JPH01193559A - High temperature heat storage device - Google Patents

High temperature heat storage device

Info

Publication number
JPH01193559A
JPH01193559A JP63014647A JP1464788A JPH01193559A JP H01193559 A JPH01193559 A JP H01193559A JP 63014647 A JP63014647 A JP 63014647A JP 1464788 A JP1464788 A JP 1464788A JP H01193559 A JPH01193559 A JP H01193559A
Authority
JP
Japan
Prior art keywords
heat
heat storage
temperature
heating medium
storage material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP63014647A
Other languages
Japanese (ja)
Inventor
Tsutomu Tomita
冨田 勉
Masanori Ebe
江部 正紀
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Chubu Electric Power Co Inc
Kawasaki Heavy Industries Ltd
Original Assignee
Chubu Electric Power Co Inc
Kawasaki Heavy Industries Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Chubu Electric Power Co Inc, Kawasaki Heavy Industries Ltd filed Critical Chubu Electric Power Co Inc
Priority to JP63014647A priority Critical patent/JPH01193559A/en
Publication of JPH01193559A publication Critical patent/JPH01193559A/en
Pending legal-status Critical Current

Links

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/14Thermal energy storage

Abstract

PURPOSE:To safely and easily retrieve a quantity of heat at a desired temperature by providing a heating medium circuit of a closed loop having a buffer tank through which the heating medium flows which does not have a phase change between the storage temperature of heat storage material and the service temperature with an inert gas filled the top of the tank. CONSTITUTION:The storage unit 1 has a heat exchanger 7, and the flow passage 8 in the heat exchanger 7 and the heat transfer pipe 6 in the latent heat storage unit 1 are connected by means of a heating medium circuit 9 of a closed circulation loop. A circulation pump 10 is disposed in a portion of the heating medium circuit 9 between the heat exchanger 7 and the latent heat storage unit 1 to circulate the heating medium. A buffer tank 11 is disposed at a suitable location in the heating medium circuit 9. An inert and noncondensible gas such as nitrogen gas is filled in the top of the buffer tank 11 to absorb the cubical expansion due to the thermal expansion of the heating medium and prevent the deterioration of the heating medium due to oxidization. By regulating the flow rate of the heating medium through the heating medium circuit 9 to a level enough to transport a quantity of heat required turn cold water into hot water or steam, hot water or steam can be delivered at a desired temperature and in a desired amount.

Description

【発明の詳細な説明】 産業上の11 本発明は、高温蓄熱システムに関する。[Detailed description of the invention] industrial 11 The present invention relates to a high temperature heat storage system.

【東11 太陽熱や産業廃熱等の間けつ的エネルギー、あるいは供
給と需要との時間がずれる深夜電力等の有効利用手段と
して、エルルギーを熱の形で蓄える各種の顕然蓄熱シス
テムや物質の固相と液相との間の相変化の際の潜熱を利
用して一定の温度で蓄熱する潜熱蓄熱システムあるいは
化学蓄熱システムが研究開発されている。
[East 11] As a means of effectively utilizing intermittent energy such as solar heat and industrial waste heat, or late-night electricity where the time between supply and demand is different, there are various explicit heat storage systems and solid materials that store energy in the form of heat. Latent heat storage systems or chemical heat storage systems that store heat at a constant temperature by utilizing latent heat during a phase change between a phase and a liquid phase are being researched and developed.

潜熱蓄熱システムにつき言及するならば、物質はその化
学組成により、ある圧力の下では一定の温度で熱を吸収
して固体から液体になり、熱を放出して液体から固体に
なる。この相変化に伴って吸収、又は放出する熱量は潜
熱と呼ばれるが、単位質当りの潜熱が大きく、換言すれ
ば蓄熱密度が高く、かつ、その相変化温度、すなわち蓄
熱温度が利用する流体温度に対して適度に高いものは潜
熱蓄熱材として優れている。
Referring to latent heat storage systems, substances, depending on their chemical composition, can absorb heat and change from a solid to a liquid at a certain temperature under a certain pressure, and change from a liquid to a solid by releasing heat. The amount of heat absorbed or released due to this phase change is called latent heat, but the latent heat per unit mass is large, in other words, the heat storage density is high, and the phase change temperature, that is, the heat storage temperature, is equal to the temperature of the fluid used. On the other hand, those with moderately high values are excellent as latent heat storage materials.

