JPH0128771B2 - - Google Patents

Info

Publication number

JPH0128771B2

JPH0128771B2 JP56087150A JP8715081A JPH0128771B2 JP H0128771 B2 JPH0128771 B2 JP H0128771B2 JP 56087150 A JP56087150 A JP 56087150A JP 8715081 A JP8715081 A JP 8715081A JP H0128771 B2 JPH0128771 B2 JP H0128771B2

Authority

JP

Japan

Prior art keywords

flame retardant

bromine

resin composition

containing flame

phosphate

Prior art date

1981-06-05

Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)

Expired

Links

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• 239000003063 flame retardant Substances 0.000 claims description 64
• RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 53
• WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 claims description 28
• GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 claims description 28
• 229910052794 bromium Inorganic materials 0.000 claims description 28
• 239000011342 resin composition Substances 0.000 claims description 20
• 239000000463 material Substances 0.000 claims description 19
• OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 17
• 229910052698 phosphorus Inorganic materials 0.000 claims description 17
• 239000011574 phosphorus Substances 0.000 claims description 17
• 239000000654 additive Substances 0.000 claims description 16
• 230000000996 additive effect Effects 0.000 claims description 15
• 238000000034 method Methods 0.000 claims description 10
• 229920005989 resin Polymers 0.000 claims description 10
• 239000011347 resin Substances 0.000 claims description 10
• 238000004519 manufacturing process Methods 0.000 claims description 9
• LIAWCKFOFPPVGF-UHFFFAOYSA-N 2-ethyladamantane Chemical compound C1C(C2)CC3CC1C(CC)C2C3 LIAWCKFOFPPVGF-UHFFFAOYSA-N 0.000 claims description 6
• BUPRYTFTHBNSBD-UHFFFAOYSA-N (2,3,4-tribromophenyl) prop-2-enoate Chemical compound BrC1=CC=C(OC(=O)C=C)C(Br)=C1Br BUPRYTFTHBNSBD-UHFFFAOYSA-N 0.000 claims description 5
• 229920006337 unsaturated polyester resin Polymers 0.000 claims description 5
• XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 claims description 4
• 150000001875 compounds Chemical class 0.000 claims description 3
• CYLVUSZHVURAOY-UHFFFAOYSA-N 2,2-dibromoethenylbenzene Chemical compound BrC(Br)=CC1=CC=CC=C1 CYLVUSZHVURAOY-UHFFFAOYSA-N 0.000 claims description 2
• YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 claims description 2
• YMOONIIMQBGTDU-VOTSOKGWSA-N [(e)-2-bromoethenyl]benzene Chemical compound Br\C=C\C1=CC=CC=C1 YMOONIIMQBGTDU-VOTSOKGWSA-N 0.000 claims description 2
• -1 tribromo phenol allyl ester Chemical class 0.000 claims description 2
• STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 2
• DQWPFSLDHJDLRL-UHFFFAOYSA-N triethyl phosphate Chemical compound CCOP(=O)(OCC)OCC DQWPFSLDHJDLRL-UHFFFAOYSA-N 0.000 claims description 2
• XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 claims description 2
• HQUQLFOMPYWACS-UHFFFAOYSA-N tris(2-chloroethyl) phosphate Chemical compound ClCCOP(=O)(OCCCl)OCCCl HQUQLFOMPYWACS-UHFFFAOYSA-N 0.000 claims description 2
• 229910019142 PO4 Inorganic materials 0.000 claims 1
• 239000007983 Tris buffer Substances 0.000 claims 1
• NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
• 239000010452 phosphate Substances 0.000 claims 1
• 230000000052 comparative effect Effects 0.000 description 4
• 230000000694 effects Effects 0.000 description 3
• 239000000123 paper Substances 0.000 description 3
• ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
• 230000002411 adverse Effects 0.000 description 2
• ADCOVFLJGNWWNZ-UHFFFAOYSA-N antimony trioxide Chemical compound O=[Sb]O[Sb]=O ADCOVFLJGNWWNZ-UHFFFAOYSA-N 0.000 description 2
• 229910052801 chlorine Inorganic materials 0.000 description 2
• 239000000460 chlorine Substances 0.000 description 2
• USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 description 2
• 229910052736 halogen Inorganic materials 0.000 description 2
• 150000002367 halogens Chemical class 0.000 description 2
• 238000010030 laminating Methods 0.000 description 2
• 239000002184 metal Substances 0.000 description 2
• 230000002195 synergetic effect Effects 0.000 description 2
• 239000004641 Diallyl-phthalate Substances 0.000 description 1
• PQYJRMFWJJONBO-UHFFFAOYSA-N Tris(2,3-dibromopropyl) phosphate Chemical compound BrCC(Br)COP(=O)(OCC(Br)CBr)OCC(Br)CBr PQYJRMFWJJONBO-UHFFFAOYSA-N 0.000 description 1
• QUDWYFHPNIMBFC-UHFFFAOYSA-N bis(prop-2-enyl) benzene-1,2-dicarboxylate Chemical compound C=CCOC(=O)C1=CC=CC=C1C(=O)OCC=C QUDWYFHPNIMBFC-UHFFFAOYSA-N 0.000 description 1
• 238000007796 conventional method Methods 0.000 description 1
• 239000003431 cross linking reagent Substances 0.000 description 1
• 239000006185 dispersion Substances 0.000 description 1
• 239000011888 foil Substances 0.000 description 1
• 238000010438 heat treatment Methods 0.000 description 1
• 239000002655 kraft paper Substances 0.000 description 1
• 239000007788 liquid Substances 0.000 description 1
• 231100000989 no adverse effect Toxicity 0.000 description 1
• 238000011056 performance test Methods 0.000 description 1
• 229920006267 polyester film Polymers 0.000 description 1
• 239000002994 raw material Substances 0.000 description 1
• 238000011160 research Methods 0.000 description 1
• 239000000758 substrate Substances 0.000 description 1
• 239000002966 varnish Substances 0.000 description 1
• 229920001567 vinyl ester resin Polymers 0.000 description 1