JPH0147038B2 - - Google Patents
Info
- Publication number
- JPH0147038B2 JPH0147038B2 JP55065006A JP6500680A JPH0147038B2 JP H0147038 B2 JPH0147038 B2 JP H0147038B2 JP 55065006 A JP55065006 A JP 55065006A JP 6500680 A JP6500680 A JP 6500680A JP H0147038 B2 JPH0147038 B2 JP H0147038B2
- Authority
- JP
- Japan
- Prior art keywords
- heat
- sheet
- heat dissipation
- heat sink
- electronic component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000012790 adhesive layer Substances 0.000 claims description 15
- 238000000034 method Methods 0.000 claims description 13
- 238000010292 electrical insulation Methods 0.000 claims description 9
- 229920002379 silicone rubber Polymers 0.000 claims description 6
- 239000004945 silicone rubber Substances 0.000 claims description 6
- 239000011256 inorganic filler Substances 0.000 claims description 5
- 229910003475 inorganic filler Inorganic materials 0.000 claims description 5
- 230000017525 heat dissipation Effects 0.000 description 31
- 230000001070 adhesive effect Effects 0.000 description 9
- 239000000853 adhesive Substances 0.000 description 8
- 229920001296 polysiloxane Polymers 0.000 description 4
- 239000000919 ceramic Substances 0.000 description 3
- 239000010410 layer Substances 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- 239000013464 silicone adhesive Substances 0.000 description 3
- 229910052582 BN Inorganic materials 0.000 description 2
- PZNSFCLAULLKQX-UHFFFAOYSA-N Boron nitride Chemical compound N#B PZNSFCLAULLKQX-UHFFFAOYSA-N 0.000 description 2
- 239000004698 Polyethylene Substances 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000006073 displacement reaction Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- -1 polyethylene Polymers 0.000 description 2
- 229920000573 polyethylene Polymers 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 229920001971 elastomer Polymers 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 239000011810 insulating material Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000012948 isocyanate Substances 0.000 description 1
- 150000002513 isocyanates Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 230000002265 prevention Effects 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 235000012239 silicon dioxide Nutrition 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- 239000000758 substrate Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Description
本発明は発熱性電子部品(以下電子部品とい
う)の取付方法、特に電子部品を取付ける際に熱
安定性及び電気絶縁性にすぐれた粘着剤層をそな
えた放熱シートの粘着剤層面を電子部品及び/又
は放熱体の表面に接するように配置して電子部品
を取付ける方法に関する。
一般的に電子部品を使用する際に、電子部品か
ら発熱するので放熱フインや金属板などの放熱体
を取り付けて放熱させるようにしているが、その
中間に、電気絶縁性及び熱伝導性の良好な絶縁体
が必要である。
従来からこのような電子部品を取り付けるのに
用いる絶縁体としてはいろいろ提案されている。
例えば(1)マイカ板、(2)ポリエステル箔、(3)金属
基板と誘電セラミツクス薄板とを接合した絶縁板
(実開昭54−49864号)、(4)金属酸化物を耐熱性ゴ
ムに充填した放熱シート(実公昭52−34947号)
があげられる。しかし、(1)および(2)のものは表面
が比較的粗いため絶縁材料と電子部品および放熱
体との接触面に熱伝導性のよくない空気が介在
し、その結果熱損失を生じて熱効率が悪く、特に
(1)のものは均一性に欠き、(2)のものは熱伝導性が
悪いという欠点があり、これらに取り付け時にグ
リースを塗布してこれらの欠点を防止するように
しても手間を必要とするだけで、その効果は少な
く実用的ではない。(3)のものは金属基盤と誘電体
セラミツク薄板が一体に接合されている複合構造
であるため、導電性接着剤の選択、接着強度が問
題となる。更に放熱シート、電子部品及び放熱体
の各面の平滑性が良くないと密着性が悪く、接着
した状態でセラミツク薄板面を研磨して、薄くか
つ平滑にしている。又ネジ止めする際の締め付け
ひずみを防止すべく配慮した構造とする必要があ
り、いきおい構造が複雑となる等の欠点があつ
た。また(4)のものは、第1図に示すように放熱シ
ートを電子部品と放熱体との間に挾んでネジ止め
をすると、放熱シートが放熱体の上でずれること
があり、作業性が悪く、電子部品と放熱体との間
で絶縁破壊したり、放熱シートが破壊したり或い
は放熱シートが本来有する特性が損なわれたりす
る問題があつた。
本発明者は従来の放熱シートの均一で熱伝導性
および電気絶縁性にすぐれた特性を損なうことな
く取り付け時におけるずれを防止する方法につい
ていろいろ研究を行つた結果本発明に到達したも
のである。
本発明はこれらの欠点を解決することを目的と
するもので、電気絶縁性にすぐれた無機充填剤を
充填したシリコーンゴムシートの少なくとも一方
の面に粘着性を有する絶縁性及び熱伝導性のすぐ
れた粘着剤層を設け、放熱シートが本来有する特
性を損なうことなく、電子部品を放熱体に取り付
けることにより作業性、密着性、電気絶縁性、熱
伝導性などの従来の問題点を解消した発熱性電子
部品の取り付け方法を提供しようとするものであ
