JPH02157139A - Glass composition for reinforcement - Google Patents
Glass composition for reinforcementInfo
- Publication number
- JPH02157139A JPH02157139A JP30988588A JP30988588A JPH02157139A JP H02157139 A JPH02157139 A JP H02157139A JP 30988588 A JP30988588 A JP 30988588A JP 30988588 A JP30988588 A JP 30988588A JP H02157139 A JPH02157139 A JP H02157139A
- Authority
- JP
- Japan
- Prior art keywords
- glass
- composition
- glass powder
- inorganic component
- vacuum vessel
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 43
- 239000000203 mixture Substances 0.000 title claims abstract description 16
- 230000002787 reinforcement Effects 0.000 title abstract description 3
- 239000000843 powder Substances 0.000 claims abstract description 15
- 239000000945 filler Substances 0.000 claims abstract description 7
- 230000003014 reinforcing effect Effects 0.000 claims abstract description 6
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 abstract description 4
- MCMNRKCIXSYSNV-UHFFFAOYSA-N Zirconium dioxide Chemical compound O=[Zr]=O MCMNRKCIXSYSNV-UHFFFAOYSA-N 0.000 abstract description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 abstract description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 abstract description 3
- 239000011230 binding agent Substances 0.000 abstract description 3
- FUJCRWPEOMXPAD-UHFFFAOYSA-N Li2O Inorganic materials [Li+].[Li+].[O-2] FUJCRWPEOMXPAD-UHFFFAOYSA-N 0.000 abstract description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 abstract description 2
- XUCJHNOBJLKZNU-UHFFFAOYSA-M dilithium;hydroxide Chemical compound [Li+].[Li+].[OH-] XUCJHNOBJLKZNU-UHFFFAOYSA-M 0.000 abstract description 2
- 229910052845 zircon Inorganic materials 0.000 abstract description 2
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 abstract description 2
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 abstract 2
- 229910020617 PbO—B2O3—SiO2 Inorganic materials 0.000 abstract 1
- 229910052681 coesite Inorganic materials 0.000 abstract 1
- 229910052593 corundum Inorganic materials 0.000 abstract 1
- 229910052906 cristobalite Inorganic materials 0.000 abstract 1
- 230000002708 enhancing effect Effects 0.000 abstract 1
- 239000000377 silicon dioxide Substances 0.000 abstract 1
- 235000012239 silicon dioxide Nutrition 0.000 abstract 1
- 229910052682 stishovite Inorganic materials 0.000 abstract 1
- 229910052905 tridymite Inorganic materials 0.000 abstract 1
- 229910001845 yogo sapphire Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 description 6
- 238000010438 heat treatment Methods 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 238000002844 melting Methods 0.000 description 4
- 230000007423 decrease Effects 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- 239000005356 container glass Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 description 2
- 239000002002 slurry Substances 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229910052797 bismuth Inorganic materials 0.000 description 1
- JCXGWMGPZLAOME-UHFFFAOYSA-N bismuth atom Chemical compound [Bi] JCXGWMGPZLAOME-UHFFFAOYSA-N 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052878 cordierite Inorganic materials 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000004031 devitrification Methods 0.000 description 1
- JSKIRARMQDRGJZ-UHFFFAOYSA-N dimagnesium dioxido-bis[(1-oxido-3-oxo-2,4,6,8,9-pentaoxa-1,3-disila-5,7-dialuminabicyclo[3.3.1]nonan-7-yl)oxy]silane Chemical compound [Mg++].[Mg++].[O-][Si]([O-])(O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2)O[Al]1O[Al]2O[Si](=O)O[Si]([O-])(O1)O2 JSKIRARMQDRGJZ-UHFFFAOYSA-N 0.000 description 1
- NKZSPGSOXYXWQA-UHFFFAOYSA-N dioxido(oxo)titanium;lead(2+) Chemical compound [Pb+2].[O-][Ti]([O-])=O NKZSPGSOXYXWQA-UHFFFAOYSA-N 0.000 description 1
- KZHJGOXRZJKJNY-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Si]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O.O=[Al]O[Al]=O KZHJGOXRZJKJNY-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 210000003746 feather Anatomy 0.000 description 1
- 239000000156 glass melt Substances 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 229910052746 lanthanum Inorganic materials 0.000 description 1
- FZLIPJUXYLNCLC-UHFFFAOYSA-N lanthanum atom Chemical compound [La] FZLIPJUXYLNCLC-UHFFFAOYSA-N 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229910052863 mullite Inorganic materials 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 229910052697 platinum Inorganic materials 0.000 description 1
- 230000001902 propagating effect Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
- 229910021489 α-quartz Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/14—Glass frit mixtures having non-frit additions, e.g. opacifiers, colorants, mill-additions
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
Abstract
Description
【発明の詳細な説明】
し産業上の利用分野］
本発明はカラー受像管の如くガラス真空容器の補強用ガ
ラス組成物に関する。DETAILED DESCRIPTION OF THE INVENTION Field of Industrial Application The present invention relates to a glass composition for reinforcing glass vacuum containers such as color picture tubes.
