JPH01256553A - Fog-preventing agricultural covering material - Google Patents
Fog-preventing agricultural covering materialInfo
- Publication number
- JPH01256553A JPH01256553A JP63083696A JP8369688A JPH01256553A JP H01256553 A JPH01256553 A JP H01256553A JP 63083696 A JP63083696 A JP 63083696A JP 8369688 A JP8369688 A JP 8369688A JP H01256553 A JPH01256553 A JP H01256553A
- Authority
- JP
- Japan
- Prior art keywords
- weight
- parts
- vinyl chloride
- fog
- group
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000463 material Substances 0.000 title claims abstract description 18
- 229920005989 resin Polymers 0.000 claims abstract description 18
- 239000011347 resin Substances 0.000 claims abstract description 18
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 claims abstract description 17
- 229910019142 PO4 Inorganic materials 0.000 claims abstract description 16
- 229910052751 metal Inorganic materials 0.000 claims abstract description 16
- 239000002184 metal Substances 0.000 claims abstract description 16
- 239000010452 phosphate Substances 0.000 claims abstract description 16
- 150000001875 compounds Chemical class 0.000 claims abstract description 13
- 150000003839 salts Chemical class 0.000 claims abstract description 13
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 6
- 150000001450 anions Chemical class 0.000 claims abstract description 5
- -1 alcohol phosphate ester Chemical class 0.000 claims description 19
- 229910052731 fluorine Inorganic materials 0.000 claims description 15
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims description 14
- 239000011737 fluorine Substances 0.000 claims description 14
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- 229910021645 metal ion Inorganic materials 0.000 claims description 2
- 239000000126 substance Substances 0.000 claims 2
- KZMAWJRXKGLWGS-UHFFFAOYSA-N 2-chloro-n-[4-(4-methoxyphenyl)-1,3-thiazol-2-yl]-n-(3-methoxypropyl)acetamide Chemical compound S1C(N(C(=O)CCl)CCCOC)=NC(C=2C=CC(OC)=CC=2)=C1 KZMAWJRXKGLWGS-UHFFFAOYSA-N 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 abstract description 10
- 238000002834 transmittance Methods 0.000 abstract description 9
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 8
- 238000002845 discoloration Methods 0.000 abstract description 7
- GDVKFRBCXAPAQJ-UHFFFAOYSA-A dialuminum;hexamagnesium;carbonate;hexadecahydroxide Chemical compound [OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[OH-].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Mg+2].[Al+3].[Al+3].[O-]C([O-])=O GDVKFRBCXAPAQJ-UHFFFAOYSA-A 0.000 abstract description 5
- 229960001545 hydrotalcite Drugs 0.000 abstract description 5
- 229910001701 hydrotalcite Inorganic materials 0.000 abstract description 5
- 239000000203 mixture Substances 0.000 abstract description 5
- 150000002222 fluorine compounds Chemical class 0.000 abstract description 3
- 238000006116 polymerization reaction Methods 0.000 abstract description 2
- 239000011342 resin composition Substances 0.000 abstract 2
- 230000015556 catabolic process Effects 0.000 abstract 1
- 238000006731 degradation reaction Methods 0.000 abstract 1
- 125000000524 functional group Chemical group 0.000 abstract 1
- 230000002265 prevention Effects 0.000 abstract 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 14
- 239000000194 fatty acid Substances 0.000 description 14
- 229930195729 fatty acid Natural products 0.000 description 14
- 239000004014 plasticizer Substances 0.000 description 11
- 150000002148 esters Chemical class 0.000 description 8
- 239000011248 coating agent Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 239000002253 acid Substances 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 5
- 244000061458 Solanum melongena Species 0.000 description 5
- 235000002597 Solanum melongena Nutrition 0.000 description 5
- 229940105990 diglycerin Drugs 0.000 description 5
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 4
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerol Natural products OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 241000220223 Fragaria Species 0.000 description 3
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 3
- 239000006096 absorbing agent Substances 0.000 description 3
- 238000004040 coloring Methods 0.000 description 3
- 230000007423 decrease Effects 0.000 description 3
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 3
- 235000011187 glycerol Nutrition 0.000 description 3
- 239000002736 nonionic surfactant Substances 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- 239000003921 oil Substances 0.000 description 3
- 235000019198 oils Nutrition 0.000 description 3
- 229950011392 sorbitan stearate Drugs 0.000 description 3
- 235000021012 strawberries Nutrition 0.000 description 3
- UHGGERUQGSJHKR-VCDGYCQFSA-N (2r,3r,4r,5s)-hexane-1,2,3,4,5,6-hexol;octadecanoic acid Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.CCCCCCCCCCCCCCCCCC(O)=O UHGGERUQGSJHKR-VCDGYCQFSA-N 0.000 description 2
- IRIAEXORFWYRCZ-UHFFFAOYSA-N Butylbenzyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCC1=CC=CC=C1 IRIAEXORFWYRCZ-UHFFFAOYSA-N 0.000 description 2
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Chemical compound CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 2
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 2
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 2
- HPEUJPJOZXNMSJ-UHFFFAOYSA-N Methyl stearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC HPEUJPJOZXNMSJ-UHFFFAOYSA-N 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- 150000007513 acids Chemical class 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 230000006866 deterioration Effects 0.000 description 2
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 2
- PUFGCEQWYLJYNJ-UHFFFAOYSA-N didodecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCC PUFGCEQWYLJYNJ-UHFFFAOYSA-N 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000000944 linseed oil Substances 0.000 description 2
- 235000021388 linseed oil Nutrition 0.000 description 2
- 229950003429 sorbitan palmitate Drugs 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- IMYZYCNQZDBZBQ-UHFFFAOYSA-N (+-)-8-(cis-3-octyl-oxiranyl)-octanoic acid Natural products CCCCCCCCC1OC1CCCCCCCC(O)=O IMYZYCNQZDBZBQ-UHFFFAOYSA-N 0.000 description 1
- INKXYFUMUBZQKV-UHFFFAOYSA-N (2,3,4-triethylphenyl) dihydrogen phosphate Chemical compound CCC1=CC=C(OP(O)(O)=O)C(CC)=C1CC INKXYFUMUBZQKV-UHFFFAOYSA-N 0.000 description 1
- XMNDMAQKWSQVOV-UHFFFAOYSA-N (2-methylphenyl) diphenyl phosphate Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C=CC=CC=1)OC1=CC=CC=C1 XMNDMAQKWSQVOV-UHFFFAOYSA-N 0.000 description 1
