JPH0141505B2 - - Google Patents
Info
- Publication number
- JPH0141505B2 JPH0141505B2 JP56045884A JP4588481A JPH0141505B2 JP H0141505 B2 JPH0141505 B2 JP H0141505B2 JP 56045884 A JP56045884 A JP 56045884A JP 4588481 A JP4588481 A JP 4588481A JP H0141505 B2 JPH0141505 B2 JP H0141505B2
- Authority
- JP
- Japan
- Prior art keywords
- electron beam
- convex pattern
- pattern layer
- pattern
- layer made
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 238000010894 electron beam technology Methods 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 30
- 238000000034 method Methods 0.000 claims description 29
- 239000000203 mixture Substances 0.000 claims description 24
- 229920005989 resin Polymers 0.000 claims description 22
- 239000011347 resin Substances 0.000 claims description 22
- 238000007639 printing Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000000576 coating method Methods 0.000 claims description 3
- 239000000758 substrate Substances 0.000 claims description 3
- 239000011248 coating agent Substances 0.000 claims description 2
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 9
- 238000007646 gravure printing Methods 0.000 description 9
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 8
- -1 polypropylene Polymers 0.000 description 8
- 238000005299 abrasion Methods 0.000 description 7
- 239000000126 substance Substances 0.000 description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000000975 dye Substances 0.000 description 5
- 239000000123 paper Substances 0.000 description 5
- FIHBHSQYSYVZQE-UHFFFAOYSA-N 6-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound C=CC(=O)OCCCCCCOC(=O)C=C FIHBHSQYSYVZQE-UHFFFAOYSA-N 0.000 description 4
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 4
- 230000001133 acceleration Effects 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical compound CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 238000004049 embossing Methods 0.000 description 4
- 239000000178 monomer Substances 0.000 description 4
- 229920000728 polyester Polymers 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 3
- 241000218645 Cedrus Species 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 3
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 3
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 3
- 239000003086 colorant Substances 0.000 description 3
- 239000000049 pigment Substances 0.000 description 3
- 239000004014 plasticizer Substances 0.000 description 3
- 238000006116 polymerization reaction Methods 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 3
- 238000007650 screen-printing Methods 0.000 description 3
- 239000007787 solid Substances 0.000 description 3
- ANRHNWWPFJCPAZ-UHFFFAOYSA-M thionine Chemical compound [Cl-].C1=CC(N)=CC2=[S+]C3=CC(N)=CC=C3N=C21 ANRHNWWPFJCPAZ-UHFFFAOYSA-M 0.000 description 3
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 3
- 239000002023 wood Substances 0.000 description 3
- LEJBBGNFPAFPKQ-UHFFFAOYSA-N 2-(2-prop-2-enoyloxyethoxy)ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOC(=O)C=C LEJBBGNFPAFPKQ-UHFFFAOYSA-N 0.000 description 2
- XFCMNSHQOZQILR-UHFFFAOYSA-N 2-[2-(2-methylprop-2-enoyloxy)ethoxy]ethyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OCCOCCOC(=O)C(C)=C XFCMNSHQOZQILR-UHFFFAOYSA-N 0.000 description 2
- INQDDHNZXOAFFD-UHFFFAOYSA-N 2-[2-(2-prop-2-enoyloxyethoxy)ethoxy]ethyl prop-2-enoate Chemical compound C=CC(=O)OCCOCCOCCOC(=O)C=C INQDDHNZXOAFFD-UHFFFAOYSA-N 0.000 description 2
- KUDUQBURMYMBIJ-UHFFFAOYSA-N 2-prop-2-enoyloxyethyl prop-2-enoate Chemical compound C=CC(=O)OCCOC(=O)C=C KUDUQBURMYMBIJ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 2
- 239000004925 Acrylic resin Substances 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 2
- 239000000020 Nitrocellulose Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- NRCMAYZCPIVABH-UHFFFAOYSA-N Quinacridone Chemical compound N1C2=CC=CC=C2C(=O)C2=C1C=C1C(=O)C3=CC=CC=C3NC1=C2 NRCMAYZCPIVABH-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 229920000180 alkyd Polymers 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 229920006026 co-polymeric resin Polymers 0.000 description 2
- 230000008021 deposition Effects 0.000 description 2
- 239000002274 desiccant Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 239000010440 gypsum Substances 0.000 description 2
- 229910052602 gypsum Inorganic materials 0.000 description 2
- 230000001678 irradiating effect Effects 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229920001220 nitrocellulos Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920005862 polyol Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000002562 thickening agent Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 229940042596 viscoat Drugs 0.000 description 2