る。
すなわち、本発明は、発熱性電子部品を放熱体
に放熱シートを介して取付けるに際し、無機充填
剤を充填したシリコーンゴムからなる放熱シート
の少なくとも片面に、熱安定性及び電気絶縁性に
すぐれた厚さ0.1〜30μの粘着剤層を施した後、そ
の粘着剤層を前記電子部品及び/又は放熱体の取
付面に接するように配置した後、放熱シートが有
する本来の特性を損なうことなく放熱シートを介
して発熱性電子部品を放熱体に取付けることを特
徴とするものである。
以下さらに本発明を詳しく説明する。
本発明は無機充填材を充填したシリコーンゴム
シートの少くともその片面に粘着剤層を設けた放
熱シートを電子部品と放熱体との間に熱安定性及
び電気絶縁性にすぐれた粘着剤層面が電子部品及
び/又は放熱体の表面と接するように配置し、電
子部品を放熱体にネジ止め等により取り付ける方
法。
本発明において用いる放熱シートはシリコーン
ゴムに酸化アルミニウム、二酸化ケイ素、酸化亜
鉛、窒化硼素などの粉末からなる電気絶縁性にす
ぐれた無機充填材を充填した放熱シートに電気絶
縁性及び熱伝導性を有する粘着剤層を積層したも
のである。
粘着剤層を構成するものとしては耐熱性及び電
気絶縁性を具えた粘着性物質であればよくその具
体例としてはアクリル系、シリコーン系粘着剤が
あげられる。これらの市販のものとしては綜研化
学(株)商品名「SKダインG−1」東芝シリコーン
(株)商品名「東芝シリコーンYR−3340」などがあ
る。
本発明の放熱シートはその粘着剤層の厚さが重
要であつて、薄すぎても粘着性が十分でなく、ま
た厚すぎても熱伝導性が悪くなるので、その厚さ
は0.1〜30μ、好ましくは5〜15μである。放熱シ
ートに粘着剤を積層する方法としては、リバース
ロールコータ、キスコータ、ナイフコータなど通
常のコータ方式により放熱シートに積層すること
ができる。具体的な手段としては例えば第2図に
示ような方式があげられるがこれに限られるもの
ではない。
次に電子部品を放熱体に取り付けるには電子部
品及び/又は放熱体の表面に前記放熱シートの粘
着剤層面が接するように配置し電子部品と放熱体
とをネジ止めすればよい。この場合放熱シートの
粘着剤層が放熱体の表面に接するように配置し取
り付ける方法が取り扱い上便利である。
以上説明したように本発明は電子部品、特に発
熱性電子部品を取付ける際に、電子部品と放熱体
との間に放熱シートを介在させて電子部品を取付
けるものであるが、本発明においては粘着剤層を
具えた放熱シートを用い、これを電子部品及び/
又は放熱体の表面に配置した上電子部品と放熱体
とをネジ止するので、電子部品を取付ける際の作
業性が良好となる他放熱シートのずれがなく又密
着性がよいので電子部品の特性を十分に発揮する
ことができるという効果がある。
以下さらに実施例をあげさらに具体的に説明す
る。
実施例 1
シリコーンゴムシートは窒化硼素を充填した電
気化学工業(株)商品名「デンカ放熱シート」を用
い、第2図に示すように、厚さ10μの粘着剤7を
塗布したポリエチレンフイルム8の上に前記放熱
シート4をホツパー9から落下させて、ポリエチ
レンフイルム8に塗布された粘着剤7を放熱シー
ト4の片面に積層した。なお粘着剤は2液型のア
クリル系粘着剤を綜研化学(株)商品名「SKダイン
G−1」に対し、イソシアネート系硬化剤0.3%
を添加したものを用いた。次にこのシートの粘着
剤層面を放熱フイン面に接するように配置した
後、トランジエスタを置きネジ止めを行つた。
この締付時のシートのずれを調べた。なお放熱
シートの形状はTO−3型及びTO−220型を用
い、放熱フインの穴径5mmφ、ネジはM3のもの
を用い、締付トルク6Kgfcmとし第1図の形でシ
ート10枚の取付けずれを目視により調べそのずれ
の割合を表に示した。
The present invention relates to a method for attaching heat-generating electronic components (hereinafter referred to as electronic components), and in particular, when attaching electronic components, the adhesive layer surface of a heat dissipating sheet provided with an adhesive layer having excellent thermal stability and electrical insulation properties is applied to the electronic components and The present invention relates to a method of attaching an electronic component by arranging it in contact with the surface of a heat sink. Generally, when using electronic components, heat is generated from the electronic components, so heat dissipation bodies such as heat dissipation fins and metal plates are attached to dissipate the heat. A suitable insulator is required. Various insulators have been proposed for use in attaching such electronic components. For example, (1) mica plate, (2) polyester foil, (3) insulating plate made by bonding a metal substrate and dielectric ceramic thin plate (Utility Model Application Publication No. 54-49864), and (4) heat-resistant rubber filled with metal oxide. heat dissipation sheet (Utility Model Publication No. 52-34947)
can be given. However, since the surfaces of (1) and (2) are relatively rough, air with poor thermal conductivity is present at the contact surface between the insulating material, electronic components, and heat sink, resulting in heat loss and thermal efficiency. is bad, especially
