JPH01215395A - Water treating device - Google Patents
Water treating deviceInfo
- Publication number
- JPH01215395A JPH01215395A JP63037422A JP3742288A JPH01215395A JP H01215395 A JPH01215395 A JP H01215395A JP 63037422 A JP63037422 A JP 63037422A JP 3742288 A JP3742288 A JP 3742288A JP H01215395 A JPH01215395 A JP H01215395A
- Authority
- JP
- Japan
- Prior art keywords
- water
- column
- sand filter
- tower
- ozone
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 51
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 42
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 claims abstract description 30
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 238000009287 sand filtration Methods 0.000 claims 2
- 239000007788 liquid Substances 0.000 claims 1
- 239000004576 sand Substances 0.000 abstract description 22
- 230000003647 oxidation Effects 0.000 abstract description 8
- 238000007254 oxidation reaction Methods 0.000 abstract description 8
- 229910052799 carbon Inorganic materials 0.000 abstract description 4
- 238000009792 diffusion process Methods 0.000 abstract 1
- 244000005700 microbiome Species 0.000 description 11
- 238000000034 method Methods 0.000 description 5
- 238000000746 purification Methods 0.000 description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 4
- 239000005416 organic matter Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
- 229910052801 chlorine Inorganic materials 0.000 description 3
- 239000000460 chlorine Substances 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 241001465754 Metazoa Species 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- 238000011001 backwashing Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 230000000813 microbial effect Effects 0.000 description 2
- 238000006385 ozonation reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 238000004659 sterilization and disinfection Methods 0.000 description 2
- 241000700605 Viruses Species 0.000 description 1
- 238000005273 aeration Methods 0.000 description 1
- 150000001299 aldehydes Chemical class 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 150000001735 carboxylic acids Chemical class 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 238000004042 decolorization Methods 0.000 description 1
- 238000004332 deodorization Methods 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000035622 drinking Effects 0.000 description 1
- 239000003651 drinking water Substances 0.000 description 1
- 235000020188 drinking water Nutrition 0.000 description 1
- 238000004299 exfoliation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000007269 microbial metabolism Effects 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 239000008213 purified water Substances 0.000 description 1
- 239000002351 wastewater Substances 0.000 description 1
Landscapes
- Treatment Of Water By Oxidation Or Reduction (AREA)
- Filtration Of Liquid (AREA)
- Water Treatment By Sorption (AREA)
Abstract
Description
【発明の詳細な説明】 〔発明の目的〕 (産業上の利用分野) 本発明は汚染された水を浄化する水処理装置に関する。[Detailed description of the invention] [Purpose of the invention] (Industrial application field) The present invention relates to a water treatment device for purifying contaminated water.
(従来の技術) 従来よりオゾンの酸化力は、水処理技術で殺菌。(Conventional technology) Traditionally, ozone's oxidizing power has been used to sterilize water using water treatment technology.
脱色・脱臭、有機物の酸化などに利用されてきた。It has been used for decolorization, deodorization, and oxidation of organic substances.
しかし、有機物を多く含む水にオゾン処理を行うとアル
デヒド、ケトン、カルボン酸などの酸化生成物が生成し
、飲料水として安心できるものではなかった。However, when water containing a large amount of organic matter is subjected to ozone treatment, oxidation products such as aldehydes, ketones, and carboxylic acids are produced, making the water unsafe for drinking.
近年、ヨーロッパを中心に開発された浄水方法ではオゾ
ン処理後の水を活性炭層を通しているうちに活性炭表面
に微生物が生育し、オゾン酸化生成物を食物として浄化
し、更に好都合なことは、オゾンで処理できないアンモ
ニアも微生物の代謝で浄化され、活性炭の寿命を長くす
ると言う方法である。最近、わが国の水源、特に河川水
の汚染によりこの水処理方法が注目されている。In recent years, water purification methods developed mainly in Europe allow microorganisms to grow on the activated carbon surface while water after ozonation is passed through an activated carbon layer, purifying the ozone oxidation products as food. In this method, unprocessable ammonia is purified by microbial metabolism, extending the lifespan of activated carbon. Recently, this water treatment method has been attracting attention due to the pollution of water sources in Japan, especially river water.
(発明が解決しようとする課題)
しかし、従来、飲料水の浄化で広く利用されていた薬剤
、つまり浄化工程での微生物損害を防止する塩素は、浄
化後の残留塩素として使用されるだけで、オゾン処理の
前段の砂ろ過塔は殺菌されないまま運転される。(Problems to be Solved by the Invention) However, the chemicals that have been widely used in the purification of drinking water, namely chlorine, which prevents microbial damage during the purification process, are only used as residual chlorine after purification. The sand filter tower before ozonation is operated without being sterilized.
