JPH01230755A - Manufacture of aluminum alloy sheet for milk-white anodic oxidation colored vessel excellent in deep drawability - Google Patents

Manufacture of aluminum alloy sheet for milk-white anodic oxidation colored vessel excellent in deep drawability

Info

Publication number
JPH01230755A
JPH01230755A JP5485088A JP5485088A JPH01230755A JP H01230755 A JPH01230755 A JP H01230755A JP 5485088 A JP5485088 A JP 5485088A JP 5485088 A JP5485088 A JP 5485088A JP H01230755 A JPH01230755 A JP H01230755A
Authority
JP
Japan
Prior art keywords
anodic oxidation
alloy
aluminum alloy
alloy sheet
milk
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP5485088A
Other languages
Japanese (ja)
Inventor
Tsutomu Moriyama
勉 森山
Makoto Tsuchida
信 土田
Yoshika Yamamoto
山本 悦加
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Light Metal Industries Ltd
Original Assignee
Sumitomo Light Metal Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Light Metal Industries Ltd filed Critical Sumitomo Light Metal Industries Ltd
Priority to JP5485088A priority Critical patent/JPH01230755A/en
Publication of JPH01230755A publication Critical patent/JPH01230755A/en
Pending legal-status Critical Current

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  • Shaping Metal By Deep-Drawing, Or The Like (AREA)

Abstract

PURPOSE:To stably and inexpensively manufacture an Al alloy sheet for milk- white anodic oxidation colored vessels excellent in deep drawability by holding an Al alloy consisting of Fe, Si, Cu, and Al at a specific temp. for a specific length of time and then applying hot working to the above. CONSTITUTION:An Al alloy having a composition consisting of, by weight, 0.3-2.2% Fe, 0.05-0.3% Si, 0.05-0.5% Cu, and the balance Al with inevitable impurities is held at >=560 deg.C for >=5hr, by which an Al-Fe compound in a metastable phase is stabilized. Subsequently, this Al alloy is subjected to hot working. By this method, the Al alloy sheet hardly causing the occurrence of cup ear at the time of deep drawing can be obtained. By subjecting this Al alloy sheet further to anodic oxidation treatment, a superior milk-white anodic oxidation film can be formed.

Description

【発明の詳細な説明】 [産業上の利用分野] 本発明は、容器やそのキャップなどを製造するときの深
絞り加工性とりわけカップ耳が小さいという性質と硫酸
陽極酸化処理で乳白色の色調か古られるという性質との
両性質を備えたアルミニウム合金板の製造方法に関する
[Detailed Description of the Invention] [Industrial Application Field] The present invention is suitable for producing containers and their caps, etc., and is characterized by deep drawing processability, especially small cup edges, and by sulfuric acid anodizing treatment, which produces a milky white color or an aged appearance. The present invention relates to a method for producing an aluminum alloy plate having both the properties of

[従来の技術] 従来、鍋や弁当箱などの器物用には、深絞り性の良好な
材料が用いられ、深絞り加工したものを塗料や電解着色
などで着色していた。しかし、陽極酸化処理による自然
発色で種々の着色が得られることから、最近特に乳白色
に発色する材料が器物用材料として好まれるようになっ
た。
[Prior Art] Conventionally, materials with good deep drawing properties have been used for pots, lunch boxes, and other utensils, and the deep drawn materials have been colored with paint or electrolytic coloring. However, since various colors can be obtained by natural coloring by anodizing, materials that develop a milky white color have recently become preferred as materials for utensils.

ところが、この乳白色に発色する材料を器物用に深絞り
加l−を行うとき、開口部に波形の大きいカップ耳を生
じ、それを切り揃えるため歩留の低ドを招いている。さ
らにカップ耳が大きいと、絞り後の板厚の変動か大きく
、材料表面にシワが発生しやすく、外観をδ・シ<損な
ってしまう。このため、カップ耳が生じなく、陽極酸化
処理で乳白色がNjられるアルミニウム合金板が装甲さ
れるようになった。
However, when this milky-white material is deep-drawn for use in making utensils, large wavy cup lugs are produced at the opening, which have to be trimmed, resulting in a low yield. Furthermore, if the cup selvage is large, the variation in the plate thickness after drawing is large, and wrinkles are likely to occur on the material surface, which impairs the appearance. For this reason, aluminum alloy plates, which do not have cup ears and whose milky white color is changed to Nj by anodizing treatment, are now being armored.

