JPH01311197A - Storage stable detergent having enhanced bleaching action - Google Patents
Storage stable detergent having enhanced bleaching actionInfo
- Publication number
- JPH01311197A JPH01311197A JP1091991A JP9199189A JPH01311197A JP H01311197 A JPH01311197 A JP H01311197A JP 1091991 A JP1091991 A JP 1091991A JP 9199189 A JP9199189 A JP 9199189A JP H01311197 A JPH01311197 A JP H01311197A
- Authority
- JP
- Japan
- Prior art keywords
- detergent
- storage
- layered silicate
- crystalline layered
- stabilized
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 39
- 238000004061 bleaching Methods 0.000 title claims description 6
- 238000003860 storage Methods 0.000 title abstract description 7
- 238000004140 cleaning Methods 0.000 claims abstract description 13
- 239000007844 bleaching agent Substances 0.000 claims abstract description 12
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229910052708 sodium Inorganic materials 0.000 claims abstract description 3
- 229910052615 phyllosilicate Inorganic materials 0.000 claims description 4
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 3
- 229910052760 oxygen Inorganic materials 0.000 claims description 3
- 239000001301 oxygen Substances 0.000 claims description 3
- 230000009466 transformation Effects 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 4
- 239000011734 sodium Substances 0.000 abstract description 4
- VTIIJXUACCWYHX-UHFFFAOYSA-L disodium;carboxylatooxy carbonate Chemical compound [Na+].[Na+].[O-]C(=O)OOC([O-])=O VTIIJXUACCWYHX-UHFFFAOYSA-L 0.000 abstract description 3
- 229940045872 sodium percarbonate Drugs 0.000 abstract description 3
- 102000004190 Enzymes Human genes 0.000 abstract 1
- 108090000790 Enzymes Proteins 0.000 abstract 1
- 229960001922 sodium perborate Drugs 0.000 abstract 1
- YKLJGMBLPUQQOI-UHFFFAOYSA-M sodium;oxidooxy(oxo)borane Chemical compound [Na+].[O-]OB=O YKLJGMBLPUQQOI-UHFFFAOYSA-M 0.000 abstract 1
- 238000005406 washing Methods 0.000 description 9
- 239000010457 zeolite Substances 0.000 description 7
- 229910021536 Zeolite Inorganic materials 0.000 description 5
- HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 5
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 description 3
- 238000000354 decomposition reaction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229910019142 PO4 Inorganic materials 0.000 description 2
- CPZRYQJPVUJHOS-UHFFFAOYSA-N [2-(2-phenylethyl)phenyl]methanol Chemical compound OCC1=CC=CC=C1CCC1=CC=CC=C1 CPZRYQJPVUJHOS-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 235000021317 phosphate Nutrition 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 235000019832 sodium triphosphate Nutrition 0.000 description 2
- 230000002087 whitening effect Effects 0.000 description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- OCUCCJIRFHNWBP-IYEMJOQQSA-L Copper gluconate Chemical class [Cu+2].OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O.OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C([O-])=O OCUCCJIRFHNWBP-IYEMJOQQSA-L 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229910021333 Na2Si Inorganic materials 0.000 description 1
- 201000002451 Overnutrition Diseases 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 125000000217 alkyl group Chemical group 0.000 description 1
- 229940045714 alkyl sulfonate alkylating agent Drugs 0.000 description 1
- 150000008052 alkyl sulfonates Chemical class 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 239000010840 domestic wastewater Substances 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000002191 fatty alcohols Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- NBZBKCUXIYYUSX-UHFFFAOYSA-N iminodiacetic acid Chemical compound OC(=O)CNCC(O)=O NBZBKCUXIYYUSX-UHFFFAOYSA-N 0.000 description 1
