JPH01306349A - High pressure spraying vehicle washing agent and method for washing vehicle - Google Patents

High pressure spraying vehicle washing agent and method for washing vehicle

Info

Publication number
JPH01306349A
JPH01306349A JP13656288A JP13656288A JPH01306349A JP H01306349 A JPH01306349 A JP H01306349A JP 13656288 A JP13656288 A JP 13656288A JP 13656288 A JP13656288 A JP 13656288A JP H01306349 A JPH01306349 A JP H01306349A
Authority
JP
Japan
Prior art keywords
vehicle
amorphous silica
washing
cleaning
pressure
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP13656288A
Other languages
Japanese (ja)
Inventor
Naoyuki Sakamoto
坂本 直行
Kazuo Iguchi
井口 和男
Masataka Obara
小原 正孝
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Kao Corp
Original Assignee
Kao Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kao Corp filed Critical Kao Corp
Priority to JP13656288A priority Critical patent/JPH01306349A/en
Publication of JPH01306349A publication Critical patent/JPH01306349A/en
Pending legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C11ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
    • C11DDETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
    • C11D3/00Other compounding ingredients of detergent compositions covered in group C11D1/00
    • C11D3/02Inorganic compounds ; Elemental compounds
    • C11D3/12Water-insoluble compounds
    • C11D3/124Silicon containing, e.g. silica, silex, quartz or glass beads

Abstract

PURPOSE:To wash a vehicle body effectively without damaging coated surfaces by applying the high pressure spray of soil suspension at the specified discharging pressure wherein said suspension is mixture of amorphous silica in a specified average grain diameter and water or interfacial active liquid solution. CONSTITUTION:Amorphous silica 5 to 150mum in average grain diameter is mixed with water or interfacial active liquid solution so that 0.2 to 5.0% of soil suspension by weight is formed. The soil suspension is applied to a vehicle body at the pressure of 30kg/cm<2> by means of high pressure spraying. By this constitution, stains on the vehicle body can effectively be washed and removed without damaging coated surfaces.

Description

【発明の詳細な説明】 〔産業上の利用分野〕 本発明は、高圧スプレー機を使用して車輌を洗浄するた
めの組成物に関するものであり、特に車輌の塗装面を傷
付けることなく汚れの除去に優れた効果を発揮する洗浄
剤に係わるものである。
DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to a composition for cleaning vehicles using a high-pressure spray machine, and in particular for removing dirt without damaging the painted surface of a vehicle. This relates to a cleaning agent that exhibits excellent cleaning effects.

〔従来の技術〕[Conventional technology]

ガソリンスタンドにおける有料洗車は門型洗車段が主流
であり、洗浄剤としては界面活性剤水溶液が使用されて
いるが、ブラシ洗いのため塗装面に傷が付き易いという
大きな欠点がある。
Gate-type car washes are the mainstream for paid car washes at gas stations, and a surfactant aqueous solution is used as the cleaning agent, but this has the major drawback of easily scratching painted surfaces due to brush washing.

また、車種により使用し難いとか、車輌の凹部やブラシ
が当たりにくい部位の汚れは除去し難いなどの問題があ
る。
In addition, there are other problems such as it being difficult to use depending on the type of vehicle, and it being difficult to remove dirt from the recesses of the vehicle and other areas that are difficult to reach with the brush.

一方、高圧スプレー機による洗車法は凹型洗車機の欠点
を補うものであるが、水の噴射圧及び界面活性剤の作用
のみでは汚れの除去は不十分である。このような現状か
らスプレ一方式によって汚れを除去できる洗浄剤の開発
が行われており、研磨剤を混入させた洗浄剤が検討され
ている。
On the other hand, a car wash method using a high-pressure spray machine compensates for the drawbacks of a concave car wash machine, but the water spray pressure and the action of a surfactant alone are insufficient to remove dirt. Under these circumstances, cleaning agents that can remove dirt by a single spray method are being developed, and cleaning agents mixed with abrasives are being considered.

