JPH01270051A - Silver halide color photographic sensitive material - Google Patents

Abstract

PURPOSE:To obtain sharpness without impairing the other transfer performance by constituting a silver halide emulsion layer and/or nonphotosensitive layers of specific materials at the time of providing said layer on a base to form the photographic sensitive material. CONSTITUTION:At least one kind of the compd. expressed by the formula A-S-M material is incorporated into the silver halide emulsion layer and/or the nonphotosensitive layer of the silver halide color photographic sensitive material having at least one silver halide emulsion layer on the base. In the formula, A denotes the atom group necessary for forming a tetrazaindene ring, triazaindene ring and pentazaindene ring; M denotes a hydrogen atom, alkali metal atom, ammonium group or group which is cloven under an alkaline condition. The sufficient inter-image is thus obtd.

Description

DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to a silver halide color photographic light-sensitive material which has improved in- and intermediate-image effects and improved sharpness.

(Prior art) By color-developing the /%O silver-genide color photographic sensitizer, the oxidized aromatic-grade amine color developing crude drug and the coupler react to form indophenol, indoaniline, indamine, It is known that azomethine, phenoxazine, phenazine and similar dyes can be produced to form color images. In this method, usually
A subtractive color method is used for color reproduction, using silver halide emulsions that are selectively sensitive to evening, green, and red colors, and color image forming agents of yellow, magenta, and cyan, which have complementary colors, respectively. Ru. To form a yellow image, for example, acylacetanilide or dibenzoylmethane couplers are used, and to form a magenta image, K is used.
Pyrazolone, virazolobenzimidazole, as king
Pyrazolopyrazoles, pyrazolotriazoles, cyanoacetophenones or indacylon couplers are used;
Phenolic or 7-tole couplers are primarily used to form cyan images.

By the way, each dye produced from these couplers does not show an ideal spectral absorption spectrum. In particular, magenta and cyan dyes have broad absorption spectral intersects and have sub-absorption in the short wavelength region, resulting in color Unfavorable for color reproduction of photographic materials.

Unfortunately, sub-absorption in the short wavelength region tends to cause a decrease in chroma. As a means of improving this, it is possible to improve it to some extent by creating an interimage effect.

Regarding the interimage effect, see, for example, Hanson (
Hanson and others, 1 Journal - Optical Society of America (Jaurna)
l of the 0ptical 5ociety
ofAmerica), Volume≠2, pp.663-66, and A. Th1e
Zeitschrift für Wissenschaftriche Fotografie-7
tfLir Wissenschaftliche P
photography.

Photophysique and Photo-c
hemie) Vol.

U.S. Patent J, 336. U.S. Pat.
1s, lit♂ No. 7 has diffusible Nobiichi thiazoline-2.
- A method is described for introducing thiones into color reversal photographic elements to obtain interimage effects.

In addition, in Tokko Sho≠Zaichi 3μ16, when developing a color photographic light-sensitive material and reducing it to silver halide, an intermediate It is stated that the effect can be obtained.

``Also, by providing a colloidal silver-containing layer between the cyan layer and the magenta layer of a color reversal photographic element, the interimage effect can be improved, according to Research Disclosure.
716/3/, Article 13//is (17th layer year).

Furthermore, U.S. Pat. Silver particles? A method is described for obtaining an interimage effect by containing silver halide grains that contain silver halide grains that can form latent layers in another layer, and silver halide grains that can be developed independently of image exposure. has been done.

(Problem to be Solved by the Invention) However, the above method often fails to provide a sufficient interimage effect, and the use of a colloidal silver-containing layer, the introduction of subfog silver halide grains, etc. In addition to the above, which often causes a decrease in color density in photosensitive materials, for example, in the color development process, developing agents such as benzotriazole derivatives and mercapto compounds are used during the coupling reaction with the oxidized form of the color developing agent. An interimage effect can be produced by using a coupler (DI)L coupler that can release an inhibitory substance, or by using a hydroquinone compound that can release a development inhibitory substance such as an iodide ion or a mercapto compound during development. However, their use is limited because the use of these compounds causes a significant reduction in W& and a decrease in color density, so alternative means to the above are recommended. development was desired.

Accordingly, an object of the present invention is to provide a silver halide color photographic material that provides excellent sharpness without sacrificing other photographic properties.

(Means for Solving the Problems) The object of the present invention is to provide a silver halide color photograph W & source material having at least seven photosensitive silver halide emulsion layers on a support. Alternatively, this was achieved by a silver halide color photographic light-sensitive material in which at least -m of the compound represented by the following general formula (I) is incorporated in a non-W&elementary hydrophilic colloid layer.

General Formula (I) A-8-M In the formula, A represents an atomic group necessary to form a tetraazaindene ring, a triazaindene ring, or a pentaazaindene ring. M represents a hydrogen atom, an alkali metal atom, an ammonium group, or a group that cleaves under alkaline conditions.

Next, the compound represented by the above general formula (I) will be explained in more detail.

Examples of triazaindene compounds, tetraazaindene compounds and hapentazaindene compounds used in the invention include jH-pyrrolo[3°2-d]pyrimidines, lH-imidazo[Hiroshi, j-b3 pyridines, j
H-pyro0(,2, j-dJ pyridazine 8% S-triazolo(4!, j-a) bipyridines s-triazolo(/, j-a) pyrimidines, jH-imidazo[μ,
J-d) Pyrimidines, S-triazo o (≠+3-a)
Pyrimidines, S-triazolo(4(,J-c)pyrimidines, 5-1-riazoaCμ, 3-b)pyridazines, jH-pyrazolo(3,4Z-d)pyrimidines, V-
triazo0(≠,j-d)pyrimidines, tetracylo(
/, j-a3 pyrimidines, etc.

M is a hydrogen atom, an alkali metal atom (eg, sodium atom, potassium atom, etc.), an ammonium group (eg, trimethylammonium chloride, dimethylbenzylammonium chloride, etc.), '! or a group that cleaves under alkaline conditions (a group that can become X=H or an alkali metal under alkaline conditions, such as acetyl, cyanoethyl, methanesulfonylethyl, etc.).

