JPH01299889A - Modifier of clay for digging - Google Patents
Modifier of clay for diggingInfo
- Publication number
- JPH01299889A JPH01299889A JP13118888A JP13118888A JPH01299889A JP H01299889 A JPH01299889 A JP H01299889A JP 13118888 A JP13118888 A JP 13118888A JP 13118888 A JP13118888 A JP 13118888A JP H01299889 A JPH01299889 A JP H01299889A
- Authority
- JP
- Japan
- Prior art keywords
- water
- clay
- modifier
- acrylamide
- copolymer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000004927 clay Substances 0.000 title claims abstract description 9
- 239000003607 modifier Substances 0.000 title claims description 7
- 229920003169 water-soluble polymer Polymers 0.000 claims abstract description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 claims abstract description 6
- 229920001577 copolymer Polymers 0.000 claims abstract description 6
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims abstract description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims abstract description 3
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims abstract description 3
- 229920002554 vinyl polymer Polymers 0.000 claims abstract description 3
- 239000000178 monomer Substances 0.000 claims abstract 2
- 238000009412 basement excavation Methods 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 5
- 238000005553 drilling Methods 0.000 claims description 3
- 150000003839 salts Chemical class 0.000 abstract description 8
- 229910052791 calcium Inorganic materials 0.000 abstract description 2
- 239000000203 mixture Substances 0.000 abstract description 2
- 229910052708 sodium Inorganic materials 0.000 abstract description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 14
- 235000002639 sodium chloride Nutrition 0.000 description 8
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 6
- 239000000440 bentonite Substances 0.000 description 6
- 229910000278 bentonite Inorganic materials 0.000 description 6
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 description 6
- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 6
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 6
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 4
- 229920002401 polyacrylamide Polymers 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 239000013505 freshwater Substances 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 2
- 239000003814 drug Substances 0.000 description 2
- 229940079593 drug Drugs 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000006266 etherification reaction Methods 0.000 description 2
- 150000004676 glycans Chemical class 0.000 description 2
- 230000007062 hydrolysis Effects 0.000 description 2
- 238000006460 hydrolysis reaction Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- -1 poly(vinyl acetate-maleic anhydride) Polymers 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 229920001282 polysaccharide Polymers 0.000 description 2
- 239000005017 polysaccharide Substances 0.000 description 2
- 239000011734 sodium Substances 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 1
- 229920002125 Sokalan® Polymers 0.000 description 1
- 239000008186 active pharmaceutical agent Substances 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000008103 glucose Substances 0.000 description 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- XJRBAMWJDBPFIM-UHFFFAOYSA-N methyl vinyl ether Chemical compound COC=C XJRBAMWJDBPFIM-UHFFFAOYSA-N 0.000 description 1
- 244000005700 microbiome Species 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920001206 natural gum Polymers 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 239000004584 polyacrylic acid Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 229920001059 synthetic polymer Polymers 0.000 description 1
Landscapes
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明は１石油ボニリング用泥水に使用する粘土類（ベ
ントナイト等）を改質する方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a method for modifying clays (bentonite, etc.) used in mud for petroleum bonilling.
（従来の技術） 従来のベントナイト改質剤としては１例えば。(Conventional technology) For example, 1 is a conventional bentonite modifier.
特公昭５７−２９５０４等に記載されているように、ポ
リアクリル酸、ポリ（ビニルアセテート−マレイン酸無
水物）、ポリ（エチレン−マレイン酸無水物）、ポリ（
ビニルメチルエーテル−マレインａ無水物）等のカルボ
ン酸含［１２０〜１００モ号％の合成ポリマーが使用さ
れる。As described in Japanese Patent Publication No. 57-29504, etc., polyacrylic acid, poly(vinyl acetate-maleic anhydride), poly(ethylene-maleic anhydride), poly(
Synthetic polymers containing carboxylic acid (120 to 100 mole %) such as vinyl methyl ether (maleic anhydride) are used.
しかしながら、このような従来の力をボン酸含有ポリマ
ーにあっては、カルボン酸が改質の根拠となっていたた
め、上記薬剤で改質された掘削用粘土類は耐塩性が不良
であった。However, in the case of conventional polymers containing carbonic acid, carboxylic acid was the basis for modification, and therefore, excavation clays modified with the above-mentioned chemicals had poor salt resistance.
特に石−油ポーリング掘削においては、使用される水が
必ずしも純水てなく、又、岩塩層を掘削する時にはＮａ
Ｃｊ！たけでなく、Ｃａ ｌ ’ 、 Ｍ ｇ ＊ ＊
等の２価塩も多量に混入し、泥水を汚染する。Particularly in oil-oil poling drilling, the water used is not necessarily pure water, and when drilling into rock salt layers, Na
Cj! Not only that, but also Cal', Mg * *
A large amount of divalent salts such as salts are mixed in and contaminate the muddy water.