- OUPZKGBUJRBPGC-UHFFFAOYSA-N 1,3,5-tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione Chemical compound O=C1N(CC2OC2)C(=O)N(CC2OC2)C(=O)N1CC1CO1 OUPZKGBUJRBPGC-UHFFFAOYSA-N 0.000 description 1
- YEVQZPWSVWZAOB-UHFFFAOYSA-N 2-(bromomethyl)-1-iodo-4-(trifluoromethyl)benzene Chemical compound FC(F)(F)C1=CC=C(I)C(CBr)=C1 YEVQZPWSVWZAOB-UHFFFAOYSA-N 0.000 description 1
- PUYRISKXBBQECH-UHFFFAOYSA-N 2-ethylhexyl 8-(3-octyloxiran-2-yl)octanoate Chemical compound CCCCCCCCC1OC1CCCCCCCC(=O)OCC(CC)CCCC PUYRISKXBBQECH-UHFFFAOYSA-N 0.000 description 1
- SIXWIUJQBBANGK-UHFFFAOYSA-N 4-(4-fluorophenyl)-1h-pyrazol-5-amine Chemical compound N1N=CC(C=2C=CC(F)=CC=2)=C1N SIXWIUJQBBANGK-UHFFFAOYSA-N 0.000 description 1
- 101150004523 BCO1 gene Proteins 0.000 description 1
- LCFVJGUPQDGYKZ-UHFFFAOYSA-N Bisphenol A diglycidyl ether Chemical compound C=1C=C(OCC2OC2)C=CC=1C(C)(C)C(C=C1)=CC=C1OCC1CO1 LCFVJGUPQDGYKZ-UHFFFAOYSA-N 0.000 description 1
- 101100283604 Caenorhabditis elegans pigk-1 gene Proteins 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 239000004803 Di-2ethylhexylphthalate Substances 0.000 description 1
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 1
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 1
- CGBXSWXZXBQCMR-UHFFFAOYSA-N Glycerol 1-hexadecanoate Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCC(O)=O CGBXSWXZXBQCMR-UHFFFAOYSA-N 0.000 description 1
- 229920001774 Perfluoroether Polymers 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 229910020489 SiO3 Inorganic materials 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 1
- ULBTUVJTXULMLP-UHFFFAOYSA-N butyl octadecanoate Chemical group CCCCCCCCCCCCCCCCCC(=O)OCCCC ULBTUVJTXULMLP-UHFFFAOYSA-N 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 125000004432 carbon atom Chemical group C* 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000009833 condensation Methods 0.000 description 1
- 230000005494 condensation Effects 0.000 description 1
- IFHYJYRDPZBMSV-UHFFFAOYSA-N decanedioic acid;hexadecanoic acid Chemical compound OC(=O)CCCCCCCCC(O)=O.CCCCCCCCCCCCCCCC(O)=O IFHYJYRDPZBMSV-UHFFFAOYSA-N 0.000 description 1
- HBGGXOJOCNVPFY-UHFFFAOYSA-N diisononyl phthalate Chemical compound CC(C)CCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC(C)C HBGGXOJOCNVPFY-UHFFFAOYSA-N 0.000 description 1
- DROMNWUQASBTFM-UHFFFAOYSA-N dinonyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCC DROMNWUQASBTFM-UHFFFAOYSA-N 0.000 description 1
- YCZJVRCZIPDYHH-UHFFFAOYSA-N ditridecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCCCC YCZJVRCZIPDYHH-UHFFFAOYSA-N 0.000 description 1
- CAMHHLOGFDZBBG-UHFFFAOYSA-N epoxidized methyl oleate Natural products CCCCCCCCC1OC1CCCCCCCC(=O)OC CAMHHLOGFDZBBG-UHFFFAOYSA-N 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- IPCSVZSSVZVIGE-UHFFFAOYSA-M hexadecanoate Chemical compound CCCCCCCCCCCCCCCC([O-])=O IPCSVZSSVZVIGE-UHFFFAOYSA-M 0.000 description 1
- VNPHWWLTEQUELD-UHFFFAOYSA-N hexadecanoic acid;hexanedioic acid Chemical compound OC(=O)CCCCC(O)=O.CCCCCCCCCCCCCCCC(O)=O VNPHWWLTEQUELD-UHFFFAOYSA-N 0.000 description 1
- 229920001519 homopolymer Polymers 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- QUAMTGJKVDWJEQ-UHFFFAOYSA-N octabenzone Chemical compound OC1=CC(OCCCCCCCC)=CC=C1C(=O)C1=CC=CC=C1 QUAMTGJKVDWJEQ-UHFFFAOYSA-N 0.000 description 1
- CKQVRZJOMJRTOY-UHFFFAOYSA-N octadecanoic acid;propane-1,2,3-triol Chemical compound OCC(O)CO.CCCCCCCCCCCCCCCCCC(O)=O CKQVRZJOMJRTOY-UHFFFAOYSA-N 0.000 description 1
- YAFOVCNAQTZDQB-UHFFFAOYSA-N octyl diphenyl phosphate Chemical compound C=1C=CC=CC=1OP(=O)(OCCCCCCCC)OC1=CC=CC=C1 YAFOVCNAQTZDQB-UHFFFAOYSA-N 0.000 description 1
- 125000006551 perfluoro alkylene group Chemical group 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- JQCXWCOOWVGKMT-UHFFFAOYSA-N phthalic acid diheptyl ester Natural products CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCC JQCXWCOOWVGKMT-UHFFFAOYSA-N 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920000151 polyglycol Polymers 0.000 description 1
- 239000010695 polyglycol Substances 0.000 description 1
- XFTALRAZSCGSKN-UHFFFAOYSA-M sodium;4-ethenylbenzenesulfonate Chemical compound [Na+].[O-]S(=O)(=O)C1=CC=C(C=C)C=C1 XFTALRAZSCGSKN-UHFFFAOYSA-M 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 241000894007 species Species 0.000 description 1
- 230000003595 spectral effect Effects 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 230000000087 stabilizing effect Effects 0.000 description 1
- 125000004079 stearyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- XZZNDPSIHUTMOC-UHFFFAOYSA-N triphenyl phosphate Chemical compound C=1C=CC=CC=1OP(OC=1C=CC=CC=1)(=O)OC1=CC=CC=C1 XZZNDPSIHUTMOC-UHFFFAOYSA-N 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 229920002554 vinyl polymer Polymers 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A40/00—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
- Y02A40/10—Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
- Y02A40/25—Greenhouse technology, e.g. cooling systems therefor
Landscapes
- Greenhouses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は農業用のトンネル、簡易温室（ハウス）等の被
覆用として用いられる農業用被覆材に関する。DETAILED DESCRIPTION OF THE INVENTION [Field of Industrial Application] The present invention relates to an agricultural covering material used for covering agricultural tunnels, simple greenhouses, etc.
〔従来の技術及び 。[Prior art and]
発明が解決しようとする課題〕
農業用のトンネル、簡易温室等の被覆材として安価で透
明性が良く保温性、強度等に優れることから塩化ビニル
系樹脂フィルム又はシートが広く用いられているが、塩
化ビニル樹脂は耐候性に問題があり、太陽光線によって
物性が劣化して透明度が低下したり、強度が低下してハ
ウス等のフレームと接触した部分に穴があき易くなる等
の欠点がある。このため従来は耐候性向上のために樹脂
に紫外線吸収剤を添加しているが、紫外線吸収剤を添加
すると紫外線の透過量が少なくなることに起因してナス
、苺等や花等の色付きが悪くなるという大きな問題があ
った。[Problems to be Solved by the Invention] Vinyl chloride resin films or sheets are widely used as covering materials for agricultural tunnels, simple greenhouses, etc. because they are inexpensive, transparent, and have excellent heat retention and strength. Vinyl chloride resin has problems with weather resistance, and its physical properties deteriorate due to sunlight, resulting in a decrease in transparency, and its strength decreases, making it more likely to form holes where it comes into contact with the frame of a house or the like. For this reason, conventionally, ultraviolet absorbers are added to resins to improve weather resistance, but adding ultraviolet absorbers reduces the amount of ultraviolet rays transmitted, resulting in color discoloration of eggplants, strawberries, etc., and flowers. The big problem was that it was getting worse.