- IANQTJSKSUMEQM-UHFFFAOYSA-N 1-benzofuran Chemical compound C1=CC=C2OC=CC2=C1 IANQTJSKSUMEQM-UHFFFAOYSA-N 0.000 description 1
- KAJBSGLXSREIHP-UHFFFAOYSA-N 2,2-bis[(2-sulfanylacetyl)oxymethyl]butyl 2-sulfanylacetate Chemical compound SCC(=O)OCC(CC)(COC(=O)CS)COC(=O)CS KAJBSGLXSREIHP-UHFFFAOYSA-N 0.000 description 1
- JJBFVQSGPLGDNX-UHFFFAOYSA-N 2-(2-methylprop-2-enoyloxy)propyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC(C)COC(=O)C(C)=C JJBFVQSGPLGDNX-UHFFFAOYSA-N 0.000 description 1
- KGPXEVIKDFHEEZ-UHFFFAOYSA-N 2-(dibenzylamino)ethyl prop-2-enoate Chemical compound C=1C=CC=CC=1CN(CCOC(=O)C=C)CC1=CC=CC=C1 KGPXEVIKDFHEEZ-UHFFFAOYSA-N 0.000 description 1
- DRHKEFCJMRVURM-UHFFFAOYSA-N 2-(diethylamino)propyl prop-2-enoate Chemical compound CCN(CC)C(C)COC(=O)C=C DRHKEFCJMRVURM-UHFFFAOYSA-N 0.000 description 1
- DPBJAVGHACCNRL-UHFFFAOYSA-N 2-(dimethylamino)ethyl prop-2-enoate Chemical compound CN(C)CCOC(=O)C=C DPBJAVGHACCNRL-UHFFFAOYSA-N 0.000 description 1
- GOXQRTZXKQZDDN-UHFFFAOYSA-N 2-Ethylhexyl acrylate Chemical compound CCCCC(CC)COC(=O)C=C GOXQRTZXKQZDDN-UHFFFAOYSA-N 0.000 description 1
- PTJDGKYFJYEAOK-UHFFFAOYSA-N 2-butoxyethyl prop-2-enoate Chemical compound CCCCOCCOC(=O)C=C PTJDGKYFJYEAOK-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- LNUXXIMFIDHHRB-UHFFFAOYSA-N 2-methoxyethyl 2-methylprop-2-enoate;2-methylprop-2-enoic acid Chemical compound CC(=C)C(O)=O.COCCOC(=O)C(C)=C LNUXXIMFIDHHRB-UHFFFAOYSA-N 0.000 description 1
- HFCUBKYHMMPGBY-UHFFFAOYSA-N 2-methoxyethyl prop-2-enoate Chemical compound COCCOC(=O)C=C HFCUBKYHMMPGBY-UHFFFAOYSA-N 0.000 description 1
- NIAGUSHJWAMKBZ-UHFFFAOYSA-N 2-methylprop-2-enoic acid;1,3,5-triazine-2,4,6-triamine Chemical compound CC(=C)C(O)=O.NC1=NC(N)=NC(N)=N1 NIAGUSHJWAMKBZ-UHFFFAOYSA-N 0.000 description 1
- POYODSZSSBWJPD-UHFFFAOYSA-N 2-methylprop-2-enoyloxy 2-methylprop-2-eneperoxoate Chemical compound CC(=C)C(=O)OOOC(=O)C(C)=C POYODSZSSBWJPD-UHFFFAOYSA-N 0.000 description 1
- VFZKVQVQOMDJEG-UHFFFAOYSA-N 2-prop-2-enoyloxypropyl prop-2-enoate Chemical compound C=CC(=O)OC(C)COC(=O)C=C VFZKVQVQOMDJEG-UHFFFAOYSA-N 0.000 description 1
- DBCAQXHNJOFNGC-UHFFFAOYSA-N 4-bromo-1,1,1-trifluorobutane Chemical compound FC(F)(F)CCCBr DBCAQXHNJOFNGC-UHFFFAOYSA-N 0.000 description 1
- GAKWESOCALHOKH-UHFFFAOYSA-N 4-methoxybutyl prop-2-enoate Chemical compound COCCCCOC(=O)C=C GAKWESOCALHOKH-UHFFFAOYSA-N 0.000 description 1
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 1
- 229920000178 Acrylic resin Polymers 0.000 description 1
- NOEMSRWQFGPZQS-UHFFFAOYSA-N CCC(O)=S.CCC(O)=S.CCC(O)=S.CCC(CO)(CO)CO Chemical compound CCC(O)=S.CCC(O)=S.CCC(O)=S.CCC(CO)(CO)CO NOEMSRWQFGPZQS-UHFFFAOYSA-N 0.000 description 1
- 229920008347 Cellulose acetate propionate Polymers 0.000 description 1
- 229920000896 Ethulose Polymers 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- 239000001859 Ethyl hydroxyethyl cellulose Substances 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 1
- DAKWPKUUDNSNPN-UHFFFAOYSA-N Trimethylolpropane triacrylate Chemical compound C=CC(=O)OCC(CC)(COC(=O)C=C)COC(=O)C=C DAKWPKUUDNSNPN-UHFFFAOYSA-N 0.000 description 1
- RUDUCNPHDIMQCY-UHFFFAOYSA-N [3-(2-sulfanylacetyl)oxy-2,2-bis[(2-sulfanylacetyl)oxymethyl]propyl] 2-sulfanylacetate Chemical compound SCC(=O)OCC(COC(=O)CS)(COC(=O)CS)COC(=O)CS RUDUCNPHDIMQCY-UHFFFAOYSA-N 0.000 description 1
- 238000009825 accumulation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- ATMLPEJAVWINOF-UHFFFAOYSA-N acrylic acid acrylic acid Chemical class OC(=O)C=C.OC(=O)C=C ATMLPEJAVWINOF-UHFFFAOYSA-N 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 239000010425 asbestos Substances 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 239000003085 diluting agent Substances 0.000 description 1
- GMSCBRSQMRDRCD-UHFFFAOYSA-N dodecyl 2-methylprop-2-enoate Chemical compound CCCCCCCCCCCCOC(=O)C(C)=C GMSCBRSQMRDRCD-UHFFFAOYSA-N 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- SUPCQIBBMFXVTL-UHFFFAOYSA-N ethyl 2-methylprop-2-enoate Chemical compound CCOC(=O)C(C)=C SUPCQIBBMFXVTL-UHFFFAOYSA-N 0.000 description 1
- MHCLJIVVJQQNKQ-UHFFFAOYSA-N ethyl carbamate;2-methylprop-2-enoic acid Chemical compound CCOC(N)=O.CC(=C)C(O)=O MHCLJIVVJQQNKQ-UHFFFAOYSA-N 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- 235000019326 ethyl hydroxyethyl cellulose Nutrition 0.000 description 1
- STVZJERGLQHEKB-UHFFFAOYSA-N ethylene glycol dimethacrylate Substances CC(=C)C(=O)OCCOC(=O)C(C)=C STVZJERGLQHEKB-UHFFFAOYSA-N 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 239000011094 fiberboard Substances 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000004088 foaming agent Substances 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 238000003475 lamination Methods 0.000 description 1