例えば、特開昭61−190599号公報には、粒径が
0.1〜5μmの珪藻土、タルク、ゼオライト、炭酸カ
ルシウム、ベントナイト、カオリン、ドロマイトなどの
モース硬度が6以下の研磨剤を配合した高圧スプレー用
車輌洗浄剤が開示されている。
For example, JP-A-61-190599 discloses a high-pressure powder containing an abrasive with a Mohs hardness of 6 or less, such as diatomaceous earth with a particle size of 0.1 to 5 μm, talc, zeolite, calcium carbonate, bentonite, kaolin, and dolomite. A spray vehicle cleaning agent is disclosed.

〔発明が解決しようとする課題〕[Problem to be solved by the invention]

しかしながら、汚れの除去に有効な研磨剤を車体面に高
圧で繰り返しスプレーすると塗装面を傷付けるという問
題が発生する。塗装の種類としてはソリッド塗装とメタ
リック塗装があるがいずれも傷が付きやすく、特にメタ
リック塗装のクリア層が弱い。塗装面に傷が付(と光沢
がなくなり、つやぼけが起こり、更に傷口が拡がると錆
の発生に到り、美観のみならず車体面の寿命を低下させ
ることはいうまでもない。
However, if an abrasive agent that is effective in removing dirt is repeatedly sprayed onto a car body surface under high pressure, a problem arises in that it damages the painted surface. There are two types of paint: solid paint and metallic paint, but both are easily scratched, and the clear layer of metallic paint is especially weak. It goes without saying that if the painted surface is scratched, it will lose its luster and become dull, and if the scratches spread, it will lead to rust, which will not only reduce the aesthetics but also reduce the lifespan of the car body.

タルク、カオリンなどの柔らかい研磨剤を使用した時で
さえ塗装面をつやぼけさせるため実用化されるに到って
いない。
Even when a soft abrasive such as talc or kaolin is used, the painted surface becomes dull, so it has not been put into practical use.

本発明は塗装面を傷付けることなく汚れの除去に優れた
効果を発揮する洗浄剤の開発を目的とするものである。
The object of the present invention is to develop a cleaning agent that is highly effective in removing stains without damaging painted surfaces.

〔課題を解決するための手段〕[Means to solve the problem]

本発明者等は、水あるいは界面活性剤水溶液に固体粒子
を配合して汚れの除去効果と塗装面の傷付は性について
鋭意検討した。その結果、非晶質シリカを配合した洗浄
剤は汚れの除去効果に優れ、塗装面の傷付は性も問題な
く、高圧スプレー機片の洗浄剤として極めて有効である
ことを見出し、本発明を完成するに到った。
The present inventors have intensively studied the dirt removal effect and damage resistance of painted surfaces by adding solid particles to water or an aqueous surfactant solution. As a result, it was discovered that a cleaning agent containing amorphous silica has an excellent dirt removal effect, does not cause any damage to painted surfaces, and is extremely effective as a cleaning agent for high-pressure spray machine pieces. It has been completed.

即ち、本発明は、非晶質シリカを含有する高圧スプレー
用車輌洗浄剤及びそれを用いた車輌の洗浄方法を提供す
るものである。
That is, the present invention provides a high-pressure spray vehicle cleaning agent containing amorphous silica and a method of cleaning a vehicle using the same.

先ず、本発明の洗浄剤中の固体粒子である非晶質シリカ
について説明する。一般に、゛シリカ″と呼ばれ、化学
式5in2で表される物質には、大きく分けて2つの物
がある。1つは珪石のように一定の結晶構造を有し、天
然に存在する゛結晶性シリカ″であり、家庭用クレンザ
−の研磨基剤として使われている。
First, amorphous silica, which is a solid particle in the cleaning agent of the present invention, will be explained. In general, there are two main types of substances called "silica" and expressed by the chemical formula 5in2.One has a certain crystal structure like silica stone, and the other has a naturally occurring "crystalline structure". silica, which is used as a polishing base in household cleansers.

他の1つは含水珪素、湿式シリカ、合成珪酸などと呼ば
れ、5i−0の網目構造からなり、一定の結晶構造を持
たない゛非晶質″又は゛無定形”シリカである。
The other type is called hydrated silicon, wet silica, synthetic silicic acid, etc., and is ``amorphous'' or ``amorphous'' silica, which has a 5i-0 network structure and does not have a fixed crystal structure.

非晶質シリカは主に増粘剤、ホワイトカーボンとして使
われている。
Amorphous silica is mainly used as a thickener and white carbon.