- 239000010954 inorganic particle Substances 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 239000004570 mortar (masonry) Substances 0.000 description 1
- 235000020823 overnutrition Nutrition 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- -1 perboric acid tetrahydrate Chemical class 0.000 description 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
- 239000010452 phosphate Substances 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 239000012418 sodium perborate tetrahydrate Substances 0.000 description 1
- IBDSNZLUHYKHQP-UHFFFAOYSA-N sodium;3-oxidodioxaborirane;tetrahydrate Chemical compound O.O.O.O.[Na+].[O-]B1OO1 IBDSNZLUHYKHQP-UHFFFAOYSA-N 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003871 sulfonates Chemical class 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/395—Bleaching agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3902—Organic or inorganic per-compounds combined with specific additives
- C11D3/3937—Stabilising agents
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/02—Inorganic compounds ; Elemental compounds
- C11D3/12—Water-insoluble compounds
- C11D3/124—Silicon containing, e.g. silica, silex, quartz or glass beads
- C11D3/1246—Silicates, e.g. diatomaceous earth
- C11D3/1253—Layer silicates, e.g. talcum, kaolin, clay, bentonite, smectite, montmorillonite, hectorite or attapulgite
- C11D3/1273—Crystalline layered silicates of type NaMeSixO2x+1YH2O
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、常用の洗剤および増量剤金倉め洗浄助剤を有
する、強化された漂白作用ｔＷする貯蔵安定化された洗
剤、殊に目の粗い洗・着物、白色洗省物および色物洗Ｉ
ｌｖ物用の家庭用洗剤に関する。DETAILED DESCRIPTION OF THE INVENTION [Industrial Field of Application] The present invention provides a storage-stabilized detergent with an enhanced bleaching action, especially for the eyes, having a conventional detergent and an extender Kanakurame cleaning aid. Coarse washing/Kimono, White washing and Color washing I
Related to household detergents for lvl items.
家庭用自動洗濯機の仔及増加によって、洗剤を変化した
洗浄条件に適合させねばならない。With the increase in the number of domestic automatic washing machines, detergents must be adapted to changed washing conditions.
従って、最近の洗剤は、洗浄活性物質、漂白剤および洗
浄力増強添加剤、一方で洗濯液の硬度を除去し、他方で
洗濯物に無機囁の沈着するのを阻止し、これによって洗
濯工程後の洗７擢物の°柔軟な感触”全配置するいわゆ
るビルダーの組合せからなる。Therefore, modern detergents contain cleaning active substances, bleaching agents and detergency-enhancing additives, which on the one hand remove the hardness of the washing liquor and on the other hand prevent the deposition of inorganic particles on the laundry and thereby 7. The soft feel of the washed product consists of a combination of so-called builders.
丁ぐれたビルダーとしては、ポリマーのｇａｒ＊塩、殊
にトリポリ燐酸ナトリウムがこれに該当する。家庭の排
水中の燐酸塩含分による河川および湖沼や海洋の高栄養
化の危険のため、ビルグーとしてゼオライトの使用が襦
案された。Suitable builders include gar* salts of polymers, especially sodium tripolyphosphate. The use of zeolite as a bilge was proposed due to the danger of overnutrition of rivers, lakes, and oceans due to the phosphate content in domestic wastewater.
ビルグーとしてのゼオライトの使用は、洗・誓物が数回
の洗浄工程を経過するうちに、好ましい１柔軟な感触″
ヲ失なうという欠点を有することが判明した。その上に
、洗剤の製造と消費との間の貯蔵時間の間に、洗剤が漂
白剤の分解によって部分的にその洗浄力を失なうことが
起きる。The use of zeolite as a building block gives a favorable 1 soft feel after the washing and oath passes through several washing processes.
It turned out that it has the disadvantage of losing its function. Moreover, during the storage time between the manufacture and consumption of the detergent, it happens that the detergent partially loses its cleaning power due to the decomposition of the bleaching agent.
