JPH02154064A - Coloring by gold salt - Google Patents
Coloring by gold saltInfo
- Publication number
- JPH02154064A JPH02154064A JP30209588A JP30209588A JPH02154064A JP H02154064 A JPH02154064 A JP H02154064A JP 30209588 A JP30209588 A JP 30209588A JP 30209588 A JP30209588 A JP 30209588A JP H02154064 A JPH02154064 A JP H02154064A
- Authority
- JP
- Japan
- Prior art keywords
- gold
- gold salt
- salt
- colored
- aqueous solution
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004040 coloring Methods 0.000 title claims description 7
- JAJIPIAHCFBEPI-UHFFFAOYSA-N 9,10-dioxoanthracene-1-sulfonic acid Chemical compound O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)O JAJIPIAHCFBEPI-UHFFFAOYSA-N 0.000 title claims 4
- 239000007787 solid Substances 0.000 claims abstract description 18
- 230000001678 irradiating effect Effects 0.000 claims abstract 3
- 238000000034 method Methods 0.000 claims description 14
- 239000012266 salt solution Substances 0.000 claims description 7
- SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 abstract description 21
- 229910052737 gold Inorganic materials 0.000 abstract description 15
- 239000010931 gold Substances 0.000 abstract description 15
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 abstract description 14
- 239000007864 aqueous solution Substances 0.000 abstract description 12
- 239000011343 solid material Substances 0.000 abstract description 9
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 5
- 239000010419 fine particle Substances 0.000 abstract description 5
- 229910052708 sodium Inorganic materials 0.000 abstract description 5
- 239000011734 sodium Substances 0.000 abstract description 5
- 150000003839 salts Chemical class 0.000 abstract description 4
- 239000002253 acid Substances 0.000 abstract description 3
- 239000000835 fiber Substances 0.000 abstract description 3
- 229920003043 Cellulose fiber Polymers 0.000 abstract description 2
- 108010010803 Gelatin Proteins 0.000 abstract description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 abstract description 2
- 239000008273 gelatin Substances 0.000 abstract description 2
- 229920000159 gelatin Polymers 0.000 abstract description 2
- 235000019322 gelatine Nutrition 0.000 abstract description 2
- 235000011852 gelatine desserts Nutrition 0.000 abstract description 2
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229910052700 potassium Inorganic materials 0.000 abstract description 2
- 239000011591 potassium Substances 0.000 abstract description 2
- 125000002091 cationic group Chemical group 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000004744 fabric Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 7
- 239000002245 particle Substances 0.000 description 6
- 238000007654 immersion Methods 0.000 description 5
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 150000002343 gold Chemical class 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- 229920000742 Cotton Polymers 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 235000010724 Wisteria floribunda Nutrition 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 238000004043 dyeing Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 241000287127 Passeridae Species 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 239000000084 colloidal system Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000002274 desiccant Substances 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000035945 sensitivity Effects 0.000 description 1
- 239000000741 silica gel Substances 0.000 description 1
- 229910002027 silica gel Inorganic materials 0.000 description 1
- ADZWSOLPGZMUMY-UHFFFAOYSA-M silver bromide Chemical compound [Ag]Br ADZWSOLPGZMUMY-UHFFFAOYSA-M 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
- LTVDFSLWFKLJDQ-UHFFFAOYSA-N α-tocopherolquinone Chemical compound CC(C)CCCC(C)CCCC(C)CCCC(C)(O)CCC1=C(C)C(=O)C(C)=C(C)C1=O LTVDFSLWFKLJDQ-UHFFFAOYSA-N 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、金塩水溶液処理および光照射を利用した、固
体表面を着色するのに有用な方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method useful for coloring a solid surface using a gold salt aqueous solution treatment and light irradiation.
は古来よ゛（゛す高級品と見なされてきた。−最に、金
属の極めて微細な粒子には強い着色力があり、たとえば
、第一錫塩で還元して得られる金の微粒子は「カシウス
の紫」と呼ばれ、陶磁器やガラスの着色に利用されてい
る。has been considered a luxury item since ancient times.Furthermore, extremely fine particles of metal have strong coloring power; for example, fine particles of gold obtained by reduction with stannous salt have a It is called "Cassius's Purple" and is used to color ceramics and glass.
発明者らは先に、金微粒子を水の中に一様に分散させた
金ヒドロシルを用い、これに含まれる金微粒子（コロイ
ドという）を吸着させることにより絹布などの繊維成形
物を紫系統の色に染色する方法を見出している（特開昭
６２−２９９５８７号公報）。The inventors previously used gold hydrosil, in which fine gold particles were uniformly dispersed in water, and by adsorbing the fine gold particles (called colloids) contained in this gold hydrosil, fabricated fibers such as silk cloth were made into purple-colored fabrics. A method of dyeing the material has been discovered (Japanese Unexamined Patent Publication No. 299587/1987).
