JPH02200831A - Covering yarn for thermoforming - Google Patents
Covering yarn for thermoformingInfo
- Publication number
- JPH02200831A JPH02200831A JP1528589A JP1528589A JPH02200831A JP H02200831 A JPH02200831 A JP H02200831A JP 1528589 A JP1528589 A JP 1528589A JP 1528589 A JP1528589 A JP 1528589A JP H02200831 A JPH02200831 A JP H02200831A
- Authority
- JP
- Japan
- Prior art keywords
- fibers
- yarn
- softening temperature
- covering
- covering yarn
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 238000003856 thermoforming Methods 0.000 title claims description 14
- 239000000835 fiber Substances 0.000 claims abstract description 76
- 239000004744 fabric Substances 0.000 claims abstract description 34
- 229920002972 Acrylic fiber Polymers 0.000 claims description 23
- 229920000728 polyester Polymers 0.000 claims description 10
- 239000004952 Polyamide Substances 0.000 claims description 6
- 229920002647 polyamide Polymers 0.000 claims description 6
- 229920006312 vinyl chloride fiber Polymers 0.000 claims description 6
- 229920003071 Polyclar® Polymers 0.000 claims 1
- 229920000742 Cotton Polymers 0.000 description 12
- 238000000034 method Methods 0.000 description 4
- 239000002985 plastic film Substances 0.000 description 4
- 229920002994 synthetic fiber Polymers 0.000 description 4
- 239000012209 synthetic fiber Substances 0.000 description 4
- 210000002268 wool Anatomy 0.000 description 4
- 238000000465 moulding Methods 0.000 description 3
- 229920001169 thermoplastic Polymers 0.000 description 3
- 239000004416 thermosoftening plastic Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 235000012766 Cannabis sativa ssp. sativa var. sativa Nutrition 0.000 description 1
- 235000012765 Cannabis sativa ssp. sativa var. spontanea Nutrition 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 235000009120 camo Nutrition 0.000 description 1
- 235000005607 chanvre indien Nutrition 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000013461 design Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- 239000011487 hemp Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 239000005022 packaging material Substances 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 238000007666 vacuum forming Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Yarns And Mechanical Finishing Of Yarns Or Ropes (AREA)
Abstract
Description
【発明の詳細な説明】
[産業上の利用分野]
本発明はカバリングヤーンに関する。さらに詳しくは、
カバー糸に高い軟化温度ををする繊維を、芯糸に低い軟
化温度を有する繊維を使用するカバリングヤーンに関す
る。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to covering yarns. For more details,
The present invention relates to a covering yarn using fibers having a high softening temperature for the cover yarn and fibers having a low softening temperature for the core yarn.
[従来の技術・発明が解決しようとする課題]プラスチ
ックシートやフィルムを加圧または真空成型によって立
体造形物を成型するのとほぼ同様な手段(以下、熱成型
という)で熱可塑性繊維布帛に凹凸立体形状を付与する
ことができることが知られている。繊維布帛はプラスチ
ックシートやフィルムと異なり、高級な外観、触感を有
しているので、このような立体形状を有する布帛はケー
スの内張などの包装材や座席カバーなどのインテリア・
家具類など比較的高級な用途に用いられる。[Conventional technology/problems to be solved by the invention] Irregularities are formed on thermoplastic fiber fabric using a method similar to that used to mold plastic sheets or films into three-dimensional objects by pressurizing or vacuum forming (hereinafter referred to as thermoforming). It is known that it is possible to give a three-dimensional shape. Unlike plastic sheets and films, fiber fabrics have a high-class appearance and feel, so fabrics with such three-dimensional shapes can be used as packaging materials such as case linings, interior decorations such as seat covers, etc.
Used for relatively high-class applications such as furniture.