- 150000002688 maleic acid derivatives Chemical class 0.000 description 1
- 150000002734 metacrylic acid derivatives Chemical class 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- FQPSGWSUVKBHSU-UHFFFAOYSA-N methacrylamide Chemical compound CC(=C)C(N)=O FQPSGWSUVKBHSU-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 239000000113 methacrylic resin Substances 0.000 description 1
- YDKNBNOOCSNPNS-UHFFFAOYSA-N methyl 1,3-benzoxazole-2-carboxylate Chemical compound C1=CC=C2OC(C(=O)OC)=NC2=C1 YDKNBNOOCSNPNS-UHFFFAOYSA-N 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 238000007645 offset printing Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000010451 perlite Substances 0.000 description 1
- 235000019362 perlite Nutrition 0.000 description 1
- QIWKUEJZZCOPFV-UHFFFAOYSA-N phenyl 2-methylprop-2-enoate Chemical compound CC(=C)C(=O)OC1=CC=CC=C1 QIWKUEJZZCOPFV-UHFFFAOYSA-N 0.000 description 1
- WRAQQYDMVSCOTE-UHFFFAOYSA-N phenyl prop-2-enoate Chemical compound C=CC(=O)OC1=CC=CC=C1 WRAQQYDMVSCOTE-UHFFFAOYSA-N 0.000 description 1
- FSDNTQSJGHSJBG-UHFFFAOYSA-N piperidine-4-carbonitrile Chemical compound N#CC1CCNCC1 FSDNTQSJGHSJBG-UHFFFAOYSA-N 0.000 description 1
- 229920006255 plastic film Polymers 0.000 description 1
- 239000002985 plastic film Substances 0.000 description 1
- 239000011120 plywood Substances 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920001483 poly(ethyl methacrylate) polymer Polymers 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002037 poly(vinyl butyral) polymer Polymers 0.000 description 1
- 229920006289 polycarbonate film Polymers 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000120 polyethyl acrylate Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920006295 polythiol Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- QCTJRYGLPAFRMS-UHFFFAOYSA-N prop-2-enoic acid;1,3,5-triazine-2,4,6-triamine Chemical compound OC(=O)C=C.NC1=NC(N)=NC(N)=N1 QCTJRYGLPAFRMS-UHFFFAOYSA-N 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- NHARPDSAXCBDDR-UHFFFAOYSA-N propyl 2-methylprop-2-enoate Chemical compound CCCOC(=O)C(C)=C NHARPDSAXCBDDR-UHFFFAOYSA-N 0.000 description 1
- 239000002964 rayon Substances 0.000 description 1
- 229910052895 riebeckite Inorganic materials 0.000 description 1
- 239000000377 silicon dioxide Substances 0.000 description 1
- 239000010454 slate Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000001629 suppression Effects 0.000 description 1
- 125000003396 thiol group Chemical group [H]S* 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 229920006305 unsaturated polyester Polymers 0.000 description 1
- 238000003466 welding Methods 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Printing Methods (AREA)
- Laminated Bodies (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Description
【発明の詳細な説明】
本発明は化粧材の製造法に関し、更に詳しく
は、耐圧性と耐摩耗性を有する凸状模様層を有す
る化粧材の製造法に関するものである。DETAILED DESCRIPTION OF THE INVENTION The present invention relates to a method for manufacturing a decorative material, and more particularly to a method for manufacturing a decorative material having a convex pattern layer having pressure resistance and abrasion resistance.
従来、凸状模様層を有する化粧材の製造法とし
ては、機械的エンボス法、発泡印刷法、ケミカル
エンボス法、重合抑制ないし促進法、塗料の弾き
を利用した法がある。 Conventionally, methods for producing decorative materials having a convex pattern layer include mechanical embossing, foam printing, chemical embossing, polymerization inhibition or acceleration, and methods utilizing paint repellency.
しかしながら、前記の従来の製造法において
は、機械的エンボス法では、高価なエンボス版を
柄毎に新しく製作する必要があり、しかも、印刷
模様とエンボス模様を正確に一致させることはむ
ずかしいという欠点を有し、発泡印刷法では発泡
剤を含有するインキで印刷を施した後に加熱発泡
するため、凸状模様層が堆積などによる圧力に弱
くつぶれやすい或いは摩耗に弱い欠点を有し、ケ
ミカルエンボス法では凸状模様層の立上がりがシ
ヤープでない欠点を有し、重合抑制ないし促進法
では部分的に重合が充分行なわれていない部分の
物理的および化学的性質が劣る欠点を有し、塗料
の弾きを利用した法ではシヤープな立上がりが実
現出来ないという欠点を有する。 However, in the conventional manufacturing method described above, the mechanical embossing method requires the production of a new expensive embossing plate for each pattern, and furthermore, it is difficult to accurately match the printed pattern and the embossed pattern. In the foam printing method, the ink containing a foaming agent is printed and then heated and foamed, so the convex pattern layer has the disadvantage that it is weak against pressure due to accumulation, etc., and is easily crushed or resistant to abrasion. It has the disadvantage that the rise of the convex pattern layer is not sharp, and the disadvantage is that the physical and chemical properties of the parts where polymerization is not sufficiently carried out are inferior when polymerization suppression or acceleration methods are used. This method has the disadvantage that a sharp rise cannot be achieved.
