JPH02211425A - Liquid crystal oriented film and formation thereof - Google Patents

Liquid crystal oriented film and formation thereof

Info

Publication number
JPH02211425A
JPH02211425A JP1033112A JP3311289A JPH02211425A JP H02211425 A JPH02211425 A JP H02211425A JP 1033112 A JP1033112 A JP 1033112A JP 3311289 A JP3311289 A JP 3311289A JP H02211425 A JPH02211425 A JP H02211425A
Authority
JP
Japan
Prior art keywords
resin
substrate
liquid crystal
alignment film
photosensitive resin
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP1033112A
Other languages
Japanese (ja)
Inventor
Nobuaki Hashimoto
伸晃 橋元
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Seiko Epson Corp
Original Assignee
Seiko Epson Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Seiko Epson Corp filed Critical Seiko Epson Corp
Priority to JP1033112A priority Critical patent/JPH02211425A/en
Publication of JPH02211425A publication Critical patent/JPH02211425A/en
Pending legal-status Critical Current

Links

Classifications

    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/13378Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation
    • G02F1/133788Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers by treatment of the surface, e.g. embossing, rubbing or light irradiation by light irradiation, e.g. linearly polarised light photo-polymerisation
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/01Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour 
    • G02F1/13Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour  based on liquid crystals, e.g. single liquid crystal display cells
    • G02F1/133Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
    • G02F1/1333Constructional arrangements; Manufacturing methods
    • G02F1/1337Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
    • G02F1/133765Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers without a surface treatment

Landscapes

  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Mathematical Physics (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • General Physics & Mathematics (AREA)
  • Optics & Photonics (AREA)
  • Liquid Crystal (AREA)

Abstract

PURPOSE:To obtain the oriented film which does not generate static electricity and dust by applying a photosensitive resin on a substrate and forming straight stripe-shaped grooves on the resin by a photoprocess. CONSTITUTION:The photosensitive resin 10 is dropped onto the substrate 1 and the substrate is rotated to uniformly coat the substrate with the resin 10. The resin 10 is then irradiated with incident light 13 through the masking part 12 of a photomask 11, by which the resin 10 is exposed in the form of straight stripes. The resin is developed with a developing soln. 14 to form the oriented film 18 having the straight stripe-shaped grooves 17 on the substrate 1. The liquid crystal molecules are regularly oriented along these fine grooves 17. Since the resin is not rubbed by fabrics, the static electricity is not generated at all and the electrostatic destruction of electrodes and active elements is prevented. The generation of the dust by a mechanical rubbing operation is obviated and the degradation in the clean degree of a clean room is prevented.

Description

【発明の詳細な説明】 [産業上の利用分野1 本発明は、液晶表示体に関し、特にその配向膜に関する
DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application 1] The present invention relates to a liquid crystal display, and particularly to an alignment film thereof.

