JPH0135960B2 - - Google Patents

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Publication number
JPH0135960B2
JPH0135960B2 JP16542581A JP16542581A JPH0135960B2 JP H0135960 B2 JPH0135960 B2 JP H0135960B2 JP 16542581 A JP16542581 A JP 16542581A JP 16542581 A JP16542581 A JP 16542581A JP H0135960 B2 JPH0135960 B2 JP H0135960B2
Authority
JP
Japan
Prior art keywords
laminated
fiberboard
long fiber
fiber material
mat
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
JP16542581A
Other languages
Japanese (ja)
Other versions
JPS5870796A (en
Inventor
Takashi Shimada
Yasuo Nakajima
Tatsuo Kishimoto
Toshuki Hiraoka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Daiken Trade and Industry Co Ltd
Original Assignee
Daiken Trade and Industry Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Daiken Trade and Industry Co Ltd filed Critical Daiken Trade and Industry Co Ltd
Priority to JP16542581A priority Critical patent/JPS5870796A/en
Publication of JPS5870796A publication Critical patent/JPS5870796A/en
Publication of JPH0135960B2 publication Critical patent/JPH0135960B2/ja
Granted legal-status Critical Current

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  • Paper (AREA)
  • Laminated Bodies (AREA)

Description

【発明の詳細な説明】[Detailed description of the invention]