又、グラビア印刷法やシルクスクリーン印刷法
によりいわゆるインキの厚盛りができることを利
用し、凸状印刷模様層を設ける方式もあるが、こ
れらの方式においては固形分の多いインキを使う
必要があり、例えば、ポリ塩化ビニルのペースト
用レジンを用いる方法などが考えられるが、印刷
対象に応じ、種々の樹脂を用いてこのような固型
分の多いインキを用いることは困難で、しかも印
刷後に高温で硬化させる必要があり、あらゆる被
印刷材料に向くとは到底言えないものである。 There is also a method of creating a convex printed pattern layer by taking advantage of the so-called thick build-up of ink produced by gravure printing and silk screen printing, but these methods require the use of ink with a high solid content. For example, a method using polyvinyl chloride paste resin may be considered, but it is difficult to use such ink with a high solid content using various resins depending on the printing target, and moreover, it is difficult to use ink with a high solid content after printing. It needs to be cured and cannot be said to be suitable for all types of printing materials.
本発明は以上のような従来法の欠点に鑑み研究
の結果生み出されたものであり、基材上に、通常
インクからなる模様層および電子線硬化性組成物
からなる凸状模様層の2種の模様層を順次に設
け、しかる後、電子線を照射し、前記凸状模様を
硬化せしめることにより、或いは、基材上に、印
刷方式により通常インクからなる模様層および電
子線硬化性組成物からなる凸状模様層の2種の模
様層を順次に設け、さらに前記2種の模様層を設
けた上に透明樹脂層を被覆し、被覆後、前記透明
樹脂層を介して電子線を照射し、前記凸状模様を
硬化せしめることより、前記の欠点を克服するの
に成功したものである。 The present invention was created as a result of research in view of the drawbacks of the conventional methods as described above, and includes two types of pattern layers, a pattern layer made of normal ink and a convex pattern layer made of an electron beam curable composition, on a base material. A pattern layer usually made of ink and an electron beam curable composition are formed by sequentially providing a pattern layer and then irradiating the convex pattern with an electron beam to cure the convex pattern, or by a printing method on a substrate. Two types of pattern layers of a convex pattern layer consisting of are sequentially provided, and a transparent resin layer is coated on the two types of pattern layers, and after coating, an electron beam is irradiated through the transparent resin layer. However, by hardening the convex pattern, the above drawbacks were successfully overcome.
以下に本発明の詳細について更に詳しく説明す
る。 The details of the present invention will be explained in more detail below.
本発明において使用される基材としては薄葉
紙、チタン紙、石こうボード紙などの紙、ポリエ
ステル、レーヨン等の繊維を原料とする不織布、
ガラス繊維等を原料とする織布、塩ビ、ポリエス
テル、ポリプロピレン等の各種プラスチツクフイ
ルム、合板および木材、パーチクルボード、繊維
板、石こうボード、パーライトボード、珪カル
板、石綿スレート板、GRC板、鉄板、アルミニ
ウム板等の金属板等が使用できる。 The base materials used in the present invention include paper such as tissue paper, titanium paper, and gypsum board paper, nonwoven fabrics made from fibers such as polyester and rayon,
Woven fabrics made from glass fiber, etc., various plastic films such as PVC, polyester, and polypropylene, plywood and wood, particle board, fiberboard, gypsum board, perlite board, silica board, asbestos slate board, GRC board, iron plate, and aluminum. A metal plate such as a plate can be used.
次に本発明における通常インクからなる模様層
を構成する通常インクとしては、インク用ビヒク
ルに必要に応じて染料または顔料等の着色剤を添
加し、更に、例えば、可塑剤、安定剤、ワツク
ス、グリース、乾燥剤、補助乾燥剤、硬化剤、増
粘剤、分散剤、充填剤等の公知の添加剤を任意に
添加して溶剤、希釈剤等で充分に混練したインク
素成物を使うことができ、インク用ビヒクルとし
ては、例えば、エチルセルロース、エチルヒドロ
キシエチルセルロース、セルロースアセテートプ
ロピオネート、酢酸セルロース等のセルロース誘
導体、ポリスチレン、ポリαメチルスチレンなど
のスチレン樹脂及びスチレン共重合樹脂、ポリメ
タクリル酸メチル、ポリメタクリル酸エチル、ポ
リアクリル酸エチル、ポリアクリル酸ブチルなど
の、アクリル又はメタクリル樹脂の単独又は共重
合樹脂、ロジン、ロジン変性マレイン酸樹脂、ロ
ジン変性フエノール樹脂、重合ロジンなどのロジ
ンエステル樹脂、ポリ酢酸ビニル樹脂、クマロン
樹脂、ビニルトルエン樹脂、塩化ビニル樹脂、ポ
リエステル樹脂、ポリウレタン樹脂、ブチラール
樹脂、更にはこれらのものを何種類か混合したも
のの中から被印刷対象である前記基材との接着性
等を考慮して適宜選択して用いる。 Next, for the ordinary ink constituting the pattern layer made of ordinary ink in the present invention, a coloring agent such as a dye or pigment is added to the ink vehicle as necessary, and further, for example, a plasticizer, a stabilizer, a wax, Using an ink composition that has been sufficiently kneaded with a solvent, diluent, etc., with optional addition of known additives such as grease, desiccant, auxiliary desiccant, curing agent, thickener, dispersant, filler, etc. Ink vehicles include, for example, cellulose derivatives such as ethyl cellulose, ethyl hydroxyethyl cellulose, cellulose acetate propionate, and cellulose acetate, styrene resins and styrene copolymer resins such as polystyrene, poly-α-methylstyrene, and polymethyl methacrylate. , acrylic or methacrylic resin alone or copolymer resin such as polyethyl methacrylate, polyethyl acrylate, polybutyl acrylate, rosin, rosin ester resin such as rosin-modified maleic acid resin, rosin-modified phenolic resin, polymerized rosin, Adhesion to the substrate to be printed from polyvinyl acetate resin, coumaron resin, vinyltoluene resin, vinyl chloride resin, polyester resin, polyurethane resin, butyral resin, or a mixture of several of these resins. The material should be selected and used as appropriate, taking into consideration gender, etc.