長期運転によって、砂ろ過塔には微生物、小動物が生育
する。定期的に逆洗されるる床での付着生物の生育は一
定量に保たれるが砂ろ過塔下部。Due to long-term operation, microorganisms and small animals grow in the sand filter tower. The growth of attached organisms on the floor that is regularly backwashed is kept at a constant level, but at the bottom of the sand filter tower.
オゾン反応塔への配管では、壁面などに付着生育したス
ライム状の固まりが剥離して、オゾン反応塔と活性炭塔
へ流れ込む、特に膜状の剥離物は、オゾン反応塔の気泡
上昇により上部へ繰返し運ばれ、塔から排出されにくい
。この間オゾンと長時間接触、オゾンを多く消費し、酸
化された水溶性の有機物の生成を起こす。膜状剥離物は
活性炭塔へ入っても逆洗時排出されにくく、また活性炭
塔の流量低下を早めると言う問題があった。In the piping to the ozone reaction tower, slime-like lumps that have grown on the walls are peeled off and flow into the ozone reaction tower and activated carbon tower.In particular, the film-like peeled off material is repeatedly sent to the upper part as bubbles rise in the ozone reaction tower. It is difficult to be transported and discharged from the tower. During this period, it comes into contact with ozone for a long time, consumes a large amount of ozone, and generates oxidized water-soluble organic substances. There was a problem in that even if the film-like peeled material entered the activated carbon tower, it was difficult to be discharged during backwashing, and it also accelerated the decrease in the flow rate of the activated carbon tower.
本発明は簡単な装置と操作によって従来法の欠点を解決
する水処理装置を提供するものである。The present invention provides a water treatment device that solves the drawbacks of conventional methods with simple equipment and operation.
(課題を解決するための手段)
本発明は有機物、アンモニアなどを含む水を砂ろ適役、
オゾン処理し、活性炭を通して水を浄化するものにおい
て、定期的に完全に排水した後、砂ろ過塔下部とオゾン
反応塔への配管内表面にオゾン化ガスを通して微生物の
殺菌、スライムの剥離を行うことを特徴とする水処理装
置である。(Means for Solving the Problems) The present invention provides water containing organic matter, ammonia, etc.
In equipment that purifies water through ozone treatment and activated carbon, after periodically completely draining the water, ozonated gas is passed through the lower part of the sand filter tower and the inner surface of the piping to the ozone reaction tower to sterilize microorganisms and remove slime. This is a water treatment device featuring:
(作用)
本発明は砂ろ過塔下部とオゾン反応塔への配管を定期的
にオゾン化ガスを通して、スライムなど付着生育を防止
し、膜状剥離物の生育をなくすものである。(Function) The present invention regularly passes ozonized gas through the pipes between the lower part of the sand filter tower and the ozone reaction tower to prevent the growth of slime and other adhesion and eliminate the growth of film-like exfoliated substances.
(実施例)
本発明の実施例を図面を用いて説明する1図面の水処理
装置は、砂ろ通塔1とオゾン反応塔2と活性炭塔3の主
要部分から構成される。(Example) An example of the present invention will be explained with reference to the drawings. The water treatment apparatus shown in FIG. 1 is composed of the main parts of a sand filter tower 1, an ozone reaction tower 2, and an activated carbon tower 3.
有機物、濁質なとで汚染された原水は、砂ろ通塔1の上
部導管4より入り、砂ろ適法5を通り濁質の除かれた水
が下部より導管6を通りオゾン反応塔2でオゾン酸化を
受ける。オゾン化ガスは、オゾン反応塔2の下部の散気
管7より水中に注入され、排ガス管8より未反応のオゾ
ン化ガスが排出される。オゾン酸化を受けた水はオゾン
反応塔下部の導管9より活性炭塔3上部に導入され、活
性炭層10を通り、浄化された水が塔下部配管11より
得られる。Raw water contaminated with organic matter and turbidity enters the upper conduit 4 of the sand filter tower 1, passes through the sand filter 5, removes the turbidity, and passes through the lower part through the conduit 6 to the ozone reaction tower 2. undergoes ozone oxidation. The ozonized gas is injected into the water through the diffuser pipe 7 at the bottom of the ozone reaction tower 2, and the unreacted ozonized gas is discharged from the exhaust gas pipe 8. Water that has undergone ozone oxidation is introduced into the upper part of the activated carbon tower 3 from a conduit 9 at the bottom of the ozone reaction tower, passes through an activated carbon layer 10, and purified water is obtained from a pipe 11 at the bottom of the tower.
