JPH02127580A - Production of fabric having colored pattern and dyed with disperse dye - Google Patents
Production of fabric having colored pattern and dyed with disperse dyeInfo
- Publication number
- JPH02127580A JPH02127580A JP63280359A JP28035988A JPH02127580A JP H02127580 A JPH02127580 A JP H02127580A JP 63280359 A JP63280359 A JP 63280359A JP 28035988 A JP28035988 A JP 28035988A JP H02127580 A JPH02127580 A JP H02127580A
- Authority
- JP
- Japan
- Prior art keywords
- fabric
- dyed
- disperse dye
- dyeing
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000004744 fabric Substances 0.000 title claims abstract description 77
- 239000000986 disperse dye Substances 0.000 title claims abstract description 38
- 238000004519 manufacturing process Methods 0.000 title claims description 8
- 238000004043 dyeing Methods 0.000 claims abstract description 24
- 239000004094 surface-active agent Substances 0.000 claims abstract description 23
- 238000010438 heat treatment Methods 0.000 claims abstract description 11
- 238000005406 washing Methods 0.000 claims description 7
- 238000010025 steaming Methods 0.000 claims description 4
- 238000000034 method Methods 0.000 abstract description 29
- -1 fatty acid ester Chemical class 0.000 abstract description 13
- 239000000975 dye Substances 0.000 abstract description 10
- 239000003795 chemical substances by application Substances 0.000 abstract description 9
- 235000014113 dietary fatty acids Nutrition 0.000 abstract description 7
- 239000000194 fatty acid Substances 0.000 abstract description 7
- 229930195729 fatty acid Natural products 0.000 abstract description 7
- 229920001515 polyalkylene glycol Polymers 0.000 abstract description 3
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 9
- 238000004042 decolorization Methods 0.000 description 8
- 238000007639 printing Methods 0.000 description 7
- 230000000694 effects Effects 0.000 description 5
- 235000014676 Phragmites communis Nutrition 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 239000001913 cellulose Substances 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 239000000835 fiber Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- HPGGPRDJHPYFRM-UHFFFAOYSA-J tin(iv) chloride Chemical compound Cl[Sn](Cl)(Cl)Cl HPGGPRDJHPYFRM-UHFFFAOYSA-J 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 244000215068 Acacia senegal Species 0.000 description 2
- 229920000084 Gum arabic Polymers 0.000 description 2
- 235000010489 acacia gum Nutrition 0.000 description 2
- 239000000205 acacia gum Substances 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 125000000304 alkynyl group Chemical group 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 238000010018 discharge printing Methods 0.000 description 2
- 229920001971 elastomer Polymers 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 238000010020 roller printing Methods 0.000 description 2
- 238000004513 sizing Methods 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000017550 sodium carbonate Nutrition 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- 210000001364 upper extremity Anatomy 0.000 description 2
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 241000416162 Astragalus gummifer Species 0.000 description 1
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical group CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- 229920000881 Modified starch Polymers 0.000 description 1
- 239000004368 Modified starch Substances 0.000 description 1
- 244000273256 Phragmites communis Species 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- AWMVMTVKBNGEAK-UHFFFAOYSA-N Styrene oxide Chemical group C1OC1C1=CC=CC=C1 AWMVMTVKBNGEAK-UHFFFAOYSA-N 0.000 description 1
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 1
- 229920001615 Tragacanth Polymers 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 238000004026 adhesive bonding Methods 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 125000005037 alkyl phenyl group Chemical group 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000001680 brushing effect Effects 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000013078 crystal Substances 0.000 description 1
- 238000009990 desizing Methods 0.000 description 1
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 239000003292 glue Substances 0.000 description 1
- 238000009981 jet dyeing Methods 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 235000019426 modified starch Nutrition 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000010022 rotary screen printing Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 235000010413 sodium alginate Nutrition 0.000 description 1
- 239000000661 sodium alginate Substances 0.000 description 1
- 229940005550 sodium alginate Drugs 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、色模様付き分散染料染色布帛の製造方法に関
する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention relates to a method for producing a disperse dye dyed fabric with a color pattern.
