JPH02142653A - Method for continuously casting steel - Google Patents

Method for continuously casting steel

Info

Publication number
JPH02142653A
JPH02142653A JP29616188A JP29616188A JPH02142653A JP H02142653 A JPH02142653 A JP H02142653A JP 29616188 A JP29616188 A JP 29616188A JP 29616188 A JP29616188 A JP 29616188A JP H02142653 A JPH02142653 A JP H02142653A
Authority
JP
Japan
Prior art keywords
tundish
powder
molten steel
surface coating
steel
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP29616188A
Other languages
Japanese (ja)
Inventor
Hisao Yamazaki
久生 山崎
Ryoji Yoda
依田 亮二
Kenji Saito
健志 斎藤
Tsutomu Nozaki
野崎 努
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP29616188A priority Critical patent/JPH02142653A/en
Publication of JPH02142653A publication Critical patent/JPH02142653A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D11/00Continuous casting of metals, i.e. casting in indefinite lengths
    • B22D11/10Supplying or treating molten metal
    • B22D11/11Treating the molten metal
    • B22D11/111Treating the molten metal by using protecting powders

Abstract

PURPOSE:To reduce erosion of tundish refractory and to produce a cast slab having little defect in a product by covering molten steel surface in the tundish with the specific composition of molten steel surface coating powder and surrounding the outer circumference of the molten steel surface coating powder with the specific composition of tundish protecting powder. CONSTITUTION:At the time of continuously casting the steel, the molten steel surface in the tundish is coasted with the molten steel surface coating powder 5 containing 40-60wt.% CaO, 20-40% Al2O3, 0.5-5.0% MgO, 0.5-2.0% C, 0.1-5.0% Na2O, 1-10% CaF2 and regulating <=7.0% SiO2. Then, the powder 5 is surrounded with the tundish protecting powder 6 containing 30-40% CaO, 30-40% SiO2, <=20% Al2O3, <=10% MgO, and by preventing contact of the molten steel covering powder 5 with the tundish 8, the tundish 8 is protected.

Description

【発明の詳細な説明】 〈産業上の利用分野〉 本発明は、鋼を連続鋳造する際に、タンディツシュ内に
添加するパウダによるタンディツシュの溶損を減少し、
アルミナ介在物起因の製品欠陥をなくした鋼の連続鋳造
方法に関するものである。
[Detailed Description of the Invention] <Industrial Application Field> The present invention reduces melting damage of the tundish due to powder added to the tundish during continuous casting of steel,
This invention relates to a continuous steel casting method that eliminates product defects caused by alumina inclusions.

〈従来の技術〉 溶鋼を連続鋳造する際に、取鍋の溶鋼は−Hタンディッ
シュに注入され、その後鋳型内に注入される。この取鍋
と鋳型の中間に位置するタンディツシュにおいてはタン
ディツシュ内溶鋼の温度低下防止、タンディツシュ内溶
鋼中に浮遊する介在物の吸着を目的として、通常、溶鋼
表面にパウダを添加する。従来の連続鋳造用クンデイツ
シュに添加されるパウダとし°ζはCaOを40wt%
(以下%と略す)程度含有し、塩基度0.8〜1.3に
調整したものが一般的である(特開昭51−16217
号参照)。
<Prior Art> When continuously casting molten steel, molten steel in a ladle is poured into a -H tundish and then into a mold. In the tundish located between the ladle and the mold, powder is usually added to the surface of the molten steel for the purpose of preventing the temperature of the molten steel in the tundish from decreasing and adsorbing inclusions floating in the molten steel in the tundish. The powder added to conventional continuous casting kundish is 40wt% CaO.
(hereinafter abbreviated as %), and the basicity is adjusted to 0.8 to 1.3 (Japanese Patent Application Laid-open No. 16217-1983).
(see issue).

しかしながら、この様なパウダを^!含有量の高い溶鋼
に使用する場合、パウダ中のSingが多いため、(1
)式の反応によって鋼中に7V80ユを生成させる。
However, powder like this ^! When using molten steel with a high content, since there is a large amount of Sing in the powder, (1
) 7V80U is generated in steel by the reaction of the formula.

