ようになり９種々の充填材を用いることができるように
なり、複合成形材料の種類の増加に寄ひできる。また、
成形に用いる樹脂の相性の良好な組合わせを選択するこ
とにより複合成形体の強度を向上できるものである。For this reason, fillers that could not be used in the past can now be used, and a variety of fillers can now be used, contributing to an increase in the variety of composite molding materials. Also,
By selecting a combination of resins used for molding with good compatibility, the strength of the composite molded product can be improved.
また、セラミックスのような硬度の高い充填材でも複合
成形材料として使用できるようになり。In addition, even hard fillers such as ceramics can now be used as composite molding materials.
それによって得られる成形体は、耐摩耗材料として使用
できる材料を提供できることも可能となった。The molded body obtained thereby also makes it possible to provide a material that can be used as a wear-resistant material.
特許出願人 住友セメント株式会社Patent applicant: Sumitomo Cement Co., Ltd.
Claims (3)
材を一部又は全部の充填材として用いて、成形用樹脂組
成物と混合したことよりなる複合成形材料。(1) A composite molding material made by using a high hardness filler whose surface has been previously coated with a resin as part or all of the filler and mixing it with a resin composition for molding.
形用樹脂組成物よりも耐熱温度が高いものであることを
特徴とする特許請求の範囲第１項の記載の複合成形材料
。(2) The composite molding material according to claim 1, wherein the resin covering the surface of the high-hardness filler has a higher heat resistance than the molding resin composition.
ＢＳ樹脂、メタクリル樹脂、酢酸ビニル系樹脂、セルロ
ース系樹脂、ポリカーボネート、ポリスルホン、シリコ
ーン樹脂、天然ゴム誘導体、ブタジエン系合成ゴム、オ
レフィン系合成ゴム、クロロスルフォン化ポリエチレン
、フェノール樹脂、エリア樹脂、メラミン樹脂、キシレ
ン樹脂、ポリエステル樹脂、エポキシ樹脂、ポリウレタ
ン樹脂、ポリイミド、ポリエチレン、ポリプロピレン、
ポリ塩化ビニル、ＡＳ樹脂、ポリアミド、ポリアセター
ル、ポリカーボネート、ＰＥＴ樹脂、ＰＢＴ樹脂、ポリ
フェニレンエーテル、フッ素樹脂、不飽和ポリエステル
樹脂、多硫化系合成ゴムからなる群から選択される少な
くとも１種である特許請求の範囲第１項の記載の複合成
形材料。(3) The resin applied to the surface of the filler is polystyrene, A
BS resin, methacrylic resin, vinyl acetate resin, cellulose resin, polycarbonate, polysulfone, silicone resin, natural rubber derivative, butadiene synthetic rubber, olefin synthetic rubber, chlorosulfonated polyethylene, phenol resin, area resin, melamine resin, xylene resin, polyester resin, epoxy resin, polyurethane resin, polyimide, polyethylene, polypropylene,
The claimed material is at least one selected from the group consisting of polyvinyl chloride, AS resin, polyamide, polyacetal, polycarbonate, PET resin, PBT resin, polyphenylene ether, fluororesin, unsaturated polyester resin, and polysulfide synthetic rubber. Composite molding material as described in scope 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29200087A JPH01135871A (en) | 1987-11-20 | 1987-11-20 | Composite molding material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP29200087A JPH01135871A (en) | 1987-11-20 | 1987-11-20 | Composite molding material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH01135871A true JPH01135871A (en) | 1989-05-29 |
Family
ID=17776228
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP29200087A Pending JPH01135871A (en) | 1987-11-20 | 1987-11-20 | Composite molding material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01135871A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2661681A1 (en) * | 1990-05-07 | 1991-11-08 | Rogers Corp | FILLING COATED PARTICLES AND PROCESS FOR PREPARING THE SAME. |
| GB2244274A (en) * | 1990-05-08 | 1991-11-27 | Rogers Corp | Thermoplastic composite material |
| JPH0692706A (en) * | 1992-01-10 | 1994-04-05 | Tarkett Ab | Plastic tile composition |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52111946A (en) * | 1976-03-17 | 1977-09-20 | Fujitsu Ltd | Minute elastic ball and its production |
| JPS59149935A (en) * | 1982-11-24 | 1984-08-28 | ウエスタ−ン・エレクトリツク・カムパニ−，インコ−ポレ−テツド | Improved filler-polymer composite body |
| JPS61258829A (en) * | 1985-03-29 | 1986-11-17 | ソシエテ アトケム | Polyamide coated particle and its production |
-
1987
- 1987-11-20 JP JP29200087A patent/JPH01135871A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS52111946A (en) * | 1976-03-17 | 1977-09-20 | Fujitsu Ltd | Minute elastic ball and its production |
| JPS59149935A (en) * | 1982-11-24 | 1984-08-28 | ウエスタ−ン・エレクトリツク・カムパニ−，インコ−ポレ−テツド | Improved filler-polymer composite body |
| JPS61258829A (en) * | 1985-03-29 | 1986-11-17 | ソシエテ アトケム | Polyamide coated particle and its production |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2661681A1 (en) * | 1990-05-07 | 1991-11-08 | Rogers Corp | FILLING COATED PARTICLES AND PROCESS FOR PREPARING THE SAME. |
| GB2244274A (en) * | 1990-05-08 | 1991-11-27 | Rogers Corp | Thermoplastic composite material |
| GB2244274B (en) * | 1990-05-08 | 1993-10-06 | Rogers Corp | Thermoplastic composite material |
| JPH0692706A (en) * | 1992-01-10 | 1994-04-05 | Tarkett Ab | Plastic tile composition |
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