陽極酸化により乳白色に発色させる方法として下記の方
法が知られている。
The following method is known as a method for developing a milky white color by anodic oxidation.

■ FeおよびTiを自白゛させ、Stを少く制限した
アルミニウム合金を560℃以上に均熱保持することに
よって、陽極酸化処理で乳白色が得られ、また絞り加工
性を改善する方法。
(2) A method of obtaining a milky white color through anodizing treatment and improving drawing workability by uniformly heating an aluminum alloy containing Fe and Ti and limiting St to a temperature of 560°C or higher.

(特開昭60−103164号公報参照)■ Feおよ
びMgを含有させ、Siを少く制限したアルミニウム合
金を550℃以上に加熱保持することにより、成形加工
後陽極酸化処理、着色、封孔処理を行い、パステル調の
色調をi)る方法(特開昭60−103197号公報参
照)。
(Refer to Japanese Unexamined Patent Publication No. 60-103164) ■ By heating and holding an aluminum alloy containing Fe and Mg and with a small amount of Si at a temperature of 550°C or higher, anodizing, coloring, and sealing can be performed after forming. i) A method of producing a pastel tone (see JP-A-60-103197).

また、乳白色をiりる合金としては、■FeとCaなど
を含有させたアルミニウム合金(特公昭[il−200
17号公報参照)が知られ、強度と加工性を得る合金と
して、■S i 0.41〜0.80wt%F e 1
.25〜1..75wt96、Cu 0.05〜0.4
0vt%と残り実質的にAlからなるアルミニウム合金
(特開昭60−200940号公報参照)が知られてい
る。
In addition, as an alloy that produces a milky white color, ■Aluminum alloy containing Fe and Ca (Tokuko Sho [il-200
(Refer to Publication No. 17) is known as an alloy that obtains strength and workability.
.. 25-1. .. 75wt96, Cu 0.05-0.4
An aluminum alloy (see Japanese Unexamined Patent Application Publication No. 60-200940) is known which consists of 0 vt% and the remainder substantially Al.

さらに、深絞り加工時の耳率(カップ耳)を゛改善する
方法として、■Fe、S 1STi、B、Cuを3白゛
するアルミニウム合金を熱圧延後5096以上の冷間圧
延する方法(特公昭52−6684号公報謬照)が提案
されている。
Furthermore, as a method to improve the selvage ratio (cup selvage) during deep drawing, we have developed a method in which an aluminum alloy containing Fe, S1STi, B, and Cu is cold-rolled to 5096 or higher after hot rolling. Publication No. 52-6684) has been proposed.

[発明が解決しようとする課題] アルミニウムの深絞り性と陽極酸化発色性の検討は、従
来それぞれ単独で行われる場合が多かった。両者を同時
に向上させるものとして、■の方法は絞り加」二性の特
に肌荒れ防止に効果があり、均一な陽極酸化皮膜を得る
ことができるが、ここでいうカップ耳の低減には効果が
ないようである。また、■は均一な陽極酸化処理皮膜を
得るための加熱処理法を提案したものであるが、乳白色
をiするためのもので、深絞り加工時のカップ耳を軽減
することはできない。■は乳白色を得るためのものであ
り、カップ耳を軽減することはできない。■は強度と加
工性を得る合金であるが、Siの自白゛量が高いため乳
白色は得られない。■は深絞り時のカップ耳を軽減した
ものであるが、これはSiが0,35νt%以上含白°
されており、安定な乳白色が得られない。
[Problems to be Solved by the Invention] In the past, the deep drawability and anodic oxidation coloring properties of aluminum were often investigated separately. As a way to improve both at the same time, method (■) is effective in preventing skin roughness, especially in the case of "squeezing", and can obtain a uniform anodic oxide film, but it is not effective in reducing the cup ears mentioned here. It seems so. In addition, (2) proposes a heat treatment method to obtain a uniform anodic oxidation film, but it is intended to make the film milky white and cannot reduce cup edges during deep drawing. ■ is for obtaining a milky white color and cannot reduce cup ears. (2) is an alloy that provides strength and workability, but because of the high amount of Si, a milky white color cannot be obtained. ■ is the one that reduces the cup selvage during deep drawing, but this is because the Si content is 0.35νt% or more.
It is difficult to obtain a stable milky white color.

