JPH0140907B2 - - Google Patents

Info

Publication number
JPH0140907B2
JPH0140907B2 JP57072268A JP7226882A JPH0140907B2 JP H0140907 B2 JPH0140907 B2 JP H0140907B2 JP 57072268 A JP57072268 A JP 57072268A JP 7226882 A JP7226882 A JP 7226882A JP H0140907 B2 JPH0140907 B2 JP H0140907B2
Authority
JP
Japan
Prior art keywords
oil
content
powder
impregnated
alloy
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP57072268A
Other languages
Japanese (ja)
Other versions
JPS58189361A (en
Inventor
Hiroshi Nishe
Tetsuo Sekimoto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Metal Corp
Original Assignee
Mitsubishi Metal Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Metal Corp filed Critical Mitsubishi Metal Corp
Priority to JP57072268A priority Critical patent/JPS58189361A/en
Publication of JPS58189361A publication Critical patent/JPS58189361A/en
Publication of JPH0140907B2 publication Critical patent/JPH0140907B2/ja
Granted legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C33/00Parts of bearings; Special methods for making bearings or parts thereof
    • F16C33/02Parts of sliding-contact bearings
    • F16C33/04Brasses; Bushes; Linings
    • F16C33/06Sliding surface mainly made of metal
    • F16C33/12Structural composition; Use of special materials or surface treatments, e.g. for rust-proofing
    • F16C33/121Use of special materials
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F16ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
    • F16CSHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
    • F16C2204/00Metallic materials; Alloys
    • F16C2204/60Ferrous alloys, e.g. steel alloys

Landscapes

  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Sliding-Contact Bearings (AREA)
  • Powder Metallurgy (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

