JPH02178218A - Tanning skin cosmetic - Google Patents
Tanning skin cosmeticInfo
- Publication number
- JPH02178218A JPH02178218A JP33220288A JP33220288A JPH02178218A JP H02178218 A JPH02178218 A JP H02178218A JP 33220288 A JP33220288 A JP 33220288A JP 33220288 A JP33220288 A JP 33220288A JP H02178218 A JPH02178218 A JP H02178218A
- Authority
- JP
- Japan
- Prior art keywords
- skin
- cosmetic
- vitamin
- tanning
- derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 18
- 150000003722 vitamin derivatives Chemical class 0.000 claims description 5
- 229940088594 vitamin Drugs 0.000 claims description 4
- 229930003231 vitamin Natural products 0.000 claims description 4
- 235000013343 vitamin Nutrition 0.000 claims description 4
- 239000011782 vitamin Substances 0.000 claims description 4
- 230000000694 effects Effects 0.000 abstract description 15
- QYSXJUFSXHHAJI-XFEUOLMDSA-N Vitamin D3 Natural products C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C/C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-XFEUOLMDSA-N 0.000 abstract description 11
- 235000005282 vitamin D3 Nutrition 0.000 abstract description 3
- 239000011647 vitamin D3 Substances 0.000 abstract description 3
- QYSXJUFSXHHAJI-YRZJJWOYSA-N vitamin D3 Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)CCC1=C QYSXJUFSXHHAJI-YRZJJWOYSA-N 0.000 abstract description 3
- 229940021056 vitamin d3 Drugs 0.000 abstract description 3
- OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 abstract description 2
- 229960002535 alfacalcidol Drugs 0.000 abstract description 2
- 230000036074 healthy skin Effects 0.000 abstract description 2
- 235000020964 calcitriol Nutrition 0.000 abstract 1
- 239000011612 calcitriol Substances 0.000 abstract 1
- GMRQFYUYWCNGIN-NKMMMXOESA-N calcitriol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@@H](CCCC(C)(C)O)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C GMRQFYUYWCNGIN-NKMMMXOESA-N 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 230000003061 melanogenesis Effects 0.000 abstract 1
- 229930003316 Vitamin D Natural products 0.000 description 8
- 235000019166 vitamin D Nutrition 0.000 description 8
- 239000011710 vitamin D Substances 0.000 description 8
- 150000003710 vitamin D derivatives Chemical class 0.000 description 8
- 229940046008 vitamin d Drugs 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000002884 skin cream Substances 0.000 description 6
- 239000006210 lotion Substances 0.000 description 5
- 238000002156 mixing Methods 0.000 description 5
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 238000003756 stirring Methods 0.000 description 3
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- XUMBMVFBXHLACL-UHFFFAOYSA-N Melanin Chemical compound O=C1C(=O)C(C2=CNC3=C(C(C(=O)C4=C32)=O)C)=C2C4=CNC2=C1C XUMBMVFBXHLACL-UHFFFAOYSA-N 0.000 description 2
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 2
- -1 Polyoxyethylene Polymers 0.000 description 2
- 229930003270 Vitamin B Natural products 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 150000004347 all-trans-retinol derivatives Chemical class 0.000 description 2
- 229910021538 borax Inorganic materials 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- RXKJFZQQPQGTFL-UHFFFAOYSA-N dihydroxyacetone Chemical compound OCC(=O)CO RXKJFZQQPQGTFL-UHFFFAOYSA-N 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 2
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 2
- 229960002216 methylparaben Drugs 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 235000010339 sodium tetraborate Nutrition 0.000 description 2
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 2
- 235000019156 vitamin B Nutrition 0.000 description 2
