JPH02113845A - Preservation of meat - Google Patents

Preservation of meat

Info

Publication number
JPH02113845A
JPH02113845A JP63266241A JP26624188A JPH02113845A JP H02113845 A JPH02113845 A JP H02113845A JP 63266241 A JP63266241 A JP 63266241A JP 26624188 A JP26624188 A JP 26624188A JP H02113845 A JPH02113845 A JP H02113845A
Authority
JP
Japan
Prior art keywords
meat
extract
preservative
licorice
food
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63266241A
Other languages
Japanese (ja)
Inventor
Hiroki Goto
後藤 浩樹
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Idemitsu Petrochemical Co Ltd
Original Assignee
Idemitsu Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Idemitsu Petrochemical Co Ltd filed Critical Idemitsu Petrochemical Co Ltd
Priority to JP63266241A priority Critical patent/JPH02113845A/en
Publication of JPH02113845A publication Critical patent/JPH02113845A/en
Pending legal-status Critical Current

Links

Abstract

PURPOSE:To improve the preservability of meat in high safety without influencing the appearance of meat by extracting licorice using a supercritical gas extraction process and adding a preservative containing said extract as an active component to the meat. CONSTITUTION:Licorice is extracted by supercritical gas extraction process (preferably using carbon dioxide under a pressure of 70-500kg/cm<2>.G at 30-100 deg.C) and the obtained extract is used as a preservative. Meat is sprayed with or immersed in the preservative.

Description

【発明の詳細な説明】 〔産業上の利用分野] 本発明は肉類の保存方法に関し、詳しくは超臨界ガス抽
出法により1↑草からiStられる安全性が高く、食品
の外観にも影響の少ない抗菌物質を添加した肉類の保存
方法に関する。
[Detailed Description of the Invention] [Field of Industrial Application] The present invention relates to a method for preserving meat, and more specifically, it is highly safe to produce iSt from 1↑ grass using a supercritical gas extraction method, and has little effect on the appearance of food. This article relates to a method for preserving meat to which antibacterial substances have been added.

〔従来の技術および発明が解決しようとする課題]近年
、様々な加工食品の生産、流通が盛んであり、その過程
において安全に食品の品質を保持、保存できる食品保存
事4が望まれているやそのため。
[Prior art and problems to be solved by the invention] In recent years, the production and distribution of various processed foods has been active, and food preservation methods 4 that can safely maintain and preserve food quality during this process are desired. Or for that reason.

合成保存ネ−1の使用も考えられるが、安全性の点から
使用規準や消費者の考え方などが厳しくなっており、食
品への使用は避けられる傾向にある。そこで、安全性の
高い天然物による食品の品質保持、保存方法が望まれて
いる。
Although it is possible to use synthetic preserved Na-1, the use standards and consumer attitudes have become stricter from a safety standpoint, and its use in food products tends to be avoided. Therefore, a method for maintaining and preserving food quality using highly safe natural products is desired.

1↑草は、日本薬局方にも記載されている通り、古くか
ら知られた生薬の一種であり、甘草床や甘草エキスが鎮
咳、去演草として利用されている。
1↑As described in the Japanese Pharmacopoeia, licorice is a type of herbal medicine that has been known for a long time, and licorice bed and licorice extract are used as antitussives and antitussives.

甘草に含まれる代表的成分はグリチルリチンと言われる
1↑味の強いトリテルペン系サポニンであり、l↑味料
、タバコ矯味料の他、医薬品にも利用されている。一方
、グリチルリチン以外の成分にも有用な成分があり、そ
の中でもフラボノイド類縁化合物が抗菌活性を示すこと
等が知られている。この抗菌活性物質を抽出するにあた
っては、一般には有機溶媒が使用されている。例えば、
エタノールによる抽出法、アセトンや酢酸エチルなどの
含酸素有機溶媒、ベンゼンやl・ルエンなどの芳香族系
有機)容媒、ヘキサンなどの脂肪族系有機溶媒などを単
独または組りる方法(特開昭60−176555号公報
、同59−46210号公報1同60−172928号
公報)等が知られている。しかしながら、エタノールを
用いる方法では抗菌性物質とともに着色成分1着臭成分
なども同時に抽出され、食品に添加した場合に色調や独
特の臭いなどの点で使用量が限定されてしまったり、抽
出物中の抗菌性を示す物質の含有量が相対的に低くなる
等の問題点がある。また、その他の有機溶媒を用いる:
!5−Ys、会与は、抗菌物質を抽出できるものの毒性
のある溶媒を用いるため安全性の点で食品に使用するこ
とは難しい。
A typical component contained in licorice is glycyrrhizin, a triterpene saponin with a strong taste, which is used in flavoring agents, tobacco flavorings, and pharmaceuticals. On the other hand, there are other useful components other than glycyrrhizin, and among these, flavonoid-related compounds are known to exhibit antibacterial activity. An organic solvent is generally used to extract this antibacterial active substance. for example,
Extraction methods using ethanol, oxygen-containing organic solvents such as acetone and ethyl acetate, aromatic organic solvents such as benzene and l. Publication No. 60-176555, Publication No. 59-46210, Publication No. 60-172928), etc. are known. However, in the method using ethanol, coloring components and odorous components are extracted at the same time as antibacterial substances, and when added to food, the amount used is limited due to color tone and unique odor. There are problems such as the relatively low content of substances exhibiting antibacterial properties. Also, using other organic solvents:
! Although 5-Ys can extract antibacterial substances, it is difficult to use in foods from the safety point of view because it uses a toxic solvent.

