JPH013095A - Ignition powder for toy fireworks - Google Patents
Ignition powder for toy fireworksInfo
- Publication number
- JPH013095A JPH013095A JP62-158301A JP15830187A JPH013095A JP H013095 A JPH013095 A JP H013095A JP 15830187 A JP15830187 A JP 15830187A JP H013095 A JPH013095 A JP H013095A
- Authority
- JP
- Japan
- Prior art keywords
- toy fireworks
- oxide
- lead
- weight
- ignition powder
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000000843 powder Substances 0.000 title claims description 24
- 239000011230 binding agent Substances 0.000 claims description 10
- YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 claims description 8
- 239000000203 mixture Substances 0.000 claims description 7
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 claims description 6
- YADSGOSSYOOKMP-UHFFFAOYSA-N dioxolead Chemical compound O=[Pb]=O YADSGOSSYOOKMP-UHFFFAOYSA-N 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 5
- 229910052782 aluminium Inorganic materials 0.000 claims description 5
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 5
- 229910044991 metal oxide Inorganic materials 0.000 claims description 5
- 150000004706 metal oxides Chemical class 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 4
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 claims description 4
- 239000003638 chemical reducing agent Substances 0.000 claims description 4
- XWHPIFXRKKHEKR-UHFFFAOYSA-N iron silicon Chemical compound [Si].[Fe] XWHPIFXRKKHEKR-UHFFFAOYSA-N 0.000 claims description 3
- 229910052751 metal Inorganic materials 0.000 claims description 3
- 239000002184 metal Substances 0.000 claims description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 claims description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 2
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 2
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 claims description 2
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 claims description 2
- 229910052796 boron Inorganic materials 0.000 claims description 2
- 239000003086 colorant Substances 0.000 claims description 2
- 229910052742 iron Inorganic materials 0.000 claims description 2
- 229910052749 magnesium Inorganic materials 0.000 claims description 2
- 239000011777 magnesium Substances 0.000 claims description 2
- 150000004972 metal peroxides Chemical class 0.000 claims description 2
- 239000000049 pigment Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims description 2
- 239000010703 silicon Substances 0.000 claims description 2
- 239000010936 titanium Substances 0.000 claims description 2
- 229910052719 titanium Inorganic materials 0.000 claims description 2
- 229910052726 zirconium Inorganic materials 0.000 claims description 2
- UHCGLDSRFKGERO-UHFFFAOYSA-N strontium peroxide Chemical compound [Sr+2].[O-][O-] UHCGLDSRFKGERO-UHFFFAOYSA-N 0.000 claims 1
- 239000002360 explosive Substances 0.000 description 14
- 238000002485 combustion reaction Methods 0.000 description 8
- 239000003721 gunpowder Substances 0.000 description 5
- 239000003973 paint Substances 0.000 description 4
- 239000011888 foil Substances 0.000 description 2
- 229910000464 lead oxide Inorganic materials 0.000 description 2
- 239000011593 sulfur Substances 0.000 description 2
- 229910052717 sulfur Inorganic materials 0.000 description 2
- 235000008708 Morus alba Nutrition 0.000 description 1
- 240000000249 Morus alba Species 0.000 description 1
- 229920001800 Shellac Polymers 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 229940007424 antimony trisulfide Drugs 0.000 description 1
- NVWBARWTDVQPJD-UHFFFAOYSA-N antimony(3+);trisulfide Chemical compound [S-2].[S-2].[S-2].[Sb+3].[Sb+3] NVWBARWTDVQPJD-UHFFFAOYSA-N 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- XMFOQHDPRMAJNU-UHFFFAOYSA-N lead(ii,iv) oxide Chemical compound O1[Pb]O[Pb]11O[Pb]O1 XMFOQHDPRMAJNU-UHFFFAOYSA-N 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 150000002823 nitrates Chemical class 0.000 description 1
- 239000007800 oxidant agent Substances 0.000 description 1
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical class OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 1
- 239000004208 shellac Substances 0.000 description 1
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 description 1
- 229940113147 shellac Drugs 0.000 description 1
- 235000013874 shellac Nutrition 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- -1 sulfur peroxide Chemical class 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
Abstract
(57)【要約】本公報は電子出願前の出願データであるた
め要約のデータは記録されません。(57) [Summary] This bulletin contains application data before electronic filing, so abstract data is not recorded.