一方、ナスの色付きを良くするために３５０ｎｍの波長
の紫外線の透過率を７０％以上としたナス栽培用フィル
ムも提案されている（特公昭６〇−２８８６０号）。し
かしながら従来は紫外線透過率を向上させるためには耐
候性を犠牲にしなければならず、優れた紫外線透過性と
、優れた耐候性とを同時に備えた防霧性農業用被覆材の
開発が望まれていた。On the other hand, an eggplant cultivation film with a transmittance of 70% or more for ultraviolet light having a wavelength of 350 nm has been proposed in order to improve the coloring of eggplants (Japanese Patent Publication No. 60-28860). However, conventionally, weather resistance had to be sacrificed in order to improve UV transmittance, and it is desired to develop fog-proof agricultural covering materials that have both excellent UV transmittance and excellent weather resistance. was.
本発明者は上記従来技術の欠点を解消し、紫外線透過性
に優れるとともに耐候性にも優れるという、従来同時に
満足し得なかった課題を同時に満足し得る防霧性農業用
被覆材を開発すべく鋭意研究した結果、塩化ビニル樹脂
に対してハイドロタルサイト類、高級アルコールリン酸
エステル金属塩及び特定の含フツ素化合物を特定量含有
せしめることにより紫外線の透過性を低下させることな
く耐候性を向上できることを見出し本発明を完成するに
到った。The present inventor aims to solve the above-mentioned drawbacks of the prior art and to develop a fog-proof agricultural coating material that can simultaneously satisfy the problems that could not be met at the same time, such as having excellent ultraviolet transmittance and excellent weather resistance. As a result of extensive research, we have improved weather resistance without reducing ultraviolet transmittance by adding specific amounts of hydrotalcites, higher alcohol phosphate metal salts, and specific fluorine-containing compounds to vinyl chloride resin. We have discovered that this can be done and have completed the present invention.
即ち本発明は、
塩化ビニル系樹脂１００重量部当たり、式、（（Ｍｌ）
、 （Ｍｚ）ｂ （Ｍｓ）ｃ ） Ｉ−ｘ ・Ａ Ｉ
Ｘ （ＯＨ） ｚ Ａ ：Ｑ ・ｍ Ｈｚ Ｏ（１）
（但しＱ＜ｘ≦０．５．０．５≦ａ＋ｂ＋Ｃ＜１、ａ＋
ｂ＋ｃ＝ｌ−Ｘ、ａ＋ｂ＞ｃ、Ｑ≦ａ＜１．０≦ｂ＜１
．０≦ｃ ＜ Ｑ、 ５、ＭｌはＭｇ” 、ＰＪＩｚは
Ｃａト又はＢａｇ＋、Ｍ３はＺｎ”°、Ｃｄ”又はＰｂ
２＋のいずれかの金属イオン、Ａ”−はｎ価のアニオン
、０Ｓｍ＜２を示す。）で示されるハイドロタルサイト
類０．１〜７重量部と、式、（但しＭ′は２価の金属、
ｉ、ｊ、ｍ、ｎは８以上の整数を示す。）で示される高
級アルコールリン酸エステル金属塩０．０５〜１重量部
及び１分子中に含むフッ素基と、水酸基或いはアルキレ
ンオキサイド基の少なくとも１種とを有する含むフッ素
化合物を０．０１〜１．０重量部を含有し、シート状或
いはフィルム状に形成したことを特徴とする防霧性農業
用被覆材を要旨とするものである。That is, in the present invention, per 100 parts by weight of vinyl chloride resin, the formula ((Ml)
, (Mz)b (Ms)c) I-x ・A I
X (OH) z A :Q ・m Hz O(1)
(However, Q<x≦0.5.0.5≦a+b+C<1, a+
b+c=l−X, a+b>c, Q≦a<1.0≦b<1
．． 0≦c<Q, 5, Ml is Mg'', PJIz is Ca or Bag+, M3 is Zn'', Cd'' or Pb
0.1 to 7 parts by weight of hydrotalcites represented by the formula, (where M' is a divalent anion, A"- is an n-valent anion, and 0Sm<2). metal,
i, j, m, and n represent integers of 8 or more. 0.05 to 1 part by weight of a higher alcohol phosphate ester metal salt represented by ) and 0.01 to 1 part by weight of a fluorine compound containing a fluorine group and at least one of a hydroxyl group or an alkylene oxide group in one molecule. The gist of the present invention is to provide a fog-proof agricultural covering material which contains 0 parts by weight and is formed into a sheet or film shape.
本発明において上記（１１式で示されるハイドロタルサ
イト類におけるＡ”−で示されるｎ価のアニオンとして
は、Ｃ１−、Ｂｒ−、！−、Ｎ０ａ−１ＣＩＯｐ −、
ＳＯ４”＼ｃｏ、”−１Ｓ ｉ Ｏｓ ”−１ＨＰＯ４
”−１ＨＢＯ８′−１ＰＯａ３−２Ｆｅ（ＣＮ）ａ ’
−１Ｆｅ（ＣＮ）４’＼ＣＨ：ｌ’ ＣＯＯ−、ＣｂＨ
４（０１１）Ｃｏｏ−１（ＣＯＯ） ｚ ”、
等が挙げら゛れ、ハイドロタルサイト類の具体例として
は、
Ｍｇｏ、 ｂｂＭｏ、 ３ａ（ＯＨ）ｚ（ＳｉＯ３）。In the present invention, the n-valent anions represented by A"- in the hydrotalcites represented by formula 11 include C1-, Br-, !-, N0a-1CIOp-,
SO4”\co,”-1S i Os”-1HPO4
"-1HBO8'-1POa3-2Fe(CN)a'
-1Fe(CN)4'\CH:l' COO-, CbH
4(011)Coo-1(COO)z'', etc. Specific examples of hydrotalcites include Mgo, bbMo, 3a(OH)z(SiO3).