[従来の技術] 従来、配向膜の形成方法としては、第2図(a)〜(C
)に示されるような方法が知られていた。第2図(a)
においてlは基板であり、液晶表示体の場合、多くはガ
ラスである。2は、樹脂であり、ポリイミド、ポリアミ
ド等がよく使用される。一定量の樹脂2を基板l上に滴
下し、第2図(b)に示すように、基板lを回転し、樹
脂2を基板1上に一定の厚さに塗布する。樹脂2中に溶
剤が含まれている場合は、溶剤を揮発させるために、ま
た、ポリイミド系樹脂の場合は、イミドの脱水縮合反応
を行うために、150℃〜250℃に基板lを1〜2時
間加熱する。その後、第2図(C)に示されるように、
4の回転ローラーに巻きつけられた布3を回転させ、基
板l上の樹脂2に押しあてながら、基tel上を回転方
向と平行な方向へ移動させる。すると、樹脂2上には微
細な溝が同一方向に多数形成される。このようにして形
成された基板上の配向膜は、もう1枚の基板上の配向膜
面II+と組み合わされ、液晶が注入される。すると、
液晶分子は、配向膜上に形成されている微細な溝にそっ
て配列し、規則的な配向を得ることができる。このよう
にして、液晶表示体の配向を得る方法が以前より知られ
ていた。もちろん、配向膜と基板の間には、液晶駆動用
の電極、必要に応じて能動素子が形成されており、それ
らによって液晶表示体は駆動されていた。
[Prior Art] Conventionally, as a method for forming an alignment film, the methods shown in FIGS. 2(a) to (C
) was known. Figure 2(a)
In the above, l is a substrate, and in the case of a liquid crystal display, it is often glass. 2 is a resin, and polyimide, polyamide, etc. are often used. A predetermined amount of resin 2 is dropped onto the substrate 1, and as shown in FIG. 2(b), the substrate 1 is rotated to apply the resin 2 onto the substrate 1 to a predetermined thickness. If the resin 2 contains a solvent, in order to volatilize the solvent, and in the case of polyimide resin, to perform the dehydration condensation reaction of imide, the substrate 1 is heated to 150 to 250 °C. Heat for 2 hours. After that, as shown in FIG. 2(C),
The cloth 3 wound around the rotating roller 4 is rotated, and while being pressed against the resin 2 on the substrate 1, it is moved on the base tel in a direction parallel to the rotation direction. Then, a large number of fine grooves are formed on the resin 2 in the same direction. The alignment film thus formed on the substrate is combined with the alignment film surface II+ on another substrate, and liquid crystal is injected. Then,
Liquid crystal molecules are aligned along the fine grooves formed on the alignment film, and regular alignment can be obtained. Methods of obtaining orientation in liquid crystal displays in this way have been known for some time. Of course, electrodes for driving the liquid crystal and active elements are formed as necessary between the alignment film and the substrate, and the liquid crystal display is driven by these.

[発明が解決しようとする課題] しかし、従来の液晶配向膜の形成方法では、樹脂を布で
こすることになるため、静電気が発生するという問題点
を有していた。すなわち、発生した静電気は、基板上に
形成されている電極、能動素子を破壊し、液晶表示体を
駆動することができなくなるという大きな問題点を有し
ていた。
[Problems to be Solved by the Invention] However, in the conventional method for forming a liquid crystal alignment film, since the resin is rubbed with a cloth, there is a problem in that static electricity is generated. That is, the generated static electricity destroys the electrodes and active elements formed on the substrate, resulting in a major problem in that the liquid crystal display cannot be driven.

また、布でこすられた樹脂からは、こすり滓が発生し、
それは、液晶表示体が製造されるクリーンルーム内での
大きな発塵源となり、他の製造工程の歩留まりを低下さ
せる大きな要因となるという大きな問題点をも有してい
た。
In addition, rubbing slag is generated from the resin rubbed with cloth,
This also poses a major problem in that it becomes a major source of dust in the clean room where the liquid crystal display is manufactured, and becomes a major factor in reducing the yield of other manufacturing processes.

このような問題点を解決するため、本発明では、静電気
が発生せず、また発塵もしない液晶配向膜の形成方法を
提供することを目的とする。
In order to solve these problems, it is an object of the present invention to provide a method for forming a liquid crystal alignment film that does not generate static electricity or generate dust.

(課題を解決するための手段) 上記問題点を解決するため、本発明の液晶配向膜の形成
方法では、基板と、前記基板上に載置された感光性を有
する樹脂が、一方向の直線縞上に露光された後、現像さ
れ、一方向の直線縞状の凹凸面に形成されていることを
特徴とする。また、本発明の液晶配向膜は、前記液晶配
向膜の形成方法によって形成されていることを特徴とす
る。
(Means for Solving the Problems) In order to solve the above problems, in the method for forming a liquid crystal alignment film of the present invention, a substrate and a photosensitive resin placed on the substrate are arranged in a straight line in one direction. It is characterized in that it is exposed on stripes and then developed to form an uneven surface in the form of linear stripes in one direction. Moreover, the liquid crystal alignment film of the present invention is characterized in that it is formed by the method for forming a liquid crystal alignment film.