低温潜熱蓄熱材としては、塩水化物、いくつかの有機物
、これらの共晶物、包接膨水化物などが挙げられ、高温
用としては金属および各種の溶融塩が挙げられる。溶融
塩としては、例えば450℃以下では苛性ソーダ系共融
混合塩が適している。これを利用して、夜間電力や従来
利用し難くかった問けつ的エネルギーを熱として蓄熱す
る場合、従来のタンクに貯溜した水を加熱して昇温させ
m熱として蓄熱するものに比して高温でかつ単位重量当
りの蓄熱量が大きくできるため装置を小型化することが
可能となる。
Examples of low-temperature latent heat storage materials include chlorides, some organic substances, their eutectics, and clathrate swollen hydrates, and examples of high-temperature materials include metals and various molten salts. As the molten salt, for example, a caustic soda-based eutectic mixed salt is suitable at temperatures below 450°C. When this is used to store nighttime electricity or critical energy that has traditionally been difficult to use as heat, compared to conventional methods that heat water stored in a tank to raise its temperature and store it as heat. Since the temperature is high and the amount of heat stored per unit weight can be increased, it is possible to downsize the device.

しかし、温水や100℃又はそれより若干高い温度の蒸
気を得ることを目的とした場合、例えば1笹記の炭酸ソ
ーダと苛性ソーダの共融混合塩を蓄熱材として使用した
蓄熱槽中に設けた伝熱管に水を流通させるとすると、蓄
熱温度が高温であることが逆に作用し水と蓄熱材との温
度差が大きいため、伝熱管中の水は瞬間的に蒸発し、そ
の圧力で装置は破壊してしまい、この装置では、高密度
に蓄熱された蓄熱材から所要の温度の流体を容易にかつ
安全に、必要な量を取出すことが困難である。
However, when the purpose is to obtain hot water or steam at a temperature of 100°C or slightly higher, for example, a heat storage tank using a eutectic mixed salt of soda carbonate and caustic soda as a heat storage material is used. When water is passed through the heat transfer tubes, the high heat storage temperature has a negative effect on the temperature difference between the water and the heat storage material, so the water in the heat transfer tubes instantly evaporates, and the pressure causes the device to With this device, it is difficult to easily and safely extract a required amount of fluid at a desired temperature from a heat storage material in which heat is stored in a high density.

目  的 本発明は、上記の実情にかんがみ、高温高密度に蓄熱さ
れた蓄熱材より所要の温度の熱を必要に応じて必要な量
を安全かつ容易に取出すことのできる蓄熱システムを提
供することを目的とする。
Purpose: In view of the above-mentioned circumstances, the present invention provides a heat storage system that can safely and easily extract heat at a desired temperature and amount as needed from a heat storage material that stores heat at high temperature and high density. With the goal.

目的達成のための手段 本発明によるN熱システムは、上記の目的を達成きせる
ため、所定の高温で蓄熱可能な蓄熱材を内蔵し、外部熱
源による上記蓄熱材の加熱手段と、上記蓄熱材に蓄熱さ
れた熱を内部を流れる熱媒体に伝熱する伝熱手段とを有
する蓄熱器と、上記の伝熱手段と、利用する温度の流体
との間に熱交換を行なう熱交換器とを含み、内部を上記
の蓄熱材の蓄熱温度と利用温度との間で相変化のない熱
媒体流体が流れ不活性ガスを上部に封入したバフアータ
ンクを有する閏ループをなす熱媒体循環路とを有するこ
とを特徴とする。
Means for Achieving the Object In order to achieve the above object, the N-thermal system according to the present invention includes a built-in heat storage material capable of storing heat at a predetermined high temperature, a heating means for the heat storage material by an external heat source, and a heat storage material for the heat storage material. A heat storage device having a heat transfer means for transferring the stored heat to a heat medium flowing inside the heat storage device, and a heat exchanger for performing heat exchange between the heat transfer means and a fluid at the temperature to be used. , having a heat medium circulation path in the form of a leap loop, through which a heat medium fluid with no phase change between the heat storage temperature of the heat storage material and the usage temperature flows, and a buffer tank in which an inert gas is sealed in the upper part. Features.