上記のような通常インクからなる模様層を基材
に設ける方式としてはグラビア印刷方式、オフセ
ツトグラビア印刷方式、オフセツト印刷方式、シ
ルクスクリーン印刷方式などの公知の印刷方式に
よればよく、被印刷対象である基材の材質、形態
に応じ適宜選択して用いればよい。 The pattern layer made of normal ink as described above may be provided on the base material by a known printing method such as a gravure printing method, an offset gravure printing method, an offset printing method, or a silk screen printing method. They may be appropriately selected and used depending on the material and form of the base material.
次に本発明における電子線硬化性組成物からな
る凸状模様層を構成する電子線硬化性組成物とし
ては、電子線硬化性化合物に必要に応じて染料ま
たは顔料等の着色剤を添加し、更に流動性付与
剤、増粘剤、分散剤、可塑剤、溶剤等の添加物を
任意に添加して混練して用いることができ、電子
線硬化性化合物としては、例えば、分子中にエチ
レン性不飽和結合を有するプレポリマーもしくは
オリゴマー例えば不飽和ポリエステル類、ポリエ
ステルアクリレート、エポキシアクリレート、ウ
レタンアクリレート、ポリエーテルアクリレー
ト、ポリオールアクリレート、メラミンアクリレ
ートなどの各種アクリレート類、ポリエステルメ
タクリレート、エポキシメタクリレート、ウレタ
ンメタクリレート、ポリエーテルメタクリレー
ト、ポリオールメタクリレート、メラミンメタク
リレートなどの各種メタクリレート類などの一種
または二種以上と、分子中にエチレン性不飽和結
合を有するモノマー、例えば、スチレン、α−メ
チルスチレン等のスチレン系モノマー類;アクリ
ル酸メチル、アクリル酸2−エチルヘキシル、ア
クリル酸メトキシエチル、アクリル酸ブトキシエ
チル、アクリル酸ブチル、アクリル酸メトキシブ
チル、アクリル酸フエニル等のアクリル酸エステ
ル類;メタクリル酸メチル、メタクリル酸エチ
ル、メタクリル酸プロピル、メタクリル酸メトキ
シエチル、メタクリル酸エトキシチチル、メタク
リル酸フエニル、メタクリル酸ラウリル等のメタ
クリル酸エステル類;アクリルアミド、メタクリ
ルアミド等の不飽和カルボン酸アミド;アクリル
酸2−(N、N−ジメチルアミノ)エチル、メタ
クリル酸2−(N、N−ジメチルアミノ)エチル、
アクリル酸2−(N、N−ジベンジルアミノ)エ
チル、メタクリル酸(N、N−ジメチルアミノ)
メチル、アクリル酸2−(N、N−ジエチルアミ
ノ)プロピル等の不飽和酸の置換アミノアルコー
ルエステル類;エチレングリコールジアクリレー
ト、プロピレングリコールジアクリレート、ネオ
ペンチルグリコールジアクリレート、1,6−ヘ
キサンジオールジアクリレート、ジエチレングリ
コールジアクリレート、トリエチレングリコール
ジアクリレート、ジプロピレングリコールジアク
リレート、エチレングリコールジメタクリレー
ト、プロピレングリコールジメタクリレート、ジ
エチレングリコールジメタクリレート等の多官能
性化合物、及び/又は分子中に2個以上のチオー
ル基を有するポリチオール化合物例えばトリメチ
ロールプロパントリチオグリコレート、トリメチ
ロールプロパントリチオプロピオネート、ペンタ
エリスリトールテトラチオグリコレートなどを混
合して用いることができる。 Next, as the electron beam curable composition constituting the convex pattern layer made of the electron beam curable composition in the present invention, a coloring agent such as a dye or pigment is added to the electron beam curable compound as necessary, Furthermore, additives such as fluidity imparting agents, thickeners, dispersants, plasticizers, and solvents can be optionally added and kneaded. Prepolymers or oligomers having unsaturated bonds, such as unsaturated polyesters, polyester acrylate, epoxy acrylate, urethane acrylate, polyether acrylate, polyol acrylate, various acrylates such as melamine acrylate, polyester methacrylate, epoxy methacrylate, urethane methacrylate, polyether One or more types of methacrylates such as methacrylate, polyol methacrylate, and melamine methacrylate, and monomers having ethylenically unsaturated bonds in the molecule, such as styrene monomers such as styrene and α-methylstyrene; acrylic acid Acrylic acid esters such as methyl, 2-ethylhexyl acrylate, methoxyethyl acrylate, butoxyethyl acrylate, butyl acrylate, methoxybutyl acrylate, phenyl acrylate; methyl methacrylate, ethyl methacrylate, propyl methacrylate, methacrylate Methoxyethyl methacrylate, ethoxytityl methacrylate, phenyl methacrylate, lauryl methacrylate, and other methacrylic acid esters; acrylamide, methacrylamide, and other unsaturated carboxylic acid amides; 2-(N,N-dimethylamino)ethyl acrylate, methacrylic acid 2-(N,N-dimethylamino)ethyl,
2-(N,N-dibenzylamino)ethyl acrylate, methacrylic acid (N,N-dimethylamino)
Substituted amino alcohol esters of unsaturated acids such as methyl and 2-(N,N-diethylamino)propyl acrylate; ethylene glycol diacrylate, propylene glycol diacrylate, neopentyl glycol diacrylate, 1,6-hexanediol diacrylate , polyfunctional compounds such as diethylene glycol diacrylate, triethylene glycol diacrylate, dipropylene glycol diacrylate, ethylene glycol dimethacrylate, propylene glycol dimethacrylate, diethylene glycol dimethacrylate, and/or compounds containing two or more thiol groups in the molecule. A mixture of polythiol compounds such as trimethylolpropane trithioglycolate, trimethylolpropane trithiopropionate, and pentaerythritol tetrathioglycolate can be used.