- 239000011720 vitamin B Substances 0.000 description 2
- 206010061218 Inflammation Diseases 0.000 description 1
- WTDRDQBEARUVNC-LURJTMIESA-N L-DOPA Chemical compound OC(=O)[C@@H](N)CC1=CC=C(O)C(O)=C1 WTDRDQBEARUVNC-LURJTMIESA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- AUNGANRZJHBGPY-SCRDCRAPSA-N Riboflavin Chemical class OC[C@@H](O)[C@@H](O)[C@@H](O)CN1C=2C=C(C)C(C)=CC=2N=C2C1=NC(=O)NC2=O AUNGANRZJHBGPY-SCRDCRAPSA-N 0.000 description 1
- 206010042496 Sunburn Diseases 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- 229960000541 cetyl alcohol Drugs 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 239000006071 cream Substances 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 229940120503 dihydroxyacetone Drugs 0.000 description 1
- 230000002500 effect on skin Effects 0.000 description 1
- 239000000839 emulsion Substances 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 239000010685 fatty oil Substances 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000019634 flavors Nutrition 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 229940074774 glycyrrhizinate Drugs 0.000 description 1
- LPLVUJXQOOQHMX-QWBHMCJMSA-N glycyrrhizinic acid Chemical compound O([C@@H]1[C@@H](O)[C@H](O)[C@H](O[C@@H]1O[C@@H]1C([C@H]2[C@]([C@@H]3[C@@]([C@@]4(CC[C@@]5(C)CC[C@@](C)(C[C@H]5C4=CC3=O)C(O)=O)C)(C)CC2)(C)CC1)(C)C)C(O)=O)[C@@H]1O[C@H](C(O)=O)[C@@H](O)[C@H](O)[C@H]1O LPLVUJXQOOQHMX-QWBHMCJMSA-N 0.000 description 1
- 230000009931 harmful effect Effects 0.000 description 1
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 1
- 230000004054 inflammatory process Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000008099 melanin synthesis Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- 230000009965 odorless effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000004328 sodium tetraborate Substances 0.000 description 1
- 229940032094 squalane Drugs 0.000 description 1
- 239000000516 sunscreening agent Substances 0.000 description 1
- 239000004094 surface-active agent Substances 0.000 description 1
- BSVBQGMMJUBVOD-UHFFFAOYSA-N trisodium borate Chemical compound [Na+].[Na+].[Na+].[O-]B([O-])[O-] BSVBQGMMJUBVOD-UHFFFAOYSA-N 0.000 description 1
Landscapes
- Cosmetics (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、ビタミンD、またはその誘導体を含有するこ
とを特徴とするタンニング皮膚化粧料に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a tanning skin cosmetic characterized by containing vitamin D or a derivative thereof.
〔従来の技術及び発明が解決しようとする課題〕サンタ
ン化粧料としては、従来サンバーンの原因となる紫外線
を吸収するサンスクリーン剤を単に配合したものや、或
いはジヒドロキシアセトンのような着色剤を配合したも
のがサンタン化粧料として販売されている。あるいは、
ドーパの酸化に対して触媒的に作用し、メラニンの生成
を促進するビタミンB +*11を配合したサンクン化
粧料が提案されている(特開昭47−35149)、L
。[Prior art and problems to be solved by the invention] Conventionally, suntan cosmetics have either simply been formulated with a sunscreen agent that absorbs ultraviolet rays that cause sunburn, or have been formulated with a coloring agent such as dihydroxyacetone. Products are sold as suntan cosmetics. or,
A sunken cosmetic containing vitamin B+*11, which acts catalytically against the oxidation of dopa and promotes the production of melanin, has been proposed (Japanese Unexamined Patent Publication No. 47-35149), L.
.
かし、このビタミンBI!類は紫外線の吸収を促進する
ため、皮膚に炎症等の悪影響をあたえる恐れがある0、
安全に小麦色の美しい健康な肌を与えることは困難であ
った。またビタミンB+tHを配合した場合には皮膚吸
収へのムラがあり、均一なタンニング効果を得ることは
困難であった。Oh, this vitamin BI! Because they promote the absorption of ultraviolet rays, they may cause harmful effects such as inflammation on the skin.
It has been difficult to safely give beautiful, healthy skin of tan color. Furthermore, when vitamin B+tH is blended, there is uneven absorption into the skin, making it difficult to obtain a uniform tanning effect.