In addition, these heterocycles include the nido O group, /1a gene atom (?l
chlorine atom, bromine atom, etc.), cyano group, substituted or unsubstituted alkyl group (e.g. methyl, ethyl, propyl, t-butyl, aryl group (e.g. phenyl, ≠-methylphenyl group, naphthyl etc.), Altanyl groups (e.g., allyl, etc.), aralkyl groups (e.g., benzyl, μm methylbenzyl, 7enethyl, etc.), alkoxy groups (e.g., methoxy, ethoxy, etc.), aryloxy groups (e.g., phenoxy, etc.), Alkylthio groups (e.g. methylthio, ethylthio, propylthio,
etc.), arylthio groups (e.g. phenylthio, etc.),
peterocyclic oxy groups (e.g., -pyridyloxy, coimidazolyloxy, etc.), heterocyclic thio groups (e.g.,
-1penzthiazolylthio, μm virazolylthio, etc.)
, sulfonyl group (e.g., t, methanesulfonyl, ethanesulfonyl & p-1-luenesulfonyl, etc.), carbamoyl group (e.g., unsubstituted carbamoyl, methylcarbamoyl, dimethylcarbamoyl, phenylcarbamoyl, etc.), sulfamoyl group ( Examples: Eva, unsubstituted sulfamoyl, methylsulfamoyl, phenylsulfamoyl, etc.), carbonamide groups (e.g., acetamide,
benzamide, etc.), sulfonamide groups (e.g., methanesulfonamide, benzenesulfonamide, p-toluenesulfonamide, etc.), acyloxy groups (e.g.,
acetyloxy, benzoyloxy, etc.), sulfonyloxy groups (e.g., methanesulfonyloxy, etc.), ureido groups (e.g., unsubstituted ureido, methylwaleido, ethylwaleido, phenylwaleido, etc.), thioaleido groups (e.g., unsubstituted ureido, ethylwaleido, phenylwaleido, etc.), substituted thioureido, methylthioureido, etc.), acyl groups (e.g., acetyl, benzoyl, etc.), heterocyclic groups (e.g., /-morpholino, /-
piperidino, 2-pyridyl, Hiro-pyridyl, 2-thienyl, l-pyrazolyl, /-imidazolyl, λ-tetrahydrofuryl, tetrahytomithienyl, etc.), oxycarbonyl group (e.g. methoxycarbonyl, phenoxycarbonyl, etc.), oxy carbonylamino group (e.g.
methoxycarbonylamino, phenoxycarbonylamino, 2-ethylhexyloxycarbonylamino, etc.)
, ami7 group (e.g., unsubstituted amino, dimethylamino,
anilino group, etc.), carboxylic acid or its salt, sulfonic acid or its salt, hydroxyl group, etc.

Among the compounds of the present invention, preferable heterocycles include S-triazolo(≠, ja)pyrimidines, S-triazolo[
/, J-a] pyrimidines, S-triazo a(” +
3'-CJ pyrimidines, S-triazolo [≠, 3-
b) Pyridazine (goods) is mentioned.

The compound represented by the general formula (I) is preferably represented by the following general formula (I[).

General formula (if) In the formula, M has the same meaning as that of the above general formula (I). A'
is the general formula (I) substituted with m number of soY+ 几-Z
It is synonymous with the person.几represents a linear or branched alkylene group, alkenylene group, aralkylene group, or arylene group, and Z represents a polar substituent. Y is -5-
1-0-1L2kL3 SOQ Expression, 几1%) ('2, R3, R4, R5, about 6,'
kL7, R8, R9 and )tlo each independently represent a hydrogen atom, or an m-substituted or unsubstituted alkyl group, aryl group, alkenyl group, or aralkyl group. n represents Oma71:, ha/. m is/or 2
represents.

More specifically, R is a linear or branched alkylene group (
For example, methylene, ethylene, propylene, butylene,
hexylene, l-methylethylene, etc.), linear or branched alkenylene groups (e.g., vinylene, /-methylvinylene, etc.), linear or branched aralkylene groups (e.g., benzyritine, etc.), arylene groups (e.g., phenylene, naphthylene, etc.).

The polar It'g8 group represented by 2 is, for example, a substituted or unsubstituted amino group (including a salt form, for example,
amino, hydrochloride of amino group, methylamino, dimethylamino, hydrochloride of dimethylamino group, dibutylamino, dipropylamino, N-dimethylaminoethyl-N-methylamino, etc.), quaternary ammoniumyl group (e.g. trimethyl ammonia milk chloride, dimethylbenzylammonylamyl chloride, etc.), alkoxy groups (e.g., methoxy, ethoxy, 2-methoxyethoxy, etc.), aryloxy groups (e.g., phenoxy, etc.), alkylthio groups (e.g., methylthio, butylthio, etc.), arylthio groups (e.g., phenylthio, etc.), heterocyclic oxy groups (e.g., λ-pyridyloxy, --imidazolyloxy, etc.), heterocyclic thio groups (e.g., nobenztheazolylthio, gouvirazolylthio, etc.), , etc.), sulfonyl groups (e.g., methanesulfonyl, ethanesulfonyl, p-
toluenesulfonyl, etc.), Calhamoy A4 (e.g.
unsubstituted carbamoyl, methylcarbamoyl, etc.), sulfamoyl group (e.g., unsubstituted sulfamoyl, methylsulfamoyl, etc.), carbonamide group (e.g., acetamide, benzamide, etc.), sulfonamide group (
For example, methanesulfonamide, benzenesulfonamide, etc.], acyloxy groups (for example, acetyloxy,
benzoyloxy, etc.), ureido groups (e.g., unsubstituted ureido, methylureido, ethylwaleido, etc.),
Acyl groups (e.g., acetyl, benzoyl, etc.), aryloxycarbonyl groups (e.g., phenoxycarbonyl, etc.), thioarydo groups (e.g., free thioureide, methylthioureide, etc.), sulfonyloxy groups (e.g., methane sulfonyl r + cy, p-) luenesulfonyloxy, etc.), heterocyclic groups (e.g. l-
morpholino, /-piperidino, λ-pyridyl, t-pyridyl, nochenyl, /-pyrazolyl, λ-imidazolyl, l-tetrahydrofuryl, l-tetrahydrothienyl, etc.), cyano group, sulfone eV or its salt, carbonyl acid or its Salts, hydroxy groups, and alkoxycarbonyl groups (eg, methoxycarbonyl, ethoxycarbonyl, etc.) are included.

The above group represented by Z may be further substituted with 411 by any combination of R and Z.

Ordinary. , R3, R4% R5, R6,1 (I7, 几8, R
9 and 几1o each independently represent a hydrogen atom, a substituted or unsubstituted alkyl group (e.g., methyl, ethyl, propyl, 2-dimethylaminoethyl, etc.), a substituted or unsubstituted aryl group (e.g., phenyl, λ -methylphenyl, etc.), substituted or unsubstituted alknyl groups (
For example, propenyl, /-methylvinyl, etc.), or a substituted or unsubstituted aralkyl group (eg, benzyl, phenethyl, etc.).

The heterocycle represented by A may be substituted with the substituent described in general formula (I).

In the general formula (■), preferably R represents an alkylene group,
Z represents a substituted or R-substituted amino group, ammonium group, thioether group, or heterocyclic group, Y
But-8-1 represents l.

In the general formula ((I), Z preferably represents a substituted or unsubstituted amino group or a heterocyclic group, respectively.

Specific compounds used in the present invention are shown below, but the compounds of the present invention are not limited thereto.

/! .

/3゜ /4Z.

