JPH01228447A - Taste improver for beverage - Google Patents

Taste improver for beverage

Info

Publication number
JPH01228447A
JPH01228447A JP63052752A JP5275288A JPH01228447A JP H01228447 A JPH01228447 A JP H01228447A JP 63052752 A JP63052752 A JP 63052752A JP 5275288 A JP5275288 A JP 5275288A JP H01228447 A JPH01228447 A JP H01228447A
Authority
JP
Japan
Prior art keywords
beverage
taste
beverages
calcium phosphate
coffee
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63052752A
Other languages
Japanese (ja)
Inventor
Hideki Aoki
秀希 青木
Yoshiharu Hata
秦 義治
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Advance Co Ltd
Original Assignee
Advance Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Advance Co Ltd filed Critical Advance Co Ltd
Priority to JP63052752A priority Critical patent/JPH01228447A/en
Publication of JPH01228447A publication Critical patent/JPH01228447A/en
Pending legal-status Critical Current

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  • Non-Alcoholic Beverages (AREA)
  • Tea And Coffee (AREA)

Abstract

PURPOSE:To improve such tastes as mildness, aftertaste and easiness to drink, of beverages such as drinking water, coffee, tea, Japanese tea or juices, by using, as the title improver, a calcium phosphate-based ceramic. CONSTITUTION:The objective taste improver consisting of a calcium phosphate- based ceramic, e.g., hydroxyapatite [Ca10(PO4)6(OH)2] produced by compression molding, to a desired shape, powder with a molar ratio Ca/P=1.67 formed by e.g., a wet process under a pressure of 500-3,000kg/cm<2> using e.g., a rubber press, followed by sintering the resultant form at 70-1,500 deg.C. This improver is applied on beverages.

Description

【発明の詳細な説明】 本発明は、水道水等の飲料水、コーヒー、紅茶等の嗜好
飲料、ジュース等の清涼飲料の味覚を改善する為の改善
材に関する。
DETAILED DESCRIPTION OF THE INVENTION The present invention relates to an improving material for improving the taste of drinking water such as tap water, beverages such as coffee and tea, and soft drinks such as juice.

通常、生活で飲料用に使用する水道水、或いは喫茶店、
乗り物等で供給される飲料水は、人体に無害であること
を目的とし、単に殺菌処理を施しであるものが多く、逆
に殺菌処理の為に生ずる塩素等の影響は、飲む者に対し
て刺激を与える結果となっている。これらの点は、浄水
器を利用して解消されるものであるが、各地方に出向い
た場合、常時浄水器が置いであるものとは限らない。そ
の上、浄水器を使用して浄化した水でも、各地方によっ
て水質が異なり、初めて飲む水には味覚工種々な刺激、
を感するものである。
Tap water that is normally used for drinking in daily life, or from coffee shops,
Drinking water supplied by vehicles, etc. is intended to be harmless to the human body, and is often simply sterilized; on the other hand, the effects of chlorine, etc., produced during sterilization have a negative impact on the drinker. The result is stimulating. These problems can be solved by using water purifiers, but when you go to each region, water purifiers are not always available. Furthermore, even if the water is purified using a water purifier, the quality of the water varies depending on the region, and the water you drink for the first time may have various stimulants on your taste buds.
It is something that you can feel.

このことは飲料水に限らず、コーヒー、紅茶等の嗜好飲
料或いはジュース等の清涼飲料に於いても、一方的提供
されるものに関しては同じようなことが指摘された。
It has been pointed out that this is not limited to drinking water, but also applies to beverages such as coffee and tea, and soft drinks such as juice, which are provided unilaterally.

上記に鑑み本発明者らは、ハイドロキシアパタイト等リ
ン酸カルシウム系セラミックスが、少なくとも飲料中に
存在する苦味やピリッとした味覚上の刺激を解消してく
れることを知見し、本発明に到達したものである。
In view of the above, the present inventors have discovered that calcium phosphate ceramics such as hydroxyapatite eliminate at least the bitterness and pungent taste irritation present in beverages, and have arrived at the present invention. .

以下本発明につき、その材料組成及び製法、形状、使用
態様等につき詳細に分脱する。
The present invention will be described in detail below regarding its material composition, manufacturing method, shape, usage mode, etc.

材料組成 本発明に於けるリン酸カルシウム系セラミックスとは、
人工的に合成したハイドロキシアパタイト(Ca+o(
PO+)e(OH)、)を初めとして、タラ骨等より精
製した天然骨粉、リン酸三カルシウム、リン酸四カルシ
ウム等を指し示す。
Material Composition Calcium phosphate ceramics in the present invention are:
Artificially synthesized hydroxyapatite (Ca+o(
PO+)e(OH),), natural bone powder purified from cod bones, tricalcium phosphate, tetracalcium phosphate, etc.