、＋？ ・０．５２１１□ＯＭｇｏ、 、ｏＮｌｏ、
ｚｏ（Ｏｉｌ）ｚ（ＨＰＯ４）ｏ、 ＋ｓ ’ ０
．４０１１ｚＯＺｎｏ、７ｏＡ７ｏ、３ｏ（ＯＨ）ｔ
Ｈ（Ｃｉ、Ｈ４（０１１）ＣＯＯ） ｏ、 ｓｏ・
０．５８ＨｚＯＭｇｏ、 ｔｏＡｌ ｏ、 ｓｏ （Ｏ
Ｈ） ｚ （ＣＯ３） ｅ、 ｒ ｓ ・０．５５１１
２０陶。、６７Ａｆｆｉ。、 ３３（ＯＨ）ｔ（ＣＯ３
）。、、６．・ ０．５Ｈ，０Ｚｎｏ、ｂｔＡｉ！ｏ、
５ｓ（ＯＨ）ｚ（Ｃｏｘ）ｏ、＋ｉ、ｓ ・０．５１
ｆｚＯＭｇｏ、 ？。Ｍｏ、、。（Ｏｉｌ） ｚ （Ｓ
０４）。、＋５・０．２１１．ＯＭｇｏ、 ？。Ｍｏ、
、。（ＯＨ） ｚ （ＣＯ３）。、１゜Ｍｇｏ、 １４
Ｚｎｏ、 ＩｏＡｌｏ、 ｚｂ（０１１）ｚ（Ｃ（ｈ）
ｏ、 ＋３ ・０．４１１２０Ｍｇｏ、 ５ｓＺｎｏ、
＋５ＡＪｌｏ、 ５（ＯＨ）ｚ（ＣＯ３）ｏ、 ＋ｓ
Ｍｇｏ、 ＋Ｃａ、、、 ｚＺｎｏ、 ３ Ａｌｏ、
３ ・（０１１） ｔ （Ｃ０３）。、＋５・０．
４５）１ｚＯＭｇｏ、ｂＣｄｏ、ｒＡｌｏ、ｓ （Ｏ
Ｈ）ｚｃｃＨｚｃＯｏ）ｏ、ｚ ・０．２５ＨｚＯＭ
ｇｏ、 ５ａＰｂ６．２゜Ａｅｏ、ｚ６（０１１）ｚ（
Ｃ１）３）。、０．・０．２ＨｚＯＭｇｏ、 ５ｏＺｎ
ｏ、 ｔｏ Ａｉ！ ｏ、 ｓｏ （Ｏｔｌ） ２ （
ＮＯ３） ｏ、 ｙ。,+?・0.5211□OMgo, ,oNlo,
zo(Oil)z(HPO4)o, +s' 0
．． 4011zOZno, 7oA7o, 3o(OH)t
H (Ci, H4 (011) COO) o, so・
0.58HzOMgo, toAl o, so (O
H) z (CO3) e, r s ・0.5511
20 pottery. , 67 Affi. , 33(OH)t(CO3
). ,,6.・0.5H, 0Zno, btAi! o,
5s(OH)z(Cox)o, +i,s ・0.51
fzOMgo, ? . Mo... (Oil) z (S
04). , +5・0.211. OMgo, ? . Mo,
,. (OH) z (CO3). , 1゜Mgo, 14
Zno, IoAlo, zb(011)z(C(h)
o, +3 ・0.41120Mgo, 5sZno,
+5AJlo, 5(OH)z(CO3)o, +s
Mgo, +Ca, zZno, 3 Alo,
3 ・(011) t (C03). , +5・0.
45) 1zOMgo, bCdo, rAlo, s (O
H)zccHzcOo)o,z ・0.25HzOM
go, 5aPb6.2゜Aeo, z6(011)z(
C1)3). ,0.・0.2HzOMgo, 5oZn
o, to Ai! o, so (Otl) 2 (
NO3) o, y.
等の化合物が挙げられる。Compounds such as
また（２）式で示される高級アルコールリン酸エステル
金属塩におけるＭ′で示される２価の金属イオンとして
は、Ｚｎ”、Ｂａ”、Ｃａ”等を例示でき、（２）式で
示される高級アルコールリン酸エステル金属塩の具体例
としては、
（ＣＩ １１１１３７０） ２ Ｐ −０ＺｎＯ−Ｐ
（０（、＋ １１８３７） ２１１］１
（ＣＩ ６１１＋３０） ｚ Ｐ −０ＺｎＯ−Ｐ
（ＯＣ＋ ａｌｌ＋：＋） ｚ１］１１
（Ｃ＋５ｔｈ７０）ｚ Ｐ −０ＣａＯ−Ｐ （ＯＣ
＋ｓＨ：＋ｙ）ｚ等の化合物が挙げられる。Examples of the divalent metal ion represented by M' in the higher alcohol phosphate metal salt represented by the formula (2) include Zn'', Ba'', Ca'', etc. Specific examples of alcohol phosphate ester metal salts include (CI 1111370) 2P-0ZnO-P
(0(,+11837) 211]1 (CI 611+30) z P -0ZnO-P
(OC+ all+:+) z1]11 (C+5th70)z P -0CaO-P (OC
Examples include compounds such as +sH:+y)z.
１分子中に含フッ素基と、水酸基或いはアルキレンオキ
サイド基の少なくとも一種とを有する含フツ素化合物に
おける含フッ素基としては、パーフルオロアルキル基（
Ｃｎ ＦＺｎ＋１基）、パーフルオロアルコキシ基（Ｃ
，ｌＦ２，１．ＩＯ基）、ポリフルオロアルキル基（Ｉ
ｔ、 Ｃ−Ｆ２，１−１− 基）、パーフルオロアル
ケニル基（Ｃ、、Ｆｚｎ−＋基）、ポリフルオロアルケ
ニル基（Ｉｔ、 Ｃ１Ｆｚｆｉ−＋−基）、パーフルオ
ロアルキレン基（Ｃ，ｌＦ２．、基）（但しｍは１〜３
の整数、ｎは３〜２０の整数）等が挙げられ、アルキレ
ンオキサイド基としては（Ｃ２１１４０）ｆｉ、（Ｃ３
１１，０） 、、（但しｎは１〜３０の整数）等が挙げ
られる。このような含フツ素化合物の具体例としては、
例えば、
ＣａＦ＋？Ｃｚｔ１４０（ＣｚＨａＯ）ｇｃＩｌ＊Ｃｓ
Ｆ ＋ ｔｃＨｚｃＨ（Ｏｆｆ） ＣＩＺＯ（Ｃ２１１
４０） Ｉ ０ＣＩＩ：ＩＣＩｏＦ、 、 ＣＩＩｚＣ
ＩＩ （０＋Ｉ） ＣＩＩｚＯ（ＣｚＨｔＯ） ａｌｌ
ＣＩ ｏｐｚ Ｉ ＣＩ（ＺＣＩ＋ （０１１） ｃｎ
ｚｏ （Ｃｆｆｌ１６０） Ｉ ｏＨＣＢＦｌ ７ＣＨ
２Ｃ１（（ＯＣＯＣＩｈ）ＣＨ２Ｏ（Ｃ３１１６０）
５ｅｔｌ＋ＣｓＦ Ｉ ７ＳＯＺＮ （Ｃｚｌｌｓ）
（ＣＪ４０） １ＪＣ６Ｆ Ｉ ３ＣＯＮ （Ｃｚｌｌ
ｓ） （ＣｚｌｌａＯ） ＪＣｓＦ＋ ｑｓＯＪ （Ｃ
ＩｈＣＯＯ（ＯＨ） ＣＩｈＣＯＯ） ｔ１１ｃＦｚｃ
ｓＦ＋。Ｃ１１□０（Ｃｔ）１４０） ｌ。ＨＣＩＦ７
０Ｃ，Ｆ６Ｃ１ｌ□ＣＨｚＳＣＩＩ （ＣＯＯＩＩ）
ＣＩｈＣＯＯ（ＣｚＨｔＯ） ＩＪＣ，Ｆ７ＱＣ６Ｆｌ
。ＣＨ２ＣＨ２５Ｃ１ｌ （ＣＨ２ＣＯＯＨ） ＣＯＯ
（ＣＪ４０） ＩｓＨ等が挙げられる。これらの含フツ
素化合物は優れた被覆材の防霧性、耐候性を高めるため
に必要なものである。The fluorine-containing group in a fluorine-containing compound having a fluorine-containing group and at least one of a hydroxyl group or an alkylene oxide group in one molecule includes a perfluoroalkyl group (
Cn FZn+1 group), perfluoroalkoxy group (C
,lF2,1. IO group), polyfluoroalkyl group (I
t, C-F2,1-1- group), perfluoroalkenyl group (C,, Fzn-+ group), polyfluoroalkenyl group (It, C1Fzfi-+- group), perfluoroalkylene group (C,lF2. , group) (where m is 1 to 3
n is an integer of 3 to 20), and examples of alkylene oxide groups include (C21140)fi, (C3
11,0), (where n is an integer of 1 to 30), and the like. Specific examples of such fluorine-containing compounds include:
For example, CaF+? Czt140(CzHaO)gcIl*Cs
F + tcHzcH (Off) CIZO (C211
40) I0CII: ICIoF, , CIIzC
II (0+I) CIIzO(CzHtO) all
CI opz I CI(ZCI+ (011) cn
zo (Cffl160) I oHCBFl 7CH
2C1((OCOCIh)CH2O(C31160)
5etl+CsF I 7SOZN (Czlls)
(CJ40) 1JC6F I 3CON (Czll
s) (CzllaO) JCsF+ qsOJ (C
IhCOO(OH) CIhCOO) t11cFzc
sF+. C11□0(Ct)140) l. HCIF7
0C, F6C1l□CHzSCII (COOII)
CIhCOO(CzHtO) IJC,F7QC6Fl
. CH2CH25C1l (CH2COOH) COO
(CJ40) IsH etc. are mentioned. These fluorine-containing compounds are necessary to improve the fog-proofing properties and weather resistance of coating materials.