上記した電子線硬化性組成物からなる凸状模様
層を設ける方式としては、通常インクからなる模
様層を設ける方式として先に挙げた方式を同様に
用いることが出来るが、凸状模様層を設ける意味
で、出来得ればシルクスクリーン印刷方式や特に
版深の大なるグラビア版を用いるグラビア印刷方
式を採ることが好ましい。 As a method for providing a convex pattern layer made of the above-mentioned electron beam curable composition, the method mentioned above as a method for providing a pattern layer made of normal ink can be similarly used, but a convex pattern layer is provided. In this sense, if possible, it is preferable to use a silk screen printing method or, in particular, a gravure printing method using a gravure plate with a large plate depth.
本発明における透明樹脂層としては、例えば、
前記した電子線硬化性組成物からなる凸状模様層
を構成する電子線硬化性組成物のうち、透明また
は着色透明もしくは半透明または着色半透明のも
のを、前記基材、模様層、凸状模様層の材質、化
粧材の用途、要求性能に応じて適宜選択して用い
るが、透明樹脂層を設ける目的は、前記凸状模様
層の摩耗を更に防止し、併せて表面の物理的、化
学的性能を向上させるものであつて、化粧材の用
途・要求性能によつては必ずしも高度な物理的・
化学的性能を要しない場合もあり、そのような場
合には電子線硬化性組成物からなる透明樹脂層を
設けないか、或いは通常の、電子線硬化性組成物
によらない透明樹脂層を設けることが好ましく、
かかる場合には、前記した通常インクから染料ま
たは顔料等の着色剤を抜いたもの等を塗布する
か、或いは、ポリエチレンフイルム、ポリエステ
ルフイルム、ポリ塩化ビニルフイルム、アクリル
フイルム、ポリカーボネートフイルム、ポリスチ
レンフイルム等のフイルム又はシートを公知のラ
ミネート法によりラミネートする、または、エク
ストルージヨンコーテイング、熱溶着などの方法
によつてもよい。 Examples of the transparent resin layer in the present invention include:
Among the electron beam curable compositions constituting the convex pattern layer made of the electron beam curable composition described above, transparent or colored transparent or semitransparent or colored semitransparent ones are used as the base material, the pattern layer, and the convex pattern layer. The transparent resin layer is selected and used as appropriate depending on the material of the pattern layer, the purpose of the decorative material, and the required performance. Depending on the application and required performance of the decorative material, advanced physical and
There are cases where chemical performance is not required, and in such cases, a transparent resin layer made of an electron beam curable composition is not provided, or a transparent resin layer not made of an ordinary electron beam curable composition is provided. It is preferable that
In such a case, apply the above-mentioned ordinary ink without colorants such as dyes or pigments, or apply ink with polyethylene film, polyester film, polyvinyl chloride film, acrylic film, polycarbonate film, polystyrene film, etc. The film or sheet may be laminated by a known lamination method, or by extrusion coating, thermal welding, or other methods.
以上のようにして基材に通常インクからなる模
様層を印刷し、該模様層に重ねて電子線硬化性組
成物からなる凸状模様層を設けた後電子線を照射
するとき、或いは、基材に通常インクからなる模
様層を印刷し、該模様層に重ねて電子線硬化性組
成物からなる凸状模様層を設け、更にその上に重
ねて透明樹脂層を被覆した後、該透明樹脂層を介
して電子線を照射するときに用いる電子線として
は、低エネルギー電子線加速器、たとえば、エネ
ルギーサイエンスインダストリー社製エレクトロ
カーテンCB200/50/30あるいはオツトーデユー
ル社製NP−ESH150などを使用し、加速電圧100
〜300kV照射電流0〜100mA、照射線量0.5〜
30Mradの電子線を用いることが好ましい。 When a pattern layer made of normal ink is printed on a base material as described above, a convex pattern layer made of an electron beam curable composition is provided on the pattern layer, and then an electron beam is irradiated, or when the base material is irradiated with an electron beam, A pattern layer made of ordinary ink is printed on the material, a convex pattern layer made of an electron beam curable composition is provided on top of the pattern layer, and a transparent resin layer is further covered on top of the pattern layer. The electron beam used when irradiating the electron beam through the layer is accelerated using a low-energy electron beam accelerator, such as Electrocurtain CB200/50/30 manufactured by Energy Science Industry Co., Ltd. or NP-ESH150 manufactured by Otsto Duel. voltage 100
~300kV irradiation current 0~100mA, irradiation dose 0.5~
Preferably, a 30 Mrad electron beam is used.
以上のような本発明に係る化粧材の製造法によ
れば通常インクからなる模様層と凸状模様層とを
意匠的に一致させることは容易であり、硬化に熱
を要しないため多くの基材に適用が効き、しかも
電子線照射のエネルギー効率が良いため高速生産
が可能であり、硬化がほぼ完全なため堆積などに
よる圧力に強くつぶれにくい、耐摩耗性がすぐれ
ているなどの利点を有する。 According to the method for producing a decorative material according to the present invention as described above, it is easy to match the pattern layer made of normal ink and the convex pattern layer in design, and since no heat is required for curing, many base materials can be used. It is effective for application to materials, and high-speed production is possible due to the high energy efficiency of electron beam irradiation, and it has advantages such as being almost completely cured, resistant to pressure from deposition, etc., and resistant to crushing, and excellent abrasion resistance. .
