JP2000096461A - Dye-discharging agent for synthetic fiber material, discharge of dye and dye-discharged synthetic fiber material - Google Patents
Dye-discharging agent for synthetic fiber material, discharge of dye and dye-discharged synthetic fiber materialInfo
- Publication number
- JP2000096461A JP2000096461A JP10268143A JP26814398A JP2000096461A JP 2000096461 A JP2000096461 A JP 2000096461A JP 10268143 A JP10268143 A JP 10268143A JP 26814398 A JP26814398 A JP 26814398A JP 2000096461 A JP2000096461 A JP 2000096461A
- Authority
- JP
- Japan
- Prior art keywords
- dye
- fiber material
- printing
- synthetic fiber
- discharge
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、抜蝕効果を有する
合成系繊維材料用抜染剤、抜染加工方法および抜染加工
された合成系繊維材料に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a discharge agent for a synthetic fiber material having a discharge effect, a discharge printing method, and a discharge-processed synthetic fiber material.
【０００２】[0002]
【従来の技術】ポリエステル系繊維の抜染加工におい
て、アルカリ剤を用いる抜染加工では、炭酸ソーダ、炭
酸カリ、第三リン酸カリ、水酸化ナトリウム、ケイ酸ソ
ーダ、第三リン酸ソーダ等を抜染剤として印捺付着させ
た後、熱処理して抜染模様を形成させる方法が知られて
いる。2. Description of the Related Art In a discharge printing process using an alkali agent in a discharge printing process for polyester fibers, sodium carbonate, potassium carbonate, potassium tertiary phosphate, sodium hydroxide, sodium silicate, sodium tertiary phosphate, etc. are used as a discharge agent. A method of forming a discharge-printed pattern by heat-treating it after printing and adhering it is known.
【０００３】しかしながら、アルカリ金属水酸化物を用
いる方法では使用できる糊剤が耐アルカリ性のあるもの
に限られ、また所望の効果を得るためにはアルカリ剤を
多量に使用することもあり、印捺糊の安定性や流動性に
影響が生じ、型際のシャープさに欠ける等の問題が起こ
り、満足な印捺柄が得られない。また、印捺糊に染料を
含有させ、印捺部のポリエステル繊維を染色する際に
は、従来のアルカリ金属水酸化物の抜染剤を用いた印捺
糊に染料を含有させると、染料が変色し、満足する色相
が得られないという問題がある。However, in the method using an alkali metal hydroxide, the sizing agent that can be used is limited to those having alkali resistance, and in order to obtain a desired effect, a large amount of an alkali agent may be used. This affects the stability and fluidity of the paste, causing problems such as lack of sharpness at the time of molding, and a satisfactory printed pattern cannot be obtained. In addition, when the dye is contained in the printing paste and the polyester fiber in the printing area is dyed, the dye will be discolored if the printing paste using a conventional alkali metal hydroxide discharge agent contains the dye. However, there is a problem that a satisfactory hue cannot be obtained.
【０００４】さらに、上記に述べられている従来の方法
では、印捺する抜染色糊は危険なものが多く、特にアル
カリ金属水酸化物を抜染色糊に使用するにあたっては作
業の際に特段の注意を要する。Furthermore, in the above-mentioned conventional method, the printed paste to be printed is often dangerous, and in particular, when an alkali metal hydroxide is used as the discharged paste, a special process is required during the operation. Be careful.
【０００５】[0005]
【発明が解決しようとする課題】本発明は、従来のアル
カリ抜染におけるアルカリ剤の使用をやめることによ
り、糊剤の限定や印捺糊中の染料の変色を無くし、鮮明
な色相を有する柄の形成と印捺模様の型際の極めてシャ
ープな模様を提供し、加えて抜蝕効果を有することによ
り、起毛品においては型際の極めてシャープな凹凸模様
を有する、意匠性に優れた抜染加工合成系繊維材料を、
極めて安全に製造することのできる抜染剤および抜染方
法を提供することを目的になされたものである。SUMMARY OF THE INVENTION The present invention eliminates the use of alkaline agents in conventional alkaline discharge printing, thereby eliminating the limitation of pastes and the discoloration of dyes in printing pastes, and providing a pattern having a sharp hue. By providing an extremely sharp pattern when forming and printing a pattern, and by having an anti-corrosion effect, the brushed product has an extremely sharp concave-convex pattern when molding and has excellent design properties. System fiber material,
An object of the present invention is to provide a discharge agent and a discharge method which can be manufactured extremely safely.