/J.

/6゜ /7° /I.

2/.

2 no.

ノ3゜ O)i ! ≠.

H3 Koj6 26° 27° ,! g.

The compounds used in the present invention are described in The Journal of Organic Chemist+)-(The Journal
of (Jrganic Chemistry).

2μ 77ri~II/(/93ri), same magazine lj,
36/~366 (/ri60), U.S. Patent No. 2. lj,
2. ≠No. 60, same 2. ')/3. ! μ No. 2゜74
13.111, same λ, 7μ3.1za0, same 2, gza7,371, same, 23! , No. 4c014, same, μ Hiro≠, No. 60, same 2. 33.3 Zaza issue, same 2.
19/, No. 162, same, Zalp/, No. 076, same J,
It can be easily synthesized by referring to the methods described in No. 7jj, No. 76, etc., and typical synthesis examples are shown below.

Synthesis example/(Synthesis method of exemplified compound B) 7-chloro-s-triazolo(/, j-a3 pyrimidine 7.7F and 30 gy of thiourea in ethyl alcohol/3
When dissolved in 0xl and heated under reflux for 30 minutes, yellow crystals precipitated. The precipitated crystals were collected, mixed with sodium hydroxide, and 30 dk of water were added, followed by heating under reflux for 3 hours. After the reaction, concentrated hydrochloric acid was added to the reaction solution to separate the precipitated crystals, which were then recrystallized from 30 d of ethyl alcohol to obtain the desired product, /P (yield: 44%). Melting point core j ~ 6°C Synthesis example 2 (synthesis method of exemplified compound 22) 2-hydrazinopyrimidine j in 12 ml of sodium hydroxide, water/10wd, and ethyl alcohol μμOdf
After adding 6 g of carbon disulfide and heating under reflux for 2 hours, the precipitated crystals were collected.

Add water/Itt to the obtained crystals to dissolve them, add vinegar #R to adjust the pH to ~j, collect the precipitated crystals 'ftP, recrystallize with methyl alcohol for 200 yd, and obtain the desired product.
6F (yield: 60%) was obtained. Melting point 2≠/-J℃ @Example 3 (Synthesis S of Exemplified Compound 3) 100 d of water was added to Compound 6.3F obtained in Synthesis Example 2, heated under reflux for 3 hours, and then crystallized to give 30 d of total methyl alcohol. Recrystallize with and obtain the object j.

gy (yield taco%) was obtained. Melting point 2≠j~6℃ Synthesis example≠
(Synthesis method of Exemplified Compound/3) 7-ri0O-j-methylthiomethyl-s-1-riazoa(/,J-a)pyrimidine 6, μritothiourea λ, J
After dissolving P in 0WL of ethyl alcohol and heating under reflux for 1 hour, the precipitated crystals were collected.

Sodium hydroxide and 30 dt of 2F water were added to the resulting friend crystals and heated under reflux for 3 hours at 7'2. After that, salt preparation fijd was added to the reaction solution to precipitate, and the next crystal was recrystallized from a mixed solvent of 30 d of methyl alcohol and 10 d of dimethylformamide to obtain the desired product/0.
3 g (yield: 2 squares) was obtained. Melting point: 22°C to 10°C @ Examples j (Examples @ g) Synthesis method of io) 7-chloro-3
-dimethylaminoethylthiomethyl-s-triazolo(/,ja)pyrimidine, r, 29 and thiourea λ,
3Pt-ethyl alcohol was dissolved in Od and the same method as in Synthesis Example ≠ was used to obtain the desired product 2°22 (yield: 100%). Melting point: 93 to 6°C The compound of the present invention represented by the general formula [1] has the following characteristics:
Or, although it differs depending on the development processing method, generally the same layer content is 1 mole of silver halide in the adjacent layer.
−1 to 10 −5 mol, preferably j
0=~3×10'mol.

In order to introduce the compound represented by the general formula (I) of the present invention into a light-sensitive material, it is dissolved in a solvent commonly used in photographic light-sensitive materials such as water, methanol, ethanol, propanol, or fluorinated alcohol, and then Add foil to hydrophilic colloid. When contained in the silver halide emulsion layer, it may be contained at the time of grain formation of the silver halide emulsion, at the time of physical ripening, immediately before chemical sensitization, during chemical sensitization, after chemical sensitization, or at the time of preparing the coating solution. It is selected based on the purpose.

The preferred silver halide contained in the photographic emulsion layer of the photographic light-sensitive material used in the present invention is silver iodobromide, silver iodochlorobromide, or silver iodochlorobromide containing about 30 mole or less silver iodide. Preferred is about λmolti to about 7molcs
Silver iodobromide containing silver iodide of not more than J and J moles is particularly preferred.

Silver halide grains in photographic emulsions include those with regular crystal shapes such as cubes, octahedrons, and tetradecahedrons, and those with irregular crystal shapes such as spherical and plate shapes. It may be one having crystal defects such as twin planes, or a composite form thereof.

The grain size of the silver halide may be fine grains of about 0.2 microns or less or large grains with a projected area diameter of up to about 70 microns, and may be a polydisperse emulsion or a monodisperse emulsion.

Silver halide photographic emulsions that can be used in the present invention are, for example, published by Research Disclosure (RD), Rot/764 (j
(/ri7g/February), pages 22-λ3, 11. Emulsion preparation and
types )”, and direction/%/za7/A(/ri7
(Year/I month), 6μg page, graphic "Physics and Chemistry of Photography", published by Paul Montell (P.

Glafkides, Chemic et Phys
iquePhotographique Paul M
ontel, /ri67), "Photographic Emulsion Chemistry" by Duffin, published by Focal Press (G, F, Duf
f in , Photographic Emulsi
on Chemistry (Focal Press
.

``Manufacture and Coating of Photographic Emulsions'' by Zerikuma et al., published by Focal Press (V, L.

Zelikman et al., Making
andCoating Photography
c Emulsion.

It can be prepared using the method described in Focal Press, 6μ), etc.

U.S. Patent No. 3,37≠, 62g, U.S. Patent No. 3.6jJ, J Rihiro and British Patent No. 7. Monodisperse emulsions described in ≠/3, 7≠g and the like are also preferred.

Tabular grains having an aspect ratio of about 3 or more are also useful in the present invention. Tabular grains are written by Gatsuto, Photographic Science and Engineer IJ.
7 Gutoff.

Photographic 5science and
Engineering), Volume 7μ 1, 24', 5
'~237 pages (/70 years): US Patent No. ≠lq3≠
, No. 226, same U, Hiro/μ, No. 310, same Hiro, ≠33°opr No., same μ, ≠32. jJO No. and British Patent No. r
, iii, ijy, etc.

The crystal structure may be --like, the inside and outside may have different halogen compositions, it may be a layered structure, or silver halides with different compositions may be joined by epitaxial bonding. often,'! For example, it may be bonded with a compound other than silver halide, such as Rodan scissors or lead oxide.