/V+5iOt→A7tOs +Si        
 (1)一方、先に本出願人が促案じた特開昭57−1
84563号公報の発明ではCaOを40〜60%含有
し、510□を7%以下に調整し、低融点化、流動性低
下を目的にCaFtを含有したパウダをクンデイツシュ
内に添加した場合、(1)式の反応は、5i0.の景が
少ないため抑制されるが、タンディツシュで長時間使用
した場合パウダ中のCaF□によってタンディツシュ耐
火物が過度に溶…されるという問題がある。
/V+5iOt→A7tOs +Si
(1) On the other hand, Japanese Patent Application Laid-Open No. 57-1 proposed by the applicant earlier
In the invention of Publication No. 84563, when powder containing CaO is adjusted to 40 to 60%, 510□ is adjusted to 7% or less, and powder containing CaFt is added to the kundish for the purpose of lowering the melting point and reducing fluidity, (1 ) reaction is 5i0. However, when used for a long time in a tundish, the problem is that the tundish refractory is excessively melted by CaF□ in the powder.

〈発明が解決しようとする課題〉 本発明は、以上の問題に鑑みてなされたもので、タンデ
ィツシュの内壁耐火物を溶tSすることなく、しかもス
ラブ表皮下2〜10m5のアルミナクラスクーの個数を
低減できる鋼の連続鋳造方法を提供するためになされた
ものである。
<Problems to be Solved by the Invention> The present invention has been made in view of the above problems, and it is possible to reduce the number of alumina cracks located 2 to 10 m5 below the surface of the slab without melting the refractories on the inner wall of the tundish. This was done in order to provide a continuous steel casting method that can reduce the amount of steel.

〈課題を解決するための手段〉 本発明は、前述した本発明の出願人の湯面被覆用パウダ
をそのまま使用するが、この湯面被覆パウダがタンディ
ツシュと直接接触しないように、タンディツシュをit
ハするCaFtを含有しないタンディツシュ保護パウダ
で湯面被覆パウダ外周を囲うことにより、クンデイツシ
ュを保護しようとするものである。
<Means for Solving the Problems> In the present invention, the above-mentioned hot water surface coating powder of the applicant of the present invention is used as is, but the tundish is made to
The purpose is to protect the kundish by surrounding the outer periphery of the hot water surface coating powder with a powder that does not contain CaFt.

本発明は、■鋼を連続鋳造する際に、クンデイツシュ湯
面にCaO: 40〜60w t%(以下%と略す)。
In the present invention, (1) CaO: 40 to 60 wt% (hereinafter abbreviated as %) is added to the kundish hot water surface when continuously casting steel.

Altos : 20〜40%、  MgO:  0.
5〜5.0%、C:0.5〜2.0%、 NatO: 
 0.1〜5.0%、 CIIF! : 1〜10%を
含有し、かつSingを7.0%以下に規制した湯面被
覆パウダを被覆する鋼の連続ltt造方法において、前
記湯面被覆パウダの外周をCaO: 30〜40%。
Altos: 20-40%, MgO: 0.
5-5.0%, C: 0.5-2.0%, NatO:
0.1-5.0%, CIIF! : In a continuous LTT manufacturing method for steel that covers a hot water surface coating powder containing CaO of 1 to 10% and Sing regulated to 7.0% or less, the outer periphery of the hot water surface coating powder contains CaO: 30 to 40%.

5iOt : 30〜40%、 u、os  :20%
以下、  MgO: 10%以下を含有するクンデイツ
シュ保護パウダで囲い、前記湯面被覆パウダとタンディ
ツシュとの接触を防止しタンディツシュを保護すること
を特徴とする鋼の連続鋳造方法であり、かつ■湯面被覆
パウダに対するタンディツシュ保護パウダの重量比を5
〜20%とすることを特徴とする前項l記載の鋼の連続
鋳造方法である。
5iOt: 30-40%, u, os: 20%
Hereinafter, it is a continuous casting method for steel characterized by protecting the tundish by surrounding it with a tundish protection powder containing 10% or less of MgO to prevent contact between the tundish and the molten metal surface coating powder, and The weight ratio of the tandish protection powder to the coating powder was 5.
20%.