〔作 用1 本発明では、基板上に感光性を有する樹脂を載置し、そ
の樹脂に一方向の直線縞状の露光を行い、現像し、基板
上の樹脂に一方向の直線縞状の凹凸面を形成することが
できるので、基板上の樹脂をこすらなくとも、配向膜の
目的とする微細な多数の同一方向溝を形成するこ゛とが
できる。液晶分子は、この溝にそって良好に配向する。
[Function 1] In the present invention, a photosensitive resin is placed on a substrate, the resin is exposed to light in the form of linear stripes in one direction, and developed, and the resin on the substrate is exposed in the form of linear stripes in one direction. Since an uneven surface can be formed, a large number of fine grooves in the same direction, which are the purpose of an alignment film, can be formed without rubbing the resin on the substrate. Liquid crystal molecules are well aligned along these grooves.

[実 施 例J 以下に、本発明の一実施例を図面に基づき、詳細に説明
する。
[Embodiment J] An embodiment of the present invention will be described in detail below based on the drawings.

第1図(a)〜(e)は、本実施例の液晶配向膜の形成
方法を示す模式図である。第1図(a)で1は、基板で
あり、−船釣に液晶表示体では、ガラス、プラスチック
、有機フィルム等が利用されている6図中には省略しで
あるが、基板上には液晶駆動用の電極、必要に応じて能
動素子等がすでに形成しである。10は感光性樹脂であ
り、船釣には、ポリアミド、ポリイミド等の樹脂が多い
が、感光性を有する樹脂であれば何でも良い。
FIGS. 1(a) to 1(e) are schematic diagrams showing a method of forming a liquid crystal alignment film of this example. In Fig. 1(a), 1 is a substrate, and glass, plastic, organic film, etc. are used in liquid crystal displays for boat fishing.Although not shown in Fig. 6, there are Electrodes for driving the liquid crystal, active elements, etc. as required have already been formed. 10 is a photosensitive resin, and for boat fishing, resins such as polyamide and polyimide are often used, but any photosensitive resin may be used.

以下本実施例においては、感光性樹脂は、ポリイミド系
樹脂、例えば宇部興産(株)製の商品名PI−400を
用いた場合について述べる。NMP等の溶媒で適当に希
釈した後、基板1上に感光性樹脂IOを滴下する0次に
第1図(b)に示すように基板1を回転し、感光性樹脂
IOを基板1上に均一になるように塗布する。感光性樹
脂10の膜厚は500〜1000人であることが多い。
In this example, a case will be described in which a polyimide resin such as PI-400 manufactured by Ube Industries, Ltd. is used as the photosensitive resin. After appropriately diluting with a solvent such as NMP, drop the photosensitive resin IO onto the substrate 1. Next, rotate the substrate 1 as shown in FIG. Apply evenly. The film thickness of the photosensitive resin 10 is often 500 to 1000.

次に第1図(C)に示すように、感光性樹脂10に入射
光13をフォトマスク11を通して照射する67オトマ
スク11にはマスキング部12が直線縞状に形成されて
おり、感光性樹脂10に、直線縞状に明暗部が露光され
るようになっている。
Next, as shown in FIG. 1(C), the photosensitive resin 10 is irradiated with the incident light 13 through the photomask 11.The masking portion 12 is formed in a straight stripe shape on the 67 otomask 11, and the photosensitive resin 10 is irradiated with the incident light 13 through the photomask 11. The bright and dark areas are exposed in linear stripes.

フォトマスク11は、図のように基板lの周囲の部分を
覆うようにマスキング部12が形成されていても良い。
The photomask 11 may have a masking portion 12 formed so as to cover the peripheral portion of the substrate l as shown in the figure.

