JPH01263173A - Ink for marking pen - Google Patents
Ink for marking penInfo
- Publication number
- JPH01263173A JPH01263173A JP63092573A JP9257388A JPH01263173A JP H01263173 A JPH01263173 A JP H01263173A JP 63092573 A JP63092573 A JP 63092573A JP 9257388 A JP9257388 A JP 9257388A JP H01263173 A JPH01263173 A JP H01263173A
- Authority
- JP
- Japan
- Prior art keywords
- ink
- resin
- lecithin
- solvent
- colorant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011347 resin Substances 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000003086 colorant Substances 0.000 claims abstract description 11
- IIZPXYDJLKNOIY-JXPKJXOSSA-N 1-palmitoyl-2-arachidonoyl-sn-glycero-3-phosphocholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCC\C=C/C\C=C/C\C=C/C\C=C/CCCCC IIZPXYDJLKNOIY-JXPKJXOSSA-N 0.000 claims abstract description 10
- 235000010445 lecithin Nutrition 0.000 claims abstract description 10
- 239000000787 lecithin Substances 0.000 claims abstract description 10
- 229940067606 lecithin Drugs 0.000 claims abstract description 10
- 239000000203 mixture Substances 0.000 claims abstract description 10
- 239000003960 organic solvent Substances 0.000 claims abstract description 5
- WTJKGGKOPKCXLL-RRHRGVEJSA-N phosphatidylcholine Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@H](COP([O-])(=O)OCC[N+](C)(C)C)OC(=O)CCCCCCCC=CCCCCCCCC WTJKGGKOPKCXLL-RRHRGVEJSA-N 0.000 claims abstract description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 11
- 239000002904 solvent Substances 0.000 abstract description 8
- 238000001035 drying Methods 0.000 abstract description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract description 4
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 abstract description 2
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 abstract description 2
- 125000000217 alkyl group Chemical group 0.000 abstract description 2
- 235000010985 glycerol esters of wood rosin Nutrition 0.000 abstract description 2
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 abstract description 2
- 150000002576 ketones Chemical class 0.000 abstract 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 15
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- 239000000654 additive Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 6
- XNWFRZJHXBZDAG-UHFFFAOYSA-N 2-METHOXYETHANOL Chemical compound COCCO XNWFRZJHXBZDAG-UHFFFAOYSA-N 0.000 description 4
- ZNQVEEAIQZEUHB-UHFFFAOYSA-N 2-ethoxyethanol Chemical compound CCOCCO ZNQVEEAIQZEUHB-UHFFFAOYSA-N 0.000 description 3
- 230000000996 additive effect Effects 0.000 description 3
- 239000003795 chemical substances by application Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000013040 bath agent Substances 0.000 description 2
- 239000008280 blood Substances 0.000 description 2
- 210000004369 blood Anatomy 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- ZTQSAGDEMFDKMZ-UHFFFAOYSA-N Butyraldehyde Chemical compound CCCC=O ZTQSAGDEMFDKMZ-UHFFFAOYSA-N 0.000 description 1
- 244000241257 Cucumis melo Species 0.000 description 1
- 235000015510 Cucumis melo subsp melo Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 229930194542 Keto Natural products 0.000 description 1