従来、色模様付き分散染料染色布帛の製造方法としては
■布帛に染液を模様状に塗布して染色すル方法（刷毛塗
り、スクリーン捺染、ローラプリント等）■布帛に染着
抑制剤を部分的に付着させて、染色後に染着抑制剤を除
去する方法（ろ−けつ染）■布帛に部分的に染液が接触
し得ないような形状を与えて染色する方法（絞り染め）
■特定の分散染料で地染した布帛に塩化錫系化合物ある
いはソーダ灰等を含む抜染糊をプリントして乾熱あるい
はスチーミングによる熱処理を施した後、洗浄して抜染
糊を除去する方法（抜染プリント）等がある。このうち
、■〜■の方法は、染色において色模様が形成されて、
染色後には色模様を付けることができない方法である。Conventionally, methods for manufacturing disperse dye-dyed fabrics with colored patterns include: - A method in which a dye solution is applied to the fabric in a pattern to dye it (brush coating, screen printing, roller printing, etc.); - A dyeing inhibitor is applied to the fabric partially. A method in which the dyeing inhibitor is removed after dyeing (roke dyeing). A method in which the dyeing agent is dyed by giving the fabric a shape that prevents it from coming into contact with the dye solution (tie dyeing).
■A method in which a discharge dyeing paste containing a tin chloride compound or soda ash is printed on a fabric dyed with a specific disperse dye, heat treated by dry heat or steaming, and then washed to remove the discharge dyeing paste (discharge printing). print) etc. Among these methods, methods ■～■ form color patterns during dyeing,
This method does not allow color patterns to be added after dyeing.
これに対して■の方法は、染色後に色模様を付ける方法
であるから、同じ地染め布帛から異なった模様柄の染色
布帛を作ることができる。しかし、■の方法は、分散染
料が塩化錫系化合物やアルカリと反応して抜染糊と共に
除去されるような回数性を存するものに限定されると言
う問題がある。また、この方法では、抜染糊で色抜きさ
れた形状の輪郭がはっきりして、ぼかし柄模様は得にく
い、なお、■、■の方法もぼかし柄模様を得にくい方法
であり、■の方法は絞り柄と言うような独特のぼかし柄
模様を作って、絞りしわが残り易い方法である。On the other hand, the method (2) is a method of adding color patterns after dyeing, so dyed fabrics with different patterns can be made from the same ground-dyed fabric. However, method (2) has a problem in that it is limited to those that have a repeatability such that the disperse dye reacts with a tin chloride compound or an alkali and is removed together with the discharge paste. In addition, with this method, the outline of the shape removed with the discharge printing paste is clear, making it difficult to obtain a blurred pattern.Methods ■ and ■ are also difficult to obtain a blurred pattern; This method creates a unique shading pattern, such as a shibori pattern, and tends to leave squeeze wrinkles.
〔発明が解決しようとする課題］
本発明は、■の方法と同様の染色後に色模様を付ける方
法であって、しかも分散染料が前述のような回復性を有
する分散染料に限定されることのない色模様付き分散染
料染色布帛の製造方法を提供するものである。[Problems to be Solved by the Invention] The present invention is a method for adding a color pattern after dyeing, similar to the method (2), and the problem is that the disperse dye is limited to a disperse dye having recovery properties as described above. The present invention provides a method for producing a disperse dye-dyed fabric with a color pattern.