［従来の技術］
カラーテレビ受像管に代表される様にガラス物体で形成
される真空容器がデイスプレー用として広く普及してい
る。特にカラーテレビ用バルブには１０〜６Ｔｏｒｒ以
上の真空度が必要であり、それ故真空容器としてのバル
ブには高耐圧強度が要求される。通常のバルブの耐圧強
度は静水圧法で見た場合３〜４ｋｇ／ｃｍ２であるが、
近年バルブの大型化に伴ないその耐圧強度もさらに高め
る必要が生じている。耐圧強度向上法として既に特公昭
３７−１４５３９に示されているようにバルブの局部に
重量％でＢ２０３１６％、 Ｚｎ０４％、 ｐｂｏ ｇ
ｏ％からなる補強用ガラスを融着させる方法が知られて
いる。つまりバルブの高強度化に対し、パネルのスカー
ト部に働く引張り応力に対抗すべく、そのスカート部全
周に低融点ガラスを融着・固着させることにより、スカ
ート部に散在するガラス表面の傷からのクラック発生お
よび伝ばんを防止する方法である。ここでこのうわ薬と
して用いる低融点ガラスはバルブ（パネル−ファンネル
）のフリットシールの熱処理条件下にて（通常４３０−
４４０℃１時間保持）十分な流動性を有しガラス表面に
濡れること並びにボアの少ない緻密な焼結構造を達成し
高強度であることさらに、熱膨張係数がガラス（パネル
）と太き（違わないことが必要である。しかしながら提
案されている低融点ガラスは前記した要求特性のうち十
分な流動性が得られずポーラスとなったり、熱膨張係数
の整合が不十分であるため、６〜８ｋｇ／ｃｍ２の高い
耐圧強度が得られないという欠点があった。従って実用
化には至っていないという現状である。[Prior Art] Vacuum containers made of glass objects, as typified by color television picture tubes, are widely used for display applications. In particular, a color television bulb requires a degree of vacuum of 10 to 6 Torr or more, and therefore, a bulb serving as a vacuum container is required to have high pressure resistance. The pressure resistance of a normal valve is 3 to 4 kg/cm2 when viewed using the hydrostatic pressure method.
In recent years, as valves have become larger, it has become necessary to further increase their pressure resistance. As already shown in Japanese Patent Publication No. 37-14539 as a method for improving pressure resistance strength, B20316%, Zn04%, pbog, etc. are added to the local part of the valve by weight%.
A method of fusing reinforcing glass consisting of 0% is known. In other words, in order to increase the strength of the bulb, in order to counter the tensile stress acting on the skirt part of the panel, low melting point glass is fused and fixed around the entire circumference of the skirt part, thereby preventing scratches on the glass surface scattered on the skirt part. This is a method to prevent cracks from forming and propagating. Here, the low melting point glass used as this glaze is heated under the heat treatment conditions of the frit seal of the bulb (panel-funnel) (usually 430-
It has sufficient fluidity (maintained at 440℃ for 1 hour) to wet the glass surface, achieves a dense sintered structure with few bores, and has high strength.Furthermore, it has a coefficient of thermal expansion that is thicker than glass (panel). However, the proposed low-melting point glass does not have sufficient fluidity among the above-mentioned required properties and becomes porous, and its thermal expansion coefficient is insufficiently matched. It has the disadvantage that a high pressure resistance of /cm2 cannot be obtained.Therefore, it has not been put into practical use yet.