Type (1) lacks uniformity, and type (2) has poor thermal conductivity, and even if it is possible to prevent these defects by applying grease when installing them, it is time-consuming. However, the effect is small and it is not practical. Since the type (3) has a composite structure in which a metal base and a dielectric ceramic thin plate are integrally bonded, the selection of conductive adhesive and adhesive strength are issues. Furthermore, if the surfaces of the heat dissipation sheet, electronic component, and heat dissipation body are not smooth, adhesion will be poor, so the surfaces of the thin ceramic plates are polished to make them thin and smooth while they are adhered. In addition, it is necessary to have a structure that takes into consideration the prevention of tightening strain when screwing, which has the disadvantage of complicating the structure. Regarding item (4), when the heat dissipation sheet is sandwiched between the electronic component and the heat dissipation body and screwed together as shown in Figure 1, the heat dissipation sheet may shift on the heat dissipation body, resulting in poor workability. Worse, there were problems in that dielectric breakdown occurred between the electronic component and the heat sink, the heat sink sheet was destroyed, or the inherent properties of the heat sink sheet were impaired. The present inventor has arrived at the present invention as a result of conducting various studies on methods of preventing displacement during installation without impairing the uniform, excellent thermal conductivity and electrical insulation properties of conventional heat dissipation sheets. The present invention is aimed at solving these drawbacks, and is a silicone rubber sheet filled with an inorganic filler having excellent electrical insulation properties and having adhesive properties on at least one side, which has excellent insulation properties and thermal conductivity. A heat generating system that solves conventional problems such as workability, adhesion, electrical insulation, and thermal conductivity by attaching electronic components to the heat sink without impairing the inherent properties of the heat dissipation sheet. The present invention aims to provide a method for attaching electronic components. That is, the present invention provides a heat dissipating sheet made of silicone rubber filled with an inorganic filler with a thickness having excellent thermal stability and electrical insulation properties when attaching a heat generating electronic component to a heat dissipating body via a heat dissipating sheet. After applying an adhesive layer with a thickness of 0.1 to 30 μm and placing the adhesive layer in contact with the mounting surface of the electronic component and/or heat sink, the heat sink sheet is formed without impairing the original properties of the heat sink sheet. The heat generating electronic component is attached to the heat sink through the heat sink. The present invention will be further explained in detail below. The present invention provides a heat dissipation sheet comprising a silicone rubber sheet filled with an inorganic filler and an adhesive layer provided on at least one side of the sheet. A method in which the electronic components and/or the electronic components are placed in contact with the surface of the heat sink, and the electronic components are attached to the heat sink using screws, etc. The heat dissipation sheet used in the present invention is a heat dissipation sheet made of silicone rubber filled with an inorganic filler that has excellent electrical insulation properties and is made of powders such as aluminum oxide, silicon dioxide, zinc oxide, and boron nitride, and has electrical insulation and thermal conductivity. It is made by laminating adhesive layers. The material constituting the adhesive layer may be any adhesive material that has heat resistance and electrical insulation properties, and specific examples thereof include acrylic and silicone adhesives. These commercially available products include Soken Chemical Co., Ltd.'s product name "SK Dyne G-1" Toshiba Silicone.