そこで、本発明は深絞り時のカップ耳の発生が小さく、
陽極酸化処理したとき乳白色の発色を得るアルミニウム
合金板を、安定してしかも安価に製造する方法を提供す
るものである。
Therefore, the present invention reduces the occurrence of cup ears during deep drawing.
The present invention provides a method for stably and inexpensively manufacturing an aluminum alloy plate that develops a milky white color when anodized.

[課題を解決するための手段] 本発明者らは、上記課題を解決するため、合金成分と熱
間圧延前の加熱条件との関係を鋭意検討した結果、Al
−Fe合金にStとCuを添加することによって、熱間
圧延板の深絞り性にに・Iするる異方性が改善され、カ
ップ耳が軽減されることを発見し、本発明を完成した。
[Means for Solving the Problems] In order to solve the above problems, the present inventors have diligently studied the relationship between alloy components and heating conditions before hot rolling, and found that Al
- Discovered that by adding St and Cu to the Fe alloy, the anisotropy of the deep drawability of hot rolled sheets was improved and the cup sag was reduced, and the present invention was completed. .

すなわち、本発明はF e  0.3〜2.2 wt%
、Sin、05〜0.05〜0.3wt、Cu 0.0
5〜0.5 wL%を含有し、残部は不可避不純物とA
lからなるアルミニウム合金を、560℃以上の温度に
5時間以上保持した後、熱間加工を行うことを特徴とす
る深絞り性に優れた乳白色陽極酸化発色性器物用アルミ
ニウム合金板の製造方法である。
That is, the present invention has Fe 0.3 to 2.2 wt%
, Sin, 05~0.05~0.3wt, Cu 0.0
5 to 0.5 wL%, the remainder being unavoidable impurities and A
A method for producing a milky-white anodized aluminum alloy plate for use in utensils with excellent deep drawability, characterized in that an aluminum alloy consisting of 1 is held at a temperature of 560° C. or higher for 5 hours or more, and then hot worked. be.

上記組成において、Feは乳白色の陽極酸化皮膜を得る
のに必要な元素である。その量が0.3vt%未満であ
ると乳白色が得られず、2.2V【%を越えて添加され
た場合には、Al−Fe化合物の不均一分散が皆しく、
筋模様を呈し、外観を損なうことと、成形性も劣化する
ことから、0.3vt%以上2.2vt%以下にする必
要がある。
In the above composition, Fe is an element necessary to obtain a milky white anodic oxide film. If the amount is less than 0.3vt%, a milky white color cannot be obtained, and if it is added in excess of 2.2V%, the Al-Fe compound will be unevenly dispersed.
Since it exhibits a streaky pattern, impairs the appearance, and also deteriorates moldability, it is necessary to keep the content between 0.3 vt% and 2.2 vt%.

SiはAl−Fe合金の深絞りの際の45°方向の耳を
小さくする効果があるが、Siを添加しすぎると、単体
Siの形で析出しやすくなり、陽極酸化皮膜を黒色化し
、乳白色に悪影響を与える。その量が0.05wt%未
満では、耳を小さくする効果が得られず、0.3wL%
を越える場合、乳白色の陽極酸化皮膜が得にくいため、
0.05ν【%以上0.3vL%以下に子る必要がある
Si has the effect of reducing the 45° angle during deep drawing of Al-Fe alloys, but if too much Si is added, it tends to precipitate in the form of simple Si, turning the anodic oxide film black and giving it a milky white color. adversely affect. If the amount is less than 0.05wt%, the effect of making the ears smaller cannot be obtained, and 0.3wL%
If it exceeds the above, it is difficult to obtain a milky white anodic oxide film.
It must be between 0.05vL% and 0.3vL%.

CuはSiと同様、Al−Fe合金の45@方向の耳を
小さくする効果がある。その瓜が0.05vL%未満で
はその効果が得られず、0.5wt%を越える場合、耳
率の低減効果がさらに得られることはなく、成形性が著
しく低下するため、0.05vt%以上0.5νt%以
下にする必要がある。
Similar to Si, Cu has the effect of reducing the selvedge in the 45@ direction of the Al-Fe alloy. If the amount of melon is less than 0.05vL%, the effect cannot be obtained, and if it exceeds 0.5wt%, the effect of reducing the ear rate cannot be further obtained and the moldability is significantly reduced, so 0.05vt% or more It is necessary to make it 0.5vt% or less.