【０００６】[0006]
【課題を解決するための手段】本発明者は、上記課題を
解決するため鋭意検討を重ねた結果、抜染成分として炭
酸グアニジンを用いることにより、従来の問題点を解決
でき、さらに抜蝕効果も付与できることを見出し、この
知見に基づき本発明を完成させた。すなわち、本発明
は、炭酸グアニジンおよび吸着性物質を含有する合成系
繊維材料用抜染剤、炭酸グアニジンおよび吸着性物質を
含有する抜染剤を用いる合成系繊維材料の抜染加工方
法、および炭酸グアニジンおよび吸着性物質を含有する
抜染剤を用いて抜染加工された合成系繊維材料を提供す
る。The present inventors have made intensive studies to solve the above-mentioned problems, and as a result, by using guanidine carbonate as a discharge-printing component, it was possible to solve the conventional problems, and furthermore, the discharge effect was also improved. The present inventors have found that it can be applied, and completed the present invention based on this finding. That is, the present invention provides a discharge agent for synthetic fiber material containing guanidine carbonate and an adsorbent substance, a method for discharging synthetic fiber material using a discharge agent containing guanidine carbonate and an adsorbent substance, and guanidine carbonate and adsorption. Provided is a synthetic fiber material which has been subjected to discharge printing using a discharge agent containing a conductive substance.
【０００７】[0007]
【発明の実施の形態】本発明の抜染剤は、炭酸グアニジ
ンおよび吸着性物質を抜染成分として含有するものであ
り、その形態としては、例えば、炭酸グアニジンと吸着
性物質との混合物、糊ペースト中に炭酸グアニジンと吸
着性物質とを混合したもの等が挙げられ、この抜染剤を
元糊に配合することによって印捺糊とすることができ
る。その配合量は、抜染の対象となる合成系繊維材料の
種類および目標とする抜染の程度によって適宜選択すれ
ばよく、特に限定されるものではないが、印捺糊中に炭
酸グアニジンが０．１〜５０重量％、好ましくは０．５
〜４０重量％配合されていればよく、かかる範囲で十分
な抜染効果が得られる。BEST MODE FOR CARRYING OUT THE INVENTION The discharge agent of the present invention contains guanidine carbonate and an adsorptive substance as discharge components, and may be in the form of, for example, a mixture of guanidine carbonate and an adsorbent substance, or a paste in paste. And a mixture of guanidine carbonate and an adsorptive substance. By mixing this discharge agent with the original paste, a printing paste can be obtained. The compounding amount may be appropriately selected depending on the type of the synthetic fiber material to be discharged and the degree of target discharge, and is not particularly limited. ~ 50% by weight, preferably 0.5
It is sufficient that the content is in the range of 40 to 40% by weight, and a sufficient discharge effect can be obtained in such a range.