丸11 以下、本発明を、図面に示す実施例に基づいて、詳細に
説明する。
Circle 11 Hereinafter, the present invention will be described in detail based on embodiments shown in the drawings.

第1図は、本発明の潜熱蓄熱システムの1実施例の概略
構成を示す図である。
FIG. 1 is a diagram showing a schematic configuration of one embodiment of the latent heat storage system of the present invention.

この実施例の蓄熱システムは、夜間電力等のエネルギー
を熱の形で潜熱蓄熱材に蓄え、必要に応じて湯又は蒸気
として外部に取り出すシステムである。
The heat storage system of this embodiment is a system that stores energy such as nighttime electricity in the form of heat in a latent heat storage material and extracts it to the outside as hot water or steam as necessary.

潜熱蓄熱器1を構成する容器2内には、300℃前後で
固液相変化をする苛性ソーダ系の共融混合塩から成る潜
熱蓄熱材3が充填されている。容器2内の蓄熱材3中に
は、夜間電力等4により加熱される発熱体、例えばパイ
プヒータ5が設けられている。容器2内の蓄熱材3中に
は、さらに、内部を熱媒体が流れる伝熱管6が設けられ
ている。
A container 2 constituting the latent heat storage device 1 is filled with a latent heat storage material 3 made of a caustic soda-based eutectic mixed salt that undergoes a solid-liquid phase change at around 300°C. In the heat storage material 3 in the container 2, a heating element, for example a pipe heater 5, which is heated by nighttime electric power or the like 4 is provided. The heat storage material 3 in the container 2 is further provided with a heat transfer tube 6 through which a heat medium flows.

蓄熱器1には、上記の熱媒体と水との間に熱交換を行な
う熱交換器7が蓄熱器1と一体化又は別設して設けられ
ている。熱交換器7のE足熱媒体の流路8と、前記の潜
熱蓄熱器1内の伝熱管6を結んで、熱媒体が、これらの
流路8及び伝熱管6を通って循環する閑ループをなす熱
媒体循環路9が配設されている。
The heat storage device 1 is provided with a heat exchanger 7 that exchanges heat between the heat medium and water, either integrated with the heat storage device 1 or provided separately. An idle loop that connects the E foot heat medium flow path 8 of the heat exchanger 7 and the heat transfer tube 6 in the latent heat storage device 1, and the heat medium circulates through these flow paths 8 and the heat transfer tube 6. A heat medium circulation path 9 is provided.

循環路9の熱交換″J9i7から潜熱蓄熱器1に至る流
路には、循環ポンプ10が設けられ、熱媒体を循環路9
内を矢印で示す方向に循環させるようにされており、ま
た、熱媒体循環路9の適宜個所には熱媒体の熱膨張を吸
収するバフアータンク11が設けられている。
A circulation pump 10 is provided in the flow path from the heat exchanger J9i7 of the circulation path 9 to the latent heat storage device 1, and the heat medium is transferred to the circulation path 9.
Buffer tanks 11 are provided at appropriate locations in the heat medium circulation path 9 to absorb thermal expansion of the heat medium.

このバフアータンク11の上部には窒素ガスのような不
活性の不凝縮性ガスが封入されており、熱媒体の熱膨張
による体積膨張を吸収すると共に熱媒体の酸化による劣
化を防止する。
An inert, non-condensable gas such as nitrogen gas is sealed in the upper part of the buffer tank 11, which absorbs volumetric expansion due to thermal expansion of the heat medium and prevents deterioration of the heat medium due to oxidation.