- FJJCIZWZNKZHII-UHFFFAOYSA-N [4,6-bis(cyanoamino)-1,3,5-triazin-2-yl]cyanamide Chemical compound N#CNC1=NC(NC#N)=NC(NC#N)=N1 FJJCIZWZNKZHII-UHFFFAOYSA-N 0.000 description 1
- 150000003862 amino acid derivatives Chemical class 0.000 description 1
- 229910052785 arsenic Inorganic materials 0.000 description 1
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 description 1
- 125000003118 aryl group Chemical group 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 239000003610 charcoal Substances 0.000 description 1
- 230000008094 contradictory effect Effects 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 239000003759 ester based solvent Substances 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- -1 fatty acid ester Chemical class 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 125000000468 ketone group Chemical group 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 239000012860 organic pigment Substances 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- RAPZEAPATHNIPO-UHFFFAOYSA-N risperidone Chemical compound FC1=CC=C2C(C3CCN(CC3)CCC=3C(=O)N4CCCCC4=NC=3C)=NOC2=C1 RAPZEAPATHNIPO-UHFFFAOYSA-N 0.000 description 1
- 230000001953 sensory effect Effects 0.000 description 1
- LXMSZDCAJNLERA-ZHYRCANASA-N spironolactone Chemical compound C([C@@H]1[C@]2(C)CC[C@@H]3[C@@]4(C)CCC(=O)C=C4C[C@H]([C@@H]13)SC(=O)C)C[C@@]21CCC(=O)O1 LXMSZDCAJNLERA-ZHYRCANASA-N 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Abstract
Description
【発明の詳細な説明】
（産業上の利用分野）
本発明はマーキングペン用インキのペン先における乾燥
の抑制に関するものである。DETAILED DESCRIPTION OF THE INVENTION (Field of Industrial Application) The present invention relates to suppressing drying of ink for marking pens at the pen tip.
（従来の技術）
マーキングペン用のインキは繊記面において描線が瞬時
に乾燥することが請求され、そのため揮発性の溶剤が用
いられることが多い。その反面、ペン先においては乾燥
の抑制が求められるという相反する困難な問題が存在す
る。かかる問題を解決するために従来は、例えばポリグ
リセリン脂肪酸エステル等を添加したシ（特公昭６２−
３４３５２号）、アミノ酸誘導体を添加したシ（特開昭
５６−１６６２７７号）、アルキルアミド又はその誘導
体を添加する（特開昭５４−７２１１８号）等の方法が
提案されている。(Prior Art) Inks for marking pens are required to dry lines instantly on the writing surface, and therefore volatile solvents are often used. On the other hand, there is a contradictory and difficult problem in that pen nibs are required to suppress drying. In order to solve this problem, conventionally, for example, polyglycerin fatty acid ester was added (Tokukoku Kokko Sho 62-
34352), adding an amino acid derivative (Japanese Patent Application Laid-Open No. 56-166277), and adding an alkylamide or a derivative thereof (Japanese Patent Application Laid-open No. 72118-1989).
（発明が解決しようとする課題）
本発明はペン先における耐乾燥性にすぐれて、勿論筆記
面における描線の乾燥性や色合等の本来のマーキングペ
ン用インキの性能を損なうことがなく、シかも僅かな世
の添加剤を加えるだけで効果が現れて溶解性の悪い溶剤
を使用した場合でも支障がないマーキングペン用インキ
の提供を目的とする。(Problems to be Solved by the Invention) The present invention has excellent drying resistance at the pen tip, and of course does not impair the original performance of the ink for marking pens, such as the dryness of drawn lines on the writing surface and the color tone. To provide an ink for a marking pen that exhibits an effect just by adding a small amount of ordinary additives and has no trouble even when a solvent with poor solubility is used.
