JPH0153452B2 - - Google Patents
Info
- Publication number
- JPH0153452B2 JPH0153452B2 JP56026631A JP2663181A JPH0153452B2 JP H0153452 B2 JPH0153452 B2 JP H0153452B2 JP 56026631 A JP56026631 A JP 56026631A JP 2663181 A JP2663181 A JP 2663181A JP H0153452 B2 JPH0153452 B2 JP H0153452B2
- Authority
- JP
- Japan
- Prior art keywords
- photosensitive
- cobalt
- salt
- complex
- image
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000463 material Substances 0.000 claims description 17
- 150000001638 boron Chemical class 0.000 claims description 7
- 150000004700 cobalt complex Chemical class 0.000 claims description 6
- -1 silver halide Chemical class 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 2
- 239000004332 silver Substances 0.000 claims description 2
- 230000001678 irradiating effect Effects 0.000 claims 1
- 150000003839 salts Chemical class 0.000 description 10
- 239000000203 mixture Substances 0.000 description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 9
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 6
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 6
- 239000007864 aqueous solution Substances 0.000 description 6
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 5
- 108010010803 Gelatin Proteins 0.000 description 5
- 229920000159 gelatin Polymers 0.000 description 5
- 239000008273 gelatin Substances 0.000 description 5
- 235000019322 gelatine Nutrition 0.000 description 5
- 235000011852 gelatine desserts Nutrition 0.000 description 5
- 239000011521 glass Substances 0.000 description 5
- 239000003446 ligand Substances 0.000 description 5
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical class OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- 229910017052 cobalt Inorganic materials 0.000 description 4
- 239000010941 cobalt Substances 0.000 description 4
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical group [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 4
- 150000003378 silver Chemical class 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- HVLJEMXDXOTWLV-UHFFFAOYSA-N 2,4-dichloronaphthalen-1-ol Chemical compound C1=CC=C2C(O)=C(Cl)C=C(Cl)C2=C1 HVLJEMXDXOTWLV-UHFFFAOYSA-N 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 3
- 229910052796 boron Inorganic materials 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 2
- GRYLNZFGIOXLOG-UHFFFAOYSA-N Nitric acid Chemical class O[N+]([O-])=O GRYLNZFGIOXLOG-UHFFFAOYSA-N 0.000 description 2
- 206010034972 Photosensitivity reaction Diseases 0.000 description 2
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- LOEIHGYNJPKGLG-UHFFFAOYSA-N cobalt;ethane-1,2-diamine Chemical compound [Co].NCCN.NCCN.NCCN LOEIHGYNJPKGLG-UHFFFAOYSA-N 0.000 description 2
- 150000001875 compounds Chemical class 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 229910052736 halogen Inorganic materials 0.000 description 2
- 150000002367 halogens Chemical class 0.000 description 2
- 229910017604 nitric acid Inorganic materials 0.000 description 2
- 230000036211 photosensitivity Effects 0.000 description 2
- 229910052708 sodium Inorganic materials 0.000 description 2
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- XRZDIHADHZSFBB-UHFFFAOYSA-N 3-oxo-n,3-diphenylpropanamide Chemical compound C=1C=CC=CC=1NC(=O)CC(=O)C1=CC=CC=C1 XRZDIHADHZSFBB-UHFFFAOYSA-N 0.000 description 1
- XBTWVJKPQPQTDW-UHFFFAOYSA-N 4-n,4-n-diethyl-2-methylbenzene-1,4-diamine Chemical compound CCN(CC)C1=CC=C(N)C(C)=C1 XBTWVJKPQPQTDW-UHFFFAOYSA-N 0.000 description 1
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 241001061127 Thione Species 0.000 description 1
- DGEZNRSVGBDHLK-UHFFFAOYSA-N [1,10]phenanthroline Chemical group C1=CN=C2C3=NC=CC=C3C=CC2=C1 DGEZNRSVGBDHLK-UHFFFAOYSA-N 0.000 description 1