く作 用〉 本発明は、ノズル閉塞を有効に防止すると共に、非金属
介在物の少ない鋳片を得ることができる本出願人が出願
した湯面被覆パウダ(特開昭57−184563号参照
)を用いて、ノズル閉塞を防止し、溶鋼中にN t O
s介在物が増加することを防止する。
Function> The present invention is directed to a hot water surface coating powder (see JP-A No. 57-184563) filed by the present applicant, which can effectively prevent nozzle clogging and produce slabs with less non-metallic inclusions. is used to prevent nozzle clogging and eliminate N t O in molten steel.
s Prevent inclusions from increasing.

一方、タンディツシュ溶損の原因であるCaFzを全く
含有せず、溶融点が1200〜1300°C程度に保つ
ようなCan、 Sing共に30〜40%であり、N
2O3介在物の吸収能を悪化さゼないためAhOsの上
限を20%と少なくし、かつ流動性などを考慮しパウダ
が硬(ならないようにMgOの上限を10%′としたク
ンデイツシュ保護パウダを前記湯面被覆パウダの外周を
囲うようにして用いた。従ってクンデイツシュ保護パウ
ダによってCaFtを含む湯面被覆パウダがクンデイツ
シュと直接接触するのを防止でき、タンディツシュ耐火
物のf8 tfiを減少することができる。
On the other hand, both Can and Sing contain 30 to 40%, which does not contain any CaFz, which causes tundish melting damage, and maintains the melting point at about 1200 to 1300 °C, and N
The upper limit of AhOs was set to 20% to avoid deterioration of the absorption capacity of 2O3 inclusions, and the upper limit of MgO was set to 10% to prevent the powder from becoming hard, considering fluidity. It was used so as to surround the outer periphery of the hot water surface coating powder.Therefore, the kundish protective powder can prevent the hot water surface covering powder containing CaFt from coming into direct contact with the kundish, and the f8 tfi of the tundish refractory can be reduced.

タンディツシュ保護パウダは、CaFmを含有する湯面
被覆パウダがタンディツシュと接触するのを防止するた
めのものでありできるだけ少ない方がよいが、以下の研
究結果から本発明では湯面被覆パウダに対してほぼ5〜
20%のm1ft比の範囲で目的を達成することができ
るとの知見を得たので、この範囲の重量比とした。
The purpose of the tandish protection powder is to prevent the hot water surface coating powder containing CaFm from coming into contact with the tundish, and it is better to minimize the amount of the tundish protection powder. 5~
Since it was found that the objective could be achieved within a m/ft ratio of 20%, the weight ratio was set within this range.

すなわち、湯面被覆パウダと保護パウダの適切な重量比
を調査するため、高塩基度の湯面被覆パウダに対する低
塩基度のタンディツシュ保護パウダの重量割合を種々変
化させ、各重量割合におけるタンディツシュ内溶鋼サン
プルのアルミナ介在物数をプロットしたところ第2図に
示すような結果を得た。
That is, in order to investigate the appropriate weight ratio of the hot water surface coating powder and the protective powder, the weight ratio of the low basicity tundish protection powder to the high basicity hot water surface coating powder was varied, and the molten steel in the tundish at each weight ratio was When the number of alumina inclusions in the sample was plotted, the results shown in FIG. 2 were obtained.

この第2図から湯面被覆パウダに対するクンデイツシュ
保護パウダの適正な範囲はほぼ5〜20%であることが
わかる。ここで下限をほぼ5.0%としたのは、はぼ5
.0%未満だと湯面被覆パウダとタンディツシュ保護パ
ウダが混合したとき、湯面被覆パウダのCaFtがタン
ディツシュと接触する恐れがあるためである。
From FIG. 2, it can be seen that the appropriate range of the kundish protection powder to the hot water surface coating powder is about 5 to 20%. Here, the lower limit was set at approximately 5.0% because Habo5
.. This is because if it is less than 0%, when the hot water surface coating powder and the tundish protection powder are mixed, there is a possibility that CaFt in the hot water surface coating powder will come into contact with the tundish.