又、透明樹脂層を被覆するときは、耐摩耗性が
格段に向上し、表面の耐汚染性や物理的・化学的
性質にもすぐれた化粧材が得られる等の利点を有
する。 Furthermore, when covering with a transparent resin layer, there are advantages such as significantly improved abrasion resistance, and a decorative material having excellent surface stain resistance and physical and chemical properties.
以下に実施例を用いて更に本発明を具体的に説
明する。 The present invention will be further specifically explained below using Examples.
実施例 1
米坪23g/m2の薄葉紙にグラビア印刷方式によ
り下記組成物を全面に塗布した。Example 1 The following composition was coated on the entire surface of thin paper with a basis weight of 23 g/m 2 by a gravure printing method.
ニトロセルロース 70重量部
変性アルキツド 30 〃
酸化チタン 100 〃
酸化鉄 10 〃
シアニンブルー 5 〃
酢酸エチル 80 〃
トルエン 80 〃
イソプロパノール 40 〃
酢酸nブチル 10 〃
さらにグラビア印刷方式により下記組成物を用
いて、杉の木目を印刷した。Nitrocellulose 70 parts by weight Modified alkyd 30 Titanium oxide 100 Iron oxide 10 Cyanine blue 5 Ethyl acetate 80 Toluene 80 Isopropanol 40 N-butyl acetate 10 Furthermore, using the following composition by gravure printing method, cedar Printed wood grain.
ニトロセルロース 70重量部
変性アルキツド 30 〃
ポリアゾ染料
キナクリドン
シアニンブルー 5〜20 〃
酢酸エチル 80 〃
トルエン 80 〃
イソプロパノール 40 〃
酢酸nブチル 20 〃
さらに、杉の木目模様の冬目部のみに重ねて下
記組成の電子線硬化性組成物を線数50線、版深
150μのグラビア版を用いたグラビア印刷方式に
より凸状模様を印刷した。Nitrocellulose 70 parts by weight Modified alkyd 30 〃 Polyazo dye Quinacridone Cyanine Blue 5-20 〃 Ethyl acetate 80 〃 Toluene 80 〃 Isopropanol 40 〃 N-butyl acetate 20 〃 Furthermore, apply the following composition over only the winter part of the cedar grain pattern. Electron beam curable composition with 50 lines and plate depth
A convex pattern was printed using a gravure printing method using a 150μ gravure plate.
エポキシアクリレートオリゴマー(大阪有機化学
工業(株)製ビスコート#540) 50重量部
1,6−ヘキサンジオールジアクリレートモノマ
ー 50重量部
しかる後、印刷とインラインで印刷模様の側か
ら窒素気流中で加速エネルギー150keV、照射電
流10mA、照射線量10Mradの電子線を照射し、
凸状模様を硬化させ、化粧材を得た。Epoxy acrylate oligomer (Viscoat #540 manufactured by Osaka Organic Chemical Industry Co., Ltd.) 50 parts by weight 1,6-hexanediol diacrylate monomer 50 parts by weight Then, in-line with printing in a nitrogen stream from the printed pattern side with an acceleration energy of 150 keV , irradiated with an electron beam with an irradiation current of 10 mA and an irradiation dose of 10 Mrad,
The convex pattern was cured to obtain a decorative material.
以上のようにして得られた化粧材は、耐摩耗性
がすぐれ、板に貼つて堆積しても凸状模様がつぶ
れないものであつた。 The decorative material obtained as described above had excellent abrasion resistance, and the convex pattern did not collapse even when it was applied to a board and deposited.
実施例 2
厚み100μmの半硬質の白色塩化ビニルシート
上にグラビア印刷方式により下記組成のインキを
用いて抽象柄の模様を印刷した。Example 2 An abstract pattern was printed on a 100 μm thick semi-rigid white vinyl chloride sheet by gravure printing using ink having the following composition.
塩化ビニール樹脂 80重量部
アクリル樹脂 20 〃
可塑剤 20 〃
メチルエチルケトン 60 〃
メチルイソブチルケトン 60 〃
トルエン 40 〃
ポリアゾ染料
キナクリドン
シアニンブルー 5〜20 〃
さらに、線数50線、版深120μmのグラビア版
を用い、グラビア印刷方式により、前記抽象柄の
一部に下記組成の電子線硬化性組成物を重ねて凸
状模様を印刷した。Vinyl chloride resin 80 parts by weight Acrylic resin 20 〃 Plasticizer 20 〃 Methyl ethyl ketone 60 〃 Methyl isobutyl ketone 60 〃 Toluene 40 〃 Polyazo dye quinacridone cyanine blue 5-20 〃 Furthermore, using a gravure plate with 50 lines and a plate depth of 120 μm, A convex pattern was printed by overlaying an electron beam curable composition having the composition shown below on a part of the abstract pattern using a gravure printing method.
ウレタンアクリレートオリゴマー(東亜合成化学
工業(株)TO−381) 50重量部
1,6−ヘキサンジオールジアクリレートモノマ
ー 50 〃
酸化チタン 20 〃
しかる後、実施例1と同様の条件で電子線照射
を行ない凸状模様を硬化させ、化粧材を得た。得
られた化粧材は実施例1と同様、耐摩耗性がすぐ
れ、堆積にも強いものであつた。Urethane acrylate oligomer (Toagosei Kagaku Kogyo Co., Ltd. TO-381) 50 parts by weight 1,6-hexanediol diacrylate monomer 50 Titanium oxide 20 After that, electron beam irradiation was performed under the same conditions as in Example 1 to form convexities. The decorative material was obtained by curing the pattern. Similar to Example 1, the obtained decorative material had excellent abrasion resistance and was resistant to deposition.