本発明は、耐衝撃性、耐屈曲性、引張強度等に
優れた多層構造を有する繊維板を湿式抄造によつ
て構造する方法に関するものである。 従来、木材繊維板は、木材チツプを蒸煮処理し
たのちデイスクリフアイナーにより解繊した所謂
サーモメカニカルパルプ(TMP)を抄造して形
成されており、断熱性、加工性等に優れており、
又、一回の抄造で比較的厚い物が構造できると共
に構造時のプレス圧等の条件を変えることにより
断熱材、建築用材、家具用パネル、梱包用材、各
種成型材用基材等の各種用途に適したものが製造
されている。 しかしながら、このようなサーモメカニカルパ
ルプのみからなる繊維板は、他の木質材に比べて
同比重であれば曲げ或いは耐衝撃性等の面で劣る
ため、所望の強度のものを得るには厚さを厚く形
成して用いたり、或いは高比重のものに形成して
用いる必要があり、軽量で且つ曲げや引張り強度
の大なる繊維板の開発が望まれている。 一方、このような木質繊維板の強度的欠点を除
去する方法として、上記サーモメカニカルパルプ
に麻繊維や合成繊維等の引張り強度に優れた長繊
維材料を混入して製造することも一般に提案され
ているが、サーモメカニカルパルプに長繊維材料
を混合分散させた繊維マツトを抄造する場合、長
繊維材料の添加量に応じて抄造スピード等の条件
を変えたり、バインダー等の種類及び量を変える
等の面倒な操作が必要であり、又、得られた繊維
板の強度的性能もその混合量に応じて漸進的に向
上するのみで飛躍的な向上は期待できない。 さらに、建材、家具用材、梱包用資材或いは成
型用基材その他の各種工業用資材においては、そ
の用途、使用部位によつては単に強度的な面のみ
の向上では不充分であつて表面の化粧性や平滑
性、曲げ加工性、耐屈曲性、表面の耐衝撃性等の
諸性能が要求されることが多く、一工程の製造ラ
インでこのような要求する性能に応じた物性を有
する繊維板を形成することは極めて困難であつ
た。 本発明はこのような欠点及び問題点をなくする
ために、サーモメカニカルパルプを抄造してなる
湿潤マツトに長繊維材料を主体とする繊維質スラ
リーを抄き合わせて積層マツトを形成し、このマ
ツトを乾燥することなく複数枚積層して加熱、圧
締し、一体化することにより、前記要望を満足し
得る新規な多層構造を有する繊維板の構造方法を
提供するものである。 本発明の実施例を図面について説明すると、ま
ず、第1図に示すように、サーモメカニカルパル
プを主体とするスラリー1aを丸網式抄造機によ
つて抄造して所望厚さのウエツトマツト1を形成
すると同時に、その抄き上げたマツト表面に、ク
ラフトパルプ、綿繊維、合成繊維、グラスウール
の一種もしくは二種以上の混合物からなる長繊維
材料を主体とする繊維質スラリー2aを抄き合わ
せてウエツトマツト上に長繊維材料層2を設けた
積層マツト3を形成する。 サーモメカニカルパルプを主体とするスラリー
1aには、必要に応じて少量のバインダー或いは
スターチ等が結合剤として添加され、その他、故
紙、合成繊維等の繊維状物やロジン、ワツクス等
のサイズ剤が少量添加される。 なお、抄き合わせ方法については、図示のよう
に、ウエツトマツト1上に直接、繊維質スラリー
2aを流し出して抄き合わせる方法以外に、別途
の長網抄造機等で抄造した長繊維材料の湿潤シー
トを前記ウエツトマツト1上に載置して抄き合わ
せる方法を採用してもよい。 又、このような抄き合わせ時に、ウエツトマツ
ト1と長繊維材料層2との界面に適宜の接着剤4
をスプレー5等で散布して両者の結合力を高めて
もよい。 次に、こうして抄き合わされてなる積層マツト
3を適宜長さ寸法毎に裁断し、これを乾燥するこ
となく、裁断された複数枚の積層マツト3a,3
aを重ね合わせて積層体6とし、この積層体6を
ホツトプレスの熱盤7,8間に挿入して加熱、圧
締することにより一体化するものである。 この際、複数枚の積層マツト3a,3aの積層
状態は得ようとする繊維板の使用目的に応じて、
さらには抄き合わせた長繊維材料に応じて任意に
決定されるものであり、例えば、長繊維材料とし
てクラフトパルプ等の繊維長が長く且つ引張り強
度の強いケミカルパルプを用いることにより表面
平滑性及び曲げ強度に優れたものを得ようとする
場合には、第1図に示すように長繊維材料層2を
上面側にして複数枚の積層マツト3a,3aを重
ね合わせるか或いは第2図に示すように最外層部
の積層マツト3a,3aの長繊維材料層2,2を
夫々外面側にして積層し、熱圧一体化するもので
ある。この場合、長繊維材料として合成繊維を単
独又はクラフトパルプ等に混合して抄き合わせた
積層マツトを用いると、表面の耐水性、吸水性を
も改善された繊維板を得ることができる。 又、第3図に示すように、長繊維材料層2,2
を各々内面側にして積層マツト3a,3aを重ね
合わせて積層一体化してもよく、この場合、絡み
合いの強い長繊維材料によつて該中心層が形成さ
れるために耐屈曲性に優れた繊維板が得られるも
のであり、特に長繊維材料としてガラス繊維のよ
うに皮膚を刺激する材料を用いる場合においては
このように長繊維材料層2,2を内面側に配した
構造の繊維板に形成するのが取扱い上好ましい。 積層マツト3a,3aの重ね合わせ後、前述し
たようにホツトプレスの熱盤7,8間に挿入して
比重が0.4〜1.0になるまで加熱圧締すると、乾燥
した繊維板を圧締接着する場合と異なり、各積層
マツト3a,3aの界面における繊維同志が水分
の移動等によつて絡み合いを生じて一体化される
と共に各積層マツト3a,3aを構成するサーモ
メカニカルパルプと長繊維材料との絡み合いも又
促進され、夫々の層間が繊維の絡み合いによつて
一体化した多層構造の繊維板が得られるものであ
る。 なお、積層マツト3aを複数枚重ね合わせる際
に、積層マツト3a,3aの界面に予め接着剤を
塗布して積層し、しかるのち加熱圧締すれば積層
マツト3a,3a間の結合力が一層高まり、強度
的性能をさらに向上せることができる。 さらに、積層マツトの長繊維材料層2の厚さ
は、繊維板の用途に応じて該スラリー2aの供給
スピードを調節するのみで自由に決定できるもの
であるから、特に限定されないが、少なくともサ
ーモメカニカルパルプのウエツトマツト1上に60
g/m2以上抄き合わせておく方が抄き合わせ斑が
生ぜず、又、強度の向上が大となつて好ましい。 次に本発明の具体的な実施例と比較例を示す。 実施例 サーモメカニカルパルプ(TMP)98部、フエ
ノール樹脂2部、硫酸バン±1.5部を混合して調
整したスラリーを丸網式抄造機によつて抄造して
フアイバー量が2000g/m2のウエツトマツトを形
成し、このウエツトマツト上に、針葉樹のクラフ
トパルプ98部、フエノール樹脂2部、硫酸バン土
1.5部を混合して調整したパルプスラリーを抄き
合わせ量200g/m2の割合で抄き合わせ、これを
適宜寸法毎に裁断して得られる積層マツトを乾燥
することなくその長繊維材料層を上方に向けた状
態で2枚重ねてホツトプレスにより180℃、20
Kg/cm2で1分間加熱加圧したのち同じく180℃、
5Kg/cm2で9分間加熱加圧して比重0.8、厚さ5.5
mm(サーモメカニカルパルプの厚さ2.5×2、長
繊維材料層の厚さ0.25×2)の4層からなる繊維
板を得た。 一方、比較例Aとして、前記サーモメカニカル
パルプを主体とするスラリー、即ち、サーモメカ
ニカルパルプ(TMP)98部、フエノール樹脂2
部、硫酸バン土1.5部からなるスラリーのみで抄
造したウエツトマツトを前記実施例と同一条件で
加熱加圧して比重0.8、厚さ5.5mmの繊維板を形成
した。 又、比較例Bとして、サーモメカニカルパルプ
(TMP)89.1部、針葉樹のクラフトパルプ8.9部、
フエノール樹脂2部、硫酸バン土1.5部を混合し
て調整したスラリーからフアイバー量4400g/m2
のウエツトマツトを抄造し、これを実施例と同一
条件で加熱加圧して比重0.8、厚さ5.5mmの繊維板
を形成した。 こうして得られた実施例と比較例A、Bとの物
性を次に表示する。但し、実施例のものは長繊維
材料層を引張り側に配してテストしている。
The present invention relates to a method for constructing a fiberboard having a multilayer structure with excellent impact resistance, bending resistance, tensile strength, etc. by wet papermaking. Traditionally, wood fiberboards have been made from so-called thermomechanical pulp (TMP), which is made by steaming wood chips and then defibrating them using a disk-cliffing iner.