しかしながら、熱可塑性繊維布帛を熱成型すると、熱成
形時に目的とする形状への布帛の変形とともに布帛表面
の繊維が熱影響のため軟化変形し、布帛表面の外観が損
なわれることがあった。However, when a thermoplastic fiber fabric is thermoformed, the fabric is deformed into the desired shape during thermoforming, and the fibers on the fabric surface are softened and deformed due to the influence of heat, which may impair the appearance of the fabric surface.
特開昭54−93LH号公報に開示されているように、
パイルのような特定の繊維布帛においては軟化温度の高
いパイル糸と軟化温度の低い地糸を組合わせることによ
り、布帛の外観を損なうことなしに熱成形が可能なもの
がえられることも知られている。しかしながら、パイル
のような特定の繊維布帛以外のものでは、外観を損なう
ことなしに熱成形が可能な繊維布帛はほとんど知られて
いない。As disclosed in Japanese Patent Application Laid-Open No. 1983-93LH,
It is also known that for certain fiber fabrics such as pile, by combining pile yarns with a high softening temperature and base yarns with a low softening temperature, it is possible to obtain fabrics that can be thermoformed without damaging the appearance of the fabric. ing. However, other than specific fiber fabrics such as pile, there are almost no known fiber fabrics that can be thermoformed without damaging the appearance.
本発明の目的は、外観を損なうことなしに、熱成形可能
なほとんどあらゆる種類の繊維布帛をうろことを目的と
する。The object of the present invention is to scale almost any type of fiber fabric that can be thermoformed without compromising its appearance.
[課題を解決するための手段]
本発明者らは熱成形性を有し、熱処理しても外観変化し
ないという性質を糸目体に付与すれば上記目的が達成さ
れるのではないかと考え、さらに検討の結果、カバリン
グヤーンを利用することにより上記目的が達成さ些るこ
とを見出した。[Means for Solving the Problems] The present inventors thought that the above object could be achieved by imparting to the thread body the property of having thermoformability and not changing its appearance even after heat treatment, and further As a result of investigation, it was found that the above object could be achieved by using covering yarn.
すなわち本発明は゛、カバー系およ′び芯糸の繊維が室
温以上の軟化温度を有し、カバー糸の繊維が芯糸の繊維
より高い軟化温度を有するカバリングヤーンに関する。That is, the present invention relates to a covering yarn in which the fibers of the cover system and the core yarn have a softening temperature above room temperature, and the fibers of the cover yarn have a softening temperature higher than the fibers of the core yarn.
本発明のカバリングヤーンからえられる布帛は芯糸の軟
化温度以上の温度で熱成形すると所望の形状に成形でき
、かつカバー糸の軟化温度が高いので成形品の表面外観
はほとんど損なわれることがない。またカバリングヤー
ンは通常どのような種類の布帛にも加工できるので、本
発明のカバリングヤーンからは外観を損なうことなく熟
成形可能なほとんどあらゆる種類の繊維布帛をうること
が可能である。The fabric obtained from the covering yarn of the present invention can be formed into a desired shape by thermoforming at a temperature higher than the softening temperature of the core yarn, and since the softening temperature of the cover yarn is high, the surface appearance of the molded product is hardly impaired. . Furthermore, since covering yarns can generally be processed into any type of fabric, it is possible to obtain almost any type of fibrous fabric from the covering yarn of the present invention which can be aged without deterioration of appearance.
[実施例]
本発明のカバリングヤーンのカバー糸となる繊維は芯糸
となる繊維より軟化温度が高く、具体的には10℃以上
、好ましくは20℃以上、さらに好ましくは30℃以上
高い繊維である。カバー糸となる繊維の軟化温度が芯糸
となる繊維の軟化温度より高いため、該カバリングヤー
ンを用いてえられる布帛を熱成形加工したのちも、カバ
ー糸となる繊維にはほとんど変化をおこすことがないか
ら、外観や風合を保持しながら芯糸となる繊維を所望の
形に熱、成形加工しうるのである。[Example] The fibers forming the cover yarn of the covering yarn of the present invention have a softening temperature higher than that of the fibers forming the core yarn, specifically, 10°C or higher, preferably 20°C or higher, and more preferably 30°C or higher. be. Since the softening temperature of the fibers that will become the cover yarn is higher than the softening temperature of the fibers that will become the core yarn, there will be almost no change in the fibers that will become the cover yarn even after thermoforming the fabric obtained using the covering yarn. Because there is no fiber, the core fiber can be heated and molded into the desired shape while maintaining its appearance and texture.