実施例 3
実施例1と同様にして杉の木目および凸状模様
を設けた後、リバースコート方式により下記組成
物を厚み12μmになるように印刷層に重ねて塗布
し、インラインにて印刷層側から、加速エネルギ
ー150keV、照射電流10mA、照射線量5Mradの
カーテン状の電子線を照射し凸状模様を硬化させ
化粧材を得た。Example 3 After providing cedar wood grain and a convex pattern in the same manner as in Example 1, the following composition was applied over the printed layer to a thickness of 12 μm using a reverse coating method, and inline was applied to the printed layer side. Then, a curtain-shaped electron beam was irradiated with an acceleration energy of 150 keV, an irradiation current of 10 mA, and an irradiation dose of 5 Mrad to harden the convex pattern and obtain a decorative material.
エポキシアクリレートオリゴマー(大阪有機化学
工業(株)製ビスコート#540) 50重量部
トリメチロールプロパントリアクリレート
10 〃
1,6−ヘキサンジオールジアクリレート
40 〃
得られた化粧材は、凸状模様の耐摩耗性にすぐ
れ、板に貼つて堆積しても凸状模様がつぶれるよ
うなこともなく、しかも透明樹脂層が被覆してあ
るため、表面の耐汚染性や化学的性質のすぐれた
ものであつた。Epoxy acrylate oligomer (Viscoat #540 manufactured by Osaka Organic Chemical Industry Co., Ltd.) 50 parts by weight trimethylolpropane triacrylate
10 〃 1,6-hexanediol diacrylate
40 The obtained decorative material has a convex pattern with excellent abrasion resistance, and even if it is attached to a board and deposited, the convex pattern does not collapse, and since it is coated with a transparent resin layer, the surface It had excellent stain resistance and chemical properties.
Claims (1)
電子線硬化性組成物からなる凸状模様層の2種の
模様層を順次に設け、しかる後、電子線を照射
し、前記凸状模様を硬化せしめることを特徴とす
る凸状模様を有する化粧材の製造法。 2 基材上に、印刷方式により通常インクからな
る模様層および電子線硬化性組成物からなる凸状
模様層の2種の模様層を順次に設け、さらに前記
2種の模様層を設けた上に透明樹脂層を被覆し、
被覆後、前記透明樹脂層を介して電子線を照射
し、前記凸状模様を硬化せしめることを特徴とす
る凸状模様を有する化粧材の製造法。[Claims] 1. Two types of pattern layers, a pattern layer made of normal ink and a convex pattern layer made of an electron beam curable composition, are sequentially provided on a substrate, and then irradiated with an electron beam. . A method for producing a decorative material having a convex pattern, which comprises curing the convex pattern. 2. Two types of pattern layers, a pattern layer made of normal ink and a convex pattern layer made of an electron beam curable composition, are sequentially provided on the base material by a printing method, and the two types of pattern layers described above are further provided. coated with a transparent resin layer,
A method for producing a decorative material having a convex pattern, characterized in that after coating, an electron beam is irradiated through the transparent resin layer to harden the convex pattern.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4588481A JPS57159652A (en) | 1981-03-28 | 1981-03-28 | Manufacture of decorative material |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP4588481A JPS57159652A (en) | 1981-03-28 | 1981-03-28 | Manufacture of decorative material |
Publications (2)
Publication Number | Publication Date |
---|---|
JPS57159652A JPS57159652A (en) | 1982-10-01 |
JPH0141505B2 true JPH0141505B2 (en) | 1989-09-06 |
Family
ID=12731656
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP4588481A Granted JPS57159652A (en) | 1981-03-28 | 1981-03-28 | Manufacture of decorative material |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPS57159652A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08244193A (en) * | 1995-03-15 | 1996-09-24 | Toppan Printing Co Ltd | Decorative sheet with uneven pattern on surface |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO1994029102A1 (en) * | 1993-06-09 | 1994-12-22 | Triangle Pacific Corp. | Hardened and fire retardant wood products |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5195107A (en) * | 1975-02-13 | 1976-08-20 | PIANOTO SOSHIAGEHOHO |
-
1981
- 1981-03-28 JP JP4588481A patent/JPS57159652A/en active Granted
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5195107A (en) * | 1975-02-13 | 1976-08-20 | PIANOTO SOSHIAGEHOHO |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH08244193A (en) * | 1995-03-15 | 1996-09-24 | Toppan Printing Co Ltd | Decorative sheet with uneven pattern on surface |
Also Published As
Publication number | Publication date |
---|---|
JPS57159652A (en) | 1982-10-01 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP4268261B2 (en) | Cosmetic material and method for producing the same | |
JP2001079990A (en) | Decorative material | |
JPH0141505B2 (en) | ||
JP2008087155A (en) | Decorative sheet | |
JPH08174783A (en) | Manufacture of decoration sheet | |
JP2000263735A (en) | Decorative board and manufacture thereof | |
JP2001199028A (en) | Decorative material | |
JPS644832B2 (en) | ||
JPH0419924B2 (en) | ||
JP3201775B2 (en) | Manufacturing method of decorative sheet | |
JP2001328228A (en) | Decorative material | |
JP2000351178A (en) | Decorative material | |
JPH0155991B2 (en) | ||
JPH0479835B2 (en) | ||
JP2008265301A (en) | Face sheet | |
JPH068391A (en) | Decorative sheet and production thereof | |
JP3226605B2 (en) | Molded article having transfer layer and method for producing the same | |
JPS641114Y2 (en) | ||
JP3122973B2 (en) | Method of forming transfer layer on molded article | |
JP3226996B2 (en) | Method for manufacturing synchronized uneven cosmetic material | |
JPS641320B2 (en) | ||
JP3217399B2 (en) | Method of forming transfer layer on molded article | |
JPS6311947B2 (en) | ||
JPH10264347A (en) | Decorative plate and its manufacture | |
JPH0679845B2 (en) | Veneer manufacturing method |