JPH01258917A - Method for granulating resin skin - Google Patents
Method for granulating resin skinInfo
- Publication number
- JPH01258917A JPH01258917A JP63087663A JP8766388A JPH01258917A JP H01258917 A JPH01258917 A JP H01258917A JP 63087663 A JP63087663 A JP 63087663A JP 8766388 A JP8766388 A JP 8766388A JP H01258917 A JPH01258917 A JP H01258917A
- Authority
- JP
- Japan
- Prior art keywords
- resin composition
- latex
- liquid resin
- resin
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011347 resin Substances 0.000 title claims abstract description 16
- 229920005989 resin Polymers 0.000 title claims abstract description 16
- 238000000034 method Methods 0.000 title claims abstract description 9
- 239000011342 resin composition Substances 0.000 claims abstract description 31
- 239000004816 latex Substances 0.000 claims abstract description 20
- 229920000126 latex Polymers 0.000 claims abstract description 20
- 238000007711 solidification Methods 0.000 claims abstract description 3
- 230000008023 solidification Effects 0.000 claims abstract description 3
- 239000007788 liquid Substances 0.000 claims description 27
- 239000000839 emulsion Substances 0.000 claims description 12
- 239000000843 powder Substances 0.000 claims description 7
- 239000013618 particulate matter Substances 0.000 claims description 3
- 230000001737 promoting effect Effects 0.000 claims description 2
- 239000007787 solid Substances 0.000 claims 1
- 229920001971 elastomer Polymers 0.000 abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 10
- 239000011248 coating agent Substances 0.000 abstract description 8
- 238000000576 coating method Methods 0.000 abstract description 8
- 150000003839 salts Chemical class 0.000 abstract description 8
- 239000000203 mixture Substances 0.000 abstract description 4
- 239000008187 granular material Substances 0.000 abstract 1
- 235000002639 sodium chloride Nutrition 0.000 description 9
- 239000000047 product Substances 0.000 description 8
- 210000003491 skin Anatomy 0.000 description 7
- 239000002245 particle Substances 0.000 description 5
- MUBZPKHOEPUJKR-UHFFFAOYSA-N Oxalic acid Chemical compound OC(=O)C(O)=O MUBZPKHOEPUJKR-UHFFFAOYSA-N 0.000 description 3
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 238000005406 washing Methods 0.000 description 3
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- ZCCIPPOKBCJFDN-UHFFFAOYSA-N calcium nitrate Chemical compound [Ca+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O ZCCIPPOKBCJFDN-UHFFFAOYSA-N 0.000 description 2
- 239000011265 semifinished product Substances 0.000 description 2
- 239000011780 sodium chloride Substances 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- DIZPMCHEQGEION-UHFFFAOYSA-H aluminium sulfate (anhydrous) Chemical compound [Al+3].[Al+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O DIZPMCHEQGEION-UHFFFAOYSA-H 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 1
- 239000004327 boric acid Substances 0.000 description 1
- 235000010338 boric acid Nutrition 0.000 description 1
- 239000004067 bulking agent Substances 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000003946 cyclohexylamines Chemical class 0.000 description 1
- 238000007598 dipping method Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 210000002615 epidermis Anatomy 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 235000006408 oxalic acid Nutrition 0.000 description 1
- 230000002093 peripheral effect Effects 0.000 description 1
- 239000001103 potassium chloride Substances 0.000 description 1
- 235000011164 potassium chloride Nutrition 0.000 description 1
- -1 salt zinc sulfate Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000004552 water soluble powder Substances 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C41/00—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor
- B29C41/02—Shaping by coating a mould, core or other substrate, i.e. by depositing material and stripping-off the shaped article; Apparatus therefor for making articles of definite length, i.e. discrete articles
- B29C41/14—Dipping a core
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C59/00—Surface shaping of articles, e.g. embossing; Apparatus therefor
- B29C59/02—Surface shaping of articles, e.g. embossing; Apparatus therefor by mechanical means, e.g. pressing
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/48—Wearing apparel
- B29L2031/4842—Outerwear
- B29L2031/4864—Gloves
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Moulding By Coating Moulds (AREA)
- Shaping Of Tube Ends By Bending Or Straightening (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、ゴム手袋、ゴム風船、ゴム引布地等の液状樹
脂組成物で構成される製品乃至半製品の表皮に凹凸を形
成する方法に関するものである。Detailed Description of the Invention [Field of Industrial Application] The present invention relates to a method for forming irregularities on the skin of products or semi-finished products made of liquid resin compositions such as rubber gloves, rubber balloons, and rubberized fabrics. It is something.