A mixture of particles of different crystalline forms may also be used.

The silver halide emulsion used is usually one that has been subjected to physical ripening, chemical ripening, and spectral sensitization. The foil additives used in such processes are Research Disclosure/I6
/76≠3 and is described in the same A/J'7/6,
The relevant sections are summarized in the table below.

Known photographic additives that can be used in the present invention are also listed in the two Research Disc A-Jars mentioned above, and the relevant listings are shown in the table below.

Additive CI agent type RD/76413 RD/17
/isl Chemical sensitizer page 23 6 μza page right column, 2 Sensitivity enhancer Same as above 3
Spectral sensitizer, page 23~-μ 6≠g page right column~
Super sensitizer 6μ page right column≠
Brightener 2≠Page j Antifoggant 24'-2≠Page 6≠Right column ~ and stabilizer 6ft, absorbent, 7. 23-j page 6 6q page right column - Ilter dye 1, 30 page left column ultraviolet absorber 7 Stain inhibitor 2≠ page right column 130 page left - right column, etc. Dye image stabilizer, 2≠ page ta Hardener 26 Page 6si page left column/
Q Binder 26 pages Same as above//
Plasticizers, lubricants, page 27, 630 right column/, 2
@Fabric aids, Table 2t~, page 27 Same top surface active agent 13 Static prevention page 27 Same top stop agent Various color couplers can be used in the present invention, specific examples of which can be found in the research disk mentioned above. Roger (
RD) 4/7Ag 3, ■-〇-G.

As a yellow coupler, for example, U.S. Pat.
No. 3.301, μ, No. 022.620, Hiroshi Mukai, 3
26.02 Hiro issue, same No. 4 oi.

No. 73.2, Special Publication No. 31-10732, British Patent No. 1
, No. 1423.01O, No. 1. ≠7A, 7Aθ, etc. are preferred.

As magenta couplers, j-virazolone and virazoloazole compounds are preferred, and are described in U.S. Patent No. DA, 31
0. Is/ri No. 331゜gri No. 7, European Patent No. 73.1s31s, U.S. Patent No. 3.06/, 432
No. 3.7λs, No. o67, Research Disclosure/16 no 1120 (/ri r < June z), JP-A-60-33332, Research Disclosure/16.2≠230 (lμ (June), % opening 6O-
No. 4L3632, U.S. t=W permit No. ≠, No. 300.630,
First, those described in No. 34c0.63j are particularly preferred.

Examples of cyan couplers include phenolic and 7-tall couplers, which are disclosed in Komeo Patent No. ≠.

OJ, No. 2.212, No. 14, No. 326, No. ≠, 221.233, No. ≠, 26. No. -00, No. 2, 36, No. 2, No. 2.10/.

No. 777, No.-,772,/ls2, No. λ.

Zarij, Za26, 3.77j, OQ-, 3.7! ;g, 30g issue, same issue≠, 33≠, O71 issue,
Hiroshi Dodai, 327. /73, West German Patent Publication No. 3,3λ, 7.2, European Patent No. 1-7゜31sjA, US Patent No. 3. R1A6.12-, same No. '1.333. Tatata issue, same number ≠, ≠si, jj issue, same number, ≠, 27
．． 7A7, European Patent Nos. 16/12AA and the like are preferred.

Colored couplers for correcting unnecessary absorption of coloring dyes are disclosed in Research Disclosure A/7.4μ3 ■-G section, US Patent No. ≠, /63°1.70, and Japanese Patent Publication No. 7-37-73. , U.S. Patent - No. U, OOμ, 2
ri issue, same issue t, /3za, koj! No. 1, British Patent No. 1. l hiro6. ．． The one described in No. 341 is preferred.

Couplers containing color dyes with appropriate diffusivity include U.S. Patent No. μ, 361s, 237 and British Patent No. r, iλ.
j, 370, European Patent No. 26.370, West German Patent (Publication) No. 3.234c,! ; those described in No. 33 are preferred.

A typical example of a polymerized subpigment-forming power puller is U.S.%
Total 3rd. ≠J/, No. 120, OlO, No. 2//, No. 367.21-, British Patent No. 2. lQλ,
It is described in No. 173, etc.

Couplers that release photographically useful residues upon coupling are also preferably used in the present invention. The DIR coupler releasing the development inhibitor is the above-mentioned R,D/7A≠3
, ■ to F, which are patents listed in Japanese Patent Application Publication No. 37-37-1! μλ3 Hiro No. 60-7g≠-μ
No. g, U.S. Patent No.

, 2≠g, and those described in Zoro λ are preferred.

As a coupler that releases a nucleating agent or a development accelerator in an imagewise manner in an emergency, British Patent No. 2. Ori 7.140,
Same 2nd. /3ノ, /l# issue, Tokukai Shojter/J71.3
? Preferred are those described in No. 4Jter/70g Hiroo No. ''.

Other couplers that can be used in the W&light material of the present invention include U.S. Patent No. ≠, /30. Competitive couplers such as those described in US Pat. No. 1°-r3. Hiro 72,
Same No. μ, 33g, 393, Same w, It, 310. Al
Multi-equivalent coupler described in No. 1 etc., JP-A-60-1139
DIR redox compound releasing coupler described in 30 etc.
Examples include a coupler that releases a dye that restores color after being chewed off, as described in European Patent No. 173.30.2A.

The coupler used in the present invention can be introduced into a light-sensitive material by a known dispersion method.

Examples of high boiling solvents used in oil-in-water dispersion methods are described in U.S. Pat. No. 1,322,027 et al.

The steps and effects of latex dispersion methods, and specific examples of latex for impregnation, are described in U.S. Pat.

No. 363, West German Patent Application (OLS) No. 2. j hiro l.

No. 27≠ and No. 2 of the same. jμ/, No. 230, etc.

Suitable supports that can be used in the present invention include, for example, the above-mentioned R
, D, page 2g of I6/71s4L3, and the same No./17
/6, page 64L7 right column to page 61It♂ left column.

The present invention can be applied to various multilayer silver halide color light-sensitive materials. Applicable to color negative film, color reversal film, reversal color paper, color paper, color positive film, large color Y-lint film, etc.

In particular, it is preferably applicable to color reversal films, reversal color papers, and the like.

The color developing solution used in the development of the light-sensitive material of the present invention is preferably an alkaline aqueous solution containing an aromatic primary amine color developing agent as a main component. As this color developing agent, aminophenol compounds are also useful, but p-phinidine diamine compounds are preferably used, and representative examples thereof include 3-methyl-≠-aminor N, N-diethyl Aniline, 3-methyl-μm amino-N-ethyl-
N-β-hydroxyethylaniline, 3-methyl-
- Amino-N-ethyl-N-β-methanesulfonamide ethylaniline, 3-methyl-guami/-N-ethyl-N-β-methoxyethylaniline and their sulfates and salts M! salt or pt-luenesulfone rII salt. Two or more of these compounds vJ can be used in combination depending on the purpose.