本発明は、タンニング効果と美肌効果に優れた皮膚化粧
料を提供することを目的としている。An object of the present invention is to provide a skin cosmetic with excellent tanning and skin beautifying effects.
本発明は、ビタミンD、またはその誘導体を含有してな
るタンニング皮膚化粧料である。The present invention is a tanning skin cosmetic containing vitamin D or a derivative thereof.
本発明において用いられるビタミンD、はコレカルシフ
ェロールのことであり、またビタミンDs誘導体として
は、1α−ヒドロキシコレカルシフェロール、1α、2
5−ジヒドロキシコレカルシフェロールなどが挙げられ
ているがいずれも公知のものである。Vitamin D used in the present invention refers to cholecalciferol, and vitamin Ds derivatives include 1α-hydroxycholecalciferol, 1α, 2
Examples include 5-dihydroxycholecalciferol, all of which are known.
これらビタミンD、またはその誘導体は総て白色の結晶
で無臭である。また、これらはエタノール、クロロホル
ムなどの有機溶媒に溶けやすく、脂肪油にやや溶けやす
く、水にはほとんど溶けない0本発明のタンニング皮膚
化粧料には、ビタミンD、およびそのm8体から一種ま
たは二種以上が任意に選ばれて用いられる。All of these vitamin D or its derivatives are white crystals and odorless. In addition, these are easily soluble in organic solvents such as ethanol and chloroform, slightly soluble in fatty oils, and almost insoluble in water. More than one species can be arbitrarily selected and used.
配合量は皮膚化粧料(組成物)の総量を基準として0.
001〜5.0重量%(以下、wt%と略記する)の範
囲が好適である。配合量が、0. OO1wt%未満で
は効果が充分に成されず、5.0 w t%を超えても
その増加分に見合った効果の向上は望めない。The blending amount is 0.0% based on the total amount of skin cosmetics (composition).
A preferable range is 0.001 to 5.0% by weight (hereinafter abbreviated as wt%). The blending amount is 0. If the amount of OO is less than 1 wt%, the effect will not be sufficiently achieved, and even if it exceeds 5.0 wt%, no improvement in the effect commensurate with the increase can be expected.
本発明の皮膚化粧料は、例えばローシラン類。The skin cosmetics of the present invention include, for example, rhosilanes.
乳液類、クリーム類、パック類等に適用することができ
る。It can be applied to emulsions, creams, packs, etc.
尚、本発明の皮膚化粧料には上記の他に色素。In addition to the above, the skin cosmetics of the present invention also contain pigments.
香料、防腐剤、界面活性剤5顔料、抗酸化剤等を本発明
の目的を達成する範囲内で適宜配合することができる。Flavors, preservatives, surfactants, pigments, antioxidants, and the like can be appropriately blended within the range that achieves the purpose of the present invention.
以下、実施例及び比較例の記載にて本発明を詳説する。 The present invention will be explained in detail below with reference to Examples and Comparative Examples.
また、本発明の皮膚化粧料のタンニング効果を評価する
ために用いたタンニング効果試験、美肌効果試験(官能
テスト)は下記の通りである。Furthermore, the tanning effect test and skin beautification effect test (sensory test) used to evaluate the tanning effect of the skin cosmetics of the present invention are as follows.
f工1 タンニング効果試験
被試験者20名の背部皮膚に、3cm四方の試験部位を
設定し、試料を1日1回20 Qmg塗布し、これを1
ケ月間連続して行った。試料塗布前と塗布終了後の皮膚
色明度(それぞれvb値。f-technique 1 Tanning effect test A 3 cm square test area was set up on the back skin of 20 test subjects, and 20 Qmg of the sample was applied once a day.
I went there continuously for several months. Skin color brightness before and after sample application (VB value, respectively).
Va値)を測定して、第1表の判定基準に従って皮膚の
タンニング程度を評価した。Va value) was measured to evaluate the degree of skin tanning according to the criteria in Table 1.