従来、エマルジョンラテックス、ベーストレジン、樹脂
溶解溶液等の液状樹脂組成物により表面が構成される製
品乃至半製品（以下、単に製品と言う、）の表面に凹凸
を形成する場合には、その所要の凹凸を表面に形成した
形枠や金型等の形材に液状樹脂組成物を塗工或は注入し
て固化させ、その形材を取り外して凹凸を転写する方法
、半固化状態にある液状樹脂組成物に形材を押圧して凹
凸を転写する方法、発泡した液状樹脂組成物の気泡痕に
よって凹凸を形成する方法等が採られる。Conventionally, when forming irregularities on the surface of a product or semi-finished product (hereinafter simply referred to as a product) whose surface is made of a liquid resin composition such as emulsion latex, base resin, or resin solution, it is necessary to A method of coating or injecting a liquid resin composition onto a shaped material such as a frame or mold that has unevenness formed on its surface and solidifying it, and then removing the shaped material and transferring the unevenness, a liquid resin in a semi-solidified state A method of transferring the unevenness by pressing a shape onto the composition, a method of forming the unevenness using bubble traces of a foamed liquid resin composition, etc. are adopted.
前記転写法では、液状樹脂組成物が固化して出来た製品
から形材を剥離しなければならないので、形材′の剥離
し得ない奥まった箇所に凹凸を付けることは出来ず、又
、凹部の谷間が谷底に向けて拡がるような四部の形際が
鋭利な凹凸の形成は困難である。In the above-mentioned transfer method, since the shape must be peeled off from the product made by solidifying the liquid resin composition, it is not possible to create irregularities in the recessed parts of the shape that cannot be peeled off, and it is not possible to create irregularities in the deep parts of the shape that cannot be peeled off. It is difficult to form concavities and convexities with sharp edges on the four parts, such that the valleys widen toward the bottom of the valley.
一方、気泡痕による場合には、気泡が液状樹脂組成物の
内部にも出来、従って気泡痕は奥深く連続し、非通気性
非透水性の表皮は形成されない。On the other hand, in the case of bubble traces, the bubbles are also formed inside the liquid resin composition, so the bubble traces are deep and continuous, and an air-impermeable and water-impermeable skin is not formed.
（発明の目的〕
そこで本発明は、液状樹脂組成物で構成される製品の奥
まった箇所の表皮にも深く細かい凹凸を付け、且つ、そ
の表皮を非通気性非透水性のものにすることを目的とす
る。(Purpose of the Invention) Therefore, the present invention aims to create deep and fine irregularities on the skin of a product made of a liquid resin composition in deep areas, and to make the skin impermeable and non-water permeable. purpose.
即ち本発明は、製品の表面となる未固化状態の液状樹脂
組成物の表面に、その固化した樹脂組成物の熔解しない
溶液に熔ける粉粒物を付着させてから、その液状樹脂組
成物を固化することにより、その樹脂組成物の形成する
表皮に凹凸を付けることを特徴とする。That is, in the present invention, particles that are soluble in an undissolved solution of the solidified resin composition are attached to the surface of an unsolidified liquid resin composition, which is the surface of a product, and then the liquid resin composition is solidified. By doing so, the epidermis formed by the resin composition is characterized by being uneven.
表皮は、所要の製品を象った金型（形材）に液状樹脂組
成物溶液に浸漬・引き揚げ、金型の表面に液状樹脂組成
物溶液を垂れ流し或は吹き付ける等して形成される。The skin is formed by dipping a mold (shaped material) shaped like the desired product into a liquid resin composition solution, pulling it out, and pouring or spraying the liquid resin composition solution onto the surface of the mold.
液状樹脂組成物としてはエマルジョンラテックス、ペー
ストレジン、樹脂溶解溶液等が通用され、そのエマルジ
ョンラテックスの場合を例にとって具体的に説明するに
、ゲル化乃至乾燥せずに未固化状態にあるエマルジョン
ラテックスの表面に、塩や糖の如く水溶性の粉粒物を付
着させ、好ましくは、塩の如くエマルジョンラテックス
のゲル化を促すものを使用する。Emulsion latex, paste resin, resin solution solution, etc. are commonly used as liquid resin compositions.To specifically explain the case of emulsion latex as an example, emulsion latex in an unsolidified state without gelling or drying. A water-soluble powder such as salt or sugar is attached to the surface, preferably a substance that promotes gelation of the emulsion latex such as salt is used.