'Furthermore, when performing reversal processing, black and white development is usually performed and then color development is performed. This black and white developer contains dihydroxybenzenes such as hydroquinone, /-phenyl-3-
Known black and white developing agents such as 3-pyrazolidones such as pyrazolidone or aminophenols such as N-methyl-p-aminophenol can be used alone or in combination.

The pH of these color developing solutions and black and white developing solutions is 7 to 2.
It is common that The amount of replenishment of these developing solutions depends on the color photographic light-sensitive material to be processed, but generally it is less than 3 grams per 100 square meters, and by reducing the bromide ion concentration in the replenishing solution,
It can also be set to 0d or less. When reducing the amount of replenishment, it is preferable to prevent evaporation of the liquid and air oxidation by increasing the contact area with the air in the processing tank. It is also possible to reduce replenishment by using a means for suppressing the accumulation of bromide ions in the developer.

After color development, the photographic emulsion layer is usually targeted.

The marking treatment may be carried out simultaneously with the mud layer treatment (or the marking foot treatment) or separately (5) Furthermore, in order to speed up the processing, it may be possible to carry out a bleaching treatment followed by a bleach-fixing treatment. . Furthermore, treatment with two consecutive bleach-fixing baths, fixing treatment before bleach-fixing treatment, or bleaching treatment after bleach-fixing treatment can be carried out as desired depending on the purpose. As a bleaching agent, for example, iron (III), Kobal) (
II), compounds of polyvalent metals such as chromium (■), copper (n), peracids, quinones, nitro compounds, etc. are used.

Typical bleaching agents include ferricyanide; dichromium M salt; organic complex salts of iron (Iff) or cobal (In), such as ethylenediamine/tetraacetic acid, diethylenetriaminepentaacetic acid, cyclohexanediaminetetraacetic acid, methyliminodiacetic acid, -Use of aminopolycarboxylic acids such as diaminopropanetetraacetic acid, glycol ether diaminetetraacetic acid, or complex salts of citric acid, tartaric acid, malic acid, etc.; persulfates; chlorates; permanganates; nitrobenzenes, etc. I can do it.

Examples of fixing agents include thiosulfates, thiocyan*t3[, thioether compounds, thioureas, and large amounts of iodide salts, but thiosulfates are commonly used, and ammonium thiosulfate is the most commonly used. Can be used widely.

Preservatives for bleach constant Nl are preferably sulfites, bisulfites, or carbonyl bisulfite adducts.

The halogenated scissors color photographic W&optical material of the present invention is generally subjected to a water washing and/or stabilization process after desilvering treatment. The amount of water used in the washing process depends on the characteristics of the photosensitive material (for example, depending on the materials used such as couplers), the application, the temperature of the washing water, the number of washing tanks (number of stages), the replenishment method such as countercurrent or forward flow, and various other conditions. Can be set over a wide range. this house,
The relationship between the number of washing tanks and the amount of water in the multistage countercurrent method is J
our own of the 5ociety
of MotionPicture and Te
1evision Engineers Volume 6≠, P.
, z < Lee-2! It can be determined by the method described in ;3 (/rijj month issue).

Various processing solutions in the present invention are used at 10°C to 30°C. Normally, the standard temperature is between 33°C and 3g°C, but higher temperatures can accelerate processing and shorten processing time, while lower temperatures can improve image quality and improve the stability of the processing solution. can do. In addition, in order to save silver on photosensitive materials, West German Patent No. 2.2λ6.770 or U.S. Patent No. 3
A treatment using cobalt intensification or hydrogen peroxide intensification as described in , 67μ, Kotata issue may also be performed.

(Example) The present invention will be explained in more detail below using examples.

Example / On a subbed triacetate cell O-Sfilm support,
A multilayer color photosensitive material consisting of each layer having the composition shown below was exploded to prepare Sample 10/.