（課題を解決するための手段）
上記目的を達成するために案出した本考案のマーキング
ペン用インキは１着色剤、樹脂及び有機溶剤を含むイン
キ組成物中にレシチン（ホスファチジルコリン）を添加
したことを特徴とするものである。ここでレシチンは次
の一段式％式％
（Ｒ：アルキル基）
で示されるもので、合成レシチンは勿論のこと大豆や卵
黄等から抽出された様々な精製度の天然レシチンが使用
可能であプ、インキ組成物中に０，０１〜５重を俤、好
ましくは０．０５〜ノ重量係の割合で配合する。着色剤
としては一般に油性マーキングペン用インキに用いる油
溶性染料や、有機顔料、加顔料等が使用可能であシ、イ
ンキ組成物中に１〜２５重量係の範囲で配合する。イン
キの粘度調節や筆記面での定着性を得る等の目的で添加
される樹脂としては、ロジン、エステルガム、ケト／樹
脂、フェノール樹脂、セルロース系樹１４１ 、ビニル
系ホリマー等の一般に油性マーキングペン用インキに用
いる樹脂が使用可能であり、インキ組成物中にθ〜３０
劃０の割合で配合する。有機溶剤としては一般的に油性
マーキングペン用インキに用いる低Ｒアルコール、エー
テル、ケトン系溶剤、エステル系溶剤、芳香原炭１ヒ水
素系溶剤等が使用可能であシ、インキ組成物中に４０〜
９８重量％の範囲で添加する。 尚、必要に応じて他
の添加剤を加えることも自由である。(Means for Solving the Problems) In order to achieve the above object, the ink for marking pens of the present invention has the following features: 1. Lecithin (phosphatidylcholine) is added to an ink composition containing a colorant, a resin, and an organic solvent. It is characterized by: Here, lecithin is expressed by the following one-stage formula % (R: alkyl group), and not only synthetic lecithin but also natural lecithin extracted from soybeans, egg yolks, etc. with various degrees of purification can be used. It is blended into the ink composition in an amount of 0.01 to 5 parts by weight, preferably 0.05 to 5 parts by weight. As the coloring agent, oil-soluble dyes generally used in oil-based marking pen inks, organic pigments, pigment additives, etc. can be used, and are blended into the ink composition in an amount of 1 to 25% by weight. Resins added for the purpose of adjusting the viscosity of the ink and achieving fixation on the writing surface are generally oil-based marking pens such as rosin, ester gum, keto/resin, phenolic resin, cellulose resin 141, and vinyl polymer. Resins used for commercial inks can be used, and the ink composition contains θ~30
Mix at a ratio of 0. As the organic solvent, low R alcohols, ethers, ketone solvents, ester solvents, aromatic raw charcoal 1 arsenic solvents, etc., which are generally used in oil-based marking pen inks, can be used. ~
It is added in a range of 98% by weight. Note that other additives may be added as necessary.
（作用）
レシチンは界面活性を有しペン先のインキ表面に吸着さ
れて薄膜を形成するので溶剤の蒸発を防ぎ従ってペン先
の乾燥を抑制する。(Function) Lecithin has surface activity and is adsorbed to the ink surface of the pen tip to form a thin film, thereby preventing evaporation of the solvent and thus suppressing drying of the pen tip.
（実施例） 以下に本発明の実施例の組成を示す。(Example) The compositions of Examples of the present invention are shown below.
第１実施例
着色剤（スピロンイエローＣ２（）Ｈ）−−−−１２，
０（上置Ｓ）樹 脂（ハイラック １）ＯＨ） −−１
０，０溶 剤（エタノール）−一−−−−７０，０（メ
チルセロソルブ）−一一−−−−−２，５（エチルセロ
ソルブ） −−−−−−−−−５，０添加剤（レシチ
ン） −−−−−−−−−０，５第２実施例
着色剤（パリファーストレッド１３０Ｂ）−−１０，０
（重＠％）樹 脂（ロジンＸ ） −−−−−□ Ｉ
Ｏ，０溶 剤（エタノール）−□ ５．０
（メチルセロソルブ）−−Ｓ、Ｏ
（エチルセロソルブ） 、６９．７添
加剤（レジチア）−−ｏ・３
第３実施例
着色剤（カーボンブラック）−−−５，０（血瓜係）樹
脂（デンカフナラール２００ＯＬ）−一−−−６，
０浴 剤（エタノール）□７６．９
（ＩＰＡ）−−−１０，０
（酢酸エチル） −−−−−一″ｓｔ・０添加剤（レシ
チン）−□ 〇、ｌ
（試験結果）