上記ハイドロタルサイト類の添加量は塩化ビニル系樹脂
１００重量部当たり、０．１〜７重量部、好ましくは０
．３〜３重量部であり、高級アルコールリン酸エステル
金属塩の添加量は塩化ビニル系樹脂１００重量部当たり
、０．０５〜１重量部、好ましくはＯ，］〜０．５重量
部であり、含フツ素化合物の添加量は塩化ビニル系樹脂
１００重量部当たり０．０１〜１重量部、好ましくは０
．０５〜０．５重量部である。ハイドロタルサイト類の
添加量が塩化ビニル系樹脂１００重量部当たり０．１重
量部未満であると、たとえ高級アルコールリン酸エステ
ル金属塩及び含フツ素化合物の添加量が上記添加量であ
ったとしても耐候性が劣り、７重量部を超えると透明性
及び強度が低下し不適なものとなる。The amount of the hydrotalcites added is 0.1 to 7 parts by weight, preferably 0.1 to 7 parts by weight, per 100 parts by weight of vinyl chloride resin.
．． 3 to 3 parts by weight, and the amount of higher alcohol phosphate ester metal salt added is 0.05 to 1 part by weight, preferably O,] to 0.5 part by weight, per 100 parts by weight of vinyl chloride resin. The amount of the fluorine-containing compound added is 0.01 to 1 part by weight, preferably 0.01 to 1 part by weight per 100 parts by weight of the vinyl chloride resin.
．． 05 to 0.5 parts by weight. If the amount of hydrotalcites added is less than 0.1 part by weight per 100 parts by weight of vinyl chloride resin, even if the amount of higher alcohol phosphate metal salt and fluorine-containing compound is the above amount. Also, the weather resistance is poor, and if it exceeds 7 parts by weight, the transparency and strength decrease, making it unsuitable.
また高級アルコールリン酸エステル金属塩の添加量が０
．０５重量部未満であると、例えハイドロタルサイト類
及び含フツ素化合物が上記添加量であったとしても耐候
性が劣り、１重量部を超えると加工時の熱変色が生じ不
適なものとなる。更に含フ・７素化合物の添加量が０．
０１重量部未満であると防霧性が劣り、１重量部を超え
ると例えハイドロタルサイト類及び高級アルコールリン
酸エステル金属塩の添加量が上記範囲であ、ったとして
も耐候性が劣り不適なものとなる。In addition, the amount of higher alcohol phosphate ester metal salt added is 0.
．． If the amount is less than 0.5 parts by weight, the weather resistance will be poor even if the hydrotalcites and fluorine-containing compounds are added in the above amounts, and if it exceeds 1 part by weight, thermal discoloration will occur during processing, making it unsuitable. . Furthermore, the amount of added fluorine-containing heptacompound is 0.
If the amount is less than 1 part by weight, the fog-proof property will be poor, and if it exceeds 1 part by weight, the weather resistance will be poor and unsuitable even if the amount of hydrotalcites and higher alcohol phosphate metal salts is within the above range. Become something.
本発明において上記ハイドロタルサイト類、高級アルコ
ールリン酸エステル金属塩、含フツ素化合物を添加する
塩化ビニル系樹脂とは、塩化ビニル単独重合体樹脂、塩
化ビニルとこれと共重合可能な単量体との共重合体樹脂
及びこれらの混合物であり、樹脂重合度は１０００〜２
５００のものが好ましい。In the present invention, the vinyl chloride resin to which the hydrotalcites, higher alcohol phosphate metal salt, and fluorine-containing compound are added refers to vinyl chloride homopolymer resin, vinyl chloride, and monomers copolymerizable therewith. copolymer resins and mixtures thereof, and the resin polymerization degree is 1000 to 2.
500 is preferred.