1st layer: anti-halation layer black colloid 0.2! y/rr? Ultraviolet absorber U -i 0.0≠1/- Ultraviolet absorber U-, 20, /II/r? UV absorber U-30,
/P/rr/ High boiling point organic solvent 0-/ 0. /cc/rr?
Gelatin layer containing (dry film thickness 2μ) 2nd layer: Intermediate layer compound H-/0.0JPld high boiling point organic solvent 0-,l O,03eC/rr? A
-j O, / 61/rr? Gelatin layer containing (dry film thickness/μ) 3rd layer: 1st red-sensitive emulsion layer sensitizing dye 5-t (o, 3/FFI”) and S-2 (
0,0μ89/rr? Spectrally sensitized with > surface latent image type nest-dispersed silver iodobromide emulsion Silver amount...0.33 r/rr? (Iodine content≠molti, average particle size 0.3μ, coefficient of variation according to particle size (hereinafter simply referred to as coefficient of variation)/T) Emulsion A O, OJri/rrl coupler C-/0. /3ri/R coupler C-20,033f/rr? High boiling point organic solvent 0-20.0gcc/rr? gelatin layer (dry film thickness 0.7μ) qth layer: λth red-sensitive emulsion layer sensitizing dye 8-1 (/, /misaki/m”) and S-2 (0,0
≠Misaki/-) spectrally sensitized nine-surface latent image type monodisperse silver iodobromide emulsion Silver amount...o, s3y/rr? (Iodine content 3 molt, average grain size 0.3 μ coefficient of variation/A%) Emulsion A O,039/l♂Coupler C-/θ,≠Of/rrlCoupler C-20,07f/ZA-4L O,02 Gelatin layer containing Ki/R high boiling point organic solvent (J-J O, 22'A/rr? (dry film thickness/, 7μ) 3rd layer: 3rd red-sensitive emulsion layer sensitizing dye 8-/C/, /'19/rr?) and S-,2
<0.0μ■/m') spectrally sensitized nine-surface latent image type monodisperse silver iodobromide emulsion Silver amount...0.33P/rr? (Iodine content imolti, average particle size 0.6μ, coefficient of variation/7chi) A-jO, Za11I9/rrl Coupler C-/θ, ≠≠9/rr? Coupler C-20,0g1/W? High boiling point organic solvent 0-2 0. JIAcc/lr?
Gelatin layer containing (dry film thickness/8 gμ) 6th layer: Intermediate layer A-/θ 10■/rr? A
−／／ ! q/rr? Compound H-70, / 1ard High boiling point organic solvent 0, / ee/r
r? Gelatin layer containing latex dispersion of polymethyl methacrylate (dry film thickness/μ) 7th layer: @/Green-sensitive emulsion layer Sensitizing dye S-3 (2,2■/-) and S-μ・(/
, otny/rrt) surface latent image type monodisperse silver iodobromide emulsion spectrally sensitized silver amount...0, j P/rr? (Iodine content 3 molt, average grain size 0.3μ, coefficient of variation 19%) Emulsion A O, OJl/lt? Coupler C-30, 27jl/rrl High boiling point organic solvent 0-, I O, / 7cc/r
r? gelatin layer (dry film thickness 0.7μ) G layer: green-sensitive emulsion layer containing sensitizing dye 8-3 (0.3K/W?) and S-μ (O0λ
Town/W? ) Spectrally sensitized monodisperse internal latent image type silver iodobromide emulsion Silver amount... 0.3 ri/rrl (Iodine content λ, j morti, average grain size 0゜4cj
μ, the distance from the latent image to the particle surface is 97! Coefficient of variation/θ%) Sensitized color z8-3 (o, tsy/rr?) and S-+ (O
o, 2sy/rr? ) Spectrally sensitized surface latent image type monodispersed silver iodobromide emulsion Silver amount...0.3P/W? (Contains iodine, t2, jmolti, average particle size 0.3!
μ, variation factor 15 (/zachi) Emulsion B O,0JPlrrl Coupler C-J O,2jl/rr? High boiling point organic solvent 0, / 3 CC/r
r? gelatin layer (dry film thickness/, 7μ); third layer: third green emulsion layer; sensitizing dye S-3 (0,2'19/rr?) and S-
Nine-surface latent image type monodisperse silver iodobromide emulsion spectrally sensitized at 1 (o, 3sy/rr?) Silver amount...0.3'l/rr? (Iodine-containing 11J morch, average powder size 0.6μ, coefficient of variation) 7%) A-70,3■/rr? Coupler C-10,2P/rr? Coupler C-30, /P/rr? High boiling point organic solvent 0-2 0.03CC/rr? Gelatin layer containing (dry film thickness/, 7μ) 1st θ layer: Intermediate layer compound H-/ 0.0! P/rr? A
-J O, OJl/W? A-/
l O,0/ri/rr? High boiling point organic solvent 0-2 0. /P/rr? Gelatin layer containing (dry film thickness/μ) 1st/layer: yellow filter layer yellow colloidal silver 0.0JP/W? A-
/ 0. /21/d compound)
1-/0.02P/d Compound H-2
0,0311rrl High boiling point M mechanical solvent o-i 0.04ccc/rr
? Gelatin layer (dry film thickness lμ) 12th layer: 1st back emulsion layer sensitizing dye 8-j (i, O'9/rr?) Silver bromide emulsion weight...0.6 ri/rr? (Particles with an iodine content of 3 molt and a diameter/thickness ratio of 7 or more occupy 304 of the projected area of all particles. Average thickness of particles 0.1Oμ) A-60, g ■/- Coupler C-30,3P /rr? A-Hiro 0.03 K/R low boiling point organic solvent o-i 0. /CC/rr? gelatin layer (dry film thickness 1.jμ) 13th layer: 2nd blue-sensitive emulsion layer A narrow latent image type tabular oxide spectrally sensitized with sensitizing dye 8-3 (2.0 K/Z). Silver bromide emulsion image - engraved... / , / P/rr? (Iodine content), j morch, and particles having a diameter/thickness ratio of 7 or more account for jO% gold of the projected area of the total particles. Average thickness of particles: 0. /! μ) A-7/19/rr? Coupler C-J/, JPIn? High boiling point organic solvent 0-. Gelatin layer (dry film thickness 3μ) containing 2 0, ko3 (A/rr?) 1st μ layer: 1st protective layer A-/J O,/11/rr?
Ultraviolet absorber U-70.0λ111n? UV absorber U
-J O,031/d Ultraviolet absorber U-30
,03ri/rr? Ultraviolet absorber U-μ O, Kota P/rr? High boiling point organic solvent 0-7 0. ．． 21
Gelatin layer containing cc/rrl (dry film thickness 2μ) 7th layer: covered with the surface of the second protective layer, fine grain iodobromide image emulsion silver...0, / P/rr? (Iodine content 1 molti, average particle size 0.06μ) Yellow colloidal steel silver amount for yellow filter layer...0.0/P/ry? A-J'IO'19/
rr? Gelatin layer (dry film thickness Q1 gμ) containing polymethyl methacrylate particles (average particles i, jμ) octa/“I/W?” In addition to the above composition, each layer contains gelatin hardening agent H-3 and surfactant. Next, add the agent.

The compounds used to prepare the samples are shown below.

−j 08H17 (tl C-Hiroshi H3 ■ -s C-7 COOC3H7(iso) -t U-λ -J Shi−≠ H-/ H-,2 )1-J 0-,2 -i −j δ −μ 5-s A-/ Q CH3 2θ //2S(J4 -J 2f15 C2145A-≠ C2) 1° A-♂ C, F1□SO□N0)l, C00K c3h.

A-ta A-// A-/2 Preparation of Emulsion A1 Emulsion B A silver bromide cubic emulsion with an average grain size of 0.73 μm was prepared by the Chondrold double jet method, and processed under low pAg using hydrazine and a gold complex salt. It was overlaid (called emulsion B). Bromide e was present on the surface of emulsion B prepared in this way.
Emulsion A is obtained by shelling the emulsion to a thickness of 23OA.

Compound A The silver iodide content of the total photosensitive halide steel grains in the layer was 7.3 molti, 6 molti, and 6 molti, respectively.
Prepare sample 1 in exactly the same manner as sample 101 except for making j morchi.
0.2.103, io version was created.

Preparation of samples ios and io6 Third layer, μth layer, @7 layer, W1g layer, seventh layer of sample ioi
Sample 103 was prepared in exactly the same manner as Sample 101 except that Compound A and Compound @B were added in the two layers in an amount of 0 to 3 moles per mole of silver. 101s'1-produced.

Preparation of samples 107-/10 3rd layer, μ-th layer, 7th layer, g-th layer of samples 10/-10IA
Samples 107 to 110f were prepared in the same manner as Samples 10/-10≠ except that 0-3 mol of the compound lλ of the present invention was added to the 12th layer, respectively, per 7 mol of silver.

Sample / / /-/ /I (D Preparation Sample 107 was prepared in exactly the same manner as Sample 107, except that in place of Compound 7.2 of Sample 107, the compounds shown in Table 1 were added to 7 mol of silver in ios-s. Sample ///~l/I' (was prepared.

The samples prepared in this manner were then exposed to white light (red light, green light, blue light) through a continuous wedge and developed as described below. In addition, samples /Q16 to ii♂ were exposed to red light (the same exposure amount as the red light during exposure of the white original) through the continuous wedge, and subjected to the following development process. - Exposure amount difference (ΔlogE(
A friend looking for something ordinary.

The value of ΔlogE(R) was used as a comparative measure of the interimage effect on the red-sensitive layer. Similarly, Δ1ogE(
G) and Δ1ogE (B) were determined.