熱交換器7内には、熱媒体の流路8と熱交換壁を介して
接し水を湯にするための水の流路12と水を蒸気にする
ための水・蒸気流路13が設けられている。熱交換器7
から出た、湯配管14及び蒸気配管15には夫々止弁1
6,17が設けられている。
Inside the heat exchanger 7, there are provided a water flow path 12 for turning water into hot water and a water/steam flow path 13 for turning water into steam, which contact the heat medium flow path 8 via a heat exchange wall. It is being heat exchanger 7
A stop valve 1 is installed in each of the hot water pipe 14 and the steam pipe 15 coming out of the
6 and 17 are provided.

熱媒体循環路9内を流す熱媒体としては、潜熱蓄熱器1
内の蓄熱材の蓄熱温度、すなわちこの実施例の場合30
0℃前後と、熱交換器7内を流れる水の温度(最低で0
℃)との閏で常に液相状態を保つ物質が使用されている
。このような熱媒体としては、例えばNeo SK o
il −1400(綜研化学株式会社の商品名)等の有
機系熱媒体を使用することができる。
As the heat medium flowing in the heat medium circulation path 9, the latent heat storage device 1
The heat storage temperature of the heat storage material within, that is, in this example, 30
The temperature of the water flowing in the heat exchanger 7 is around 0°C (minimum 0°C).
A substance that maintains a liquid phase at all times is used. As such a heat medium, for example, Neo SK o
An organic heat medium such as il-1400 (trade name of Soken Kagaku Co., Ltd.) can be used.

この装置は、以上の如く構成されているので、伝熱管6
、熱交換器7における伝熱係数を考慮して、湯又は蒸気
の使用量に応じて熱媒体循環路9を循環する熱媒体の流
量を、水を湯又は蒸気にするのに必要な熱量を運搬する
だけの流量にすることにより、水は急激に加熱されて爆
発的に蒸発することなく、必要な流量の所定温度の湯又
は蒸気を得ることができる。
Since this device is configured as described above, the heat exchanger tube 6
, taking into account the heat transfer coefficient in the heat exchanger 7, the flow rate of the heat medium circulating through the heat medium circuit 9 according to the amount of hot water or steam used, and the amount of heat required to turn water into hot water or steam. By setting the flow rate to just enough to transport the water, it is possible to obtain the required flow rate of hot water or steam at a predetermined temperature without the water being rapidly heated and evaporating explosively.

また、熱媒体は閑空間である熱媒体循環路9の中にあっ
て、熱の取出し状況の変化に伴ない温度が変化するがそ
れに伴う熱膨張はバフデータンク11中の不活性かつ不
凝縮の窒素ガスの空間により吸収され、循環路9を破損
することはない。
In addition, the heat medium is located in the heat medium circulation path 9, which is a quiet space, and the temperature changes as the heat extraction situation changes. It is absorbed by the gas space and does not damage the circulation path 9.

第2図は、第1図で説明した潜熱蓄熱システムにおいて
、熱交換器7より取出す湯又は蒸気の流量に応じて、熱
媒体の循環速度を自動的に最適の値に調整することので
きる装置を示す図である。
FIG. 2 shows a device that can automatically adjust the circulation speed of the heat medium to an optimal value according to the flow rate of hot water or steam taken out from the heat exchanger 7 in the latent heat storage system explained in FIG. 1. FIG.

この装置では、熱媒体の循環路9の熱交換器7から潜熱
蓄熱器1に至る部分に設けられた循環ボン110は、所
要熱量を運搬するのに充分な流量の定量ポンプであり、
これと併列にバイパス管21を設け、このバイパス管2
1の循環ポンプ10の吐出側での合流点23の下流側に
流N調整弁23を設けるとともに、熱交換器7からの湯
、蒸気出口側配管14.15の熱交換器出口直近に、そ
の部分を流れる湯又は蒸気の温度検知器24.25を設
け、その検出温度と、所定の温度との差により、上記流
量調整弁の開度を自動調整するようにされている。
In this device, a circulation bong 110 provided in a portion of the heat medium circulation path 9 from the heat exchanger 7 to the latent heat storage device 1 is a metering pump with a flow rate sufficient to convey the required amount of heat,
A bypass pipe 21 is provided in parallel with this, and this bypass pipe 2
A flow N adjustment valve 23 is provided downstream of the confluence 23 on the discharge side of the circulation pump 10 of No. 1, and the hot water from the heat exchanger 7 and the steam outlet side piping 14. Temperature detectors 24, 25 for the hot water or steam flowing through the section are provided, and the opening degree of the flow rate regulating valve is automatically adjusted based on the difference between the detected temperature and a predetermined temperature.