また、合金溶製に際し、結晶組織改浜のためしばしば添
加される 0,1wt%までのT i 、 0.05%
までのBの添加は、本発明合金の製造方法による陽極酸
化皮膜の色調およびカップ耳に特に影響がないので差支
えない。
In addition, Ti up to 0.1 wt%, 0.05%, is often added to modify the crystal structure during alloy melting.
The addition of B up to the above does not particularly affect the color tone and cup edge of the anodic oxide film produced by the method for producing the alloy of the present invention, so there is no problem.

製造条件において、560℃以上の温度でソーキングを
行うのは、Al−Fe合金へのStとCuの添加による
耳率の低減効果を得るためと、A l 6 F e s
 A l m F eといった準安定相であるAl−F
e化合物を、安定相であるAl3Feに相変化させ、良
好な乳白色の陽極酸化皮膜を得るためである。そして、
それらの効果を得るには5時間以上の保持が必要である
In the manufacturing conditions, soaking is performed at a temperature of 560°C or higher in order to obtain the effect of reducing the selvage rate by adding St and Cu to the Al-Fe alloy, and
Al-F is a metastable phase such as Al m Fe.
This is to phase change the e compound to Al3Fe, which is a stable phase, and obtain a good milky white anodic oxide film. and,
Holding for 5 hours or more is required to obtain these effects.

[実施例] 次に実施例を比較例とともに表に示す。[Example] Next, examples are shown in a table along with comparative examples.

ソーキング後の製造条件としては、5IIII厚で熱間
圧延を行った後、中間焼鈍を行わずに、1mm厚に冷間
圧延し、H2O)IJ当の調質にするため200〜23
0℃の温度で焼鈍した。N o、 1〜No、8はいず
れも本発明の実施例であり、耳率はいずれも6%以ドで
あり、シワの発生がなく、乳白色の良好な色調が得られ
ている。
The manufacturing conditions after soaking are as follows: hot rolling to a thickness of 5III, then cold rolling to a thickness of 1 mm without intermediate annealing, and tempering equivalent to H2O)IJ.
Annealed at a temperature of 0°C. No. 1 to No. 8 are all examples of the present invention, and the selvage ratio is 6% or more, no wrinkles occur, and a good milky white color tone is obtained.

一方、No、9〜No、1Bの比較例は、成分およびソ
ーキング条件のいずれかが特許請求の範囲に入らないも
のであり、カップ耳、シワ、乳白色の色調の全てを満足
しているものはない。例えばNo、14のCuが0.7
シL 96と特許請求の範囲を越えるものは、乳白色は
得られるものの、カップに絞れず、成形性が著しく悪い
On the other hand, in Comparative Examples No. 9 to No. 1B, either the ingredients or the soaking conditions do not fall within the scope of the claims, and those that satisfy all of the cup ears, wrinkles, and milky color tone are do not have. For example, the Cu of No. 14 is 0.7
Although a milky white color can be obtained with Sil.96 and those exceeding the claimed range, they cannot be squeezed into a cup and have extremely poor moldability.

東蓄耳率ニブランク径B4ramφ、ポンチ径331i
Ilφ、平頭ポンチにて深絞りを行い、下記の 式で計算し、3個の平均値で表オ〕シた。
East ear storage rate blank diameter B4ramφ, punch diameter 331i
Ilφ, deep drawing was performed using a flat head punch, calculation was made using the following formula, and the average value of the three values was tabulated.

数値の前の+は、圧延方向に対し45゜方向の4つの山
を形成する耳のことを 示す。
The + in front of the numerical value indicates ears forming four peaks oriented at 45° with respect to the rolling direction.

東2色調:1596M酸浴、浴温20℃、電流密度IA
/da+2にて陽極酸化処理を行い、10〜208mの
膜厚になった状態で観察した。
East 2 tone: 1596M acid bath, bath temperature 20℃, current density IA
Anodic oxidation treatment was performed at /da+2, and the film was observed in a state where the film thickness was 10 to 208 m.

”Ti、13:本発明の効果を損なわない任意成分であ
る。
``Ti, 13: An optional component that does not impair the effects of the present invention.