［発明の解決しようとする課題］
本発明はパネル−ファンネルのフリットシール条件（通
常４４０°Ｃ，１時間保持）で融着でき、且つ融着固化
したうわ薬の焼結構造が緻密で高強度の被膜が形成でき
、さらにパネルガラスの如く熱膨張係数９５〜１０５
Ｘｌ０−７／°Ｃのものに整合する補強用ガラス組成物
の提供を目的とする。[Problems to be Solved by the Invention] The present invention can be fused under panel-funnel frit seal conditions (usually held at 440°C for 1 hour), and the sintered structure of the fused and solidified glaze is dense and has high strength. A film can be formed, and the coefficient of thermal expansion is 95-105 like panel glass.
The object is to provide a reinforcing glass composition matching that of Xl0-7/°C.
［課題を解決するための手段］
即ち、本発明は無機成分がガラス粉末５０〜９９重量％
と耐大物フィラー１〜５０重量％とからなり、該ガラス
粉末は重量％表示で実質的にＰｂＯ７３〜８８％
８２０３１〜１４％
５ｉｎ２０．１〜１０％
ＺｎＯＩ］〜１３％
Ａ１２０３０〜５％
ＭｇＯ＋ＣａＯ＋ＳｒＯ＋ＢａＯＯ〜５％Ｌｉ２Ｏ＋Ｎ
ａ２Ｏ＋Ｋ２Ｏ０〜３％
ＳｎＯ□＋ＴｉＯ２＋Ｚｒ０ｚ ３〜３％からなる
真空容器補強用ガラス組成物を提供するものである。[Means for Solving the Problems] That is, the present invention provides a method in which the inorganic component is glass powder in an amount of 50 to 99% by weight.
and 1 to 50% by weight of a large-sized filler, and the glass powder is substantially PbO73 to 88% in weight% 82031 to 14% 5in20.1 to 10% ZnOI] to 13% A12030 to 5% MgO + CaO + SrO + BaOO to 5 %Li2O+N
The present invention provides a glass composition for reinforcing a vacuum container comprising 0 to 3% of a2O+K2O and 3 to 3% of SnO□+TiO2+Zr0z.
本発明の組成物の限定理由は次の通りである。本発明の
ガラス粉末は例えば４４０℃以下の温度で充分に流動性
を有し、耐火物フィラー表面およびガラス表面を濡らし
、且つ一部結晶化する特性を有するものが好ましい。無
機成分中のガラス粉末の含有量が５０％より少ないと流
動性が悪くなり十分な濡れ性が得られず、一方９９％を
越えると熱膨張係数の整合が計れなくなる。ガラス粉末
は上記範囲中６０〜９５％が好ましい。一方、耐火物フ
ィラーとしては、ジルコン チタン酸鉛、コージェライ
ト、α−アルミナ、α−石英あるいはムライト等を単独
もしくは併用でき、いずれも熱膨張係数の整合化調整剤
および焼結体被膜の高強度化の目的で使用する。The reasons for limiting the composition of the present invention are as follows. The glass powder of the present invention preferably has sufficient fluidity at a temperature of 440° C. or lower, wets the refractory filler surface and the glass surface, and partially crystallizes. If the content of glass powder in the inorganic component is less than 50%, fluidity will be poor and sufficient wettability will not be obtained, while if it exceeds 99%, matching of thermal expansion coefficients will not be possible. The glass powder is preferably 60 to 95% within the above range. On the other hand, as the refractory filler, zircon, lead titanate, cordierite, α-alumina, α-quartz, mullite, etc. can be used alone or in combination, and all of these are used as thermal expansion coefficient matching adjusters and to increase the strength of the sintered body coating. used for the purpose of
本発明におけるガラス粉末の限定理由は次の通りである
。The reasons for limiting the glass powder in the present invention are as follows.
ＰｂＯニア３％よりも少ないと軟化点が高くなり過ぎ流
動性が悪くなるので好まし
くない。８８％よりも多いと熱膨張係
数が太き（なり過ぎるので好ましく
ない。より望ましくは７５〜８５％である。If the PbO content is less than 3%, the softening point becomes too high and fluidity deteriorates, which is not preferable. If it is more than 88%, the coefficient of thermal expansion becomes too thick, which is not preferable.More preferably, it is 75 to 85%.