本発明者らは、布帛を分散染料で染色する際に均染剤と
して用いられる界面活性剤の作用について考察した結果
、界面活性剤には布帛に染着された分散染料を布帛から
分離させると言う作用もあって、その作用は分散染料が
高濃度で布帛に染着された濃染部分に強く働き、そして
布帛から分離した分散染料も再び布帛に染着されるよう
になるから、その結果として布帛が均一に染色されるの
ではないかと考えた。そしてさらに、然りとすれば界面
活性剤を抜色剤として用いて染色後に色模様を付けるこ
とは可能であり、それによれば分散染料が特定のものに
限定されると言う問題も解消し得ると考えた。そこで界
面活性剤を抜色剤として用いる研究を重ねた結果、本発
明に到達した。As a result of considering the effect of surfactants used as leveling agents when dyeing fabrics with disperse dyes, the present inventors found that surfactants can separate the disperse dyes dyed onto the fabrics from the fabrics. There is also the effect that the disperse dye has a high concentration and acts strongly on the darkly dyed part of the fabric, and the disperse dye that has been separated from the fabric is also dyed on the fabric again, so as a result. I thought that the fabric could be dyed uniformly. Furthermore, if this is true, it would be possible to use a surfactant as a color remover to add color patterns after dyeing, and this would solve the problem of being limited to specific types of disperse dyes. I thought. Therefore, as a result of repeated research on the use of surfactants as color removers, the present invention was achieved.
本発明は、布帛を分散染料で染色して得られた地染めま
たは部分染めの布帛の着色部分に部分的に界面活性剤を
主とする抜色剤を付与して乾熱またはスチーミングによ
る熱処理を行った後、洗浄して布帛から抜色剤を除去す
ることを特徴とする色模様付き分散染料染色布帛の製造
方法にある。The present invention applies a color remover mainly composed of a surfactant to the colored parts of ground-dyed or partially-dyed fabric obtained by dyeing the fabric with a disperse dye, and then heat-processes the fabric by dry heat or steaming. A method for producing a disperse dye-dyed fabric with colored patterns, which comprises washing the fabric to remove the color remover from the fabric.
本発明の方法は、■の方法と同様の染色後に色模様を付
ける方法であり、しかも分散染料による染色の均染剤と
して用いられるような界面活性剤を抜色剤として用いる
方法であるから、分散染料が■の方法におけるような特
定の分散染料に限定されることがない、また、界面活性
剤は、適当な粘度のものを用いることができるから、単
独でも用いることができ、粘度の相違も含めた界面活性
剤の種類、布帛への付与方法、熱処理方法等によってぼ
かし柄模様やばかしの殆どない色模様を付けることがで
きる。The method of the present invention is a method of adding a color pattern after dyeing, similar to method (2), and is a method of using a surfactant as a color removal agent, such as the one used as a leveling agent in dyeing with disperse dyes. The disperse dye is not limited to a specific disperse dye as in the method (2), and the surfactant can be of an appropriate viscosity, so it can be used alone, and the difference in viscosity Depending on the type of surfactant used, the method of applying it to the fabric, the heat treatment method, etc., it is possible to create a shading pattern or a color pattern with almost no gradations.
本発明において、分散染料で染色した地染めまたは部分
染め布帛は、ポリエチレンテレフタレート、ポリブチレ
ンテレフタレート、あるいはそれらに５−ナトリウムス
ルホンイソフタル酸と言ったスルホネート基含有化合物
などの改質剤を共重合したポリマーを主成分とするポリ
エステル系の繊維から成る織編物や不織布等の布帛が好
ましいが、それに限らず、分散染料で染色された布帛で
あれば他の繊維から成る布帛であってもよい０例えばア
セテート繊維から成る布帛も分散染料で染色できるから
、本発明に用いられる。In the present invention, ground dyed or partially dyed fabrics dyed with disperse dyes are polyethylene terephthalate, polybutylene terephthalate, or polymers obtained by copolymerizing them with a modifier such as a sulfonate group-containing compound such as 5-sodium sulfone isophthalate. Fabrics such as woven or knitted fabrics or non-woven fabrics made of polyester fibers having as a main component are preferred, but the fabric is not limited thereto, and fabrics made of other fibers may be used as long as they are dyed with disperse dyes.For example, acetate Fabrics made of fibers can also be dyed with disperse dyes and are therefore used in the present invention.