第 1 表
Vb−Va ≧ 0゜5
0、 5 > V b −V a ≧ 0
.3Q、 3 > V b −V a
≧ 0. 10、 1 > V b −V
a ≧ 00>Vb−Va
尚、皮膚の明度(V値)は高速分光色彩計で測定して得
られたマンセル値より算出した。また、評価は被試験者
20名の平均値で示した。Table 1 Vb-Va ≧ 0゜5 0, 5 > V b -V a ≧ 0
.. 3Q, 3 > V b −V a
≧0. 10, 1 > Vb −V
a≧00>Vb-Va The brightness of the skin (V value) was calculated from the Munsell value obtained by measuring with a high-speed spectrocolorimeter. Moreover, the evaluation was shown as the average value of 20 test subjects.
(2) 美肌効果試験(官能テスト)女子被験者20
人が試料を1日2回(朝・夕)連続3ケ月間使用後の効
果を評価した。試験結果は、皮膚の湿潤性、均一性、肌
荒れの各項目に対して、皮膚に潤いが生した。タンニン
グ効果にムラがなかった。肌荒れがなかったと回答した
人数で示した。(2) Beautiful skin effect test (sensory test) 20 female subjects
The effects were evaluated after humans used the sample twice a day (morning and evening) for three consecutive months. The test results showed that the skin was moisturized in terms of skin wettability, uniformity, and rough skin. There was no uneven tanning effect. It is shown by the number of people who answered that they did not have rough skin.
実施例1−12.比較例1 スキンローション下記の組
成の如く配合し、実施例1〜12及び比較例1のスキン
ローションを調製し、各試験に使用した。Example 1-12. Comparative Example 1 Skin Lotion Skin lotions of Examples 1 to 12 and Comparative Example 1 were prepared by blending the following compositions and used in each test.
(1) 組成
プロピレングリコール 3.0グリセリン
5.0メチルパラベン
0.1ポリオキシ工チレンヒマシ油誘導体
0.5エタノール 5.0ビ
タミンD、類 第2表記載精製水
残量
(2) 調製法
エタノールにビタミンD3 mおよびポリオキシエチレ
ンヒマシ油誘導体を加えて撹拌溶解後、残りの成分を順
次撹拌溶解して、各スキンローションを調製した。(1) Composition Propylene glycol 3.0 Glycerin 5.0 Methylparaben
0.1 Polyoxyethylene castor oil derivative 0.5 Ethanol 5.0 Vitamin D, etc. Remaining amount of purified water listed in Table 2 (2) Preparation method Add vitamin D3m and polyoxyethylene castor oil derivative to ethanol and stir to dissolve. Each skin lotion was prepared by sequentially stirring and dissolving the remaining ingredients.
(3) 特性
スキンローションの諸試験を実施した結果を第2表右横
に記載した。(3) Characteristics The results of various tests conducted on the skin lotion are listed on the right side of Table 2.
第2表から明らかなように、ビタミンD、類およびその
誘導体を含有した実施例のスキンローションは、無添加
の比較例のものに比べてタンニング効果、実用テストで
優れていた。特にビタミンD、誘導体を含有した実施例
5〜12は非常に優れていた。As is clear from Table 2, the skin lotions of the Examples containing vitamin D and their derivatives had superior tanning effects and practical tests compared to the comparative examples containing no additives. In particular, Examples 5 to 12 containing vitamin D and derivatives were very excellent.
実施例13〜14.比較例2 スキンクリーム下記の組
成の如く配合し、実施例13〜14及び比較例2のスキ
ンクリームを調製し、各試験に使用した。Examples 13-14. Comparative Example 2 Skin Cream Skin creams of Examples 13 to 14 and Comparative Example 2 were prepared by blending the following compositions and used in each test.
(111fi成
ミツロウ
ステアリン酸
セタノール
スクワラン
グリチルリチン酸モノカリうム
メチルバラベン
香料
3.0
8、 0
3.0
4.0
4、 0
0.1
0.5
スキンクリームの諸試験を実施した結果を第2表右欄に
記載した。(111fi adult beeswax stearate cetanol squalane glycyrrhizinate monopotassium methyl paraben fragrance 3.0 8, 0 3.0 4.0 4, 0 0.1 0.5 The results of various tests on skin cream are shown in Table 2. It is listed in the right column.