- HZRHYYCODYDSJY-UHFFFAOYSA-N [Co].NCCCN.C(CCN)N.C(CCN)N Chemical compound [Co].NCCCN.C(CCN)N.C(CCN)N HZRHYYCODYDSJY-UHFFFAOYSA-N 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 229940006460 bromide ion Drugs 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 150000001868 cobalt Chemical class 0.000 description 1
- UNCUMLYFHZICFS-UHFFFAOYSA-N cobalt propane-1,2-diamine Chemical compound [Co].C(C(C)N)N.C(C(C)N)N.C(C(C)N)N UNCUMLYFHZICFS-UHFFFAOYSA-N 0.000 description 1
- 150000004985 diamines Chemical class 0.000 description 1
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 1
- 229910052753 mercury Inorganic materials 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 229920000768 polyamine Polymers 0.000 description 1
- 229910052700 potassium Inorganic materials 0.000 description 1
- 239000011591 potassium Substances 0.000 description 1
- 239000002244 precipitate Substances 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 230000001568 sexual effect Effects 0.000 description 1
- 229910000029 sodium carbonate Inorganic materials 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000003232 water-soluble binding agent Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03C—PHOTOSENSITIVE MATERIALS FOR PHOTOGRAPHIC PURPOSES; PHOTOGRAPHIC PROCESSES, e.g. CINE, X-RAY, COLOUR, STEREO-PHOTOGRAPHIC PROCESSES; AUXILIARY PROCESSES IN PHOTOGRAPHY
- G03C1/00—Photosensitive materials
- G03C1/67—Compositions containing cobalt salts or cobalt compounds as photosensitive substances
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Non-Silver Salt Photosensitive Materials And Non-Silver Salt Photography (AREA)
Description
【発明の詳細な説明】
本発明は安価で現像可能な非銀塩系の感光性記
録材料に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an inexpensive and developable non-silver salt photosensitive recording material.
感光性記録材料としては銀塩が古くから用いら
れているが、近年は銀資源の有限性に対する不安
や価格の膳貴の問題があり、非銀塩を用いる感光
材料の開発が要望されている。 Silver salts have been used as photosensitive recording materials for a long time, but in recent years there have been concerns about the limited availability of silver resources and problems with pricing, and there has been a demand for the development of photosensitive materials that use non-silver salts. .
しかし非銀塩の感光性記録材料は一般に銀塩と
比較して感度が小さい。これは銀塩では現像によ
り感度を著しく増巾することが可能であるためで
あり、非銀塩の感光材料についても現像により感
度を増巾することが望ましい。 However, non-silver salt photosensitive recording materials generally have lower sensitivity than silver salts. This is because the sensitivity of silver salts can be significantly increased by development, and it is also desirable to increase the sensitivity of non-silver salt photosensitive materials by development.
本発明者らは、安価な非銀塩の材料を用いて光
画像を記録し、これを現像することのできる感光
性記録材料について鋭意検討した結果、次のよう
な本発明に至つた。即ち、本発明は第三コバルト
の錯塩を結合剤とともに支持体に塗布し、乾燥し
たもので、その上に画像状に露光し、その後、通
常のカラー写真用現像液で現像することのできる
感光性記録材料である。 The present inventors have conducted intensive studies on photosensitive recording materials that can record and develop optical images using inexpensive non-silver salt materials, and as a result, have arrived at the following invention. That is, in the present invention, a complex salt of tertiary cobalt is applied to a support together with a binder, dried, and then imagewise exposed to light, which can then be developed with a common color photographic developer. It is a sexual recording material.
本発明で用いる感光成分は、コバルト錯体の有
機ホウ素塩であり、このものは、コバルト錯体塩
と有機ホウ素塩とを反応させることにより得るこ
とができる。 The photosensitive component used in the present invention is an organic boron salt of a cobalt complex, which can be obtained by reacting a cobalt complex salt and an organic boron salt.
〔CoK〕・Ｘ＋（Pn）4B・Ｙ→〔Co〕
・Ｂ（Pn）4＋XY
前記式中、〔CoK〕はコバルト錯体を表わし、
Ｘはハロゲン、無機酸（硝酸、硫酸など）の残基
であり、Ｒは有機基、例えばメチル、エチル、プ
ロピル、ヘキシル、シクロヘキシルなどのアルキ
基、フエニル基、トリル、キシリルなどのアリル
基であり、Ｙはナトリウム、カリウムなどのチオ
ンである。 [CoK]・X+(Pn) 4 B・Y→[Co]・B(Pn) 4 +XY In the above formula, [CoK] represents a cobalt complex,
and , Y is a thione such as sodium or potassium.