なお、第2図における高塩基度の湯面被覆パウダ5の組
成は、CaO+ 66、1%、 AhOs  : 15
%、 Mgo : 5.2%、C:1.0%、  Na
、0:  3.2%、  Cart : 4゜0%、 
5(OH:  5.5%であり、低塩基度のタンディツ
シュ保護パウダ6の組成は、CaO: 37.1%、 
SiO□: 39.2%、NtOs : 2.4%、 
hgo: 3.5%、その他: 17.8%である。
The composition of the high basicity hot water surface coating powder 5 in FIG. 2 is: CaO+ 66.1%, AhOs: 15
%, Mgo: 5.2%, C: 1.0%, Na
, 0: 3.2%, Cart: 4゜0%,
5 (OH: 5.5%, low basicity tandish protection powder 6 has the following composition: CaO: 37.1%,
SiO□: 39.2%, NtOs: 2.4%,
hgo: 3.5%, others: 17.8%.

〈実施例〉 本発明の具体的な実施例を第1図を用いて説明する。<Example> A specific embodiment of the present invention will be described with reference to FIG.

第1図は、取鍋と鋳型の間に位置するタンディツシュの
一部切断斜視図で、1は取鍋の溶鋼をタンディツシュに
注入する注入ノズル、タンディツシュ蓋2には注入ノズ
ルlを配設する注入孔3と測温、サンプリングおよび鋳
造前のタンディツシュを加熱するバーナー挿入に用いる
タンディツシュ蓋穴4とパウダ投入穴7とが設けられ、
これらは鋳造前からタンディツシュパウダを添加するま
では、溶鋼の再酸化防止のために密閉されている。
Fig. 1 is a partially cutaway perspective view of the tundish located between the ladle and the mold, in which 1 is an injection nozzle for injecting molten steel from the ladle into the tundish, and the tundish lid 2 is equipped with an injection nozzle 1. A hole 3, a tundish cover hole 4 used for temperature measurement, sampling, and insertion of a burner for heating the tundish before casting, and a powder input hole 7 are provided.
These are sealed to prevent re-oxidation of the molten steel from before casting until tanditsu powder is added.

鋼の連続鋳造に際して、前述の高塩基度の湯面被覆パウ
ダ5はこれらの穴から投入される。耐火物の溶損に影響
を与えない前記のタンディツシュ保護パウダ6は、タン
ディツシュ蓋の端に設けたパウダ穴7から投入される。
During continuous casting of steel, the above-mentioned high basicity molten metal surface coating powder 5 is introduced through these holes. The tundish protection powder 6, which does not affect the melting of the refractory, is introduced through a powder hole 7 provided at the end of the tundish lid.

このようにしてタンディツシュ湯面が湯面被覆パウダで
被覆され、タンディツシュがタンディツシュ保護パウダ
で保護された状態で連続鋳造が開始される。
In this way, the tundish hot water surface is covered with the tundish surface coating powder, and continuous casting is started with the tundish being protected by the tundish protecting powder.

以下により具体的な実施例を説明する。More specific examples will be described below.

AIを0.04〜0.05%含有した冷延鋼板用低炭素
アルミキルド綱を1つのクンデイツシュで連続的に15
00 を鋳造する際、本発明の実施例としてタンディツ
シュ耐火物側に第1表のAパウダを30kg添加し、そ
の内側の領域に第1表のBパウダを150kg添加した
。また比較例としてAパウダおよびBパウダをそれぞれ
単独で添加し、上記実施例と同一の鋼種、同一の条件で
1つのタンディツシュで連続的に1500 を鋳造した
。これら3種類の鋳造によって実施例の効果を明確にす
るため、鋳造実施回数をlOチャンス、つまり1500
0 tとし、それぞれのパウダで鋳造されたスラブ表皮
下2〜10m+に存在するアルミナクラスター数と冷延
鋼板表面に発生ずるアルミナ介在物起因のスリーパー欠
陥発生率を調査する一方、鋳造後の耐火物(Mho系)
の溶rJlimを測定し耐火物溶損指数とした。
150% of low carbon aluminum killed steel for cold rolled steel sheets containing 0.04 to 0.05% AI is continuously produced in one kundishu.
When casting 00, 30 kg of powder A shown in Table 1 was added to the tundish refractory side as an example of the present invention, and 150 kg of powder B shown in Table 1 was added to the inner region. Further, as a comparative example, powder A and powder B were added individually, and 1500 mm was continuously cast in one tundish using the same steel type and under the same conditions as in the above example. In order to clarify the effect of the example using these three types of casting, the number of castings was set to 10 chances, that is, 1500.
0 t, and investigated the number of alumina clusters existing 2 to 10 m below the skin of slabs cast with each powder and the incidence of sleeper defects caused by alumina inclusions occurring on the surface of cold rolled steel sheets. (Mho type)
The melt rJlim was measured and used as the refractory corrosion index.