【０００８】本発明で用いられる吸着物質としては、従
来より吸着物質として用いられているものを使用するこ
とができ、例えば、タルク、カオリン等の鉱産物、酸化
アルミニウム等の金属酸化物、活性炭、セラミックス、
金属粉末等が挙げられる。本発明の抜染剤は、通常、元
糊に配合した印捺糊の形に調整して使用される。印捺糊
を調整するための元糊としては特に限定されず、通常の
各種印捺糊に用いられる元糊を適宜選択して用いること
ができる。例えば、デンプン、アラビアゴム、クリスタ
ルゴム、タマリンド、アルギン酸ソーダ等の天然糊料、
カルボキシメチル繊維素ソーダ、プロピオキシセルロー
ス、アルギン酸エステル、グアガムエチレンオキサイド
付加物、エチルセルロース、メチルセルロース、ブリテ
ィッシュガム等の加工糊料、ポリアクリル酸塩、ポリア
クリル酸誘導体、ポリ酢酸ビニル、アクリル酸エステル
−酢酸ビニル共重合体、ポリビニルアルコール、ポリビ
ニルブチラール、ポリウレタン、ポリマレイン酸共重合
体塩、非イオン界面活性剤等の合成糊料や合成樹脂エマ
ルジョン、珪藻土、ケイ酸コロイド等の無機系糊料など
の各種糊料を、各々単独であるいは２種以上を混合し
て、糊料として用い、これを水または有機溶剤に加えて
溶液または分散液としたもの、水と石油系溶剤との粘液
エマルジョンとしたもの、前記２者の混合物など、従来
から用いられている元糊を使用することができる。As the adsorbent used in the present invention, those conventionally used as adsorbents can be used. For example, minerals such as talc and kaolin, metal oxides such as aluminum oxide, activated carbon, Ceramics,
Metal powder and the like. The discharge agent of the present invention is usually used after being adjusted to the form of printing paste mixed with the original paste. The base paste for adjusting the printing paste is not particularly limited, and the base paste used for various various printing pastes can be appropriately selected and used. For example, starch, natural gums such as gum arabic, crystal gum, tamarind, sodium alginate,
Carboxymethyl cellulose soda, propoxycellulose, alginic acid ester, guar gum ethylene oxide adduct, ethylcellulose, methylcellulose, processed glue such as British gum, polyacrylate, polyacrylic acid derivative, polyvinyl acetate, acrylate-acetic acid Various glues such as vinyl glue, polyvinyl alcohol, polyvinyl butyral, polyurethane, polymaleic acid copolymer salt, synthetic glue such as nonionic surfactant and synthetic glue such as synthetic resin emulsion, diatomaceous earth, and silicate colloid Ingredients, either alone or as a mixture of two or more, are used as pastes, which are added to water or an organic solvent to form a solution or dispersion, a viscous emulsion of water and a petroleum-based solvent, Conventionally used, such as a mixture of the two It is possible to use the glue.
【０００９】上記元糊中には、本発明の抜染剤以外に
も、必要に応じて染料、顔料、界面活性剤、還元防止
剤、金属イオン封鎖剤、増量剤、吸湿剤、浸透剤、電解
質、油脂、蛍光増白剤、防腐剤、紫外線吸収剤、酸化防
止剤等、通常の染色用薬剤を適宜配合することができ
る。配合できる染料としては、任意の染料を用いること
ができが、特に好ましくはアルカリに耐え得る染料でキ
ノン系、キノフタロン系の分散染料や反応染料が用いら
れる。In the base paste, besides the discharge agent of the present invention, a dye, a pigment, a surfactant, a reduction inhibitor, a sequestering agent, a bulking agent, a hygroscopic agent, a penetrant, an electrolyte Ordinary dyeing agents such as oils, fats, fluorescent brighteners, preservatives, ultraviolet absorbers, antioxidants and the like can be appropriately compounded. Any dye can be used as the dye that can be blended, and particularly preferably, a quinone-based or quinophthalone-based disperse dye or a reactive dye that can withstand alkali is used.
【００１０】布帛への印捺糊の印捺は、従来より行われ
ている任意の方法によって行うことができ、模様等の部
分印捺からほぼ全面の印捺まで任意に印捺することがで
きる。また、他の印捺部と一部を重ねて印捺してもよ
い。次に、必要に応じて予備乾燥した後、乾熱または湿
熱処理を施す。これらの処理を行う方法は、特に限定さ
れず、例えば、乾熱処理法としてはオーブンや乾燥機を
用いてベーキングを施す方法や熱プレス機を用いてベー
キングを施す方法等を採用することができ、湿熱処理法
としてはＨＴスチーマー等を用いてスチーミングを施す
方法などを採用できる。処理条件については、対象とな
る合成系繊維材料の種類によっても異なり、一概には言
えないが、いずれの方法においても９０〜２００℃程度
の温度で３０秒〜３０分程度の処理を行えば好ましい効
果を得ることができる。その後、必要に応じて、処理材
料に水洗、ソーピング等の後処理を施し、乾燥する。Printing of the printing paste on the fabric can be performed by any conventional method, and printing can be performed arbitrarily from partial printing of a pattern or the like to printing of almost the entire surface. . Further, the printing may be performed by partially overlapping another printing section. Next, after pre-drying as necessary, dry heat or wet heat treatment is performed. The method of performing these treatments is not particularly limited, and, for example, a method of performing baking using an oven or a dryer or a method of performing baking using a hot press machine can be adopted as a dry heat treatment method. As the wet heat treatment method, a method of performing steaming using an HT steamer or the like can be employed. The treatment conditions vary depending on the type of the synthetic fiber material to be treated, and cannot be unconditionally determined. However, in any method, it is preferable to perform the treatment at a temperature of about 90 to 200 ° C. for about 30 seconds to 30 minutes. The effect can be obtained. Thereafter, if necessary, the processing material is subjected to post-processing such as water washing and soaping, and dried.