上記の各実施例と比較例について籠記性の官能試験と描
線の乾燥時間を測定した結果を下表に示す。なお比較例
の組成は以下の通りである。1st Example Colorant (Spirone Yellow C2()H)---12,
0 (Upper S) Resin (High Lac 1) OH) --1
0,0 Solvent (ethanol) -1---70,0 (methyl cellosolve) -11---2,5 (ethyl cellosolve)---5,0 Additive (Lecithin) -------0,5 Second Example Colorant (Pali Fast Red 130B) ---10,0
(Weight @%) Resin (Rosin X) ------□ I
O, 0 Solvent (ethanol) - □ 5.0 (Methyl Cellosolve) - - S, O (Ethyl Cellosolve), 69.7 Additive (Resitia) - O.3 3rd Example Colorant (Carbon Black) ---5,0 (blood melon related) resin (Denkafunaral 200OL) -1 ---6,
0 bath agent (ethanol)□76.9 (IPA) ---10,0 (ethyl acetate) ------1"st・0 additive (lecithin) -□ 〇, l (Test results) Each of the above The table below shows the results of a sensory test for marking properties and measurement of the drying time of drawn lines for the Examples and Comparative Examples.The composition of the Comparative Examples is as follows.
第１比較例
着色剤（スピロンイエロー０２０Ｈ） −７２，０（重
板チ）樹 脂（ハイラック！）（Ｊｌｉ）
１０．０溶 剤（エタノール）７０・５
（メチルセロソルブ） −２，５（エチ
ルセロソルブ）−−−−−−−−−−−５，０第２比較
例
着色剤（バリファストレッドｔ３ｏｓ）
ｔ ｏ、ｏ （重機％ ）樹 脂（ロジンＸ）−−−−
ノ０．Ｏ
ｍ 剤（エタノール） −５，０
（メチルセロソルブ）−５，０
（エチルセロソルブ） ７ ｏ、。First Comparative Example Colorant (Spiron Yellow 020H) -72,0 (Juitachi) Resin (Hilac!) (Jli)
10.0 Solvent (ethanol) 70.5 (Methyl Cellosolve) -2,5 (Ethyl Cellosolve) ------------------------5.0 Second Comparative Example Colorant (Varifast Red T3OS)
t o, o (Heavy equipment %) Resin (Rosin X) -----
No 0. O m agent (ethanol) -5,0 (methyl cellosolve) -5,0 (ethyl cellosolve) 7 o,.
第３比較例
着色剤（カーボンブラック）−−Ｓ、Ｏ（血鼠膚）樹
ＷＩ（デンカブチラール２■０Ｌ）−６，。Third Comparative Example Colorant (Carbon Black)--S, O (Blood Rat Skin) Tree
WI (Denka Butyral 2■0L)-6.
解 剤（エタノール） −−□−−７７，０（ＩＰＡ）
−１０，０
（酢酸エチル） ２．Ｌ）試験結
果
（試験条件＝２５℃、６５％、恒温室）Ｍ＆記性の試験
結果において
○は良好
△は普通
Ｘ ｒｉ不良を夫々示す。Plug-in agent (ethanol) --□--77,0 (IPA)
-10,0 (ethyl acetate) 2. L) Test results (Test conditions = 25° C., 65%, constant temperature room) In the test results for M&meability, ◯ indicates good, △ indicates normal X ri, and poor.
（発明の効果）
本発明は上記の試験結果からも明らかなようにキャップ
オ、７ｍかなシの時間が経過しても良好な傘記性を維持
しており、即ちペン先の朗乾に性が極めて同上する。ま
７ｃ描踪乾燥時間についても比較例に比べて劣化するこ
とかなく％１九巴付等も良化することなく本末のインキ
性能を損ねることがない。さらに浴解性の悪い低級アル
コールやエーテル吟の浴剤とともに使用しても文庫がな
いので静剤の制約が収和される半１１点かめる。(Effects of the Invention) As is clear from the above test results, the present invention maintains good writing performance even after a cap-off time of 7 m or more has elapsed, that is, the pen nib remains dry easily. Very same as above. Also, regarding drying time, there is no deterioration compared to the comparative example, and there is no improvement in %1 nine-point adhesion, and there is no deterioration of the final ink performance. Furthermore, even when used with bath agents such as lower alcohols and ether gins, which have poor bath dissolution properties, there are no paperbacks available, so the limitations of static agents can be accommodated.