界面活性剤としては、ポリアルキレングリコール脂肪酸
エステル、ポリオキシアルキレンエーテル、ポリオキシ
アルキレンアルキルフェニルエーテル、ポリオキシアル
キレンフェニルエーテル。Examples of surfactants include polyalkylene glycol fatty acid ester, polyoxyalkylene ether, polyoxyalkylene alkylphenyl ether, and polyoxyalkylene phenyl ether.
ポリオキシアルキレンアルキルアミン、アンヒドロソル
ビトール脂肪酸エステル、脂肪酸モノグリセリド等の非
イオン系界面活性剤、中でも先の方に挙げた４群の界面
活性剤、特にＣ＋ＪｓａＣＯＯ（ＣＨｚＣｔｌｌＯ）＊
ＣＯＣ＋Ｊｓｓ ； （ｎ−２２）で表されるポリエチ
レンリコール脂肪酸エステル。Nonionic surfactants such as polyoxyalkylene alkylamines, anhydrosorbitol fatty acid esters, fatty acid monoglycerides, among others, the four groups of surfactants mentioned earlier, especially C+JsaCOO (CHzCtllO)*
COC+Jss; polyethylene recall fatty acid ester represented by (n-22).
で表されるポリオキシエチレントリスチルフェニルエー
テルが好ましく用いられるが、それに限らず、分散染料
での染色に均染剤として用いられる界面活性剤なら大抵
は用いることができる。なお、非イオン系界面・活性剤
中の好ましい４群は下記のようなものである。Polyoxyethylene tristylphenyl ether represented by is preferably used, but the invention is not limited thereto, and most surfactants used as a leveling agent in dyeing with disperse dyes can be used. The four groups of nonionic surfactants and active agents are as follows.
一般式
ポリアルキレングリコール トＣ−０−（Ａ） 、−ρ
′諷
脂肪酸エステル ０
ポリオキシアルキレン Ｒ，−０−（Ａ） 、１−）
１アルキルエーテル
アルキルフェニルエーテル
ポリオキシアルキレン
トリスチルフェニルエーテル
但し、−ａ式中、Ａはエチレンオキシド、プロピレンオ
キシド ブチレンオキシドまたはスチレンオキシド基、
ｎはｌＯ〜１００の整数、Ｒ，Ｒ１は炭素数１０〜２０
のアルキル基、アルケニル基またはアルキニル基、Ｒ′
はＨまたは炭素数１０〜２０のアルキル基、アルケニル
基またはアルキニル基、Ｒ１は炭素数１〜２０のアルキ
ル基、Ｒ，は炭素数１〜１０のアルキル基を表す。General formula polyalkylene glycol C-0-(A), -ρ
'Fatty acid ester 0 polyoxyalkylene R, -0-(A), 1-)
1 Alkyl ether Alkylphenyl ether Polyoxyalkylene tristylphenyl ether However, in the formula -a, A is an ethylene oxide, propylene oxide, butylene oxide or styrene oxide group,
n is an integer of lO to 100, R and R1 are carbon atoms of 10 to 20
an alkyl group, alkenyl group or alkynyl group, R'
represents H or an alkyl group having 10 to 20 carbon atoms, an alkenyl group or an alkynyl group, R1 represents an alkyl group having 1 to 20 carbon atoms, and R represents an alkyl group having 1 to 10 carbon atoms.