高圧スプレー洗浄において結晶性シリカは塗装面を著し
く傷付ける。一方、非晶質シリカは塗装面を全く損傷す
ることなく、しかも汚れの除去に極めて有効であるとい
うことは驚くべきことである。
Crystalline silica seriously damages painted surfaces during high-pressure spray cleaning. On the other hand, it is surprising that amorphous silica does not damage painted surfaces at all and is extremely effective in removing stains.

非晶質シリカの製造法には乾式法、エアロゲル法、湿式
法等があるが本発明ではいずれの製法によるものでも使
用できる。非晶質シリカはトクシール(徳山曹達)、ア
エロジル(日本アエロジル社)などの商標名で市販され
ている。
Methods for producing amorphous silica include a dry method, an airgel method, a wet method, etc., and any method can be used in the present invention. Amorphous silica is commercially available under trade names such as Tokusil (Tokuyama Soda) and Aerosil (Nippon Aerosil Co.).

本発明に使用する非晶質シリカは平均粒径の比較的大き
なものがよく、5〜150μmの範囲のものが好適であ
る。この範囲外のものは汚れの除去効果が低下する。
The amorphous silica used in the present invention preferably has a relatively large average particle size, preferably in the range of 5 to 150 μm. If it is outside this range, the stain removal effect will be reduced.

本発明組成物は撹拌装置付きの洗浄剤容器内で混合され
、ポンプの吐出圧力でスプレーガンのノズル部から車輌
のボディー等にスプレーされるか又は粉体の自吸が可能
なスプレーガンを用い、非晶質シリカを粉体のまま吸入
してノズル部で水又は界面活性剤溶液と混合してスプレ
ーされる。
The composition of the present invention is mixed in a cleaning agent container equipped with a stirring device, and is sprayed onto the body of a vehicle from the nozzle of a spray gun using the discharge pressure of a pump, or by using a spray gun capable of self-priming powder. , amorphous silica is sucked in as a powder, mixed with water or a surfactant solution at a nozzle, and sprayed.

このように、本発明組成物は液体あるいは粉体の形態で
高圧スプレー機に供給される。スプレー液は水又は界面
活性剤水溶液及び非晶質シリカを含有する。
Thus, the composition of the invention is supplied to the high-pressure spray machine in liquid or powder form. The spray solution contains water or an aqueous surfactant solution and amorphous silica.

スプレー液中における非晶質シリカの含有量はO52〜
5重量%の範囲が好ましく、5重里%を越えても汚れの
除去効果は変わらず、0.2重量%未満では除去効果は
著しく低下する。
The content of amorphous silica in the spray liquid is O52 ~
A range of 5% by weight is preferable, and even if it exceeds 5% by weight, the dirt removal effect remains the same, while if it is less than 0.2% by weight, the removal effect is significantly reduced.

本発明は単に水に非晶質シリカを混合したスプレー液で
も十分な汚れ除去効果が得られるが、界面活性剤水溶液
とともに使用したほうが界面活性剤の洗浄効果により優
れた効果が得られる。
In the present invention, a sufficient stain removal effect can be obtained by simply using a spray solution prepared by mixing amorphous silica with water, but when used together with an aqueous surfactant solution, a superior cleaning effect of the surfactant can be obtained.

斯かる界面活性剤としては、通常の洗浄剤に使用される
陽イオン系、陰イオン系、非イオン系、両性イオンのい
ずれも使用できる。
As such a surfactant, any of cationic, anionic, nonionic, and amphoteric surfactants used in ordinary detergents can be used.