他方、その製法は、ハイドロキシアパタイトを例とする
と、Ca/Pモル比が1,67湿式法等、従来の方法で
生成した粉末を、ラバープレス等により500〜300
0kg/cm”程度の圧力下、所望形状に圧縮成形し、
次いでこれを700〜1500°C程度の温間で焼結処
理して得られるものであるが、より詳しくは下記公知技
術が参照される。すなわち、特開昭51−40400.
同52−142707、同52−147606、同52
−149895、同53−110999、特公昭57−
40776及び同57−40803号公報。
On the other hand, in the production method, taking hydroxyapatite as an example, powder produced by a conventional method such as a wet method with a Ca/P molar ratio of 1.67 and a Ca/P molar ratio of 500 to 300 using a rubber press or the like is used.
Compression molding into the desired shape under a pressure of about 0 kg/cm'',
This is then obtained by sintering it at a warm temperature of about 700 to 1500°C. For more details, refer to the following known techniques. That is, JP-A-51-40400.
52-142707, 52-147606, 52
-149895, 53-110999, Special Publication 1977-
No. 40776 and No. 57-40803.

飲  料 本発明に於ける飲料は、水道水、井戸水等の飲料水、コ
ーヒー、紅茶、日本茶、ジュース等の嗜好飲料水である
Beverage Beverages in the present invention include drinking water such as tap water and well water, and recreational drinking water such as coffee, black tea, Japanese tea, and juice.

形状乃至構造 本発明飲料用味覚改善材は、使用目的に応じて所望のも
のとなし得るが、その典型的な形状としては、次に掲げ
るものがある。
Shape or Structure The taste improving material for beverages of the present invention can be made into any desired shape depending on the purpose of use, and typical shapes include the following.

1、棒状支持体の一端にリン酸カルシウム系セラミック
ス材の緻密体を接続固定したもの、或いは粉末による射
出成形層を形成した、いわゆる攪拌棒状のもの。
1. A rod-shaped support with a dense body of calcium phosphate ceramic material connected and fixed to one end, or a so-called stirring rod-shaped support with an injection molded layer of powder formed thereon.

2、顆粒状のリン酸カルシウム系セラミックスを綿状袋
に収納し、更に綿状袋に把持用の糸を接続した、いわゆ
るティーバッグ状のもの。
2. A so-called tea bag-like product in which granular calcium phosphate ceramics are housed in a cotton-like bag, and a gripping thread is connected to the cotton-like bag.

3、飲料抽出口(水道であれば蛇口)に、リン酸カルン
ウム系セラミックス多孔質を収納した容器を接続し、飲
料が容器中のリン酸カルンウム系セラミックス層内を通
過するようにした濾過器タイプとしたもの。
3. A filter type in which a container containing porous carunium phosphate ceramic is connected to the beverage outlet (faucet if it is a water supply), and the beverage passes through the carunium phosphate ceramic layer in the container. What was said.

4、容器の一部にはめ込んだもの。4. Something that is fitted into a part of the container.

5、容器状に成形したもの。5. Shaped into a container.

上記形状を取る本発明改善材の使用態様としては、1.
2の場合は、カップ、グラス等に抽かれた飲料に、攪拌
棒又はティーカップ状に形成した本発明改善材を入れ、
数回かき回せば足りるものである。又、3の場合は、飲
料が本発明改善材を通過すれば足りるものである。4゜
5の場合は、容器自体がリン酸カルシウム系セラミック
スとして形成されているものであるから、容器の中へ飲
料を入れれば足りるものである。
Usage modes of the improved material of the present invention having the above shape include 1.
In case 2, the improved material of the present invention formed in the shape of a stirring rod or teacup is placed in a drink brewed in a cup, glass, etc.
It is enough to stir it several times. Further, in case 3, it is sufficient that the beverage passes through the improving material of the present invention. In the case of 4°5, since the container itself is made of calcium phosphate ceramics, it is sufficient to put the beverage into the container.

即ち本発明に示すリン酸カルシウム系セラミックスは、
飲料中の味覚を悪化させる原因物質を吸着する能力に浸
れており、その具体的吸着性能は次に示す実験で明らか
である。
That is, the calcium phosphate ceramics shown in the present invention are
It has the ability to adsorb substances that cause taste deterioration in beverages, and its specific adsorption performance is clear in the following experiment.

実験l 味覚改善材は、湿式合成したアパタイトを転動造粒した
後、1100°Cで焼成したφ3.8mm、密度90%
、1粒当たり30mgの顆粒体とした。
Experiment 1 The taste improving material was made by rolling granulating wet-synthesized apatite and then firing it at 1100°C.The material had a diameter of 3.8 mm and a density of 90%.
, granules weighing 30 mg per granule.