以上のような界面活性剤は、それだけで布帛に付与して
もよいし、または糊剤を用いて捺染糊として付与しても
よい、糊剤には、友禅糊、トラガントゴム、セネガルゴ
ム、アラビアゴム、アルギン酸ソーダ等の天然糊剤、カ
ルボキシメチルセルロース、繊維素メチル、繊維素エチ
ル、繊維素ハイドロオキシエチル等の繊維素誘導体糊剤
、加工澱粉、シラフッゴム。ナツトクリスタルゴム、シ
ーザーゴム等の加工天然ゴム糊剤、ポリビニルアルコー
ル、ポリ酢酸ビニル、ポリアクリル酸エステル等の合成
糊剤を適当に用いることができる。The above-mentioned surfactants may be applied to the fabric by themselves, or may be applied as a printing paste using a sizing agent. Examples of the sizing agent include Yuzen glue, gum tragacanth, gum gum Arabic, and gum arabic. , natural thickening agents such as sodium alginate, cellulose derivative thickening agents such as carboxymethylcellulose, cellulose methyl, cellulose ethyl, and cellulose hydroxyethyl, modified starch, and Silaf gum. Processed natural rubber pastes such as nut crystal rubber and Caesar rubber, synthetic pastes such as polyvinyl alcohol, polyvinyl acetate, and polyacrylic acid esters can be suitably used.
捺染糊として付与する場合は、界面活性剤の割合を変え
ることで抜色の程度やぼかしの程度を変えることができ
るが、抜色の効果を得るために界面活性剤の割合を５重
１％以上好ましくは２０重量％以上とする。また、布帛
が前述のような回数性を有する分散染料で染色されたも
のである場合は、界面活性剤または捺染糊に塩化錫系化
合物やソーダ灰等を水溶液の形で添加してもよい。また
、界面活性剤または捺染糊に布帛を染色した分散染料と
は異なる色の分散染料を添加してもよい、それによって
、添加された分散染料が布帛の着色部分の界面活性剤で
抜色された部分に適当に移行して、単なる抜色模様では
ない着色部分とは異なる色の色模様を布帛の着色部分に
付けるとかできる。When applied as a printing paste, the degree of color removal and blurring can be changed by changing the proportion of surfactant, but in order to obtain the effect of color removal, the proportion of surfactant should be 5 times 1%. The content is preferably 20% by weight or more. In addition, when the fabric is dyed with a disperse dye having repeatability as described above, a tin chloride compound, soda ash, etc. may be added to the surfactant or printing paste in the form of an aqueous solution. In addition, a surfactant or a disperse dye of a different color from the disperse dye that dyed the fabric may be added to the printing paste, so that the color of the added disperse dye is removed by the surfactant of the colored part of the fabric. It is possible to apply a color pattern to the colored part of the fabric, which is not just a color pattern, but a different color from the colored part.
界面活性剤または捺染糊を布帛の着色部分に部分的に付
与するのは、刷毛塗り、スプレー法、スクリーン捺染機
やローラ捺染機を用いる方法等によって行われ、高級品
を得るにはスクリーン捺染機を用いる方法が適している
。また、ぼかし柄模様を得るには比較的粘度の低い液を
用いるのが好ましい。Partial application of surfactant or printing paste to the colored parts of the fabric is done by brushing, spraying, or using a screen printing machine or roller printing machine, etc. To obtain high-quality products, a screen printing machine is used. The method using is suitable. Further, in order to obtain a blurred pattern, it is preferable to use a liquid with relatively low viscosity.
付与後の布帛の熱処理は、ぼかし柄模様を得る場合は、
１３０°Ｃ１３０分程度または１８０°Ｃ，７分程度の
スチーミング処理するか、１２０°Ｃ，３分程度の乾熱
処理した後１６０ ”Ｃ以上好ましくは１７０ ’Ｃ以
上で１分程度の乾熱処理すればよい、また、輪郭の比較
的はっきりした色模様を得る場合は、１６０°Ｃ以上好
ましくは１７０°Ｃ以上で１分程度の乾熱処理すればよ
い、１６０°Ｃ以上の熱処理時間を余り長くすると、布
帛に変色や変質が生じるようになる。Heat treatment of the fabric after application is necessary to obtain a shading pattern.
Steaming at 130°C for about 130 minutes, or 180°C for about 7 minutes, or dry heat treatment at 120°C for about 3 minutes, followed by dry heat treatment at 160'C or more, preferably 170'C or more for about 1 minute. In addition, if you want to obtain a color pattern with relatively clear outlines, dry heat treatment for about 1 minute at 160°C or higher, preferably 170°C or higher, is sufficient.If the heat treatment time at 160°C or higher is too long, , the fabric begins to change color and deteriorate in quality.