界面活性剤は特に限定されるものではないが、例えば、
アルキルベンゼンスルホン酸塩、高級アルコール硫酸エ
ステル塩、ポリオキンエチレンアルキル硫酸エステル塩
、オレフィンスルホン酸塩、アルキルスルホン酸塩、高
級脂肪酸塩などの陰イオン界面活性剤、ポリオキシエチ
レンアルキルエーテル、ポリオキンエチレンアルキルフ
ェニルエーテル、多価アルコール高級脂肪酸エステル又
はそのポリオキシエチレン付加物、高級脂肪酸アルカノ
ールアミド又はそのポリオキシエチレン付加物、アミン
オキサイドなどの非イオン界面活性剤、アルキル型第4
級アンモニウム塩などの陽イオン界面活性剤、アルキル
ベタイン型、アルキルイミダシリン型両性界面活性剤が
代表例として挙げられる。界面活性剤のスプレー液中に
おける濃度は0.01〜1.0%が適当である。
Surfactants are not particularly limited, but for example,
Anionic surfactants such as alkylbenzene sulfonates, higher alcohol sulfate ester salts, polyoxine ethylene alkyl sulfate ester salts, olefin sulfonates, alkyl sulfonates, higher fatty acid salts, polyoxyethylene alkyl ethers, polyoxine ethylene alkyl esters, etc. Nonionic surfactants such as phenyl ether, polyhydric alcohol higher fatty acid ester or its polyoxyethylene adduct, higher fatty acid alkanolamide or its polyoxyethylene adduct, amine oxide, alkyl type 4
Typical examples include cationic surfactants such as ammonium salts, alkyl betaine type and alkylimidacilline type amphoteric surfactants. The appropriate concentration of the surfactant in the spray liquid is 0.01 to 1.0%.

尚、本発明組成物中には溶剤、pH緩衝剤、防錆剤、分
散剤、香料、染料、ワックスなどを配合してもよい。
Incidentally, the composition of the present invention may contain a solvent, a pH buffer, a rust preventive, a dispersant, a fragrance, a dye, a wax, and the like.

又、スプレー液の吐出圧力は少なくとも30kg/cm
2以上、好ましくは30〜70kg/cm2であること
が必要であり、それ以下の吐出圧力では汚れの除去効果
は低下する。
In addition, the discharge pressure of the spray liquid is at least 30 kg/cm.
It is necessary that the discharge pressure is 2 or more, preferably 30 to 70 kg/cm2, and if the discharge pressure is lower than that, the dirt removal effect will be reduced.

〔実施例〕〔Example〕

以下に示す試験方法により、本発明による組成配合と比
較配合を評価した。
The composition formulation according to the present invention and the comparative formulation were evaluated by the test method shown below.

(1)洗浄効果の評価法 洗浄試験(I) アミノアルキッド樹脂塗装した試験パネルにモチ゛ル汚
れとしてエタノール中にカーボンブラックを5%を分散
した液を塗布し乾燥後、吐出圧20〜7Qkg/cm2
で洗浄液を10秒間スプレーし、水洗してから汚れの落
ち程度を下記の基準に従って目視判定した。
(1) Evaluation method of cleaning effect Cleaning test (I) A liquid containing 5% carbon black dispersed in ethanol was applied as a mole stain to a test panel coated with amino alkyd resin, and after drying, the discharge pressure was 20 to 7 Qkg/cm2.
A cleaning solution was sprayed for 10 seconds, and after washing with water, the degree of stain removal was visually judged according to the following criteria.

洗浄試験(II) 白色塗装面を有する乗用車を通常のワックスがけをして
1力月間走行させ、汚れが付着したボディに吐出圧20
〜70kg/cm”で洗浄液を1台当たり約3分間スプ
レーし、水洗してから汚れ落ち程度を次の基準に従い目
視判定した。
Cleaning test (II) A passenger car with a white painted surface was waxed normally and driven for one month, and a discharge pressure of 20% was applied to the dirty body.
A cleaning solution was sprayed at a pressure of ~70 kg/cm'' for about 3 minutes per unit, and after washing with water, the degree of stain removal was visually judged according to the following criteria.

評価基準:○ 汚れが落ちている。Evaluation criteria: ○ Dirt has been removed.

△ 汚れが少し目につく。△ A little dirt is visible.

X 汚れが目立つ。X Dirt is noticeable.

(2)塗装面の傷付き性の評価法 塗装傷付き性(I) アミノアルキッド樹脂塗装した試験パネルに各吐出圧で
洗浄液を30秒間スプレーし、水洗してから光沢度計に
よる光沢度を測定した。
(2) Evaluation method for scratch resistance of painted surfaces Paint scratch resistance (I) Spray cleaning liquid on test panels coated with amino alkyd resin for 30 seconds at each discharge pressure, rinse with water, and measure gloss using a gloss meter. did.