本発明においては被覆材の内面への結露防止のために必
要に応じて上記塩化ビニル系樹脂１００重量部当たり、
０．５重量部以上、更に好ましくは０．５〜４重量部、
特に好ましくは１〜３重量部の非イオン界面活性剤を添
加することができる。非イオン界面活性剤としてはソル
ビタン脂肪酸エステル、ソルビトール脂肪酸エステル、
ジグリセリン脂肪酸エステル、グリセリン脂肪酸エステ
ル、ソルビタン脂肪酸・二塩基酸エステル、ソルビトー
ル脂肪酸・二塩基酸エステル、ジグリセリン脂肪酸・二
塩基酸エステル、グリセリン脂肪酸・二塩基酸エステル
等の多価アルコールと脂肪酸とのエステル、多価アルコ
ールと脂肪酸及び二塩基酸とのエステル、或いはこれら
にアルキレンオキサイドが付加されたもの等が挙げられ
る。なかでも炭素数１２〜２２の脂肪酸とのエステル、
或いはこの脂肪酸及び二塩基酸のエステル等が挙げられ
、具体的には、ソルビタンパルミテート、ソルビタンス
テアレート、ソルビタンステアレート・エチレンオキサ
イド３モル付加物、ソルビタンパルミテート・プロピレ
ンオキサイド２モル付加物、ソルビトールステアレート
、ソルビトールステアレート・エチレンオキサイド３モ
ル付加物、ジグリセリンパルミテート、ジグリセリンス
テアレート、グリセリンパルミチーＩ・、グリセリンス
テアレート、グリセリンパルミテート・エチレンオキサ
イド２モル付加物、ソルビタンステアレートアジベート
・プロピレンオキサイド１モル付加物、ソルビトールス
テアレートアジペート・エチレンオキサイド３モル・プ
ロピレンオキサイド３モル付加物、ジグリセリンパルミ
テートセバケート・プロピレンオキサイド２モル付加物
、ソルビトールパルミテートアジペート・プロピレンオ
キサイド３モル付加物等が挙げられる。これら非イオン
界面活性剤は１種又は２種以上混合して用いることがで
きる。In the present invention, in order to prevent dew condensation on the inner surface of the coating material, per 100 parts by weight of the vinyl chloride resin,
0.5 parts by weight or more, more preferably 0.5 to 4 parts by weight,
Particularly preferably 1 to 3 parts by weight of nonionic surfactants can be added. Nonionic surfactants include sorbitan fatty acid ester, sorbitol fatty acid ester,
Polyhydric alcohols and fatty acids such as diglycerin fatty acid ester, glycerin fatty acid ester, sorbitan fatty acid/dibasic acid ester, sorbitol fatty acid/dibasic acid ester, diglycerin fatty acid/dibasic acid ester, glycerin fatty acid/dibasic acid ester, etc. Examples include esters, esters of polyhydric alcohols with fatty acids and dibasic acids, and those to which alkylene oxide is added. Among them, esters with fatty acids having 12 to 22 carbon atoms,
Alternatively, esters of these fatty acids and dibasic acids can be mentioned, and specific examples include sorbitan palmitate, sorbitan stearate, 3 mole adduct of sorbitan stearate and ethylene oxide, 2 mole adduct of sorbitan palmitate and propylene oxide, and sorbitol. Stearate, 3 mole adduct of sorbitol stearate and ethylene oxide, diglycerin palmitate, diglycerin stearate, glycerin palmicyi I, glycerin stearate, 2 mole adduct of glycerin palmitate and ethylene oxide, sorbitan stearate adibate - 1 mole adduct of propylene oxide, sorbitol stearate adipate, 3 mole ethylene oxide, 3 mole adduct of propylene oxide, 2 mole adduct of diglycerin palmitate sebacate/propylene oxide, 3 mole adduct of sorbitol palmitate adipate/propylene oxide etc. These nonionic surfactants can be used alone or in combination of two or more.
本発明被覆材には更に必要に応じて可―剤、安定剤、安
定化助剤等の添加剤を添加することもできる。上記可塑
剤としてはフタル酸エステル系可塑剤、リン酸エステル
系可塑剤、エポキシ系可塑剤、アジピン酸エステル系可
塑剤等が挙げられる。Additives such as a softener, a stabilizer, and a stabilizing aid may be added to the coating material of the present invention, if necessary. Examples of the plasticizers include phthalate plasticizers, phosphate plasticizers, epoxy plasticizers, and adipate plasticizers.
フタル酸エステル系可塑剤としては例えばジブチルフタ
レート、ジドデシルフタレート、ジ−ｎ−オクチルフタ
レート、ジイソオクチルフタレート、ジー２−エチルへ
キシルフタレート、ジノニルフタレート、ジイソノニル
フタレート、ジイソデシルフタレート、ジドデシルフタ
レート、ジイソデシルフタレート、ジトリデシルフタレ
ート、ブチルベンジルフタレート等が挙げられる。リン
酸エステル系可塑剤としては例えばトリオクチルホスフ
ェート、トリフェニルホスフェート、トリクレジルホス
フェート、トリキシレニルホスフェート、ジフェニルオ
クチルホスフェート、ジフェニルクレジルホスフェート
、トリエチルフェニルホスフェート等が挙げられる。ま
たエポキシ系可塑剤としては例えばエポキシ化大豆油、
エポキシ化アマニ油、エポキシ化魚油、エポキシ化ヒマ
シ油、エポキシ化すフラワー油、エポキシ化トール油脂
肪酸エステル、エポキシ化アマニ油脂肪酸エステル、エ
ポキシ化生脂油、エポキシ化ポリブタジェン、エポキシ
ステアリン酸メチル、エポキシステアリン酸ブチル、エ
ポキシステアリン酸−２−エチルヘキシル、エポキシス
テアリン酸ステアリル、トリス（エポキシプロビル）イ
ソシアヌレート、３−（２−キセノキシ）−１，２−エ
ポキシプロパン、ビスフェノールＡ・ジグリシジルエー
テル、ビニルジクロヘキセンジエボキサイド、２，２−
ビス（４−ヒドロキシフェニル）プロパンとエピクロル
ヒドリンとの重縮合物等が挙げられる。上記可塑剤は１
種又は２種以上混合して用いられるが、好ましい添加量
は塩化ビニル系樹脂１００重量部当たり、フタル酸エス
テル系可塑剤で３０〜７０重量部、リン酸エステル系可
Ｗ剤で１〜７重量部、エポキシ系可塑剤で０．５〜７重
量部である。Examples of phthalate ester plasticizers include dibutyl phthalate, didodecyl phthalate, di-n-octyl phthalate, diisooctyl phthalate, di-2-ethylhexyl phthalate, dinonyl phthalate, diisononyl phthalate, diisodecyl phthalate, didodecyl phthalate, Examples include diisodecyl phthalate, ditridecyl phthalate, butylbenzyl phthalate, and the like. Examples of phosphoric acid ester plasticizers include trioctyl phosphate, triphenyl phosphate, tricresyl phosphate, tricylenyl phosphate, diphenyloctyl phosphate, diphenyl cresyl phosphate, triethylphenyl phosphate, and the like. Examples of epoxy plasticizers include epoxidized soybean oil,
Epoxidized linseed oil, epoxidized fish oil, epoxidized castor oil, epoxidized flower oil, epoxidized tall oil fatty acid ester, epoxidized linseed oil fatty acid ester, epoxidized raw tallow oil, epoxidized polybutadiene, epoxy methyl stearate, epoxy stearic acid Butyl, 2-ethylhexyl epoxy stearate, stearyl epoxy stearate, tris(epoxypropyl) isocyanurate, 3-(2-xenoxy)-1,2-epoxypropane, bisphenol A diglycidyl ether, vinyl dichlorohexendie Boxide, 2,2-
Examples include polycondensates of bis(4-hydroxyphenyl)propane and epichlorohydrin. The above plasticizer is 1
They can be used as a species or as a mixture of two or more, but the preferred addition amounts are 30 to 70 parts by weight of the phthalate ester plasticizer and 1 to 7 parts by weight of the phosphate ester wicking agent per 100 parts by weight of the vinyl chloride resin. parts, and the epoxy plasticizer is 0.5 to 7 parts by weight.
更に必要に応じてポリオキシエチレンアルキルアミン、
ポリグリコールエーテル、ｐ−スチレンスルホン酸ナト
リウム等の帯電防止剤あるいは酸化防止剤、着色剤等の
添加剤を適宜添加することもでき、またナス、苺、花等
の色付きを阻害しない範囲内で少量の紫外線吸収剤を添
加することもできる。Furthermore, if necessary, polyoxyethylene alkylamine,
Additives such as antistatic agents, antioxidants, colorants, etc. such as polyglycol ether and sodium p-styrene sulfonate may be added as appropriate, and may be added in small amounts within a range that does not inhibit the coloring of eggplants, strawberries, flowers, etc. UV absorbers can also be added.