従って、西ドイツ１１！特許出嘘公開第３４１６６６９
号においては、洗剤に付加的に結晶性の層状珪酸塩また
は珪酸アルカリを添加することが提案されている。これ
によって、洗濯物の柔軟な感触は、ビルダーとしてゼオ
ライトを使用する場合でも達成することができる；しか
し洗剤の貯峻安定性はこれによって影響されない。Therefore, West Germany 11! Patent lie publication No. 3416669
No. 2, it is proposed to additionally add crystalline phyllosilicates or alkali silicates to detergents. Thereby, a soft feel of the laundry can be achieved even when using zeolites as builders; however, the storage stability of the detergent is not affected by this.
本発明の課題は、改善された貯蔵安定性および強化され
た喋白作用を何し、ならびに洗濯嘗における°柔軟な感
触”を維持丁゛る洗剤を提供することである。It is an object of the present invention to provide detergents which exhibit improved storage stability and enhanced whitening action and maintain a "soft feel" on the wash coat.
〔課題を解決するための手段〕
１くべきことに、ビルダーとして結晶性の層状珪酸塩１
０〜ｓｏｘｗ％、殊に２０〜３５Ｍｔ幅および漂白剤を
含有し、その際漂白剤の量が、洗剤中に洗浄活性酸素（
ＡＶＯＸ ） Ｑ、５〜４重ｆ４、殊に１．０〜２．５
重ｔ％が存在するように定められている場合に１強化さ
れた漂白作用ｔＷする貯蔵安定化された洗剤が得られる
ことが判明した・
一般式：
％式％
〔式中ＭはＮａ ｌたはＨである〕で示される結晶性層
状珪酸塩がとくに有利であることが立証されている。[Means for solving the problem] 1. Preferably, crystalline layered silicate 1.
0 to 35 Mt width, in particular 20 to 35 Mt width and bleach, the amount of bleach being the amount of cleaning active oxygen (
AVOX) Q, 5-4 double f4, especially 1.0-2.5
It has been found that storage-stabilized detergents with an enhanced bleaching action tW are obtained when t% by weight is determined to be present. General formula: % formula % [where M is Na is H] has proven to be particularly advantageous.
結晶性の層状珪酸塩がＮａ２５ｉ、２０δのδ変態に一
致する場合、とくに良好な結果が得られる。Particularly good results are obtained when the crystalline layered silicate corresponds to the δ transformation of Na25i,20δ.
嘔らに、本発明による洗剤は優先的かつ選択的に次の特
徴を有することができる：
ａ）結晶性の層状珪酸塩が０．０１〜１０００μ馬、殊
に１〜２０μｍの粒子直径ｔｒｉすること；ｂ）結晶性
の層状珪酸塩が無水物質１００Ｉあたり４００〜１２０
０ミリモルＮａ＋のイオン交換容′Ｐｋを有すること；
Ｃ）漂白剤が過硼酸す） ＩＪウム四水和物、過硼酸ナ
トリウム−水和物および／ｌたは過爽酸ナトリウムであ
ること；
ｄ）付加的ビルダーとして無機および／または有機の燐
酸塩、硼酸塩、クエン酸塩、グルコン酸ｔｉ、ニド１７
０） ＋７酢酸（ＮＴＡ ）および／またはイミノジ酢
酸塩を２０重を鴫１での着で含有すること；
ｅ）０．２５〜２．５ｎの範囲内の粒度を有する凝集粒
子からなりかつｒ＃Ｌ１１混合法によって得られたもの
であること；
ｆ）洗剤としてアルキルペンゾールスルホネート、高級
アルキルスルホネートおよび／または高級脂肪アルコー
ルポリエトキシレートスルフェート、殊にアルキル基中
に平均１０〜１８のＣ原子を有するアルキル基を有する
もののアルカリ＠を含有すること；
ｇ）洗浄助剤としてカルボキシメチルセルロース、カル
ボキシメチル殿粉および／ｌたはメチルセルロースｔ＝
１０ｍ１４ｔでの量で含πすること。In addition, the detergent according to the invention may preferentially and selectively have the following characteristics: a) The crystalline phyllosilicate has a particle diameter of from 0.01 to 1000 μm, in particular from 1 to 20 μm. b) The crystalline layered silicate is 400 to 120 per 100 I of anhydrous material.