Ｂ２Ｏ３：１％より少ないと軟化点が高（なり過ぎ流動
性が低下し好ましくない。B2O3: If it is less than 1%, the softening point will be too high (too much, and the fluidity will decrease, which is not preferable).
一方、１４％より多いとガラスの化学 ）λ 、（へ ”：ｔｔ：’ｑ、′１ ｉ０２ ｎ０ Ａ１２０３ 的耐久性が低下し補強用ガラスとし て好ましくない。より望ましくは３ 〜１２％である。On the other hand, if it is more than 14%, the glass chemistry )λ ,(fart ”:tt:’q,’1 i02 n0 A1203 The durability of the material decreases and it is used as reinforcement glass. I don't like it. More preferably 3 ~12%.
・０１％より少ないとガラス溶融中に 失透する恐れがあり好ましくない。・If it is less than 0.01%, the glass will melt during glass melting. It is not preferable because it may cause devitrification.
一方、１０％より多いと軟化点が高く なり過ぎ流動性が悪くなる。より望 ましくは０．５〜６％である。On the other hand, if it is more than 10%, the softening point will be high. If it becomes too much, liquidity will deteriorate. more desired Preferably it is 0.5 to 6%.
、必要成分ではないが含有させること により溶解性を向上し、結晶化を促 進し、ガラス軟化点を下げることが できる。しかしその含有量が１３％を 越えると流動性が低下するので好ま しくない。より望ましくは１２％以下 である。Although it is not a necessary ingredient, it should be included. improves solubility and promotes crystallization. and lower the glass softening point. can. However, its content is 13% It is preferable because the fluidity decreases if it exceeds It's not right. More preferably 12% or less It is.
ニガラスの化学的耐久性の向上および 結晶化調整剤として使用できる。し かし、５％を越えると結晶の生成が 抑制されるので好ましくない。より 望ましくは４％以下である。Improving the chemical durability of Nigarasu and Can be used as a crystallization modifier. death However, if it exceeds 5%, crystal formation will occur. This is not desirable because it is suppressed. Than It is preferably 4% or less.
ガラスの溶解性および熱膨張係数調 整剤として使用できる。しかし５％ を越えると熱膨張係数が太き（なり 過ぎるので好ましくない。より望ま しくは４％以下である。Glass solubility and thermal expansion coefficient It can be used as a medicine. But 5% If it exceeds I don't like it because it's too much. more desirable or less than 4%.
、熱膨張係数、ガラスの化学的耐久性
向上剤として使用できる。しかし、
十に２０３％を越えると熱膨張係数が大きくなり過ぎる
ので好ましくない。より
望ましくは２％以下である。It can be used as an agent to improve thermal expansion coefficient and chemical durability of glass. However, if it exceeds 203%, the coefficient of thermal expansion becomes too large, which is not preferable. More preferably, it is 2% or less.
主として、化学的耐久性向上剤とし て用いる。しかし、３％を越えると 軟化点が高くなり過ぎるので好まし くない。より望ましくは２％以下で ある。Mainly used as a chemical durability improver. used. However, if it exceeds 3% It is preferable because the softening point becomes too high. Not. More preferably 2% or less be.
ガラス粉末は以上の成分の総量が９８％以上であればよ
く、残部２％についてはビスマス、タンタル、ランタン
の酸化物を含有してもよい。The glass powder only needs to have a total amount of 98% or more of the above components, and the remaining 2% may contain oxides of bismuth, tantalum, and lanthanum.
本発明による組成物は、それに有機バインダーを添加し
スラリー状あるいはペースト状に＋Ｔ１０２
ＳｎＯ□
＋Ｎａ２Ｏ
＋ＺｒＯ２
ｇＯ
＋ＣａＯ
＋ＳｒＯ
＋Ｂａ０
して補強したい部位例えばパネルのスカート部に塗布形
成し焼き付ける。The composition according to the present invention is prepared by adding an organic binder thereto in the form of a slurry or paste +T102 SnO□ +Na2O +ZrO2 gO +CaO +SrO +Ba0, and applying the composition to a portion to be reinforced, such as the skirt portion of a panel, and baking.