温度検知器24又は25で検知された流体の実際温度が
設定温度に達する迄は流量調整弁23は全開に制御され
、熱媒体はポンプ10の能力により決定される一定の流
量で流れ蓄熱材3から熱を取得して昇温し、熱交換器7
より排出される流体の温度は漸次上昇する。温度検知器
により検知された流体の実際温度が設定温度を超すと、
その温度差に応じて流量調整弁23の開度を絞ることに
より、ポンプ10より吐出された熱媒体は、流量調整弁
の絞り度に応じてバイパス21を循環し、伝熱管6及び
熱交換器7内の熱媒体流路8を通る循環路9を流れる流
量は減少し、蓄熱材3から水に運搬される熱量は減少し
、湯又は蒸気の温度は所定の温度に維持される。
The flow rate regulating valve 23 is controlled to be fully open until the actual temperature of the fluid detected by the temperature sensor 24 or 25 reaches the set temperature, and the heat medium flows at a constant flow rate determined by the capacity of the pump 10, and the heat storage material 3 heat exchanger 7.
The temperature of the fluid discharged increases gradually. When the actual temperature of the fluid detected by the temperature sensor exceeds the set temperature,
By restricting the opening degree of the flow rate adjustment valve 23 according to the temperature difference, the heat medium discharged from the pump 10 circulates through the bypass 21 according to the degree of restriction of the flow rate adjustment valve. The flow rate flowing through the circulation path 9 passing through the heat medium flow path 8 in the heating medium 7 decreases, the amount of heat transferred from the heat storage material 3 to the water decreases, and the temperature of the hot water or steam is maintained at a predetermined temperature.

湯又は蒸気の出目弁16.17の開度を変え、湯又は蒸
気の流量を変えると、湯又は蒸気の温度が変化するので
、自動的に流量調整弁の開度が変り、熱媒体循環路を循
環する熱媒体の流路が変り、湯又は蒸気は設定された温
度になる。
If you change the opening degree of the hot water or steam outlet valve 16 or 17 and change the flow rate of hot water or steam, the temperature of the hot water or steam will change, so the opening degree of the flow rate adjustment valve will automatically change, and the heat medium circulation will be improved. The flow path of the heat medium circulating through the path changes, and the hot water or steam reaches the set temperature.

上記の実施例では、潜熱蓄熱材として融点が300℃前
後の苛性ソーダ系の潜熱蓄熱材を用い、熱媒体としてN
eo SK oil−1400を使用して湯又は蒸気を
取出す装置を説明したが、本発明はこれに限定されるも
のではなく、上記のものと異る蓄熱材と、これに応じた
適当な熱媒体を介して、種々の流体を加熱するシステム
に応用することができる。
In the above example, a caustic soda-based latent heat storage material with a melting point of around 300°C was used as the latent heat storage material, and N was used as the heat medium.
Although a device for extracting hot water or steam using eo SK oil-1400 has been described, the present invention is not limited thereto, and may include heat storage materials different from those described above and appropriate heat medium accordingly. It can be applied to systems for heating various fluids through the heating method.

効  果 以上の如く、本発明によれば、夜間電力のような低コス
トのエネルギーや、通常利用困難な間けつ的エネルギー
を、コンパクトな装置に蓄えて必要に応じて容易、かつ
安全に利用することが可能となる。
Effects As described above, according to the present invention, low-cost energy such as nighttime electricity and intermittent energy that is normally difficult to use can be stored in a compact device and used easily and safely as needed. becomes possible.

