JPH01229873A - Washing and bleaching of mop - Google Patents
Washing and bleaching of mopInfo
- Publication number
- JPH01229873A JPH01229873A JP63055817A JP5581788A JPH01229873A JP H01229873 A JPH01229873 A JP H01229873A JP 63055817 A JP63055817 A JP 63055817A JP 5581788 A JP5581788 A JP 5581788A JP H01229873 A JPH01229873 A JP H01229873A
- Authority
- JP
- Japan
- Prior art keywords
- bleaching
- mops
- cleaning
- isocyanuric acid
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000004061 bleaching Methods 0.000 title claims abstract description 19
- 238000005406 washing Methods 0.000 title description 10
- 238000004140 cleaning Methods 0.000 claims abstract description 13
- 150000007973 cyanuric acids Chemical class 0.000 claims abstract description 13
- 238000000034 method Methods 0.000 claims abstract description 10
- 239000003599 detergent Substances 0.000 abstract description 9
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract description 6
- 239000007844 bleaching agent Substances 0.000 abstract description 6
- 239000000460 chlorine Substances 0.000 abstract description 6
- 229910052801 chlorine Inorganic materials 0.000 abstract description 6
- CEJLBZWIKQJOAT-UHFFFAOYSA-N dichloroisocyanuric acid Chemical compound ClN1C(=O)NC(=O)N(Cl)C1=O CEJLBZWIKQJOAT-UHFFFAOYSA-N 0.000 abstract description 6
- IFIDXBCRSWOUSB-UHFFFAOYSA-N potassium;1,3-dichloro-1,3,5-triazinane-2,4,6-trione Chemical compound [K+].ClN1C(=O)NC(=O)N(Cl)C1=O IFIDXBCRSWOUSB-UHFFFAOYSA-N 0.000 abstract description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 abstract 1
- 239000003513 alkali Substances 0.000 abstract 1
- 239000007800 oxidant agent Substances 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 9
- 230000000694 effects Effects 0.000 description 7
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 4
- 239000003795 chemical substances by application Substances 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 3
- 230000000052 comparative effect Effects 0.000 description 3
- 239000000428 dust Substances 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- -1 polyoxyethylene Polymers 0.000 description 3
- 235000019832 sodium triphosphate Nutrition 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000004115 Sodium Silicate Substances 0.000 description 2
- 229920002978 Vinylon Polymers 0.000 description 2
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000002736 nonionic surfactant Substances 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 229910000029 sodium carbonate Inorganic materials 0.000 description 2
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 description 2
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 description 2
- 229910052911 sodium silicate Inorganic materials 0.000 description 2
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- ZKQDCIXGCQPQNV-UHFFFAOYSA-N Calcium hypochlorite Chemical compound [Ca+2].Cl[O-].Cl[O-] ZKQDCIXGCQPQNV-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 239000005708 Sodium hypochlorite Substances 0.000 description 1
- 239000012190 activator Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- WPUINVXKIPAAHK-UHFFFAOYSA-N aluminum;potassium;oxygen(2-) Chemical compound [O-2].[O-2].[Al+3].[K+] WPUINVXKIPAAHK-UHFFFAOYSA-N 0.000 description 1
- ANBBXQWFNXMHLD-UHFFFAOYSA-N aluminum;sodium;oxygen(2-) Chemical compound [O-2].[O-2].[Na+].[Al+3] ANBBXQWFNXMHLD-UHFFFAOYSA-N 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000001768 carboxy methyl cellulose Substances 0.000 description 1
- 239000013522 chelant Substances 0.000 description 1
- 239000002738 chelating agent Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000004090 dissolution Methods 0.000 description 1