本発明の農業用被覆材はフィルム又はシート状に形成さ
れるが、その厚みは０．０３〜０．３鰭程度が好ましい
。The agricultural covering material of the present invention is formed into a film or sheet, and the thickness thereof is preferably about 0.03 to 0.3 fins.
以下に実施例を挙げて本発明を更に詳細に説明する。 The present invention will be explained in more detail with reference to Examples below.
実施例１〜５、比較例１〜４
第１表に示す配合物をヘンシェルミキサーに仕込み、１
０分間攪拌混合した後、溶融して１７５℃のカレンダー
ロールにて厚さ０．１璽ｌのフィルムに形成した。各フ
ィルムをバイブハウスの被覆材として使用し、茨城県海
浜地区において昭和６２年１月１０日〜同年１２月２０
日までの間暴露試験を行い、耐候性の評価を行った。各
フィルムの防霧性はトンネルハウスに展張して行った。Examples 1 to 5, Comparative Examples 1 to 4 The formulations shown in Table 1 were charged into a Henschel mixer, and 1
After stirring and mixing for 0 minutes, the mixture was melted and formed into a film with a thickness of 0.1 liter using a calendar roll at 175°C. Each film was used as a covering material for vibe houses in the seaside area of Ibaraki Prefecture from January 10, 1988 to December 20 of the same year.
An exposure test was conducted for up to 15 days to evaluate weather resistance. The fog-proof properties of each film were tested by spreading them in a tunnel house.
各フィルムの紫外線透過率は分光光線透過率測定機を用
いて波長３５０ｎｍの紫外線透過率１（％）を測定した
。結果を第２表にあわせて示す。The ultraviolet transmittance of each film was determined by measuring the ultraviolet transmittance 1 (%) at a wavelength of 350 nm using a spectral light transmittance measuring device. The results are also shown in Table 2.
第２表
※ｌ ： Ｍｇｏ、 ｂ□Ａ１ａ、 ：１ｓ（ＯＩＩ）
２（ＣＯ３）ｏ、 ＋６５ ・０．５１１ｚＯで示され
るハイドロタルサイト
※２ ： Ｚｎｏ、 ｂｔＭｏ、 ３３（Ｃ）ｌ）ｚ（
ＣＯ３）ｏ、 ＋６５ ・０．５ＨｚＯで示されるハイ
ドロタルサイト
※ ３ ： Ｍｇｏ、ｂａＺｎｏ、＋ｏＡｌｏ、ｚ
ｂ（０１１ン２ ・（ＣＯ３）。、１３・０．、ｉｌ
ｈ。Table 2 *l: Mgo, b□A1a, :1s (OII)
Hydrotalcite shown as 2(CO3)o, +65 ・0.511zO *2: Zno, btMo, 33(C)l)z(
CO3) o, +65 Hydrotalcite indicated by 0.5HzO*3: Mgo, baZno, +oAlo, z
b(011n2 ・(CO3)., 13・0., il
h.
で示されるハイトコタルサイト
※４ ： （（ＣＩ８Ｈ３７０）２ＰＯＯ） ｚＺｎ
※５：２−ヒドロキシ−４−オクトキシベンゾフェノン
※６ ： ＣｓＦ＋ｙＣ１１ｚＣＨ（０１１）Ｃ１ｚＯ
（ＣｚｌｌｔＯ）ｑｌｌ※７ ： ＨＣＦ２Ｃ？Ｆ＋
ａＣＩ＋２０（Ｃ２＋１４０） Ｉ ＊Ｃｌ１３※８：
Ｃ，Ｆ、□５ＯｚＮ（Ｃｚｌｉｓ）ＣＩｌ□Ｃ００Ｋ
（大日本インキ化学製：メガファソクＦ−１２０）
※９：耐候性は、
○：変色劣化、フィルＪ、の破れ共になし。Hytocotalsite*4 indicated by: ((CI8H370)2POO) zZn
*5: 2-hydroxy-4-octoxybenzophenone *6: CsF+yC11zCH(011)C1zO
(CzlltO)qll*7: HCF2C? F+
aCI+20 (C2+140) I *Cl13*8:
C, F, □5OzN (Czlis) CIl□C00K
(Dainippon Ink Chemical Co., Ltd.: Mega Fasoku F-120) *9: Weather resistance: ○: No discoloration or tearing of Fill J.
ロ：変色劣化なし。ハウスパイプ上にフィルムの亀裂発
生。B: No discoloration or deterioration. Cracks occur in the film on house pipes.
△：微少の変色発生。ハウスパイプ上にフィルムの破れ
発生。△: Slight discoloration occurred. A tear occurred in the film on the house pipe.
×：褐色劣化大。フィルムの破れ大。×: Significant browning deterioration. Severe film damage.
として評価した。It was evaluated as
※１０：防霧性は、 ○：霧発生なし。*10: Fog resistance is ○: No fog generation.
△：霧発生ややあり。△: Slight fog formation.
×：霧発生多い。×: A lot of fog is generated.
として評価した。It was evaluated as
以上説明゛したように本発明農業用被覆材は、塩化ビニ
ル系樹脂１００重量部当たり、ハイドロタルサイト０．
１〜７重量部と、高級アルコールリン酸エステル金属塩
０，０５〜１重景部重量特定の含フツ素化合物０．０１
〜１重量部配置部たことにより、防霧性に優れるととも
に被覆材に紫外線による変色劣化が生じたり、破れ等が
生じる虞れがないとともに、本発明被覆材は紫外線の透
過性も良く、本発明被覆材をハウス等の被覆用に用いれ
ばナス、苺、花等の色付きが良好となる等の効果を有す
る。As explained above, the agricultural covering material of the present invention has 0.00% hydrotalcite per 100 parts by weight of vinyl chloride resin.
1 to 7 parts by weight, and 0.05 to 1 part by weight of the higher alcohol phosphate metal salt, and 0.01 part by weight of the specified fluorine-containing compound.
By placing ~1 part by weight, the coating material of the present invention has excellent fog-proofing properties and there is no risk of discoloration or tearing of the coating material due to ultraviolet rays. When the inventive coating material is used to cover greenhouses, etc., it has the effect of improving the coloring of eggplants, strawberries, flowers, etc.