The results are shown in Table 1.

Also, through the MTF measurement pattern, sample 10/~//I
f It was exposed to white light and subjected to the following development process. Then, the sharpness was compared based on the MTF value of IO cycle/frame.

The results are shown in Table 1.

Treatment process Time Temperature Washing with water λN 3 za Reversal 2 3 Za1 Color development 1sp 31p Adjustment 2N 3za Bleaching 1. tt 3fz Fixation　　μl〃3〃 Wash with water 　　μl　3〃 The composition of each treatment liquid was determined as follows.

First developer Nitri o-N,N,N-2,oy Trimethylenephosphonic acid/j Sodium salt Sodium sulfite 309 Hyde a
Quinone Monosulfonic Acid 2011 Potassium Potassium Carbonate 339/-Phenyl-≠-Methyl-4- 2. OP° hydroxymethyl-3-pyrazolidone potassium bromide, 2. JlK potassium thiocyanate /, 2P potassium iodide, add owg water
1000vdpH, 10p)i was adjusted with hydrochloric acid or potassium hydroxide.

Reversal solution - Nitrilo-N, N, N-j, Oftrimethylenephosphonic acid, j, sodium salt, stannous chloride, dihydrate /, 01p-7 minophenol, o, i1p, sodium hydroxide, 1, ry, glacial acetic acid
1stph
t, o.

Adjusted with pHFi, hydrochloric acid or hydroxide).

Color developer Cotrilo-N, N, N-2, op Trimethylenephosphonic acid/j sodium salt Sodium sulfite ゛ 7. Of trisodium phosphate, 12 water [31,y potassium bromide
1. θ Potassium Taiodide
Taoq sodium hydroxide
3. Of Citrazine#! /・5y N-ethyl-N-(β-methane //p sulfonamidoethyl)-3-methyl-≠-aminoaniline sulfate 3.6-cythiaoctane/, 1 /, Of-diol pHii, 0 paFi, Adjusted with hydrochloric acid or potassium hydroxide.

Adjustment liquid Ethylene diamine fluoroacetic acid 2s r, oy thorium salt - hydrate Sodium sulfite lλ1 Nauthioglycerin 0. ≠dp)i
6.20pH with hydrochloric acid or sodium hydroxide? J4 friends.

Bleach solution Ethylenediamine diacetic acid, 2S-6OF thorium salt, λ water salt Ethylenediamine fluoroacetic acid, F e / 20P
(III)・Ammonium・Potassium dichlorobromide 1001! Ammonium nitrate 10ml Add all the water
1000100 Oj, 70 pH adjusted with hydrochloric acid or sodium hydroxide.

Fixer sodium thiosulfate toy sodium sulfite 3.09 sodium bisulfite s, oypHb, t.

The pH was adjusted with hydrochloric acid or aqueous ammonia.

Stabilizing liquid Formalin (37%) J, ON polyoxyethylene-p -0, 3yd 7-tononyl phenyl ether (average degree of incorporation 1O) p) 1 Without adjustment Example λ A paper support laminated on both sides with polyethylene was coated with the following: A color photographic light-sensitive material sample 207 was prepared from No. 1-1 of 1-2, which was coated with two layers of Deshi. The polyethylene coating side of the first layer contains titanium white as a white pigment and a trace amount of ultramarine as a bluish dye.

(Photosensitive layer composition) Below are the ingredients and jl/rr? It is shown in units and the next application f7 is shown.

Regarding silver halide, the coating amount is shown based on scissors JII 8 calculation.

1st layer (gelatin layer) Gelatin... 7.30 2nd layer (
Antihalation layer) Black colloidal silver... o, i.

Gelatin...0.70 3rd layer (
Low-sensitivity red-sensitive layer) Spectrally sensitized with red sensitizing dyes (*l, *, 2) silver friendiobromide (silver iodide 3.0 molti, average grain size 0.4tμ)
... o, ij gelatin
... /, 00 cyan coupler (*ri ...
0. / Dacyano coupler (*≠) ... 0.07 Antifading agent (*j, *A and *7) ... θ, 10 Coupler solvent (*zato*ri) ・ ・ ・ 0.06 Hiro layer (High-sensitivity red-sensitive layer) Iodobromide bride (silver iodide 6.0 molti, average grain size 0.7μ) spectral pII sensitive with red sensitizing dyes (*/ and *ko)
... o, is gelatin
... i, o.

Cyan coupler (*3) ... 0. ．． 20 cyan coupler (*μ)...0. IQ anti-fading agent (*j,
*6 and *7) ... 0. lj coupler solvent (*g and *ri) ・ ・ ・ O, / 0 j1-th (intermediate layer) magenta colloid silver --- O, Oa gelatin
... / , 00 color mixture prevention agent (*/θ
) ... O0θg color mixing inhibitor solvent (*// and *1
2) ・ ・ ・ 0.76 Polymer latex (*lj) ・ ・ ・ 0, I O 6th layer (low sensitivity green sensitive layer) Spectrally sensitized with a green sensitizing dye (*/≠) and bromoiobromide # i(
Silver iodide 2. j molti, particle size θ.

≠μ) ... 0,10 gelatin
... o, g.

Magenta coupler (*2j) ・ ・ ・ 0, I O Antifading agent (*/A) ・・・ 0. IO stain inhibitor (*/7)... 0.0/stain inhibitor (*
/g)... 0.00/coupler solvent (*/) and */
・ ・ ・ o, is 7th layer (high sensitivity green sensitivity II) Silver iodobromide (
Silver iodide 3.3 molti, grain size O1μ)
... θ, 10 gelatin
... OozaO magenta coupler (*/j) ■ ・ 0.10 Anti-fading agent (*/l) ... 0.10 Anti-stain agent (*/7)... 0.0/ Anti-stain agent (*
lza)... 0.00/coupler solvent (*/l and */
ri) ・ ・ ・ 0. /J Gth layer (yellow filter layer) Yellow colloid)' Silver ---0,20 Seratin
... /, 00 color mixture prevention agent (*i0
) ... o, o6 color mixture inhibitor solvent (*l/ and */, 2) ・ ・ ・ 0.7 j Polymer latex (*/J) ・ ・ ・ 0.10 th layer (low sensitivity blue sensitive layer ) Spectrally sensitized with a blue sensitizing dye (*, zO) and then silver iodobromide (
Silver iodide J, j morti, grain size O6jμ)
・ ・ ・ o, i, s gelatin
... 0. JO yellow coupler (*,
2/) ・ ・ ・ 0.20 Stain inhibitor (*/J')... o, ooi coupler solvent (*ri)... 0.03rd io layer (high sensitivity V-sensitive layer) Blue sensitizing dye Silver iodobromide sensitized with (*, 20) (
Iodizing scissors, j morti, particle size 7゜2μ)
... Q, λj gelatin ・
・・・ / , 00 Yellow coupler (*, 2/) ・ ・ ・ 0 , μ0 Stain inhibitor (*/za) ・・・ 0.002 Coupler solvent (*ri) ・・・ 0810 1st/layer (ultraviolet absorption layer) Gelatin... /,! 0 Ultraviolet absorber (*22, *6 and *7) ・ ・ ・ /, 00 Color mixing prevention agent (*ko3) ... 0.01 Color mixing prevention agent solvent (*ri) ... 0.7j Irradiation prevention Dye (*2μ) ・ ・ ・ 0.0λ Anti-irradiation dye (*λ3) ・ ・ ・ 0.02 72nd layer (protective layer) Fine particle chlorobromide @ (chloride 77 molti, average size O1λ
μ) ... 0.07 gelatin
... i, j.