Co., Ltd.'s product name is ``Toshiba Silicone YR-3340.'' The thickness of the adhesive layer of the heat dissipation sheet of the present invention is important; if it is too thin, the adhesiveness will not be sufficient, and if it is too thick, the thermal conductivity will deteriorate, so the thickness should be 0.1 to 30 μm. , preferably 5 to 15μ. As a method for laminating the adhesive on the heat dissipation sheet, it can be laminated on the heat dissipation sheet using a normal coater method such as a reverse roll coater, a kiss coater, or a knife coater. As a specific means, for example, a method as shown in FIG. 2 can be cited, but the method is not limited to this. Next, in order to attach the electronic component to the heat radiator, the adhesive layer surface of the heat radiator sheet may be placed in contact with the surface of the electronic component and/or the heat radiator, and the electronic component and the heat radiator may be screwed together. In this case, it is convenient for handling to arrange and attach the heat dissipation sheet so that the adhesive layer is in contact with the surface of the heat dissipation body. As explained above, the present invention is for attaching electronic components, especially heat-generating electronic components, by interposing a heat dissipating sheet between the electronic component and the heat dissipating body. A heat dissipation sheet with a layer of heat dissipation material is used, and it is used for electronic components and/or
Or, since the electronic components placed on the surface of the heat radiator and the heat radiator are screwed together, the workability when installing the electronic components is good, and the heat radiator sheet does not shift and has good adhesion, which improves the characteristics of the electronic components. This has the effect of being able to fully demonstrate the The present invention will be described in more detail below with reference to Examples. Example 1 The silicone rubber sheet was Denka Heat Dissipation Sheet, a product of Denki Kagaku Kogyo Co., Ltd. filled with boron nitride, and as shown in Figure 2, a polyethylene film 8 coated with an adhesive 7 with a thickness of 10μ was used. The heat dissipation sheet 4 was dropped from the hopper 9 onto the heat dissipation sheet 4, and the adhesive 7 applied to the polyethylene film 8 was laminated on one side of the heat dissipation sheet 4. The adhesive is a two-component acrylic adhesive manufactured by Soken Kagaku Co., Ltd. under the trade name "SK Dyne G-1" with 0.3% isocyanate curing agent.
was used. Next, the adhesive layer surface of this sheet was placed in contact with the heat dissipation fin surface, and then the transistor was placed and screwed. The displacement of the sheet during this tightening was investigated. The shapes of the heat dissipation sheets are TO-3 type and TO-220 type, the hole diameter of the heat dissipation fin is 5 mmφ, the screws are M3, and the tightening torque is 6 kgfcm. was visually inspected and the percentage of deviation is shown in the table.
【表】
更に、熱抵抗及び絶縁耐力を調べたところ、本
発明により製造したものは0.27℃/w、比較例は
0.26℃/wであつた。絶縁耐力は実施例、比較例
共にDC5KV以上であり、実質的特性差は認めら
れなかつた。
実施例 2
粘着剤層の厚さ15μとした以外は実施例1と同
様に行つた。その結果は実施例1と同様であつ
た。
実施例 3
シリコーン系粘着剤を東芝シリコーン(株)商品名
「東芝シリコーンYR−3340」を用い、その粘着
剤層を5μの厚さとした以外は実施例1と同様に
行つた。その結果は実施例1と同様であつた。
実施例 4
実施例3のシリコーン系粘着剤層をシートの両
面に5μの厚さに設けたものを用いた以外実施例
1と同様に行つた。ネジ止め時におけるずれは実
施例1と同様であつた。[Table] Furthermore, when the thermal resistance and dielectric strength were investigated, the one manufactured by the present invention was 0.27℃/w, and the comparative example was 0.27℃/w.