Claims (1)
学式、表等があります▼（１） （但し０＜ｘ≦０．５、０．５≦ａ＋ｂ＋ｃ＜１、ａ＋
ｂ＋ｃ＝１−ｘ、ａ＋ｂ＞Ｃ、０≦ａ＜１、０≦ｂ＜１
、０≦ｃ＜０．５、Ｍ＿１はＭｇ＾２＾＋、Ｍ＿２はＣ
ａ＾２＾＋又はＢａ＾２＾＋、Ｍ＿３はＺｎ＾２＾＋、
Ｃｄ＾２＾＋又はＰｂ＾２＾＋のいずれかの金属イオン
、Ａ＾ｎ＾−はｎ価のアニオン、０≦ｍ＜２を示す。）
で示されるハイドロタルサイト類０．１〜７重量部と、
式、 ▲数式、化学式、表等があります▼（２） （但しＭ′は２価の金属、ｉ、ｊ、ｍ、ｎは８以上の整
数を示す。）で示される高級アルコールリン酸エステル
金属塩０．０５〜１重量部及び１分子中に含フッ素基と
、水酸基或いはアルキレンオキサイド基の少なくとも１
種とを有する含フッ素化合物０．０１〜１．０重量部と
を含有し、シート状或いはフィルム状に形成したことを
特徴とする防霧性農業用被覆材。[Claims] There are formulas, ▲mathematical formulas, chemical formulas, tables, etc. per 100 parts by weight of vinyl chloride resin▼(1) (However, 0<x≦0.5, 0.5≦a+b+c<1, a+
b+c=1-x, a+b>C, 0≦a<1, 0≦b<1
, 0≦c<0.5, M_1 is Mg^2^+, M_2 is C
a^2^+ or Ba^2^+, M_3 is Zn^2^+,
Metal ion of either Cd^2^+ or Pb^2^+, A^n^- indicates an n-valent anion, 0≦m<2. )
0.1 to 7 parts by weight of hydrotalcites represented by
There are formulas, ▲mathematical formulas, chemical formulas, tables, etc.▼(2) (However, M' is a divalent metal, and i, j, m, and n are integers of 8 or more.) Higher alcohol phosphate ester metal 0.05 to 1 part by weight of salt and at least one fluorine-containing group and one hydroxyl group or alkylene oxide group in one molecule
1. A fog-proof agricultural covering material, characterized in that it contains 0.01 to 1.0 parts by weight of a fluorine-containing compound having seeds, and is formed into a sheet or film shape.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63083696A JPH01256553A (en) | 1988-04-05 | 1988-04-05 | Fog-preventing agricultural covering material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP63083696A JPH01256553A (en) | 1988-04-05 | 1988-04-05 | Fog-preventing agricultural covering material |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPH01256553A true JPH01256553A (en) | 1989-10-13 |
| JPH0518345B2 JPH0518345B2 (en) | 1993-03-11 |
Family
ID=13809659
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP63083696A Granted JPH01256553A (en) | 1988-04-05 | 1988-04-05 | Fog-preventing agricultural covering material |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPH01256553A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH01301742A (en) * | 1988-05-31 | 1989-12-05 | Mitsui Toatsu Chem Inc | Agricultural vinyl chloride-based resin film |
| JPH0228236A (en) * | 1988-02-09 | 1990-01-30 | Mitsui Toatsu Chem Inc | Agricultural vinyl chloride resin film |
| JPH0269538A (en) * | 1988-09-05 | 1990-03-08 | Mitsubishi Kasei Vinyl Co | Agricultural synthetic resin covering material |
| JPH07118473A (en) * | 1993-10-19 | 1995-05-09 | Asahi Denka Kogyo Kk | Stabilized chlorine-containing resin composition |
| JP2020500998A (en) * | 2016-12-12 | 2020-01-16 | エスシージー ケミカルズ カンパニー，リミテッド | Polymer composition |
Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5714648A (en) * | 1980-06-28 | 1982-01-25 | C I Kasei Co Ltd | Covering material for agriculture and its use |
| JPS5846146A (en) * | 1981-09-14 | 1983-03-17 | 鳥居 宗一 | Circular loom for producing double bag |
| JPS5935573A (en) * | 1982-08-23 | 1984-02-27 | Fuji Electric Co Ltd | Constant margin angle control system for multistage cascade thyristor converter |
| JPS5978251A (en) * | 1982-10-27 | 1984-05-07 | Mitsubishi Monsanto Chem Co | Weather-resistant agricultural vinyl chloride resin film |
| JPS59102944A (en) * | 1982-12-03 | 1984-06-14 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin coating material for agricultural use |
| JPS59113046A (en) * | 1982-12-20 | 1984-06-29 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| JPS61111349A (en) * | 1984-11-06 | 1986-05-29 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin composition for molding anti-fogging agricultural film |
| JPS61190543A (en) * | 1985-02-18 | 1986-08-25 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin film for agricultural use |
| JPS6212931A (en) * | 1985-07-10 | 1987-01-21 | Sharp Corp | Driving device for objective lens |
| JPS6231744A (en) * | 1985-07-31 | 1987-02-10 | Aisin Warner Ltd | Multistage automatic speed control device |
| JPS6335636A (en) * | 1986-07-31 | 1988-02-16 | Dainippon Ink & Chem Inc | Anti-fogging synthetic resin film for agricultural use |
| JPS63312361A (en) * | 1987-06-15 | 1988-12-20 | Mitsubishi Kasei Vinyl Co | Agricultural covering material made of synthetic resin |
-
1988
- 1988-04-05 JP JP63083696A patent/JPH01256553A/en active Granted
Patent Citations (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS5714648A (en) * | 1980-06-28 | 1982-01-25 | C I Kasei Co Ltd | Covering material for agriculture and its use |
| JPS5846146A (en) * | 1981-09-14 | 1983-03-17 | 鳥居 宗一 | Circular loom for producing double bag |
| JPS5935573A (en) * | 1982-08-23 | 1984-02-27 | Fuji Electric Co Ltd | Constant margin angle control system for multistage cascade thyristor converter |
| JPS5978251A (en) * | 1982-10-27 | 1984-05-07 | Mitsubishi Monsanto Chem Co | Weather-resistant agricultural vinyl chloride resin film |
| JPS59102944A (en) * | 1982-12-03 | 1984-06-14 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin coating material for agricultural use |
| JPS59113046A (en) * | 1982-12-20 | 1984-06-29 | Adeka Argus Chem Co Ltd | Halogen-containing resin composition |
| JPS61111349A (en) * | 1984-11-06 | 1986-05-29 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin composition for molding anti-fogging agricultural film |
| JPS61190543A (en) * | 1985-02-18 | 1986-08-25 | Mitsubishi Monsanto Chem Co | Vinyl chloride resin film for agricultural use |
| JPS6212931A (en) * | 1985-07-10 | 1987-01-21 | Sharp Corp | Driving device for objective lens |
| JPS6231744A (en) * | 1985-07-31 | 1987-02-10 | Aisin Warner Ltd | Multistage automatic speed control device |
| JPS6335636A (en) * | 1986-07-31 | 1988-02-16 | Dainippon Ink & Chem Inc | Anti-fogging synthetic resin film for agricultural use |
| JPS63312361A (en) * | 1987-06-15 | 1988-12-20 | Mitsubishi Kasei Vinyl Co | Agricultural covering material made of synthetic resin |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH0228236A (en) * | 1988-02-09 | 1990-01-30 | Mitsui Toatsu Chem Inc | Agricultural vinyl chloride resin film |
| JPH01301742A (en) * | 1988-05-31 | 1989-12-05 | Mitsui Toatsu Chem Inc | Agricultural vinyl chloride-based resin film |
| JPH0269538A (en) * | 1988-09-05 | 1990-03-08 | Mitsubishi Kasei Vinyl Co | Agricultural synthetic resin covering material |
| JPH07118473A (en) * | 1993-10-19 | 1995-05-09 | Asahi Denka Kogyo Kk | Stabilized chlorine-containing resin composition |
| JP2020500998A (en) * | 2016-12-12 | 2020-01-16 | エスシージー ケミカルズ カンパニー，リミテッド | Polymer composition |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0518345B2 (en) | 1993-03-11 |
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