[発明の効果] 本発明によれば、深絞り加工したときにカップ耳の発生
が小さく、陽極酸化処理によって乳白色に発色するアル
ミニウム合金材料が、安定して安価に得られ、該材料は
容器やそのキャップの成形加工に適したものである。
[Effects of the Invention] According to the present invention, an aluminum alloy material that produces little cup ears when deep drawn and develops a milky white color when anodized can be obtained stably and inexpensively, and the material can be used for containers and other purposes. It is suitable for molding the cap.

特許出願人 住友軽金属工業株式会社 代理人 弁理士 小 松 秀 岳 代理人 弁理士 旭     宏Patent applicant: Sumitomo Light Metal Industries, Ltd. Agent Patent Attorney Hidetake Komatsu Agent Patent Attorney Hiroshi Asahi

Claims (1)

【特許請求の範囲】[Claims] Fe0.3〜2.2wt%、Si0.05〜0.3wt
、Cu0.05〜0.5wt%を含有し、残部は不可避
不純物とAlからなるアルミニウム合金を、560℃以
上の温度に5時間以上保持した後、熱間加工を行うこと
を特徴とする深絞り性に優れた乳白色陽極酸化発色性器
物用アルミニウム合金板の製造方法。
Fe0.3-2.2wt%, Si0.05-0.3wt
, a deep drawing process characterized by hot working an aluminum alloy containing 0.05 to 0.5 wt% of Cu, with the remainder consisting of unavoidable impurities and Al, after being held at a temperature of 560°C or higher for 5 hours or more. A method for producing a milky-white anodized aluminum alloy plate for sexual organs with excellent properties.
JP5485088A 1988-03-10 1988-03-10 Manufacture of aluminum alloy sheet for milk-white anodic oxidation colored vessel excellent in deep drawability Pending JPH01230755A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP5485088A JPH01230755A (en) 1988-03-10 1988-03-10 Manufacture of aluminum alloy sheet for milk-white anodic oxidation colored vessel excellent in deep drawability

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP5485088A JPH01230755A (en) 1988-03-10 1988-03-10 Manufacture of aluminum alloy sheet for milk-white anodic oxidation colored vessel excellent in deep drawability

Publications (1)

Publication Number Publication Date
JPH01230755A true JPH01230755A (en) 1989-09-14

Family

ID=12982073

Family Applications (1)

Application Number Title Priority Date Filing Date
JP5485088A Pending JPH01230755A (en) 1988-03-10 1988-03-10 Manufacture of aluminum alloy sheet for milk-white anodic oxidation colored vessel excellent in deep drawability

Country Status (1)

Country Link
JP (1) JPH01230755A (en)

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5618358A (en) * 1995-03-01 1997-04-08 Davisson; Thomas Aluminum alloy composition and methods of manufacture
JP2010285688A (en) * 2009-05-14 2010-12-24 Fujikura Ltd Al ALLOY AND Al ALLOY CONDUCTIVE WIRE
WO2011071097A1 (en) * 2009-12-11 2011-06-16 株式会社フジクラ Power feed body and method for manufacturing same
JP2011252185A (en) * 2010-05-31 2011-12-15 Fujikura Ltd Al ALLOY CONDUCTIVE WIRE

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60103164A (en) * 1983-11-10 1985-06-07 Kobe Steel Ltd Production of aluminum alloy for vessel of the like
JPS6320500A (en) * 1986-07-11 1988-01-28 Hokuriku Alum Kk Uniform color film forming treatment for welded aluminum product

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS60103164A (en) * 1983-11-10 1985-06-07 Kobe Steel Ltd Production of aluminum alloy for vessel of the like
JPS6320500A (en) * 1986-07-11 1988-01-28 Hokuriku Alum Kk Uniform color film forming treatment for welded aluminum product

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5618358A (en) * 1995-03-01 1997-04-08 Davisson; Thomas Aluminum alloy composition and methods of manufacture
JP2010285688A (en) * 2009-05-14 2010-12-24 Fujikura Ltd Al ALLOY AND Al ALLOY CONDUCTIVE WIRE
WO2011071097A1 (en) * 2009-12-11 2011-06-16 株式会社フジクラ Power feed body and method for manufacturing same
JPWO2011071097A1 (en) * 2009-12-11 2013-04-22 株式会社フジクラ Power transmission body and manufacturing method thereof
JP2011252185A (en) * 2010-05-31 2011-12-15 Fujikura Ltd Al ALLOY CONDUCTIVE WIRE

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