エマルジョンラテックスのゲル化を促す水溶性の粉粒物
を具体的に例示するに、塩化ナトリウム、硫酸バンド、
塩化カルシウム、硝酸カルシウム、ケイフッ化ナトリウ
ム、硫酸アルミニウム、第二鉄塩硫酸亜鉛、塩化カリウ
ム、蓚酸、硼酸、シクロヘキシルアミン塩等があり、粉
粒物はこれらを増量剤に配合してそれを一部に含有する
ものであってもよい。Specific examples of water-soluble powders that promote gelation of emulsion latex include sodium chloride, sulfuric acid,
Calcium chloride, calcium nitrate, sodium silicofluoride, aluminum sulfate, ferric salt zinc sulfate, potassium chloride, oxalic acid, boric acid, cyclohexylamine salt, etc., and part of the powder is mixed with a bulking agent. It may contain.
これらの粉粒物は、液状樹脂組成物の皮膜が固化してか
ら水洗除去されるや
〔発明の効果〕
本発明によると、未固化状態の液状樹脂組成物の表面に
粉粒物を付着させると、それらの粉粒物が液状樹脂組成
物の中に食い込み、その液状樹脂組成物が固化してから
、樹脂組成物の溶解しない溶液、例えばエマルジョンラ
テックスの樹脂皮膜に対しては水を用いて塩や糖の粉粒
物を洗浄除去するとき、それらの粉粒物の食い込んだ付
着痕としての凹部が、粉粒物の形状に応じて細かく樹脂
表皮に形成される。These particulate matter are removed by washing with water after the film of the liquid resin composition solidifies. [Effect of the Invention] According to the present invention, the particulate matter is attached to the surface of the liquid resin composition in an unsolidified state. Then, these powder particles bite into the liquid resin composition, and after the liquid resin composition solidifies, water is used to remove the solution in which the resin composition does not dissolve, for example, the resin film of emulsion latex. When salt or sugar powder is removed by washing, fine recesses are formed in the resin skin according to the shape of the powder and the particles are stuck there.
そして特に、塩の如く潮解性とゲル化促進機能を有する
ものでは、エマルジョンラテックス中の水分を吸収する
様に液状樹脂組成物の表面に食い込んで溶解し、そこに
水滴の如き粒状溶液として細かく介在し、その接する周
囲の液状樹脂組成物を他の部分に先がけて固化し、その
後、液状樹脂組成物全体が固化するとき、その粉粒物が
角張ったものであっても、その食い込んだ塩の痕跡は半
球形の綺麗な凹部となる。In particular, salts that have deliquescent properties and gelation promoting functions penetrate into the surface of the liquid resin composition and dissolve, absorbing the water in the emulsion latex, intervening finely as particulate solutions such as water droplets. However, when the surrounding liquid resin composition in contact with the liquid resin composition is solidified before other parts, and then the entire liquid resin composition is solidified, even if the powder particles are angular, the salt that has eaten away will be removed. The trace becomes a beautiful hemispherical depression.
それと共に、それが付着すると同時に周囲の固化を促す
から液状樹脂組成物の内部へと余り深くは食い込まず、
従って内部は液状樹脂組成物だけの層となるから、凹凸
を有するも非通気性非透水性の表皮が形成され、表面が
滑り難い製品が得られる。At the same time, as it adheres, it also promotes solidification of the surrounding area, so it does not penetrate too deeply into the liquid resin composition.
Therefore, since the inside is a layer made only of the liquid resin composition, a non-air permeable and non-water permeable skin is formed, although it has irregularities, and a product with a non-slip surface can be obtained.
液状樹脂組成物を次の通り調製した。 A liquid resin composition was prepared as follows.
ＳＤＲラテックス（樹脂分６０％）・・・１００．０重
量部老化防止剤（パーマナフクスＷＳＯ、
バルナフクス社）・・・・・・・・・・・・ＬＯ重量部
アニオン界面活性剤・・・・・・・・・・・・・・・・
・・・・・・・・・・・０．５ｉ［部消泡剤（テヒドラ
ン１２２７、ヘンケル社）０．４ｆｉｉ！上記の組成の
ラテックス組成物中にゴム手袋金型を浸漬し取り上げて
金型の表面にラテックス組 −酸物の塗膜１）を形
成し、その未固化状態のラテックス塗膜１）の上に、粒
径３０メツシユの食ＰＡ１２を散布付着させ、そのまま
１２０℃にて４０分間加熱して塗膜１）を加硫し、その
後食塩を水洗除去した。SDR latex (resin content 60%)...100.0 parts by weight Anti-aging agent (Permanafux WSO, Barnafukus)...LO parts by weight anionic surfactant...・・・・・・・・・・・・
・・・・・・・・・・・・0.5i [part antifoaming agent (Tehydran 1227, Henkel) 0.4fii! A rubber glove mold is immersed in the latex composition having the above composition and taken up to form a coating film 1) of the latex compound-acid on the surface of the mold, and then on the unsolidified latex coating film 1). , edible PA12 having a particle size of 30 mesh was applied by spraying and heated as it was at 120° C. for 40 minutes to vulcanize the coating film 1), and then the common salt was removed by washing with water.