have an ion exchange capacity 'Pk of 0 mmol Na+; C) the bleaching agent is perboric acid tetrahydrate, sodium perborate-hydrate and/l or sodium persurate; d) ) as additional builders inorganic and/or organic phosphates, borates, citrates, ti gluconates, nido 17
0) containing 20 parts of +7 acetic acid (NTA) and/or iminodiacetate; e) consisting of agglomerated particles having a particle size within the range of 0.25 to 2.5n and r# be obtained by the L11 mixing method; f) alkylpenzole sulfonates, higher alkyl sulfonates and/or higher fatty alcohol polyethoxylate sulfates as detergents, in particular with an average of 10 to 18 C atoms in the alkyl group; g) carboxymethyl cellulose, carboxymethyl starch and /l or methyl cellulose as cleaning aids;
Include π in the amount of 10m14t.
さらに、洗剤５０重量ｔ４１で、殊に２〜２０重黄憾を
洗剤製品中へ混合下れば、有利な洗浄結果が達成される
ことが判明した。Furthermore, it has been found that advantageous cleaning results can be achieved if 50 weight t41 of the detergent is mixed in particular with 2 to 20 tungsten into the detergent product.
本発明による洗剤の製造の際に使用される結晶性の層状
Ｆ！酸塩は、西ドイツ国特許出願公開第３４１３５７１
号によって製造することができる。西ドイツ国特許出願
公開第３４１３５７１号に記載されている丁ぺての結晶
性の層状珪酸塩を本発明による洗剤に使用することがで
きるが、δ−Ｎａ２Ｓｉ□０．が、洗浄工程に際して旨
められたべ臼杵用を生じるので有利であることが判明し
た。The crystalline layered F! used in the production of the detergent according to the invention! The acid salt is disclosed in West German Patent Application No. 3413571
It can be manufactured by No. The crystalline phyllosilicates described in DE 34 13 571 can be used in the detergent according to the invention, but δ-Na2Si□0. However, this has been found to be advantageous as it results in a cleaner mortar during the cleaning process.
漂白剤ならびに洗剤の洗浄活性酸素（ＡＶＯＸ ）の測
定は、ヘイナー：ｘ、 （Ｄｒ、 Ｅ、 Ｈｅ１ｎｅｒ
ｔｈ ）（” ’ｒｅｎｓｔａｅ″、第２巻（１９６５
年）Ｍ２Ｂ５貞）の規定に従って実施した。調べた過硼
酸すトリウム四水和物（ＮａＢＯ３＠ ４ Ｈ２Ｏ）は
１０１ｉｔ４のＡＶＯＸ値金有し、過硼酸ナトリウム−
水和物（ＮａＢＯ３−Ｈ２Ｏ）は１５ｉ１１１Ｌ１７）
ＡＶＯＸ値’ｔ−Ｗし、過炭酸ナトリウム（２Ｎａ２Ｃ
Ｏ３・５ Ｈ２Ｏ２）は１３．５重量％のＡＶＯＸ値を
有していた。Determination of detergent active oxygen (AVOX) in bleach and detergents is carried out by Dr.
th) ("'renstae", Volume 2 (1965
It was carried out in accordance with the regulations of M2B5 Sada). The investigated sodium perborate tetrahydrate (NaBO3@4H2O) has an AVOX value of 101it4, and sodium perborate-
Hydrate (NaBO3-H2O) is 15i111L17)
AVOX value 't-W, sodium percarbonate (2Na2C
O3.5 H2O2) had an AVOX value of 13.5% by weight.
洗剤の洗浄力Ｃ’ｌＡ白作用）は、ＤＩＮ４４９８５に
よる試験布（タール汚れ全頁するＷＦＫポリエステル／
木綿、コード番号２０Ｇ）の白色度として確かめた。The cleaning power of the detergent (C'lA whitening effect) is determined by the test cloth according to DIN 44985 (WFK polyester with all tar stains).