この合成アパタイト顆粒体を府中市水道水(l 1. 
m Q )に浸漬、攪拌後、室温で1時間静置、5A濾
紙で濾過した後、残留塩素についてDPD比色法により
測定した。
This synthetic apatite granule was mixed with Fuchu City tap water (l 1.
m Q ), stirred, left at room temperature for 1 hour, filtered through 5A filter paper, and residual chlorine was measured by DPD colorimetry.

一方、合成アパタイトを浸漬しない水道水の残留塩素に
ついても測定した。
On the other hand, residual chlorine in tap water in which synthetic apatite was not immersed was also measured.

結果を第1表に示す。The results are shown in Table 1.

第1表 第1表から、味覚を悪質化する塩素の吸着が行なわれて
いることが知見された。
Table 1 From Table 1, it was found that chlorine, which deteriorates the taste, was adsorbed.

実験2 味覚改善材は、脱脂タラ骨粉(大洋化学工業製)を70
0℃で焼成した後、乳鉢で粉砕した天然アパタイト粉末
とした。
Experiment 2 The taste improving material was defatted cod bone powder (manufactured by Taiyo Kagaku Kogyo) at 70%
After firing at 0°C, it was ground in a mortar to obtain natural apatite powder.

上記天然アパタイト粉末を府中市水道水50mQにIg
加え、攪拌した後、約10分室温中に静置した。静置後
濾過し、この濾過した水道水中の遊離残留塩素の濃度に
ついて測定した。一方、天然アパタイトを加えない水道
水の遊離残留塩素についても測定した。
Ig the above natural apatite powder in 50 mQ of Fuchu city tap water.
After addition and stirring, the mixture was allowed to stand at room temperature for about 10 minutes. After standing still, it was filtered, and the concentration of free residual chlorine in the filtered tap water was measured. On the other hand, free residual chlorine in tap water without natural apatite added was also measured.

結果を第2表に示す。The results are shown in Table 2.

第2表 第2表から、実験1と同様、塩素の吸着が行なわれてい
ることが明らかとなった。
Table 2 From Table 2, it was revealed that chlorine was adsorbed as in Experiment 1.

実験3 味覚改善材は、脱脂タラ骨を1200℃で焼成した後、
乳鉢で粉砕した粉末を打鍵機にかけ、相対密度85%、
1粒当たりio、5mgの錠剤とした。
Experiment 3 The taste improving material was made by baking defatted cod bones at 1200°C.
The powder crushed in a mortar was put through a key press, and the relative density was 85%.
Each tablet was io, 5 mg.

この錠剤を、約75°Cの鳩(府中市水道)に粉末コー
ヒーを溶かして生成したコーヒー飲料に浸漬、軽く攪拌
した後、約20mQずつ採って、5分後、15分後、4
0分後、80分後にpl測定を行った。
The tablets were immersed in a coffee drink made by dissolving powdered coffee in Hato (Fuchu City Suido) at about 75°C, stirred lightly, and then taken in portions of about 20 mQ.After 5 minutes, after 15 minutes,
PL measurements were performed after 0 minutes and 80 minutes.

一方、アパタイト顆粒体を浸漬しないコーヒーのpHも
、前記と同じ時刻に測定した。
On the other hand, the pH of the coffee without soaking the apatite granules was also measured at the same time as above.

結果を第3表に示す。The results are shown in Table 3.

第3表 第3表から、通常pHが弱酸性を示すインスタントコー
ヒーが、アパタイトの浸漬によって中性方向へと移項し
、ピリゾとした刺激に係る酸味の基となるクロロゲン酸
等の吸着が行なわれたことを示している。
Table 3 Table 3 shows that instant coffee, which normally has a slightly acidic pH, shifts to a neutral pH by soaking in apatite, and adsorption of chlorogenic acid, etc., which is the source of the sour taste associated with the pyrizoic irritation, takes place. It shows that

実験4 味覚改善材は、脱脂タラ骨粉(大洋化学工業製)を乳鉢
で粉砕した粉末を打錠機にかけ、1200℃で焼成し、
相対密度85%、口径3.8mm。
Experiment 4 The taste improving material was prepared by crushing defatted cod bone powder (manufactured by Taiyo Kagaku Kogyo) in a mortar, applying it to a tablet machine, and baking it at 1200°C.
Relative density 85%, diameter 3.8mm.

100mgのアパタイト錠剤とした。It was made into a 100 mg apatite tablet.