【００１１】本発明による抜染加工された合成系繊維材
料には、当然ながら、抜染加工後に通常の染色または捺
染加工を施すこともできる。抜染加工での柄、色相とさ
らなる染色または捺染加工での柄、色相との組み合わせ
によって多種多様の高度の意匠効果を付与することも可
能である。本発明に用いられる合成系繊維材料として
は、ポリエステル繊維、ポリアミド繊維、およびこれら
の繊維と綿、レーヨン、絹、アセテート等との複合繊維
を素材とした、織物、編物、起毛布、不織布等が挙げら
れる。The discharge-processed synthetic fiber material according to the present invention can of course be subjected to ordinary dyeing or printing after the discharge printing. A wide variety of advanced design effects can be provided by a combination of the pattern and hue in the discharge printing process and the pattern and hue in the further dyeing or printing process. Examples of the synthetic fiber material used in the present invention include polyester fibers, polyamide fibers, and composite fibers of these fibers and cotton, rayon, silk, acetate, and the like, and include woven fabrics, knitted fabrics, raised fabrics, and nonwoven fabrics. No.
【００１２】[0012]
【実施例】以下、本発明を実施例により具体的に説明す
るが、本発明はこれらにより何ら限定されるものではな
い。実施例、比較例中の「部」は「重量部」を表す。 試験布の作成 供試布：ポリエステル起毛布（白布、精練上がり） 染色浴：染料（C.I. Dispers Blue 73） １．０％o.w.f. ＲＭ−ＥＸ（分散均染剤、日華化学（株）製） ０．５g/リットル ９０％酢酸 ０．１g/リットル 浴 比：１：２０ 染色条件：２℃／分で昇温し、１３０℃で３０分保持 その後、水洗、ソーピングし、乾燥して試験布とする。EXAMPLES Hereinafter, the present invention will be described specifically with reference to Examples, but the present invention is not limited thereto. “Parts” in Examples and Comparative Examples represents “parts by weight”. Preparation of test cloth Test cloth: polyester raised cloth (white cloth, scouring finished) Dyeing bath: dye (CI Dispers Blue 73) 1.0% owf RM-EX (dispersion leveling agent, manufactured by Nichika Chemical Co., Ltd.) 0 0.5 g / l 90% acetic acid 0.1 g / l bath ratio: 1:20 Dyeing condition: Heat at 2 ° C./min, hold at 130 ° C. for 30 min, then wash with water, soap and dry to obtain test cloth .
【００１３】実施例１ ニッカガムＡＬ（アルギン酸ソーダ、日華化学（株）
製）３部、水５７部からなる元糊６０部に、炭酸グアニ
ジン１５部、活性炭１０部、分散染料（Ｃ．Ｉ．Ｄｉｓ
ｐｅｒｓｅ Ｒｅｄ ９２））２部、水１３部を混合
し、赤色の印捺糊を調製した。前記の青色に染色された
ポリエステル起毛布上にこの印捺糊を柄状に印捺し、乾
燥した。次いで、ＨＴスチーマー（ＨＴ−３−５５０
型：辻井染機工業（株）製）を用いて１８０℃で７分間
のスチーミング処理を施し、その後、水洗、ソーピング
を経て乾燥した。印捺糊のポリエステル起毛布に対する
付着率は、平均１２０重量％であった。Example 1 Nikka gum AL (sodium alginate, Nika Chemical Co., Ltd.)