【図面の簡単な説明】[Brief explanation of the drawing]

第1図は本発明の実施例のN熱システムの概略構成を示
す系統図、第2図はその利用流体温度の自動調整装置の
一例を示す系統図である。 1・−・蓄熱器、2・・・容器、3・・・蓄熱材、4・
・・深夜電力(外部熱源)、 5・−バイズヒータ(加熱手段)、
FIG. 1 is a system diagram showing a schematic configuration of an N-thermal system according to an embodiment of the present invention, and FIG. 2 is a system diagram showing an example of an automatic adjustment device for the temperature of the fluid used. 1... Heat storage device, 2... Container, 3... Heat storage material, 4...
・・Late-night power (external heat source), 5.-Vise heater (heating means),

Claims (3)

【特許請求の範囲】[Claims] (1)高温で蓄熱可能な蓄熱材を内蔵し、外部熱源によ
る上記蓄熱材の加熱手段と、上記蓄熱材に蓄熱された熱
を内部を流れる熱媒体に伝熱する伝熱手段とを有する蓄
熱器と、 上記の伝熱手段と、利用する温度の流体と の間に熱交換を行なう熱交換器とを含み、内部を上記の
蓄熱材の蓄熱温度と利用温度との間で相変化のない熱媒
体流体が流れ不活性ガスを上部に封入したバフアータン
クを有する閉ループをなす熱媒体循環路とを有すること
を特徴とする蓄熱システム。
(1) A heat storage having a built-in heat storage material capable of storing heat at a high temperature, a heating means for the heat storage material using an external heat source, and a heat transfer means for transferring the heat stored in the heat storage material to a heat medium flowing inside the heat storage material. and a heat exchanger for exchanging heat between the heat transfer means and the fluid at the temperature to be used, the interior of which does not undergo a phase change between the heat storage temperature of the heat storage material and the temperature to be used. 1. A heat storage system comprising a closed-loop heat medium circulation path having a buffer tank in which a heat medium fluid flows and an inert gas is sealed in the upper part.
(2)上記の熱媒体循環路の上記熱交換器から蓄熱器に
至る流路に定流量循環ポンプとバイパス管とが並列に設
けられ、循環ポンプ吐出側の該バイパス管の合流点より
下流側の循環路に流量調整弁が設けられ、該流量調整弁
は利用流体の熱交換器出口温度の検出値により弁開度が
制御され、利用流体の取出し温度を制御するようにした
ことを特徴とする請求項1に記載の蓄熱システム。
(2) A constant flow circulation pump and a bypass pipe are provided in parallel in the flow path from the heat exchanger to the heat storage device of the heat medium circulation path, and a downstream side of the confluence of the bypass pipes on the circulation pump discharge side. A flow rate regulating valve is provided in the circulation path, and the opening degree of the flow rate regulating valve is controlled based on the detected value of the heat exchanger outlet temperature of the utilized fluid, thereby controlling the take-out temperature of the utilized fluid. The heat storage system according to claim 1.
(3)上記の熱媒体流体が金属に対する腐食の少ない有
機系熱媒体であることを特徴とする請求項1に記載の潜
熱蓄熱システム。
(3) The latent heat storage system according to claim 1, wherein the heat transfer fluid is an organic heat transfer medium that is less corrosive to metals.
JP63014647A 1988-01-27 1988-01-27 High temperature heat storage device Pending JPH01193559A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP63014647A JPH01193559A (en) 1988-01-27 1988-01-27 High temperature heat storage device

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP63014647A JPH01193559A (en) 1988-01-27 1988-01-27 High temperature heat storage device

Publications (1)

Publication Number Publication Date
JPH01193559A true JPH01193559A (en) 1989-08-03

Family

ID=11866993

Family Applications (1)

Application Number Title Priority Date Filing Date
JP63014647A Pending JPH01193559A (en) 1988-01-27 1988-01-27 High temperature heat storage device

Country Status (1)

Country Link
JP (1) JPH01193559A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102128503A (en) * 2011-02-23 2011-07-20 南京工业大学 Automatic heat storage hot water tank capable of being rapidly started to heat and automatic heat storage method

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102128503A (en) * 2011-02-23 2011-07-20 南京工业大学 Automatic heat storage hot water tank capable of being rapidly started to heat and automatic heat storage method

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