In addition, it is possible to construct relatively thick products in a single papermaking process, and by changing conditions such as press pressure during construction, it can be used for various purposes such as insulation materials, construction materials, furniture panels, packaging materials, and base materials for various molding materials. A suitable product is manufactured. However, fiberboard made only of thermomechanical pulp is inferior to other wood materials in terms of bending and impact resistance at the same specific gravity, so it is difficult to obtain the desired strength due to the thickness. It is necessary to use a fiberboard formed to be thick or to have a high specific gravity, and there is a desire to develop a fiberboard that is lightweight and has high bending and tensile strength. On the other hand, as a method to eliminate such strength defects of wood fiberboards, it has generally been proposed to manufacture wood fiberboards by mixing long fiber materials with excellent tensile strength such as hemp fibers or synthetic fibers into the thermomechanical pulp. However, when making a fiber mat made by mixing and dispersing long fiber material into thermomechanical pulp, it is necessary to change conditions such as the paper making speed depending on the amount of long fiber material added, or to change the type and amount of binder, etc. Cumbersome operations are required, and the strength performance of the obtained fiberboard is only improved gradually depending on the amount of the fiberboard mixed, and no dramatic improvement can be expected. Furthermore, for various industrial materials such as building materials, furniture materials, packaging materials, molding base materials, etc., depending on the purpose and the area of use, it may not be sufficient to simply improve the strength, and the cosmetic appearance of the surface may be insufficient. Various properties such as flexibility, smoothness, bending workability, bending resistance, and surface impact resistance are often required, and fiberboard with physical properties that meet these required performances can be produced in one production line. It was extremely difficult to form. In order to eliminate such drawbacks and problems, the present invention forms a laminated mat by mixing a wet mat made of thermomechanical pulp with a fibrous slurry mainly made of long fiber material, and The present invention provides a method for constructing a fiberboard having a novel multilayer structure that satisfies the above requirements by laminating, heating, pressing, and integrating a plurality of fiberboards without drying them. An embodiment of the present invention will be explained with reference to the drawings. First, as shown in FIG. 1, a slurry 1a mainly composed of thermomechanical pulp is made into paper using a circular mesh paper making machine to form a wet mat 1 having a desired thickness. At the same time, a fibrous slurry 2a mainly made of a long fiber material consisting of one or a mixture of two or more of kraft pulp, cotton fibers, synthetic fibers, and glass wool is mixed on the surface of the wet pine. A laminated mat 3 provided with a long fiber material layer 2 is formed. A small amount of binder or starch is added as a binding agent to the slurry 1a, which is mainly composed of thermomechanical pulp, and a small amount of fibrous materials such as waste paper and synthetic fibers, and sizing agents such as rosin and wax are added as needed. added. As for the paper-combining method, as shown in the figure, in addition to the method of directly pouring the fibrous slurry 2a onto the wet mat 1 and combining the paper, there is also a method of wetting long fiber material made by a separate fourdrinier machine or the like. A method may be adopted in which the sheets are placed on the wet mat 1 and then combined. Also, during such papermaking, an appropriate adhesive 4 is applied to the interface between the wet mat 1 and the long fiber material layer 2.
may be sprayed with a sprayer 5 or the like to increase the bonding strength between the two. Next, the laminated mat 3 thus made is cut into appropriate lengths, and without drying, a plurality of cut laminated mats 3a, 3 are cut.
A is superimposed to form a laminate 6, and this laminate 6 is inserted between hot plates 7 and 8 of a hot press, heated and pressed to be integrated. At this time, the laminated state of the plurality of laminated mats 3a, 3a depends on the purpose of use of the fiberboard to be obtained.