［実施例］
目標組成となるように各原料を調合し、これを白金坩堝
中にて１０００℃〜１２００°Ｃで０，５時間〜２時間
溶解した。次いで、ガラス融液を水砕またはフレーク状
とした。粉砕は通常良く知られているボールミルにて、
耐火物フィラーと上記ガラスを目標構成となるように秤
量し、粉砕兼混合した。得られた粉末の粒度（平均粒径
）は３〜７μｍ程度であった。次いでこれら粉末と有機
バインダー（例えばニトロセルロースを含むビヒクルに
よりスラリー化あるいはペースト化しパネルスカート部
に羽毛塗りもしくはロールコータ−法により塗布形成し
、４４０℃、１時間の熱処理にて焼き付けた。焼き付け
たガラス膜厚は５０μｍ〜２００μｍであった。焼き付
けされたパネルを用いてカラーブラウン管を作成し、そ
の耐圧強度を測定した。これらの結果については表１に
示した。[Example] Each raw material was prepared to have a target composition, and dissolved in a platinum crucible at 1000°C to 1200°C for 0.5 to 2 hours. Next, the glass melt was made into granules or flakes. Grinding is usually done using a well-known ball mill.
The refractory filler and the above-mentioned glass were weighed so as to have the target composition, and were crushed and mixed. The particle size (average particle size) of the obtained powder was about 3 to 7 μm. Next, these powders and an organic binder (for example, a vehicle containing nitrocellulose) were made into a slurry or paste, which was coated on the panel skirt by feather coating or a roll coater method, and baked by heat treatment at 440° C. for 1 hour. Baked glass The film thickness was 50 μm to 200 μm. A color cathode ray tube was prepared using the baked panel, and its pressure resistance strength was measured. Table 1 shows these results.
比較として本発明による組成物以外のものについても同
一のテストを行なったので、その結果も合わせて併記し
た。For comparison, the same test was conducted on compositions other than the composition according to the present invention, and the results are also listed.
次に表・１に示す特性についての評価方法を説明する。Next, the evaluation method for the characteristics shown in Table 1 will be explained.
流動性
緻密性
熱膨張係数
バルブの
耐圧強度
粉末１０ｇを外径１２．５ｍｍΦにドライプレスし４４
０℃、３０分の熱処理
後の拡がり代を測定する。Fluidity Dense Coefficient of Thermal Expansion 10g of valve pressure resistance powder was dry pressed to an outer diameter of 12.5mmΦ44
Measure the amount of expansion after heat treatment at 0°C for 30 minutes.
４４０°Ｃ１３０分熱処理後のガラス被膜の断面構造を
ＳＥＭ観察により
行なった。The cross-sectional structure of the glass coating after heat treatment at 440° C. for 130 minutes was observed by SEM.
４４０°Ｃ１３０分熱処理品の熱膨張係数を加熱昇温曲
線より求め、５０
℃−４００℃の平均線膨張係数とし
て求めた。The thermal expansion coefficient of the product heat-treated at 440°C for 130 minutes was determined from the heating temperature rise curve, and was determined as the average linear expansion coefficient from 50°C to 400°C.
試作バルブの耐圧強度は、バルブ を水中に浸漬し、バルブ内外の圧 力差を徐々に増加してゆき、パル ブが破壊する圧力の直前の値を耐 圧強度（ｋｇ ／ｃｍ２）とした。The pressure resistance of the prototype valve is immersed in water to reduce the pressure inside and outside the valve. Gradually increase the force difference and the pulse Withstand the pressure just before the pressure that causes the tube to break It was defined as compressive strength (kg/cm2).
［発明の効果］
本発明によればパネルガラスの如（熱膨張係数が９５〜
１００ Ｘｌ０−’／”Ｃ程度の真空容器ガラスに整合
し、高強度で緻密な被膜が形成されるので、該容器ガラ
スの強度を大幅に向上することができる。[Effects of the Invention] According to the present invention, a panel glass (having a coefficient of thermal expansion of 95 to 95)
Since a high-strength and dense coating is formed that matches the vacuum container glass of about 100 Xl0-'/''C, the strength of the container glass can be greatly improved.