その結果、表面に細かい凹凸１３があり非通気性非透水
性ゴム皮膜１）によるゴム手袋を得た。As a result, a rubber glove with a non-breathable and non-water permeable rubber film 1) having fine irregularities 13 on the surface was obtained.
この凹凸の凹部１３は、■−につき約２５６（ｌｌＪの
割合で形成されており、その周縁１４が環状に僅かに隆
起し、孔径は約０．４８ ｓｍであり、深さが約０゜１
２ｍｍで、半球状の窪んでおり、その谷底でのゴム皮膜
１）の厚みは約０．１８鶴で、ゴム手袋全体でのゴム皮
膜の厚みは約０．３鰭であった。This uneven concave portion 13 is formed at a ratio of approximately 256 (llJ) per ■-, its peripheral edge 14 is slightly raised in an annular shape, the hole diameter is approximately 0.48 sm, and the depth is approximately 0°1.
The thickness of the rubber film 1) at the bottom of the groove was about 0.18 mm, and the thickness of the rubber film as a whole was about 0.3 mm.
第１図は本発明により得られたゴム手袋のゴム皮膜の拡
大断面図である。
１）・・・皮膜、１２・・・食塩、１３・・・凹部、１
４・・・周縁。FIG. 1 is an enlarged sectional view of a rubber film of a rubber glove obtained according to the present invention. 1)...film, 12...salt, 13...recess, 1
4...Periphery.
Claims (2)
固化した樹脂組成物の溶解しない溶液に溶ける粉粒物を
付着させてから、その液状樹脂組成物を固化することを
特徴とする樹脂表皮への凹凸付形法。(1) The liquid resin composition is characterized by adhering to the surface of the unsolidified liquid resin composition a particulate matter that is soluble in a solution that does not dissolve the solidified resin composition, and then solidifying the liquid resin composition. A method for creating unevenness on resin skin.
表面に、その樹脂エマルジョンラテックスの固化を促す
性質を有する水溶性の固体粉粒物を付着させて後、樹脂
エマルジョンラテックスを固化せしめることを特徴とす
るエマルジョンラテックス樹脂表皮への凹凸付形法。(2) A water-soluble solid powder having a property of promoting solidification of the resin emulsion latex is attached to the surface of the resin emulsion latex in an unsolidified state, and then the resin emulsion latex is solidified. A method for forming irregularities on the emulsion latex resin skin.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63087663A JP2639415B2 (en) | 1988-04-09 | 1988-04-09 | Concavo-convex forming method for resin skin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63087663A JP2639415B2 (en) | 1988-04-09 | 1988-04-09 | Concavo-convex forming method for resin skin |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01258917A true JPH01258917A (en) | 1989-10-16 |
| JP2639415B2 JP2639415B2 (en) | 1997-08-13 |
Family
ID=13921190
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63087663A Expired - Lifetime JP2639415B2 (en) | 1988-04-09 | 1988-04-09 | Concavo-convex forming method for resin skin |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2639415B2 (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001077210A3 (en) * | 2000-04-11 | 2002-02-21 | Apex Medical Tech | Vulcanization of dip-molded rubber articles with molten media baths |
| WO2005002375A1 (en) * | 2003-07-02 | 2005-01-13 | Ansell Healthcare Products Llc | Textured surface coating for gloves and method of making |
| WO2006075980A1 (en) * | 2005-01-12 | 2006-07-20 | Ansell Healthcare Products Llc | Latex gloves and articles with geometrically defined surface texture providing enhanced grip and method for in-line processing thereof |
| WO2008123356A1 (en) * | 2007-03-30 | 2008-10-16 | Towa Corporation Ltd. | Process for formation of resin surface, process for production of articles having recesses different in size on the surface, such articles, process for production of gloves, and gloves |
| JP2012197358A (en) * | 2011-03-22 | 2012-10-18 | Denso Corp | Bonded article and method of manufacturing the same |
| CN105778357A (en) * | 2016-05-17 | 2016-07-20 | 江苏杰盛手套有限公司 | Point contact-type air permeable PVC gloves and preparation method thereof |
| US9695292B2 (en) | 2013-11-26 | 2017-07-04 | Ansell Limited | Effervescent texturing |
| US10292440B2 (en) | 2015-03-10 | 2019-05-21 | Ansell Limited | Supported glove having an abrasion resistant nitrile coating |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4795477B1 (en) * | 2010-04-28 | 2011-10-19 | ショーワグローブ株式会社 | Non-slip gloves and manufacturing method thereof |
-
1988
- 1988-04-09 JP JP63087663A patent/JP2639415B2/en not_active Expired - Lifetime