〔課題を解決するための手段〕[Means to solve the problem]

そこで、本発明者は上記問題点を解消した安全で、かつ
食品に添加しても外観に影響のない保存料を用いて肉類
を保存する方法を開発すべく鋭意研究を車ねた結果、超
臨界ガス抽出法により得られる甘草の抽出物を用いれば
よいごとを見出し、本発明を完成させた。
Therefore, the present inventor conducted intensive research to develop a method for preserving meat using a safe preservative that solves the above problems and does not affect the appearance even when added to food. The inventors discovered that it is advantageous to use a licorice extract obtained by the critical gas extraction method, and completed the present invention.

すなわち、本発明は超臨界ガス抽出法によってjニドら
れる甘草の抽出物を有効成分とする保存f」を添加する
ことを特徴とする肉類の保存方法を従供するものである
That is, the present invention provides a method for preserving meat, which is characterized by adding a preservation agent containing as an active ingredient an extract of licorice extracted by a supercritical gas extraction method.

本発明において、肉類とは牛肉、豚肉等の畜肉類や魚肉
の他、ハム、ウィンナ−ソーセージ、ミドボール等の肉
類加工食品を意味する。
In the present invention, meat means livestock meat such as beef and pork, fish meat, and processed meat foods such as ham, Vienna sausage, and midballs.

本発明で用いる甘草は、原木のままでもよく、さらには
破砕、あるいは粉砕されたもの、温水。
The licorice used in the present invention may be raw wood, crushed or crushed, or heated with hot water.

希アンモニア水などでグリチルリチンを抽出した残渣の
いずれであってもよい。
It may be any residue obtained by extracting glycyrrhizin with dilute ammonia water or the like.

一ヒ記甘草から抗菌活性物質を抽出するにあたっては、
超臨界ガス抽出法を用いる。超臨界ガスとしては、巴1
界条件が温和であり食品に用いても無害でかつ不活性で
ある点で、二酸化炭素を用いることが好ましい。二酸化
炭素を用いた場合の抽出条件は、圧カフ0〜500 k
g、/cIil−G、温度30〜100°Cの範囲であ
り、代表的な抽出条件は圧力200 kg/Cl1l−
G、温度40゛Cである。また、抽出効果を上げるため
にエタノールを0〜50・5″、= 1%、好ましくは
5〜20W【% 程度加えることが好ましい。有効成分
を含んだ超臨界ガスは、常法に従って減圧、分剤を行な
って抽出物を得る。
In extracting antibacterial active substances from licorice,
Uses supercritical gas extraction method. As a supercritical gas, Tomoe 1
It is preferable to use carbon dioxide because its environmental conditions are mild and it is harmless and inert even when used in foods. Extraction conditions when using carbon dioxide are pressure cuff 0-500 k
g,/cIil-G, temperature ranges from 30 to 100°C, typical extraction conditions are pressure 200 kg/Cl1l-
G, temperature is 40°C. In addition, in order to increase the extraction effect, it is preferable to add ethanol in an amount of 0 to 50.5", = 1%, preferably 5 to 20 W[%. The supercritical gas containing the active ingredient is depressurized and separated according to the usual method. to obtain an extract.

このようにして得られた抽出物は、溶剤抽出によるもの
よりも抗菌活性の優れた画分を選択的に含んでおり、色
1)4も淡黄色と改善され、着色成分も含んでいない。
The extract thus obtained selectively contains a fraction with better antibacterial activity than that obtained by solvent extraction, and the color 1) 4 has also been improved to pale yellow, and it does not contain any colored components.