本明細書にいう軟化温度とは、一般に繊維の軟化温度の
測定に用いられている軟化温度測定器(東洋精器■製の
繊維軟化度測定器を用い、荷重5 B/デニール、試料
3000デニール、試長り0m1%昇温速度3℃/分で
測定)で測定し、軟化開始温度(接線法)を求めたもの
である。しかし、軟化曲線の接線が不明瞭のためにこの
方法で軟化開始温度が測定できないばあいには繊維のl
O%収縮温度を、また10%収縮温度も測定できないば
あいには最大収縮温度を求めて相対比較をすればよい。The softening temperature referred to in this specification refers to a softening temperature measuring device that is generally used to measure the softening temperature of fibers (a fiber softening degree measuring device manufactured by Toyo Seiki ■), a load of 5 B/denier, and a sample of 3000 denier. The softening start temperature (tangential method) was determined by measuring at a temperature increase rate of 3° C./min with a trial length of 0 m1%. However, if the softening start temperature cannot be measured using this method because the tangent to the softening curve is unclear,
If it is not possible to measure the 0% shrinkage temperature or the 10% shrinkage temperature, the maximum shrinkage temperature may be determined and a relative comparison made.
前記カバー糸となる繊維の好ましい具体例としては、た
とえば木綿、麻、羊毛、絹などの天然繊維や、合成繊維
のうちでも軟化温度の比較的高いポリエステル繊維、ポ
リアミド繊維、アクリル繊維があげられ、芯糸の繊維の
軟化温度よりも高い軟化温度、を存する繊維が使用され
うる。これらの繊維は単独で用いてもよく、2種以上併
用してもよい。なお天然繊維などでは、高温においても
繊維が軟化せず、軟化温度かえられないものがある。こ
のような繊維のばあい、非常に高い軟化温度を有する繊
維として取扱うものとする。Preferred specific examples of the fibers serving as the cover yarn include natural fibers such as cotton, hemp, wool, and silk, and among synthetic fibers, polyester fibers, polyamide fibers, and acrylic fibers that have a relatively high softening temperature. Fibers having a softening temperature higher than that of the fibers of the core yarn may be used. These fibers may be used alone or in combination of two or more. Note that some natural fibers do not soften even at high temperatures, and their softening temperature cannot be changed. In the case of such fibers, they shall be treated as fibers having a very high softening temperature.
前記芯糸となる繊維としては、合成繊維のうちでも軟化
温度の比較的低いアクリル繊維、アクリル系繊維、ポリ
塩化ビニル繊維、塩化ビニル系繊維、ポリクラール繊維
などがあげられ、カバー糸の繊維の軟化温度よりも低い
軟化温度を有する繊維が使用されうる。これらの繊維は
単独で用いてもよく、2種以上併用してもよい。The fibers that become the core yarn include acrylic fibers, acrylic fibers, polyvinyl chloride fibers, vinyl chloride fibers, polychloride fibers, etc., which have relatively low softening temperatures among synthetic fibers, and softening of the fibers of the cover yarn. Fibers having a softening temperature below the temperature can be used. These fibers may be used alone or in combination of two or more.