長期間使用していると、砂ろ通塔lで除去された濁質の
量が多くなり、砂ろ適法5の抵抗が太きくなるため、逆
洗水配管12より逆洗水を入れ、砂ろ適法5を逆洗し、
濁質を排水配管13より塔外へ排出させ、再び砂ろ適法
を静置し、原水を通す。When used for a long period of time, the amount of suspended solids removed by the sand filter passing tower 1 increases, and the resistance of the sand filter method 5 increases. Backwash filtration method 5,
The suspended solids are discharged from the tower through the drainage pipe 13, the sand filter is left still, and the raw water is passed through.
活性炭塔3でも同様に長期の使用では、オゾン処理水中
の酸化生成物が活性炭表面に生育した微生物により代謝
され、微生物量が多くなり活性炭層10の抵抗が大きく
なるため、逆洗水配管14より逆洗水を入れ活性炭層1
0を崩し、流動させ、活性炭表面についた微生物を剥離
し逆洗排水として配管15より塔外へ排出し、再び活性
炭層10を静置させ、オゾン処理水を通す。Similarly, when the activated carbon tower 3 is used for a long time, the oxidation products in the ozonated water are metabolized by the microorganisms grown on the activated carbon surface, and the amount of microorganisms increases and the resistance of the activated carbon layer 10 increases. Add backwash water and activate carbon layer 1
The microorganisms attached to the surface of the activated carbon are peeled off and discharged to the outside of the tower from the piping 15 as backwash wastewater, and the activated carbon layer 10 is allowed to stand still again, and ozonated water is passed through.
この浄水方法は活性炭表面の微生物の効果を最大限に利
用するため残留性の強い塩素を使用しない。このため、
オゾンに接する以前の有機物の多い水を通す装置内面に
は微生物、小動物が生育することになる。特に、砂ろ通
塔1の下部壁面、導管6の内面に付着生育したスライム
が膜状の固まりとなって剥離し、オゾン反応塔2.活性
炭塔3に障害を起こすことになる。This water purification method makes maximum use of the effects of microorganisms on the surface of activated carbon, so it does not use chlorine, which has strong residual properties. For this reason,
Microorganisms and small animals grow on the inside of the device that passes water rich in organic matter before it comes into contact with ozone. In particular, the slime that has grown on the lower wall of the sand filter tower 1 and the inner surface of the conduit 6 becomes a film-like mass and peels off. This will cause damage to the activated carbon tower 3.
本発明は、砂ろ通塔1の下部に排水時、底部に水が滞留
しないよう傾斜をつけるドレン弁Aから完全に排水した
後、定期的にオゾン化ガスを導入し、砂ろ通塔1の下部
に導管6の内面を殺菌することにより壁面に生育する微
生物、膜状の付着物の生成を防止するものである6
オゾン化ガスはオゾン反応塔上部に排出される未反応オ
ゾンガスでも表面殺菌には十分利用できるため、ドレン
弁Aから排水する時、オゾン反応塔2へ散気管7から注
入されるオゾン化ガスの注入ガス流量と同量で排水を行
えば、排オゾンをそのまま導入することができる。また
分配管16によりオゾン化ガスを高濃度のまま弁Bから
直接導入することもできる。In the present invention, when draining water to the lower part of the sand filter tower 1, after the water is completely drained from the drain valve A which is sloped so that water does not accumulate at the bottom, ozonized gas is periodically introduced into the sand filter tower 1. By sterilizing the inner surface of the conduit 6 at the bottom of the ozone reactor, it is possible to prevent microorganisms growing on the wall surface and the formation of film-like deposits. Therefore, when draining water from the drain valve A, if the same amount as the flow rate of the ozonized gas injected into the ozone reaction tower 2 from the aeration pipe 7 is used, the exhausted ozone can be introduced as is. Can be done. Further, the ozonized gas can be directly introduced from valve B using the distribution pipe 16 while remaining at a high concentration.
底部に水の滞留部があると、水面下の塔、配管表面の微
生物殺菌効果は不完全となり、長期的には膜状剥離物を
生成するため砂ろ通塔底部に傾斜をつけ全表面を同時に
殺菌することが重要である。If water remains at the bottom, the microbial sterilization effect on the surface of the tower and pipes below the water surface will be incomplete, and in the long run, film-like exfoliation will occur. It is important to sterilize at the same time.