本発明では、上記方法により得られた抽出物を単独で保
存料として肉類に添加してもよく、また抽出物にエタノ
ール、有機酸またはその塩、グリソン、リヅチーム等の
食品衛生法上使用制限のない食品保存効果のある物質を
1種もしくは2種以上併用してもよい。有機酸またはそ
の塩としては、クエン酸、コハク酸、リンゴ酸、酢酸な
らびにそれらの塩を挙げることができる。
In the present invention, the extract obtained by the above method may be added alone to meat as a preservative, or the extract may contain substances such as ethanol, organic acids or their salts, grison, and liduzime whose use is restricted under the Food Sanitation Act. One type or two or more types of substances that have a food preservation effect may be used in combination. Examples of organic acids or salts thereof include citric acid, succinic acid, malic acid, acetic acid, and salts thereof.

添加方法は、肉類には上記保存料を液状とし、左面に噴
霧するか、または、夜に1浸漬させてもよい。
The method of adding the preservative to meat is to make the above preservative in liquid form and spray it on the left side of the meat, or to soak it overnight.

肉類IJII玉食品には製造工程の途中の段階で原料と
混和、混合するか、または製品となったものに噴霧して
もよい。保存料のlト加量は11位抽出物を中独で用い
る場合は、原料に対して0.04〜0.1%、往Q抽出
物と食品保存効果のある物質を併用する場&は、原料に
対して甘草抽出物0.02〜0.1%、食品保存効果の
ある物質として有機酸またはその塩を用いる場合は0.
04〜0.5%、グリシンを用いる場合は0.1〜0.
5%、リヅチームを用いる場合は0.002〜0.01
%とすればよい。
For meat IJII food products, it may be mixed with the raw materials during the manufacturing process, or it may be sprayed onto the finished product. The amount of preservatives added is 0.04 to 0.1% based on the raw material when using the 11th extract in China and Germany, and when using the extract in combination with a substance that has a food preservative effect. , 0.02 to 0.1% of licorice extract based on the raw material, and 0.0% when using an organic acid or its salt as a substance with a food preservation effect.
04-0.5%, 0.1-0.0% when using glycine.
5%, 0.002-0.01 when using Rizteam
%And it is sufficient.

〔実施例〕〔Example〕

次に、本発明を実施例により説明する。 Next, the present invention will be explained by examples.

実験例 1↑草500gを温度40°C1圧力200kq/cイ
・を得た。
Experimental Example 1↑ 500g of grass was obtained at a temperature of 40°C and a pressure of 200kq/c.

一方、1↑草4a 500 gを10倍星のエタノール
に浸漬し、黒褐色の抽出物830gを得た。
On the other hand, 500 g of 1↑Grass 4a was immersed in 10 times star ethanol to obtain 830 g of a dark brown extract.

得られた抽出物AおよびBに゛ついて、ラクトバー1−
ルス・プランクラに対する最小生育阻止濃度(M、i、
C,)を測定したところ、抽出物Aは20ppmであり
、抽出物Bはlooppmであった。
Regarding the obtained extracts A and B, Lactovar 1-
Minimum inhibitory concentration (M, i,
C,) was measured and found to be 20 ppm for extract A and looppm for extract B.

この結果より、抽出物への方が抗菌活性が優れているこ
とがわかった。
These results showed that the extract had better antibacterial activity.

実施例1〜4および比較例1〜3 合い挽肉500F暦、玉ねぎ80g、パン粉20g、塩
5gおよび水20 gをよく混合し、第1表に示した所
定!tの物質を添加して、さらにより714合した。混
合物を約20gづつボール状に成形し20分間蒸した後
、放冷し、滅菌したビニール袋に封入して製品I〜7を
得た。なお、甘草抽出物は前記実験例で得られた抽出物
Aを用いた。
Examples 1 to 4 and Comparative Examples 1 to 3 500F minced meat, 80 g of onion, 20 g of bread crumbs, 5 g of salt, and 20 g of water were thoroughly mixed and the mixture was prepared as specified in Table 1. t material was added and further combined. The mixture was formed into balls of about 20 g each, steamed for 20 minutes, allowed to cool, and sealed in sterilized plastic bags to obtain products I to 7. As the licorice extract, extract A obtained in the above experimental example was used.

iiトられた装晶1〜7を20°Cにて保存し、防腐効
果を調べた。評価は経巨的に一般生菌数をηlす定する
ことによりj”;””:た。この結果を第2表に示す。
ii The prepared crystals 1 to 7 were stored at 20°C and the preservative effect was examined. The evaluation was carried out by determining the number of general viable bacteria over time. The results are shown in Table 2.