Furthermore, it is arbitrarily determined depending on the long fiber material used in the papermaking. For example, by using chemical pulp such as kraft pulp, which has long fiber length and strong tensile strength, as the long fiber material, surface smoothness and When trying to obtain a material with excellent bending strength, a plurality of laminated mats 3a, 3a are stacked on top of each other with the long fiber material layer 2 on the top side as shown in FIG. 1, or as shown in FIG. In this way, the outermost laminated mats 3a, 3a are laminated with the long fiber material layers 2, 2 facing outward, respectively, and integrated under heat and pressure. In this case, if a laminated mat made of synthetic fiber alone or mixed with kraft pulp or the like is used as the long fiber material, a fiberboard with improved surface water resistance and water absorption can be obtained. Further, as shown in FIG. 3, long fiber material layers 2, 2
The laminated mats 3a, 3a may be laminated and integrated with each other facing the inner surface. In this case, since the center layer is formed of a long fiber material with strong entanglement, the fibers have excellent bending resistance. In particular, when a material that irritates the skin, such as glass fiber, is used as the long fiber material, it is necessary to form a fiber board with a structure in which the long fiber material layers 2, 2 are arranged on the inner side. It is preferable to do this in terms of handling. After stacking the laminated mats 3a and 3a, as described above, they are inserted between the hot plates 7 and 8 of the hot press and heated and pressed until the specific gravity becomes 0.4 to 1.0. Differently, the fibers at the interface of each laminated mat 3a, 3a are entangled and integrated due to the movement of moisture, etc., and the thermomechanical pulp and long fiber material that constitute each laminated mat 3a, 3a are also entangled. Further, it is possible to obtain a fiberboard having a multilayer structure in which the interlayers are integrated by intertwining of fibers. In addition, when stacking a plurality of laminated mats 3a, if adhesive is applied to the interface of the laminated mats 3a, 3a in advance, and then the laminated mats 3a are laminated, and then heat-pressed, the bonding strength between the laminated mats 3a, 3a is further increased. , strength performance can be further improved. Further, the thickness of the long fiber material layer 2 of the laminated mat is not particularly limited, as it can be determined freely by simply adjusting the supply speed of the slurry 2a depending on the use of the fiberboard, but at least thermomechanical 60 on pulp wet mats 1
It is preferable to combine the sheets at a rate of g/m 2 or more, since unevenness will not occur and the strength will be greatly improved. Next, specific examples and comparative examples of the present invention will be shown. Example: A slurry prepared by mixing 98 parts of thermomechanical pulp (TMP), 2 parts of phenol resin, and ±1.5 parts of ban sulfate was made into a wet mat with a fiber amount of 2000 g/m 2 by using a circular mesh paper making machine. 98 parts of coniferous kraft pulp, 2 parts of phenolic resin, and vanium sulfate were formed on this wet mat.
Pulp slurry prepared by mixing 1.5 parts of pulp slurry is mixed at a mixing rate of 200 g/ m2 , and the resulting laminated mat is cut into appropriate dimensions, and the long fiber material layer is removed without drying. Stack two sheets facing upwards and heat press at 180℃ for 20 minutes.
After heating and pressurizing at Kg/cm 2 for 1 minute,
Heat and pressurize at 5Kg/ cm2 for 9 minutes, specific gravity 0.8, thickness 5.5
A fiber board was obtained consisting of four layers of mm (thickness of thermomechanical pulp 2.5×2, thickness of long fiber material layer 0.25×2). On the other hand, as Comparative Example A, a slurry mainly composed of the thermomechanical pulp, that is, 98 parts of thermomechanical pulp (TMP), 2 parts of phenol resin,
A wet mat made from a slurry consisting of 1.5 parts of aluminum sulfate and 1.5 parts of aluminum sulfate was heated and pressed under the same conditions as in the above example to form a fiberboard with a specific gravity of 0.8 and a thickness of 5.5 mm. In addition, as Comparative Example B, 89.1 parts of thermomechanical pulp (TMP), 8.9 parts of softwood kraft pulp,
Fiber amount 4400g/m 2 from slurry prepared by mixing 2 parts of phenolic resin and 1.5 parts of aluminum sulfate.
A wet mat was made into paper and heated and pressed under the same conditions as in the example to form a fiberboard with a specific gravity of 0.8 and a thickness of 5.5 mm. The physical properties of Examples and Comparative Examples A and B thus obtained are shown below. However, in the example, the long fiber material layer was placed on the tension side and tested.