第2表から明らかなように、ビタミンDI Mおよびそ
の誘導体を含有した実施例のスキンクリームは、無添加
の比較例のものに比べてタンニング水 プロピレングリ
コール 3.0相 グリセリン
3.0成 硼砂(ホウ酸ナトリウム)0.4
(2) 調製法
油相成分混合物と水相成分混合物とを80℃にてそれぞ
れ撹拌後、均一に油相成分中に水相成分を添加、混合し
た後、徐々に冷却して各スキンクリームを調製した。As is clear from Table 2, the skin cream of the example containing vitamin DIM and its derivatives was more effective than the skin cream of the comparative example containing no additives.
3.0 composition Borax (sodium borate) 0.4 (2) Preparation method After stirring the oil phase component mixture and the water phase component mixture at 80°C, add the water phase component uniformly into the oil phase component, After mixing, each skin cream was prepared by gradually cooling.
(3) 特性
〔発明の効果〕
以上記載の如く、本発明の如くビタミンD、類を皮膚化
粧料基剤に含有することにより皮膚のメラニン生成を穏
和に促進し、安全に小麦色の美しい健康な肌を与え、さ
らに美肌効果を有する優れたタンニング化粧料を提供す
ることは明らかである。(3) Characteristics [Effects of the Invention] As described above, by containing vitamin D, etc. in the skin cosmetic base as in the present invention, melanin production in the skin is moderately promoted, and the skin is safely and beautifully healthy. It is clear that the present invention provides an excellent tanning cosmetic that gives beautiful skin and also has a beautifying effect.
Claims (1)
た一種又は二種以上を含有してなるタンニング皮膚化粧
料。A tanning skin cosmetic containing one or more selected from the group consisting of vitamin D_3 and its derivatives.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33220288A JPH02178218A (en) | 1988-12-27 | 1988-12-27 | Tanning skin cosmetic |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP33220288A JPH02178218A (en) | 1988-12-27 | 1988-12-27 | Tanning skin cosmetic |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH02178218A true JPH02178218A (en) | 1990-07-11 |
Family
ID=18252318
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP33220288A Pending JPH02178218A (en) | 1988-12-27 | 1988-12-27 | Tanning skin cosmetic |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH02178218A (en) |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997018817A1 (en) * | 1995-11-20 | 1997-05-29 | Kiyoshi Kita | External preparation containing vitamin d or vitamin k |
US6187331B1 (en) | 1997-06-10 | 2001-02-13 | New Vision Co., Ltd. | Composition for prophylaxis and/or treatment of dry syndrome comprising vitamin D |
US8747818B1 (en) * | 2011-02-07 | 2014-06-10 | Dennis Gross | Self-tanning compositions |
-
1988
- 1988-12-27 JP JP33220288A patent/JPH02178218A/en active Pending
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1997018817A1 (en) * | 1995-11-20 | 1997-05-29 | Kiyoshi Kita | External preparation containing vitamin d or vitamin k |
US6162801A (en) * | 1995-11-20 | 2000-12-19 | Kita; Kiyoshi | External ophthalmic preparation containing vitamin D |
US6187331B1 (en) | 1997-06-10 | 2001-02-13 | New Vision Co., Ltd. | Composition for prophylaxis and/or treatment of dry syndrome comprising vitamin D |
US6410006B2 (en) | 1997-06-10 | 2002-06-25 | New Vision Co., Ltd. | Composition for prophylaxis and/or treatment of dry eye syndrome comprising vitamin D |
US8747818B1 (en) * | 2011-02-07 | 2014-06-10 | Dennis Gross | Self-tanning compositions |
US9789041B2 (en) | 2011-02-07 | 2017-10-17 | Dennis F. Gross | Self-tanning compositions |
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