JPH02154063A - Coloring by noble metal salt - Google Patents
Coloring by noble metal saltInfo
- Publication number
- JPH02154063A JPH02154063A JP30209488A JP30209488A JPH02154063A JP H02154063 A JPH02154063 A JP H02154063A JP 30209488 A JP30209488 A JP 30209488A JP 30209488 A JP30209488 A JP 30209488A JP H02154063 A JPH02154063 A JP H02154063A
- Authority
- JP
- Japan
- Prior art keywords
- noble metal
- metal salt
- treated
- color
- heat
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 229910000510 noble metal Inorganic materials 0.000 title claims abstract description 26
- 238000004040 coloring Methods 0.000 title claims abstract description 9
- 150000003839 salts Chemical class 0.000 title abstract description 21
- 239000007787 solid Substances 0.000 claims abstract description 17
- 238000000034 method Methods 0.000 claims description 15
- 238000010438 heat treatment Methods 0.000 claims description 13
- 239000012266 salt solution Substances 0.000 claims description 4
- 239000007864 aqueous solution Substances 0.000 abstract description 10
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 abstract description 8
- 239000002253 acid Substances 0.000 abstract description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 abstract description 4
- 229910001961 silver nitrate Inorganic materials 0.000 abstract description 4
- 229910052708 sodium Inorganic materials 0.000 abstract description 4
- 239000011734 sodium Substances 0.000 abstract description 4
- 239000000835 fiber Substances 0.000 abstract description 3
- PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 abstract description 2
- 239000002184 metal Substances 0.000 abstract description 2
- 229920003043 Cellulose fiber Polymers 0.000 abstract 1
- 238000005562 fading Methods 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- 229920000742 Cotton Polymers 0.000 description 8
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 6
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 6
- 239000000126 substance Substances 0.000 description 6
- 229910052737 gold Inorganic materials 0.000 description 5
- 239000010931 gold Substances 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000003292 glue Substances 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000010419 fine particle Substances 0.000 description 3
- 238000007654 immersion Methods 0.000 description 3
- 229910052742 iron Inorganic materials 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000003825 pressing Methods 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 150000002343 gold Chemical class 0.000 description 2
- 239000010970 precious metal Substances 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 239000011343 solid material Substances 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- VFKZECOCJCGZQK-UHFFFAOYSA-M 3-hydroxypropyl(trimethyl)azanium;chloride Chemical compound [Cl-].C[N+](C)(C)CCCO VFKZECOCJCGZQK-UHFFFAOYSA-M 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 235000010724 Wisteria floribunda Nutrition 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004043 dyeing Methods 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 150000002940 palladium Chemical class 0.000 description 1
- 150000003057 platinum Chemical class 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003283 rhodium Chemical class 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- SDKPSXWGRWWLKR-UHFFFAOYSA-M sodium;9,10-dioxoanthracene-1-sulfonate Chemical compound [Na+].O=C1C2=CC=CC=C2C(=O)C2=C1C=CC=C2S(=O)(=O)[O-] SDKPSXWGRWWLKR-UHFFFAOYSA-M 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Landscapes
- Chemical Or Physical Treatment Of Fibers (AREA)
- Decoration Of Textiles (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、貴金属塩水溶液処理および加熱処理を利用し
た、固体表面を着色するのに有用な方法に関するもので
ある。DETAILED DESCRIPTION OF THE INVENTION [Industrial Application Field] The present invention relates to a method useful for coloring a solid surface using noble metal salt aqueous solution treatment and heat treatment.
があり、たとえば、第一錫塩で還元して得られる金の微
粒子はｒカシウスの＃Ｊと呼ばれ、陶磁器やガラスの着
色に利用されている。For example, fine gold particles obtained by reduction with stannous salts are called Cassius #J and are used to color ceramics and glass.
発明者らは先に、金微粒子を水の中に一様に分散させた
金ヒドロシルを用い、これに含まれる金コロイドを吸着
させることにより絹布などの繊維成形物を紫系統の色に
染色する方法を見出している（特開昭６２−２９９５８
７号公報）。The inventors first used gold hydrosil, in which fine gold particles were uniformly dispersed in water, to dye fiber molded products such as silk cloth in a purple color by adsorbing the gold colloid contained in this gold hydrosil. found a method (Japanese Patent Application Laid-Open No. 62-29958
Publication No. 7).