It was confirmed as the whiteness of cotton (code number 20G).
洗濯液の洗浄力（漂白作用）は、方程式ｌ：憾Ｗしｍ４
ＷＧ、ｇ−係ｗｅｂ
からの差額法に従って算定した。式中、４ＷＫ −傷
洗浄力（漂白作用）
俤ＷＧｇ −鴫洗・僧した物の白色度
憾ｗｏｂ−爆未洗、屑物の白色度
貯、Ｒ試験は、次の強制試−条件に従って行なった：
耐候試験器中で、調べるべき洗剤を大気相対；握度７０
俤、ｍＫ５７℃で貯蔵した。この場合、洗剤はクラ引厚
紙に包装した。包装の水蒸気透過率は０．４９ ／ Ｆ
１１２・ｈであった。The detergency (bleaching effect) of the washing liquid is expressed by the equation l:
Calculated according to the difference method from the WG, G-section website. In the formula, 4WK - Scratch cleansing power (bleaching effect) 俤WGg - Whiteness of washed and cleaned items wob - Whiteness storage of unwashed and scraped items The R test was conducted in accordance with the following forced test conditions. In a weather tester, the detergent to be tested was exposed to the atmosphere;
The mK was stored at 57°C. In this case, the detergent was packaged in cardboard. The water vapor transmission rate of the packaging is 0.49/F
It was 112.h.
表１には、試験した洗剤製品が列挙されている。Table 1 lists the detergent products tested.
表２には、強制貯欲条件からの経過時間に依存する漂白
剤の分解値が１とめられている。付加的に、表２にはそ
れぞれゼオライトおよびトリポリ燐酸ナトリウムを主体
とする２つの市販洗剤を記載した。漂白剤、殊に過炭酸
ナトリウムの分解は、ゼオライトの存在では非常に大き
い。In Table 2, the decomposition value of the bleach is given as 1 depending on the elapsed time from the forced storage condition. Additionally, Table 2 lists two commercially available detergents based on zeolite and sodium tripolyphosphate, respectively. The decomposition of bleach, especially sodium percarbonate, is much greater in the presence of zeolites.
洗１結果：
ＤＩＮ ４４９８３によって洗剤製品２および４を試験
し、式■に従って計算した。洗剤２の洗浄力（ｆ！４白
作用）は３０．０４であり；本発明による洗剤４の洗浄
力ＣＩ！ｌ白作用）は３６．５４であった。Wash 1 results: Detergent products 2 and 4 were tested according to DIN 44983 and calculated according to the formula ■. The cleaning power (f!4 white action) of detergent 2 is 30.04; the cleaning power CI! of detergent 4 according to the invention! The white effect) was 36.54.
専門家姿員今による感触判断では、本発明による洗剤４
で洗潰した洗噸物は、ゼオライト倉荷洗剤２で洗γ肩し
た洗瀾物に比して明らかに１より柔軟な感触”を生じた
。According to the tactile judgment by experts, the detergent according to the present invention 4
The washed material washed with Zeolite Warehouse Detergent 2 clearly had a softer feel than the washed material washed with Zeolite Warehouse Detergent 2.