- 239000012153 distilled water Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- 229940005740 hexametaphosphate Drugs 0.000 description 1
- 238000011086 high cleaning Methods 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 230000035515 penetration Effects 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 235000019353 potassium silicate Nutrition 0.000 description 1
- 229910052913 potassium silicate Inorganic materials 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000003352 sequestering agent Substances 0.000 description 1
- 230000021148 sequestering of metal ion Effects 0.000 description 1
- 229910001388 sodium aluminate Inorganic materials 0.000 description 1
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 description 1
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 description 1
- 235000019982 sodium hexametaphosphate Nutrition 0.000 description 1
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229910000031 sodium sesquicarbonate Inorganic materials 0.000 description 1
- 235000018341 sodium sesquicarbonate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 description 1
- UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 1
- LWIHDJKSTIGBAC-UHFFFAOYSA-K tripotassium phosphate Chemical compound [K+].[K+].[K+].[O-]P([O-])([O-])=O LWIHDJKSTIGBAC-UHFFFAOYSA-K 0.000 description 1
- RYFMWSXOAZQYPI-UHFFFAOYSA-K trisodium phosphate Chemical compound [Na+].[Na+].[Na+].[O-]P([O-])([O-])=O RYFMWSXOAZQYPI-UHFFFAOYSA-K 0.000 description 1
- WCTAGTRAWPDFQO-UHFFFAOYSA-K trisodium;hydrogen carbonate;carbonate Chemical compound [Na+].[Na+].[Na+].OC([O-])=O.[O-]C([O-])=O WCTAGTRAWPDFQO-UHFFFAOYSA-K 0.000 description 1
Abstract
Description
【発明の詳細な説明】
(産業上の利用分野)
本発明は使用済の汚染された清掃用モツプの効果的な洗
浄漂白方法に関するものである。更に詳しくは汚染され
た清掃用モツプを回転式洗浄機または、ドラム型洗浄機
を用いて洗浄漂白する方法において塩素化イソシアヌル
酸を用いる洗浄漂白方法に関するものである。DETAILED DESCRIPTION OF THE INVENTION Field of the Invention The present invention relates to an effective method for cleaning and bleaching used and contaminated cleaning mops. More specifically, the present invention relates to a cleaning and bleaching method using chlorinated isocyanuric acid in a method of cleaning and bleaching contaminated cleaning mops using a rotary washer or a drum type washer.
(従来技術と問題点)
床面、家具等の清掃に使われるレンタル用モツプはモツ
プコードを基布の片面に、他面はハンドルを固定するモ
ツプホルダーから成るキャンパスから出来ている。使用
して汚染したモツプは回収されワッシャーと呼ばれる回
転式洗浄機によって洗浄漂白処理を行いその後、染色や
吸油処理を行って再びレンタル用モツプとし繰り返し使
用されている。従来この洗浄漂白工程では業務用洗剤を
添加してワッシャーの中またはドラム型洗浄機中で洗浄
漂白を行うが、モツプの中でも特にキャンパス部分の洗
浄漂白は困難であった。(Prior Art and Problems) A rental motsupu used for cleaning floors, furniture, etc. is made of a canvas consisting of a motsupu cord on one side of a base fabric and a motsupu holder on the other side to which a handle is fixed. Used and contaminated motu are collected, washed and bleached using a rotary washing machine called a washer, and then dyed and oil-absorbed before being used again and again as rental motsu. Conventionally, in this washing and bleaching process, commercial detergent is added and washing and bleaching is carried out in a washer or a drum-type washing machine, but washing and bleaching the canvas part of the mop was particularly difficult.
モツプは埃や塵を吸着させて拭き取ることを目的として
いるため、各種の油剤や活性剤を含浸させており、この
油剤成分中に汚れやシミとなる成分が溶は込み、これが
通常の業務用洗浄漂白剤では除去困難の原因となってい
る。Since the purpose of motupu is to absorb and wipe away dust and dust, it is impregnated with various oils and activators, and the components that cause dirt and stains are dissolved in these oil components, which is what makes it difficult to wipe off dirt and dust. This makes it difficult to remove using bleach.
本発明の目的はモツプ特にキャンパス基布を備えたモツ
プの効果的な洗浄漂白方法の提供にある。SUMMARY OF THE INVENTION An object of the present invention is to provide an effective method for cleaning and bleaching mops, especially mops with a canvas base fabric.