【表】 上記表から明らかなように、本発明実施例で得
られた繊維板は比較例A、Bの繊維板に比べて曲
げ強度及び耐衝撃性のいずれの点においても優れ
た物性を示した。 以上のように本発明は、サーモメカニカルパル
プを抄造してなる湿潤マツトの少なくとも片面
に、クラフトパルプ、綿繊維、合成繊維、グラス
ウールの単独もしくはこれらの混合物からなる長
繊維材料を主体とする繊維質スラリーを抄き合わ
せて積層マツトを形成したのち、該積層マツトを
乾燥することなく複数枚積層して加熱圧締し、一
体化することを特徴とする多層構造を有する繊維
板の構造方法に係るものであるから、サーモメカ
ニカルパルプと長繊維材料層とが一体に且つ多層
に層着して曲げ強度及び耐衝撃性に優れた繊維板
を簡単に得ることができ、この際、長繊維材料層
を表面にすることによつて表面化粧性、平滑性、
曲げ加工性の優れた繊維板に形成し得る一方、長
繊維材料層を内層に配すると耐屈曲性に優れた繊
維板に形成でき、従つて、要望する性能に応じた
物性を有する繊維板を容易に得ることができるも
のである。
[Table] As is clear from the above table, the fiberboards obtained in the Examples of the present invention exhibited superior physical properties in terms of both bending strength and impact resistance compared to the fiberboards of Comparative Examples A and B. Ta. As described above, the present invention provides a wet mat made of thermomechanical pulp, on at least one side of which is coated with a fibrous material mainly consisting of a long fiber material consisting of kraft pulp, cotton fiber, synthetic fiber, glass wool alone or in a mixture thereof. A method of constructing a fiberboard having a multilayer structure, which comprises: mixing slurry to form a laminated mat, and then laminating a plurality of the laminated mats without drying and heat-pressing them to integrate them. Therefore, it is possible to easily obtain a fiberboard with excellent bending strength and impact resistance by integrally layering the thermomechanical pulp and the long fiber material layer in multiple layers, and in this case, the long fiber material layer By making the surface cosmetic, smoothness,
While it is possible to form a fiberboard with excellent bending properties, it is also possible to form a fiberboard with excellent bending resistance by disposing a long fiber material layer in the inner layer. It is something that can be easily obtained.