3 parts and 57 parts of water, 60 parts of original glue, 15 parts of guanidine carbonate, 10 parts of activated carbon, and a disperse dye (CI Dis)
Perse Red 92)) 2 parts and 13 parts of water were mixed to prepare a red printing paste. This printing paste was printed in a pattern on the above-mentioned polyester brushed cloth dyed blue and dried. Then, HT steamer (HT-3-550)
(Steaming process at 180 ° C. for 7 minutes) using a mold (manufactured by Tsujii Dyeing Machinery Co., Ltd.), followed by washing with water and soaping, followed by drying. The adhesion rate of the printing paste to the polyester raising cloth was 120% by weight on average.
【００１４】かくして得られたポリエステル起毛布は、
印捺部が抜蝕され、抜染されたことにより、凹部が赤色
に染色され、凸部の青色が残った立体柄を呈するもので
あった。 実施例２ 実施例１において、活性炭１０部に代えてカオリン１０
部を用いた以外は、実施例１と同様にして抜染加工し
た。The polyester raised cloth thus obtained is
The printed portion was etched and discharged, so that the concave portion was dyed red and the convex portion exhibited a three-dimensional pattern in which the blue remained. Example 2 In Example 1, kaolin 10 was used instead of activated carbon 10 parts.
Except for using a part, discharge printing was performed in the same manner as in Example 1.
【００１５】かくして得られたポリエステル起毛布は、
実施例１と同様であり、印捺部が抜蝕され、抜染された
ことにより、凹部が赤色に染色され、凸部の青色が残っ
た立体柄を呈するものであった。 実施例３ ニッカガム３Ａ（加工澱粉、日華化学（株）製）６部、
水５４部からなる元糊６０部に、炭酸グアニジン１５
部、カオリン１０部、分散染料（Ｃ．Ｉ． Ｄｉｓｐｅ
ｒｓｅ Ｒｅｄ ９２）２部、水１３部を混合し、赤色
の印捺糊を調製した。前記の青色に染色されたポリエス
テル起毛布上にこの印捺糊を柄状に印捺し、乾燥した。
次いで、ＨＴスチーマー（ＨＴ−３−５５０型：辻井染
機工業（株）製）を用いて１８０℃で７分間のスチーミ
ング処理を施し、その後、水洗、ソーピングを経て乾燥
した。印捺糊のポリエステル起毛布に対する付着率は、
平均１１０重量％であった。The polyester raising cloth thus obtained is
As in Example 1, the printed portion was etched and discharged, so that the concave portion was dyed red and the convex portion exhibited a three-dimensional pattern in which blue remained. Example 3 6 parts of Nikka gum 3A (processed starch, manufactured by Nikka Chemical Co., Ltd.)
Guanidine carbonate 15 is added to 60 parts of original paste consisting of 54 parts of water.
Part, kaolin 10 parts, disperse dye (CI Dispe)
rs Red 92) 2 parts and water 13 parts were mixed to prepare a red printing paste. The printing paste was printed in a pattern on the brushed polyester cloth dyed in blue and dried.
Next, a steaming treatment was performed at 180 ° C. for 7 minutes using an HT steamer (HT-3-550: manufactured by Tsujii Dyeing Machinery Co., Ltd.), followed by washing with water and drying through soaping. The adhesion rate of the printing paste to the polyester brushed cloth is
The average was 110% by weight.
【００１６】かくして得られたポリエステル起毛布は、
実施例１と同様であり、印捺部が抜蝕され、抜染された
ことにより、凹部が赤色に染色され、凸部の青色が残っ
た立体柄を呈するものであった。 比較例１ 実施例３において、炭酸グアニジン１５部に代えて４８
％水酸化ナトリウム水溶液１５部を用いた以外は、実施
例３と同様にして抜染加工した。The polyester raising cloth thus obtained is
As in Example 1, the printed portion was etched and discharged, so that the concave portion was dyed red and the convex portion exhibited a three-dimensional pattern in which blue remained. Comparative Example 1 In Example 3, 48 parts of guanidine carbonate were used instead of 15 parts.