しかし、この方法では、金コロイドの吸着量が増加する
につれて全微粒子間の凝集がひどくなり、その結果、濃
い色にはならず黒味のかかった冴えない色となる。また
、目的物の表面にのみ金微粒子が分布しているので、特
に湿潤状態では摩擦により脱落し易い６ さらに、この
方法では、特定のパターンに従って着色することが難し
い１本発明は、４色にすることが難しく、また摩擦堅ろ
う度に劣るという従来法の欠点を解決し、貴金属を用い
一定のパターン形成が容易な新しい着色方法を提供する
ものである。However, in this method, as the amount of adsorbed gold colloid increases, the aggregation among all the fine particles becomes severe, and as a result, the color does not become deep, but becomes a dull color with a blackish tint. In addition, since the gold particles are distributed only on the surface of the object, they are likely to fall off due to friction, especially in wet conditions.6 Furthermore, with this method, it is difficult to color according to a specific pattern1. The present invention solves the drawbacks of the conventional method of being difficult to color and having poor friction fastness, and provides a new coloring method that uses precious metals and makes it easy to form a certain pattern.
本発明者らは、責合ｍ３用い、濃色に着色することがで
き、しかも摩擦に対する堅ろう度の優れた着色方法を求
めて鋭意研究を重ねた結果、固体表面に付与された貴金
属塩が、加熱により貴金属微粒子に変換されて発色する
ことと見出し、本発明をなすに至った。The inventors of the present invention have conducted extensive research in search of a coloring method that can be colored in a deep color using 300g m3 and has excellent fastness against friction.As a result, the noble metal salt applied to the solid surface is It was discovered that when heated, it is converted into noble metal fine particles and develops color, and the present invention was completed.
すなわち、本発明は、固体表面を責合民塩水溶液で処理
した後、加熱処理すること′５：特徴とする着色方法を
提供するものである。That is, the present invention provides a coloring method characterized in that the solid surface is treated with an aqueous salt solution and then subjected to heat treatment.
本発明方法において用いられる貴金属塩としては、塩化
金酸、塩化金酸ナトリウム、硝酸銀、塩化パラジウム、
塩化白金酸、塩化ロジウム酸ナトリウムなどの水溶性貴
金属塩があげられる。The noble metal salts used in the method of the present invention include chloroauric acid, sodium chloroaurate, silver nitrate, palladium chloride,
Examples include water-soluble noble metal salts such as chloroplatinic acid and sodium chloride rhodate.
本発明を実施するには、まず、固体物質を貴金属塩水溶
液に浸漬してその表面に貴金属塩を付与し、そのまま乾
燥するか、あるいは、水洗した後乾燥する。To carry out the present invention, first, a solid substance is immersed in an aqueous solution of a noble metal salt to apply a noble metal salt to its surface, and then dried as is, or washed with water and then dried.
ここで論、シられる水溶液中の貴金属塩の濃度は。The concentration of the noble metal salt in the aqueous solution discussed here is:
１〜１００ ｍｍｏｌ／Ｌ浸漬時間は１０秒〜１０時間
の範囲の中で這ばれる。浸漬温度は０〜１００°Ｃの範
囲で選ばれるが、通常は室温でよい、水溶液中の貴金属
塩の濃度が高いほど、浸漬温度が高いほど、また、浸漬
時間が長いほど固体表面に移る責合５塩の量が多くなり
、加熱処理した後の色が濃色になる。The immersion time for 1 to 100 mmol/L is within the range of 10 seconds to 10 hours. The immersion temperature is selected within the range of 0 to 100°C, but room temperature is usually sufficient. The amount of salt increases and the color becomes darker after heat treatment.
固体物質をこのように貴金属塩水溶液中に浸漬した後、
アルカリ処理をしてもよい、アルカリ処理には、炭酸ナ
トリウムやアンモニアなどの弱アルカリ水溶液が用いら
れる。After immersing the solid substance in the noble metal salt aqueous solution in this way,
Alkali treatment may be performed. For alkaline treatment, a weak alkaline aqueous solution such as sodium carbonate or ammonia is used.
貴金属塩を付与した固体物質の加熱処理は、恒温乾燥器
、ホットプレート、電子レンジ、サーマルヘッド、加熱
用ビームなどを用いて行う、加熱温度および加熱時間は
、貴金属塩の種類によって異なるが、通常、１４０’Ｃ
以上でしかも固体物質が変質しない範囲の組合せの中か
ら選ばれる。Heat treatment of solid substances to which noble metal salts have been added is performed using a constant temperature dryer, hot plate, microwave oven, thermal head, heating beam, etc. The heating temperature and heating time vary depending on the type of noble metal salt, but usually , 140'C
The combination is selected from among the above combinations within a range in which the solid substance does not change in quality.
ある一定のパターンに従って着色させたいときは、固体
表面のその部分だけに高温の金属片などを押し当てるか
、あるいは、サーマルヘッドや各種の加熱用ビームを走
査させることによって加熱する。こうして、加熱された
部分の貴金属塩だけが貴金属微粒子に変換され、その結
果、固体表面が望むパターンに従って着色される。If you want to color the solid surface according to a certain pattern, you can heat it by pressing a hot metal piece or the like against that part of the solid surface, or by scanning it with a thermal head or various heating beams. In this way, only the noble metal salt in the heated portion is converted into noble metal fine particles, so that the solid surface is colored according to the desired pattern.