しかし、この方法では、金微粒子の吸着量が増加するに
つれて金微粒子間の凝集がひどくなり、その結果、濃い
色にはならず黒味のかかった冴えない色となる。また、
目的物の表面にのみ金微粒子が分布しているので、特に
湿潤状態では中擦により脱落し易い、さらに、この方法
では、特定の画像（または模様）に従って着色すること
が難しい１本発明は、濃色にすることが難しく、また摩
擦堅ろう度に劣る従来法の問題点を解決し、金を用い画
像形成が容易な新しい着色方法を提供するものである。However, with this method, as the amount of gold particles adsorbed increases, the aggregation between the gold particles becomes more severe, and as a result, the color does not become deep, but instead becomes a dull color with a black tinge. Also,
Since the gold fine particles are distributed only on the surface of the object, they are likely to fall off during rubbing, especially in a wet state.Furthermore, with this method, it is difficult to color according to a specific image (or pattern). The present invention solves the problems of the conventional method in that it is difficult to obtain a deep color and is poor in friction fastness, and provides a new coloring method that uses gold and facilitates image formation.
本発明者らは、金を用い、摩擦に対する堅ろう度に優れ
た濃色の着色が可能となるような方法を求めて鋭意研究
を重ねた結果、固体表面に付与された金塩が、光を照射
した部分でのみ金微粒子に変換されて発色することを見
出し、本発明となすに至った。The inventors of the present invention have conducted extensive research in search of a method that would enable deep coloring with excellent friction resistance using gold. It was discovered that only the irradiated area was converted into fine gold particles and colored, leading to the present invention.
すなわち、本発明は、固体表面を金塩水溶液で処理した
後、光を照射することを特徴とする着色方法を提供する
ものである。That is, the present invention provides a coloring method characterized in that a solid surface is treated with an aqueous gold salt solution and then irradiated with light.
本発明方法において用いられる金塩としては、塩化金酸
、塩化金酸ナトリウム、テトラシアノ合歓カリウムなど
の水溶性金塩があげられる。Examples of the gold salts used in the method of the present invention include water-soluble gold salts such as chloroauric acid, sodium chloroaurate, and potassium tetracyanoate.
本発明を実施するには、まず、目的とする固体物質を金
塩水溶液に浸漬してその表面に含塩を付与し、そのまま
乾燥するか、あるいは、水洗した後乾燥する。To carry out the present invention, first, a target solid substance is immersed in an aqueous gold salt solution to impart salt content to its surface, and then dried as is, or washed with water and then dried.
ここで：・冒いられる金塩水溶液中の金塩の濃度は、１
〜１００ ｍｍｏｌ／ｌの範囲で選ばれる。浸漬時間は
１０秒〜１０時間の範囲の中で選ばれるが、通常は１０
分間程度でよい、浸漬温度は０〜１００℃の範囲で選ば
れるが、通常は室温でよい、水溶液中の含塩の濃度が高
いほど、浸漬温度が高いほど、また、浸漬時間が長いほ
ど固体表面に移る金塩の呈が多くなり、光照射した後濃
色に着色する。Here:・The concentration of gold salt in the affected gold salt aqueous solution is 1
-100 mmol/l. The immersion time is selected within the range of 10 seconds to 10 hours, but usually 10
The immersion temperature is selected within the range of 0 to 100°C, but usually room temperature is sufficient.The higher the concentration of salt in the aqueous solution, the higher the immersion temperature, and the longer the immersion time, the more solid The amount of gold salt transferred to the surface increases and becomes darkly colored after irradiation with light.
手順としてはこの他、固体物質を金塩水溶液中に浸漬し
た後、長時間水中に浸漬するか、炭酸ナトリウムやアン
モニアなどの弱アルカリの水溶液中に浸漬してから水洗
し、乾燥してもよい、こうした処理により、特に固体物
質が絹の場合には、光に対する怒度が高められ着色が促
進される。Other procedures include immersing the solid substance in an aqueous gold salt solution and then immersing it in water for a long time, or immersing it in an aqueous solution of a weak alkali such as sodium carbonate or ammonia, washing it with water, and drying it. This treatment increases the sensitivity to light and promotes coloration, especially when the solid material is silk.