A discharge printing process was performed in the same manner as in Example 3 except that 15 parts of a 15% aqueous sodium hydroxide solution was used.
【００１７】この加工では、抜染加工されたポリエステ
ル起毛布は得られたが、抜染部のエッジングが不十分で
あり、赤色の変色も大きいものであった。水酸化ナトリ
ウムの添加量を増やすと、エッジング効果は大きくなっ
たものの、印捺糊の粘度が保てなくなった。In this processing, a polyester brushed cloth subjected to discharge printing was obtained. However, the edging of the discharge-printed portion was insufficient, and red discoloration was large. When the amount of sodium hydroxide added was increased, the edging effect was increased, but the viscosity of the printing paste could not be maintained.
【００１８】[0018]
【発明の効果】本発明によれば、型際のシャープな模様
および凹凸模様を有し、また色糊中の染料変色がなく、
鮮明な色相を有する柄部が形成され、意匠性に優れた抜
染加工合成系繊維材料を簡易に、かつ、安全に提供でき
る。According to the present invention, it has a sharp pattern and a concave-convex pattern at the time of molding, and there is no discoloration of the dye in the color paste.
A pattern portion having a clear hue is formed, and a discharge-printed synthetic fiber material excellent in design can be easily and safely provided.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4H057 AA01 AA02 CA06 CA23 CA33 CB04 CB15 CB38 CB47 CB90 CC01 CC02 DA01 DA17 DA20 DA30 DA34 GA04 GA13 GA90 HA01 HA19 JA10 JA11 JB03 4L031 AA12 AA18 AA20 AB01 BA34 CA07 CA08 DA00 DA09 4L033 AA04 AA07 AA08 AB01 AC15 BA81 CA07 4L049 AA06 AB00 BA21 BA25 BA36 BA39 DA25 ──────────────────────────────────────────────────続 き Continued on front page F-term (reference) 4H057 AA01 AA02 CA06 CA23 CA33 CB04 CB15 CB38 CB47 CB90 CC01 CC02 DA01 DA17 DA20 DA30 DA34 GA04 GA13 GA90 HA01 HA19 JA10 JA11 JB03 4L031 AA12 AA18 AA20 AB01 BA34 CA07 A08 DA00 AA07 AA08 AB01 AC15 BA81 CA07 4L049 AA06 AB00 BA21 BA25 BA36 BA39 DA25
Claims (7)
する合成系繊維材料用抜染剤。1. A discharge agent for synthetic fiber materials containing guanidine carbonate and an adsorbent.
する抜染剤を用いる合成系繊維材料の抜染加工方法。2. A discharge printing method for a synthetic fiber material using a discharge agent containing guanidine carbonate and an adsorptive substance.
する印捺糊を用いる合成系繊維材料の抜染加工方法。3. A discharge printing method for a synthetic fiber material using a printing paste containing guanidine carbonate and an adsorptive substance.
０．０重量％の量で含まれる請求項２または３記載の方
法。4. The guanidine carbonate is contained in the printing paste in an amount of 0.1 to 5%.
4. A method according to claim 2 or 3 wherein it is contained in an amount of 0.0% by weight.
湿熱処理を施す、請求項２〜４のいずれかに記載の方
法。5. The method according to claim 2, wherein the printing paste is printed, followed by a dry heat treatment or a wet heat treatment.
リアミド繊維またはこれらの繊維と他の繊維との複合繊
維からなる、請求項２〜５のいずれかに記載の方法。6. The method according to claim 2, wherein the synthetic fiber material comprises a polyester fiber, a polyamide fiber, or a composite fiber of these fibers and another fiber.