第2表にその結果をまとめて示した。低塩基度のBパウ
ダの比較例2に比べて高塩基度のΔパウダである比較例
1および実施例は、スラブ表皮下のアルミナクラスター
数が著しく少なく、その結果冷延鋼板表面に発生するス
リーパー欠陥も少ない。
Table 2 summarizes the results. Compared to Comparative Example 2, which is a B powder with a low basicity, Comparative Example 1 and Examples, which are Δ powders with a high basicity, have a significantly smaller number of alumina clusters under the slab surface, and as a result, the number of sleepers that occur on the surface of the cold rolled steel sheet is reduced. There are few defects.

一方、実施例の鋳造後のタンディツシュ耐火物の?′8
1JI Nは、比較例1のパウダ使用後のタンディツシ
ュ耐火物の?a IJifftを100として比較する
と11であり、約1 /10に減少する。また比較例2
もタンディツシュ耐火物のt8 N1 !iに関しては
実施例とほぼ同等であるが、スラブ表皮下のアルミナク
ラスター数、スリーパー欠陥発生率は多い。
On the other hand, what about the tundish refractories after casting in the examples? '8
1JIN is the tundish refractory after using the powder of Comparative Example 1? When comparing a IJift with 100, it is 11, which is reduced to about 1/10. Also, comparative example 2
Also Tanditshu refractory T8 N1! Regarding i, it is almost the same as the example, but the number of alumina clusters under the slab surface and the incidence of sleeper defects are large.

さらに実施例が比較例1よりアルミナクラスタ、スリー
パー率が少ないのは、耐火物熔1nによる溶鋼中への酸
素の混入がない為である。
Furthermore, the reason why the alumina cluster and sleeper ratios in the example are lower than in comparative example 1 is because there is no mixing of oxygen into the molten steel due to the refractory melt 1n.

以上の結果から、本発明方法によればタンディツシュ耐
火物のt8 tliを減少し、かつ鋼中アルミナ介在物
が少ない低炭素アルミキルド鋼鋳片鋳造できることが明
らかである。
From the above results, it is clear that according to the method of the present invention, it is possible to reduce the t8 tli of the tundish refractory and to cast a low carbon aluminum killed steel slab with less alumina inclusions in the steel.

第2表 〈発明の効果〉 本発明方法によると、クンデイツシュ耐火物の溶用を減
少し、かつアルミナ介在物起因の製品欠陥が少ない低炭
素アルミキルド鋼鋳片を製造することができた。
Table 2 (Effects of the Invention) According to the method of the present invention, it was possible to reduce the use of kundish refractories and to produce low carbon aluminum killed steel slabs with fewer product defects due to alumina inclusions.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は、本発明を説明するためのタンディツシュの一
部切断斜視図、第2図は、低塩基度パウダの添加割合と
溶鋼中アルミナ介在物数との関係を示す特性図である。 1・・・注入ノズル、  2・・・タンディツシュ蓋、
3・・・注入孔、     4・・・タンディツシュ型
穴、5・・・湯面被覆パウダ、 6・・・タンディッシェ保護パウダ、 7・・・パウダ投入孔、  8・・・タンディツシュ。
FIG. 1 is a partially cutaway perspective view of a tundish for explaining the present invention, and FIG. 2 is a characteristic diagram showing the relationship between the addition ratio of low basicity powder and the number of alumina inclusions in molten steel. 1... Injection nozzle, 2... Tanditshu lid,
3... Injection hole, 4... Tandish mold hole, 5... Hot water surface coating powder, 6... Tundishe protection powder, 7... Powder injection hole, 8... Tundish.