籍許 出 願人 三菱鉛筆株式会社License applicant: Mitsubishi Pencil Co., Ltd.
Claims (1)
チン（ホスファチジルコリン）を添加したことを特徴と
するマーキングペン用インキ。An ink for a marking pen, characterized in that lecithin (phosphatidylcholine) is added to an ink composition containing a colorant, a resin, and an organic solvent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9257388A JP2594457B2 (en) | 1988-04-14 | 1988-04-14 | Ink for marking pen |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP9257388A JP2594457B2 (en) | 1988-04-14 | 1988-04-14 | Ink for marking pen |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01263173A true JPH01263173A (en) | 1989-10-19 |
| JP2594457B2 JP2594457B2 (en) | 1997-03-26 |
Family
ID=14058171
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP9257388A Expired - Lifetime JP2594457B2 (en) | 1988-04-14 | 1988-04-14 | Ink for marking pen |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2594457B2 (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0739957A1 (en) * | 1995-04-18 | 1996-10-30 | Domino Printing Sciences Plc | Ink-jet printing inks |
| EP0926211A1 (en) * | 1997-12-23 | 1999-06-30 | Pelikan Produktions Ag | Pigmented ink jet ink with improved de-wetting properties |
| JP2002002177A (en) * | 2000-06-16 | 2002-01-08 | Mitsubishi Pencil Co Ltd | Writing implement |
| US6474893B1 (en) | 1998-12-18 | 2002-11-05 | Mitsubishi Pencil Kabushiki Kaisha | Writing instrument having excellent cap-off performance |
| CN104109419A (en) * | 2014-07-21 | 2014-10-22 | 常熟市协新冶金材料有限公司 | Low-temperature-resistant super-lubricating oil based ink for ballpoint pen |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2002205486A (en) | 2000-11-09 | 2002-07-23 | Mitsubishi Pencil Co Ltd | Writing utensil excellent in cap-off performance |
-
1988
- 1988-04-14 JP JP9257388A patent/JP2594457B2/en not_active Expired - Lifetime
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0739957A1 (en) * | 1995-04-18 | 1996-10-30 | Domino Printing Sciences Plc | Ink-jet printing inks |
| EP0926211A1 (en) * | 1997-12-23 | 1999-06-30 | Pelikan Produktions Ag | Pigmented ink jet ink with improved de-wetting properties |
| US6474893B1 (en) | 1998-12-18 | 2002-11-05 | Mitsubishi Pencil Kabushiki Kaisha | Writing instrument having excellent cap-off performance |
| JP2002002177A (en) * | 2000-06-16 | 2002-01-08 | Mitsubishi Pencil Co Ltd | Writing implement |
| US6761496B2 (en) | 2000-06-16 | 2004-07-13 | Mitsubishi Pencil Kabushiki Kaisha | Writing utensil |
| EP1295734A4 (en) * | 2000-06-16 | 2005-02-09 | Mitsubishi Pencil Co | Writing utensil |
| JP4610049B2 (en) * | 2000-06-16 | 2011-01-12 | 三菱鉛筆株式会社 | Writing instrument |
| CN104109419A (en) * | 2014-07-21 | 2014-10-22 | 常熟市协新冶金材料有限公司 | Low-temperature-resistant super-lubricating oil based ink for ballpoint pen |
Also Published As
| Publication number | Publication date |
|---|---|
| JP2594457B2 (en) | 1997-03-26 |
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