する抜染剤を用いて抜染加工された合成系繊維材料。7. A synthetic fiber material subjected to discharge printing using a discharge agent containing guanidine carbonate and an adsorbent substance.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10268143A JP2977546B1 (en) | 1998-09-22 | 1998-09-22 | Discharge agent for synthetic fiber material, discharge printing method, and discharge synthetic fiber material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10268143A JP2977546B1 (en) | 1998-09-22 | 1998-09-22 | Discharge agent for synthetic fiber material, discharge printing method, and discharge synthetic fiber material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2977546B1 JP2977546B1 (en) | 1999-11-15 |
| JP2000096461A true JP2000096461A (en) | 2000-04-04 |
Family
ID=17454500
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10268143A Expired - Fee Related JP2977546B1 (en) | 1998-09-22 | 1998-09-22 | Discharge agent for synthetic fiber material, discharge printing method, and discharge synthetic fiber material |
Country Status (1)
| Country | Link |
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| JP (1) | JP2977546B1 (en) |
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|---|---|---|---|---|
| WO2005005560A1 (en) * | 2003-07-15 | 2005-01-20 | Seiren Co., Ltd. | 3-d pattern forming ink-jet-use ink, 3-d pattern forming method using it, and 3-d pattern formed cloth obtained by it |
| WO2005033221A1 (en) * | 2003-09-30 | 2005-04-14 | Seiren Co., Ltd. | Inkjet discharge printing ink and process for producing polyester fiber fabric having undergone discharge printing |
| JP2005126861A (en) * | 2003-10-24 | 2005-05-19 | Seiren Co Ltd | Method for producing fiber fabric having formed pattern |
| JP2007154354A (en) * | 2005-12-05 | 2007-06-21 | Dainippon Ink & Chem Inc | Method for processing synthetic fiber napped fabric and surface-treated synthetic fiber napped fabric |
| KR101162253B1 (en) | 2009-06-23 | 2012-07-03 | 태광개발(주) | dischargingagent manufacturing methods and dischargingagent composition |
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| WO2005005560A1 (en) * | 2003-07-15 | 2005-01-20 | Seiren Co., Ltd. | 3-d pattern forming ink-jet-use ink, 3-d pattern forming method using it, and 3-d pattern formed cloth obtained by it |
| JPWO2005005560A1 (en) * | 2003-07-15 | 2007-09-20 | セーレン株式会社 | Three-dimensional pattern forming inkjet ink, three-dimensional pattern forming method using the same, and three-dimensional pattern forming fabric obtained thereby |
| US7553009B2 (en) | 2003-07-15 | 2009-06-30 | Seiren Company, Ltd | Ink jet printing ink for forming three-dimensional patterns, process for forming three-dimensional patterns using the same and cloth having three-dimensional patterns obtained thereby |
| CN100537675C (en) * | 2003-07-15 | 2009-09-09 | 世联株式会社 | Ink jet printing ink for forming three-dimensional patterns, process for forming three-dimensional patterns using the same and cloth having three-dimensional patterns obtained thereby |
| JP4673219B2 (en) * | 2003-07-15 | 2011-04-20 | セーレン株式会社 | Three-dimensional pattern forming inkjet ink, three-dimensional pattern forming method using the same, and three-dimensional pattern forming fabric obtained thereby |
| WO2005033221A1 (en) * | 2003-09-30 | 2005-04-14 | Seiren Co., Ltd. | Inkjet discharge printing ink and process for producing polyester fiber fabric having undergone discharge printing |
| JP4897291B2 (en) * | 2003-09-30 | 2012-03-14 | セーレン株式会社 | Discharge ink for inkjet and method for producing discharged polyester fiber fabric |
| JP2005126861A (en) * | 2003-10-24 | 2005-05-19 | Seiren Co Ltd | Method for producing fiber fabric having formed pattern |
| JP4563666B2 (en) * | 2003-10-24 | 2010-10-13 | セーレン株式会社 | Method for producing fiber fabric with pattern formed |
| JP2007154354A (en) * | 2005-12-05 | 2007-06-21 | Dainippon Ink & Chem Inc | Method for processing synthetic fiber napped fabric and surface-treated synthetic fiber napped fabric |
| KR101162253B1 (en) | 2009-06-23 | 2012-07-03 | 태광개발(주) | dischargingagent manufacturing methods and dischargingagent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2977546B1 (en) | 1999-11-15 |
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