(課題を解決するための手段)
本発明者等は上述の問題を解決するために鋭意研究の結
果、塩素系漂白剤の中で次亜塩素酸ナトリウムや高度晒
粉等の無機塩素剤では殆ど漂白効果を示さないが、塩素
化イソシアヌル酸を用いると意外にも極めてモツプの漂
白効果が高い事を見出し本発明を完成した。(Means for Solving the Problems) As a result of intensive research to solve the above-mentioned problems, the present inventors have found that among chlorine bleaches, inorganic chlorine agents such as sodium hypochlorite and highly bleached powder Although it does not show any bleaching effect, the present invention was completed after discovering that the use of chlorinated isocyanuric acid has a surprisingly high effect on bleaching motsu.
即ち本発明は、モツプの洗浄漂白において塩素化イソシ
アヌル酸を用いることを特徴とするモツプの漂白方法に
関する。That is, the present invention relates to a method for bleaching mops, which is characterized by using chlorinated isocyanuric acid in washing and bleaching mops.
塩素化イソシアヌル酸としてはジクロロイソシアヌル酸
ナトリウム、ジクロロイソシアヌル酸ナトリウムの水和
物、ジクロロイソシアヌル酸カリウム等が好ましい。As the chlorinated isocyanuric acid, sodium dichloroisocyanurate, a hydrate of sodium dichloroisocyanurate, potassium dichloroisocyanurate, etc. are preferable.
塩素化イソシアヌル酸を使用するに際しては、無機ビル
ダー及び界面活性剤を併用するのがより好ましい。When using chlorinated isocyanuric acid, it is more preferable to use an inorganic builder and a surfactant together.
無機ビルダーとしては、オルト燐酸ナトリウム、オルト
燐酸カリウム、ヘキサメタ燐酸すトリウム、ヘキサメタ
燐酸カリウム、トリポリ燐酸ナトリウム、トリポリ燐酸
カリウム、メタ珪酸すトリウム、メタ珪酸カリウム及び
アルミン酸ナトリウム、アルミン酸カリウム、硫酸ナト
リウム、炭酸ナトリウム等が挙げられる。Inorganic builders include sodium orthophosphate, potassium orthophosphate, sodium hexametaphosphate, potassium hexametaphosphate, sodium tripolyphosphate, potassium tripolyphosphate, sodium metasilicate, potassium metasilicate and sodium aluminate, potassium aluminate, sodium sulfate, Examples include sodium carbonate.
また、界面活性剤としてはノニオン系界面活性剤或いは
アニオン系界面活性剤が好ましい。Moreover, as the surfactant, a nonionic surfactant or anionic surfactant is preferable.
特に、ノニオン系界面活性剤であるポリオキシエチレン
アルキルエーテルおよび/またはポリオキシエチレンア
ルキルフェノールエーテル等が好ましい。Particularly preferred are nonionic surfactants such as polyoxyethylene alkyl ether and/or polyoxyethylene alkylphenol ether.
塩素化イソシアヌル酸と無機ビルダー及び界面活性剤の
添加量は、塩素化イソシアヌル酸100重量部に対して
無機ビルダーは100〜1000重量部、界面活性剤は
2〜100重量部で用いることが好ましい。The amounts of the chlorinated isocyanuric acid, inorganic builder, and surfactant to be added are preferably 100 to 1000 parts by weight of the inorganic builder and 2 to 100 parts by weight of the surfactant to 100 parts by weight of chlorinated isocyanuric acid.
使用に際しては、有効塩素が100〜11000ppと
なる範囲に調整し、温水を用いて洗浄漂白処理するのが
好ましい。更に、金属封鎖剤として、各種キレート剤や
カルボキシメチルセルロースナトリウム等の再汚染防止
剤等を添加しても良い。In use, it is preferable to adjust the available chlorine to a range of 100 to 11,000 pp, and wash and bleach using warm water. Furthermore, various chelating agents and anti-recontamination agents such as sodium carboxymethylcellulose may be added as metal sequestering agents.