この発明は、なじみ性、潤滑性、および耐摩耗
性にすぐれ、かつ相手攻撃性も低く、特に高速回
転および高荷重条件下での使用に際しても発熱の
きわめて小さいFe基焼結合金製含油軸受に関す
るものである。 従来、例えば自動車や二輪車のスターターモー
タや、一般の駆動モータなどの軸受のうち、その
使用条件が高速回転および高荷重となる軸受に
は、なじみ性および潤滑性にすぐれ、かつ相手攻
撃性も小さいCu基焼結合金製含油軸受が使用さ
れている。 一方、これらCu基焼結合金製含油軸受は、主
要原料粉末として高価なCu粉末を使用するめに
コストの高いものとなるばかりでなく、主成分が
Cuであるために比較的耐摩耗性の低いものとな
つている。 そこで、上記のCu基焼結合金製含油軸受に代
つてコストが安く、かつ耐摩耗性のあるFe基焼
結合金製含油軸受を使用する試みもなされたが、
これらFe基焼結合金製含油軸受は、なじみ性が
悪いばかりでなく、使用中の発熱も大きいので、
軸受中に含浸された油が著しく消耗するようにな
り、この結果かじりやロツク現象が発生し、かえ
つてその使用が短かくなるものであり、さらに相
手材たる軸に対する攻撃性(相手攻撃性)も大き
いものであり、したがつて高速回転および高荷重
条件下での使用はほとんど不可能であるのが現状
である。 とこで、本発明者等は、上述のような観点か
ら、Cu基焼結合金製含油軸受のもつすぐれたな
じみ性および潤滑性、さらに著しく低い相手攻撃
性を有し、かつ耐摩耗性にもすぐれた含油軸受を
コストの比較的安価なFe基焼結合金にて得べく
研究を行なつた結果、含油軸受を、Cu:15〜40
%、Pb:5〜20%、C:0.1〜5.0%を含有し、さ
らにSn:0.1〜5.0%、Zn:0.1〜3.0%、および
P:0.1〜1.0%のうちの1種または2種以上を含
有し、残りがFeと不可避不純物からなる組成
(以上重量%)、並びにCu合金,Pb、および遊離
黒鉛が素地中に分散した組織を有し、かつ含油率
が3〜35容量%のFe基焼結合金で構成すると、
このFe基焼結合金製含油軸受は、特に高速回転
および高荷重条件下での使用に際して、発熱がき
わめて小さく、かつ相手攻撃性も著しく低い状態
で、すぐれたなじみ性、潤滑性、および耐摩耗性
を示すという知見を得たのである。 この発明は、上記知見にもとづいてなされたも
のであつて、以下に成分組成範囲および含油率を
上記の通りに限定した理由を説明する。 (a) Cu Cu成分には、その一部が素地に固溶して、そ
の強度を向上させ、一方残りがSn,Zn、および
Pのうちの1種または2種以上と合金化した形で
素地中に分散してなじみ性および耐摩耗性を向上
させる作用があるほか、焼結時におけるFeとPb
のぬれ性を促進せてPbの飛散を防止し、これを
安定化させる作用があるが、その含有量が15%未
満では前記作用に所望の効果が得られず、一方40
%を越えて含有させると、素地が硬くなりすぎて
相手攻撃性が大きくなることから、その含有量を
15〜40%と定めた。 (b) Pb Pb成分には、焼結時に原料粉末たる黒鉛粉末
がFe粉末と反応してセメンタイトを形成するの
を抑制すると共に、素地中に均一に分散してなじ
み性および耐焼付性を向上させる作用があるが、
その含有量が5%未満では前記作用に所望の効果
が得られず、一方20%を越えて含有させると、軸
受強度がが低下するようになることから、その含
有量を5〜20%と定めた。 (c) C C成分には、その一部が素地に固溶し、また他
の一部がパーライトを形成して素地を強化し、さ
らに残部が遊離黒鉛として素地中に均一に分散し
て潤滑性を向上させる作用があるが、その含有量
が0.1%未満では前記作用に所望の効果が得られ
ず、一方5.0%を越えて含有させると軸受強度が
低下するようになることから、その含有量を0.1
〜5.0%と定めた。 (d) Sn,Zn、およびP これらの成分には、それぞれ単独粉末で配合し
た場合には焼結時にCu中に固溶し(したがつて
これら成分をCu合金粉末の形で配合してもよ
い)、素地中に均一に分散したCu−(Sn,Zn,
P)合金を形成して、なじみ性および耐摩耗性を
向上させる作用があるが、その含有量はそれぞれ
Sn:0.1%未満、Zn:0.1%未満、およびP:0.1
%未満では前記作用に所望の効果が得られず、一
方それぞれSn:5%、Zn:3%、およびP:1
%を越えて含有させてもなじみ性および耐摩耗性
により一段の向上効果が得られないことから、そ
の含有量をSn:0.1〜5.0%、Zn:0.1〜3.0%、お
よびP:0.1〜1.0%と定めた。 (e) 含油率 含油率が5容量%未満では所望の潤滑性を確保
することができず、一方35容量%を越えた含油率
にすると軸受強度が著しく低下するようになるこ
とから、含油率を5〜35容量%と定めた。 つぎに、この発明の含油軸受を実施例により具
体的に説明する。 実施例 原料粉末として、粒度:−100meshのアトマイ
ズ鉄粉、同−150meshの電解銅粉末、同−
150meshのりん片状黒鉛粉末、同−100meshのPb
粉末、同−100meshのSn粉末、同−100meshの
Cu−Sn合金(Sn:9%含有)粉末、同−
100meshのZn粉末、同−100meshのCu−Zn合金
(Zn:30%含有)粉末、同−100meshのCu−P合
金(P:8%含有)粉末を用意し、これら原料粉
末をそれぞれ第1表に示される配合組成に配合
し、これに潤滑剤として0.4%のステアリン酸亜
鉛を添加して混合し、この混合粉末よりそれぞれ
3〜5ton/cm2の範囲内の適宜の圧力にて圧粉体を
成形し、ついでこれらの圧粉体を、アンモニア分
解ガス中、温度:1000〜1100℃の範囲内の適宜温
度に60分間保持の条件で焼結し、最終的に真空浸
油処理を施すことによつて、実質的に配合組成と
同一の成分組成、並びにそれぞれ第1表に示され
る含油率を有し、かつ外径:16mmφ×内径:8mm
φ×高さ:10mmの寸法をもつた本発明含油軸受1
〜23および比較含油軸受1〜8をそれぞれ製造し
た。なお、比較含油軸受1
The present invention relates to an oil-impregnated bearing made of an Fe-based sintered alloy that has excellent conformability, lubricity, and wear resistance, and has low attack potential, and in particular generates very little heat even when used under high-speed rotation and high load conditions. It is something. Conventionally, bearings used in starter motors for automobiles and motorcycles, general drive motors, etc., which are used under high-speed rotation and high load conditions, have excellent conformability and lubricity, and are less likely to attack others. Oil-impregnated bearings made of Cu-based sintered alloy are used. On the other hand, oil-impregnated bearings made of Cu-based sintered alloys are not only expensive because they use expensive Cu powder as the main raw material powder, but also
Since it is Cu, it has relatively low wear resistance. Therefore, attempts have been made to use oil-impregnated bearings made of Fe-based sintered alloys, which are cheaper and more wear-resistant, in place of the oil-impregnated bearings made of Cu-based sintered alloys mentioned above.
These oil-impregnated bearings made of Fe-based sintered alloys not only have poor conformability but also generate a large amount of heat during use.
The oil impregnated in the bearing becomes significantly consumed, resulting in galling and locking phenomena, which shortens its use, and furthermore, it becomes aggressive towards the mating shaft (aggressiveness). It is also large, and therefore it is currently almost impossible to use it under high speed rotation and high load conditions. From the above-mentioned viewpoint, the inventors of the present invention have developed an oil-impregnated bearing made of a Cu-based sintered alloy that has excellent conformability and lubricity, has extremely low attack resistance, and has excellent wear resistance. As a result of conducting research to obtain excellent oil-impregnated bearings using relatively inexpensive Fe-based sintered alloys, we found that oil-impregnated bearings with Cu: 15 to 40