この点については後に詳述する0次に第1図(d)に示
すように、基板lを現像液14中につける。現像液14
中で、感光性樹脂の非感光部16は感光しておらず樹脂
の3次元硬化が進んでいないので溶解する。しかし、感
光性樹脂の感光部15は樹脂が3次元硬化するため、現
像液14へは溶解しない。現(’21液14はNMP系
の溶媒が使用されることが多い。このようにして、第1
図(e)に示されるような、基板1上に直線綿状の満1
7を持った配向lla 18が形成される。最後に、基
Ifit1を230℃30分程加熱し、感光性樹脂中に
含まれる溶媒を除去し、完全なポリイミド樹脂とする。
Regarding this point, the substrate 1 is immersed in the developer 14 as shown in FIG. developer 14
Among them, the non-exposed part 16 of the photosensitive resin is not exposed to light and three-dimensional curing of the resin has not progressed, so it is dissolved. However, the photosensitive portion 15 made of photosensitive resin is not dissolved in the developer 14 because the resin is three-dimensionally cured. At present ('21 liquid 14, NMP-based solvent is often used. In this way, the first
As shown in FIG.
An orientation lla 18 with 7 is formed. Finally, the base Ifit1 is heated at 230° C. for about 30 minutes to remove the solvent contained in the photosensitive resin and form a complete polyimide resin.

配向膜中の溝は、なるべく間隔が狭(なるようにフォト
マスク11を設計した方が、後述する液晶の配向性は向
上する。また、現像時に、非感光部の感光性樹脂が完全
に溶解する前に、ハーフエツチングの状態で現像から取
り出して用いても良い。
If the photomask 11 is designed so that the grooves in the alignment film are as narrow as possible, the alignment of the liquid crystal, which will be described later, will be improved.Also, during development, the photosensitive resin in the non-exposed areas will be completely dissolved. Before etching, the film may be taken out from development in a half-etched state and used.

第3図は、TNモードの液晶表示体に本発明の液晶配向
膜を用いた例を説明する斜視図である。
FIG. 3 is a perspective view illustrating an example in which the liquid crystal alignment film of the present invention is used in a TN mode liquid crystal display.

第3図において、前述の方法で基板l上に直線縞状に形
成された配向膜18の直線方向が90°ずれるように、
もう−枚の配向膜18付の基板1を設置する。すると、
縦長棒状分子であるTN液晶分子19は、分子自身のポ
テンシャルが最少になるように、配向II! 18上の
溝17にそって並ぼうとする1両基板は、90°ずらし
て設置しであるので液晶分子も90°ねじれてうまく配
向するのである。これで、TNモードの液晶表示体とな
るのである。この液晶表示体の駆動は、公知のように基
板l上に予め形成しである電極、能動素子等で行われる
。また、第3図に示すように基板1の周囲の部分の配向
膜を、前述した現像工程で無くしてしまえば、シール材
20で、2枚の基板を接着しようとした場合、従来配向
膜が付いていた基板上ではなく、シール材20は基板1
の上に直接接着させることができるようになる。
In FIG. 3, the linear direction of the alignment film 18 formed in the form of linear stripes on the substrate l by the method described above is shifted by 90°.
Another substrate 1 with an alignment film 18 is installed. Then,
The TN liquid crystal molecules 19, which are vertically long rod-shaped molecules, are aligned in II! orientation so that the potential of the molecules themselves is minimized. Since the two substrates that are to be lined up along the groove 17 on the substrate 18 are set apart from each other by 90 degrees, the liquid crystal molecules are also twisted by 90 degrees and are properly oriented. This makes it a TN mode liquid crystal display. The liquid crystal display is driven, as is well known, by electrodes, active elements, etc., which are previously formed on the substrate l. Furthermore, as shown in FIG. 3, if the alignment film around the substrate 1 is removed in the above-mentioned development process, when attempting to bond two substrates together using the sealant 20, the conventional alignment film The sealant 20 is not on the board it was attached to, but on the board 1.
It can be glued directly onto the.

【発明の効果1 以上、説明したように本発明による液晶配向膜及びその
形成方法では、基板上に載置される樹脂を感光性樹脂と
し、フォトプロセスで樹脂上に、液晶配向用の溝を形成
したので以下の効果を持つ。
Effects of the Invention 1 As explained above, in the liquid crystal alignment film and the method for forming the same according to the present invention, the resin placed on the substrate is a photosensitive resin, and grooves for liquid crystal alignment are formed on the resin by a photo process. Since it has been formed, it has the following effects.