Claims (1)
フィラー１〜５０重量％とからなり、該ガラス粉末は重
量％表示で実質的に ＰｂＯ ７３〜８８％ Ｂ＿２Ｏ＿３ １〜１４％ ＳｉＯ＿２ ０．１〜１０％ ＺｎＯ ０〜１３％ Ａｌ＿２Ｏ＿８ ０〜５％ ＭｇＯ＋ＣａＯ＋ＳｒＯ＋ＢａＯ ０〜５％Ｌｉ＿２Ｏ
＋Ｎａ＿２Ｏ＋Ｋ＿２Ｏ ０〜３％ＳｎＯ＿２＋ＴｉＯ
＿２＋ＺｒＯ＿２ ０〜３％からなる真空容器補強用ガ
ラス組成物。(1) The inorganic component consists of 50-99% by weight of glass powder and 1-50% by weight of refractory filler, and the glass powder is substantially PbO 73-88% B_2O_3 1-14% SiO_2 0. 1-10% ZnO 0-13% Al_2O_8 0-5% MgO+CaO+SrO+BaO 0-5% Li_2O
+Na_2O+K_2O 0~3%SnO_2+TiO
A glass composition for reinforcing vacuum containers consisting of _2+ZrO_2 0 to 3%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30988588A JPH02157139A (en) | 1988-12-09 | 1988-12-09 | Glass composition for reinforcement |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30988588A JPH02157139A (en) | 1988-12-09 | 1988-12-09 | Glass composition for reinforcement |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02157139A true JPH02157139A (en) | 1990-06-15 |
Family
ID=17998486
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30988588A Pending JPH02157139A (en) | 1988-12-09 | 1988-12-09 | Glass composition for reinforcement |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02157139A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5916832A (en) * | 1997-10-14 | 1999-06-29 | Asahi Glass Company Ltd. | Hermetic sealing composition |
| JP2008303075A (en) * | 2007-06-05 | 2008-12-18 | Central Glass Co Ltd | Insulating coating material |
| US8390775B2 (en) | 2005-06-30 | 2013-03-05 | Lg Display Co., Ltd. | Liquid crystal display device with protection film at connection of TCP and therminal and fabrication method thereof |
-
1988
- 1988-12-09 JP JP30988588A patent/JPH02157139A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5916832A (en) * | 1997-10-14 | 1999-06-29 | Asahi Glass Company Ltd. | Hermetic sealing composition |
| US8390775B2 (en) | 2005-06-30 | 2013-03-05 | Lg Display Co., Ltd. | Liquid crystal display device with protection film at connection of TCP and therminal and fabrication method thereof |
| JP2008303075A (en) * | 2007-06-05 | 2008-12-18 | Central Glass Co Ltd | Insulating coating material |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US4084976A (en) | Lead-free glaze for alumina bodies | |
| JP3814810B2 (en) | Bismuth glass composition | |
| JP3845853B2 (en) | Tin borophosphate glass and sealing material | |
| US5650364A (en) | Self-opacifying enamel frits for the enamelling of aluminum or aluminum alloys | |
| JP3951514B2 (en) | Silica tin phosphate glass and sealing material | |
| JP2003095697A (en) | Sealing composition | |
| US4256497A (en) | Lead-free glaze for alumina bodies | |
| JP4061792B2 (en) | Lead-free low melting glass and glass frit | |
| US4120733A (en) | Lead-free glaze for alumina bodies | |
| JP4061762B2 (en) | Low hygroscopic glass frit, glass ceramic composition and fired body | |
| JPH11106234A (en) | Glass composition for glazing agent | |
| JPH1143351A (en) | Glass composition for glaze | |
| JP2001039733A (en) | Lead-free glaze and spark plug | |
| JP2000313635A (en) | Material for plasma display panel | |
| US4376169A (en) | Low-melting, lead-free ceramic frits | |
| JPH09188544A (en) | Glass composition | |
| US2972543A (en) | Ceramic glaze composition | |
| JPH02157139A (en) | Glass composition for reinforcement | |
| US4469798A (en) | Low melting, opaque enamel frit | |
| JP2001180972A (en) | Lead free glass with low melting point | |
| US3862844A (en) | SnO{HD 2 {B containing lead silicate glass having a low melting point | |
| JP3422049B2 (en) | Glass material for sealing | |
| JPH01145347A (en) | Aluminum enamel article having high brightness | |
| JPH02102147A (en) | Decorative glass composition | |
| US3449203A (en) | High expansion sealing glass and composite article |