Cited By (22)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2001077210A3 (en) * | 2000-04-11 | 2002-02-21 | Apex Medical Tech | Vulcanization of dip-molded rubber articles with molten media baths |
| US6569375B1 (en) | 2000-04-11 | 2003-05-27 | Apex Medical Technologies, Inc. | Vulcanization of dip-molded rubber articles with molten media baths |
| AU2001253207B2 (en) * | 2000-04-11 | 2004-09-09 | O&M Halyard International Unlimited Company | Vulcanization of dip-molded rubber articles with molten media baths |
| AU2004253557B2 (en) * | 2003-07-02 | 2009-05-07 | Ansell Healthcare Products Llc | Textured surface coating for gloves and method of making |
| EP1638423A4 (en) * | 2003-07-02 | 2009-03-11 | Ansell Healthcare Prod Llc | Textured surface coating for gloves and method of making |
| EP2404730A3 (en) * | 2003-07-02 | 2012-02-22 | Ansell Healthcare Products Inc. | Glove having a textured surface |
| WO2005002375A1 (en) * | 2003-07-02 | 2005-01-13 | Ansell Healthcare Products Llc | Textured surface coating for gloves and method of making |
| US7771644B2 (en) * | 2003-07-02 | 2010-08-10 | Ansell Healthcare Products Llc | Textured surface coating for gloves and method of making |
| WO2006075980A1 (en) * | 2005-01-12 | 2006-07-20 | Ansell Healthcare Products Llc | Latex gloves and articles with geometrically defined surface texture providing enhanced grip and method for in-line processing thereof |
| US7378043B2 (en) | 2005-01-12 | 2008-05-27 | Ansell Healthcare Products Llc | Latex gloves and articles with geometrically defined surface texture providing enhanced grip and method for in-line processing thereof |
| EP2932861A1 (en) | 2005-01-12 | 2015-10-21 | Ansell Healthcare Products LLC | Method of making latex gloves |
| US8522363B2 (en) | 2005-01-12 | 2013-09-03 | Ansell Healthcare Products Llc | Latex gloves and articles with geometrically defined surface texture providing enhanced grip and method for in-line processing thereof |
| US7814570B2 (en) | 2005-01-12 | 2010-10-19 | Ansell Healthcare Products Llc | Latex gloves and articles with geometrically defined surface texture providing enhanced grip method for in-line processing thereof |
| EP2409586A1 (en) | 2005-01-12 | 2012-01-25 | Ansell Healthcare Products LLC | Latex gloves and articles with geometrically defined surface texture providing enhanced grip |
| JP4331782B2 (en) * | 2007-03-30 | 2009-09-16 | 株式会社東和コーポレーション | Method for forming resin surface, method for manufacturing article having concave portions of different sizes on the surface, article, method for manufacturing glove, and glove |
| US8387167B2 (en) | 2007-03-30 | 2013-03-05 | Towa Corporation Ltd. | Method for forming resin surface, method for manufacturing article which forms recessed portions different in size randomly on surface thereof and article manufactured by the method, and method for manufacturing gloves and gloves manufactured by the method |
| JP2008274521A (en) * | 2007-03-30 | 2008-11-13 | Towa Corp:Kk | Process for forming resin surface, process for producing article having mixture of recessed parts different in size in surface, this article, process for producing glove, and glove |
| WO2008123356A1 (en) * | 2007-03-30 | 2008-10-16 | Towa Corporation Ltd. | Process for formation of resin surface, process for production of articles having recesses different in size on the surface, such articles, process for production of gloves, and gloves |
| JP2012197358A (en) * | 2011-03-22 | 2012-10-18 | Denso Corp | Bonded article and method of manufacturing the same |
| US9695292B2 (en) | 2013-11-26 | 2017-07-04 | Ansell Limited | Effervescent texturing |
| US10292440B2 (en) | 2015-03-10 | 2019-05-21 | Ansell Limited | Supported glove having an abrasion resistant nitrile coating |
| CN105778357A (en) * | 2016-05-17 | 2016-07-20 | 江苏杰盛手套有限公司 | Point contact-type air permeable PVC gloves and preparation method thereof |
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|---|---|
| JP2639415B2 (en) | 1997-08-13 |
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