前記カバー糸の繊維と芯糸の繊維との組合わせの具体例
としては、一般に軟化温度を有しない天然繊維である木
綿、羊毛、絹などをカバー糸として用い、軟化温度を存
する合成繊維(アクリル繊維、アクリル系繊維、塩化ビ
ニル系繊維、ポリフラール繊維)を芯糸として用いるば
あいや、ポリエステル繊維、ポリアミド繊維、アクリル
繊維をカバー糸として用い、アクリル繊維、アクリル系
繊維、塩化ビニル系繊維、ポリフラール繊維のうちでカ
バー糸の軟化温度より低い軟化温度の繊維からなる芯糸
を用いるばあいなどがあげられる。As a specific example of the combination of the fibers of the cover yarn and the fibers of the core yarn, natural fibers that do not have a softening temperature such as cotton, wool, or silk are used as the cover yarn, and synthetic fibers that have a softening temperature (acrylic fibers) are used as the cover yarn. fibers, acrylic fibers, vinyl chloride fibers, polyfural fibers) are used as core yarns, polyester fibers, polyamide fibers, acrylic fibers are used as cover yarns, and acrylic fibers, acrylic fibers, vinyl chloride fibers, polyfural fibers are used as cover yarns. Among the fibers, a core yarn made of fibers having a softening temperature lower than that of the cover yarn may be used.
前者の組合わせのばあい、綿とアクリル繊維、綿とポリ
フラール繊維、綿とアクリル系繊維、羊毛とアクリル繊
維、絹とアクリル繊維などの組合わせが、軟化温度差な
どの点から好ましく、後者の組合わせのばあい、ポリエ
ステル繊維とアクリル繊維、ポリエステル繊維とアクリ
ル系繊維、ポリエステル繊維とポリフラール繊維、ポリ
エステル繊維と塩化ビニル系繊維、ポリアミド繊維とア
クリル繊維、ポリアミド繊維とアクリル系繊維、ポリア
ミド繊維とポリフラール繊維の組合わせ、さらには、ア
クリル繊維とアクリル系繊維、アクリル繊維と塩化ビニ
ル繊維の組合わせなども、軟化温度差などの点から好ま
しい。In the case of the former combination, combinations such as cotton and acrylic fiber, cotton and polyfural fiber, cotton and acrylic fiber, wool and acrylic fiber, silk and acrylic fiber are preferable from the viewpoint of softening temperature difference, etc. In the case of combinations, polyester fibers and acrylic fibers, polyester fibers and acrylic fibers, polyester fibers and polyfural fibers, polyester fibers and vinyl chloride fibers, polyamide fibers and acrylic fibers, polyamide fibers and acrylic fibers, polyamide fibers and polyfural Combinations of fibers, such as combinations of acrylic fibers and acrylic fibers, and combinations of acrylic fibers and vinyl chloride fibers, are also preferred from the viewpoint of softening temperature difference.
本発明の熱成形用、カバリングヤーンは外観的には一般
のカバリングヤーンと全く変りなく、たとえば1.5〜
5デニ一ル程度の繊度を有する単繊維からなる10〜4
0番手(綿番手)程度の紡績糸またはフィラメント糸の
カバー糸と、たとえば1.5〜5デニ一ル程度の繊度を
存する単繊維からなる20〜40番手(綿番手)程度の
紡績糸またはフィラメント糸の芯糸とを用い、通常のカ
バリングヤーンの製法により紡績したものが一般的な例
としてあげられる。このようにしてえられるカバリング
ヤーンとしての番手は、カバー糸と芯糸との組合わせた
ものとして2.0〜5.0番手(メートル番手)程度が
一般的であり、このような番手のものが応用範囲も広い
。The covering yarn for thermoforming of the present invention has no difference in appearance from general covering yarn, for example,
10-4 consisting of single fibers with a fineness of about 5 denier
A spun yarn or filament of about 20 to 40 count (cotton count) consisting of a cover yarn of spun yarn or filament yarn of about 0 count (cotton count) and a single fiber having a fineness of about 1.5 to 5 denier, for example. A common example is one that is spun using a core yarn of yarn and a normal covering yarn manufacturing method. The count of the covering yarn obtained in this way is generally about 2.0 to 5.0 (meter count) as a combination of cover yarn and core yarn. It has a wide range of applications.