掘削用粘土類を調整するに当っては、各種要求に対応す
ることが必要、となり、清水ばかりでなく、塩水に対し
ても有効であることがより望ましい。When preparing clay for excavation, it is necessary to meet various requirements, and it is more desirable that it be effective not only for fresh water but also for salt water.
従来のカルボン酸含有ポリマーでは上記問題に対しては
無効であり、清水使用の場合においてのみ有効であると
いう問題点があった。Conventional carboxylic acid-containing polymers are ineffective against the above problems and are only effective when using fresh water.
（発明が解決しようとする課題）
以上の現状に鑑み１本発明が解決しようとする課題は、
ｔａ削用粘土類を調整するに当って、清水ばかりでなく
塩水に対しても有効である掘削粘土類の改質剤を提供す
ることである。(Problems to be solved by the invention) In view of the above-mentioned current situation, one problem to be solved by the present invention is:
To provide a modifier for excavating clay that is effective not only for fresh water but also for salt water in preparing clay for excavating.
（課題を解決するための手段）
この発明は、このような従来の問題点に着目してなされ
たものである。すなわち、ラムザンガム単独、又は、ラ
ムザンガムと他の水溶性ポリマーを用いて掘削用に使用
する粘土類を改質する方法を見い出した。(Means for Solving the Problems) The present invention has been made by focusing on such conventional problems. That is, we have discovered a method of modifying clays used for excavation using Ramsan gum alone or Ramsan gum and other water-soluble polymers.
掘削用に使用する粘土類に対し。For clays used for excavation.
■ラムザンガム０．０１〜１重量％
又は
■ラムザンガム０．０１〜１重量％及び■他の水溶性ポ
リマー０．０１〜１重量％を併用する。(2) 0.01-1% by weight of Ramsan gum or (2) 0.01-1% by weight of Ramsan gum and (2) 0.01-1% by weight of other water-soluble polymers.
本発明に使用するラムザンガムは醗酵多糖類であり、微
生物Ａｌｃａｌｉｇｅｎｅｓ ｓｐｅ −ｃｉｅｓ、
ＡＴＣＣ３１９６１（Ａｍｅｒｉｃ−ａｎ Ｔｙｐｅ
Ｃｕ１ｔｕｒｅ Ｃｏ１１ｅ−ｃｔｉｏｎに登録
されたＮｏ、）がグルコースを醗酵させてその菌体外に
蓄積した多糖類を、精製し粉末にした天然ガム質である
。その化学構造は、２個のグルコースより構成されてい
る。Ramzan gum used in the present invention is a fermented polysaccharide, and is produced by microorganisms Alcaligenes spe-cies,
ATCC31961 (American-an Type
It is a natural gum substance made by fermenting glucose and accumulating the polysaccharide outside the bacterial cells, which is purified and powdered. Its chemical structure is composed of two glucose units.
（Ｍ◆はナトリウム、カルシウム。(M◆ is sodium and calcium.
ラムザンガムに併用できる他の水溶性ポリマートしては
、
ａ、ＣＭＣ（カルボキシメチルセルロース）。Other water-soluble polymers that can be used in combination with Ramsan gum include: a. CMC (carboxymethyl cellulose).
ｂ、アクリルアミドとアクリル酸との共重合ポリマー
Ｃ，アクリルアミドと共重合可能なその他のビニル七ツ
マ−との共重合体
等が掲げられる。b, a copolymer C of acrylamide and acrylic acid, a copolymer C of acrylamide and other vinyl heptamers which can be copolymerized, and the like.
ラムザンガムは単独でも充分効果を有するが。Ramsan gum alone is effective enough.
他の水溶性ポリマーを併用しても良い。Other water-soluble polymers may be used in combination.
本発明改質剤は通常の方法で粘土と共に配合し、泥水を
調整すればよい。The modifier of the present invention may be mixed with clay in a conventional manner to prepare muddy water.
（作用）
本方法は塩水系システムにおいても増粘し、従来のカル
ボン酸含有薬剤では達成できないＦＬ値を小さくするこ
とができ１品質の劣るベントナイトに少量添加すること
により、泥水調整時のマッド特性値を改良できる。(Effect) This method increases the viscosity even in saltwater systems, and can reduce the FL value that cannot be achieved with conventional carboxylic acid-containing chemicals. 1. By adding a small amount to inferior quality bentonite, mud properties when adjusting muddy water. Values can be improved.
（実施例）
次に実施例を挙げて本発明を説明するが、本発明はこれ
ら実施例に限定されるものではない、実施例中の％は重
量基準で表わす。(Examples) Next, the present invention will be explained with reference to Examples, but the present invention is not limited to these Examples. The percentages in the Examples are expressed on a weight basis.