Description
【発明の詳細な説明】 ＊産業上の利用分野 本発明は玩具花火用の点火薬に関するものである。[Detailed description of the invention] *Industrial application fields The present invention relates to igniters for toy fireworks.
＊従来の技術
玩具花火用の点火薬としては、過塩素酸塩類、硝酸塩類
等の酸化剤およびゴムランク、木炭わ）、セラック粉末
、天然樹脂粉、三硫化アンチモン、硫黄等の助燃剤に１
７１Ｉｌ利を混入してなる配合火薬が既に知られている
。* Conventional igniters for toy fireworks include oxidizing agents such as perchlorates and nitrates, and combustion improvers such as rubber rank, charcoal, shellac powder, natural resin powder, antimony trisulfide, and sulfur.
Combination gunpowder containing 71Il is already known.
本発明が解決しようとする問題点
上記の点火薬は燃焼時に充分な高熱を発しないため、こ
れを表面に塗料等の皮膜を有する火薬部の先端、直径が
極めて大きいか又は極めて小さい火薬部の先端、火薬を
詰め込んだアルミニウム箔、厚紙等の筒状体の先端、表
面積が広い被点火部、細長い被点火縁等に付着させたと
きには、点火環境により点火薬が燃焼してもアルミニウ
ム等の金属粉を含む火薬に着火しにくいという問題があ
った。この問題は、特に火薬部の表面に塗料皮膜を形成
したスパークラ−等の玩具花火の場合に顕著であった。Problems to be Solved by the Invention Since the above-mentioned ignition powder does not emit sufficiently high heat during combustion, it is used at the tip of the explosive part that has a coating of paint or the like on its surface, or at the tip of the explosive part with a very large or small diameter. When attached to the tip, aluminum foil filled with gunpowder, the end of a cylindrical body such as cardboard, a part with a large surface area to be ignited, a long and narrow rim to be ignited, etc., even if the igniter burns due to the ignition environment, metal such as aluminum There was a problem in that gunpowder containing powder was difficult to ignite. This problem was particularly noticeable in toy fireworks such as sparklers that had a paint film formed on the surface of the explosive part.
また、前記従来の点火薬は不完全燃焼のため燃焼時に多
量の発煙を生ずると共に燃焼か不安定で必るという問題
もあった。Further, the conventional ignition powder has the problem that it generates a large amount of smoke during combustion due to incomplete combustion, and the combustion is unstable.
本発明は上記の如き問題点を解決しようとしてなされた
ものである。The present invention has been made in an attempt to solve the above problems.
＊問題点を解決するための手段
上記問題点を解決するために、本発明は金属酸化物（金
属過酸化物を含む）と還元剤としての金属性粉末とを主
剤とし、これにバインダーとしてスターチ系の粘結剤を
混合せしめてなる玩具花火用の点火薬を提供するもので
ある。*Means for solving the problems In order to solve the above problems, the present invention uses metal oxides (including metal peroxides) and metal powder as a reducing agent as main ingredients, and starch as a binder. To provide an igniter for toy fireworks, which is made by mixing a type of binder.
前記金属酸化物としては、過酸化ス［〜ロンチウム、過
酸化バリウム、二酸化鉛（酸化鉛（ＪＶ））、酸化鉄（
Ｂｌａｃｋ 、 ｆｌｅｄ）、一酸化鉛（酸化鉛（］Ｉ
））、酸化銅（ＩＩ）、四三酸化鉛（鉛丹）等の安定し
た金属酸化物の中から選ばれた少なくとも１種を組成物
全体の５０〜９０重量％使用することが望ましい。The metal oxides include sulfur peroxide [~rontium, barium peroxide, lead dioxide (lead oxide (JV)), iron oxide (
Black, fled), lead monoxide (lead oxide (]I
It is desirable to use at least one kind selected from stable metal oxides such as copper (II) oxide, trilead tetroxide (redium), etc., in an amount of 50 to 90% by weight of the entire composition.