%, Pb: 5 to 20%, C: 0.1 to 5.0%, and one or more of Sn: 0.1 to 5.0%, Zn: 0.1 to 3.0%, and P: 0.1 to 1.0%. Fe with an oil content of 3 to 35% by volume, with a composition in which the remainder is Fe and unavoidable impurities (more than % by weight), and a structure in which Cu alloy, Pb, and free graphite are dispersed in the matrix. When composed of a base sintered alloy,
This oil-impregnated bearing made of Fe-based sintered alloy generates very little heat and has extremely low aggressiveness, especially when used under high-speed rotation and high load conditions, and has excellent conformability, lubricity, and wear resistance. They obtained the knowledge that it indicates gender. This invention was made based on the above findings, and the reason why the component composition range and oil content were limited as described above will be explained below. (a) Cu A part of the Cu component is dissolved in the base material to improve its strength, while the rest is alloyed with one or more of Sn, Zn, and P. In addition to dispersing into the base material and improving conformability and wear resistance, Fe and Pb during sintering
It has the effect of promoting the wettability of Pb, preventing scattering of Pb, and stabilizing it, but if the content is less than 15%, the desired effect cannot be obtained;
If the content exceeds %, the material will become too hard and the opponent will be more aggressive, so the content should be reduced.
It was set at 15-40%. (b) Pb The Pb component suppresses the reaction of graphite powder, which is a raw material powder, with Fe powder during sintering to form cementite, and also improves conformability and seizure resistance by uniformly dispersing it in the base material. It has the effect of causing
If the content is less than 5%, the desired effect cannot be obtained, while if the content exceeds 20%, the bearing strength will decrease, so the content should be set at 5 to 20%. Established. (c) C A part of the C component dissolves in the base material, another part forms pearlite to strengthen the base material, and the remaining part is uniformly dispersed in the base material as free graphite and provides lubrication. However, if the content is less than 0.1%, the desired effect cannot be obtained, while if the content exceeds 5.0%, the bearing strength will decrease. amount 0.1
It was set at ~5.0%. (d) Sn, Zn, and P When these components are blended as individual powders, they dissolve into Cu during sintering (therefore, even if these components are blended in the form of Cu alloy powder, Cu-(Sn, Zn,
P) It has the effect of forming an alloy and improving conformability and wear resistance, but the content of each
Sn: less than 0.1%, Zn: less than 0.1%, and P: 0.1
%, the desired effect cannot be obtained in the above action, while Sn: 5%, Zn: 3%, and P: 1
Even if the content exceeds 0.9%, no further improvement effect can be obtained due to conformability and wear resistance. %. (e) Oil content If the oil content is less than 5% by volume, the desired lubricity cannot be secured, while if the oil content exceeds 35% by volume, the bearing strength will drop significantly. was set at 5 to 35% by volume. Next, the oil-impregnated bearing of the present invention will be specifically explained using examples. Example Raw material powders include atomized iron powder with a particle size of -100mesh, electrolytic copper powder with a particle size of -150mesh, and -
150mesh flaky graphite powder, 100mesh Pb
Powder, -100mesh Sn powder, -100mesh
Cu-Sn alloy (Sn: 9% content) powder,
Prepare 100mesh Zn powder, -100mesh Cu-Zn alloy (Zn: 30% content) powder, and -100mesh Cu-P alloy (P: 8% content) powder. 0.4% zinc stearate is added as a lubricant and mixed, and the mixed powder is pressed into a green compact at an appropriate pressure within the range of 3 to 5 tons/ cm2 . These compacts are then sintered in ammonia decomposition gas at an appropriate temperature within the range of 1000 to 1100°C for 60 minutes, and finally subjected to vacuum oil immersion treatment. Accordingly, it has substantially the same component composition as the blended composition and the oil content shown in Table 1, and outer diameter: 16 mmφ x inner diameter: 8 mm
Oil-impregnated bearing 1 of the present invention with dimensions of φ x height: 10 mm
-23 and comparative oil-impregnated bearings 1-8 were manufactured, respectively. In addition, comparative oil-impregnated bearing 1