(1)樹脂を布でこするというような、静電気を発生す
る工程を完全に無くすることができるので、静電気はま
ったく発生しない、このため、基板上に形成された電極
や、能動素子を静電破壊することが無くなり、静電破壊
による液晶表示体の歩留まり低下をおさえることができ
る。
(1) It is possible to completely eliminate processes that generate static electricity, such as rubbing the resin with a cloth, so no static electricity is generated. There is no possibility of electrical damage, and it is possible to suppress a decrease in the yield of liquid crystal displays due to electrostatic damage.

(2)機械的なこすり操作は行わないので、こすり滓の
ような埃は発生しないので、液晶表示装置を製造するク
リーンルーム内のクリーン度を低下させることがないた
め、他の製造工程の歩留まりを低下させることがない (3) 1(脂を基板上にスピンコードで付ける場合、
フォトパターニングの際、配向溝形成と同時に、基板の
周辺部も同時に樹脂を落とすことができる。こうすれば
、この基板同志を組み合わせて、液晶表示体を形成する
場合、これらをはり合わせるシール材の位置には樹脂を
なくすることができるため、基板のはり合わせ強度を大
きく上昇することができ、またシール材上の樹脂からの
水蒸気の透過を無くすることができるので、液晶表示体
の耐湿性を上昇させることができる。
(2) Since there is no mechanical scrubbing operation, no dust such as scrubbing slag is generated, so the cleanliness in the clean room where LCDs are manufactured will not be reduced, and the yield rate of other manufacturing processes will be reduced. (3) 1 (When attaching fat to the substrate with a spin cord,
During photopatterning, resin can be removed from the peripheral portion of the substrate at the same time as alignment grooves are formed. In this way, when combining these substrates to form a liquid crystal display, it is possible to eliminate the resin at the position of the sealant where these are bonded together, and the strength of bonding the substrates can be greatly increased. Moreover, since the permeation of water vapor from the resin on the sealing material can be eliminated, the moisture resistance of the liquid crystal display can be improved.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図(a)〜(−)は、本発明による液晶配向膜の形
成方法を示す工程図であり、第2図(a)〜(c)は従
来の液晶配向膜の形成方法を示す工程図である。第3図
は本発明による液晶配向膜を用いた液晶表示体の構造を
示す斜視図である。 l・・・基板 2・・・樹脂 3・・・布 4 ・ 10 ・ l 1 ・ l 2 ・ 13 ・ l 4 ・ 15 ・ 16 ・ 17 ・ l 8 ・ l 9 ・ 20 ・ ・回転ローラー ・感光性樹脂 ・フォトマスク ・マスキング部 ・入射光 ・現像液 感光部 ・非感光部 ・溝 ・配向膜 ・液晶分子 ・シール材 以上 出願人 セイコーエプソン株式会社 代理人 弁理士 鈴 木 喜三部(他1名)(Q−) (b) 第2図 第 図 te)
FIGS. 1(a) to (-) are process diagrams showing a method for forming a liquid crystal alignment film according to the present invention, and FIGS. 2(a) to (c) are process diagrams showing a conventional method for forming a liquid crystal alignment film. It is a diagram. FIG. 3 is a perspective view showing the structure of a liquid crystal display using a liquid crystal alignment film according to the present invention. l... Substrate 2... Resin 3... Cloth 4 ・ 10 ・ l 1 ・ l 2 ・ 13 ・ l 4 ・ 15 ・ 16 ・ 17 ・ l 8 ・ l 9 ・ 20 ・ ・Rotating roller・photosensitive Resin, photomask, masking area, incident light, developer exposed area, non-exposed area, groove, alignment film, liquid crystal molecule, sealing material Applicant: Seiko Epson Co., Ltd. Agent Patent attorney Kizobe Suzuki (1 other person) ) (Q-) (b) Figure 2 Figure te)