こうして得られた、表面に金塩が付与された固体物質に
光を照射すると、金塩が還元されて金微粒子が形成され
、その結果、固体物質が赤紫色ないし暗紫色に着色する
。照射する光としては、蛍光灯、タングステンランプ、
水銀ランプ、キセノンランプなどを光源とする人工の可
視・紫外光、および日光が利用される。光の照射に要す
る時間は光の強さによって違い、５分間〜１ケ月間の範
囲で適当に選ばれる。When the thus obtained solid material with gold salt applied to its surface is irradiated with light, the gold salt is reduced and gold fine particles are formed, and as a result, the solid material is colored reddish-purple or dark purple. The light to be irradiated includes fluorescent lamps, tungsten lamps,
Artificial visible and ultraviolet light from sources such as mercury lamps and xenon lamps, as well as sunlight, are used. The time required for light irradiation varies depending on the intensity of the light, and is appropriately selected from 5 minutes to 1 month.
本発明方法により着色される固体物質としては、金塩水
溶液中に浸漬することにより、その表面に金塩が付与さ
れるものであればよく、このような条件を満たすものと
して、たとえば、絹！ａ維、カチオン化処理をしたセル
ロース繊維、ゼラチンの塗布された固体物質があげられ
る。The solid material to be colored by the method of the present invention may be any material whose surface can be coated with gold salt by immersing it in an aqueous gold salt solution. Examples of solid materials that meet these conditions include silk! Examples include a-fiber, cationized cellulose fiber, and solid material coated with gelatin.
本発明方法によれば、固体表面を、一定の画像（模様）
に従って着色することが可能である。このためには、ま
ず固体物質を金塩水溶液中に浸漬して、その表面に金塩
を付与した後乾燥する。こうして得られた固体表面に、
適当な画像担体を用い陰画像の光を投影して部分的に金
微粒子を形成させる。最後に、写真用定着液などの中に
浸漬することにより未露光部分の金塩を溶かしだして除
去した後、水洗し乾燥して、露光部分のみが紫色に着色
した陽画像が得られる。According to the method of the present invention, a solid surface is formed into a certain image (pattern).
It is possible to color according to the following. For this purpose, a solid substance is first immersed in an aqueous gold salt solution, the gold salt is applied to the surface of the solid substance, and the solid substance is then dried. On the solid surface obtained in this way,
Using a suitable image carrier, a negative image of light is projected to partially form gold particles. Finally, the gold salt in the unexposed areas is dissolved and removed by immersion in a photographic fixer, followed by washing with water and drying to obtain a positive image in which only the exposed areas are colored purple.
においで雀しの水分の存在が不可欠であるが、これは通
常の空気中から補給される水分量で十分である。しかし
、たとえばシリカゲルや塩化カルシウムなどの乾燥剤の
共存するデシケータ−中などの絶乾状態では、金塩を付
与した固体表面に光が当たっても発色することはなく、
これを利用して、金塩を付与した固体物質と明所におい
て発色することなく長期間保存することができる。こう
して保存された固体物質は、空気中に取り出して光と照
射することにより、随時発色させることができる。Although the presence of water in the odor is essential for sparrows, the amount of water supplied from the normal air is sufficient. However, in an absolutely dry state, such as in a desiccator with a desiccant such as silica gel or calcium chloride, no color develops even when light hits the solid surface coated with gold salt.
Utilizing this, solid materials coated with gold salts can be stored for long periods of time in the light without developing color. The solid material thus stored can be colored at any time by being taken out into the air and irradiated with light.
実施例 次に、実施例により本発明をさらに詳しく説明する。Example Next, the present invention will be explained in more detail with reference to Examples.
実施例１
４ ｃｍＸ ４ ｃｍの１４匁付平織り絹布（日本規格
協会、染色堅ろう度試験用添付白布）を、室温下で２０
ｍｍｏｌ／ｌの塩化金酸水溶液中に１０分間浸漬した
後水洗し、次に、５％の炭酸ナトリウム水溶液中に１０
分間浸漬し、水洗し乾燥した。こうして得られた淡橙色
の絹布に１０日間ガラスを通した間接日光を照射して、
濃赤紫色に着色した絹布が得られた。Example 1 A 4 cm x 4 cm plain-woven silk cloth with 14 momme (Japanese Standards Association, attached white cloth for dyeing fastness test) was heated at room temperature for 20 min.
After immersing in mmol/l chloroauric acid aqueous solution for 10 minutes, washing with water, then dipping in 5% sodium carbonate aqueous solution for 10 min.
It was soaked for a minute, washed with water, and dried. The pale orange silk fabric thus obtained was irradiated with indirect sunlight through glass for 10 days.
A silk cloth colored deep reddish-purple was obtained.