次に本発明で用いるコバルト錯体の有機ホウ素
塩の具体例を示す。 Next, specific examples of the organic boron salt of the cobalt complex used in the present invention will be shown.
ここでＲはアルキル基、アリール基である。こ
この式のコバルト錯体部分は二座配位子が第二コ
バルトに３個配位子して、６配位錯体を形成して
いる。 Here, R is an alkyl group or an aryl group. In the cobalt complex portion of this formula, three bidentate ligands are attached to secondary cobalt to form a six-coordination complex.
本発明に用いることができる配位子の代表例と
しては以下に示すポリアミン系のものが挙げられ
る。エチレンジアミン、プロピレンジアミン、ト
リルチレンジアミン、ジエチレントリアミン、ト
リエチレンテトラミン、例えばエチレンジアミン
錯塩は以下の構造をとつていると考えられる。 Typical examples of the ligands that can be used in the present invention include the following polyamine-based ligands. Ethylenediamine, propylenediamine, tolylethylenediamine, diethylenetriamine, triethylenetetramine, such as ethylenediamine complex salt, is thought to have the following structure.
二座配位のジアミン錯体の他に全てアンモニア
が配位した以下の構造の化合物も本発明に用いる
ことができる。 In addition to bidentate diamine complexes, compounds having the following structure in which all ammonia is coordinated can also be used in the present invention.
また窒素を含む複素環状化合物も本発明に用い
ることができる。代表例としてはフエナントロリ
ンがあり、その場合の錯塩の化学構造は以下に例
示されるようである。 Further, nitrogen-containing heterocyclic compounds can also be used in the present invention. A typical example is phenanthroline, and the chemical structure of the complex salt in that case is exemplified below.
またこれらの錯塩の配位子の一部を別の配位子
で置き換えた化合物も本発明に用いることができ
る。このような例としては〔Co（NH3）5X〕〔Ｂ
（C6H5）4〕3〔Co（en）2X2〕〔Ｂ（C6H5）4〕3があり
、
Ｘは例えば塩素イオン、臭素イオン、ニトロイオ
ンなどであり、enはエチレンジアミンを表わし
ている。 Compounds in which some of the ligands of these complex salts are replaced with other ligands can also be used in the present invention. An example of this is [Co(NH 3 ) 5 X] [B
(C 6 H 5 ) 4 ] 3 [Co(en) 2 X 2 ] [B(C 6 H 5 ) 4 ] 3 ,
X is, for example, a chloride ion, bromide ion, nitro ion, etc., and en represents ethylenediamine.
以上の錯塩は通常ハロゲン、硝酸、硫酸等の塩
として知られているもので、このような塩では水
溶性である。しかし上のような塩としては、感光
性が小さく、このままでは感光材料として用いる
ことができない。しかしこれをテトラフエニルホ
ウ素塩にすると水に不溶性となり、感光性が著し
く向上する。 The above complex salts are generally known as salts of halogen, nitric acid, sulfuric acid, etc., and such salts are water-soluble. However, the above salts have low photosensitivity and cannot be used as photosensitive materials as they are. However, when it is made into a tetraphenyl boron salt, it becomes insoluble in water and the photosensitivity is significantly improved.
本発明に用いる錯塩は以下の方法で合成する。
即ち、上述の錯体のハロゲン、硝酸、硫酸の塩を
文献に記載の方法で合成する（例えば日本化学会
編、新実験化学講座８、丸善（1977））、これを適
当量の水に溶解する、同じく市販のテトラフエニ
ルホウ素ナトリウムを適当量の水に溶解する、両
溶液を２つの化合物の割合が１：３になるように
混合して沈殿を生ぜしめ、ろ過する。こうして合
成したテトラフエニルホウ素塩は一般に水に難溶
で、アルコール、アセトン等の有機溶媒に可溶で
ある。 The complex salt used in the present invention is synthesized by the following method.
That is, the salts of halogen, nitric acid, and sulfuric acid of the above-mentioned complex are synthesized by the method described in the literature (for example, edited by the Chemical Society of Japan, New Experimental Chemistry Course 8, Maruzen (1977)), and this is dissolved in an appropriate amount of water. , Dissolve commercially available sodium tetraphenylboronate in an appropriate amount of water, mix both solutions at a ratio of 1:3 to form a precipitate, and filter. The tetraphenyl boron salt synthesized in this way is generally sparingly soluble in water and soluble in organic solvents such as alcohol and acetone.