塗装傷付き性(II) 白色塗装及びメタリック塗装した乗用車のボディの1部
に各吐出圧で洗浄液を30秒間スプレーし、水洗してか
ら塗装面の傷付きを次の基準に従い目視判定した。
Paint Scratch Resistance (II) A part of the body of a passenger car painted with white paint or metallic paint was sprayed with cleaning liquid for 30 seconds at each discharge pressure, and after washing with water, scratches on the painted surface were visually judged according to the following criteria.

評価基準 ○;塗装面に傷なし。Evaluation criteria ○: No scratches on painted surface.

△:塗装面に少しつやぼけがある。△: The painted surface is slightly dull.

×:塗装面の光沢がなくなり、つやぼけがある。×: The painted surface loses its luster and is dull.

表1に評価結果を示す。Table 1 shows the evaluation results.

*1 固体粒子の種類 A−1非晶質シリカ、品名トクシールP (粒径5μm
、徳山曹達) A−2非晶質シリカ、品名トクシールGO(粒径10μ
m、徳山曹達) A−3非晶質シリカ、品名トクシールNR(粒径110
μm、徳山曹達) A−4非晶質シリカ、品名トクシールUR(粒径150
μm、徳山曹達) B タルク(粒径10μm、 モース硬度1)Cカオリ
ン(粒径3μm、 モース硬度2)D ゼオライト(粒
径5μm、モース硬度4)E 珪石 (粒径15μm、
 モース硬度7)本2 固体粒子の添加量 洗浄試験では0.5重量%、塗装傷付き性では1.0重
量% 本3 界面活性剤 ドデシルベンゼンスルホン酸ソータ0.2%表1かられ
かるように、本発明組成物であるA−1,八−2,A−
3,A−4の如く、非晶質シリカを使用し、吐出圧を3
0kg/cm2以上とすることにより汚れが完全に除去
され、しかも塗装面を傷付けない優れた高圧スプレー用
洗浄組成物が得られた。比較例として挙げたB、 C,
D及び巳は汚れの除去効果は十分であるが、塗装面を傷
付けg傾向が見られ、高圧でのスプレー洗車を繰り返す
ことにより塗装面の光沢度が低下し、つやぼけが発生す
る。
*1 Solid particle type A-1 amorphous silica, product name Tokusil P (particle size 5 μm
, Tokuyama Soda) A-2 amorphous silica, product name Tokusil GO (particle size 10μ
m, Tokuyama Soda) A-3 amorphous silica, product name Tokusil NR (particle size 110
μm, Tokuyama Soda) A-4 amorphous silica, product name Tokusil UR (particle size 150
μm, Tokuyama Soda) B Talc (particle size 10 μm, Mohs hardness 1) C Kaolin (particle size 3 μm, Mohs hardness 2) D Zeolite (particle size 5 μm, Mohs hardness 4) E Silica stone (particle size 15 μm, Mohs hardness 4)
Mohs hardness 7) Book 2 Amount of solid particles added 0.5% by weight for cleaning test, 1.0% by weight for paint scratch resistance Book 3 Surfactant Dodecylbenzenesulfonic acid sorter 0.2% As seen from Table 1 The composition of the present invention, A-1, 8-2, A-
3. As shown in A-4, use amorphous silica and set the discharge pressure to 3.
By adjusting the amount to 0 kg/cm2 or more, an excellent cleaning composition for high-pressure spraying that completely removed stains and did not damage painted surfaces was obtained. B, C, listed as comparative examples
D and Sn have a sufficient dirt removal effect, but tend to damage the painted surface, and repeating high-pressure spray car washes reduces the gloss of the painted surface and causes it to become dull.

〔発明の効果〕〔Effect of the invention〕

本発明組成物は高圧スプレー機を用い汚れの付着した車
体面に高圧スプレーすることにより、塗装面を傷付ける
ことなく汚れを除去することができるものである。
The composition of the present invention can be sprayed at high pressure onto a dirty car body surface using a high-pressure sprayer to remove dirt without damaging the painted surface.

スプレー洗車法は門型洗車機の問題点即ち車種により使
用し難いとかブラシの当たらない部位の汚れを除去でき
ないことなどを解決する方法であり、傷を付けずに汚れ
を除去できる本洗浄剤の発明によって優れた車輌洗浄剤
方法を提供できることとなった。
The spray car wash method is a method that solves the problems of gate-type car washes, such as the difficulty of using them depending on the car model and the inability to remove dirt from areas that cannot be touched by the brush. The invention has made it possible to provide an excellent vehicle cleaning agent method.