【表】【table】

【表】 〜7はいずれも構成成分のうちのいずれかの成分
含有量、並びに含油率(第1表※印を付したも
の)がこの発明の範囲から外れたものであり、ま
た比較含油軸受8は従来Cu基焼結合金製のもの
である。 ついで、この結果得られた本発明含油軸受1〜
23および比較含油軸受1〜8について、圧環強度
を測定すると共に、PV値:700Kg/cm2・m/
min、周速:150m/minおよび200m/minの条
件(高速回転・高荷重条件)での摩耗量、摩擦係
数、および軸受温度を測定した。これらの測定結
果を第1表に合せて示した。 第1表に示される結果から、本発明含油軸受1
〜23は、いずれも従来Cu基焼結合金製含油軸受
に相当する比較含油軸受8に比して一段とすぐれ
た強度および耐摩耗性を有し、かつこれと同等の
すぐれたなじみ性および潤滑性、並びに低い相手
攻撃性を有するのに対して、比較含油軸受1〜7
に見られるように成分組成および含油率がこの発
明の範囲から外れると、上記の軸受特性のうちの
少なくともいずれかの性質が劣つたものになるこ
とが明らかである。 上述のように、この発明の含油軸受は、Fe基
焼結合金製であるので安価であり、かつすぐれた
なじみ性、潤滑性、および耐摩耗性、並びに低い
相手攻撃性を有し、しかも特に高速回転・高荷重
条件下での使用に際しても発熱がきわめて少ない
ものであるので、広い範囲での長期に亘つての安
定的使用が可能となるなどの工業上有用な特性を
有するのである。
[Table] - 7 all have the content of one of the constituent components and the oil content (marked with * in Table 1) outside the scope of this invention, and comparative oil-impregnated bearings 8 is a conventional one made of Cu-based sintered alloy. Next, the oil-impregnated bearings 1 to 1 of the present invention obtained as a result
23 and comparative oil-impregnated bearings 1 to 8, the radial crushing strength was measured and the PV value: 700Kg/cm 2 m/
The wear amount, friction coefficient, and bearing temperature were measured at circumferential speeds of 150 m/min and 200 m/min (high-speed rotation and high load conditions). These measurement results are also shown in Table 1. From the results shown in Table 1, oil-impregnated bearing 1 of the present invention
-23 all have superior strength and wear resistance compared to comparative oil-impregnated bearing 8, which corresponds to conventional oil-impregnated bearings made of Cu-based sintered alloy, and have excellent conformability and lubricity equivalent to this. , as well as low opponent aggression, whereas comparative oil-impregnated bearings 1 to 7
It is clear that when the component composition and oil content are outside the scope of the present invention, at least one of the above-mentioned bearing properties becomes inferior, as shown in FIG. As mentioned above, the oil-impregnated bearing of the present invention is made of an Fe-based sintered alloy, so it is inexpensive, and has excellent conformability, lubricity, and wear resistance, as well as low aggressiveness to others. Since it generates very little heat even when used under high speed rotation and high load conditions, it has industrially useful properties such as being able to be used stably over a wide range over a long period of time.