実施例２
４ ｃｉＸ ４ ｃｍの綿布（日本規格協会、染色堅ろ
う度試験用添付白布）を、３−クロロ−２−ヒドロキシ
プロピルトリメチルアンモニウムクロライドおよび水酸
化ナトリウムを用いてカチオン化処理した後（加工技術
、２２巻３号１７５頁記載の方法による）、この綿布を
室温下で２０ ＋ａ＋ｉｏｌ／ｌの塩化金酸ナトリウム
水溶液中に１０分間浸漬した後水洗し、次に、５％のア
ンモニア水溶液中に１０分間浸漬し、水洗し乾燥した。Example 2 A 4 ciX 4 cm cotton cloth (Japanese Standards Association, attached white cloth for dye fastness test) was cationized using 3-chloro-2-hydroxypropyltrimethylammonium chloride and sodium hydroxide (processing technology). , Vol. 22, No. 3, p. 175), the cotton cloth was immersed in a 20 + a + iol/l sodium chloraurate aqueous solution for 10 minutes at room temperature, washed with water, and then soaked in a 5% ammonia aqueous solution for 10 min. It was soaked for a minute, washed with water, and dried.
こうして得られた淡黄色の絹布に１０日間ガラスを通し
た間接日光を照射して、黒灰色に着色した綿布が得られ
た。The pale yellow silk fabric thus obtained was irradiated with indirect sunlight through a glass for 10 days to obtain a black-gray colored cotton fabric.
実施例３
実施つ１、−６−用いえ、同七菱。ｆａ□を室温Ｔ１”
２０ｍ＋＋＋ｏｌ／］の塩化金酸ナトリウム水溶液中に
１０分間浸漬した後ひきあげ、手早く水洗し乾燥して淡
橙色絹布を得た。この絹布の表面に、模様の形の紙片を
貼り付け、これに４００Ｗ高圧水銀ランプを５ｃｍの距
離から１時間照射した１次に、紙片をはがした後、写真
用定着液（富士写真フィルム■製、フジフィックス〉中
に約１０分間浸漬して未露光部分の金塩を溶かしだし、
水洗し乾燥して、紙片の当たっていた部分だけが白色で
、残りの部分が暗紫色に着色した絹布が得られた。Example 3 Example 1, -6- No, same Shichibishi. fa□ to room temperature T1”
After being immersed in an aqueous solution of sodium chloraurate of 20 m+++ ol/] for 10 minutes, it was pulled up, quickly washed with water, and dried to obtain a pale orange silk cloth. A piece of paper in the shape of a pattern was pasted on the surface of this silk cloth, and it was irradiated with a 400W high-pressure mercury lamp from a distance of 5 cm for 1 hour.After peeling off the paper piece, a photographic fixer (Fuji Photo Film ■ The gold salt in the unexposed areas is dissolved by immersing it in FUJIFIX manufactured by Fuji Fix for about 10 minutes.
After washing with water and drying, a silk cloth was obtained in which only the part that had been touched by the paper strip was white, and the remaining part was colored dark purple.
実施例４
４ ｃｍＸ ４ ｃｍの印画紙（富士写真フィルム■製
、フジプロＷＰ）を、未露光、未現像のまま写真用定着
液（フジフィックス）中に約１０分間浸漬して臭化銀を
除去した後、水洗し乾燥した。この印画紙登、室温下で
２０１ｏｌ／ｌの塩化金酸ナトリウム水溶液中に１０分
間浸漬した後１手早く水洗し乾燥した。こうして得られ
た淡黄色の印画紙にモノクロ陰画フィルムを密着させて
かぶせ、これに１時間晴天下の直射日光を照射した後、
写真用定着／ｌ！（フジフィックス）中に約１０分間浸
漬して未露光部分の金塩を溶がしだし、水洗し乾燥して
、紫色の陽画を持つ印画紙が得られた。Example 4 A 4 cm x 4 cm piece of photographic paper (manufactured by Fuji Photo Film ■, Fuji Pro WP) was immersed in a photographic fixer (Fujifix) for about 10 minutes while unexposed and undeveloped to remove silver bromide. After that, it was washed with water and dried. This photographic paper was immersed for 10 minutes in a 201 ol/l sodium chloraurate aqueous solution at room temperature, then quickly washed with water and dried. The pale yellow photographic paper thus obtained was closely covered with a monochrome negative film, and after being exposed to direct sunlight under clear skies for one hour,
Photographic fixer/l! (Fujifix) for about 10 minutes to dissolve the gold salt in the unexposed areas, washed with water and dried to obtain photographic paper with a purple positive image.