熱処理後の布帛から界面活性剤や捺染糊等を除去する洗
浄は、通常の還元洗浄方法すなわち、必要に応じ洗剤と
してアルカリや界面活性剤を加えた洗液で洗浄した後、
水洗して乾燥する方法で行われる。洗液による洗浄は８
０°Ｃで２０〜３０分程度行程度十分である。Washing to remove surfactants, printing paste, etc. from the fabric after heat treatment is carried out using the usual reduction washing method.
This is done by washing with water and drying. Cleaning with washing liquid is 8
20 to 30 minutes at 0°C is sufficient.
以上によって、分散染料で地染めまたは部分染めされた
布帛の着色部分に抜色模様またはそれが着色部分とは異
なる色の分散染料で着色された色模様を付けられた分散
染料染色布帛が得られる。Through the above steps, a disperse dye-dyed fabric can be obtained in which the colored part of the fabric that has been ground-dyed or partially dyed with a disperse dye has a removed color pattern or a colored pattern colored with a disperse dye of a different color from the colored part. .
本発明は、普通のブレーンな布帛に限らず、起毛、立毛
、パイル布等に対しても適用でき、本発明の方法によっ
て得られた色模様付き分散染料染色布帛は、布帛の種類
によって衣料用、インテリア用、カーシート用、靴用等
種々の用途に用いられる。The present invention is applicable not only to ordinary plain fabrics but also to raised, raised, piled fabrics, etc. The disperse dye dyed fabrics with colored patterns obtained by the method of the present invention can be used for clothing depending on the type of fabric. It is used for a variety of purposes, including interior design, car seats, and shoes.
以下、さらに本発明を具体的な実施例によって説明する
。Hereinafter, the present invention will be further explained with reference to specific examples.
実施例１゜
７５ｄｅ／３６ ｆｉｌのポリエステルフィラメント糸
を用いた２８ゲ一ジ天竺編地を可法性のない分散染料（
三菱化成■製Ｄｉａｎｉｘ Ｂｌｕｅ ＢＧ−ＦＳ２０
０％）を２％ｏ、ｗ、ｆ、で常法により染色して地染め
布帛を得た。Example 1 A 28-gauge jersey knitted fabric using 75 de/36 fil polyester filament yarn was dyed with an illegal disperse dye (
Dianix Blue BG-FS20 manufactured by Mitsubishi Kasei ■
0%) was dyed with 2% O, W, F by a conventional method to obtain a ground-dyed fabric.
この地染め布帛にポリエチレングリコール脂肪酸エステ
ル（日華化学■製ニッカサンソル目２００）８０重量％
と水２０重量％とから成る抜色剤を１２５０メツシユの
ロータリースクリーンにより水玉模様に印捺して付与し
た。この印捺布に対して、それぞれ第１表にＮα１〜９
で示した乾熱処理を施した後、通常の還元洗浄を行った
。得られた布帛の抜色模様の抜色程度と輪郭のシャープ
性とを第１表に合わせて示した。80% by weight of polyethylene glycol fatty acid ester (Nicca Sansol 200 manufactured by NICCA Chemical Co., Ltd.) is added to this ground-dyed fabric.
A color remover consisting of and 20% by weight of water was applied by printing in a polka dot pattern using a 1250 mesh rotary screen. For this printed fabric, Nα1 to 9 are shown in Table 1, respectively.
After performing the dry heat treatment shown in , ordinary reduction cleaning was performed. Table 1 shows the degree of color removal and the sharpness of the outline of the color removal pattern of the obtained fabric.