上記アパタイト錠剤9.Ogを、70°Cの湯120m
σにインスタントコーヒー粉末2.4gを溶かして得た
コーヒー飲料に浸漬し、1時間放置した後、アパタイト
錠剤を取り出し、錠剤中のタンニン及び無水カフェイン
の量を分析した。
The above apatite tablet9. Og, 70°C hot water 120m
The apatite tablets were immersed in a coffee beverage prepared by dissolving 2.4 g of instant coffee powder in σ, left for 1 hour, and then taken out, and the amounts of tannin and anhydrous caffeine in the tablets were analyzed.

結果を第4表に示す。The results are shown in Table 4.

第4表 第4表から、インスタントコーヒーに執拗な苦味、刺激
を与えるタンニン、無水カフェイン等がアパタイトによ
り吸着除去され、味覚の改善が行なわれていることを知
見した。
Table 4 From Table 4, it was found that tannins, anhydrous caffeine, etc. that give instant coffee a persistent bitter taste and irritation were adsorbed and removed by apatite, thereby improving the taste.

次に、味覚官能評価により本発明を具体的に説明する。Next, the present invention will be specifically explained using taste sensory evaluation.

実験5 脱脂タラ骨粉を700°Cで焼成した後、乳鉢で粉砕し
た粉末を打錠機にかけ、相対密度85%、1粒当たりi
o、5mgの天然アパタイト錠剤を得た。
Experiment 5 After calcining defatted cod bone powder at 700°C, the powder was crushed in a mortar and then applied to a tablet machine, with a relative density of 85% and i per tablet.
o. 5 mg of natural apatite tablets were obtained.

75℃の湯に2.4gのインスタントコーヒーを溶かし
て得たコーヒー飲料に上記錠剤を1分間浸し攪拌後、2
0名のパネルによって官能評価を行なった。
The above tablets were immersed in a coffee beverage obtained by dissolving 2.4 g of instant coffee in 75°C hot water for 1 minute and stirred.
Sensory evaluation was performed by a panel of 0 people.

結果を第5表に示す。The results are shown in Table 5.

(以下空欄) 第5表 いずれの項目ら危険率1%以下で有意差があった。(Blank below) Table 5 There was a significant difference in all items with a risk rate of 1% or less.

特許出願人 株式会社アドバンスPatent applicant Advance Co., Ltd.

Claims (3)

【特許請求の範囲】[Claims] (1)飲料を通過させることによって飲料の味覚を改善
させる物質がリン酸カルシウム系セラミックスであるこ
とを特徴とする飲料用味覚改善材。
(1) A taste-improving material for beverages, characterized in that the substance that improves the taste of a beverage by passing the beverage through it is a calcium phosphate ceramic.
(2)飲料中に浸すことによって飲料の味覚を改善させ
る物質がリン酸カルシウム系セラミックスであることを
特徴とする飲料用味覚改善材。
(2) A taste-improving material for a beverage, characterized in that the substance that improves the taste of a beverage by being immersed in the beverage is a calcium phosphate ceramic.
(3)飲料が、飲料水、嗜好飲料、清涼飲料であること
を特徴とする飲料用味覚改善材。
(3) A taste-improving material for beverages, characterized in that the beverage is drinking water, a recreational beverage, or a soft drink.
JP63052752A 1988-03-08 1988-03-08 Taste improver for beverage Pending JPH01228447A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63052752A JPH01228447A (en) 1988-03-08 1988-03-08 Taste improver for beverage

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63052752A JPH01228447A (en) 1988-03-08 1988-03-08 Taste improver for beverage

Publications (1)

Publication Number Publication Date
JPH01228447A true JPH01228447A (en) 1989-09-12

Family

ID=12923629

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63052752A Pending JPH01228447A (en) 1988-03-08 1988-03-08 Taste improver for beverage

Country Status (1)

Country Link
JP (1) JPH01228447A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999064619A2 (en) * 1998-06-10 1999-12-16 Novozymes A/S Novel mannanases

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4943444A (en) * 1972-08-31 1974-04-24
JPS5745386A (en) * 1980-08-29 1982-03-15 Tdk Corp Additive for ionized water manufacturing device
JPS59145087A (en) * 1983-02-09 1984-08-20 Saga Shoko:Kk Sintered body for purification of drinking water

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS4943444A (en) * 1972-08-31 1974-04-24
JPS5745386A (en) * 1980-08-29 1982-03-15 Tdk Corp Additive for ionized water manufacturing device
JPS59145087A (en) * 1983-02-09 1984-08-20 Saga Shoko:Kk Sintered body for purification of drinking water

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO1999064619A2 (en) * 1998-06-10 1999-12-16 Novozymes A/S Novel mannanases
WO1999064619A3 (en) * 1998-06-10 2000-03-02 Novo Nordisk As Novel mannanases

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