本発明のカバリングヤーンは通常の方法により布帛に加
工される。布帛の種類としてはほとんどあらゆるものが
可能であるが、椅子張り用、カーテン用など意匠性が重
視される布帛に好適である。また布帛に加工する際、本
発明のカバリングヤーンのみを用いてもよく、他の紡績
糸などと併用して用いてもよい。The covering yarn of the present invention is processed into fabric by conventional methods. Although almost any type of fabric can be used, it is suitable for fabrics for which design is important, such as for upholstery and curtains. Furthermore, when processing into a fabric, the covering yarn of the present invention may be used alone or in combination with other spun yarns.
本発明のカバリングヤーンを用いた布帛を熱成形する際
の好ましい条件としては、芯糸の繊維の軟化点程度の温
度で、カバー糸の繊維の軟化点よりもlO℃程度以上低
い温度で熱成形するのが好ましい。このような条件で本
発明のカバリングヤーンを用いた布帛を熱成形すること
により、布帛の風合や外観などを損わずに良好な形の成
形体かえられる。Preferred conditions for thermoforming a fabric using the covering yarn of the present invention include thermoforming at a temperature approximately equal to the softening point of the fibers of the core yarn and at least 10°C lower than the softening point of the fibers of the cover yarn. It is preferable to do so. By thermoforming a fabric using the covering yarn of the present invention under such conditions, a molded article of good shape can be obtained without impairing the feel or appearance of the fabric.
本発明のカバリングヤーンは芯糸に熱可塑性繊維を使う
ため、カバー糸のオーバーフィード量とカバー糸の成形
時の温度における伸度の加算値まで成形することが可能
である。またカバー糸の素材を選択することにより、各
種要望、たとえば耐光性の要求に対してはポリエステル
繊維、天然の風合を要求されるときは綿、ウール(羊毛
)などを使用することにより対応しうる。さらに織物側
の風合で表面品質特性に応じて素材を選んで成形でき、
かつ形態を保持することができる。Since the covering yarn of the present invention uses thermoplastic fibers for the core yarn, it is possible to mold the yarn up to the sum of the overfeed amount of the cover yarn and the elongation of the cover yarn at the temperature during molding. In addition, by selecting the material for the cover yarn, we can respond to various requests, such as polyester fiber to meet light resistance requirements, and cotton or wool to meet natural texture requirements. sell. In addition, materials can be selected and molded according to the texture of the fabric and the surface quality characteristics.
and can maintain its shape.
以下、本発明のカバリングヤーンを実施例をあげて説明
するが、本発明はこれらに限定されるものではない。The covering yarn of the present invention will be described below with reference to Examples, but the present invention is not limited thereto.
実施例1
アクリロニトリル約50%、塩化ビニル約50%含有の
アクリル系合成繊維(軟化温度150℃)の糸(綿番手
30番手)2本を芯糸にし、ポリエステル繊維(軟化温
度220℃)の糸(綿番手10番手)2本をカバー糸に
して、1.3倍のオーバーフィードで綿番手24番のカ
バリングヤーンを製造した。Example 1 Two threads (cotton count 30) of acrylic synthetic fiber (softening temperature 150°C) containing about 50% acrylonitrile and about 50% vinyl chloride were used as core threads, and polyester fiber (softening temperature 220°C) threads were used as core threads. (Cotton count 10) Two covering yarns were used as cover yarns, and a covering yarn of cotton count 24 was produced by overfeeding 1.3 times.
このカバリングヤーンを経31本/10、緯23本/i
nの打込みで織物を作った。この織物を200℃雰囲気
中で40秒間加熱し、マツチモールド法にて成形テスト
を行なったところ、展開率(原反面積と成形後の表面積
の比)180%が可能であり、芯糸もカバー糸で覆われ
て、かつ、ポリエステルの風合を残したままで、かつ、
布帛のみで形態を保持する成形体をうろことができた。This covering yarn has a warp of 31 yarns/10 and a weft of 23 yarns/i.