塩素化イソシアヌル酸が他の無機系塩素剤と比較して汚
れたモツプの洗浄漂白効果があるのは、他の無機系塩素
剤はモツプに使用されている油分と親和性がないが、塩
素化イソシアヌル酸はこの油分と親和性があり、また、
次亜塩素酸カルシウム等では、その成分であるカルシウ
ム分が、洗浄剤中にある金属イオン封鎖(キレート)効
果により捕られられることにより、本来の洗剤の効果で
ある浸透、乳化、溶解、分散等の作用が抑えられるため
と思われる。The reason why chlorinated isocyanuric acid is more effective in cleaning and bleaching dirty motsu than other inorganic chlorine agents is that other inorganic chlorine agents have no affinity with the oil used in motu, but chlorinated Isocyanuric acid has an affinity for this oil, and
With calcium hypochlorite, etc., the calcium component is captured by the metal ion sequestration (chelate) effect in the detergent, resulting in the effects of penetration, emulsification, dissolution, and dispersion, which are the original effects of detergents. This is thought to be because the effects of
以下、実施例、比較例をもって本発明を更に詳細に説明
する。Hereinafter, the present invention will be explained in more detail with reference to Examples and Comparative Examples.
実施例1〜7及び比較例1〜6
表−1及び表−2に示すような漂白剤と下記組成の洗剤
を用いて、使用済のモツプのキャンパス部分を4.5c
mX9.Ocmに切り、またモツプの汚れと類似の人工
汚染布(4,5cmX9.Ocm)を用いて以下の評価
を行った。Examples 1 to 7 and Comparative Examples 1 to 6 Using the bleach shown in Tables 1 and 2 and a detergent with the following composition, the canvas part of a used motsu was cleaned by 4.5 cm.
mX9. The following evaluations were carried out using an artificially stained cloth (4.5 cm x 9.0 cm) similar to that of a mop.
〔評価方法]
A8人工汚染布の調整方法
JIS C−9606に準じて木綿及びビニロン布地
で洗濯性能試験の人工汚染布を調整した。[Evaluation Method] Method for Preparing A8 Artificially Stained Fabric Artificially stained fabrics for the washing performance test were prepared using cotton and vinylon fabrics in accordance with JIS C-9606.
B、評価方法
4連式の洗浄力試験機(ターゴツトメーター、ユナイテ
ッドステーツ テスティング カンパニー社製)を用い
て、ステンレスビー力に500m1の蒸留水を入れ、こ
れに表−1及び表−2の漂白剤、および下記C0に記載
の洗剤を1g添加し、WjM後、前記のモツプのキャン
パス(ビニロン基布)あるいは人工汚染布を各々5枚ず
つ入れ、57〜60°C180回転/分で15分間洗浄
後、流水にて濯ぎ洗浄後、30°Cで1時間で温風乾燥
後、モツプのキャンパスの洗浄度合いを測色色差系を用
いて5枚の色の変化を測定しY値の平均値で表した。結
果を表−1及び表−2に示す。B. Evaluation method Using a 4-bar detergency tester (Targottometer, manufactured by United States Testing Company), add 500ml of distilled water to a stainless steel detergent, and add Tables 1 and 2 to it. Add 1g of bleach and detergent described in C0 below, and after WjM, add 5 pieces of each of the Motsupu canvas (vinylon base fabric) or artificially contaminated cloth, and heat at 57-60°C at 180 rotations/min for 15 minutes. After washing for minutes, rinsing with running water, drying with warm air at 30°C for 1 hour, measure the degree of cleaning of the motu canvas by measuring the color change of 5 sheets using a colorimetric color difference system, and average the Y value. Expressed as a value. The results are shown in Table-1 and Table-2.