前記還元剤としては、ケイ素、ケイ素鉄、マグネシウム
、ホウ素、ジルコニウム、チタン、鉄、アルミニウム等
の粉末の中から選ばれた少なくとも１種を組成物全体の
５〜３０重倒％使用することが望ましい。As the reducing agent, at least one selected from powders of silicon, iron silicon, magnesium, boron, zirconium, titanium, iron, aluminum, etc. is preferably used in an amount of 5 to 30% by weight of the entire composition. .
前記バインダーとしては、スターチ系の粘結剤を組成物
全体の５〜３０ ｍ ’３％使用することが望ましい。As the binder, it is desirable to use a starch-based binder in an amount of 5 to 30 m'3% of the total composition.
また、必要に応じて染お１、顔料等の着色剤を組成物全
体の５〜１０重Ｑ％含ませることが望ましい。Further, it is desirable to include 5 to 10 weight Q% of the entire composition of coloring agents such as dyestuffs and pigments, if necessary.
ニド実施例
鉛丹（光明月）７小砒部とケイ素鉄３重量部とバインダ
ーとしてのスターチ系の粘結剤１重量部とを混合攪拌し
てペースト状の点火薬１を作った。Example 7 A paste-like igniter 1 was prepared by mixing and stirring 7 parts of red lead (Komeigetsu), 3 parts by weight of silicon iron, and 1 part by weight of a starch-based binder as a binder.
この点火薬１を、火薬部２の表面に塗料皮膜を形成した
スパークラ−３（第１図）における火薬部２の先端と、
別のスパークラ−３−（第２図、第３図）における火薬
部２−の先端と、噴き出し花火（第４図、第５図）にお
いてペースト状点火桑として導火線５．５の根元部とに
それぞれ塗着し乾燥させた。This ignition powder 1 is applied to the tip of the explosive part 2 in a sparkler 3 (FIG. 1) in which a paint film is formed on the surface of the explosive part 2,
The tip of the explosive part 2- in another sparkler 3- (Figs. 2 and 3) and the base of the fuse 5.5 as a paste ignition mulberry in the squirting fireworks (Figs. 4 and 5). Each was painted and dried.
上記各花火についてマツチ、ライター及び導火線の燃焼
用で点火試験を行なったところ、点火薬１は容易に着火
し、従来の点火薬よりも迅速に火薬部本体に着火させた
。また、この点火薬は完全には無ガスではないものの、
従来の点火薬と比較すると燃焼時にほとんどガスを発生
しなかった。When ignition tests were conducted on each of the above fireworks using a match, a lighter, and a fuse for combustion, Ignition Powder 1 ignited easily and ignited the main body of the explosive part more quickly than conventional ignition powder. Also, although this ignition powder is not completely gas-free,
Compared to conventional igniters, it produces almost no gas during combustion.
本発明の効果
本発明による点火薬は、直らに石火し高熱を発して燃焼
するため、玩具花火の火薬部にス・１づる石火能力が極
めて大きい。従って、この点火薬を表面に塗料皮膜を形
成した火薬部の先端に塗着した場合や噴き出し花火にｄ
３ける点火薬として用いた場合はもとより、この点火薬
を直径が極めて大きいか又は極めて小さい火薬部の先端
、火薬を詰め込んだアルミニウム箔、厚紙等の筒状体の
先端、表面積が広い被点火部、細長い被点火縁等に使用
した場合でも、火薬部は迅速かつ確実に着火する。Effects of the Present Invention The ignition powder according to the present invention burns immediately and generates high heat, so it has an extremely large ability to be used as a spark in the explosive portion of toy fireworks. Therefore, if this ignition powder is applied to the tip of an explosive part that has a paint film formed on its surface, or when a firework is ejected,
Not only can this igniter be used as an igniter, but it can also be used at the tip of an explosive part with an extremely large or small diameter, at the tip of a cylindrical body such as aluminum foil or cardboard filled with gunpowder, or at an ignited part with a large surface area. The explosive part ignites quickly and reliably even when used on elongated edges to be ignited.
また、本発明による、点火薬が燃焼時にガスをほとんど
発生しないことも前述の通りである。Further, as described above, the igniter according to the present invention generates almost no gas during combustion.