Claims (1)
強化された漂白作用を有する貯蔵安定化された洗剤にお
いて、ビルダーとして結晶性の層状珪酸塩１０〜５０重
量％および漂白剤を含有し、その際漂白剤の量は、洗剤
中に洗浄活性酸素０．５〜４重量％が存在するように定
められていることを特徴とする強化された漂白作用を有
する貯蔵安定化された洗剤 ２、結晶性の層状珪酸塩が一般式： ＮａＭＳｉ＿２Ｏ＿５ を有し、式中ＭはＮａまたはＨである、請求項１記載の
貯蔵安定化された洗剤 ３、結晶性の層状珪酸塩がＮａ＿２Ｓｉ＿２Ｏ＿５のδ
変態に一致する請求項１記載の貯蔵安定化された洗剤[Claims] 1. Contains cleaning aids including conventional detergents and fillers;
Storage-stabilized detergents with enhanced bleaching action contain 10 to 50% by weight of crystalline phyllosilicates as builders and bleaching agents, the amount of bleaching agent being such that the amount of cleaning active oxygen in the detergent is 0 to 50% by weight. 2, a crystalline layered silicate having the general formula: NaMSi_2O_5; Storage-stabilized detergent 3 according to claim 1, wherein M is Na or H, wherein the crystalline layered silicate is δ of Na_2Si_2O_5
Storage-stabilized detergent according to claim 1, which corresponds to a transformation.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3812555.2 | 1988-04-15 | ||
| DE3812555A DE3812555A1 (en) | 1988-04-15 | 1988-04-15 | STORAGE-STABILIZED DETERGENT WITH REINFORCED WHITENING EFFECT |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01311197A true JPH01311197A (en) | 1989-12-15 |
| JPH0633419B2 JPH0633419B2 (en) | 1994-05-02 |
Family
ID=6352058
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP1091991A Expired - Lifetime JPH0633419B2 (en) | 1988-04-15 | 1989-04-13 | Storage-stabilized detergent with enhanced bleaching action |
Country Status (10)
| Country | Link |
|---|---|
| EP (1) | EP0337219B1 (en) |
| JP (1) | JPH0633419B2 (en) |
| KR (1) | KR910006072B1 (en) |
| CA (1) | CA1324306C (en) |
| DE (2) | DE3812555A1 (en) |
| DK (1) | DK169725B1 (en) |
| ES (1) | ES2138953T3 (en) |
| FI (1) | FI92329C (en) |
| NO (1) | NO172750C (en) |
| SG (1) | SG40030A1 (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999003969A1 (en) * | 1997-07-18 | 1999-01-28 | Kao Corporation | Powdery detergent composition |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB9018157D0 (en) * | 1990-08-17 | 1990-10-03 | Procter & Gamble | Detergent compositions |
| GB9021761D0 (en) * | 1990-10-06 | 1990-11-21 | Procter & Gamble | Detergent compositions |
| DE4034131C2 (en) * | 1990-10-26 | 1999-08-26 | Henkel Kgaa | Builders for detergents |
| US5540855A (en) * | 1991-04-23 | 1996-07-30 | The Procter & Gamble Company | Particulate detergent compositions |
| GB9108639D0 (en) * | 1991-04-23 | 1991-06-12 | Procter & Gamble | Particulate detergent compositions |
| DE4134914A1 (en) * | 1991-10-23 | 1993-04-29 | Henkel Kgaa | DETERGENT AND CLEANING AGENT WITH SELECTED BUILDER SYSTEMS |
| DE4139826A1 (en) * | 1991-12-03 | 1993-06-09 | Basf Ag, 6700 Ludwigshafen, De | WASHING AND CLEANING AGENT |
| EP0550077A1 (en) * | 1992-01-03 | 1993-07-07 | The Procter & Gamble Company | Granular laundry bleaching composition |
| GB9209386D0 (en) * | 1992-04-30 | 1992-06-17 | Unilever Plc | Liquid cleaning products |
| GB9216409D0 (en) * | 1992-08-01 | 1992-09-16 | Procter & Gamble | Detergent compositions |
| EP0639639B2 (en) * | 1993-08-17 | 2010-07-28 | The Procter & Gamble Company | Detergent compositions comprising percarbonate bleaching agents |
| GB2294704A (en) * | 1994-11-05 | 1996-05-08 | Procter & Gamble | Bleaching composition |