【図面の簡単な説明】[Brief explanation of drawings]

図面は本発明の実施例を示すもので、第1図は
その構造工程を示す簡略側面図、第2図及び第3
図は積層マツトの異なつた重ね合わせ状態を示す
説明図である。 1……ウエツトマツト、2……長繊維材料層、
3a……積層マツト、6……積層体。
The drawings show an embodiment of the present invention, and FIG. 1 is a simplified side view showing the construction process, and FIGS.
The figures are explanatory views showing different overlapping states of the laminated mats. 1... wet mat, 2... long fiber material layer,
3a...Laminated mat, 6...Laminated body.

Claims (1)

【特許請求の範囲】 1 サーモメカニカルパルプを抄造してなる湿潤
マツトの少なくとも片面に、クラフトパルプ、綿
繊維、合成繊維、グラスウールの単独もしくはこ
れらの混合物からなる長繊維材料を主体とする繊
維質スラリーを抄き合わせて積層マツトを形成し
たのち、該積層マツトを乾燥することなく複数枚
積層して加熱圧締し、一体化することを特徴とす
る多層構造を有する繊維板の製造方法。 2 積層マツト同志の界面に接着剤を塗布して積
層一体化することを特徴とする特許請求の範囲第
1項記載の多層構造を有する繊維板の製造方法。 3 積層マツトの長繊維材料層の少なくとも一方
が外表面側になるようにして積層一体化すること
を特徴とする特許請求の範囲第1項又は第2項記
載の多層構造を有する繊維板の製造方法。 4 積層マツトの長繊維材料層が内面側になるよ
うにして積層一体化することを特徴とする特許請
求の範囲第1項又は第2項記載の多層構造を有す
る繊維板の製造方法。 5 全体の比重が0.4〜1.0になるまで加熱圧締す
ることを特徴とする特許請求の範囲第1項、第2
項、第3項又は第4項記載の多層構造を有する繊
維板の製造方法。
[Scope of Claims] 1. A fibrous slurry mainly consisting of a long fiber material consisting of kraft pulp, cotton fiber, synthetic fiber, glass wool alone or a mixture thereof, on at least one side of a wet mat made from thermomechanical pulp. A method for producing a fiberboard having a multilayer structure, which comprises: forming a laminated mat by combining the laminated mats, and then laminating a plurality of the laminated mats without drying and heat-pressing them to integrate them. 2. A method for manufacturing a fiberboard having a multilayer structure according to claim 1, characterized in that the laminated mats are laminated and integrated by applying an adhesive to their interfaces. 3. Production of a fiberboard having a multilayer structure according to claim 1 or 2, characterized in that the laminated mat is laminated and integrated so that at least one of the long fiber material layers is on the outer surface side. Method. 4. A method for producing a fiberboard having a multilayer structure according to claim 1 or 2, characterized in that the laminated mat is laminated and integrated so that the long fiber material layer faces the inner surface. 5 Claims 1 and 2, characterized in that the material is heated and pressed until the overall specific gravity becomes 0.4 to 1.0.
A method for manufacturing a fiberboard having a multilayer structure according to item 1, 3 or 4.
JP16542581A 1981-10-15 1981-10-15 Production of fiberboard having multilayer structure Granted JPS5870796A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP16542581A JPS5870796A (en) 1981-10-15 1981-10-15 Production of fiberboard having multilayer structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP16542581A JPS5870796A (en) 1981-10-15 1981-10-15 Production of fiberboard having multilayer structure

Publications (2)

Publication Number Publication Date
JPS5870796A JPS5870796A (en) 1983-04-27
JPH0135960B2 true JPH0135960B2 (en) 1989-07-27

Family

ID=15812173

Family Applications (1)

Application Number Title Priority Date Filing Date
JP16542581A Granted JPS5870796A (en) 1981-10-15 1981-10-15 Production of fiberboard having multilayer structure

Country Status (1)

Country Link
JP (1) JPS5870796A (en)

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2619645B2 (en) * 1987-08-12 1997-06-11 和穂 木川 Fiberboard making machine
JP2544234B2 (en) * 1990-06-06 1996-10-16 株式会社ノダ Composite plate and method for manufacturing the same
WO2001094700A1 (en) * 2000-06-09 2001-12-13 Ibiden Co., Ltd. Papermaking sludge processing method and processing device and hardened body

Also Published As

Publication number Publication date
JPS5870796A (en) 1983-04-27

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