It was 0.26℃/w. The dielectric strength was 5 KV DC or more in both the Examples and Comparative Examples, and no substantial difference in characteristics was observed. Example 2 The same procedure as in Example 1 was carried out except that the thickness of the adhesive layer was 15 μm. The results were the same as in Example 1. Example 3 The same procedure as in Example 1 was carried out, except that the silicone adhesive was Toshiba Silicone Co., Ltd. under the trade name "Toshiba Silicone YR-3340" and the adhesive layer had a thickness of 5 microns. The results were the same as in Example 1. Example 4 The same procedure as in Example 1 was carried out except that the silicone adhesive layer of Example 3 was provided on both sides of the sheet to a thickness of 5 μm. The deviation during screw tightening was the same as in Example 1.
図面は本発明の実施例を示すもので、第1図は
トランジエスタを放熱フインに取付け時の模式
図、第2図は、リバースロールコータによる片面
粘着シート製造の概略図である。
付号 1……放熱フイン、2……トランジエス
タ、3……ボルト、4……放熱シート、5……絶
縁ブツシユ、6……ナツト、7……シリコーンオ
イル、8……キヤリヤフイルム、9……放熱シー
ト供給ホツパー。
The drawings show an embodiment of the present invention, and FIG. 1 is a schematic diagram of a transistor mounted on a heat radiation fin, and FIG. 2 is a schematic diagram of manufacturing a single-sided adhesive sheet using a reverse roll coater. Numbers 1... Heat dissipation fin, 2... Transistor, 3... Bolt, 4... Heat dissipation sheet, 5... Insulating bush, 6... Nut, 7... Silicone oil, 8... Carrier film, 9 ...Heat dissipation sheet supply hopper.
Claims (1)
て取付けるに際し、無機充填剤を充填したシリコ
ーンゴムからなる放熱シートの少なくとも片面
に、熱安定性及び電気絶縁性にすぐれた厚さ0.1
〜30μの粘着剤層を施した後、その粘着剤層を前
記電子部品及び/又は放熱体の取付面に接するよ
うに配置した後、放熱シートが有する本来の特性
を損なうことなく放熱シートを介して発熱性電子
部品を放熱体に取付けることを特徴とする発熱性
電子部品の取付方法。1. When attaching a heat-generating electronic component to a heat sink via a heat-dissipating sheet, at least one side of the heat-dissipating sheet made of silicone rubber filled with an inorganic filler has a thickness of 0.1 mm with excellent thermal stability and electrical insulation properties.
After applying an adhesive layer of ~30 μm and placing the adhesive layer in contact with the mounting surface of the electronic component and/or heat sink, the adhesive layer is placed in contact with the mounting surface of the electronic component and/or the heat sink, and then the heat sink is inserted through the heat sink without impairing the original properties of the heat sink. A method for attaching a heat generating electronic component, comprising attaching the heat generating electronic component to a heat sink.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6500680A JPS56161699A (en) | 1980-05-16 | 1980-05-16 | Method of mounting electric part and insulating heat dissipating sheet used therefor |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP6500680A JPS56161699A (en) | 1980-05-16 | 1980-05-16 | Method of mounting electric part and insulating heat dissipating sheet used therefor |
Related Child Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP23596884A Division JPS60157244A (en) | 1984-11-10 | 1984-11-10 | Insulation heat-dissipating sheet with adhesive |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS56161699A JPS56161699A (en) | 1981-12-12 |
JPH0147038B2 true JPH0147038B2 (en) | 1989-10-12 |
Family
ID=13274465
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP6500680A Granted JPS56161699A (en) | 1980-05-16 | 1980-05-16 | Method of mounting electric part and insulating heat dissipating sheet used therefor |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS56161699A (en) |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60179269A (en) * | 1984-02-28 | 1985-09-13 | Fuji Xerox Co Ltd | Thermal head |
JP4446514B2 (en) * | 1999-06-15 | 2010-04-07 | 電気化学工業株式会社 | Thermally conductive silicone molded body heat dissipation member |
JPWO2021060318A1 (en) * | 2019-09-25 | 2021-04-01 |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4968233A (en) * | 1972-11-04 | 1974-07-02 | ||
JPS5334842B2 (en) * | 1972-12-27 | 1978-09-22 |
Family Cites Families (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5639110Y2 (en) * | 1976-08-31 | 1981-09-11 |
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1980
- 1980-05-16 JP JP6500680A patent/JPS56161699A/en active Granted
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4968233A (en) * | 1972-11-04 | 1974-07-02 | ||
JPS5334842B2 (en) * | 1972-12-27 | 1978-09-22 |
Also Published As
Publication number | Publication date |
---|---|
JPS56161699A (en) | 1981-12-12 |
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