オゾン化ガスでの殺菌は10分程度で十分であり使用後
の未反応オゾン化ガスの排出は、砂ろ通塔6に通水すれ
ば自動的に配管6を通り配管8から排出される。Sterilization with ozonized gas takes about 10 minutes, and unreacted ozonized gas after use is discharged automatically through piping 6 through piping 8 when water is passed through sand filter tower 6.
これらの操作は特に砂ろ過装置1の逆洗前に行えば効果
的である。These operations are particularly effective if performed before backwashing the sand filter device 1.
オゾンは水中の微生物、ビールスを殺菌、不活性化する
ことが知られており、配管内面に付着生育する微生物、
スライムをも殺菌、剥離することも確認されている。底
部に傾斜をつけ完全に排水した後、砂ろ通塔の下部、配
管の内面に定期的にオゾン化ガスを導入すれば表面に生
育する微生物を殺菌でき障害を起こす膜状剥離物まで生
長することはなく、安心して水処理が行える。Ozone is known to sterilize and inactivate microorganisms and viruses in water.
It has also been confirmed that it can also sterilize and exfoliate slime. After sloping the bottom and draining the water completely, introducing ozonized gas periodically to the bottom of the sand filter tower and the inside of the piping can kill the microorganisms growing on the surface and prevent them from growing into film-like flakes that can cause problems. Water treatment can be carried out with peace of mind.
図面は本発明の一実施例を示す水処理装置の構成図であ
る。
1・・・砂ろ通塔 2・・・オゾン反応塔3・
・・活性炭塔 16・・・分配管A・・・ドレ
ン弁 B・・・弁代理人 弁理士 則 近 憲
佑
同 山 下 −The drawing is a configuration diagram of a water treatment device showing an embodiment of the present invention. 1... Sand filter tower 2... Ozone reaction tower 3.
...Activated carbon tower 16...Distribution pipe A...Drain valve B...Valent agent Patent attorney Noriyuki Chika Yudo Yamashita -
Claims (1)
ゾン反応塔と、オゾン処理水を通す活性炭塔とによって
水を浄化する水処理装置において、砂ろ過塔下部とオゾ
ン反応塔への配管内との全表面をオゾン化ガスにより殺
菌を行うため、排水時底部に水の滞留部をなくした砂ろ
過塔を具備してなる水処理装置。Water that has passed through the sand filtration tower is purified by an ozone reaction tower that brings ozonized gas into gas-liquid contact and an activated carbon tower that passes the ozonated water. This water treatment equipment is equipped with a sand filtration tower that eliminates water retention at the bottom during drainage, in order to sterilize the interior and all surfaces using ozonized gas.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63037422A JPH01215395A (en) | 1988-02-22 | 1988-02-22 | Water treating device |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP63037422A JPH01215395A (en) | 1988-02-22 | 1988-02-22 | Water treating device |
Publications (1)
Publication Number | Publication Date |
---|---|
JPH01215395A true JPH01215395A (en) | 1989-08-29 |
Family
ID=12497086
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP63037422A Pending JPH01215395A (en) | 1988-02-22 | 1988-02-22 | Water treating device |
Country Status (1)
Country | Link |
---|---|
JP (1) | JPH01215395A (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03157186A (en) * | 1989-11-14 | 1991-07-05 | Isomura Housui Kiko Kk | Water cleaning treatment device |
KR100337541B1 (en) * | 1999-08-17 | 2002-05-21 | 상 을 이 | Safety type system for purifying water without using chemical agents |
CN103111258A (en) * | 2013-02-22 | 2013-05-22 | 山东大学 | Reaction column filled with river-sand loaded graphene oxide/titanium dioxide (GO/TiO2) filler |
CN104150717A (en) * | 2014-08-22 | 2014-11-19 | 同济大学 | Ozone-biological activated carbon combined water treatment simulation experimental device |
-
1988
- 1988-02-22 JP JP63037422A patent/JPH01215395A/en active Pending
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH03157186A (en) * | 1989-11-14 | 1991-07-05 | Isomura Housui Kiko Kk | Water cleaning treatment device |
KR100337541B1 (en) * | 1999-08-17 | 2002-05-21 | 상 을 이 | Safety type system for purifying water without using chemical agents |
CN103111258A (en) * | 2013-02-22 | 2013-05-22 | 山东大学 | Reaction column filled with river-sand loaded graphene oxide/titanium dioxide (GO/TiO2) filler |
CN104150717A (en) * | 2014-08-22 | 2014-11-19 | 同济大学 | Ozone-biological activated carbon combined water treatment simulation experimental device |
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