本発明の感光材緑は上記の第二コバルト錯塩を
水溶性の結合剤と混合して、支持体に塗布し、乾
燥して得られる。 The green photosensitive material of the present invention is obtained by mixing the second cobalt complex salt described above with a water-soluble binder, coating the mixture on a support, and drying the mixture.
この感光材料を輻射線により画像状に露光し、
その後、カラー写真用の現像液で現像すると画像
が得られる。現像液は銀塩写真のカラー現像に用
いるものとほぼ同じ組成の現像液を用いることが
できる。現像主薬は例えばＮ，N′−ジエチル−
パラーフエニレン、２−アミノ−５−ジエチルア
ミノトルエン、４−アミノ−Ｎ−エチル−Ｎ−
（Ｂ−メタンスルホンアミドエチル）−ｍ−トルイ
ジンである。またカプラーは１−フエニール−３
−メチル−５−ピラゾール、２，４−ジクロロ−
１−ナフトール、ベンゾイルアセトアニリドを用
いることができる。現像はカプラーなしでも可能
であるが、カプラーを用いることにより、コント
ラストを大きくすることができる。 This photosensitive material is imagewise exposed to radiation,
Thereafter, an image is obtained by developing with a color photographic developer. A developer having approximately the same composition as that used for color development of silver salt photographs can be used. The developing agent is, for example, N,N'-diethyl-
Paraphenylene, 2-amino-5-diethylaminotoluene, 4-amino-N-ethyl-N-
(B-methanesulfonamidoethyl)-m-toluidine. Also, the coupler is 1-phenyl-3
-Methyl-5-pyrazole, 2,4-dichloro-
1-naphthol, benzoylacetanilide can be used. Although development is possible without a coupler, the contrast can be increased by using a coupler.
以下、実施例を挙げて本発明を具体的に説明す
る。 The present invention will be specifically described below with reference to Examples.
実施例 １
暗所で以下の物質を混合してガラス板に塗布し
た。ヘキサアンミンコバルトテトラフエニルホウ
素0.5ｇ、ゼラチン５％水溶液１c.c.、一昼夜以上
暗所で乾燥した後に、100Wの超高圧水銀灯で画
像状に０〜15秒露光した。その後、以下の組成の
現像液に約１分間浸漬して現像した後に、５％酢
酸水溶液に瞬時浸漬して現像を停止し、簡単に水
洗した。Example 1 The following substances were mixed and applied to a glass plate in a dark place. After drying 0.5 g of hexaammine cobalt tetraphenyl boron and 1 c.c. of a 5% aqueous gelatin solution in the dark for over a day and night, the mixture was imagewise exposed for 0 to 15 seconds using a 100 W ultra-high pressure mercury lamp. Thereafter, the film was developed by immersing it in a developer having the following composition for about 1 minute, and then instantaneously immersing it in a 5% acetic acid aqueous solution to stop the development, and then briefly washing it with water.
Ｎ，N′−ジエチル−パラーフエニレン硫酸塩
0.1ｇ／35c.c.（水）、１−フエニル−３−メチル−
５−ピラゾール0.1M（メタノール溶液）1.5c.c.、
Na2CO32M0.5c.c.、およそ0.5秒の露光で青紫色の
像が得られた。 N,N'-diethyl-paraphenylene sulfate
0.1g/35c.c. (water), 1-phenyl-3-methyl-
5-pyrazole 0.1M (methanol solution) 1.5cc,
Na 2 CO 3 2M0.5c.c., a blue-purple image was obtained with approximately 0.5 second exposure.
実施例 ２
以下の物質を混合して、ガラス板に塗布した、
トリス（エチレンジアミン）コバルトテトラフエ
ニルホウ素0.5ｇ、ゼラチン５％水溶液１c.c.実施
例１と同様にして露光し、以下の組成の現像液で
約１分間現像し、５％酢酸水溶液で停止した後、
水洗した。Example 2 The following substances were mixed and applied to a glass plate.