このあと、適宜、非加熱部分に残された貴金属塩を、写
真用定着液などの中に浸漬することにより溶かし出して
除去してもよい。Thereafter, the noble metal salt remaining in the non-heated portion may be dissolved and removed by immersion in a photographic fixer or the like, as appropriate.
加熱後の着色の色は、用いる貴金属塩の種類により異な
り、たとえば、金塩の場合は紫色系統の色、銀塩では黄
色系統の色、パラジウム塩、白金塩、ロジウム塩などで
は褐色系統の色となる。The color after heating varies depending on the type of noble metal salt used; for example, gold salts are purple in color, silver salts are yellow in color, palladium salts, platinum salts, rhodium salts, etc. are brown in color. becomes.
本発明方法では、固体表面への貴金属塩の付与を、貴金
属塩水溶液中に浸漬する代わりに、貴金属塩を溶解した
糊を固体表面に塗布して行うこともできる。これによっ
ても、固体物質表面の特定の部分だけを着色したり模様
を描くことができる。In the method of the present invention, the noble metal salt can be applied to the solid surface by applying a paste in which the noble metal salt is dissolved, instead of immersing the solid surface in an aqueous noble metal salt solution. This also makes it possible to color or draw a pattern on only a specific part of the surface of a solid material.
本発明方法により着色される固体物質としては、貴金属
塩水溶液中に浸漬することにより、その表実施例
次に、実施例により本発明をさらに詳しく説明する。The solid material to be colored by the method of the present invention is prepared by immersing it in an aqueous solution of a noble metal salt.
実施例１
４ ｃｍＸ ４ ｃｍの白色平織り綿布（日本規格協会
、染色堅ろう度試験用添付白布）を、３−クロロ−２−
ヒドロキシプロピルトリメチルアンモニウムクロライド
および水酸化ナトリウムを用いて、加工技術、２２巻３
号１７５頁記載の方法によりカチオン化処理した。この
綿布を、室温下で２０鳳ｍｏｌ／ｌの塩化金酸ナトリウ
ム水溶液中に１０分間浸漬した後水洗し、さらに、５％
の炭酸ナトリウム水溶液中に１０分間浸漬し、水洗後乾
燥して黄色の綿布を得た。この綿布の半分の部分に、表
面温度が１８０°Ｃのアイロンを１分間押し当てて加熱
し１次に、写真用定着液（富士写真フィルム■製、フジ
フィックス）中に約１０分間浸漬して、加熱しなかった
部分の金塩を溶かしだし、水洗し乾燥して、加熱した半
分が濃い紫色に着色し残りの部分が白色の綿布を得た。Example 1 A 4 cm x 4 cm white plain-woven cotton cloth (Japanese Standards Association, attached white cloth for dyeing fastness test) was coated with 3-chloro-2-
Using hydroxypropyltrimethylammonium chloride and sodium hydroxide, Processing Technology, Vol. 22, 3.
Cationization treatment was carried out by the method described on page 175 of the issue. This cotton cloth was immersed in a 20 mol/l sodium chloraurate aqueous solution for 10 minutes at room temperature, washed with water, and then 5%
The cloth was immersed in an aqueous sodium carbonate solution for 10 minutes, washed with water, and dried to obtain a yellow cotton cloth. Half of this cotton cloth was heated by pressing an iron with a surface temperature of 180°C for 1 minute, and then immersed in a photographic fixer (manufactured by Fuji Photo Film ■, Fujifix) for about 10 minutes. The gold salt in the unheated part was dissolved, washed with water, and dried to obtain a cotton cloth in which the heated half was colored deep purple and the remaining part was white.
実施例２
直径７ｃｍの１紙（東洋Ｐ紙■製、 Ｎｏ、２）を、
室温下で２０ ｍｍｏｌ／Ｉの硝酸銀水溶液に１０分間
浸漬した後、水洗し乾燥した。この１紙の全面に、表面
温度が１８０℃のアイロンを１分間押し当てて加熱し、
黄色に着色した１紙を得た。Example 2 A piece of paper (manufactured by Toyo P Paper ■, No. 2) with a diameter of 7 cm was
After being immersed in a 20 mmol/I silver nitrate aqueous solution for 10 minutes at room temperature, it was washed with water and dried. Heat an iron with a surface temperature of 180℃ for 1 minute on the entire surface of this piece of paper.
A piece of paper colored yellow was obtained.