第
表
第１表から明らかなように、抜色模様を得るには、乾熱
により１６０°Ｃで１分程度好ましくは１７０°Ｃで１
分程度以上の処理を行い、ぼかし柄模様を得るにはその
前に１６０°Ｃよりも低い１２０〜１３０°Ｃ程度で３
分程度の乾熱処理を行えばよいことが分かる。As is clear from Table 1, in order to obtain a color removal pattern, it is necessary to dry heat at 160°C for about 1 minute, preferably at 170°C for about 1 minute.
To obtain a blurred pattern, heat the treatment at 120-130°C (lower than 160°C) for 30 minutes.
It can be seen that dry heat treatment for about a minute is sufficient.
実施例２゜
２枚筬よりなる２８ゲ一ジトリコツト編機を用い、前肢
にポリエステルフィラメント糸５０ｄｅ／４８ ｆｉｌ
を、後筬にポリエステルフィラメント糸５０ｄｅ／２４
ｆｉｌを通して、フレンチパイル組織（筬の振り表示：
前肢１，０／３，４、後筬１． Ｏ／１． ２）の起
毛用編地を編成した。この編地を針布起毛機で起毛し、
起毛したパイルの先端部を剪毛してパイル長を揃えたパ
イル布帛を得た。このパイル布帛を液流染色機に可法性
のない分散染料の染液を用いて常法により１３０°Ｃ２
３０分間染色し、ブルーのパイル布帛とした。染液の組
成は下表に示す通りである。Example 2 A 28-gauge tricot knitting machine consisting of two reeds was used, and 50 de/48 fil of polyester filament yarn was used in the forelimbs.
In the rear reed, polyester filament thread 50de/24
Through fil, French pile structure (reed swing display:
Forelimbs 1,0/3,4, hind reed 1. O/1. 2) The raised knitted fabric was knitted. This knitted fabric is raised with a needle cloth raising machine,
The tips of the raised piles were sheared to obtain pile fabrics with uniform pile length. This pile fabric was dyed in a jet dyeing machine at 130°C2 using a conventional method using an illegal disperse dye dyeing solution.
It was dyed for 30 minutes to produce a blue pile fabric. The composition of the dye liquor is shown in the table below.
染液組成
り１ａｎｉｘ Ｂｌｕｅ ＢＧ−ＦＳ ２００％（三菱
化成■製 分散染料）
Ｍｉｋｅｔｏｎ Ｐｏｌｙｅｇｔｓｒ Ｂｌｕｅ ＢＧ
（三井東圧染料■製 分散染料）
イオネントＲＡＰ ２８５
（三洋化成工業■製 均染剤）
酢酸
１．５ ％ ｏ、ｗ、ｆ。Dye liquid composition 1anix Blue BG-FS 200% (Disperse dye manufactured by Mitsubishi Kasei ■) Miketon Polyegtsr Blue BG
(Disperse dye manufactured by Mitsui Toatsu Dye ■) Ionent RAP 285 (Leveling dye manufactured by Sanyo Chemical Industries ■) Acetic acid 1.5% o, w, f.
０．５ ％ ｏ、 ｗ、 ｆ 。0.5 % o, w, f .
１ｇ／２
０．２ ｃｃ／１
次いで、染色パイル布帛に乾燥９幅出しセットを行って
、地染め布帛を得た。この地染め布帛のパイル面に下記
組成の抜染糊
抜染糊組成
ニッカガム？ＩＡ−４４（１７％）
（日華化学ｖ４製 糊剤） ３０重量％サンモ
ールＦＬ
（日華化学■製 界面活性剤）６０重世％水
１０重量％を１０００メツ
シユのロータリースクリーン捺染機により格子柄状に印
捺した。得られた印捺布帛を１２０°Ｃで５分間乾燥し
、次いで１７５°Ｃで７分間高温スチーミングした後、
脱糊９水洗、ソーピング。1 g/2 0.2 cc/1 Next, the dyed pile fabric was subjected to a drying 9 width setting to obtain a ground dyed fabric. Discharge dyeing paste with the following composition on the pile side of this ground-dyed fabric Discharge dyeing paste composition Nikka gum? IA-44 (17%) (Gluing agent manufactured by NICCA CHEMICAL V4) 30% by weight Sunmoor FL (Surfactant manufactured by NICCA CHEMICAL ■) 60% water
10% by weight was printed in a checkered pattern using a 1000 mesh rotary screen printing machine. The obtained printed fabric was dried at 120°C for 5 minutes, then high temperature steamed at 175°C for 7 minutes,
Desizing 9. Washing and soaping.