Tris (ethylenediamine) cobalt tetraphenylboron 0.5 g, gelatin 5% aqueous solution 1 c.c. Exposure was carried out in the same manner as in Example 1, developed for about 1 minute with a developer having the following composition, and stopped with a 5% acetic acid aqueous solution. rear,
Washed with water.
Ｎ，N′−ジエチル−パラーフエニレン硫酸塩
0.1ｇ／35c.c.（水）、2.4−ジクロロ−１−ナフト
ール0.04M1.5c.c.（アセトン溶液）Na2CO32M、
0.5c.c.、青紫色の像が得られた。 N,N'-diethyl-paraphenylene sulfate
0.1g/35c.c. (water), 2.4-dichloro-1-naphthol 0.04M 1.5c.c. (acetone solution) Na 2 CO 3 2M,
0.5cc, a blue-purple image was obtained.
実施例 ３
実施例２と同様にして調製した乾板を画像状に
露光して、同様の組成の現像主薬と炭酸ナトリウ
ムを含み、カプラーのない現像液で現像した。Example 3 A plate prepared as in Example 2 was imagewise exposed and developed in a developer containing a similar composition of developing agent and sodium carbonate, but without coupler.
かつ色の像が得られた。 And a color image was obtained.
実施例 ４
以下の物質を混合して、ガラス板に塗布した。
トランス−ジクロロビス（エチレンジアミン）コ
バルトテトラフエニルホウ素0.5ｇ、ゼラチン５
％水溶液１c.c.、実施例１と同様の方法で露光し
て、実施例２と同様の現像液で現像した。Example 4 The following materials were mixed and applied to a glass plate.
trans-dichlorobis(ethylenediamine) cobalt tetraphenylboron 0.5g, gelatin 5
% aqueous solution 1 c.c., exposed in the same manner as in Example 1, and developed with the same developer as in Example 2.
青紫色の像が得られた。 A blue-purple image was obtained.
実施例 ５
実施例４と同様の乾板を実施例３と同様の現像
液で現像した。Example 5 The same dry plate as in Example 4 was developed with the same developer as in Example 3.
青紫色の像が得られた。 A blue-purple image was obtained.
実施例 ６
以下の物質をガラス板に塗布し、乾燥した。ト
リス（トリメチレンジアミン）コバルトテトラフ
エニルホウ素0.5ｇ、ゼラチン５％水溶液１c.c.、
実施例１と同様に露光した後に、以下の組成の現
像液で現像した。Example 6 The following materials were applied to a glass plate and dried. Tris (trimethylene diamine) cobalt tetraphenyl boron 0.5 g, gelatin 5% aqueous solution 1 c.c.,
After exposure in the same manner as in Example 1, development was performed using a developer having the following composition.
Ｎ，Ｎ−ジエチル−パラーフエニレン硫酸塩
0.035ｇ／35c.c.（水）0.5c.c.、２，４−ジクロロ−
１−ナフトール0.04M1.5c.c.（アセトン溶液）
青黒色の像が得られた。 N,N-diethyl-paraphenylene sulfate
0.035g/35c.c. (water) 0.5cc, 2,4-dichloro-
1-Naphthol 0.04M1.5c.c. (acetone solution) A blue-black image was obtained.
実施例 ７ 以下の物質をガラス板に塗布して乾燥した。Example 7 The following materials were applied to a glass plate and dried.
トリス（プロピレンジアミン）コバルトテトラ
フエニルホウ素0.5ｇ、ゼラチン５％水溶液１c.c.、
実施例１と同様に露光して、実施例２と同様の現
像液で現像した。 Tris (propylene diamine) cobalt tetraphenyl boron 0.5 g, gelatin 5% aqueous solution 1 c.c.,
It was exposed in the same manner as in Example 1 and developed with the same developer as in Example 2.
赤紫色の像が得られた。 A reddish-purple image was obtained.
以上の実施例のうち、トリス（エチレンジアミ
ン）コバルトとジクロロビス（エチレンジアミ
ン）コバルト塩は300〜400mmの紫外光に主として
感度を持ち、その他は300〜500mmの紫外光および
可視光に主として感度を持つている。 Among the above examples, tris(ethylenediamine) cobalt and dichlorobis(ethylenediamine) cobalt salts are primarily sensitive to ultraviolet light of 300 to 400 mm, and the others are primarily sensitive to ultraviolet light and visible light of 300 to 500 mm. .