Claims (1)

【特許請求の範囲】 1 非晶質シリカを含有することを特徴とする高圧スプ
レー用車輌洗浄剤。 2 非晶質シリカの平均粒径が5〜150μmである請
求項1記載の高圧スプレー用車輌洗浄剤。 3 吐出圧が30kg/cm^2以上の高圧スプレー機
を使用して固体粒子を懸濁させた洗浄液をスプレーして
車輌を洗浄する方法において、固体粒子として非晶質シ
リカを用いたことを特徴とする車輌の洗浄方法。
[Scope of Claims] 1. A high-pressure spray vehicle cleaning agent characterized by containing amorphous silica. 2. The high-pressure spray vehicle cleaning agent according to claim 1, wherein the amorphous silica has an average particle size of 5 to 150 μm. 3. A method of cleaning a vehicle by spraying a cleaning liquid in which solid particles are suspended using a high-pressure spray machine with a discharge pressure of 30 kg/cm^2 or more, characterized in that amorphous silica is used as the solid particles. How to wash a vehicle.
JP13656288A 1988-06-02 1988-06-02 High pressure spraying vehicle washing agent and method for washing vehicle Pending JPH01306349A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP13656288A JPH01306349A (en) 1988-06-02 1988-06-02 High pressure spraying vehicle washing agent and method for washing vehicle

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP13656288A JPH01306349A (en) 1988-06-02 1988-06-02 High pressure spraying vehicle washing agent and method for washing vehicle

Publications (1)

Publication Number Publication Date
JPH01306349A true JPH01306349A (en) 1989-12-11

Family

ID=15178144

Family Applications (1)

Application Number Title Priority Date Filing Date
JP13656288A Pending JPH01306349A (en) 1988-06-02 1988-06-02 High pressure spraying vehicle washing agent and method for washing vehicle

Country Status (1)

Country Link
JP (1) JPH01306349A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11302696A (en) * 1998-04-24 1999-11-02 Yokohama Yushi Kogyo Kk Aqueous detergent composition for pressure spraying and cleaning method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH11302696A (en) * 1998-04-24 1999-11-02 Yokohama Yushi Kogyo Kk Aqueous detergent composition for pressure spraying and cleaning method

Similar Documents

Publication Publication Date Title
US7658805B2 (en) Concrete cleaning and preparation composition
WO2007070715A9 (en) Cleaning and polishing composition for metallic surfaces
US3879216A (en) Method and composition for cleaning surfaces
US5690539A (en) Method of abarding using surface abrasion compositions
JP3046918B2 (en) How to clean painted surfaces
CA1324063C (en) Metal cleaning process
US6562114B1 (en) Wax and method of wax application
JPH06506496A (en) Low-volatile organic compound cleaning compositions and methods
JP4944342B2 (en) Cleaning composition for oily soil removal
US20080026150A1 (en) Silica-Free Surface Abrasion Compositions and Their Uses
JPH01306349A (en) High pressure spraying vehicle washing agent and method for washing vehicle
JPWO2003016452A1 (en) Vehicle cleaning agent, vehicle cleaning method and vehicle cleaning device
JPH07119440B2 (en) Automotive cleaning composition
US5073407A (en) Method of treating a surface
JPS61190599A (en) Car washing composition for high pressure spraying
US6383557B1 (en) Plumbing fixture surface restoration process
US7282100B1 (en) Method of cleaning automobile painted surfaces and automobile glass surfaces
JPS61113698A (en) Water fur washing composition for gate shaped car washing machine
US7135446B1 (en) System for cleaning and protecting windshields
JPH05230499A (en) Fur detergent for the coated surface of vehicle
JP4077734B2 (en) Vehicle cleaning composition and vehicle cleaning method using the cleaning composition
TW201629157A (en) Spraying compound for surface repairing and manufacturing method thereof
JPS61178253A (en) Method of removing water scale from vehicle
JPH10152694A (en) Detergent for contaminated surface ascribed to vehicle
JPS61192799A (en) Water fur detergent composition for gate type car washer