乾燥、仕上処理して、パイル面に抜色模様を有する染色
パイル布帛を得た。このパイル布帛は、起毛パイル部分
が格子柄状に抜色されて、その抜色模様が従来にない柄
状に杢感を表現した高級起毛布帛であった。After drying and finishing treatment, a dyed pile fabric having a color removal pattern on the pile surface was obtained. This pile fabric was a high-quality brushed fabric in which the brushed pile portion was colored in a checkered pattern, and the colored pattern expressed a heathered feel in a pattern that had never been seen before.
本発明の方法によれば、分散染料で染色された布帛に分
散染料が可抜染料であるか否かに拘らず抜色模様を付け
ることができ、またぼかし柄模様を付けることも容易に
なし得ると言う優れた効果が得られる。According to the method of the present invention, a color removal pattern can be applied to a fabric dyed with a disperse dye regardless of whether the disperse dye is a removable dye or not, and a shading pattern can also be easily applied. You can get excellent effects.
Claims (2)
部分染め布帛の着色部分に部分的に界面活性剤を主とす
る抜色剤を付与して乾熱またはスチーミングによる熱処
理を行った後、洗浄して布帛から抜色剤を除去すること
を特徴とする色模様付き分散染料染色布帛の製造方法。(1) A color remover mainly consisting of a surfactant is applied to the colored parts of ground dyed or partially dyed fabric obtained by dyeing the fabric with disperse dyes, and heat treatment is performed by dry heat or steaming. A method for producing a disperse dye-dyed fabric with a colored pattern, which comprises washing the fabric to remove the color remover from the fabric.
の分散染料も付与される特許請求の範囲第１項記載の色
模様付き分散染料染色布帛の製造方法。(2) The method for producing a colored patterned disperse dye-dyed fabric according to claim 1, wherein a disperse dye of a color different from the disperse dye is also applied together with the application of the color remover.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63280359A JPH02127580A (en) | 1988-11-08 | 1988-11-08 | Production of fabric having colored pattern and dyed with disperse dye |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63280359A JPH02127580A (en) | 1988-11-08 | 1988-11-08 | Production of fabric having colored pattern and dyed with disperse dye |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JPH02127580A true JPH02127580A (en) | 1990-05-16 |
Family
ID=17623905
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63280359A Pending JPH02127580A (en) | 1988-11-08 | 1988-11-08 | Production of fabric having colored pattern and dyed with disperse dye |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH02127580A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005024124A1 (en) * | 2003-08-05 | 2005-03-17 | Nabro Corporation Limited | Cloth having pattern or the like drawn thereon and process for producing the same |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5014886A (en) * | 1973-06-15 | 1975-02-17 | ||
| JPS5063285A (en) * | 1973-10-03 | 1975-05-29 | ||
| JPS55163287A (en) * | 1979-06-01 | 1980-12-19 | Hoechst Ag | Local brightening * white discharge style and coloring discharge style of dyeing of sheet like fiber molded article |
-
1988
- 1988-11-08 JP JP63280359A patent/JPH02127580A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5014886A (en) * | 1973-06-15 | 1975-02-17 | ||
| JPS5063285A (en) * | 1973-10-03 | 1975-05-29 | ||
| JPS55163287A (en) * | 1979-06-01 | 1980-12-19 | Hoechst Ag | Local brightening * white discharge style and coloring discharge style of dyeing of sheet like fiber molded article |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005024124A1 (en) * | 2003-08-05 | 2005-03-17 | Nabro Corporation Limited | Cloth having pattern or the like drawn thereon and process for producing the same |
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