実施例5〜8および比較例4〜5 豚肉700 g、馬肉300gにでん粉、調味オ′15
六率講−Nを適宜加え、サイレント・カッターにて練り
合わせ、第3表に示した所定鼠の物質を添加してよく混
和後、羊腸ケーシングに充填し、72°Cご20分間加
熱殺菌して製品8〜13を得た。なお、往草抽出物は前
記実験例で得られた抽出物へを用いた。
Examples 5 to 8 and Comparative Examples 4 to 5 700 g of pork, 300 g of horse meat, starch, seasoning o'15
Add Rokusanko-N as appropriate, knead with a silent cutter, add the specified substances shown in Table 3, mix well, fill in sheep intestine casings, and heat sterilize at 72°C for 20 minutes. Products 8-13 were obtained. Incidentally, the extract obtained in the above experimental example was used as the Ogusa extract.

第  3 表 第 表 得られた製品8〜13を30’Cにて保存し、ネトとカ
ビの発生状況を観察した。この結果を第4表に示す。
Table 3 The obtained products 8 to 13 were stored at 30'C and observed for growth of mold and mildew. The results are shown in Table 4.

(発明の効果〕 本発明によれば、安全で、がっ肉類の外fiJJに影響
を与えずに保存性を高めることができる。
(Effects of the Invention) According to the present invention, it is possible to safely enhance the preservability of meat without affecting the external fiJJ of the meat.

Claims (1)

【特許請求の範囲】[Claims] (1)超臨界ガス抽出法によって得られる甘草の抽出物
を有効成分とする保存料を添加することを特徴とする肉
類の保存方法。
(1) A method for preserving meat, characterized by adding a preservative whose active ingredient is a licorice extract obtained by a supercritical gas extraction method.
JP63266241A 1988-10-24 1988-10-24 Preservation of meat Pending JPH02113845A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63266241A JPH02113845A (en) 1988-10-24 1988-10-24 Preservation of meat

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63266241A JPH02113845A (en) 1988-10-24 1988-10-24 Preservation of meat

Publications (1)

Publication Number Publication Date
JPH02113845A true JPH02113845A (en) 1990-04-26

Family

ID=17428236

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63266241A Pending JPH02113845A (en) 1988-10-24 1988-10-24 Preservation of meat

Country Status (1)

Country Link
JP (1) JPH02113845A (en)

Similar Documents

Publication Publication Date Title
AU703527B2 (en) Processed meat, meat food material using the same, and production method for processed meat
PL117372B1 (en) Method of manufacturing liquid smoke concentrates
JPS6228664B2 (en)
CN108185313A (en) Natural anti-oxidation composite pickling agent and its preparation method and application
CN106174120A (en) A kind of Qiang flavored preserved pork and preparation method thereof
CN105285773A (en) Production method of liquor-preserved crab
JP7138362B2 (en) Cold smoked meat product and its manufacturing method
CN107981253B (en) Salted fish salt and preparation process thereof
KR100651160B1 (en) Method for treating skate ray and delaying decomposition of food made of treated skate ray
KR100625272B1 (en) Process for producing smoked chicken
EP3247228B1 (en) Cellobiose in fermented meat products and sausages
CN106577988A (en) Natural compound meat preservative and preparation method thereof
RU2586916C1 (en) Method of salting delicatessen fish
JPH02113845A (en) Preservation of meat
Pegg et al. 12 Processing of Nitrite-Free Cured Meats
KR20180041273A (en) A method of producing ham or sausage composition containing yucca extracts and ham or sausage produced by the same
JPH07327638A (en) Fish and meat processed foods containing propolis
JPH02113846A (en) Preservation of pickles
KR101593173B1 (en) Method of Slice of Dried Chicken
JP2005058003A (en) Method for producing dried fish
KR20130077399A (en) The manufacturing method of fermentation sausages additional herb
CN107439662A (en) A kind of preparation method of the pork bacon with sweet osmanthus fragrance
RU2240006C2 (en) Composite for protection of foodstuffs and method for its applying for protection of foodstuffs from loss and microbiological spoiling
Zeitoun et al. Natural Antioxidant and Antimicrobial and its Relation to Quality and Safety of Smoked Mullet Fish
RU2158089C1 (en) Meat preservative