実施例１
ベントナイト八に薬剤０．２％量を均−混合後、４％Ｎ
ａＣＪｌ水に調整後のベン上ナイト４％量を懸濁して泥
水を調整した。Example 1 After uniformly mixing 0.2% of the drug with bentonite, 4% N
Mud water was prepared by suspending 4% of the adjusted bennite in aCJl water.
（以下余白）
ＰＡＭ：ポリアクリルアミドの２５％加水分解率１分子
量１０００万
ＣＭＣ： １％粘度３０００ＣＰ、エーテル化度０．８
５のカルボキシメチルセルロー
スＨａ
本ＡＶ、ＦＬ：ＡＰＩの方法による。ＡＶは見かけ粘度
（ＣＰ）、ＦＬは濾水
量（ｍｌ）。(Left below) PAM: 25% hydrolysis rate of polyacrylamide 1 molecular weight 10 million CMC: 1% viscosity 3000CP, degree of etherification 0.8
Carboxymethylcellulose Ha of No. 5 According to the method of this AV, FL: API. AV is apparent viscosity (CP), and FL is free water volume (ml).
発明例の１．２．３は比較例に比して得られた泥水のＡ
Ｖ値、及びＦＬ値が良好である。1.2.3 of the invention example is A of the muddy water obtained compared to the comparative example.
Good V value and FL value.
実施例２
ベントナイトＢに薬剤０．１％量を均一に混合後、本ベ
ントナイト４％量を〔３０％ＮａＣｊＬ＋１％ＣａＣＪ
Ｌ２＋ｔ％ＭｇＣＪＬ２）を組成とする塩水に対して懸
濁させて泥水を調整した。Example 2 After uniformly mixing 0.1% of the drug into bentonite B, 4% of this bentonite was added to [30% NaCjL + 1% CaCJ
Mud water was prepared by suspending it in salt water having a composition of L2+t%MgCJL2).
（以下余白）
ＰＡＭ：ポリアクリルアミドの２５％加水分解率、分子
量１０００万
ＣＭＣ：１％粘度３０００ＣＰ、エーテル化度０．８５
のカルボキシメチルセルロー
スＮａ
本ＡＶ、ＦＬは実施例１と同じ。(Left below) PAM: 25% hydrolysis rate of polyacrylamide, molecular weight 10 million CMC: 1% viscosity 3000CP, degree of etherification 0.85
Carboxymethylcellulose Na This AV and FL are the same as in Example 1.
発明例の１．２．３は比較例に比して得られた泥水のＡ
Ｖ値、及びＦＬ値が良好である。1.2.3 of the invention example is A of the muddy water obtained compared to the comparative example.
Good V value and FL value.
、（発明の効果）
以上説明した通り、本発明により掘削用粘土類の耐塩性
が向上し、掘削用粘土類を利用する各種産業に貢献し得
る。(Effects of the Invention) As explained above, the present invention improves the salt resistance of excavating clays and can contribute to various industries that utilize excavating clays.
特許出願人 第一工業製薬株式会社Patent applicant Daiichi Kogyo Seiyaku Co., Ltd.
Claims (1)
ポリマーを必須成分とする掘削用泥水に使用する粘土類
の改質剤。 ２、ラムザンガムを掘削用粘土に対し、０．０１〜１重
量％量使用することを特徴とする掘削用粘土の改質法。 ３、請求項１における他の水溶性ポリマーがａ、ＣＭＣ
、 ｂ、アクリルアミドとアクリル酸との共重合体、又は、 ｃ、アクリルアミドと共重合可能なその他のビニルモノ
マーとの共重合体である請求項 １の改質剤。[Claims] 1. A clay modifier for use in drilling mud containing Ramsan gum alone or Ramsan gum and other water-soluble polymers as essential components. 2. A method for modifying excavation clay, characterized in that Ramsan gum is used in an amount of 0.01 to 1% by weight based on the excavation clay. 3. The other water-soluble polymer in claim 1 is a, CMC
The modifier according to claim 1, which is: (b) a copolymer of acrylamide and acrylic acid; or (c) a copolymer of acrylamide and another vinyl monomer copolymerizable with the modifier.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13118888A JPH064846B2 (en) | 1988-05-27 | 1988-05-27 | Drilling clay modifier |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP13118888A JPH064846B2 (en) | 1988-05-27 | 1988-05-27 | Drilling clay modifier |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01299889A true JPH01299889A (en) | 1989-12-04 |
| JPH064846B2 JPH064846B2 (en) | 1994-01-19 |
Family
ID=15052075
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP13118888A Expired - Lifetime JPH064846B2 (en) | 1988-05-27 | 1988-05-27 | Drilling clay modifier |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH064846B2 (en) |
-
1988
- 1988-05-27 JP JP13118888A patent/JPH064846B2/en not_active Expired - Lifetime
Also Published As
| Publication number | Publication date |
|---|---|
| JPH064846B2 (en) | 1994-01-19 |
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