Claims (1)

【特許請求の範囲】[Claims] 1 Cu:15〜40%、Pb:5〜20%、C:0.1〜5.0
%を含有し、さらにSn:0.1〜5.0%,Zn:0.1〜
3.0%、およびP:0.1〜1.0%のうちの1種または
2種以上を含有し、残りがFeと不可避不純物か
らなる組成(以上重量%)、並びにCu合金、Pb、
および遊離黒鉛が素地中に分散した組織を有し、
かつ含油率:5〜35容量%を有することを特徴と
するなじみ性および潤滑性のすぐれたFe基焼結
合金製含油軸受。
1 Cu: 15-40%, Pb: 5-20%, C: 0.1-5.0
%, and further contains Sn: 0.1~5.0%, Zn: 0.1~
3.0%, and P: 0.1 to 1.0%, and the remainder is Fe and unavoidable impurities (wt%), as well as Cu alloy, Pb,
and has a structure in which free graphite is dispersed in the matrix,
An oil-impregnated bearing made of an Fe-based sintered alloy having excellent conformability and lubricity, and having an oil content of 5 to 35% by volume.
JP57072268A 1982-04-28 1982-04-28 Oil-containing bearing made of sintered fe alloy with superior fitness and lubricity Granted JPS58189361A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP57072268A JPS58189361A (en) 1982-04-28 1982-04-28 Oil-containing bearing made of sintered fe alloy with superior fitness and lubricity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP57072268A JPS58189361A (en) 1982-04-28 1982-04-28 Oil-containing bearing made of sintered fe alloy with superior fitness and lubricity

Publications (2)

Publication Number Publication Date
JPS58189361A JPS58189361A (en) 1983-11-05
JPH0140907B2 true JPH0140907B2 (en) 1989-09-01

Family

ID=13484363

Family Applications (1)

Application Number Title Priority Date Filing Date
JP57072268A Granted JPS58189361A (en) 1982-04-28 1982-04-28 Oil-containing bearing made of sintered fe alloy with superior fitness and lubricity

Country Status (1)

Country Link
JP (1) JPS58189361A (en)

Families Citing this family (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH01275735A (en) * 1988-04-27 1989-11-06 Isamu Kikuchi Sintered alloy material and its manufacture
JP2551981B2 (en) * 1988-09-14 1996-11-06 大同メタル工業 株式会社 Multi-layer iron copper lead alloy bearing material
JP2631146B2 (en) * 1989-09-11 1997-07-16 勇 菊池 Sintered metal body and method for producing the same
JPH03199348A (en) * 1989-12-28 1991-08-30 Isamu Kikuchi Sintered alloy bearing
GB2333779A (en) * 1997-08-07 1999-08-04 Porite Corp Composite metal powder for sintered bearing, and sintered oil-retaining bearing
JP4507766B2 (en) * 2004-08-27 2010-07-21 株式会社ダイヤメット Sintered Cu alloy bearing for recirculation exhaust gas flow control valve of EGR type internal combustion engine showing high strength and excellent wear resistance in high temperature environment
CN103071800A (en) * 2012-11-23 2013-05-01 东睦(江门)粉末冶金有限公司 Iron-based oil-containing bearing and manufacturing method thereof
JP6817094B2 (en) * 2016-07-29 2021-01-20 株式会社ダイヤメット Iron-copper-based sintered oil-impregnated bearing and its manufacturing method
CN108465808A (en) * 2018-04-02 2018-08-31 常熟市华德粉末冶金有限公司 A kind of preparation method of tin bronze ferrous based powder metallurgical and its oiliness bearing
CN111001813B (en) * 2019-12-28 2022-02-18 合肥波林新材料股份有限公司 High-antifriction iron-based vulcanized powder metallurgy oil-retaining bearing material and preparation method and application thereof

Also Published As

Publication number Publication date
JPS58189361A (en) 1983-11-05

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