実施例３
塩化パラジウムな２０モル倍量のアンモニアと共に２０
ｔａ＋ｏｌ／Ｉの濃度で水に溶解し、これに直径７ｃ
ｍのＦ紙（東洋ｒ紙ｔｍ製、Ｎｏ、 ２ ＞を、室温下
で１０分間浸漬した。これを水洗し乾燥した後、表面温
度が１８０℃のアイロンを１分間押し当てて加熱し、褐
色に着色した１紙を得た。Example 3 Palladium chloride with 20 molar amounts of ammonia
Dissolved in water at a concentration of ta+ol/I, and added a diameter 7c
F paper (manufactured by Toyo R Paper TM, No. 2) was immersed for 10 minutes at room temperature. After washing and drying it with water, it was heated by pressing an iron with a surface temperature of 180°C for 1 minute to make it brown. A piece of colored paper was obtained.
実施例４ 硝酸銀と１００倍重量のでんぷん糊（ヤマト■製。Example 4 Silver nitrate and 100 times the weight of starch glue (manufactured by Yamato ■).
ヤマト糊）に溶解して得た糊を用い、４ｃｍ×４Ｃ１ｕ
の白色平織り綿布（日本規格協会、染色堅ろう度試験用
添付白布）に一定の模様を描いた。１０分後によく水洗
して糊を除去し乾燥した０次に、この綿布３１８０°Ｃ
の恒温乾燥話中で１分間加熱し、黄色の模様のある白色
の綿布が得られた。Using glue obtained by dissolving in Yamato glue), 4cm x 4C1u
A certain pattern was drawn on a white plain-woven cotton cloth (Japanese Standards Association, attached white cloth for dye fastness test). After 10 minutes, the cotton cloth was thoroughly washed with water to remove the glue and dried at 3180°C.
After heating for 1 minute in a constant temperature drying mode, a white cotton cloth with a yellow pattern was obtained.
本発明方法により得られる着色した固体物質は、いずれ
も格調高い色を呈し、この色は摩擦によって脱落するこ
とがなく、長期間明所に放置しても変色や退色すること
がない、また、本発明方法によれば、部分的に加熱する
ことにより一定のパターンに従った着色ができる。しか
も、着色後の固体物質を用いた製品は、希少な貴金属を
用いて着色されたという価値が加わり、高級品のイメー
ジが付与される効果がある。All of the colored solid substances obtained by the method of the present invention exhibit a high-quality color, and this color does not fall off due to friction, and does not discolor or fade even if left in a bright place for a long period of time. According to the method of the present invention, coloring according to a certain pattern can be achieved by heating the parts locally. Moreover, products using solid substances after coloring have the added value of being colored using rare precious metals, and have the effect of giving the product an image of a luxury product.
Claims (2)
て発色させることを特徴とする着色方法。(1) A coloring method characterized by treating the solid surface with an aqueous noble metal salt solution and then heating it to develop color.
を一定のパターンに従つて加熱して発色させることを特
徴とするパターン形成方法。(2) A pattern forming method characterized by treating a solid surface with an aqueous noble metal salt solution and then heating the surface according to a certain pattern to develop color.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30209488A JPH02154063A (en) | 1988-11-29 | 1988-11-29 | Coloring by noble metal salt |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP30209488A JPH02154063A (en) | 1988-11-29 | 1988-11-29 | Coloring by noble metal salt |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02154063A true JPH02154063A (en) | 1990-06-13 |
Family
ID=17904855
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP30209488A Pending JPH02154063A (en) | 1988-11-29 | 1988-11-29 | Coloring by noble metal salt |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02154063A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010047866A (en) * | 2008-08-21 | 2010-03-04 | Yamanashi Prefecture | Silver-dyeing method for animal fiber, method of silver-dyeing control using aqueous solution of 2-mercaptoethanesulfonic acid salt, and animal fiber applied with these methods |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4930038A (en) * | 1972-07-18 | 1974-03-18 | ||
| JPS5026729A (en) * | 1973-07-11 | 1975-03-19 | ||
| JPS51145438A (en) * | 1975-03-01 | 1976-12-14 | Shoei Chemical Ind Co | Method of coating with metal |
| JPS5994676A (en) * | 1982-11-20 | 1984-05-31 | 中越パルプ工業株式会社 | Conductive cellulose material and production thereof |
-
1988
- 1988-11-29 JP JP30209488A patent/JPH02154063A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS4930038A (en) * | 1972-07-18 | 1974-03-18 | ||
| JPS5026729A (en) * | 1973-07-11 | 1975-03-19 | ||
| JPS51145438A (en) * | 1975-03-01 | 1976-12-14 | Shoei Chemical Ind Co | Method of coating with metal |
| JPS5994676A (en) * | 1982-11-20 | 1984-05-31 | 中越パルプ工業株式会社 | Conductive cellulose material and production thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2010047866A (en) * | 2008-08-21 | 2010-03-04 | Yamanashi Prefecture | Silver-dyeing method for animal fiber, method of silver-dyeing control using aqueous solution of 2-mercaptoethanesulfonic acid salt, and animal fiber applied with these methods |
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