C1洗剤の組成
(1)ポリオキシエチレンアルキルフ
ェノールエーテル(エチレンオ
キサイドの付加モル数10) 〜−−−−−−− 1
3%(2)トリポリリン酸ナトリウム −−−−−
20(3)炭酸ナトリウム −−−−−
−−−・−・ 20(4)セスキ炭酸ナトリウム
−一−−−−−−25(5)珪酸ナトリウム
−・−・−・−20(6)カルボキシメチル
セルロース
のナトリウム塩 −−−−一−−−−−
−・ 2表−1(実施例)
注) DCCNa : ジクロロイソシアヌル酸ナトリ
ウムDCCNa・211zO:ジクロロイソシアヌル酸
ナトリウムの2永和塩
DCCK ニジクロロイソシアヌル酸カリウム表−2(
比較例)
参考例1〜2
漂白剤を使用しないで実施例で使用した洗剤のみで実施
例と同様に洗浄し、測定した時のY値は以下のようであ
った。Composition of C1 detergent (1) Polyoxyethylene alkylphenol ether (number of added moles of ethylene oxide: 10) ~--------- 1
3% (2) Sodium tripolyphosphate -----
20(3) Sodium carbonate -----
---・-・20(4) Sodium sesquicarbonate
-1-------25(5) Sodium silicate
−・−・−・−20(6) Sodium salt of carboxymethyl cellulose −−−−1−−−−
-・Table 2-1 (Example) Note) DCCNa: Sodium dichloroisocyanurate DCCNa・211zO: Two-elongated salt of sodium dichloroisocyanurate DCCK Potassium dichloroisocyanurate Table-2 (
Comparative Example) Reference Examples 1 and 2 Washing was carried out in the same manner as in the example using only the detergent used in the example without using bleach, and the Y values when measured were as follows.
Y(iη
モノプキャンハス−−m−・−−一一一12.3人工汚
染布 28.2表−1と表−
2を比較すると、本発明の塩素化イソシアヌル酸を用い
る方法が、洗浄漂白効果が高いことを示している。Y(iη Monopcanhas--m-・--111 12.3 Artificially contaminated cloth 28.2 Table-1 and Table-
A comparison of 2 shows that the method using chlorinated isocyanuric acid of the present invention has a high cleaning and bleaching effect.
特許出願人 日産化学工業株式会社Patent applicant: Nissan Chemical Industries, Ltd.
Claims (1)
を用いることを特徴とするモップの洗浄漂白方法。(1) A method for cleaning and bleaching mops, which comprises using chlorinated isocyanuric acid in cleaning and bleaching mops.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63055817A JP2845369B2 (en) | 1988-03-09 | 1988-03-09 | How to wash and bleach mop |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63055817A JP2845369B2 (en) | 1988-03-09 | 1988-03-09 | How to wash and bleach mop |
Publications (2)
Publication Number | Publication Date |
---|---|
JPH01229873A true JPH01229873A (en) | 1989-09-13 |
JP2845369B2 JP2845369B2 (en) | 1999-01-13 |
Family
ID=13009497
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63055817A Expired - Lifetime JP2845369B2 (en) | 1988-03-09 | 1988-03-09 | How to wash and bleach mop |
Country Status (1)
Country | Link |
---|---|
JP (1) | JP2845369B2 (en) |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4830713A (en) * | 1971-08-23 | 1973-04-23 | ||
JPS5428283A (en) * | 1977-08-05 | 1979-03-02 | Kirisan Kasei Kk | Bleaching agent |
JPS5847509A (en) * | 1981-09-12 | 1983-03-19 | Daido Steel Co Ltd | Manufacture of tapered rod |
JPS606400A (en) * | 1983-05-28 | 1985-01-14 | 土田 勝久 | Die edge tool |
JPS62136984U (en) * | 1986-02-21 | 1987-08-28 |
-
1988
- 1988-03-09 JP JP63055817A patent/JP2845369B2/en not_active Expired - Lifetime
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS4830713A (en) * | 1971-08-23 | 1973-04-23 | ||
JPS5428283A (en) * | 1977-08-05 | 1979-03-02 | Kirisan Kasei Kk | Bleaching agent |
JPS5847509A (en) * | 1981-09-12 | 1983-03-19 | Daido Steel Co Ltd | Manufacture of tapered rod |
JPS606400A (en) * | 1983-05-28 | 1985-01-14 | 土田 勝久 | Die edge tool |
JPS62136984U (en) * | 1986-02-21 | 1987-08-28 |
Also Published As
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JP2845369B2 (en) | 1999-01-13 |
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