Gelatin hardener (*λ6)...0.77 car/3
．． ! '-dichloro-3,3'-di(3-sulfobutyl)
-terethylthiacarbocyanine Na salt *λ triethylammonium-3-(,2-(,2-
[3-(3-sulfobutyl)su7to(/,,2-d)thiazoline-2-indenmethyl]-
/-butenyl)-3-naphtho(/,,2-d)thiazolino]propanesulfonate*JJ-(α-(-1Hiro-di-t-amyl7enoxy)
hexaneamide]-≠, 6-dichloro-j-ethyl7ethyl*4Cj-(λ-chlorobenzoylamide]-μmchloroo-j-(α-(λ-chloroa-≠-1-amylphenoxy ) octanamide]-7enol*j J-(,2-hydroxy-3-sec -!
-t-butylphenyl)benzotriazole*6 2-(2-hydroxy-j-1-purphenyl)benzotriazole*7 Co(2-hydroxy-3,j-di-butylphenyl)6-ral Benztriazole*g di(coethylhexyl) phthalate
Tri/nyl phosphate *10 j, J-di-t-octylhydroquinone */-/ tricresyl phosphate */2 dibutyl 7-thalerate *13 polyethyl acrylate */da J,! '-diphenyl router ethyl-3゜3'
-Disulfopropyloxacarbocyanine Na salt */3 7-riao-1,-methy-2-(/ -(λ
-octyloxy-j- (co-octyloxy-j-1
-octylbenzene-sulfonamide)2-propyl)
-/h-pyrazolo(/, j-bJ(/, j.

[Hiroshi] triazole*/ls 3,3.3', j'-tetramethyl-
j.

A,! ;', A'Tetrapropoxyl.

/'-bisspia indane*/7 3-(J-ethylhexyloxycarbonyloxy)-/-C3-hexadecyloxyphenyl)-2
-pyrazolino*/f, l-methyl-j- -octylhydroquinone*l trioctyl phosphate ゛*co0 triethylammonium 3-[λ-(3-benzylrhodanine-s-yrif':i) -3 -benzoxazolinyl]butanesulfonate*2/α-pivaloyl-α-((,2,Hiro-dioxo-7-benzyl-j-ethoxyhydantoin-3-yl)-2-chloro-j-(α -2,4!-di-t-amylphenoxy)butanamide]acetanilide*2.2 3-ria-(λ-hydroxy-3-1
-butyl-j-octyl)phenylbenztriazole*, 23. 2.3-G5ec-octylhydroquinone *ノμ *! j 126 /, 2-bis(vinylsulfonylacetamido)ethane samples 202 to -10 preparation samples, 20 / +7) 3rd layer, wJv layer, 6th layer, 7th layer, 3rd layer, 10th layer. Samples 202-210 were prepared in exactly the same manner as Sample 20/, except that each of the compounds shown in Table 2 was added at 3X/0-3 mol per mol of silver.
was created.

To obtain the interimage effect of these samples 20/-207, the compounds were exposed in the same manner as in Example 1 and developed as described below to obtain ΔlogE(R), ΔlogE(G), Δlog
E(B) was measured.

The results are shown in Table 2.

[Processing process]

First development (black and white development) 3g℃/'/j'Water wash 3g"c i'3o'Reversedew"lf, 100Lux or more 71 or more Color development 3g'C,2'/J'Water wash
3 ff 'C17J' bleach constant N
3g'''c, 2'oo'Wash
3g"C,,2'/3' [Processing solution composition] 1st developer: Nitrilo-N,N,N-trimethylenephosphonic acid, pentasodium salt 0.6nodiethelenetriaminepentaacetic acid, pentasodium salt ≠, oy Potassium sulfite 30.09 Potassium thiocyanate
/, Kota potassium carbonate
3J, Op hydroquinone monosulfonate potassium salt, 2J, Of diethylene glycol / j, Oxd/-phenyl-≠-hydroxymethyl-Hiroshi-methyl-3-pyrazolidone -0Q potassium bromide o, jy potassium iodide J, 0~ add water
/fL(p)i, 70) Color developer benzyl alcohol /J, Otl diethylene glycol /co, om3.6-cythia/,za-oftanediol o, ip nitrilo-
N,N,N-trinoterenephosphonic acid pentasodium salt 0. ! p-diethylenetriaminepentaacetic acid, pentasodium salt, Q, sodium sulfite, z, oy, potash carbonate
2J, 09 Hydroxylamine sulfate 3.01 N-ethyl-N-(β-methanesulfonamidoethyl)-3-methyl 1 μm aminoaniline sulfate J, Of potassium bromide o, sp Potassium diiodium
/, add 0 k water
/L(p)i/0,≠O) Bleach-fix solution 2-mercapto-/, 3. μm Triazole i, oy ethylenediaminetetraacetic acid, disodium, trihydrate s, oy ethylenediaminetetraacetic acid, Fe(II), ammonium hydrate 0. Q sodium sulfite /j, 0 sodium tathiosulfate (7001/Jl solution) /60. Or! Add glacial acetic acid J, Oyd water
/A (pHA, JO) From the results in Tables 2 and 2, it can be seen that the present invention has a larger interimage effect than the comparative example. It was also confirmed that other photographic performance did not deteriorate.

(Effects of the Invention) According to the present invention, a good interimage effect is produced, particularly in a reversal color photographic light-sensitive material, and the sharpness of the resulting image is extremely excellent.

Also, during this time, other photographic performance will not be impaired.
The practical benefits are significant.

Claims (1)

[Scope of Claims] In a silver halide color photographic light-sensitive material having at least one silver halide emulsion layer on a support, the silver halide emulsion layer and/or non-photosensitive layer has the following general formula (I
) A silver halide color photographic light-sensitive material containing at least one compound represented by the following. General Formula (I) A-SM In the formula, A represents an atomic group necessary to form a tetrazaindene ring, a triazaindene ring, or a pentazaindene ring. M is a hydrogen atom, an alkali metal atom, an ammonium group,
Or represents a group that is cleaved under alkaline conditions.