| EP2123742A1 (en) † | 2008-05-14 | 2009-11-25 | The Procter and Gamble Company | A solid laundry detergent composition comprising light density silicate salt |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS614879A (en) * | 1984-06-15 | 1986-01-10 | Atsugi Motor Parts Co Ltd | Motor self-cooling type air pump |
| JPS62185799A (en) * | 1986-02-08 | 1987-08-14 | ヘンケル・コマンデイツトゲゼルシヤフト・アウフ・アクチエン | Detergent for fiber product |
| EP0263520A2 (en) * | 1986-10-08 | 1988-04-13 | Hoechst Aktiengesellschaft | Detergents containing softeners |
Family Cites Families (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1425177A (en) * | 1972-11-20 | 1976-02-18 | Procter & Gamble Ltd | Clay compositionp |
| FR2423536A1 (en) * | 1978-04-17 | 1979-11-16 | Interox | COMPOSITIONS AND METHOD FOR WASHING AND BLEACHING |
| EP0028432B1 (en) * | 1979-11-03 | 1984-01-18 | THE PROCTER & GAMBLE COMPANY | Granular laundry compositions |
| DE3742043A1 (en) * | 1987-12-11 | 1989-06-22 | Hoechst Ag | METHOD FOR PRODUCING CRYSTALLINE SODIUM LAYER SILICATES |
-
1988
- 1988-04-15 DE DE3812555A patent/DE3812555A1/en not_active Withdrawn
-
1989
- 1989-03-28 CA CA000594859A patent/CA1324306C/en not_active Expired - Fee Related
- 1989-04-01 ES ES89105745T patent/ES2138953T3/en not_active Expired - Lifetime
- 1989-04-01 SG SG1995001380A patent/SG40030A1/en unknown
- 1989-04-01 DE DE58909857T patent/DE58909857D1/en not_active Expired - Fee Related
- 1989-04-01 EP EP89105745A patent/EP0337219B1/en not_active Expired - Lifetime
- 1989-04-13 KR KR1019890004877A patent/KR910006072B1/en not_active IP Right Cessation
- 1989-04-13 FI FI891765A patent/FI92329C/en not_active IP Right Cessation
- 1989-04-13 JP JP1091991A patent/JPH0633419B2/en not_active Expired - Lifetime
- 1989-04-14 NO NO891545A patent/NO172750C/en unknown
- 1989-04-14 DK DK181789A patent/DK169725B1/en not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS614879A (en) * | 1984-06-15 | 1986-01-10 | Atsugi Motor Parts Co Ltd | Motor self-cooling type air pump |
| JPS62185799A (en) * | 1986-02-08 | 1987-08-14 | ヘンケル・コマンデイツトゲゼルシヤフト・アウフ・アクチエン | Detergent for fiber product |
| EP0263520A2 (en) * | 1986-10-08 | 1988-04-13 | Hoechst Aktiengesellschaft | Detergents containing softeners |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1999003969A1 (en) * | 1997-07-18 | 1999-01-28 | Kao Corporation | Powdery detergent composition |
| US6265371B1 (en) | 1997-07-18 | 2001-07-24 | Kao Corporation | Powdery detergent composition containing a partially neutralized chelant |
Also Published As
| Publication number | Publication date |
|---|---|
| DE3812555A1 (en) | 1989-10-26 |
| NO891545D0 (en) | 1989-04-14 |
| EP0337219B1 (en) | 1999-09-22 |
| DE58909857D1 (en) | 1999-10-28 |
| NO172750B (en) | 1993-05-24 |
| CA1324306C (en) | 1993-11-16 |
| FI92329B (en) | 1994-07-15 |
| EP0337219A2 (en) | 1989-10-18 |
| FI891765A0 (en) | 1989-04-13 |
| JPH0633419B2 (en) | 1994-05-02 |
| EP0337219A3 (en) | 1991-04-10 |
| ES2138953T3 (en) | 2000-02-01 |
| FI92329C (en) | 1994-10-25 |
| NO891545L (en) | 1989-10-16 |
| DK181789A (en) | 1989-10-16 |
| SG40030A1 (en) | 1997-06-14 |
| DK169725B1 (en) | 1995-01-23 |
| DK181789D0 (en) | 1989-04-14 |
| FI891765A (en) | 1989-10-16 |
| NO172750C (en) | 1993-09-01 |
| KR910006072B1 (en) | 1991-08-12 |
| KR900016446A (en) | 1990-11-13 |
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