第１図は本発明による点火薬をスパークラ−にＪ３ける
火薬部の先端に塗るさせた状態を示す正面図、第２図は
同上点火薬を他のスパークラ−における火薬部の先端に
塗着させた状態を示す斜視図、第３図は第２図に示すス
パークラ−における火薬部と点火薬とを示す断面図、第
４図は同上点火薬を噴き出し花火にあける点火薬として
使用した状態を示す斜視図、第５図は第４図の噴き出し
花火の縦断面図である。
１：点火薬 ２．２−１２″ ：火薬部３．３′ニ
スパークラ−４：噴き出し花火５：導火線
出願人 井上玩具煙大株式会社Figure 1 is a front view showing the state in which the ignition powder according to the present invention is applied to the tip of the explosive part of a sparkler J3, and Figure 2 is a front view showing the state in which the same ignition powder is applied to the tip of the explosive part of another sparkler. FIG. 3 is a cross-sectional view showing the explosive part and ignition powder in the sparkler shown in FIG. 2, and FIG. 4 shows the same ignition powder used as the ignition powder to blow out fireworks. The perspective view, FIG. 5, is a vertical sectional view of the ejecting firework of FIG. 4. 1: Ignition powder 2.2-12'': Gunpowder part 3.3' Varnish sparkler - 4: Spouting fireworks 5: Fuse Applicant: Inoue Toy Endai Co., Ltd.
Claims (1)
の金属性粉末とを主剤とし、これにバインダーとしてス
ターチ系の粘結剤を混合せしめてなる玩具花火用の点火
薬。 ２、前記金属酸化物として、過酸化ストロンチウム、過
酸化バリウム、二酸化鉛（酸化鉛（IV））、酸化鉄（Ｂ
ｌａｃｋ、Ｒｅｄ）、一酸化鉛（酸化鉛（II））、酸化
銅（II）、三酸化鉛（鉛丹）等の安定した金属酸化物の
中から選ばれた少なくとも１種を組成物全体の５０〜９
０重量％使用したことを特徴とする特許請求の範囲第１
項記載の玩具花火用の点火薬。 ３、前記還元剤として、ケイ素、ケイ素鉄、マグネシウ
ム、ホウ素、ジルコニウム、チタン、鉄、アルミニウム
等の粉末の中から選ばれた少なくとも１種を組成物全体
の５〜３０重量％使用したことを特徴とする特許請求の
範囲第１項記載の玩具花火用の点火薬。 ４、前記バインダーとして、スターチ系の粘結剤を組成
物全体の５〜３０重量％使用したことを特徴とする特許
請求の範囲第１項記載の玩具花火用の点火薬。 ５、染料、顔料等の着色剤を組成物全体の５〜０重量含
ませたことを特徴とする特許請求の範囲第１項記載の玩
具花火用の点火薬。[Claims] 1. Toy fireworks made of a metal oxide (including metal peroxide) and a metal powder as a reducing agent, mixed with a starch-based binder as a binder. ignition powder. 2. As the metal oxide, strontium peroxide, barium peroxide, lead dioxide (lead (IV) oxide), iron oxide (B
Lack, Red), lead monoxide (lead (II) oxide), copper (II) oxide, lead trioxide (red), etc. 50-9
Claim 1 characterized in that 0% by weight is used.
Ignition powder for toy fireworks as described in Section 1. 3. As the reducing agent, at least one selected from powders of silicon, iron silicon, magnesium, boron, zirconium, titanium, iron, aluminum, etc. is used in an amount of 5 to 30% by weight of the entire composition. An igniter for toy fireworks according to claim 1. 4. The igniter for toy fireworks according to claim 1, wherein a starch-based binder is used as the binder in an amount of 5 to 30% by weight of the entire composition. 5. The igniter for toy fireworks according to claim 1, which contains a coloring agent such as a dye or a pigment in an amount of 5 to 0 by weight based on the total weight of the composition.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-158301A JPH013095A (en) | 1987-06-25 | Ignition powder for toy fireworks |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP62-158301A JPH013095A (en) | 1987-06-25 | Ignition powder for toy fireworks |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS643095A JPS643095A (en) | 1989-01-06 |
| JPH013095A true JPH013095A (en) | 1989-01-06 |
Family
ID=
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