Claims (2)

【特許請求の範囲】[Claims] (1)鋼を連続鋳造する際に、タンディッシュ湯面にC
aO:40〜60wt%、Al_2O_3:20〜40
wt%、MgO:0.5〜5.0wt%、C:0.5〜
2.0wt%、Ha_2O:0.1〜5.0wt%、C
aF_2:1〜10wt%を含有し、かつSiO_2を
7.0wt%以下に規制した湯面被覆パウダを被覆する
鋼の連続鋳造方法において、前記湯面被覆パウダの外周
をCaO:30〜40wt%、SiO_2:30〜40
wt%、Al_2O_3:20wt%以下、MgO:1
0wt%以下を含有するタンディッシュ保護パウダで囲
い、前記湯面被覆パウダとタンディッシュとの接触を防
止しタンディッシュを保護することを特徴とする鋼の連
続鋳造方法。
(1) When continuously casting steel, C on the tundish surface
aO: 40-60 wt%, Al_2O_3: 20-40
wt%, MgO: 0.5 to 5.0 wt%, C: 0.5 to
2.0wt%, Ha_2O: 0.1-5.0wt%, C
In a continuous casting method for steel coating a surface coating powder containing aF_2: 1 to 10 wt% and with SiO_2 regulated to 7.0 wt% or less, the outer periphery of the surface coating powder is coated with CaO: 30 to 40 wt%, SiO_2: 30-40
wt%, Al_2O_3: 20wt% or less, MgO: 1
A continuous casting method for steel, characterized in that the tundish is protected by surrounding it with a tundish protection powder containing 0 wt% or less to prevent contact between the tundish and the tundish.
(2)湯面被覆パウダに対するタンディッシュ保護パウ
ダの重量比を5〜20%とすることを特徴とする請求項
1記載の鋼の連続鋳造方法。
(2) The continuous steel casting method according to claim 1, characterized in that the weight ratio of the tundish protection powder to the hot water surface coating powder is 5 to 20%.
JP29616188A 1988-11-25 1988-11-25 Method for continuously casting steel Pending JPH02142653A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP29616188A JPH02142653A (en) 1988-11-25 1988-11-25 Method for continuously casting steel

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP29616188A JPH02142653A (en) 1988-11-25 1988-11-25 Method for continuously casting steel

Publications (1)

Publication Number Publication Date
JPH02142653A true JPH02142653A (en) 1990-05-31

Family

ID=17829948

Family Applications (1)

Application Number Title Priority Date Filing Date
JP29616188A Pending JPH02142653A (en) 1988-11-25 1988-11-25 Method for continuously casting steel

Country Status (1)

Country Link
JP (1) JPH02142653A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5179997A (en) * 1991-09-12 1993-01-19 Atlantic Metals Corporation Process for insulating molten steel during continuous casting
CN102744381A (en) * 2012-07-25 2012-10-24 洛阳市科丰冶金新材料(集团)有限公司 High-alkalinity tundish covering agent
CN103495714A (en) * 2013-10-23 2014-01-08 武汉钢铁(集团)公司 Peritectic steel covering slag containing cobaltous oxide and preparation method thereof
CN110548842A (en) * 2019-10-10 2019-12-10 万恩同 Weak electrolyte protective slag

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5179997A (en) * 1991-09-12 1993-01-19 Atlantic Metals Corporation Process for insulating molten steel during continuous casting
CN102744381A (en) * 2012-07-25 2012-10-24 洛阳市科丰冶金新材料(集团)有限公司 High-alkalinity tundish covering agent
CN103495714A (en) * 2013-10-23 2014-01-08 武汉钢铁(集团)公司 Peritectic steel covering slag containing cobaltous oxide and preparation method thereof
CN103495714B (en) * 2013-10-23 2016-01-13 武汉钢铁(集团)公司 Containing the peritectic steel covering slag and preparation method thereof of cobalt oxide
CN110548842A (en) * 2019-10-10 2019-12-10 万恩同 Weak electrolyte protective slag

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