Claims (1)
ルホウ素塩を含む感光層を形成させてなる感光性
記録材料。 ２ 支持体上に第二コバルト錯体のテトラフエニ
ルホウ素塩を含む感光層を形成させてなる感光性
記録材料に光照射して画像を記録したのち、通常
のハロゲン化銀写真用カラー現像液で現像を行う
ことを特徴とする画像記録方法。[Scope of Claims] 1. A photosensitive recording material comprising a support and a photosensitive layer containing a tetraphenyl boron salt of a second cobalt complex. 2. After recording an image by irradiating a photosensitive recording material formed by forming a photosensitive layer containing a tetraphenyl boron salt of a secondary cobalt complex on a support, the photosensitive recording material is prepared using a common silver halide photographic color developer. An image recording method characterized by performing development.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2663181A JPS57139739A (en) | 1981-02-24 | 1981-02-24 | Photosensitive recording material and using method for it |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2663181A JPS57139739A (en) | 1981-02-24 | 1981-02-24 | Photosensitive recording material and using method for it |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS57139739A JPS57139739A (en) | 1982-08-28 |
| JPH0153452B2 true JPH0153452B2 (en) | 1989-11-14 |
Family
ID=12198791
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2663181A Granted JPS57139739A (en) | 1981-02-24 | 1981-02-24 | Photosensitive recording material and using method for it |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS57139739A (en) |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5415984A (en) * | 1993-04-23 | 1995-05-16 | Konica Corporation | Image forming element |
| US5476755A (en) * | 1993-11-19 | 1995-12-19 | Konica Corporation | Image forming element and image forming method |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS516026A (en) * | 1974-07-03 | 1976-01-19 | Fuji Photo Film Co Ltd | GAZOKEISEIHOHO |
| JPS561046A (en) * | 1979-06-18 | 1981-01-08 | Ricoh Co Ltd | Photosensitive heat-sensitive type recording member |
-
1981
- 1981-02-24 JP JP2663181A patent/JPS57139739A/en active Granted
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS516026A (en) * | 1974-07-03 | 1976-01-19 | Fuji Photo Film Co Ltd | GAZOKEISEIHOHO |
| JPS561046A (en) * | 1979-06-18 | 1981-01-08 | Ricoh Co Ltd | Photosensitive heat-sensitive type recording member |
Also Published As
| Publication number | Publication date |
|---|---|
| JPS57139739A (en) | 1982-08-28 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP2721220B2 (en) | Stabilizing bath for photographic processing | |
| JPS5930535A (en) | Image forming method using radiation | |
| EP0020397B1 (en) | Photographic bleach compositions and methods of photographic processing | |
| JPH09127663A (en) | Aqueous solution for photographic processing and bleaching or bleaching-fixing method using it | |
| JPH0153452B2 (en) | ||
| JPS6024935B2 (en) | Color photo processing method | |
| US4040837A (en) | Photographic bleach-fixer | |
| US3446619A (en) | Radiation sensitive silver-dye complexes | |
| US3149970A (en) | Production of photographic silver images by physical development | |
| US3640713A (en) | Photographic processes and compositions therefor | |
| US3265499A (en) | Photographic developing compositions | |
| GB1234632A (en) | ||
| US3702247A (en) | Color photographic process using a bleach-fix solution containing a selenosulfate | |
| EP0187879B1 (en) | Method and material for the production of continuous tone silver images by the silver complex diffusion transfer reversal process | |
| JPS61143755A (en) | Treatment of color photographic sensitive material | |
| GB2038497A (en) | Silver halide cyan colour image-forming process | |
| US4826745A (en) | Method of preparing a hologram | |
| US3954473A (en) | Method of bleaching metallic silver | |
| US3645731A (en) | Silver salt diffusion alkaline bath of trisodium phosphate and a polyalcohol | |
| JPS5820424B2 (en) | Color image forming method | |
| US2193574A (en) | Process for the production of colored images by photography | |
| US2987396A (en) | Photographic silver halide diffusion transfer process | |
| JPS5929244A (en) | Thermally erasable photographic recording material | |
| JPS62250450A (en) | Method for processing silver halide color photographic sensitive material | |
| JPS61183645A (en) | Manufacture of silver image containing stabilized fixing treatment |