本発明方法により着色した固体物質は、いずれも美しい
紫色を呈し、この色は長期間明所に放置しても変退色す
ることがない、また、本発明方法によれば、陰画を通し
て光照射することにより、複雑な模様を描いたり写真画
像を焼き付けたりすることもできる。しかも、こうして
着色した固体物質を用いた製品には、希少で高価な金を
用いて着色されたという価値が加わるので、より高級な
イメージが付与される効果がある。All of the solid substances colored by the method of the present invention exhibit a beautiful purple color, and this color does not change or fade even if left in a bright place for a long period of time. This allows you to draw complex patterns or print photographic images. Furthermore, products using colored solid substances have the added value of being colored using rare and expensive gold, giving them a more luxurious image.
Claims (2)
て発色させることを特徴とする着色方法。(1) A coloring method characterized by treating a solid surface with an aqueous gold salt solution and then irradiating it with light to develop color.
通して光を照射してその一部分を発色させ、次いで、未
露光部分の金塩を除去することを特徴とする画像形成方
法。(2) An image forming method characterized by treating the solid surface with an aqueous gold salt solution, irradiating light through the image carrier to develop color in a portion thereof, and then removing the gold salt in the unexposed portion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63302095A JPH0615743B2 (en) | 1988-11-29 | 1988-11-29 | Gold colored image forming method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63302095A JPH0615743B2 (en) | 1988-11-29 | 1988-11-29 | Gold colored image forming method |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH02154064A true JPH02154064A (en) | 1990-06-13 |
| JPH0615743B2 JPH0615743B2 (en) | 1994-03-02 |
Family
ID=17904867
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63302095A Expired - Lifetime JPH0615743B2 (en) | 1988-11-29 | 1988-11-29 | Gold colored image forming method |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH0615743B2 (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4930038A (en) * | 1972-07-18 | 1974-03-18 | ||
| JPS62133076A (en) * | 1985-12-03 | 1987-06-16 | Adachi Shin Sangyo Kk | Production of metal plated inorganic substance |
| JPS63192875A (en) * | 1987-02-06 | 1988-08-10 | Electroplating Eng Of Japan Co | Production of metal coated film |
| JPS63192874A (en) * | 1987-02-06 | 1988-08-10 | Electroplating Eng Of Japan Co | Production of metal coated film |
-
1988
- 1988-11-29 JP JP63302095A patent/JPH0615743B2/en not_active Expired - Lifetime
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4930038A (en) * | 1972-07-18 | 1974-03-18 | ||
| JPS62133076A (en) * | 1985-12-03 | 1987-06-16 | Adachi Shin Sangyo Kk | Production of metal plated inorganic substance |
| JPS63192875A (en) * | 1987-02-06 | 1988-08-10 | Electroplating Eng Of Japan Co | Production of metal coated film |
| JPS63192874A (en) * | 1987-02-06 | 1988-08-10 | Electroplating Eng Of Japan Co | Production of metal coated film |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0615743B2 (en) | 1994-03-02 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| US2895892A (en) | Photochemical process | |
| JPH02154064A (en) | Coloring by gold salt | |
| US1962307A (en) | Photographically sensitive element | |
| US2750292A (en) | Process for producing colored photographic contrasts | |
| US2647057A (en) | Protecting color pictures exposed to high humidities against fading and staining | |
| US1972323A (en) | Photographically printed fibrous product and method of producing the same | |
| US2623821A (en) | Photographic development of color on textile and other materials | |
| US2171609A (en) | Toning photographic prints | |
| US1582050A (en) | Photographic print-out paper and prints made therefrom | |
| US4262074A (en) | Photographic copy method and materials | |
| Abney et al. | Platinotype | |
| US1623123A (en) | Process for producing colored photographs | |
| US3259494A (en) | Exposure, heat development and fixing of photosensitive mercurous oxalate and silvercompositions | |
| JPS59191035A (en) | Method for simply processing photosensitive silver salt material | |
| US1305962A (en) | crabtree | |
| US2199580A (en) | Photographic printing | |
| US1843822A (en) | Photographic printing process | |
| US3753717A (en) | Photographic material | |
| JPH02154063A (en) | Coloring by noble metal salt | |
| SU781748A1 (en) | Photographic material | |
| SU1099308A1 (en) | Method of producing photographic picture | |
| US3284203A (en) | Direct positive photographic materials | |
| SU38568A1 (en) | The method of obtaining photosensitive layers using diazoanhydrides | |
| GB222523A (en) | Direct colour photography | |
| US1610788A (en) | Production of photographs on paper, parchment, and the like |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| EXPY | Cancellation because of completion of term |