A woven fabric was made by n-stroke. When this fabric was heated in an atmosphere of 200°C for 40 seconds and a molding test was performed using the matuti mold method, it was possible to achieve a development rate (ratio of the original fabric area to the surface area after molding) of 180%, and the core yarn was also covered. It is covered with thread and still retains the texture of polyester, and
It was possible to move around a molded object that maintained its shape using only the fabric.
比較例1
実施例1のカバリングヤーンのカバー糸のかわりに、芯
糸と同じアクリル系繊維を紡績した30番手(綿番手)
の糸を用いた他は実施例1と同様にして熱成形用布帛を
作り、実施例1と同一条件で熱成形したが、成形品のカ
バリングヤーンの部分はカバー糸が熱変化しており、外
観、風合ともに熱成形前と著しく異なり、商品価値の低
いものであった。Comparative Example 1 Instead of the cover yarn of the covering yarn of Example 1, the same acrylic fiber as the core yarn was spun with 30 count (cotton count).
A fabric for thermoforming was made in the same manner as in Example 1, except that the thread was used, and thermoforming was carried out under the same conditions as in Example 1, but the covering yarn in the covering yarn part of the molded product was thermally changed. Both appearance and texture were significantly different from before thermoforming, and the commercial value was low.
[発明の効果]
本発明のカバリングヤーンを用いた布帛は、熱成形加工
しても布帛の風合、外観などが損われず、形態を保持す
る成形体を与える。また本発明のカバリングヤーンを用
いればほとんどすべての種類の布帛をうろことができる
。[Effects of the Invention] A fabric using the covering yarn of the present invention provides a molded article that maintains its shape without losing its texture or appearance even when subjected to thermoforming. Also, the covering yarn of the present invention can be used to coat almost all types of fabrics.
Claims (1)
有し、カバー糸の繊維が芯糸の繊維より高い軟化温度を
有するカバリングヤーン。 2 カバー糸が天然繊維、ポリエステル繊維、ポリアミ
ド繊維およびアクリル繊維の少なくとも1種からなり、
芯糸がアクリル繊維、アクリル系繊維、塩化ビニル系繊
維およびポリクラール繊維の少なくとも1種からなり、
カバー糸の繊維の軟化温度が芯糸の繊維の軟化温度より
10℃以上高い繊維で構成されている請求項1記載のカ
バリングヤーン。 3 請求項1記載のカバリングヤーンからえられる熱成
形用布帛。[Scope of Claims] 1. A covering yarn in which the fibers of the cover yarn and the core yarn have a softening temperature higher than room temperature, and the fibers of the cover yarn have a softening temperature higher than the fibers of the core yarn. 2. The cover yarn is made of at least one of natural fibers, polyester fibers, polyamide fibers, and acrylic fibers,
The core yarn is made of at least one of acrylic fibers, acrylic fibers, vinyl chloride fibers, and polyclar fibers,
2. The covering yarn according to claim 1, wherein the covering yarn is composed of fibers whose softening temperature is 10° C. or more higher than the softening temperature of the core yarn. 3. A thermoforming fabric obtained from the covering yarn according to claim 1.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1528589A JPH02200831A (en) | 1989-01-25 | 1989-01-25 | Covering yarn for thermoforming |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP1528589A JPH02200831A (en) | 1989-01-25 | 1989-01-25 | Covering yarn for thermoforming |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02200831A true JPH02200831A (en) | 1990-08-09 |
Family
ID=11884581
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP1528589A Pending JPH02200831A (en) | 1989-01-25 | 1989-01-25 | Covering yarn for thermoforming |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02200831A (en) |
-
1989
- 1989-01-25 JP JP1528589A patent/JPH02200831A/en active Pending
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