Claims (2)

【特許請求の範囲】[Claims] (1)感光性を有する樹脂が一方向にそろった直線縞状
で基板上に形成されたことを特徴とする液晶配向膜。
(1) A liquid crystal alignment film characterized in that a photosensitive resin is formed in linear stripes aligned in one direction on a substrate.
(2)基板上に感光性を有する樹脂を塗布する工程と、
該樹脂を一方向の直線縞状に露光する工程と、該樹脂を
現像する工程とを有することを特徴とする液晶配向膜の
形成方法。
(2) a step of applying a photosensitive resin onto the substrate;
A method for forming a liquid crystal alignment film, comprising the steps of exposing the resin in a linear stripe pattern in one direction and developing the resin.
JP1033112A 1989-02-13 1989-02-13 Liquid crystal oriented film and formation thereof Pending JPH02211425A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP1033112A JPH02211425A (en) 1989-02-13 1989-02-13 Liquid crystal oriented film and formation thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP1033112A JPH02211425A (en) 1989-02-13 1989-02-13 Liquid crystal oriented film and formation thereof

Publications (1)

Publication Number Publication Date
JPH02211425A true JPH02211425A (en) 1990-08-22

Family

ID=12377570

Family Applications (1)

Application Number Title Priority Date Filing Date
JP1033112A Pending JPH02211425A (en) 1989-02-13 1989-02-13 Liquid crystal oriented film and formation thereof

Country Status (1)

Country Link
JP (1) JPH02211425A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05232473A (en) * 1991-07-26 1993-09-10 F Hoffmann La Roche Ag Liquid crystal display cell

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH05232473A (en) * 1991-07-26 1993-09-10 F Hoffmann La Roche Ag Liquid crystal display cell
US5838407A (en) * 1991-07-26 1998-11-17 Rolic Ag Liquid crystal display cells

Similar Documents

Publication Publication Date Title
KR100258847B1 (en) Liquid crystal alignment film, method manufacturing the film, liquid crystal display using the film and method, and method of manufacturing the liquid crystal
US8514355B2 (en) Liquid crystal display device with column spacers and a sidewall and method for manufacturing the same
KR100296498B1 (en) Method of manufacturing monomolecular film having orientation property chemically adsorbed
JP2572915B2 (en) Liquid crystal display device and method of manufacturing the same
JPH08160433A (en) Liquid crystal display device and its production
US20060286699A1 (en) Fabricating method for flat panel display device
KR0172204B1 (en) Liquid crystal display device and method of manufacturing the same
KR20010062545A (en) Liquid crystal display device and method for manufacturing the same
JPH02211425A (en) Liquid crystal oriented film and formation thereof
JPS61173221A (en) Formation of liquid crystal display device
KR101107701B1 (en) Method of forming an alignment layer for liquid crystal display device and liquid crystal display device using the same
JPS581129A (en) Two-layer type and guest-host type liquid crystal display element and its manufacture
JPH10333150A (en) Liquid crystal display device and its manufacture
JP2001142083A (en) Method of producing display device and display device
JPS5978318A (en) Manufacture of color liquid-crystal display cell
JPH0784266A (en) Production of liquid crystal display element
US4816381A (en) Method for fabricating PLZT light valve device
JPH07140466A (en) Method for controlling pretilt angle and production of liquid crystal display device
KR100769192B1 (en) Method and Apparatus of forming an alignment layer for a liquid crystal display device, and Method of manufacturing a liquid crystal display device using the same
JP3033632B2 (en) Method for manufacturing color filter and liquid crystal display element
JP3026880B2 (en) Rubbing cloth for aligning liquid crystal molecules and method for manufacturing liquid crystal display element
JP3301960B2 (en) Liquid crystal alignment film, method for manufacturing liquid crystal alignment film, liquid crystal display device, and method for manufacturing liquid crystal display device
JPH07181496A (en) Apparatus for producing liquid crystal display device
JPH0756550B2 (en) Liquid crystal cell manufacturing method
JPH03288828A (en) Formation of spacer